A. G. Laytrer Inc.
SAFETY DATA SHEET
SDS Distribution: The information in this document
should be made available to all who may handle the
product.
A,G. Layne, lnc, urges each customer or recipient of this SDS to study it carefully and consult appropriate expertise, as necessary or appropriate, to
become aware of and understand the data contained in this SDS and any hazards associated with the product. lt is the Buyer’s/User’s responsibility to
ensure that his activities comply with all Federal, State, Provincial or Local laws. The information presented here pertains only to the product as shipped.
Tha.information contained herein is bassd on our current knowledge of the underlying data and is intended to describe the productfor the purpose of
health, safety and environmental requirements only. Nor,varffHjfil:r;ii”.-J#:?fi:T,1;lffo”to resarding the accuracy of this data or the results
Product lD Denatured Alcohol 190
Denatured Alcohol 190
www.aglayne.com Page ‘l
of 9
SAFETY DATA SHEET
sEcfloN 1) cHEMICAL PRODUCT AND SUPPLIER’S IDENTIFICATION
Product lO:
Product Name:
Revision Date:
Version:
Denatured Ak;ohol 190
Denatured Alcohol 190
Oct 07, 2015
1.1
Date Printed:
Suparsedes Date
Ocl 07, 2015
May
’18,
2015
Addross: 4578 Brazil Street Los Angeles, CA, US, S0039
Emergency Phone: CHEMTREC US : 1-800-424-9300, INTERNATIONAL CALLS: 1-703’527’3887
lnformation Phone: 323-245-2345
Fax:
ProducURecommended Uses: Wood coatings and a variety of industrial applications
sEcTroN 2) HAZARDS IDENTIFICATION
Classification:
Specific Target Organ Toxicity – Single Exposure – Category 1
Skin lrrilation – Category 2
Eye lnitaliorr – Category 2A
Carcinogenicily – Category 2
Flammable Liquids Category 1
Acute toxicity, Oral – Category 4
Plctograms:
Signal Word:
Danqer
Hazardous Statements – Physical:
Extremely flanrmable liquid and vapor
Hazardous Statements – Health:
Harmful if swallowed
Suspocted of causing cancer (slate roule of exposure if it is conclusively proven that no other routes of exposure c ause the hazard)
Causes serious eye irrilation
Causes skin initation
Causes damage to organs.
Precautionary Sialements – General:
lf medical advice is needed, have product container or label at hand.
Keep out o{ reach of children-
Read label before use.
Precautionary Stalements – Prevention:
Wash with soap and waler thoroughly afler handling.
t
a
Denarlured Alcohol 190
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Do not eat, drink or smoke when using this product’
Obtain special inslructions before use’
Do not handle until all safety precaulions have been read and understood.
Wear protective gloves/protective clothing/eye protection/face protection.
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
Keep container tightly closed.
Ground/bond container and receivirrg equipment.
Use explosion-prool electrical/ventilating/lighting equiptnent.
llsc only non-sparking lools.
Take action to prevent static discharges.
Do not breathe dusUfume/gas/misUvapors/spray.
Precautionary Staiements – Response:
lF SWALLOWED: Call a POISON CENTER:/doctor if you feel unwell.
lF expossd ot concerned: Get medical advice/attentior
lF lN EyES: Rinse cauliously with water for several minutes. Remove contact lenses, if present and easy to do. Conlinue rinsing
lf eye initation persisls: Get medical advic6/attenlion.
lF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse with water or shower.
In case of fire: Use DRY chemical, alcohol- resistant foam, water spray/log or carbon-dioxide to extinguish.
lF ON SKIN: Wash with plenty of water.
Specific treatment (see First-aid on this label).
lf skin irritation occurs: Get medical advics/attention.
Take off contamlnated clothlng. And wash lt betore reuse’
lF exposed or concerned: Call a POISON CENTER/doctor/?
Precautionary Statements . Storage:
Store locked up,
Store in a well-ventilated place’ Keep cool.
Precautionary Staiements – Disposal:
Dispt-rsu of r-:urrtsrtts/conlainer to disposal recycling center.
waste managemenl should be in full compliance with federal, state and local laws.
sEcroN 3)COMPOSITION / INFORMATION ON INGREDIENTS
cAs
0000064-1 7-5
0000067-63-0
0007732-1 8-5
0000067-56-1
00001 08-1 0-1
0000075-07-0
Chemical Name
ETHYL ALCOHOL
ISOPROPYL ALCOHOL
WATER
METHANOL
METHYL ISOBUTYL KETONE
ACETALDEHYDE
% By Weight
64% –
g60k
8.360% – 9.240%
6.175% – 6.8250/o
3.990% – 4.410%
0.882″/” – 0.918%
0 – 0.001 %
sEcTloN 4) FIRST-AID MEASURES
lnhalation:
Remove source of exposure or nrove person to fresh air and keep comfortable for breathing. lf victim is not brealhirrg, call 911 and
administer CPR as direcled.
