@
BUILDING TRUST
Printing date I 0/28/201 9
Safety Dota Sheet
qcc. to OSHA HCS
Page I/12
Reviev,ed on I 0/28/201 9
Product idenli/ier
Trude name: EPOLAM 2500 Hurdener
Article number: 102495 5
Applicaliort of the substunce,/ the mixture Lantintrting epox1, fi4vrJu’tu”
Detoils of the supplier of lhe s(fetJ) data sheet
Sika Advanced Resins, US
EHS Department
M o tr ttfttcl u r er/S u pp I i e r :
Supplier’s Name: Sika Advanced Resin.s, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
ehs-us@axson.com
I nfo rmoli o tt d ep a rt m e nl : P r o du ct s afety d ep a r t nt en t
E ntergency lelep h on e nu mb er :
During normal opening tintes: + I (24B) 5BB-2270
CHEMTREC 24-hour Entergency: +1 (800) 424-9300
2 Hazo rd (s) ide ntift c at i o n
of tlrc substunce or nixlure
GHS]5 Coryosion
Skin Con. IA
Eye Dam. I
H3I4 Cause.t severe skin burns and e1,s duntuge.
H3I8 Causes serious eye damage.
GHSOT
Acute Tox. 4 H302 Harmful if swallowed.
Skin Sens. I H317 May cause an allergic skin react ion
Aquatic Acute 3 H402 Harmful to aquatic life.
Aquatic Chronic 3 H4l2 Harntful to aquatic Iife with long lasting e//bcts
Label elements
GHS label elemenls The product is classified and labeled uccording to the Globqlly Harmonized System (GHS).
(Contd. on page 2)
I
o
US
BUILDING TRUST
Printing date 1 0/28/20 1 9
Ssfety Dsta Sheet
qcc. to OSHA HCS
Page 2/12
Reviev,ed on I 0/28/20 1 9
I
Trade nanre: EPOLAM 2500 Hurrlener
(Contd. ofpage l)
Hazard piclogrants
GHSO5 GHSOT
Signal wotd Danger
H azard-delerni ni n g co mp o n en ts of I a be I i n g :
3 – antinom et hy l- 3, 5, 5 – t r i nt e t hy I ct, c I o lt,’xy I a nr i n e
P o I yoxypr opy I e n e d i a m i n e
3 – a m i n opropy I d i e t hy I a m i n e
Hazarrl stotemenls
Harmful if swallov,ed.
Causes severe skin burns and e1,e damage.
May cause an allergic skin reac!ion.
Harmful to aquatic life.
Harmful to aquatic life u,ith long lasting effbcts.
Precautionury stilements
Av o i d br e a t h ing du s t/fu nt e/ g a s/ m i s t/v a p ot” s/ s p r ay
Do not breathe dusts or mists.
LVear protective gloves/protective clothing/eye protection/face protection.
If swallowed: Call a poison center/doctor ifyoufeel unwell.
If on skin (or hair): Take off imnrediatellt all contantinated clothing. Rinse skin with water/shower.
IF INHALED: Remove pet’son to.fi”esh air and keep confortablefor breathing.
If in eyes: Rinse cautiously v,ith water.for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment (see on this lubel).
Store locked up.
Dispose of contents/container in accordancewith local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
Health :
3
Fire : I
Reactivity: 0
HMlS-ruings(scde0-4)
Health —
*3
Fire : l
nencrvtrvi b’l: Reactivity :
0
Otlter hazards
Results of PBT ond vPvB ussessntent
PBT: Not applicable.
(Contd. on page 3)
US
BUILDING TRUST
Pt’inting tlure I 0i28/20 I 9
Scfety Data Sheet
acc. to OSHA HCS
Page 3/12
Revievted on I 0/28/2019
Traile nume: EPOLA|VI 2500 Hardener
(Contd. ol-page 2)
t,PvB: Not upplicable.
3 Composition/information on ingredients
C h e m i co I c h o racle riz.uti o u : Mixlu res
Descriptiott: Mixture of the substances listed below with nonhazardous additions.
