38PRIMER6_SDS.pdf

CHT UK BRIDGWATER LTD
PRIMER NO 6
Revision nr.2
Dated 2/2/2024
Printed on 2/2/2024
Page n. 1 / 11
Replaced revision:1 (Dated 11/3/2020)
EN
EPY 11.6.1 – SDS 1004.14
Safety Data Sheet

According to U.S.A. Federal Hazcom 2012
1. Identification

1.1. Product identifier

Product name PRIMER NO 6

1.2. Relevant identified uses of the substance or mixture and uses advised against

Intended use Primer.

1.3. Details of the supplier of the safety data sheet

Name CHT UK BRIDGWATER LTD
Full address Amber House Showground Road
District and Country TA6 6AJ Bridgwater (Somerset)
England
Tel. +44(0)1278411400
Fax +44(0)1278411444
e-mail address of the competent person
responsible for the Safety Data Sheet info.uk@cht.com

Supplier: CHT USA, Inc.
805 Wolfe Avenue
Cassopolis, MI 49031

1.4. Emergency telephone number

For urgent inquiries refer to Transport: +1-703-527-3887 CHEMTREC (North America, 24 hours) (CCN 1014369)
Toll Free: 1-800-424-9300 CHEMTREC (North America, 24 hours)
+52 55 8526 4930 CHEMTREC (Central America, 24 hours)
+55 11 4349 1359 CHEMTREC (South America, 24 hours)

2. Hazards identification

2.1. Classification of the substance or mixture

The product is classified as hazardous pursuant to the provisions set forth in OSHA Hazard Communication Standard (HCS) (29 CFR
1910.1200). The product thus requires a safety datasheet.
Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet.

Classification and Hazard Statement
Flammable liquid, category 3 Flammable liquid and vapour.
Acute toxicity, category 4 Harmful if swallowed.
Specific target organ toxicity – repeated exposure,
category 2
May cause damage to organs through prolonged or repeated
exposure.
Serious eye damage, category 1 Causes serious eye damage.
Skin irritation, category 2 Causes skin irritation.
Hazard pictograms:

Signal words: Danger

Hazard statements:
H226 Flammable liquid and vapour.
H302 Harmful if swallowed.
H373 May cause damage to organs through prolonged or repeated exposure.
H318 Causes serious eye damage.
H315 Causes skin irritation.

CHT UK BRIDGWATER LTD
PRIMER NO 6
Revision nr.2
Dated 2/2/2024
Printed on 2/2/2024
Page n. 2 / 11
Replaced revision:1 (Dated 11/3/2020)
EN
EPY 11.6.1 – SDS 1004.14
2. Hazards identification… / >>
Precautionary statements:
Prevention:
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P260 Do not breathe dust / fume / gas / mist / vapours / spray.
P242 Use only non-sparking tools.
P233 Keep container tightly closed.
P280 Wear protective gloves / eye protection / face protection.
P270 Do not eat, drink or smoke when using this product.
P264 Wash . . . thoroughly after handling.
P240 Ground / bond container and receiving equipment.
P243 Take precautionary measures against static discharge.
P241 Use explosion-proof electrical / ventilating / lighting / . . . / equipment.
Response:
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water / shower.
P310 Immediately call a POISON CENTER / doctor / . . .
P330 Rinse mouth.
P302+P352 IF ON SKIN: wash with plenty of water / . . .
P362+P364 Take off contaminated clothing and wash it before reuse.
P370+P378 In case of fire: use . . . to extinguish.
Storage:
P403+P235 Store in a well-ventilated place. Keep cool.
Disposal:
P501 Dispose of contents / container to . . .

The mixture contains 10.38% of components of unknown acute oral toxicity.

2.2. Other hazards

Information not available

3. Composition/information on ingredients

3.1. Substances

Information not relevant

3.2. Mixtures

Contains:

Identification x = Conc. % Classification:

