81MGSR935D_SDS.pdf

Page:1/16

Version: 2.0 Date of issue/Date of revision: 05/13/2015 Date of previous issue: 09/18/2012

SAFETY DATA SHEET

FOR INDUSTRIAL USE ONLY

EPIKOTE

Resin MGS RIMR 935

Section 1. Product and company identification

GHS product identifier : EPIKOTE

Resin MGS RIMR 935
MSDS Number : 16S-00150
Product type : Epoxy Resin
Material uses : Epoxy Resin Systems

Manufacturer/Supplier/Impor
ter
: Hexion Inc.
180 East Broad Street
Columbus, Ohio
43215 USA

Contact person : 4information@hexion.com

Telephone : For additional health and safety or regulatory information, call
1 888 443 9466.

Emergency telephone number : For Emergency Medical Assistance
Call Health & Safety Information Services
1-866-303-6949

For Emergency Transportation Information
CHEMTREC US Domestic (800) 424-9300
CHEMTREC International (703) 527-3887
CANUTEC CA Domestic (613) 996-6666

Section 2. Hazards identification

Classification of the substance or
mixture
: SKIN CORROSION/IRRITATION – Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION – Category 2A
SKIN SENSITIZATION – Category 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
[central nervous system (CNS)] – Category 1
SPECIFIC TARGET ORGAN TOXICITY (REPEATED
EXPOSURE) [skin, liver] – Category 1

GHS label elements

Hazard pictograms :

Signal word : Danger
Hazard statements : H315 Causes skin irritation.
H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.

EPIKOTE

Resin MGS RIMR 935 Page:2/16

Version: 2.0 Date of issue/Date of revision: 05/13/2015 Date of previous issue: 09/18/2012

H370 Causes damage to organs: (central nervous system (CNS))
H372 Causes damage to organs through prolonged or repeated
exposure: (skin, liver)

Precautionary statements

General : Not applicable.

Prevention : Wear protective gloves.
Wear eye or face protection.
Do not breathe vapor.
Do not eat, drink or smoke when using this product.
Wash hands thoroughly after handling.
Contaminated work clothing should not be allowed out of the
workplace.

Response : Get medical attention if you feel unwell.
IF exposed:
Call a POISON CENTER or physician.
IF ON SKIN:
Wash with plenty of soap and water.
Take off contaminated clothing.
Wash contaminated clothing before reuse.
If skin irritation or rash occurs:
Get medical attention.
IF IN EYES:
Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
If eye irritation persists:
Get medical attention.

Storage : Store locked up.

Disposal : Dispose of contents and container in accordance with all local,
regional, national and international regulations.

Other hazards which do not result
in classification
: None known.