Eliminate all ignition sources if safe to do so.
Skin Contach
Rinse/wash with lukewarm, genily flowirlg water (and mild soap) for 15-20 minutes or until product is removed. ll skin rrritalion occurs ot
you feel unwell: Get medical advice/attention.
Eye Contact:
Denatured Alcohol 190
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Page 3 of 9
Rentove source o{ exposure or move person to fresh air. Rinse eyes cautiotlsly v/ith lukewarrll, gently flowing water for 15-20 minutes,
while holding the eyeiids open. Renrove contact lenses, if present and easy to do. Continue rinsinq. Take care not lo rinse conlaminated
vr’ater into the unaffectecJ eye ot onto the face. Get immidiate medical attention.
lngestion:
Do NOT induce vomiting. lf vomiting occurs naturally, lie on yourside, in the recovery position. lmmediately call 911 POISON
CENTER/doctor/. lnrmediately transport to the nearest nredical facility for trealr.”1enl.
sEcfloN s) FIRE-FIGHTING MEASURES
Suitabl6 Extinguishing Medial
Dry chernrcal, foarn, carbon dioxide or fog is recommende.j. Waler spray is reconlntended to cool ot protect exl:)osed materials or
strlctures- Carbon rJioxide can displace oxygen. Use caution when applyrng carbon dioxtde in confined spaces. Sirnultaneous use of
foam and water on the same surface is to be avoided as water destroys the loam. Sand or earth may be used for small flres only.
Unsuitable Extinguislring Media:
No data available.
Specific Hazards in Gase of Flre:
No data available.
Fi re-fi ghting Procedures;
lsolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done safely. Move undamaged
containers lrom immecliate hazard area if it can be done safely. Water spray may be useful in minimizing or dispersing vapors and to
prolect personnel.
Dispose of fire debris and contaminated extinguishing water in accordance with oflicial regulations.
Special Protective Actions:
Wear protective pressure self-contained breathing apparatus (SCBA) and full turnout gear.
sEcIoN 6) ACCTDENTAL RELEASE MEASURES
Emergency Procedure:
ELIMINATE all ignilion sourc s (no smoking, flares, sparks or flames in immediale area).
RELEASE CAN CAUSE FIRSEXPLOSION. LIOUIDS/VAPORS MAY IGNITE.
Do not inrrch or walk lhrough spilled material.
lsolate hazarcl area and keep unnecessary people away. Remove all possible sources of ignition in the surrounding area. Notify authorities
if any exposure to tlre general public or lhe environmenl occurs ot is likely [o occur.
l{ spilted material is cleaned up using a regulated solvent, the resulting was{e mixture may be regulated.
Recommended Equipment:
positive pressure, full-facepiece self-contained breathing appatatus (SCBA), or positive pressure supplied air respirator with escape SCBA
(NlOSl-l approved).
Personal Precaulions:
Avoid breathing vapor. Avoid contact with skin, eye or clothing. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in
immediate arei;. Use explosive proof equipment. Avoid inhalation of dusl and contacl with skin and eyes. Do not touch damaged
containers or spillecl materials unless wearing appropriate proteciive clothing’
Environmental Precautions:
Stop spill/release if it can hn dona safcly. Prevent spilled malerial from entering sewers, storm drains, other unauthorized drainac-1e systems
and natural wateruays by using sand, earth, or other appropriate barriers.
Methods and Materials for Containment and Cleanlng up:
Sand, clay and absolbent socks can be used to contain a spill’
SECT|ON 7) HANDLING AND STORAGE
General
Wasir hands attet use.
Do not get in eyes, on skin or on clothing.
Do not brealhe vapors or mists.
Use qood personal hygiene practices.
Eating, drinking and srnoking in work areas is prohibited.
Rernove contaminated clolhing and protective equipment bte{ore entering eating areas.
Dr.,nalr;r.erj Alcohol 1 90 www.aglaync.cont Page 4 of 9
Eyewaslr slations ancl showers should be available in areas where this material is used and stored.
Ventilatlon Requirements :
Use only with adequate ventilalion to control air contaminants to their exposure limits. The use of local ventilalion is reconrmended to
control emissions near the source.
