10% SURFACING AGENT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue: 10/13/2021 Revision date: 10/2/2024
10/2/2024 (Revision date) EN (English US) 1/15
SECTION 1: Identification
1.1. Identification
Product form : Mixture
Trade name : 10% SURFACING AGENT
CAS-No. : mixture
Product code : 39SURF102 39SURF103
Formula : N/A
1.2. Recommended use and restrictions on use
Use of the substance/mixture : GEL COAT REPAIR ADDITIVE
1.3. Supplier
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909-546-1162
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300
SECTION 2: Hazard(s) identification
2.1. Classification of the substance or mixture
GHS US classification
Flammable liquids Category 2 H225 Highly flammable liquid and vapor
Acute toxicity (inhalation:vapor) Category 4 H332 Harmful if inhaled
Skin corrosion/irritation Category 2 H315 Causes skin irritation
Serious eye damage/eye irritation Category 2 H319 Causes serious eye irritation
Reproductive toxicity Category 2 H361 Suspected of damaging fertility or the unborn child
Specific target organ toxicity (repeated exposure) Category 1 H372 Causes damage to organs through prolonged or repeated
exposure
Hazardous to the aquatic environment – Chronic Hazard Category 3 H412 Harmful to aquatic life with long lasting effects
Full text of H statements : see section 16
2.2. GHS Label elements, including precautionary statements
GHS US labeling
Hazard pictograms (GHS US) :
Signal word (GHS US) : Danger
Hazard statements (GHS US) : H225 – Highly flammable liquid and vapor
H315 – Causes skin irritation
H319 – Causes serious eye irritation
H332 – Harmful if inhaled
10% SURFACING AGENT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/2/2024 (Revision date) EN (English US) 2/15
H361 – Suspected of damaging fertility or the unborn child
H372 – Causes damage to organs through prolonged or repeated exposure
H412 – Harmful to aquatic life with long lasting effects
Precautionary statements (GHS US) : P201 – Obtain special instructions before use.
P202 – Do not handle until all safety precautions have been read and understood.
P210 – Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P233 – Keep container tightly closed.
P240 – Ground/Bond container and receiving equipment.
P241 – Use explosion-proof electrical, lighting, ventilating equipment.
P242 – Use only non-sparking tools.
P243 – Take precautionary measures against static discharge.
P260 – Do not breathe dust, fume, mist, spray, vapors.
P261 – Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 – Wash EXPOSED AREA. thoroughly after handling.
P270 – Do not eat, drink or smoke when using this product.
P271 – Use only outdoors or in a well-ventilated area.
P273 – Avoid release to the environment.
P280 – Wear eye protection, protective clothing, protective gloves.
P302+P352 – If on skin: Wash with plenty of water.
P303+P361+P353 – If on skin (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower.
P304+P340 – If inhaled: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P313 – If exposed or concerned: Get medical advice/attention.
P312 – Call a poison center or doctor if you feel unwell.
P314 – Get medical advice/attention if you feel unwell.
P321 – Specific treatment (see SEEK MEDICAL AID. on this label).
P332+P313 – If skin irritation occurs: Get medical advice/attention.
P337+P313 – If eye irritation persists: Get medical advice/attention.
P362+P364 – Take off contaminated clothing and wash it before reuse.
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish.
P403+P235 – Store in a well-ventilated place. Keep cool.
P405 – Store locked up.
P501 – Dispose of contents/container to LOCAL, STATE, AND NATIONAL REGULATIONS..
2.3. Other hazards which do not result in classification
No additional information available
2.4. Unknown acute toxicity (GHS US)
No additional information available
SECTION 3: Composition/Information on ingredients
3.1. Substances
Not applicable
10% SURFACING AGENT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/2/2024 (Revision date) EN (English US) 3/15
3.2. Mixtures
Name Product identifier % GHS US classification
styrene, inhibited CAS-No.: 100-42-5 82.2 Flam. Liq. 3, H226
Acute Tox. 4 (Inhalation:vapour),
H332
Skin Irrit. 2, H315
Eye Irrit. 2, H319
Repr. 2, H361
STOT RE 1, H372
Aquatic Chronic 3, H412
heptane CAS-No.: 142-82-5 7.1 Flam. Liq. 2, H225
Skin Irrit. 2, H315
STOT SE 3, H336
Asp. Tox. 1, H304
Aquatic Acute 1, H400
Aquatic Chronic 1, H410
Full text of hazard classes and H-statements : see section 16
SECTION 4: First-aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice
(show the label where possible).
