AKPEROX L40S
Revision nr. 0.0
Dated 18/05/2023
Printed on 18/05/2023
Page n. 1/14
Replaced revision:-
Safety Data Sheet
According to U.S.A. Federal Hazcom 2012
1. Identification
1.1. Product identifier
Product name AKPEROX L40S
Chemical name and synonym Di Benzoyl Peroxide, Paste, 40%
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified Uses Industrial Professional Consumer
Industrial
– –
Uses Advised Against
No specific uses advised against are identified.
1.3. Details of the supplier of the safety data sheet
Name AKPA KIMYA AMBALAJ SAN. VE TIC. A.S.
Full address Yenibosna Merkez Mah. Ladin Sok. No:36/70 Kat:12 Townofis Bah elievler
District and Country 34197 stanbul (www.akpakimya.com)
TR
Tel. +90 212 580 55 59
Fax +90 212 580 55 21
e-mail address of the competent person info@akpakimya.com
Export Deparment – export@akpakimya.com
1.4. Emergency telephone number
Emergency telephone CHEMTREC: TOLL Free 1-800-424-9300 / Local: +1-703-527-3887
For product information AKPA CHEMICALS US: +1 803 686 2888
2. Hazards identification
2.1. Classification of the substance or mixture
The product is classified as hazardous pursuant to the provisions set forth in OSHA Hazard Communication Standard (HCS) (29 CFR 1910.1200). The
product thus requires a safety datasheet.
Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet.
Classification and Hazard Statement
Hazard pictograms:
Organic peroxide, type E Heating may cause a
fire.
Eye irritation, category 2 Causes serious eye
irritation.
Skin sensitization, category 1 May cause an allergic
skin reaction.
Signal words: Warning
AKPEROX L40S
Revision nr. 0.0
Dated 18/05/2023
Printed on 18/05/2023
Page n. 2/14
Replaced revision:-
Hazard statements:
H242 Heating may cause a fire.
H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
Prevention:
Precautionary
statements:
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P261 Avoid breathing dust / fume / gas / mist / vapours / spray.
P220 Keep/Store away from clothing/ strong acids, bases, heavy metal salts and other reducing substances /combustible
materials
P234 Keep only in original container.
P280 Wear protective gloves / eye protection / face protection.
P264 Wash skin thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
Response:
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
P333+P313 If skin irritation or rash occurs: Get medical advice / attention.
P337+P313 If eye irritation persists: Get medical advice / attention.
P302+P352 IF ON SKIN: Wash with plenty of water.
P363 Wash contaminated clothing before reuse.
Storage:
P411+P235 Store at temperatures not exceeding (0) – (25 C) .Keep cool.
P410 Protect from sunlight.
Disposal:
P501 Dispose of contents/ container to an approved waste dis-posal plan
2.2. Other hazards
Environmental classification as for Reg. (EC) 1272/2008 (CLP):
The product is classified as hazardous for environment pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP).
Classification and Hazard Statement
Hazardous to the aquatic environment, acute toxicity, category 1 Very toxic to aquatic life.
Hazardous to the aquatic environment, chronic toxicity, category 1 Very toxic to aquatic life with long lasting effects.
Hazard pictograms:
Signal words: Warning
Hazard statements:
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
Prevention:
Precautionary
statements:
P273 Avoid release to the environment.
Response:
P391 Collect spillage.
AKPEROX L40S
Revision nr. 0.0
Dated 18/05/2023
Printed on 18/05/2023
Page n. 3/14
Replaced revision:-
Storage:
—
Disposal:
P501 Dispose of contents / container to . . .