Storage Room Requirements:
Keep container(s) tiglrtly closed and properly labeled. Store in cool, dry, well-ventilated areas a{iay from hcat, direct sunlighl, strong
oxidizers and any incompatibilities. Store irr approved cor’ltainefs and protect agailrst physical damage. Keep containers securely sealed
when not in use. lndoor storage should meet OSHA standards and appropriate llre codes. Containers that have been opened must be
carefully resealed to prevent leakage. Ernpty container retairl residue and nray be dangerous.
Use non’sparking venlilation systcms, opprovod oxplosion-proof cqL’liprncnl and intrinsically safc clcctrical systcms in aroas whcrc lhis
product is used and stored.
Ground and bond containers and receiving equiprnent. Avoid static eleclricity by grountling.
other fl ammable products.
Respiratory Protection :
lf engineering controls do not maintain airbome concentrations io a level whiclr is adequate to protect worker, a respiralory protection
progranr lhat meels or is equivalenl to OSHA 29 CFR 1910.134 and ANSI 288.2 should be followed. Check with respiratory protective
equipment suppli6rs.
Skin Protection:
Use of gloves approved to relevant standards nrade from the following rnalerials nray provide suitable chemical proleclion: PVC, neoprene
or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of conlact, chemical
resistance of glove nralerial, glove thickness, dexterity. Always seek advice fronr glove suppliers. Contaminaled gloves should be replaced.
Use oi an apron and over- boots of chenrically impervious materials such as neoprene or nitrile rubber is recommended to avoid skin
sonsitization. The type of protective equipment must be selected according to the concenlralion and amount of the dangerous subslance at
the specific workplace. Launder soiled cloihes or properly disposed o{ contaminated material, which cannot be decontaminated.
Eye Protection;
Wear eye prolection with side shields or
additional prolection is needed for entire
Appropriate Engineering Controls :
goggles. Wear indirect-vent, impact and splash resistanl goggles when working with liquids. lf
face, use in combination with a face shiold.
Provide exhaust ventilation or other engineering controls to keep the airtrorne concentrations of vapors below their respective threshold
limit value.
Chemical Name
ACETALDEHYDE
ETHYL ALCOHOL
ISOPROPYL
ALCOHOL
METHANOL
MFTHYL ISOBUTYL
KETONE
Chemical Name
ACETALDEHYDE
ETHYL ALCOHOL
ISOPROPYL
ALCOHOL
I4ETHANOI
MET}JYL ISOBUTYL
KETONE
OSHA
TWA
(mg/m3)
360
OSHA
STFI
{ppm)
1 900
980
260
410
ACGII{ ACGIH
]WA STEL
{mg/m3)
(ppm)
c25
1 000
400
250
75
OSHA
Tahk;s
iZ1
22,23)
1
OSHA
TWA
(ppm)
200
1 000
400
200
100
ACGIH
TWA
(ppm)
o$l-lA
STFI
(mg/m3)
ACGIH
STEL
(mg/m3)
0iiHA
OSIIA Skin
Carcrnogen desrgnalion
NIOSH
(ppm)
r.llosH
.I-WA
(mg/m3)
NIOSH
STEL
(ppm)
NIOSH
STTL
(mg/m:l)
NIOSH
Carcinogen
I
1000
,t00
200
50
1 900
9BC
26C
205
500
1a1q
250
a”E
15 300
ACGIH ACGIH
Carcinogen Notalions
A2 A2
44;BEl
Skin; BEI
43; BEI
ACGIH
TLV Basis
Eye & URT
!rr
URT irr
Eye &,
URT kr;
CNS imparr
llendrcho.
$Vri dA,I
l-il{ [ irr.
!lil.’ il,tsr
lxi.t(13(tlrr:
A3
A4
328
307
200
200
20
Denatured Alcohol 190
zoz
A3
Paile 5 ol 9www.a.:qlaVrrc.c ;rrr
sEcTroN 9)PHYSICAL AND CHEMICAL PROPERTIES
P[Vsic3! and Chemlcal ProPerties
Specific Gravity
Density
% voc
VOC Actual
Deneity VCIC
% Solids By Weight
0.81
6.75 lb/gal
100.00%
6.75 lb/gal
6 75lb/sal
0.00%
Appearance
Odor Threshold
Odor Description
Water Solubility
Flammabilily
Flash Point Symbol
Flash Point
Vlscosity
Lower Explosion Level
Upper Explosion Level
Vapor Pressure
Vapor Density
Freezing Point
Melting Point
Low Boiling Point
Hlgh Boiling Point
Auto lgnition Temp
Decomposition Pt
Evaporation Rats
Coefficient Water/Oil
VOC Composile Partial Pressure
N/A
Flashpoint bolow 73 “F
c
14 “C
NiA
NiA
N/A
N1A
N/A
NIA
N/A
N/A
N/A
N/A
0
NiA
NiA
Clear liquid
N/A
Characteristic
39.3675 mmHg (Calculated @ 20 cl68 F)
sEcTroN 1o)STABILITY AND REACTIVITY
Stablllty:
Stable under normal conditions ol use.