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Allow affected person to breathe
fresh air. Allow the victim to rest. Remove victim to fresh air and keep at rest in a position
comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell.
First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Wash
with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs:
wash throughly for five minutes. seek medical attention. Get medical advice/attention. Specific
treatment (see seek medical attention. on this label).
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: SEEK IMMEDIATE MEDICAL ATTENTION. Get
medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a poison
center/doctor/physician if you feel unwell.
4.2. Most important symptoms and effects (acute and delayed)
Potential Adverse human health effects and
symptoms
: Harmful if inhaled.
Symptoms/effects : May cause genetic defects (avoid skin contact and inhalation.). May cause cancer (avoid skin
contact and inhalation.).
Symptoms/effects after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
4.3. Immediate medical attention and special treatment, if necessary
Treat symptomatically.
10% SURFACING AGENT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/2/2024 (Revision date) EN (English US) 4/15
SECTION 5: Fire-fighting measures
5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media : Sand. Water spray. Dry powder. Foam. Carbon dioxide.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Specific hazards arising from the chemical
Fire hazard : Highly flammable liquid and vapor.
Explosion hazard : May form flammable/explosive vapor-air mixture.
Reactivity in case of fire : No reactivity hazard other than the effects described in sub-sections below.
Hazardous decomposition products in case of fire : Toxic fumes may be released.
5.3. Special protective equipment and precautions for fire-fighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Do
not attempt to take action without suitable protective equipment. Self-contained breathing
apparatus. Complete protective clothing.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No
smoking.
6.1.1. For non-emergency personnel
Protective equipment : Gloves. Protective goggles. Protective clothing.
Emergency procedures : Ventilate spillage area. Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Do not attempt to take action without suitable protective equipment. Equip cleanup crew with
proper protection. For further information refer to section 8: “Exposure controls/personal
protection”.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Dam up the liquid spill. Contain released product, pump into suitable containers.
Methods for cleaning up : Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or
diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
Other information : Dispose of materials or solid residues at an authorized site.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection. For further information refer to section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapors are flammable.
10% SURFACING AGENT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/2/2024 (Revision date) EN (English US) 5/15
Precautions for safe handling : Wear personal protective equipment. Wash hands and other exposed areas with mild soap and
water before eating, drinking or smoking and when leaving work. Provide good ventilation in
process area to prevent formation of vapor. No open flames. No smoking. Use only non-sparking
tools. Use only outdoors or in a well-ventilated area. Avoid breathing DUST, FUMES, MIST, OR
VAPORS. Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Eliminate all ignition sources if safe to do so.
Hygiene measures : Wash HANDS thoroughly after handling. Do not eat, drink or smoke when using this product.
Always wash hands after handling the product.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond
container and receiving equipment. Use explosion-proof electrical, ventilating and lighting
equipment. equipment.
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : HEAT SPARKS
OR OPEN FLAMES. Keep in fireproof place. Keep container tightly closed. Store in a well-
ventilated place. Keep cool.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
10% SURFACING AGENT (mixture)
No additional information available
styrene, inhibited (100-42-5)
USA – ACGIH – Occupational Exposure Limits
ACGIH OEL TWA [ppm] 20 ppm
ACGIH OEL STEL [ppm] 40 ppm
heptane (142-82-5)
USA – ACGIH – Occupational Exposure Limits
ACGIH OEL TWA [ppm] 400 ppm
ACGIH OEL STEL [ppm] 500 ppm
8.2. Appropriate engineering controls
Appropriate engineering controls : Ensure exposure is below occupational exposure limits (where available). Ensure good
ventilation of the work station.
Environmental exposure controls : Avoid release to the environment.
8.3. Individual protection measures/Personal protective equipment
Personal protective equipment:
Avoid all unnecessary exposure.
Hand protection:
Wear protective gloves.
Eye protection:
Chemical goggles or safety glasses. Safety glasses
10% SURFACING AGENT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/2/2024 (Revision date) EN (English US) 6/15
Skin and body protection:
Wear suitable protective clothing
Respiratory protection:
Wear appropriate mask
Personal protective equipment symbol(s):
Other information:
Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Color : clear
Odor : characteristic
Odor threshold : No data available
pH : No data available
Melting point : Not applicable
Freezing point : No data available
Boiling point : 209 F
Flash point : 24.8 F
Relative evaporation rate (butyl acetate=1) : No data available
Flammability (solid, gas) : Highly flammable liquid and vapor.
