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49.1.7
1 Identification
Product identifier
Trade name: P12 Pine
Article number:I012188
Application of the substance / the mixturePolyester filler
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
ehs-us@axson.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
* 2 Hazard(s) identification
Classification of the substance or mixture
GHS02 Flame
Flam. Liq. 3 H226 Flammable liquid and vapor.
GHS08 Health hazard
Carc. 2 H351 Suspected of causing cancer.
Repr. 2 H361 Suspected of damaging fertility or the unborn child.
STOT RE 1 H372 Causes damage to the hearing organs through prolonged or repeated exposure.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2B H320 Causes eye irritation.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
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49.1.7
Hazard pictograms
GHS02GHS07GHS08
Signal wordDanger
Hazard-determining components of labeling:
Styrene
Hazard statements
Flammable liquid and vapor.
Causes skin and eye irritation.
Suspected of causing cancer.
Suspected of damaging fertility or the unborn child.
Causes damage to the hearing organs through prolonged or repeated exposure.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Keep away from heat/sparks/open flames/hot surfaces. – No smoking.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting/equipment.
Do not breathe dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Store in a well-ventilated place. Keep cool.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
1
3
0
Health = 1
Fire = 3
Reactivity = 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
1
3
0
Health = 1
Fire = 3
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
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49.1.7
vPvB:Not applicable.
* 3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 100-42-5
EINECS: 202-851-5
Styrene 20-50%
CAS: 121-69-7
EINECS: 204-493-5
N,N-dimethylaniline 0.25-<1%
CAS: 91-99-6 N,N-Bishydroxyethyl-m-toluidine 0.1-1%
* 4 First-aid measures
Description of first aid measures
General information:
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
After inhalation:In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing:If symptoms persist consult doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
* 5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Special hazards arising from the substance or mixture
During heating or in case of fire poisonous gases are produced.
Advice for firefighters
Protective equipment:
Mouth respiratory protective device.
Wear self-contained respiratory protective device.
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49.1.7
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
* 6 Accidental release measures
Personal precautions, protective equipment and emergency procedures
Mount respiratory protective device.
Wear protective equipment. Keep unprotected persons away.
Environmental precautions:Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
100-42-5 Styrene 20 ppm
121-69-7 N,N-dimethylaniline 10 ppm
PAC-2:
100-42-5 Styrene 130 ppm
121-69-7 N,N-dimethylaniline 330 ppm
PAC-3:
100-42-5 Styrene 1100* ppm
121-69-7 N,N-dimethylaniline 2,000 ppm
* 7 Handling and storage
Handling:
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Prevent formation of aerosols.
Information about protection against explosions and fires:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Keep respiratory protective device available.
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49.1.7
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:Keep receptacle tightly sealed.
Specific end use(s)No further relevant information available.
* 8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
The following constituents are the only constituents of the product which have a PEL, TLV or other recommended
exposure limit.
At this time, the remaining constituent has no known exposure limits.
100-42-5 Styrene
ACGIH TLV Short-term value: 170 at 40 ppm mg/m
Long-term value: 85 at 20 ppm mg/m
OSHA PEL Long-term value: 100 ppm mg/m
Ceiling limit value: 200 ppm mg/m
PEL Long-term value: 100 ppm
Ceiling limit value: 200; 600* ppm
*5-min peak in any 3 hrs
REL Short-term value: 425 mg/m , 100 ppm
Long-term value: 215 mg/m , 50 ppm
TLV Short-term value: (170) mg/m , (40) NIC-20 ppm
Long-term value: (85) mg/m , (20) NIC-10 ppm
BEI, NIC-A3, NIC-OTO
121-69-7 N,N-dimethylaniline
PEL Long-term value: 25 mg/m , 5 ppm
Skin
REL Short-term value: 50 mg/m , 10 ppm
Long-term value: 25 mg/m , 5 ppm
Skin
TLV Short-term value: 50 mg/m , 10 ppm
Long-term value: 25 mg/m , 5 ppm
Skin; BEI-M
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49.1.7
Ingredients with biological limit values:
121-69-7 N,N-dimethylaniline
BEI 1.5 % of hemoglobin
Medium: blood
Time: during or end of shift
Parameter: Methemoglobin (background, nonspecific, semi-quantitative)
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Tightly sealed goggles
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49.1.7
* 9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Thixotropic Paste
Color: Pine
Odor: Pungent
Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range:Undetermined.
Boiling point/Boiling range:145 C (293 F)
Flash point: 31 C (87.8 F)
Flammability (solid, gaseous):Not applicable.
Ignition temperature: 490 C (914 F)
Decomposition temperature: Not determined.
Auto igniting: Product is not selfigniting.