Additional hazards
Information not available
3. Composition/information on ingredients
3.1. Substances
Information not relevant
3.2. Mixtures
Contains:
Dibenzoyl Peroxide 39 x < 41 Organic peroxide, type B H241, Eye irritation, category 2 H319, Skin sensitization, category 1 H317, Hazardous to the aquatic environment, acute toxicity, category 1 H400 M=1, Hazardous to the aquatic environment, chronic toxicity, category 1 H410 M=1 EC 202-327-6 CAS 94-36-0 Zinc stearate 1 x < 5 EC 209-151-9 CAS 557-05-1 The full wording of hazard (H) phrases is given in section 16 of the sheet. 4. First-aid measures 4.1. Description of first aid measures EYES: Remove contact lenses, if present. Wash immediately with plenty of water for at least 15 minutes, opening the eyelids fully. If problem persists, seek medical advice. SKIN: Remove contaminated clothing. Wash immediately with plenty of water. If irritation persists, get medical advice/attention. Wash contaminated clothing before using it again. INHALATION: Remove to open air. In the event of breathing difficulties, get medical advice/attention immediately. INGESTION: Get medical advice/attention. Induce vomiting only if indicated by the doctor. Never give anything by mouth to an unconscious person, unless authorised by a doctor. 4.2. Most important symptoms and effects, both acute and delayed Specific information on symptoms and effects caused by the product are unknown. 4.3. Indication of any immediate medical attention and special treatment needed Information not available 5. Fire-fighting measures 5.1. Extinguishing media AKPEROX L40S Revision nr. 0.0 Dated 18/05/2023 Printed on 18/05/2023 Page n. 4/14 Replaced revision:- SUITABLE EXTINGUISHING EQUIPMENT The extinguishing equipment should be of the conventional kind: carbon dioxide, foam, powder and water spray. UNSUITABLE EXTINGUISHING EQUIPMENT None in particular. 5.2. Special hazards arising from the substance or mixture HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE Do not breathe combustion products. 5.3. Advice for firefighters GENERAL INFORMATION Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of contaminated water used for extinction and the remains of the fire according to applicable regulations. SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137). 6. Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Block the leakage if there is no hazard. Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent any contamination of skin, eyes and personal clothing. These indications apply for both processing staff and those involved in emergency procedures. 6.2. Environmental precautions The product must not penetrate into the sewer system or come into contact with surface water or ground water. 6.3. Methods and material for containment and cleaning up Collect the leaked product into a suitable container. Evaluate the compatibility of the container to be used, by checking section 10. Absorb the remainder with inert absorbent material. Make sure the leakage site is well aired. Contaminated material should be disposed of in compliance with the provisions set forth in point 13. 6.4. Reference to other sections Any information on personal protection and disposal is given in sections 8 and 13. 7. Handling and storage 7.1. Precautions for safe handling Ensure that there is an adequate earthing system for the equipment and personnel. Avoid contact with eyes and skin. Do not breathe powders, vapours or mists. Do not eat, drink or smoke during use. Wash hands after use. Avoid leakage of the product into the environment. 7.2. Conditions for safe storage, including any incompatibilities Store only in the original container. Store in a ventilated and dry place, far away from sources of ignition. Keep containers well sealed. Keep the product AKPEROX L40S Revision nr. 0.0 Dated 18/05/2023 Printed on 18/05/2023 Page n. 5/14 Replaced revision:- in clearly labelled containers. Avoid overheating. Avoid violent blows. Keep containers away from any incompatible materials, see section 10 for details. 