Conditions to Avoid:
Avoid heal, sparks, open llames and other ignition sources.
Hazardous Reactions/Polymerization :
No data available.
lncompatlble Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Thermal decomposition may yield carbon dioxide and/or carbon monoxido’
sEcTroN 11)TOXICOLOGICAL IN FORMATION
Acute toxicity:
lngestion: May be harmful or fatal if swallowed.
Skin GorrosionJlrritation :
Denatured Alcohol 190
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Causes skin irritation
Serious eye damage/irritation :
Causes serious eye initation
Germ cell mutagenicity:
No data available
Respiratory/Skin Sensitizationt
Slighlly lrritating to respiratory syslenr.
Carcinogenicily:
Strspecled of caLtsing cancer (state route rrf exposlri’e ii it is conclusively proven thal no other routes of exposura c aus6 the hazard)
Reproductlve toxlclty :
No data available
Specific Target Organ Toxicity . Repeated Exposure:
No data available
Aspiration hazard:
No data available
Specific Target Organ Toxicity – Single Exposure:
Cause$ damage to organs.
0000064-17-5 ETHYL ALCOHOL
0000067-63-0 rsoPRoPYL ALCOHOL
0000067-56-1 METHANOL
OOOO1OB.1O.1 METHYL ISOBUTYL KETONE
OOOOOT5-07.0 ACETALDEHYDE
Potential Health Effects – Miscellaneous
0000064-17-5 ETHYLALCOHoL
The following medical conditions may be aggravated by exposure: liver disease. Tests in some laboratory animals indicate this
compound may llave embryotoxic activity. Tssts in anirnals demonslrale reproductive toxicity. lngestion flay causo any oi the following:
stupor(central nervous system depression), gastrointeslinal irrjtalion. ll absorbed through the skin, may be: harmful.
0000067-56-1 METtlANOL
lncreased susceptibility to the effects of this malerrerl ma)/ be observed in people with preexisting disease of any of tho following: oycs,
kidneys, liver, skin. Excessive human exposure to inethanol nray lead to: fatigue, headache, anaesthetic, neurologic effects, and visual
difficulties including blindness or death. Recurrenl overexposLrre nray result in liver and kidney injury, Has been toxic to the fetus in
laboratory animals at doses that are toxic to the molher. lngeslion may cause any of the following: blirrdness. Eye conlact may cause
any of the following: conjunclivitis, mild irritation. corne;rl opacity.
0000067-63-0 TSoPRoPYLALCOHOT.
The following medical conditions may be aggravated by exposure: dermatitis, respiratory disease. Developmental ioxicily was seen itl
rat?s offspring at doses that were maternally toxic. Contact will cause moderate to severe redness and swelling, ilching, tingling
sensation, painful burning. May cause injury to the contea of the eyes. Prolonged or repeated exposure rnay causo damage to any of
the following organsisystems: liver. lngestion studies on laboralory animals showed that very high oral doses caused increased liver
and kidney weights.
OOOOlOB-10-1 METHYL ISOBUTYL KETONE
The following medical conditions may be aggravated by exposurer asthma, respiralory disoase, eye disorders, pulnorrary corrditiorrs,
skin disorders. Repeated or prolonged skin contact may cause any of the following: dryness, cracking of the skin, defatting. lnhalation
may cause any of lhe followingl dizziness, stupor (central nervous syst 11-l d prossion), dl0wsirress, respiratory truct irritatirirr.
sEcTroN 12) ECOLOGTCAL TNFORMATTON
Bio-accumulative Potential:
No data available.
Persistence and Degradability:
No data available.
Mobility in Soil;
No data available.
Toxicity:
,’ , ,.r :Jrllit r,ll- i;i.)fil Paec 7 of I
Denatured Alcohol 190
No data available
Other adverse effecls
No data available.
Mobility in Soil
0000067-56-1 METHANOL
Will not adsorb on soil.