D a n g e ro u s c o rrlp o n ents :
CAS:101-78-9
EINECS: 203-236-4
50- I 00%L’AS: 2855-r3-2
EIN ECS,, 220-666-8
3 – a nt i n ont e t hy I – 3, 5, 5 – t r i m e t hy I cy c I o h exy I a nt i n e
CAS:9046-10-0 P o ly oxy p r o py I e n e d i a m i n e I0-20%
>t-<5%3 - a nt i n o p r opy I d ie t hy I a nt in e
4 First-aid measures
D es c ri pti o tr o.f .fi rcl a i d me us u res
G en erol i rtforntalion :
lntmediutely remove any clothing soiled by the product.
S),mptons of poisoning may even occur after several hour.s; therefore ntedical observationJbr qt least 48 hours
u/ier the accident.
A.fler inhalution:
,Supply/)'esh air and to be sure callfor a doctor.
ln case of'unconsciousness place patient stably in side positionfor transportation.
A.fter skitt conlocl: Imntediately u,ash with water and soap and rinse thoroughly.
zl.fter eye conloct: Rinse opened eyefor several minutes under runningwater. Then consult a doctor.
A.fter swullowirtg:
lnmediately call a doctor.
Drink copious amounts ofwater and providefresh air. Imntediately call a doctor.
I n
fo rmuti on fo r doctor:
Most irnportont il,ntplonts und effects, both ucute tnd delayed Nofurther relevant information available.
Indicatiort o.f any itnmediate medical otlention ond special lreulment needed
N o .furt
lt e t' r e l ev a n l i nform a t i on av ai la b l e.
Extitrguishing media
Saitfile extirtgtrisltiug agenls: Usefirefighting measures that suit the environment.
Special hazurds orising front
the substance or mixture
During heating or in case offire poisonous gases are produced.
.4 d v i c e
.fo
r
.fi refi g h te rs
Proleclive equipmenl:
A4outh respiratory protective device.
(Contd. on page 4)
5 Fire-lighting meas ures
US
BUILDING TRUST
Printing date I 0/28/20 l 9
Ssfety Data Slreet
qcc. to OSHA HCS
Page 4/12
Revievted on I 0/28/20 I 9
Trade narne: EPOLAM 2500 Hurdener
(Contd. olpage 3)
LI/ e a r s e lf- c o n t a i n e d r es p ir a t ory p r o t e c t iv e d ev i c e.
A dd i ti o n al i n fo rmali o rr
Dispose offire debris and contaminated./ire.fightingvtater in accordance v,ith official regulations.
Hundling:
Precuutions for
sufe ltandling
Ensure good ventilation/exhaustion at the workplace.
Pr ev ent for
nt a tion of a eros o ls.
Informatiort oboat proleclion against explosiotrs andJires: Keep respiratory) plotective device available.
(Contd. on page 5)
*
6 Accidental release measures
Personol precaulions, prolective equipmenl and emergency procedures
M ou n t r esp ir at ory pr ot ect iv e dev ice.
Iilear protective equipment. Keep unprotected persons away.
Ettvi ro nntenlil p recuu I i ons :
Do not allow product lo reach sewage syslem or any water course.
Infornt respective authorities in case of seepage intowater course or sewage system.
Do not allow to enter sewers/ surface or ground vtater.
Methods and mileriulfor contdnment ond cleaning up:
Absorb with liquid-binding material (sand, dialomite, acid binders, universal binders, sawdust)
Us e n eutra lizing agent.
Dispose contaminated material qs waste according to itetn I3.
Ensur e a dequ ate vent il a tion.
Reference lo other sections
See Section 7 for information on,sde handling.
See Section Sfor information on personal protection equipntent.
See Section l3 for disposal informalion.
