SAFETY DATA SHEET
1. Identification
TR-309 & 307 Rubbing CompoundProduct identifier
Other means of identification
309, 307Product code
Polish.Recommended use
Workers (and your customers or users in the case of resale) should be informed of the potential
presence of respirable dust and respirable crystalline silica as well as their potential hazards.
Appropriate training in the proper use and handling of this material should be provided as required
under applicable regulations.
Recommended restrictions
Manufacturer/Importer/Supplier/Distributor information
TR Industries a Division of Granitize Products Inc.Manufacturer/Supplier
11022 Vulcan StreetAddress
South Gate, CA 90280-0893 United States
(562) 923-5438Telephone:
CHEMTREC: (800) 424-9300Emergency
CHEMTREC International: 00 1-703-527-3887
2. Hazard(s) identification
Not classified.Physical hazards
Category 1Skin corrosion/irritationHealth hazards
Category 1Serious eye damage/eye irritation
Category 1ACarcinogenicity
Category 3 respiratory tract irritationSpecific target organ toxicity, single exposure
Category 2 (Lung)Specific target organ toxicity, repeated
exposure
Not classified.OSHA defined hazards
Label elements
Signal word Danger
Hazard statement Causes severe skin burns and eye damage. May cause cancer. May cause respiratory irritation.
May cause damage to organs (Lung) through prolonged or repeated exposure.
Precautionary statement
Prevention Do not breathe dust/fume/gas/mist/vapors/spray. Wash thoroughly after handling. Wear protective
gloves/protective clothing/eye protection/face protection. Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood. Use only outdoors or in
a well-ventilated area.
Response If swallowed: Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all
contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. If
inhaled: Remove person to fresh air and keep comfortable for breathing. Immediately call a
poison center/doctor. If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise
classified (HNOC)
None known.
Supplemental information None.
TR-309 & 307 Rubbing Compound SDS US
3627 Version #: 01 Revision date: – Issue date: 03-September-2018 1 / 8
3. Composition/information on ingredients
Mixtures
7732-18-5 35 – 40Water
CAS number %Chemical name
64742-96-7 30 – 35Solvent Naphtha (petroleum),
Heavy Aliphatic
14808-60-7 15 – 20Quartz
61790-12-3 5 – 10Tall Oil, Fatty Acids
141-43-5 1 – 52-Aminoethanol
8002-09-3 1 – 5Pine Oil
All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in
percent by volume.
Composition comments
4. First-aid measures
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison
center or doctor/physician if you feel unwell.
Inhalation
Take off immediately all contaminated clothing. Rinse skin with water/shower. Call a physician or
poison control center immediately. Chemical burns must be treated by a physician.
Skin contact
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Call a physician or poison control center immediately.
Eye contact
Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If
vomiting occurs, keep head low so that stomach content doesn’t get into the lungs.
Ingestion
Burning pain and severe corrosive skin damage. Causes permanent skin damage (scarring).
Causes serious eye damage. Symptoms may include stinging, tearing, redness, swelling, and
blurred vision. Permanent eye damage including blindness could result. Ingestion may produce
burns to the lips, oral cavity, upper airway, esophagus and possibly the digestive tract. May cause
respiratory irritation. Coughing. Wheezing. Difficulty in breathing. Shortness of breath. Prolonged
exposure may cause chronic effects. Causes digestive tract burns.
Most important
symptoms/effects, acute and
delayed
Provide general supportive measures and treat symptomatically. Chemical burns: Flush with water
immediately. While flushing, remove clothes which do not adhere to affected area. Call an
ambulance. Continue flushing during transport to hospital. Keep victim under observation.
Symptoms may be delayed.
Indication of immediate
medical attention and special
treatment needed
IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice
(show the label where possible). Ensure that medical personnel are aware of the material(s)
involved, and take precautions to protect themselves.