Danger of explosion: Product is not explosive. However, formation of explosive air/vapor
mixtures are possible.
Explosion limits:
Lower: 0.9 Vol %
Upper: 6.8 Vol %
Vapor pressure at 20 C (68 F):6 hPa (4.5 mm Hg)
Density at 20 C (68 F): 0.95 g/cm (7.93 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Solvent content:
Organic solvents: 0.4 %
VOC content: 20.55 %
195.2 g/l / 1.63 lb/gal
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49.1.7
Solids content: 39.9 %
Other information No further relevant information available.
* 10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:Carbon monoxide and carbon dioxide
* 11 Toxicological information
Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
100-42-5 Styrene
Oral LD50 >2,000 mg/kg (rat)
Dermal LD50 >2,000 mg/kg (rat)
Inhalative LC50/4 h 11.8 mg/l (rat)
Primary irritant effect:
on the skin:Irritant to skin and mucous membranes.
on the eye:Irritating effect.
Sensitization:No sensitizing effects known.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Irritant
Carcinogenic categories
IARC (International Agency for Research on Cancer)
14807-96-6 Talc (Mg3H2(SiO3)4) 3
100-42-5 Styrene 2B
112926-00-8 Precipitated silica (Silica-Amorphous) 3
13463-67-7 titanium dioxide 2B
121-69-7 N,N-dimethylaniline 3
64-17-5 ethanol 1
7631-86-9 silicon dioxide, chemically prepared 3
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49.1.7
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
12 Ecological information
Toxicity
Aquatic toxicity:No further relevant information available.
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Additional ecological information:
General notes:
Water hazard class 1 (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
* 14 Transport information
UN-Number
DOT, IMDG, IATA UN1866
UN proper shipping name
DOT Resin solution
IMDG, IATA RESIN SOLUTION
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Transport hazard class(es)
DOT
Class 3 Flammable liquids
Label 3
Packing group
DOT III
Environmental hazards:
Marine pollutant: No
Special precautions for user Not applicable.
EMS Number: F-E,S-E
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
UN “Model Regulation”: not regulated
* 15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
100-42-5 Styrene
121-69-7 N,N-dimethylaniline
TSCA (Toxic Substances Control Act):
Polyester Resin ACTIVE
14807-96-6 Talc (Mg3H2(SiO3)4) ACTIVE
100-42-5 Styrene ACTIVE
65997-17-3 Fibrous Glass ACTIVE
112926-00-8 Precipitated silica (Silica-Amorphous) *
546-93-0 Magnesite ACTIVE
13463-67-7 titanium dioxide ACTIVE
1318-59-8 Chlorite ACTIVE
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16389-88-1 dolomite ACTIVE
121-69-7 N,N-dimethylaniline ACTIVE
64-17-5 ethanol ACTIVE
91-99-6 N,N-Bishydroxyethyl-m-toluidine ACTIVE
7631-86-9 silicon dioxide, chemically prepared ACTIVE
21645-51-2 aluminium hydroxide ACTIVE
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
Hazardous Air Pollutants
100-42-5 Styrene
121-69-7 N,N-dimethylaniline
108-10-1 4-methylpentan-2-one
Proposition 65
Chemicals known to cause cancer:
100-42-5 Styrene
13463-67-7 titanium dioxide
108-10-1 4-methylpentan-2-one
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
64-17-5 ethanol
108-10-1 4-methylpentan-2-one
Carcinogenic categories
TLV (Threshold Limit Value established by ACGIH)
121-69-7 N,N-dimethylaniline A4
NIOSH-Ca (National Institute for Occupational Safety and Health)
13463-67-7 titanium dioxide
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
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49.1.7
Hazard pictograms
GHS02GHS07GHS08
Signal wordDanger
Hazard-determining components of labeling:
Styrene
Hazard statements
Flammable liquid and vapor.
Causes skin and eye irritation.
Suspected of causing cancer.
Suspected of damaging fertility or the unborn child.
Causes damage to the hearing organs through prolonged or repeated exposure.
Precautionary statements
Keep away from heat/sparks/open flames/hot surfaces. – No smoking.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting/equipment.
Do not breathe dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Store in a well-ventilated place. Keep cool.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision10/16/2019 / 3
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
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49.1.7
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
BEI: Biological Exposure Limit
Flam. Liq. 3: Flammable liquids Category 3
Skin Irrit. 2: Skin corrosion/irritation Category 2
Eye Irrit. 2B: Serious eye damage/eye irritation Category 2B
Carc. 2: Carcinogenicity Category 2
Repr. 2: Reproductive toxicity Category 2
STOT RE 1: Specific target organ toxicity (repeated exposure) Category 1
* Data compared to the previous version altered.
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