Protective Action Criteria for Chemicals
PAC-I:
9046- I 0-0P o ly oxy p r o py I e n e d i a m i n e 4.8 ntg/m3
I 04-78-93 - am in opr opy I d i et hy I a m i n e 1.7 mg/nt3
PAC-2:
9046-1 0-0P o ly oxy pr opy I e ne di amin e 53 rug/m3
I 04-78-93 - aminop r opy I d i et hy I a m in e l8 mg/m3
PAC-3:
9046-1 0-0P o ly oxypr opyl enediam in e 320 mg/m3
I 04-78-93 - a m i n o p r o py I d i e t hy I a m i ne I l0 ntg/nt3
7 Handling &nd storflge
US
BUILDING TRUSTA
Printing date I 0/28/20 I 9
Sofety Dcrtcr Slteet
occ. t0 OSHA HCS
Page 5/12
Revievted on I 0/28/2 0 I 9
*
Trude nante: EPOLAM 2500 Hurderrer
(Contd. olpage 4)
Corrtlitiorrs for
sufe slorage, incIutlirtg uny incompatibiIities
Storage:
Requirentenls to be mel by slorcroonrs and receplacles: No special requirentents.
Informotiotr about slorage in one common slorage.fttcilily: Not required.
Furlher informaliou aboul sloruge conditiotts: Keep receptacle tightly sealed.
SpecrJic end use(s) Nofurther relevant inforntation available.
Adtlitional informaliou aboul design of technical syslems: No further data; see item 7.
Control prtrumelers
Componenls with limil values thut require ntoniloring ot tlte workphce:
The product does not contain any relevant cluantities of nraterials with critical values that have to be ntonitored al
the workplace.
Adrlitional information: The lists that were valid during the creation were used as basis.
Exposure conlrols
Pers o n a I p roteclive e q u ip menl :
General prolective urtd hygienic nrcosures:
K e ep aw ay fr
ont fo
o ds tuffs, b ev er a ges a n d fe
e d.
Immediately remove all soiled and contantinated clothing.
Ilash hands before breaks and at the end ofwork.
Avoid contact with the eyes.
Avoid contact v,ith the eyes and skin.
B reailt i tt g eq u ip rnenl :
In case of brief exposure or low pollution use respiratoryfilter device. Incase of intensive or longer exposure use
respiratory prolective device that is independent ofcirculating air.
Prolecliort of huttds:
Protective gloves
The glove material has to be intpernteable and resistant Io the product/ the substance/ the preparation.
Due to ntissing tests no recontmendation to the glove material can be givenfor the product/ the preparation/ the
chemical ntixture.
Selection of the glove ntateriol on consideration of the penetration times, rates of dffision and the degradation
Malerial of gloves
The selection of the suitable gloves does not only depend on the material, but also onfurther mark.s of quality and
variesfront ntandacturer to manufacturer. As the product is a preparation ofseveral substances, the resistance of
the glove ntaterial can not be calculqted in advance qnd has therefore to be checked prior to the application.
Penetrctiotr tinte of glove materisl
The exact break through time has to beJbund out by the ntanufacturer of the protective gloves and ha.s to be
observed.
(Conld. on page 6)
8 Exposure corrtrols/personal protection
US
BUILDING TRUST
Printing date I0/28/20I 9
Scfety Dats Sheet
ncc. to OSHA HCS
Puge (t/12
Rct;icv'etl ott I 0/28/20 I 9
Trade name: EPOLAM 2500 Hurtlener
Eye prolecliort:
@
Tightly sealed goggles
lContd. ol'page 5)
*
9 Physical arrd chemicol properties
Informotion on basic physical ond chenical properlies
Generol Itrformotion
Appeurance:
Form: Fluid
Color: According to product specification
Odor: Characteristic
Odor thresholtl: Not deterntined.
pH-value:
Flash poitrt:
Not deterntined.
>100″c(>212″F)
Change in conditiott
M elt i n g po i n t/M e lti rtg rnt ge :
B oil i n g poi trl/B o i I irt g range :
Undeternrined.
232 “C (449.6 “F)
Not deterntined.
Producl does not present an explosion hozard.
Product is not .selfgniting.
D eco nrp osili o n lentp e rotu re : Not deterntined.
Auto igniling:
Danger of explosiott
Vapor pressure:
0.7 Vol%
5Vol%
0.91 g/cmr (7.59 lbs/gal)
Not determined,
Not determined.
Not determined.
Flammability (solid, goseous): Not applicable.
Density ut 20
oC
(68 “F):
Relutive density
Vupor density
Evoporation rale
Explosiotr Iimits:
Lower:
Upper:
Soluhility in / Miscihility with
llaler: Not miscible or di//icult to mix.