Persistence and Degradability
0000067-s6-1 METHANOL
7 Zoh aer obic biorlcAradability.
sEcTroN 13) D|SPOSAL CONSTDERATTONS
Wryte plqposql
![e!hod:
Under RCRA it is the re ponsibility of the user of lhe product to determine at the lime of disposal whether lhe product meets RCRA crileria
for hazardous waste. Waste management should be in full compliance with federal, state and local laws.
Emply Containers retain product residuo which may exhibit hazards of material, therefore do not pressurize, cut, glaze, weld or use for any
other purposes. Return drums to reclamation centers for proper cleaning ancl reu$o,
sEcTloN 14) TRANSPORT TNFORMATTON
U.S. DOT lnformation:
NA19B7, Denatured Alcohol, 3 PG tt
Emergency Response Guide (ERG);
Emergency Response Guide 127
sEcTtoN 15) REGULATORY TNFORMATTON
cAs
000000,t- 1 7-5
00c0067-63-0
0007732- 1 s,5
0030l]ri7-5(j. I
000010&10-1
Chemical Name
ETHYL ALCOHOL
lsoPRoPYL ALC0t-rOt
WATER
METHANOL
METHYL ISOBUTYL
KETONE
% By Weight Re0ulalioo List
64r/0 – 960/u SARA31 2,VOC,T-CCA,OSHA
8,360% – 9.240% SARA3l2,SARA3l3,VOC,lARCCarcinogen,TSCA,0SHA
6.175%-6.B2506 TSCA
000007F07-0 AcETnrDEl.tYDE
3.990%-4.410%
0.882% – 0.S180/o
0 – 0.001 %
CERCLA,SARA312,SAR4313,V0C,TSCA,RCRA,CA_TAC_TOX.NEt – Narionat Emission$
lnventory,CA_Prcp65 – California Proposition 65,CA*Prop65_Type_Toxicity_Develop –
CA_Proposition6S*Type_Toxicily_Developmental, OSHA
CERCLA,SARA3l2,SARA313,VOC,TSCA,RCM,CA_TAC_TOX,CA_Carcinogen,NEl – Nationat Emissions
lnventory,CA_Prop65 – California Proposition 65,CA_Prop65_Type*Toxicity_Cancer –
CA_Pr0position6S_Type_Toxicity*Cancer,CA_Prop65_Type_Toxicity_Develop –
CA*Proposition6S_Type-Toxicity_Developmental,0SHA
CERCLA,SARA3l2,SARA3l3,V0C,lARCCarcinogen,TSCA,RCRA,CA_TAC*TOX,CA_TAC_Carcinogen,C
A_Carcinogen,NEl – National Emlsslons lnvenlory,CA_Prop65 – Califomia
proposition
65,CA*Prop65_Type*Toxicity_Cancer – CA_Proposition6S_Type_Toxicity_Cancer,OSHA
sEcTtoN {6) oTHER TNFORMATTON
General:
A.G’ Layne, lnc. urges each customer or recipient o{ this SDS to study il carefully and consult appropriate expertise, as necessary or
appropriale, to become aware of and understand the data conlained in this SDS and any hazards associated with the product. lt is the
Buyer’s/User’s responsibility to ensure ihat his activities comply with all Federal, State, Provincial or Local laws. The in[ormation presented
here perlains only to the product as shipped. The inforrnation contained herein is based on our currenl knowleclge of lhe underlying cJata
and is intended to describe lhe product for the purpose of health, safety and environmenlal requirenrents onty. NO warranty or gulraniee
is expressed or implicd regarding the accuracy of lhis data or lhe resu,ts to be obtained from the use of the product.
Denatured Alcohol 190
n,w'”v.arylayne.com Pagre B of I
HMIS
ChronlcE
Change in Section 8-Respirator
DISCLAIMER
To the best of our knowledge, the information contained herein is accuraie. However, neither A, G, Layne, lnc. nor any of its subsidiaries assumes
any liability whatsoever for the accuracy or completeness of the informalion contained herein. Final detonnlnation of suitability of any malerial is the
sole responsibility of the user. All malerials may present unknown hazards and should be used with cautlon. Although cerlain hazards are
described herein, we cannot guarantee that these are the only hazards that exist, The above information penains to this product as currently
forntulated, and is based on lhe inforrnation available at this time. Addition of reducers or other addltives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are outside our conlrol, wo make no warranlies, exprass or implied, and assume
no liabillty in connection with any use of this inforrnation.
Denatured Alcohol 190
www.aglayne.com Pagc 9 of I