HARWICK
STANDARD
SAFETY DATA SHEET
STAN.MASK 21600 LEMON
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product identifier
Product Name STAN-MASK 21600 LEMON
Other means of identification
Recommendqd USe of thlr chemical and restrictions on use
Recommended Use Fragrances
Uses advised against No information available
Details of the supplier of the safety data sheet
CAS No
Synonyms
Manufacturered for and Supplied by:
Mixture
None
Harwick Standard Distribution Corporation
P.O. Box 9360
60 S. Seiberling Street Akron, OH 44305 USA
(330) 798-9300
vyww.ha rwi ckstand a rd. com
Classification
This chemical is considered hazardous by the 2A12 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Skin corrosion/irritation – Category 2
Serious eye damage/eye irritation – Category 24
Skin sensitizaiion – Category 1B
Aspiraiion toxicity – Category 1
Label elements
Signal word – Danger
Hazard statements
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Product Name: STAN-MASK 21600 LEMON
t
I
Causes skin irritation
Causes serious eye irritation
May cause an allergic skin reaction
May be fatal if swallowed and enters airways
Appearance clear liquid Physical State @20″C liquid
Precautionary Statements
Wash face, hands and any exposed skin thoroughly after handling
Avoid bre ath i n g d usVfu me/g as/misvva pors/spray
Contaminated work clothing must not be allowed out of the workplace
Wear protective gloves/eye protection/face protection
Odor Characteristic
Specific treatment (see supplemenial first aid instructions on this label)
lF lN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
lf eye irritation persists: Get medical adviceiattention
lF ON SKIN: Wash with plenty of water and soap
Take off conlaminated clothing and wash it before reuse
lf skin irritation or rash occurs: Get medical advice/attention
lF SWALLOWED: lmmediately call a POISON CENTER or doctor
Do NOT induce vomiting
Precautionary Statements – Storage
Store locked up
Precautionary Statements – Disposal
Dispose of contents/container io an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Not applicable
Other lnformation
May be harmful if swallowed Toxic to aquatic life with long lasting effects Very toxic to aquatic life
Unknown acute toxicity 0.75645 % of the mixture consists of ingredient(s) of unknown toxicity
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance
Chemical name CAS No Weiqht-% Trade seciet
D’LIMONENE 5989-27-5 20-30
ORANGE OIL CA 8008-57-9 10 – 20
LEMON TERPENES 6891 7-33-9 10-20
CITRUS OIL 68647-72-3 1Q-20
HEXYL CIN NAMIC ALDEHYDE 1 01 -86-0 10-24
LIME TERPENES 68917-71-5 1- 10
DIHYDRO MYRCENOL 1 8479-58-B 1- l0
BENZYL BENZOATE 120-51,4 1-10
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Product Name: STAN-MASK 21600 LEMON
GRAPEFRUIT OIL FLORIDA 8016-20-4 1 – 10
.The
exact percentage (concentration) of composition has been withheld as a trade secret.
4, FIRST AID MEASURES
Description of first aid measures
lnhalation Remove to fresh air,
Eye contact Rinse thoroughly with plenty of water for at least
’15
minutes, lifting lower and upper eyelids.
Consult a physician.
Skin contact Wash skin with soap and water.
lngestion Clean mouth with water and drink afterwards plenty of water.
Most important symptoms and effects. both acute and delaved
Symptoms No information available
lndication of anv i iate meclical attention and soecialtreAimenf needed
Note to physicians Treat symptomatically
5.FIRE-FIGHTNGMEASURES.
Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.
CAUTION: Use of water spray when fighting fire may be inefficient.
No information available.
Unsuitable extinguishing media
Specific hazards arising from the
chemical
Explosion data
Sensitivity to Mechanical lmpact None.
Sensitivity to Static Discharge None.
Special protective equipment for Firefighters should wear self-contained breathing apparatus and full firefighting turnout
fire-fighters gear. Use personal proiection equipment.
Personal precautions, protective eou ipment a nd emerqency procedures
Personal precautions Ensure adequate ventilaiion.
Environmental precautions
Environmental precautions See Section 12 for additional Ecological lnformation.
Methods and material for containment and cleaninq up
Methods for containment Prevent further leakage or spillage if safe to do so.
ACCIDENTAL E MEAS
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Product Name: STAN-MASK 21600 LEMON
Methods for cleaning uP
Preverrtion of secondary hazards
Pick up and transfer to properly labeled containers.