Parlitiort coeflicient (n-oclanol/waler) : Not determined.
Viscosity:
Dynumic:
(Contd. on page 7)
Not deterntined.
IJS
@
BUILDING TRUST
Printing date I 0/28/20 I 9
Scfety Dotu Slteet
ncc. t0 OSHA HCS
Page 7/l 2
Reviewed on 10/28/2019
Trade nanrc: EPOLAM 2500 Hardener
(Contd. ofpage 6)
Kinemalic:
Solvenl conlent:
VOC content:
Solids content:
Otlter itrformatiort
Nol delerntined.
0.00 %
0.0 g/l / 0.00 lb/gul
0.0 %
N o.furt her rel eva n ! i nfbr nt o| i on av a i I a bI e.
I0 Stability and reactivity
Re o cl i v i ty N o fur
t h e r r e I ev a nt i nfornt a t i o n av a i I a h I e.
Chemicul stability
TIrcrmil tlecompositiort / corrtlitions to be avoided: No decomposition if-usecl according to specifications.
Possibility of hazardous reactions No dangerous reaclions knot’r,tt.
C o ttd itiotts to uvo id N o furt
h er rel ev a n t infor nt a t i on at, a i I u I’s I e.
I n contp ili b I e materi uls : N o fu
rt h e r r e I ev an t i nfornt a t i on av a i I u b I e.
Hszardous decomposition producls: Carbon monoxide antl cqrbon clioxide
I I Toxicological information
*
Infornrati on on toxi co Io gi cu I effecls
Acule toxicity:
9 04 6- I 0-0 Po Iy oxypropy I en ed iumi n e
2,855 mg/kg
2,980 mg/kg (rabbit)
P rintary i r r it ant effe ct :
on the skin: Strong caustic ffict
on skin and mucous membrqnes.
on tlte eye:
Strong caustic effect.
Strong irritant with the danger of severe eye injury.
Sensitizotion: Sensitization possible through skin con! oct.
Atl tlil i onul toxico lo gica I informot i o n :
The product shows thefollowing dangers according to internally approvecl calculation ntethodsfor preparations
Harnful
Cotosive
Irritant
(Contd. on page 8)
LD/LC10 volues lhat ore relevant.for clossiJicatiort:
Oral
Dermal
LD5O
LD5O
2 8 5 5- I 3 -2 3 -anrinomelltyl-3, 5, 5-lri methy lcJ) c I o h exy I u rtri n e
2,000 ng/kg (rat)
1,030 (rat)
Oral
Derntal
LD5O
LD5O
US
BUILDING TRUST
Puge 8/12
Sqfuty Dota Sheet
ncc. to OSHA HCS
Printing date I 0/28/2019 Revi etvecl on I 0/28/2 0 I 9
Trade name: EPOLAM 2500 Ilunlener
(Contd. ofpagc 7)
Stvallotving,vill leacl Io u. t’one cctu.stic e//bct on trtouth and throal and to the danget” oJ perforution ofesophagu.s
and stontach.
Carci n ogen ic calego ries
IARC (Intertrationol Agettc1,.fttr Reseurch on Cancer)
None oJ’tlte ingredients is li.ttetl.
NTP (Nalionol Toxicolog.l, Progrunt)
None of tlte ingredients is li.stctl.
OSHA-CI (Occupatiortul Sufety & lleulth Adtrtittistraliott)
None of the ingredients is li.stecl.
I 2 Ecological information
96 hr LC50
NOEC
2 8 5 5- I 3-2 3-umin oruethy I–1, 5,5-tri nrcthy IcycIoh exyIamine
Il0 nrg,’l (Fish)
3 ntg/l (dophnial
48 hr EC50
96 hr LC50
72 or 96 hr ErC50
Toxicity
Aquutic toxicity
904 6- I 0-0 Po lyoxypropy len ed i a tni n e
B0 ntgil (daphnia)
772 ntg/l (f i,e111
|5 ntg/l (Algea)
Persistettce and degradabil it1, l{s evant
Belruvior in environmertlul sJtslenrs:
B ioacc u nu I ative p ole n t i u I N o./ilr t h e r re I ev a nt i nfornt a t ion av a il a bl e.
