INDEX
40514001
40514001
4051400101
4051400102
4051400104
40514001B
40514001C
40514001Q
Composite ResourceWhitePigment
Safety Data Sheet4051400101 and 4051400102
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue:11/24/2014 Revision date: Supersedes:
11/12/2014 EN(English) Page 1
SECTION 1:Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product form :Mixture
Trade name :WhitePigment
CAS No :Mixture
Product code :4051400101and 4051400102
Formula :NA
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :PigmentDispersion
1.3. Details of the supplier of the safety data sheet
Composite Resources is supplied by Revchem Composites. 2720 South Willow Ave., Bloomington, CA 92316 1-800-281-4975
1.4. Emergency telephone number
Emergency number :800.424.9300
CHEMTREC: 1-800-424-9300
SECTION 2:Hazards identification
2.1. Classification of the substance or mixture
GHS-US classification
Not classified
2.2. Label elements
GHS-US labelling
No labelling applicable
2.3. Other hazards
No additional information available
2.4. Unknown acute toxicity (GHS-US)
No data available
SECTION 3:Composition/information on ingredients
3.1. Substance
Not applicable
Full text of H-phrases: see section 16
3.2. Mixture
Name Product identifier % GHS-US classification
Titanium(IV) oxide (CAS No)13463-67-7 <= 70 Carc. 2, H351
Unsaturated Polyester Resin (CAS No)TRADE SECRET <= 30 Not classified
SECTION 4:First aid measures
4.1. Description offirst aid measures
First-aid measures general :Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice
(show the label where possible).
First-aid measures after inhalation :Remove to fresh air and keep at rest ina position comfortable for breathing. Call a POISON
CENTER/doctor/physician if you feel unwell. Assure fresh air breathing. Allow the victim to rest.
First-aid measures after skin contact :Remove/Take off immediately all contaminated clothing. Rinse skinwith water/shower.
First-aid measures after eye contact :Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness
persist.
First-aid measures after ingestion :Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
Composite ResourceWhitePigment
Safety Data Sheet4051400101 and 4051400102
according toFederal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
11/12/2014 EN(English) 2/6
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries :May cause genetic defects (avoid skin contact and inhalation.). May cause cancer (avoid skin
contact and inhalation.). Not expected to present a significant hazard under anticipated
conditions of normal use.
Symptoms/injuries after inhalation :Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled.
4.3. Indication of any immediate medical attention and specialtreatment needed
No additional information available
SECTION 5:Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media :Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media :Do not use a heavy waterstream.
5.2. Special hazards arising from the substance or mixture
Fire hazard :Highly flammable liquid and vapour. Flammable liquid and vapour.
Explosion hazard :May form flammable/explosive vapour-air mixture.
Reactivity :No reactivity hazard other than the effects described in sub-sections below.
5.3. Advice for firefighters
Firefighting instructions :Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Avoid (reject) fire-fighting water to enter environment.
Protection during firefighting :Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6:Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures :Remove ignition sources. Use special care to avoid static electric charges. No naked lights. No
smoking.
6.1.1.For non-emergency personnel
Protective equipment :Gloves. Protective goggles. Protective clothing.
Emergency procedures :Evacuate unnecessary personnel.
6.1.2.For emergency responders
Protective equipment :Equip cleanup crew with proper protection.
Emergency procedures :Ventilate area.
6.2. Environmental precautions
Prevent entry to sewers and public waters. Notifyauthorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment :Dam up the liquid spill. Contain released substance, pump into suitable containers.
Methods for cleaning up :Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect
spillage. Store away from other materials.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.
SECTION 7:Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed :Handle empty containers with care because residual vapours are flammable.
Precautions for safe handling :Use only outdoors or in a well-ventilated area. Avoid breathing DUST, FUMES, MIST, OR
VAPORS. Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Eliminate all ignition sources if safe to do so. Wash hands and other
exposed areas with mild soap and water before eat, drink or smoke and when leaving work.