Section 3. Composition/information on ingredients

Substance/mixture : Mixture

Ingredient name % by weight CAS
number
4,4′-Isopropylidenediphenol-Epichlorohydrin Copolymer 35 – 50 25068-38-6
Formaldehyde, polymer with (chloromethyl)oxirane and
phenol, mw <=700 20 - 25 9003-36-5 1,4-Butanedioldiglycidyl Ether 15 - 20 2425-79-8 Polyglycidyl Ether (Proprietary) 15 - 20 There are no additional ingredients present which, within the current knowledge of the supplier and in the EPIKOTE Resin MGS RIMR 935 Page:3/16 Version: 2.0 Date of issue/Date of revision: 05/13/2015 Date of previous issue: 09/18/2012 concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Section 4. First aid measures Description of necessary first aid measures Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. If necessary, call a poison center or physician. Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Skin contact : Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. If necessary, call a poison center or physician. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse. Ingestion : Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. If necessary, call a poison center or physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Indication of immediate medical attention and special treatment needed, if necessary Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Protection of first aid personnel : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. See toxicological information (Section 11) Section 5. Fire-fighting measures Extinguishing media EPIKOTE Resin MGS RIMR 935 Page:4/16 Version: 2.0 Date of issue/Date of revision: 05/13/2015 Date of previous issue: 09/18/2012 Suitable extinguishing media : Use an extinguishing agent suitable for the surrounding fire. Unsuitable extinguishing media : None known. Specific hazards arising from the chemical : In a fire or if heated, a pressure increase will occur and the container may burst. Hazardous thermal decomposition products : Decomposition products may include the following materials: carbon dioxide carbon monoxide halogenated compounds Special protective actions for fire- fighters : Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective equipment for fire-fighters : Fire-fighters should wear appropriate protective equipment and self- contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency personnel : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel". Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Methods and material for containment and cleaning up Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Large spill : Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non- combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see section 13 of SDS). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see section 1 of SDS for emergency contact information and section 13 of SDS for waste disposal. EPIKOTE Resin MGS RIMR 935 Page:5/16 Version: 2.0 Date of issue/Date of revision: 05/13/2015 Date of previous issue: 09/18/2012 Section 7. Handling and storage Precautions for safe handling Protective measures : Put on appropriate personal protective equipment (see section 8 of SDS). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Advice on general occupational hygiene : Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Conditions for safe storage, including any incompatibilities : Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10 of SDS) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Section 8. Exposure controls/personal protection Control parameters Occupational exposure limits None. Recommended monitoring procedures : If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the determination of hazardous substances will also be required. Appropriate engineering controls : If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. EPIKOTE Resin MGS RIMR 935 Page:6/16 Version: 2.0 Date of issue/Date of revision: 05/13/2015 Date of previous issue: 09/18/2012 Individual protection measures Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Skin protection Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Body protection : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection : Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Section 9. Physical and chemical properties Appearance Physical state : Liquid Color : Yellowish. Odor : characteristic. Odor threshold : Not available pH : Not available Melting point/ Freezing point : Not available Boiling point : 200 C (392.00 F) Flash point : 120 C (248.00 F) Burning time : Not available EPIKOTE Resin MGS RIMR 935 Page:7/16 Version: 2.0 Date of issue/Date of revision: 05/13/2015 Date of previous issue: 09/18/2012 Burning rate : Not available Evaporation rate : Not available Flammability (solid, gas) : Not available Lower and upper explosive (flammable) limits : Lower: Not available Upper: Not available Vapor pressure : 4 hPa @ 20 C (68.00 F) Vapor density : Not available Relative density : Not available Density : 1.140 g/cm3 Solubility : Not available Solubility in water : Negligible Partition coefficient: n- octanol/water : Not available Auto-ignition temperature : Not available Decomposition temperature : Not available SADT : Not available Viscosity : Dynamic: 150 - 450 mPa s @ 25 C (77.00 F) (DIN 53015) Kinematic: Not available Other information No additional information. Section 10. Stability and reactivity Reactivity : Stable under normal conditions. Chemical stability : The product is stable. Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Conditions to avoid : No specific data. Incompatible materials : No specific data. Hazardous decomposition products : Under normal conditions of storage and use, hazardous decomposition products should not be produced. Section 11. Toxicological information Information on toxicological effects Acute toxicity Product/ingredient name Result Species Dose Exposure 4,4'-Isopropylidenediphenol-Epichlorohydrin Copolymer LD50 Oral Rat 11,400 mg/kg - LD50 Dermal Rat 2,000 mg/kg - Formaldehyde, polymer with (chloromethyl)oxirane and phenol, mw <=700 EPIKOTE Resin MGS RIMR 935 Page:8/16 Version: 2.0 Date of issue/Date of revision: 05/13/2015 Date of previous issue: 09/18/2012 LD50 Oral Rat > 2,000 mg/kg –
LD50 Dermal Rabbit > 2,000 mg/kg –
1,4-Butanedioldiglycidyl Ether
LD50 Oral Rat 1,163 mg/kg
OECD-Guideline
401 (Acute Oral
Toxicity)
–
LC50 Inhalation Rat > 11.3 mg/l 4 h
LD50 Dermal Rabbit 1,130 mg/kg –
Polyglycidyl Ether (Proprietary)
LD50 Oral Rat > 2,000 mg/kg –
LD50 Dermal Rat > 2,000 mg/kg –
Conclusion/Summary : Not available