Mobility irr soil Nofut’ther relevanl in/brntation available.
Ecotoxical effects:
Rernurk : Harmfu I to./i.sh
Additionol ecoIogicaI inJbrntation :
General noles:
Water hazard class I (SelJ-ussessntent): slightly hazardous for water
Do not allou,undilutecl product or lurge quantities of it to reach groundwater, water course orsewqge system.
Must not reach bodies of-v’uter or drainage ditch undiluted or unneutralized.
H annftrl !o aqua! ic ot’eutt i.snr.t
Resuhs of PBT and vPvB ussesstnenl
PBT: Not applicable.
vPvB: Not applicable.
Other udverse effects Nct.filrther relevunt inforntation available.
US
(Contd. on page 9)
BUILDING TRUST
Printittg tlate I 0/28/20I 9
Scfety Dats Sheet
ncc. t0 OSHA HCS
Page 9/12
Revievted on l 0/28/20 l 9
Trude name: EPOLAM 2500 Hurdener
(Contd. olpage 8)
13 Disposal considerations
Wosl e t realnr enl nteth o ds
Recomnrcndation:
Must rtd be disposed of together with household garbage. Do not allow product to reach sewage systenl
Uncleaned pockagings:
Recommendulion: Disposal ntust be made according to oficial regulations.
14 Transport information
/A
,/g#!
yz
Z
V
UN-Nnmber
DOT,IMDG,IATA
UN proper shipping name
DOT
IMDG,IATA
Tra n sp o rl h uza rd class (es)
DOT
Cluss
Label
IMDG,IATA
Class
Label
Pucking group
DOT,IMDG,IATA
Envi ro n m ent u I h aza rds :
Murine pollulant:
Special precuutiorrs for user
Danger code (Kemler):
EMS Number:
uN2289
Isophoronediamine
ISOPHORONEDIAMINE
B Corrosive substances
8
B Corrosive substances
8
ilI
No
VI/ arn ing : C orr os iv e subs t an c es
80
F-A,S-B
(Contd. on page I 0)
US
BUILDING TRUST
Printing date I 0/28/20 1 9
Snfnty Dttttt Sheet
lcc. to OSHA HCS
Page l0/12
Revieu,ed on I 0/28/20 I 9
Trade name: EPOLAM 2500 Hanlener
(Contd. ofpage 9)
Stowage Category A
Transport in bulk according to Annex II o./
MARPOLT3/78 and the IBC Code Not applicable.
T r n n s p o rl/A d d i t i o n a I i nfo r nru t i o tr :
DOT
Quonlity Iimitstions On passenger aircraft/rail: 5 L
On cargo aircraft only: 60 L
IMDG
Limited qu antities (LQ)
Excepted qu antities (EQ)
5L
Code: El
Maxinttrm net quantity per inner packaging: 30 nl
Maxirnunt net quantity per outer packaging: 1000 ml
UN ” Model Regu latiort” : UN 2289 ISOPHORONED]AMINE, B, ]II
1 5 Regultttory informilion
*
Sofety, healllt trnd environntenlul regulcrtions/legislalion speciJic.for the subslonce or mixturc
Saru
Section 355 (extremely ltuardous subslunces):
None of the ingredients is listed.
Sectiott 313 (SpeciJic toxic chemical listings):
None of the ingredicnts is listed.
TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
Chemicols reguliled by TSCA Sectiort l2(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(u)(2)rule:
None of the ingredients is listed.
H azardo u s Ai r Po I I u lanls
None of the i.s listed.
Propositiorr 65
Cltemicals knowtt to c(use cuncer:
7 5-56-9propylene oxide
Chemicsls ktrowrt lo cuuse reproductive toxicity.fot.females:
None of the ingredients is listed.
Chemicals known to cause reproduclive toxicity.for males
(Contd. on page I I )
None of’the ingredients is listed.
US
BUILDING TRUST
Printing date I 0/28/20 I 9
Sofnty Dsta Sheet
ncc. to OSHA HCS
Page l l/12
Reviewed on 10/28/2019
Trade nante: EPOLAM 2500 Hurdener
(Contd. ofpage l0)
Chemiculs knowtr to c(use developmental toxicity:
None of the ingredients is listed.