Vapor pressure : No data available
Relative vapor density at 20 C : No data available
Relative density : 0.9
Solubility : No data available
Partition coefficient n-octanol/water (Log Pow) : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosion limits : No data available
Explosive properties : No data available
Oxidizing properties : No data available
9.2. Other information
VOC content : 89.3
SECTION 10: Stability and reactivity
10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Not established. Highly flammable liquid and vapor. May form
flammable/explosive vapor-air mixture.
10% SURFACING AGENT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/2/2024 (Revision date) EN (English US) 7/15
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Harmful if inhaled.
10% SURFACING AGENT (mixture)
ATE US (vapors) 13.382 mg/l/4h
styrene, inhibited (100-42-5)
LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
LD50 oral > 6000 mg/kg body weight (Hamster, Male, Weight of evidence, Oral)
LD50 dermal rat > 2000 mg/kg body weight (OECD 402: Acute Dermal Toxicity, 24 h, Rat, Male / female,
Experimental value, Dermal)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 Inhalation – Rat 11.8 mg/l air (4 h, Rat, Inconclusive, insufficient data, Inhalation (vapours))
LC50 Inhalation – Rat [ppm] 2770 ppm/4h (Rat; Literature study)
ATE US (vapors) 11 mg/l/4h
heptane (142-82-5)
LD50 oral rat > 5000 mg/kg body weight (Equivalent or similar to OECD 401, Rat, Male / female, Read-
across, Oral)
LD50 dermal rabbit > 2000 mg/kg body weight (Equivalent or similar to OECD 402, 24 h, Rabbit, Male / female,
Read-across, Dermal)
LC50 Inhalation – Rat > 29.29 mg/l air (Equivalent or similar to OECD 403, 4 h, Rat, Male / female, Experimental
value, Inhalation (vapours))
Skin corrosion/irritation : Causes skin irritation.
styrene, inhibited (100-42-5)
pH Not applicable
Serious eye damage/irritation : Causes serious eye irritation.
styrene, inhibited (100-42-5)
pH Not applicable
Respiratory or skin sensitization : Not classified
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Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
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Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans
National Toxicology Program (NTP) Status Reasonably anticipated to be Human Carcinogen
Reproductive toxicity : Suspected of damaging fertility or the unborn child.
Specific target organ toxicity single exposure : Not classified
heptane (142-82-5)
Specific target organ toxicity single exposure May cause drowsiness or dizziness.
Specific target organ toxicity repeated exposure : Causes damage to organs through prolonged or repeated exposure.
styrene, inhibited (100-42-5)
Specific target organ toxicity repeated exposure Causes damage to organs through prolonged or repeated exposure.
Aspiration hazard : Not classified
Viscosity, kinematic : No data available
styrene, inhibited (100-42-5)
Viscosity, kinematic 0.8 mm /s
heptane (142-82-5)
Viscosity, kinematic 0.641 mm /s (20 C, EN ISO 3104: Capillary viscometer)
Potential Adverse human health effects and
symptoms
: Harmful if inhaled.
Symptoms/effects : May cause genetic defects (avoid skin contact and inhalation.). May cause cancer (avoid skin
contact and inhalation.).
Symptoms/effects after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
SECTION 12: Ecological information
12.1. Toxicity
Ecology – general : Dangerous for the environment. Harmful to aquatic life.
styrene, inhibited (100-42-5)
LC50 – Fish [1] 10 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Flow-through
system, Fresh water, Experimental value, GLP)
EC50 – Crustacea [1] 4.7 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Flow-
through system, Fresh water, Experimental value, GLP)
ErC50 algae 4.9 mg/l (EPA OTS 797.1050, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, GLP)
12.2. Persistence and degradability
10% SURFACING AGENT (mixture)
Persistence and degradability Not established.
styrene, inhibited (100-42-5)
Persistence and degradability Biodegradable in the soil. Readily biodegradable in water.
10% SURFACING AGENT
Safety Data Sheet
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styrene, inhibited (100-42-5)
Chemical oxygen demand (COD) 2.8 g O /g substance
ThOD 3.07 g O /g substance
BOD (% of ThOD) 0.42 (Literature study)
heptane (142-82-5)
Persistence and degradability Biodegradable in the soil. Readily biodegradable in water.