Irritation/Corrosion

Product/ingredient name Result Species Score Exposure Observation
4,4′-Isopropylidenediphenol-
Epichlorohydrin Copolymer
Skin –
Erythema/E
schar 404
Acute
Dermal
Irritation/Co
rrosion
Rabbit 1.5 – 2 –
Skin –
Edema 404
Acute
Dermal
Irritation/Co
rrosion
Rabbit 1.0 – 1.5 –
eyes – – 405
Acute Eye
Irritation/Co
rrosion
Rabbit 0 –
eyes –
Redness of
the
conjunctiva
e
Rabbit 0.7 –
Skin –
Moderate
irritant
Rabbit 24 hrs –
Skin –
Severe
irritant
Rabbit 24 hrs –
eyes – Mild
irritant
Rabbit –
Formaldehyde, polymer with
(chloromethyl)oxirane and phenol,
mw <=700 Skin - Erythema/E schar 404 Acute Dermal Irritation/Co rrosion Rabbit 0.7 4 hrs 72 hrs EPIKOTE Resin MGS RIMR 935 Page:9/16 Version: 2.0 Date of issue/Date of revision: 05/13/2015 Date of previous issue: 09/18/2012 Skin - Edema 404 Acute Dermal Irritation/Co rrosion Rabbit 0 4 hrs 4 - 504 hrs eyes - Cornea opacity 405 Acute Eye Irritation/Co rrosion Rabbit 0 1 - 168 hrs eyes - Iris lesion 405 Acute Eye Irritation/Co rrosion Rabbit 0 1 - 168 hrs eyes - Redness of the conjunctiva e 405 Acute Eye Irritation/Co rrosion Rabbit 0 1 - 168 hrs eyes - Edema of the conjunctiva e 405 Acute Eye Irritation/Co rrosion Rabbit 0 1 - 168 hrs Skin - Mild irritant Rabbit 24 hrs - 1,4-Butanedioldiglycidyl Ether Skin - Erythema/E schar 404 Acute Dermal Irritation/Co rrosion Rabbit 0 24 - 72 hrs Skin - Edema 404 Acute Dermal Irritation/Co rrosion Rabbit 0 24 - 72 hrs Skin - Erythema/E schar OPP 81-5 Acute Dermal Irritation Rabbit 2.5 24 hrs Skin - Rabbit 2.3 24 hrs EPIKOTE Resin MGS RIMR 935 Page:10/16 Version: 2.0 Date of issue/Date of revision: 05/13/2015 Date of previous issue: 09/18/2012 Edema OPP 81-5 Acute Dermal Irritation eyes - Cornea opacity 405 Acute Eye Irritation/Co rrosion Rabbit 1.22 24 - 72 hrs eyes - Iris lesion 405 Acute Eye Irritation/Co rrosion Rabbit 0.78 24 - 72 hrs eyes - Edema of the conjunctiva e 405 Acute Eye Irritation/Co rrosion Rabbit 2.33 24 - 72 hrs eyes - Redness of the conjunctiva e 405 Acute Eye Irritation/Co rrosion Rabbit 2.22 24 - 72 hrs eyes - Moderate irritant Rabbit - Skin - Moderate irritant Rabbit 24 hrs - Conclusion/Summary Skin : Not available eyes : Not available Respiratory : Not available Sensitization Conclusion/Summary Skin : Not available Respiratory : Not available Mutagenicity Conclusion/Summary : Not available Carcinogenicity Conclusion/Summary : Not available EPIKOTE Resin MGS RIMR 935 Page:11/16 Version: 2.0 Date of issue/Date of revision: 05/13/2015 Date of previous issue: 09/18/2012 Reproductive toxicity Product/ingredient name Maternal toxicity Fertility Development toxin Species Dose Exposure 4,4'- Isopropylidenediphenol -Epichlorohydrin Copolymer - - - - - - Remarks: No adverse reproductive effects were observed in an O.E.C.D. Test Guideline no. 416 GLP two- generation rat oral gavage study conducted up to a high dose level of 750 mg/kg/day that resulted in adult body weight decrements. Conclusion/Summary : Not available Teratogenicity Conclusion/Summary : Not available Specific target organ toxicity (single exposure) Product/ingredient name Category Route of exposure Target organs 4,4'-Isopropylidenediphenol- Epichlorohydrin Copolymer Category 3 Respiratory tract irritation Formaldehyde, polymer with (chloromethyl)oxirane and phenol, mw <=700 Category 3 Respiratory tract irritation 1,4-Butanedioldiglycidyl Ether Category 3 Category 1 Respiratory tract irritation central nervous system (CNS) Polyglycidyl Ether (Proprietary) Category 3 Respiratory tract irritation Specific target organ toxicity (repeated exposure) Product/ingredient name Category Route of exposure Target organs 1,4-Butanedioldiglycidyl Ether Category 1 Category 2 skin liver Polyglycidyl Ether (Proprietary) Category 1 skin Aspiration hazard Not available Information on the likely routes of exposure : Not available Potential acute health effects Eye contact : Causes serious eye irritation. Inhalation : No known significant effects or critical hazards. Skin contact : Causes skin irritation. May cause an allergic skin reaction. Ingestion : Irritating to mouth, throat and stomach. Symptoms related to the physical, chemical and toxicological characteristics EPIKOTE Resin MGS RIMR 935 Page:12/16 Version: 2.0 Date of issue/Date of revision: 05/13/2015 Date of previous issue: 09/18/2012 Eye contact : Adverse symptoms may include the following: pain or irritation watering redness Inhalation : No specific data. Skin contact : Adverse symptoms may include the following: irritation redness Ingestion : No specific data. Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Potential immediate effects : Not available Potential delayed effects : Not available Long term exposure Potential immediate effects : Not available Potential delayed effects : Not available Potential chronic health effects Conclusion/Summary : Not available General : Causes damage to organs through prolonged or repeated exposure: Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : No known significant effects or critical hazards. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Numerical measures of toxicity Acute toxicity estimates Route ATE value Dermal 7,533.4 mg/kg Route ATE value Inhalation (vapors) 73.33 mg/l Section 12. Ecological information Toxicity Product/ingredient name Result Species Exposure reaction product: bisphenol-A-(epichlorhydrin); epoxy resin (number average molecular weight 700) Acute LC50 1.3 mg/l - 203 Fish, Acute Toxicity Test Fish - Fish 96 h Acute EC50 2.1 mg/l - 202 Daphnia sp. Acute Immobilization Test and Aquatic invertebrates. Water flea 48 h EPIKOTE Resin MGS RIMR 935 Page:13/16 Version: 2.0 Date of issue/Date of revision: 05/13/2015 Date of previous issue: 09/18/2012 Reproduction Test Acute NOEC 0.3 mg/l - 211 Daphnia Magna Reproduction Test Aquatic invertebrates. Water flea 21 d Acute LC50 > 11 mg/l – Aquatic plants – Algae 72 h
Formaldehyde, polymer with (chloromethyl)oxirane and phenol, mw <=700 Acute LC50 2.54 mg/l - Fish - Fish 96 h Acute EC50 2.55 mg/l - 202 Daphnia sp. Acute Immobilization Test and Reproduction Test Aquatic invertebrates. Water flea 48 h Acute EC50 > 1,000 mg/l – 201 Alga,
Growth Inhibition Test
Aquatic plants – Algae 72 h
1,4-bis(2,3 epoxypropoxy)butane
Acute LC50 24 mg/l – 203 Fish, Acute
Toxicity Test
Fish – Zebra danio 96 h
Acute EC50 76 mg/l – 202 Daphnia sp.
Acute Immobilization Test and
Reproduction Test
Aquatic invertebrates.
Water flea
24 h
Acute EC50 110 mg/l – 201 Alga,
Growth Inhibition Test
Aquatic plants – Algae 72 h