Provide good ventilation in process area to prevent formation of vapour. No naked lights. No
smoking. Take precautionary measures against static discharge. Use only non-sparking tools.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures :Proper grounding procedures to avoid static electricity should be followed. Ground/bond
container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/
equipment.
Composite ResourceWhitePigment
Safety Data Sheet4051400101 and 4051400102
according toFederal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
11/12/2014 EN(English) 3/6
Storage conditions :Keep in fireproof place. Keep only in the original container in a cool, well ventilated place away
from : Keep container tightly closed.
Incompatible products :Strong bases. strong acids.
Incompatible materials :Sources of ignition. Direct sunlight.Heat sources.
7.3. Specific end use(s)
No additional information available
SECTION 8:Exposure controls/personal protection
8.1. Control parameters
titanium(IV) oxide (13463-67-7)
USA ACGIH ACGIH TWA (mg/m ) 10 mg/m
8.2. Exposure controls
Appropriate engineering controls :Ensure exposure is below occupational exposure limits (where available).
Personal protective equipment :Avoid all unnecessary exposure.
Hand protection :Wear protective gloves.
Eye protection :Chemical goggles or safety glasses.
Respiratory protection :Wear approved mask.
Other information :When using, do not eat, drink or smoke.
SECTION 9:Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state :Liquid
Colour :White
Odour :Characteristic
Odour threshold :No data available
pH :No data available
Relative evaporation rate (butylacetate=1):No data available
Melting point :No data available
Freezing point :No data available
Boiling point : 64 C ( 147 F)
Flash point :30-34 C (86-93 F)
Auto-ignition temperature :No data available
Decomposition temperature :No data available
Flammability (solid, gas) :No data available
Vapour pressure :No data available
Relative vapour density at 20 C :No data available
Relative density : 1.1
Solubility :No data available
Log Pow :No data available
Log Kow :No data available
Viscosity, kinematic :No data available
Viscosity, dynamic :No data available
Explosive properties :No data available
Oxidising properties :No data available
Explosive limits :No data available
9.2. Other information
No additional information available
SECTION 10:Stability and reactivity
10.1.Reactivity
No reactivity hazard other than the effects described in sub-sections below.
Composite ResourceWhitePigment
Safety Data Sheet4051400101 and 4051400102
according toFederal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
11/12/2014 EN(English) 4/6
10.2.Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Highly flammable liquid and vapour. Not established. Flammable liquid
and vapour. May form flammable/explosive vapour-air mixture.
10.3.Possibility of hazardous reactions
Not established.
10.4.Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Heat.
10.5.Incompatible materials
strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11:Toxicological information
11.1.Information on toxicological effects
Acute toxicity :Not classified
titanium(IV) oxide (13463-67-7)
LD50 oral rat > 10000 mg/kg (Rat; Experimental value,Rat; Experimental value)
LD50 dermal rabbit > 10000 mg/kg (Rabbit; Experimental value,Rabbit; Experimental value)
LC50 inhalation rat (mg/l) > 6.8 mg/l/4h (Rat; Experimental value,Rat; Experimental value)
Skin corrosion/irritation :Not classified
Serious eye damage/irritation :Not classified
Respiratory or skin sensitisation :Not classified
Germ cell mutagenicity :Not classified
Carcinogenicity :Not classified
titanium(IV) oxide (13463-67-7)
IARC group 2B-Possibly Carcinogenic to Humans
Reproductive toxicity :Not classified
Based on available data, the classification criteria are not met
Specific target organ toxicity (single exposure):Not classified
Specific target organ toxicity (repeated
exposure)
:Not classified
Based on available data, the classification criteria are not met
Aspiration hazard :Not classified
Based on available data, the classification criteria are not met
Potential Adverse human health effects and
symptoms
:Harmful if inhaled. Based on available data, the classification criteria are not met.