Biochemical oxygen demand (BOD) 1.92 g O /g substance
Chemical oxygen demand (COD) 0.06 g O /g substance
ThOD 3.52 g O /g substance
BOD (% of ThOD) > 0.5 (5 day(s), Literature study)
12.3. Bioaccumulative potential
10% SURFACING AGENT (mixture)
Bioaccumulative potential Not established.
styrene, inhibited (100-42-5)
BCF – Fish [1] 35.5 (Carassius auratus, Literature study)
Partition coefficient n-octanol/water (Log Pow) 2.96 (Experimental value, OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
heptane (142-82-5)
BCF - Other aquatic organisms [1] 552 (BCFBAF v3.00, Calculated value)
Partition coefficient n-octanol/water (Log Pow) 4.66 (Experimental value)
Bioaccumulative potential Potential for bioaccumulation (4 Log Kow 5).
12.4. Mobility in soil
styrene, inhibited (100-42-5)
Surface tension 0.032 N/m (20 C)
Organic Carbon Normalized Adsorption Coefficient
(Log Koc)
2.55 (log Koc, Estimated value)
Ecology - soil Low potential for adsorption in soil.
heptane (142-82-5)
Surface tension 19.66 mN/m (25 C)
Organic Carbon Normalized Adsorption Coefficient
(Log Koc)
2.38 (log Koc, SRC PCKOCWIN v2.0, Calculated value)
Ecology - soil Low potential for adsorption in soil.
12.5. Other adverse effects
Other information : Avoid release to the environment.
10% SURFACING AGENT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/2/2024 (Revision date) EN (English US) 10/15
SECTION 13: Disposal considerations
13.1. Disposal methods
Regional legislation (waste) : Disposal must be done according to official regulations.
Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions.
Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to approved disposal site..
Additional information : Handle empty containers with care because residual vapors are flammable.
Ecology - waste materials : Avoid release to the environment.
SECTION 14: Transport information
In accordance with DOT / TDG / IMDG / IATA
14.1. UN number
DOT NA No : UN1263
UN-No. (TDG) : UN1263
UN-No. (IMDG) : 1263
UN-No. (IATA) : 1263
14.2. UN proper shipping name
Proper Shipping Name (DOT) : Paint related material
Proper Shipping Name (TDG) : PAINT RELATED MATERIAL
Proper Shipping Name (IMDG) : PAINT RELATED MATERIAL
Proper Shipping Name (IATA) : Paint related material
14.3. Transport hazard class(es)
DOT
Transport hazard class(es) (DOT) : 3
Hazard labels (DOT) : 3
TDG
Transport hazard class(es) (TDG) : 3
Hazard labels (TDG) : 3
IMDG
Transport hazard class(es) (IMDG) : 3
Hazard labels (IMDG) : 3
IATA
Transport hazard class(es) (IATA) : 3
10% SURFACING AGENT
Safety Data Sheet
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Hazard labels (IATA) : 3
14.4. Packing group
Packing group (DOT) : II
Packing group (TDG) : II
Packing group (IMDG) : II
Packing group (IATA) : II
14.5. Environmental hazards
Other information : No supplementary information available.
14.6. Special precautions for user
DOT
UN-No.(DOT) : UN1263
10% SURFACING AGENT
Safety Data Sheet
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DOT Special Provisions (49 CFR 172.102) : 149 - When transported as a limited quantity or a consumer commodity, the maximum net
capacity specified in 173.150(b)(2) of this subchapter for inner packaging may be increased to 5
L (1.3 gallons).
367 - For the purposes of documentation and package marking: a. The proper shipping name
Paint related material may be used for consignments of packages containing Paint and Paint
related material in the same package; b. The proper shipping name Paint related material,
corrosive, flammable may be used for consignments of packages containing Paint, corrosive,
flammable and Paint related material, corrosive, flammable in the same package; c. The
proper shipping name Paint related material, flammable, corrosive may be used for
consignments of packages containing Paint, flammable, corrosive and Paint related material,
flammable, corrosive in the same package; and d. The proper shipping name Printing ink
related material may be used for consignments of packages containing Printing ink and
Printing ink related material in the same package.
383 - Packages containing toy plastic or paper caps for toy pistols described as UN0349,
Articles, explosive, n.o.s. (Toy caps), 1.4S or NA0337, Toy caps, 1.4S are not subject to the
subpart E (labeling) requirements of this part when offered for transportation by motor vehicle,
rail freight, cargo vessel, and cargo aircraft and, notwithstanding the packing method assigned in
173.62 of this subchapter, in conformance with the following conditions:
B52 - Notwithstanding the provisions of 173.24b of this subchapter, non-reclosing pressure relief
devices are authorized on DOT 57 portable tanks.