TETRA N BUTYL TITANATE
5 x < 6 Flammable liquid, category 3 H226, Serious eye damage, category 1 H318, Skin irritation, category 2 H315, Specific target organ toxicity - single exposure, category 3 H335, Specific target organ toxicity - single exposure, category 3 H336 EC 227-006-8 CAS 5593-70-4 REACH Reg. 01-2119967423-33 TETRAKIS (2-BUTOXYETHYL) ORTHOSILICATE 4,5 x < 5 Specific target organ toxicity - repeated exposure, category 2 H373, Skin irritation, category 2 H315 EC 242-560-0 CAS 18765-38-3 REACH Reg. 01-2120761533-55-0002 * There is a batch to batch variation. The full wording of hazard (H) phrases is given in section 16 of the sheet. 4. First-aid measures 4.1. Description of first aid measures EYES: Remove contact lenses, if present. Wash immediately with plenty of water for at least 30-60 minutes, opening the eyelids fully. Get medical advice/attention. SKIN: Remove contaminated clothing. Rinse skin with a shower immediately. Get medical advice/attention. CHT UK BRIDGWATER LTD PRIMER NO 6 Revision nr.2 Dated 2/2/2024 Printed on 2/2/2024 Page n. 3 / 11 Replaced revision:1 (Dated 11/3/2020) EN EPY 11.6.1 - SDS 1004.14 4. First-aid measures... / >>
INGESTION: Have the subject drink as much water as possible. Get medical advice/attention. Do not induce vomiting unless explicitly
authorised by a doctor.
INHALATION: Get medical advice/attention immediately. Remove victim to fresh air, away from the accident scene. If the subject stops
breathing, administer artificial respiration. Take suitable precautions for rescue workers.

4.2. Most important symptoms and effects, both acute and delayed

Specific information on symptoms and effects caused by the product are unknown.

4.3. Indication of any immediate medical attention and special treatment needed

Information not available

5. Fire-fighting measures

5.1. Extinguishing media

SUITABLE EXTINGUISHING EQUIPMENT
Extinguishing substances are: carbon dioxide, foam, chemical powder. For product loss or leakage that has not caught fire, water spray can
be used to disperse flammable vapours and protect those trying to stem the leak.
UNSUITABLE EXTINGUISHING EQUIPMENT
Do not use jets of water. Water is not effective for putting out fires but can be used to cool containers exposed to flames to prevent
explosions.

5.2. Special hazards arising from the substance or mixture

HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE
Excess pressure may form in containers exposed to fire at a risk of explosion. Do not breathe combustion products.

5.3. Advice for firefighters

GENERAL INFORMATION
Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for
health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of
contaminated water used for extinction and the remains of the fire according to applicable regulations.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS
Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with
self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137).

6. Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Block the leakage if there is no hazard.
Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent
any contamination of skin, eyes and personal clothing. These indications apply for both processing staff and those involved in emergency
procedures.

6.2. Environmental precautions

The product must not penetrate into the sewer system or come into contact with surface water or ground water.

6.3. Methods and material for containment and cleaning up

Collect the leaked product into a suitable container. Evaluate the compatibility of the container to be used, by checking section 10. Absorb
the remainder with inert absorbent material.
Make sure the leakage site is well aired. Contaminated material should be disposed of in compliance with the provisions set forth in point
13.

6.4. Reference to other sections

Any information on personal protection and disposal is given in sections 8 and 13.

CHT UK BRIDGWATER LTD
PRIMER NO 6
Revision nr.2
Dated 2/2/2024
Printed on 2/2/2024
Page n. 4 / 11
Replaced revision:1 (Dated 11/3/2020)
EN
EPY 11.6.1 – SDS 1004.14
7. Handling and storage

7.1. Precautions for safe handling

Keep away from heat, sparks and naked flames; do not smoke or use matches or lighters. Without adequate ventilation, vapours may
accumulate at ground level and, if ignited, catch fire even at a distance, with the danger of backfire. Avoid bunching of electrostatic charges.
Do not eat, drink or smoke during use. Remove any contaminated clothes and personal protective equipment before entering places in
which people eat. Avoid leakage of the product into the environment.

7.2. Conditions for safe storage, including any incompatibilities

Store only in the original container. Store in a cool and well ventilated place, keep far away from sources of heat, naked flames and sparks
and other sources of ignition. Keep containers away from any incompatible materials, see section 10 for details.

7.3. Specific end use(s)

Information not available

8. Exposure controls/personal protection

8.1. Control parameters

Regulatory references:

EU OEL EU Directive (EU) 2022/431; Directive (EU) 2019/1831; Directive (EU) 2019/130; Directive (EU)
2019/983; Directive (EU) 2017/2398; Directive (EU) 2017/164; Directive 2009/161/EU; Directive
2006/15/EC; Directive 2004/37/EC; Directive 2000/39/EC; Directive 98/24/EC; Directive
91/322/EEC.