Clean contaminated objects and areas thoroughly observing environmental regulations
7. HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling Handle in accordance with good industrial hygiene and safety practice.
Conditions for safe storage, including anv incompatibilities
Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place.
8.EXPOSUREcoNTROLS/PERSoNALPROTECTION
Control parameters
Exposure Limits
Appropriate engineerinq controls
Engineering controls
Incliviclual protection measures. Such as personal protective equipment
Eye/face protection
Skin and body protection
Respiratory protection
General hygiene considerations
The following ingredients are the only ingredients of the product above the cut-off level (or
level that contributes to the hazard classification of the mixture) which have an exposure
limit applicable in the region for which this safety data sheet is intended or other
recommended limit. At this time, the other relevant constituents have no known exposure
limits from the sources listed here.
Showers
Eyewash stations
Ventilation systems.
No special protective equipment required.
No special protective equipment required.
No protective equipment is needed under normal use conditions. lf exposure limits are
exceeded or irritation is experienced, ventilation and evacuation may be required.
Handle in accordance with good industrial hygiene and safety practice.
lnformation on basic phvsical and chemical Droperties
Physical State @20″C
liquid
Appearance clear liquld
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Product Name: STAN-MASK 21600 LEMON
Odor
Color
Odor threshold
Specific gravity
Refractive lndex
Propertv
pH
Meltirrg point / freezing point
Boiling point / boiling range
Flash point
Evaporation rate
Flammability {solid, gas)
Flammability Limit in Air
Upper flammability limit;
Lower flammability limit:
Vapor pressure
Vapor density
Relative density
Water solubility
Solubility in other solvents
Partition coefficient
Autoi gn ition temperature
Decom position temperature
Kinematic viscosity
Dynamic viscosity
Explosive properties
Oxidizing properties
Softening point
Molecular weight
VOC Content (%)
Density VALUE
Bulk density
Characteristic
Light Yellow – Yellow
No information available
0.8533 – 0.8733
1.4721 – 1.4921
Values
No data available
No data available
>35’C/95’F
94 “C I 202 ‘F CC (closed cup)
No data available
No data available
No data available
No data available
No data available
No data available
No data available
No data available
No daia available
No data available
No data available
No data available
No data available
No data available
No information available
No information available
No information available
No information available
No information available
No information available
No information available
10. STABILITY AND REAGTIVITY
Reactivity No information available.
Chemical stability Stable under normal conditions.
Possibility of hazardous reactions None under normal processing.
Conditions to avoid None known based on information supplied
lncompatible materials None known based on information supplied
Hazardous decomposition products None known based on information supplied
1 1 . TOXICOLOGICAL INFORM,ATION
lnformation on likelv routes of exposure
Product lnformation
lnhalation Specific test data for the substance or mixture is not available,
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Product Namer STAN-MASK 21600 LEMON
Eye contact Specific test data for the substance or mixture is not available.
Skin contact Specific test data for the substance or mixture is not available.
lngestion Specific test data for the substance or mixture is not available.
lnformation on toxicolooical effects
Symptoms No information available.
Numerical meas u res
_of toxicity
Acute toxicity Specific test data for the subslance or mixture are not available.
h
Skin corrosion/irritation
Serious eye damage/eye irritation
Respiratory or skin sensitization
Germ cell mutagenicity
Carcinogenicity
Reproductive toxicity
STOT – single exposure
STOT – repeated exposure
Aspiration hazard
No information available.
No information available.
No inforrnation available.
No information available.
No information available.
No information available.
No information available.
No information available.
No information available
table below indicates whether eachenhas listed an asa en
Chemical name- ACGIH IARC
OSHA
D’LIMONENF
_ 5989-27-5
Group 3
X
2.1ECOLOGtcAt-NFORMATION
Ecotoxicity
Persistence and degradability
Bioaccumulation
Other adverse effects
The environmentar impact of this product has not been fuily investigated
No information available.
There is no data for this product.
No information available.
L3.1DISPOSA CONSIDERAto
Waste treatment methods
Waste from residues/unused Dispose of in accordance with local regulations. Dispose of waste in accordance with
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Product Name: STAN-MASK 21600 LEMON
products
Contaminated packaging
environmental legislation.
Do not reuse empty containers.