B131 - When transported by highway, rail, or cargo vessel, waste Paint and Paint related
material (UN1263; PG II and PG III), when in plastic or metal inner packagings of not more than
26.5 L (7 gallons), are excepted from the marking requirements in 172.301(a) and (c) and the
labeling requirements in 172.400(a), when further packed in the following specification and non-
specification bulk outer packagings and under the following conditions:
a. Primary receptacles must conform to the general packaging requirements of subpart B of part
173 of this subchapter and may not leak. If they do leak, they must be overpacked in packagings
conforming to the specification requirements of part 178 of this subchapter or in salvage
packagings conforming to the requirements in 173.12 of this subchapter.
b. Primary receptacles must be further packed in non-specification bulk outer packagings such
as cubic yard boxes, plastic rigid-wall bulk containers, dump trailers, and roll-off containers. Bulk
outer packagings must be liquid tight through design or by the use of lining materials.
c. Primary receptacles may also be further packed in specification bulk outer packagings.
Authorized specification bulk outer packagings are UN11G fiberboard intermediate bulk
containers (IBC) and UN13H4 woven plastic, coated and with liner flexible intermediate bulk
containers (FIBCs) meeting the Packing Group II performance level and lined with a plastic liner
of at least 6 mil thickness.
d. All inner packagings placed inside bulk outer packagings must be blocked and braced to
prevent movement during transportation that could cause the container to open or fall over.
Specification IBCs and FIBCs are to be secured to a pallet.
IB2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite
(31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110
kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized.
T4 - 2.65 178.274(d)(2) Normal............. 178.275(d)(3)
TP1 - The maximum degree of filling must not exceed the degree of filling determined by the
following: Degree of filling = 97 / 1 + a (tr - tf) Where: tr is the maximum mean bulk temperature
during transport, and tf is the temperature in degrees celsius of the liquid during filling.
TP8 - A portable tank having a minimum test pressure of 1.5 bar (150 kPa) may be used when
the flash point of the hazardous material transported is greater than 0 C (32 F).
TP28 - A portable tank having a minimum test pressure of 2.65 bar (265 kPa) may be used
provided the calculated test pressure is 2.65 bar or less based on the MAWP of the hazardous
material, as defined in 178.275 of this subchapter, where the test pressure is 1.5 times the
MAWP.
DOT Packaging Exceptions (49 CFR 173.xxx) : 150
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DOT Packaging Non Bulk (49 CFR 173.xxx) : 173
DOT Packaging Bulk (49 CFR 173.xxx) : 242
DOT Quantity Limitations Passenger aircraft/rail (49
CFR 173.27)
: 5 L
DOT Quantity Limitations Cargo aircraft only (49
CFR 175.75)
: 60 L
DOT Vessel Stowage Location : B - (i) The material may be stowed on deck or under deck on a cargo vessel and on a
passenger vessel carrying a number of passengers limited to not more than the larger of 25
passengers, or one passenger per each 3 m of overall vessel length; and (ii) On deck only on
passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this
section is exceeded.
TDG
UN-No. (TDG) : UN1263
TDG Special Provisions : 59 - Substances that are listed by name in Schedule 1 must not be transported under this
shipping name. Substances transported under this shipping name may contain not more than
20% nitrocellulose if the nitrocellulose contains not more than 12.6% nitrogen (by dry mass),142
- The following shipping names may be used to meet the requirements of Part 3
(Documentation) and Part 4 (Dangerous Goods Safety Marks) when these dangerous goods are
offered for transport in the same means of containment:
(a) PAINT RELATED MATERIAL may be used for a means of containment containing both
paint and paint related material;
(b) PAINT RELATED MATERIAL, CORROSIVE, FLAMMABLE may be used for a means of
containment containing both paint, corrosive, flammable, and paint related material, corrosive,
flammable;
(c) PAINT RELATED MATERIAL, FLAMMABLE, CORROSIVE may be used for a means of
containment containing both paint, flammable, corrosive, and paint related material, flammable,
corrosive; and
(d) PRINTING INK RELATED MATERIAL may be used for a means of containment containing
both printing ink and printing ink related material.