Symptoms/injuries after inhalation :Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled.
SECTION 12:Ecological information
12.1.Toxicity
titanium(IV) oxide (13463-67-7)
LC50 fishes 1 > 1000 mg/l (96 h; Pimephales promelas)
EC50 Daphnia 1 < 1000 mg/l (432 h; Daphnia magna; Static system)
LC50 fish 2 > 1 g/l (96 h; Leuciscus idus)
EC50 Daphnia 2 < 500 mg/l (720 h; Daphnia magna; Static system)
12.2.Persistence and degradability
WHITE PIGMENT(mixture)
Persistence and degradability Not established.
Composite ResourceWhitePigment
Safety Data Sheet4051400101 and 4051400102
according toFederal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
11/12/2014 EN(English) 5/6
Unsaturated Polyester Resin (TRADE SECRET)
Persistence and degradability Not established.
titanium(IV)oxide (13463-67-7)
Persistence and degradability Biodegradability: not applicable.
Biochemical oxygen demand (BOD) Not applicable
Chemical oxygen demand (COD) Not applicable
ThOD Not applicable
BOD (% of ThOD) Not applicable
12.3.Bioaccumulativepotential
WHITE PIGMENT(mixture)
Bioaccumulative potential Not established.
Unsaturated Polyester Resin (TRADE SECRET)
Bioaccumulative potential Not established.
titanium(IV) oxide (13463-67-7)
Bioaccumulative potential No bioaccumulation data available.
12.4.Mobility in soil
No additional information available
12.5.Other adverse effects
Other information :Avoid release to the environment.
SECTION 13:Disposal considerations
13.1.Waste treatment methods
Waste disposal recommendations :Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to ...
Additional information :Handle empty containers with care because residual vapours are flammable.
Ecology-waste materials :Avoid release tothe environment.
SECTION 14:Transport information
In accordance with DOT
No dangerous good in sense of transport regulations
Additional information
Other information :No supplementary information available.
ADR
Transport document description :
Transport by sea
No additional information available
Air transport
No additional information available
SECTION 15:Regulatory information
15.1. US Federal regulations
No additional information available
15.2. International regulations
CANADA
No additional information available
EU-Regulations
No additional information available
Composite ResourceWhitePigment
Safety Data Sheet4051400101 and 4051400102
according toFederal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
11/12/2014 EN(English) 6/6
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Not classified
Classification according to Directive 67/548/EEC or 1999/45/EC
Carc.Cat.2; R45
Muta.Cat.2; R46
F; R11
Xn; R20
Xi; R36/38
Full text of R-phrases: see section 16
15.2.2.National regulations
No additional information available
15.3. US State regulations
WHITE PIGMENT(mixture)
State or local regulations U.S.-Pennsylvania-RTK (Rightto Know) List
U.S.-Pennsylvania-RTK (Right to Know)-Environmental Hazard List
U.S.-New Jersey-TCPA-Extraordinarily Hazardous Substances (EHS)
U.S.-New Jersey-Right to Know Hazardous Substance List
U.S.-Massachusetts-Right To Know List
SECTION 16:Other information
Other information :None.
Full text of H-phrases: see section 16:
------Carc. 2 Carcinogenicity, Category 2
------H351 Suspected of causing cancer
NFPA health hazard :1-Exposure could cause irritation but only minor residual
injury even if no treatment is given.
NFPA fire hazard :2-Must be moderately heated or exposed to relatively high
temperature before ignition can occur.
NFPA reactivity :1-Normallystable, but can become unstable at elevated
temperatures and pressures or may react with water with
some release of energy, but not violently.
HMIS III Rating
Health :1 Slight Hazard-Irritation or minor reversible injury possible
Flammability :1 Slight Hazard
Physical :1 Slight Hazard
Personal Protection :H
SDS US (GHS HazCom 2012)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an otherwarranties, expressed or impliedincluding but not limited to any implied
warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.