Conclusion/Summary : Not available

Persistence/degradability

Conclusion/Summary : Not available

Bioaccumulative potential

Product/ingredient name LogPow BCF Potential
4,4′-Isopropylidenediphenol-
Epichlorohydrin Copolymer
2.64 – 3.78 3 – 31 31.00 low
Formaldehyde, polymer with
(chloromethyl)oxirane and phenol,
mw <=700 3.3 150 150.00 low 1,4-Butanedioldiglycidyl Ether -0.269-0.15 - low Mobility in soil Soil/water partition coefficient (KOC) : Not available Other adverse effects : No known significant effects or critical hazards. Section 13. Disposal considerations Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging EPIKOTE Resin MGS RIMR 935 Page:14/16 Version: 2.0 Date of issue/Date of revision: 05/13/2015 Date of previous issue: 09/18/2012 should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Section 14. Transport information The data provided in this section is for information only and may not be specific to your package size or mode of transport. You will need to apply the appropriate regulations to properly classify your shipment for transportation. International transport regulations Regulatory information UN/NA number Proper shipping name Classes/*PG Reportable Quantity (RQ) CFR Non-regulated TDG Non-regulated IMO/IMDG 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (EPOXIDE DERIVATIVES) Class 9 III IATA (Cargo) 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (EPOXIDE DERIVATIVES) Class 9 III *PG : Packing group Special precautions for user : Transport within user s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. Section 15. Regulatory information United States U.S. Federal regulations : United States - TSCA 12(b) - Chemical export notification: None required. United States - TSCA 5(a)2 - Final significant new use rules: Not listed United States - TSCA 5(a)2 - Proposed significant new use rules: Not listed United States - TSCA 5(e) - Substances consent order: Not listed California Prop. 65: : WARNING: This product contains less than 0.1% of a chemical known to EPIKOTE Resin MGS RIMR 935 Page:15/16 Version: 2.0 Date of issue/Date of revision: 05/13/2015 Date of previous issue: 09/18/2012 the State of California to cause cancer. Ingredient name Cancer Reproductive No significant risk level Maximum acceptable dosage level Oxirane, 2-(phenoxymethyl)- Yes. No. 5 g/day No. United States inventory (TSCA 8b) : All components are listed or exempted. Canada WHMIS (Canada) : Class D-2B: Material causing other toxic effects (Toxic). Canadian lists Canadian NPRI : None required. CEPA Toxic substances : None required. International regulations International lists : Australia inventory (AICS): All components are listed or exempted. Canada inventory: All components are listed or exempted. Japan inventory: All components are listed or exempted. China inventory (IECSC): All components are listed or exempted. Korea inventory: All components are listed or exempted. New Zealand Inventory (NZIoC): Not determined. Philippines inventory (PICCS): All components are listed or exempted. United States inventory (TSCA 8b): All components are listed or exempted. Taiwan inventory (CSNN): All components are listed or exempted. Section 16. Other information Hazardous Material Information System III (U.S.A.) : Health * 2 Flammability 1 Physical hazards 0 Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS ratings are not required on MSDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS ratings are to be used with a fully implemented HMIS program. HMIS is a registered mark of the National Paint & Coatings Association (NPCA). HMIS materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. Full text of abbreviated H statements : Not applicable. History Date of printing : 09/06/2016 Date of issue/Date of revision : 05/13/2015 EPIKOTE Resin MGS RIMR 935 Page:16/16 Version: 2.0 Date of issue/Date of revision: 05/13/2015 Date of previous issue: 09/18/2012 Date of previous issue : 09/18/2012 Version : 2.0 Prepared by : Product Safety Stewardship Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) RID = The Regulations concerning the International Carriage of Dangerous Goods by Rail UN = United Nations References : Not available Notice to reader The information provided herein was believed by Hexion Inc. ("Hexion") to be accurate at the time of preparation or prepared from sources believed to be reliable, but it is the responsibility of the user to investigate and understand other pertinent sources of information, to comply with all laws and procedures applicable to the safe handling and use of the product and to determine the suitability of the product for its intended use. All products supplied by Hexion are subject to Hexion's terms and conditions of sale. HEXION MAKES NO WARRANTY, EXPRESSED OR IMPLIED, CONCERNING THE PRODUCT OR THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE OR CONCERNING THE ACCURACY OF ANY INFORMATION PROVIDED BY HEXION, except that the product shall conform to Hexion's specifications. Nothing contained herein constitutes an offer for the sale of any product. and Licensed trademarks of Hexion Inc.