Explosive Limit and Limited Quantity Index : 5 L
Excepted quantities (TDG) : E2
Passenger Carrying Road Vehicle or Passenger
Carrying Railway Vehicle Index
: 5 L
Emergency Response Guide (ERG) Number : 128
IMDG
Special provision (IMDG) : 163, 367
Limited quantities (IMDG) : 5 L
Excepted quantities (IMDG) : E2
Packing instructions (IMDG) : P001
Packing provisions (IMDG) : PP1
IBC packing instructions (IMDG) : IBC02
Tank instructions (IMDG) : T4
Tank special provisions (IMDG) : TP1, TP8, TP28
EmS-No. (Fire) : F-E - FIRE SCHEDULE Echo - NON-WATER-REACTIVE FLAMMABLE LIQUIDS
EmS-No. (Spillage) : S-E - SPILLAGE SCHEDULE Echo - FLAMMABLE LIQUIDS, FLOATING ON WATER
Stowage category (IMDG) : B
Properties and observations (IMDG) : Miscibility with water depends upon the composition.
IATA
PCA Excepted quantities (IATA) : E2
PCA Limited quantities (IATA) : Y341
PCA limited quantity max net quantity (IATA) : 1L
PCA packing instructions (IATA) : 353
PCA max net quantity (IATA) : 5L
CAO packing instructions (IATA) : 364
CAO max net quantity (IATA) : 60L
Special provision (IATA) : A3, A72, A192
10% SURFACING AGENT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/2/2024 (Revision date) EN (English US) 14/15
ERG code (IATA) : 3L
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
SECTION 15: Regulatory information
15.1. US Federal regulations
Commercial status of components according to the United States Environmental Protection Agency s Toxic Substances Control Act (TSCA):
Name CAS-No. Listing Commercial
status
Flags
styrene, inhibited 100-42-5 Present Active
heptane 142-82-5 Not present -
styrene, inhibited (100-42-5)
Subject to reporting requirements of United States SARA Section 313
Listed on EPA Hazardous Air Pollutant (HAPS)
CERCLA RQ 1000 lb
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Reactive hazard
Fire hazard
Delayed (chronic) health hazard
15.2. International regulations
CANADA
styrene, inhibited (100-42-5)
Listed on the Canadian DSL (Domestic Substances List)
EU-Regulations
No additional information available
National regulations
styrene, inhibited (100-42-5)
Listed on IARC (International Agency for Research on Cancer)
Listed as carcinogen on NTP (National Toxicology Program)
15.3. US State regulations
styrene, inhibited (100-42-5)
U.S. - California -
Proposition 65 -
Carcinogens List
U.S. - California -
Proposition 65 -
Developmental Toxicity
U.S. - California -
Proposition 65 -
Reproductive Toxicity
- Female
U.S. - California -
Proposition 65 -
Reproductive Toxicity
- Male
No significant risk
level (NSRL)
Maximum allowable
dose level (MADL)
Yes No No No 27 g/day
10% SURFACING AGENT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/2/2024 (Revision date) EN (English US) 15/15
Component State or local regulations
styrene, inhibited(100-42-5) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know Hazardous
Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
SECTION 16: Other information
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date : 10/2/2024
Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE
COUNCIL of 16 December 2008 on classification, labeling and packaging of substances and
mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending
Regulation (EC) No 1907/2006.
Other information : None.
Full text of H-phrases
H225 Highly flammable liquid and vapor
H226 Flammable liquid and vapor
H304 May be fatal if swallowed and enters airways
H315 Causes skin irritation
H319 Causes serious eye irritation
H332 Harmful if inhaled
H336 May cause drowsiness or dizziness
H361 Suspected of damaging fertility or the unborn child
H372 Causes damage to organs through prolonged or repeated exposure
H400 Very toxic to aquatic life
H410 Very toxic to aquatic life with long lasting effects
H412 Harmful to aquatic life with long lasting effects
NFPA health hazard : 2 - Materials that, under emergency conditions, can cause temporary
incapacitation or residual injury.
NFPA fire hazard : 3 - Liquids and solids (including finely divided suspended solids) that can
be ignited under almost all ambient temperature conditions.
NFPA reactivity : 2 - Materials that readily undergo violent chemical change at elevated
temperatures and pressures.
Hazard Rating
Health : 2 Moderate Hazard - Temporary or minor injury may occur
Flammability : 3 Serious Hazard - Materials capable of ignition under almost all normal temperature conditions.
Includes flammable liquids with flash points below 73 F and boiling points above 100 F. as well
as liquids with flash points between 73 F and 100 F. (Classes IB IC)
Physical : 1 Slight Hazard - Materials that are normally stable but can become unstable (self-react) at high
temperatures and pressures. Materials may react non-violently with water or undergo hazardous
polymerization in the absence of inhibitors.
Personal protection : H - Splash goggles, Gloves, Synthetic apron, Vapor respirator
Safety Data Sheet (SDS), USA