TETRAKIS (2-BUTOXYETHYL) ORTHOSILICATE
Threshold Limit Value
Type Country TWA/8h STEL/15min Remarks / Observations
mg/m3 ppm mg/m3 ppm
OEL EU 98

INHAL

Legend:
(C) = CEILING ; INHAL = Inhalable Fraction ; RESP = Respirable Fraction ; THORA = Thoracic Fraction.

8.2. Exposure controls

As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is
well aired through effective local aspiration. Personal protective equipment must comply with current regulations.
HAND PROTECTION
Protect hands with category III work gloves.
The following should be considered when choosing work glove material (OSHA 29 CFR 1910.138): compatibility, degradation, failure time
and permeability.
The work gloves’ resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves’ wear time depends
on the duration and type of use.
SKIN PROTECTION
Wear category I professional long-sleeved overalls and safety footwear. Wash body with soap and water after removing protective clothing.
EYE PROTECTION
Wear airtight protective goggles (OSHA 29 CFR 1910.133).
RESPIRATORY PROTECTION
If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, wear a mask with a
NIOSH certified filter, whose class must be chosen according to the limit of use concentration (NIOSH 42 CFR 84, OSHA 29 CFR
1910.134). In the presence of gases or vapours of various kinds and/or gases or vapours containing particulate (aerosol sprays, fumes,
mists, etc.) combined filters are required.
Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker’s exposure to the
threshold values considered. The protection provided by masks is in any case limited.
If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an
emergency, wear open-circuit compressed air breathing apparatus or external air-intake breathing apparatus. For a correct choice of
respiratory protection device, see standard NIOSH 42 CFR 84, OSHA 29 CFR 1910.134.
ENVIRONMENTAL EXPOSURE CONTROLS
The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure
compliance with environmental standards.

CHT UK BRIDGWATER LTD
PRIMER NO 6
Revision nr.2
Dated 2/2/2024
Printed on 2/2/2024
Page n. 5 / 11
Replaced revision:1 (Dated 11/3/2020)
EN
EPY 11.6.1 – SDS 1004.14
9. Physical and chemical properties

9.1. Information on basic physical and chemical properties

Properties Value Information
Appearance liquid
Colour straw-coloured
Odour characteristic of solvent
Odour threshold not available
pH not available
Melting point / freezing point not available
Initial boiling point not available
Boiling range not available
Flash point 28 C (82.4 F)
Evaporation rate not available
Flammability not available
Lower inflammability limit not available
Upper inflammability limit not available
Lower explosive limit not available
Upper explosive limit not available
Vapour pressure not available
Vapour density not available
Relative density 0.83
Solubility immiscible with water
Partition coefficient: n-octanol/water not available
Auto-ignition temperature not available
Decomposition temperature not available
Viscosity 1.2048 cSt Temperature: 23 C
Explosive properties not available
Oxidising properties not available
9.2. Other information

Information not available

10. Stability and reactivity

10.1. Reactivity

There are no particular risks of reaction with other substances in normal conditions of use.

10.2. Chemical stability

The product is stable in normal conditions of use and storage.

10.3. Possibility of hazardous reactions

The vapours may also form explosive mixtures with the air.

10.4. Conditions to avoid

Avoid overheating. Avoid bunching of electrostatic charges. Avoid all sources of ignition.

10.5. Incompatible materials

Information not available

10.6. Hazardous decomposition products

In the event of thermal decomposition or fire, gases and vapours that are potentially dangerous to health may be released.

11. Toxicological information

In the absence of experimental data for the product itself, health hazards are evaluated according to the properties of the substances it
contains, using the criteria specified in the applicable regulation for classification.
It is therefore necessary to take into account the concentration of the individual hazardous substances indicated in section 3, to evaluate the
toxicological effects of exposure to the product.

CHT UK BRIDGWATER LTD
PRIMER NO 6
Revision nr.2
Dated 2/2/2024
Printed on 2/2/2024
Page n. 6 / 11
Replaced revision:1 (Dated 11/3/2020)
EN
EPY 11.6.1 – SDS 1004.14
11. Toxicological information… / >>
11.1. Information on toxicological effects

Metabolism, toxicokinetics, mechanism of action and other information

Information not available

Information on likely routes of exposure

Information not available

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Information not available

Interactive effects

Information not available

ACUTE TOXICITY

TETRAKIS (2-BUTOXYETHYL) ORTHOSILICATE
> 2000 mg/kg (Rat)LD50 (Oral):

SKIN CORROSION / IRRITATION

Causes skin irritation

SERIOUS EYE DAMAGE / IRRITATION

Causes serious eye damage

RESPIRATORY OR SKIN SENSITISATION