C orci n o gen i c c ileg o ries
TLV (Threshold Linit vslue estublished by ACGIH)
None of the ingredients is listed.
Listed in ClltC Regulatious
None of the ingredients is listed.
NIOSH-Ca (Nationol Institute for Occupational Sofety nnd Healtlt)
None of the ingredients is listed.
GHS lcbel elements
Hazard pictograms
t.sassifed and labeled according to (GHS)
GHSOs GHSOT
Signal word Danger
H azartl-deternrini n g co mp on enls of I a bel i n g :
3 – ant inomethyl- 3, 5, 5 -trin etlrylcyclo h exy I am ine
P o ly oxypr opy I en e di a m in e
3 – a m i n opr opy I d i e t hy I anr i n e
Hazard statements
Harmful if swallowed.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Harntful to aquatic life.
Harmful to aquatic life with long lasting efficts.
P r ec a u t ion a ry st ste nten I s
Do not breathe dusts or misls.
I4ear protective gloves/protective clothing/eye protection/face protection.
If swallou,ed: Call a poison center/doctor ifyoufeel unwell.
If on skin (or hair): Take offintnediately all contaminated clothing. Rinse skinwithwater/shower.
IF INHALED: Remove person tofresh air and keep comfortablefor breathing.
lf in eyes: Rinse cautiously with waterfor several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Imntediately call a poison center/doctor.
Specific treatment (see on this label).
Store locked up,
Dispose of contents/container in accordqnce v,ilh local/regional/national/international regulalions.
(Contd. on page l2)
Harmon
T
o
US
BUILDIN6 TRUST
Printing date 10/28/20I 9
Scfety Duttt Sheet
acc. to OSHA HCS
Pogc l2/12
Revietvccl on I 0/28/20 I 9
Trude name: EPOLAM 2500 Hardener
(Contd. ol’page I l)
Chemicul sofety asssssment: A Chentical Safety Assessment has no! been corrietl out
This in/brmation is based on our present knowledge. Hov,ever, this shall not crtrt.sliltrte a guurQnleefor any
specific prodtrct features
and shall not establish a legally valid contrctctual relationship.
Date of prepototiott / Iast revisiort 10/28/2019 / 2
Abhrevi ali o tts an d acro n)) ms :
IMDG: lntenntional Maritine Code.for Dangerous Goods
DOT: US Deparlnent of Tronsportalion
I ATA : I n le rna I i ona I A i r Transporl A ss oc ial i ot1
ACGIH: Anterican Conference of Governmenlal Industriol Hygienisls
EINECS: European lnventory of Exisling Comntercial Chemical Subslances
ELINCS: European List of Notrfied Chentical Substartces
CAS: Che rnical Abslracls Service (division of lhe Anretican Chemical Society)
NFPA: Notional Fire Protection Association (USA)
l’! lvl I S : U aza rd ous M ate r i a I s I d en t ifi ca t i on Sys te m (U S A)
ItOC: I/olotile Organic Compounds (USA, EU)
LC50: Lethal concenlration, 50 percenl
LD50: Lethol dose, 50 percent
PBT: Persislenl, Bioaccumulative and Toxic
vPvB: ve11, Persislent and vew Bioacatmulalive
NIOSH: Nalional lnslilute for Occupational Safety
OSHA: Occupational Safety & Health
TLII: Threshold Limit Value
PEL: Pernissible Exposure Linril
REL: Reconnrcnded Exposure Limil
Acule Tox. 4: tlcule loxicily – Category 4
Skin Corr. I il: Skin corrosion/itilation – Caregory l A
Eye Dant. l: Serious eye damage/eye irrilatiotl –
Category I
Skin Sens. l: Skin sensilisalion –
Category l
Aqucttic Acute 3: Hazardous lo lhe dqualic environnrcnt – aaile aqualic hazard Category 3
Aquotic Chronic 3: Hazardous lo the aquLtic environmenl – long-term aclualic hazard – Calegory 3
*
Dala conrporcd lo the previous vetsiotl ahered.
US