7.3. Specific end use(s) Information not available 8. Exposure controls/personal protection 8.1. Control parameters Regulatory References: USA NIOSH-REL NIOSH publication No. 2005-149, 3th printing, 2007. USA OSHA-PEL Occupational Exposure Limits - Limits for Air Contaminants TABLE Z-1-1910.1000. USA CAL/OSHA-PEL California Division of Occupational Safety and Health (Cal-OSHA) Permissible Exposure Limits (PELs). Zinc stearate Threshold Limit Value Type Country TWA/8h STEL/15min Remarks / Observations mg/m3 ppm mg/m3 ppm OSHA USA 15 INHAL OSHA USA 5 RESP CAL/OSHA USA 10 NIOSH USA 10 INHAL NIOSH USA 5 RESP Dibenzoyl Peroxide Threshold Limit Value Type Country TWA/8h STEL/15min Remarks / Observations mg/m3 ppm mg/m3 ppm OSHA USA 5 CAL/OSHA USA 5 NIOSH USA 5 Legend: (C) = CEILING ; INHAL = Inhalable Fraction ; RESP = Respirable Fraction ; THORA = Thoracic Fraction. 8.2. Exposure controls As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is well aired through effective local aspiration. Personal protective equipment must comply with current regulations. HAND PROTECTION Protect hands with category III work gloves. The following should be considered when choosing work glove material (OSHA 29 CFR 1910.138): compatibility, degradation, failure time and permeability. The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on the duration and type of use. SKIN PROTECTION AKPEROX L40S Revision nr. 0.0 Dated 18/05/2023 Printed on 18/05/2023 Page n. 6/14 Replaced revision:- Wear category I professional long-sleeved overalls and safety footwear. Wash body with soap and water after removing protective clothing. EYE PROTECTION Wear airtight protective goggles (OSHA 29 CFR 1910.133). RESPIRATORY PROTECTION If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, wear a mask with a NIOSH certified filter, whose class must be chosen according to the limit of use concentration (NIOSH 42 CFR 84, OSHA 29 CFR 1910.134). In the presence of gases or vapours of various kinds and/or gases or vapours containing particulate (aerosol sprays, fumes, mists, etc.) combined filters are required. Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure to the threshold values considered. The protection provided by masks is in any case limited. If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an emergency, wear open-circuit compressed air breathing apparatus or external air-intake breathing apparatus. For a correct choice of respiratory protection device, see standard NIOSH 42 CFR 84, OSHA 29 CFR 1910.134. ENVIRONMENTAL EXPOSURE CONTROLS The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure compliance with environmental standards. Product residues must not be indiscriminately disposed of with waste water or by dumping in waterways. 9. Physical and chemical properties 9.1. Information on basic physical and chemical properties Properties Value Information Appearance Emulsion Colour white Odour characteristic Melting point / freezing point not available Viscosity 1000 200 cP 25 C Solubility(ies) Water solubility insoluble Density and/or relative density 1,175 0,005 g/cm3 20 C 9.2. Other information Active Oxygen Content 2,57 - 2,71 % SADT 50 C 10. Stability and reactivity 10.1. Reactivity Information not available 10.2. Chemical stability The product is stable if stored in original containers at temperatures lower than the self accelerated decomposition temperature (SADT). 10.3. Possibility of hazardous reactions Information not available 10.4. Conditions to avoid AKPEROX L40S Revision nr. 0.0 Dated 18/05/2023 Printed on 18/05/2023 Page n. 7/14 Replaced revision:- Avoid overheating. Avoid bunching of electrostatic charges. Avoid all sources of ignition. Avoid transferring into containers that may have been contaminated with other substances. Avoid storing close to inflammable or combustible products. 10.5. Incompatible materials Strong reducing or oxidising agents, strong acids or alkalis, hot material. 10.6. Hazardous decomposition products Thermal decomposition can lead to the formation of explosive peroxides or other potentially hazardous substances. 11. Toxicological information 11.1. Information on toxicological effects Metabolism, toxicokinetics, mechanism of action and other information Information not available Information on likely routes of exposure Information not available Delayed and immediate effects as well as chronic effects from short and long-term exposure Information not available Interactive effects Information not available ACUTE TOXICITY Does not meet the classification criteria for this hazard class SKIN CORROSION / IRRITATION Does not meet the classification criteria for this hazard class AKPEROX L40S Revision nr. 0.0 Dated 18/05/2023 Printed on 18/05/2023 Page n. 8/14 Replaced