14. TRANSPORT INFORMATION
DOT Not regulated
IATA
UN/lD no
Proper Shipping Name
Hazard Class
Packing group
ERG Code
Description
IMDG
UN/ID no
Proper Shipping Name
Hazard Class
Packing group
EmS No.
Special Provisions
Marine pollutant
Description
ADR
UN/lD no
Proper Shipping Name
Hazard Class
Packing group
Classification code
Tunnel restriction code
Special Provisions
Description
ADR/RlD.Labels
uN3062
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O S
o
ilt
9L
UN3082, Environmentally hazardous substance, tiquid, n.o.s.(D’ LIMONENE), 9, lll
uN3082
ENVIRONMENTALLY HAZARDOUS SUBSTANCE. LIQUID, N.O.S.
o
ilt
F-A, S-F
274,335
This product contains a chemical which is listed as a marine pollutant according to
IMDG/IMO
UN3082, Environmentally hazardous substance, liquid, n.o s.(D’ LIMONENE), 9, lll
UN3OB2
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIOUID, N,O S.
ilt
M6
E
274,335,601, 375
UN3082, Environmentally hazardous substance, liquid, n.o.s.(D’ LTMONENE), 9, lll
I
-:.
TORYULAREG
lnternational lnventories
TSCA
DSL/NDSL
EINECS/ELINCS
ENCS
IECSC
KECL
Ptccs
Complies
Complies
Complies
No data available
Complies
No data available
Complies
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Product Name: STAN-MASK 21600 LEMON
NZIoC
Atcs
TCSI
No data available
Complies
Complies
section3l3ofTitlelll oftheSuperfundAmendmentsandReauthorizationActof
1gg6(SARA). Thisproductdoesnotcontainany
chemicals which are subject to the reporting requirements of the Act and riile 40 of the code of Federal Regulations, paft372.
Legend:
TSCA – United states Toxic Substances control Act section B(b) lnventory
DSLINDSL – canadian Domestic substances LisvNon-Domestic substanies List
EINE-CS/ELINCS – European. lnventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS – Japan Existing and New Chemical Substances
IECSC – China lnventory of Existing Chemical Substances
KECL – Korean Existing and Evaluated Chemical Substances
Plccs – Philippines rnventory of chemicars and chemicar substances
NZIoC – New Zealand lnventory of Chemicals
AICS – Australian lnventory of Chemical Substances
TCSI – Taiwan Chemical Substance lnventory
US Federal Requlatigns
SARA 313
SARA 3111312 Ha.zard Categories
Acute health hazard
Chronic Health Hazard
Fire hazard
Sudden release of pressure hazard
Reactive Hazard
CWA (Clean Water Act)
This product does not contain any substances
cFR 122.42).
US State Requlations
California Proposition 6E
This product does not contain any proposition
65 chemicals.
U.S, State Riqht-to-Know Regulations
US State Regulations This product may contain substances regulated by state right-to,know regulations
U.S. EPA Label lnformation
EPA Pesticide Registration Number Not applicable
Yes
Yes
No
No
No
regulated as poilutants pursuant to the crean water Act (40 cFR 122.21 and 40
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances underthe Comprehensive
Environmental Response compensation and Liability Act (cEdcLA) (40 cFR 302) or the superfunJ Amendments and
Reaulhorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material.
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Product Name: STAN-MASK 21600 LEMON
1b.OTHERNFoRMATtoNINcLUDINGDATEoFPREPARATONOFTHELA.STREVIsoN
NFPA_
HMIS
lssue Date:
Version #:
Revision Note:
Health hazards 2 Flammability 0
Health hazards 2 Flammability 0
12-08-2017
0’1
No information available
lnstability 0
Physical hazards 0
Physical and chemical
properties –
Personal protection X
Disclaimer: The information and recommendations contained herein are based upon data that are believed to be accurate
and reliable. Application and performance information are provided only as a guide, since the conditions of use are
beyond the control of Harwick Standard Distribution Corporation. Consequently, Hanirick Standard makes no warranties,
express or implied, with respect to the goods or use of the goods or the performance of the goods and makes no
warranties of fitness for a particular purpose or merchantability. Buyer acknowledges that Hinrvick Standard will not be
liable for consequential,,incidental, direct or special damages arising, directly or indirectly, in respect to such goods or
the use orfailure thereof, whether based on breach of warranty, negligence, strict liability in tort or otherwise.
End of Safety Data Sheet
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Product Name: STAN-MASK 21600 LEMON