revision:- SERIOUS EYE DAMAGE / IRRITATION Causes serious eye irritation RESPIRATORY OR SKIN SENSITISATION Sensitising for the skin GERM CELL MUTAGENICITY Does not meet the classification criteria for this hazard class CARCINOGENICITY Does not meet the classification criteria for this hazard class Carcinogenicity Assessment: REPRODUCTIVE TOXICITY Does not meet the classification criteria for this hazard class STOT - SINGLE EXPOSURE Does not meet the classification criteria for this hazard class STOT - REPEATED EXPOSURE Does not meet the classification criteria for this hazard class ASPIRATION HAZARD Does not meet the classification criteria for this hazard class AKPEROX L40S Revision nr. 0.0 Dated 18/05/2023 Printed on 18/05/2023 Page n. 9/14 Replaced revision:- 12. Ecological information This product is dangerous for the environment and highly toxic for aquatic organisms. In the long term, it have negative effects on aquatic environment. 12.1. Toxicity Information not available 12.2. Persistence and degradability Information not available 12.3. Bioaccumulative potential Information not available 12.4. Mobility in soil Information not available 12.5. Results of PBT and vPvB assessment On the basis of available data, the product does not contain any PBT or vPvB in percentage than 0,1%. 12.6. Other adverse effects Information not available 13. Disposal considerations 13.1. Waste treatment methods Reuse, when possible. Neat product residues should be considered special non-hazardous waste. Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations. CONTAMINATED PACKAGING Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations. 14. Transport information 14.1. UN number ADR / RID, IMDG, IATA: 3107 14.2. UN proper shipping name ADR / RID: ORGANIC PEROXIDE TYPE E, LIQUID(DIBENZOYL PEROXIDE) IMDG: ORGANIC PEROXIDE TYPE E, LIQUID(DIBENZOYL PEROXIDE) IATA: ORGANIC PEROXIDE TYPE E, LIQUID(DIBENZOYL PEROXIDE) 14.3. Transport hazard class(es) AKPEROX L40S Revision nr. 0.0 Dated 18/05/2023 Printed on 18/05/2023 Page n. 10/14 Replaced revision:- ADR / RID: Class: 5.2 Label: 5.2 IMDG: Class: 5.2 Label: 5.2 IATA: Class: 5.2 Label: 5.2 14.4. Packing group ADR / RID, IMDG, IATA: - 14.5. Environmental hazards ADR / RID: Environmentally Hazardous IMDG: Marine Pollutant IATA: NO For Air transport, environmentally hazardous mark is only mandatory for UN 3077 and UN 3082. 14.6. Special precautions for user ADR / RID: HIN - Kemler: -- Limited Quantities: 0,125 L Tunnel restriction code: (D) Special provision: 122, 274 IMDG: EMS: F-J, S-R Limited Quantities: 0,125 L IATA: Cargo: Maximum quantity: 25 L Packaging instructions: 570 Passengers: Maximum quantity: 10 L Packaging instructions: 570 Special provision: A20, A150, A802 14.7. Transport in bulk according to Annex II of Marpol and the IBC Code Information not relevant 15. Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture U.S. Federal Regulations Clean Air Act Section 112(b): No component(s) listed. AKPEROX L40S Revision nr. 0.0 Dated 18/05/2023 Printed on 18/05/2023 Page n. 11/14 Replaced revision:- Clean Air Act Section 602 Class I Substances: No component(s) listed. Clean Air Act Section 602 Class II Substances: No component(s) listed. Clean Water Act Priority Pollutants: No component(s) listed. Clean Water Act Toxic Pollutants: No component(s) listed. DEA List I Chemicals (Precursor Chemicals): No component(s) listed. DEA List II Chemicals (Essential Chemicals): No component(s) listed. EPA List of Lists: 313 Category Code: 94-36-0 Dibenzoyl Peroxide EPCRA 302 EHS TPQ: No component(s) listed. EPCRA 304 EHS RQ: No component(s) listed. CERCLA RQ: No component(s) listed. EPCRA 313 TRI: 94-36-0 Dibenzoyl Peroxide RCRA Code: No component(s) listed. CAA 112 (r) RMP TQ: No component(s) listed. AKPEROX L40S Revision nr. 0.0 Dated 18/05/2023 Printed on 18/05/2023 Page n. 12/14 Replaced revision:- State Regulations Massachussetts: 557-05-1 Zinc stearate 94-36-0 Dibenzoyl Peroxide Minnesota: 557-05-1 Zinc stearate 94-36-0 Dibenzoyl Peroxide New Jersey: 557-05-1 Zinc stearate 94-36-0 Dibenzoyl Peroxide New York: No component(s) listed. Pennsylvania: 557-05-1 Zinc stearate 94-36-0 Dibenzoyl Peroxide California: 94-36-0 Dibenzoyl Peroxide Proposition 65: This product does not contain any substances know to the State of California to cause cancer, reproductive harm or birth defects. International Regulations Substances subject to exportation reporting pursuant to Regulation (EU) 649/2012: None Substances subject to the Rotterdam Convention: None Substances subject to the Stockholm Convention: None 16. Other information Text of hazard (H) indications mentioned in section 2-3 of the sheet: H241 Heating may cause a fire or explosion. AKPEROX L40S Revision nr. 0.0 Dated 18/05/2023 Printed on 18/05/2023 Page n. 13/14 Replaced revision:- H242 Heating may cause a fire. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. LEGEND: - 313 CATEGORY CODE: Emergency Planning and Community Right-to Know Act Section 313 Category Code - ADR: European Agreement concerning the carriage of Dangerous goods by Road - ATE: Acute Toxicity Estimate - CAA 112 RMP TQ: Risk Management Plan Threshold Quantity (Clean Air Act Section 112 ) - CAS: Chemical Abstract Service Number - CE50: Effective concentration (required to induce a 50% effect) - CERCLA RQ: Reportable Quantity (Comprehensive Environment Response, Compensation, and Liability Act) - CLP: Regulation (EC) 1272/2008 - DEA: Drug Enforcement Administration - EmS: Emergency Schedule - EPA: US Environmental Protection Agency - EPCRA: Emergency Planning and Community Right-to Know Act - EPCRA 302 EHS TPQ: Extremely Hazardous Substance Threshold Planning Quantity (Section 302 Category Code) - EPCRA 304 EHS RQ: Extremely Hazardous Substance Reportable Quantity (Section 304 Category Code) - EPCRA 313 TRI: Toxics Release Inventory (Section 313 Category Code) - GHS: Globally Harmonized System of classification and labeling of chemicals - IATA DGR: International Air Transport Association Dangerous Goods Regulation - IC50: Immobilization Concentration 50% - IMDG: International Maritime Code for dangerous goods - IMO: International Maritime Organization - LC50: Lethal Concentration 50% - LD50: Lethal dose 50% - OEL: Occupational Exposure Level - PEL: Predicted exposure level - RCRA Code: Resource Conservation and Recovery Act Code - REACH: Regulation (EC) 1907/2006 - REL: Recommended exposure limit - RID: Regulation concerning the international transport of dangerous goods by train - TLV: Threshold Limit Value - TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure. - TSCA: Toxic Substances Control Act - TWA: Time-weighted average exposure limit - TWA STEL: Short-term exposure limit - VOC: Volatile organic Compounds - WHMIS: Workplace Hazardous Materials Information System. GENERAL BIBLIOGRAPHY: - GHS rev. 3 - The Merck Index. 10th Edition - Handling Chemical Safety - Niosh - Registry of Toxic Effects of Chemical Substances - INRS - Fiche Toxicologique (toxicological sheet) - Patty - Industrial Hygiene and Toxicology - N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition - ECHA website - Database of SDS models for chemicals - Ministry of Health and ISS (Istituto Superiore di Sanit ) - Italy - 6 NYCRR part 597 - Cal/OSHA website - California Safe Drinking Water and Toxic Enforcement Act - EPA website - Hazard Comunication Standard (HCS 2012) - IARC website - List Of Lists EPA: Consolidated List of Chemicals Subject to EPCRA, CERCLA and Section 112 of the Clean Air Act - Massachussetts 105 CMR Department of public health 670.000: "Right to Know" - Minensota Chapter 5206 Departemnt Of Labor and Industry Hazardous Substances, Employee "Right to Know". AKPEROX L40S Revision nr. 0.0 Dated 18/05/2023 Printed on 18/05/2023 Page n. 14/14 Replaced revision:- - New Jersey Worker and Community Right to know Act N.J.S.A. - NTP. 2011. Report on Carcinogens, 12th Edition. - OSHA website - Pennsylvania, Hazardous Substance List, Chapter 323 Note for users: The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the suitability and thoroughness of provided information according to each specific use of the product. This document must not be regarded as a guarantee on any specific product property. The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health and safety laws and regulations. The producer is relieved from any liability arising from improper uses. Provide appointed staff with adequate training on how to use chemical products. CALCULATION METHODS FOR CLASSIFICATION Product classification derives from criteria established by the OSHA Hazard Communication Standard (HCS) (29 CFR 1910.1200), unless determined otherwise in Section 11 and 12. The data for evaluation of chemical-physical properties are reported in section 9.