General information
5. Fire-fighting measures
Alcohol resistant foam. Carbon dioxide (CO2).Suitable extinguishing media
Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing
media
Fire may produce irritating, corrosive and/or toxic gases.Specific hazards arising from
the chemical
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipment
and precautions for firefighters
In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do
so without risk. Cool containers exposed to heat with water spray and remove container, if no risk
is involved. Use standard firefighting procedures and consider the hazards of other involved
materials.
Fire fighting
equipment/instructions
Material will burn in a fire.General fire hazards
6. Accidental release measures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear
appropriate protective equipment and clothing during clean-up. Do not touch damaged containers
or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation.
Local authorities should be advised if significant spillages cannot be contained. For personal
protection, see section 8 of the SDS.
Personal precautions,
protective equipment and
emergency procedures
TR-309 & 307 Rubbing Compound SDS US
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Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product
recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re-use. Put material in suitable, covered, labeled
containers. For waste disposal, see section 13 of the SDS.
Methods and materials for
containment and cleaning up
Avoid discharge into drains, water courses or onto the ground.Environmental precautions
7. Handling and storage
Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Do not breathe mist or vapor. Do not get in eyes, on skin, or on clothing. Avoid
prolonged exposure. Should be handled in closed systems, if possible. Use only in well-ventilated
areas. Wear appropriate personal protective equipment. Observe good industrial hygiene
practices.
Precautions for safe handling
Store locked up. Keep away from heat and sources of ignition. Store in original tightly closed
container. Store away from incompatible materials (see Section 10 of the SDS).
Conditions for safe storage,
including any incompatibilities
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
FormValueComponents Type
PEL 6 mg/m32-Aminoethanol (CAS
141-43-5)
3 ppm
PEL 0.05 mg/m3 Respirable dust.Quartz (CAS 14808-60-7)
PEL 400 mg/m3Solvent Naphtha
(petroleum), Heavy
Aliphatic (CAS 64742-96-7)
100 ppm
US. OSHA Table Z-3 (29 CFR 1910.1000)
FormValueComponents Type
TWA 0.1 mg/m3 Respirable.Quartz (CAS 14808-60-7)
2.4 mppcf Respirable.
US. ACGIH Threshold Limit Values
FormValueComponents Type
STEL 6 ppm2-Aminoethanol (CAS
141-43-5)
TWA 3 ppm
TWA 0.025 mg/m3 Respirable fraction.Quartz (CAS 14808-60-7)
TWA 200 mg/m3 Non-aerosol.Solvent Naphtha
(petroleum), Heavy
Aliphatic (CAS 64742-96-7)
US. NIOSH: Pocket Guide to Chemical Hazards
FormValueComponents Type
STEL 15 mg/m32-Aminoethanol (CAS
141-43-5)
6 ppm
TWA 8 mg/m3
3 ppm
TWA 0.05 mg/m3 Respirable dust.Quartz (CAS 14808-60-7)
No biological exposure limits noted for the ingredient(s).Biological limit values
Occupational exposure to nuisance dust (total and respirable) and respirable crystalline silica
should be monitored and controlled. Occupational Exposure Limits are not relevant to the current
physical form of the product.
Exposure guidelines
TR-309 & 307 Rubbing Compound SDS US
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US ACGIH Threshold Limit Values: Skin designation
Solvent Naphtha (petroleum), Heavy Aliphatic (CAS
64742-96-7)
Can be absorbed through the skin.
Good general ventilation should be used. Ventilation rates should be matched to conditions. If
applicable, use process enclosures, local exhaust ventilation, or other engineering controls to
maintain airborne levels below recommended exposure limits. If exposure limits have not been
established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency
shower must be available when handling this product.
Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Wear safety glasses with side shields (or goggles) and a face shield.Eye/face protection
Skin protection
Wear appropriate chemical resistant gloves. Be aware that the liquid may penetrate the gloves.
Frequent change is advisable. Suitable gloves can be recommended by the glove supplier.
Hand protection
Skin protection
Wear chemical-resistant gloves, footwear and protective clothing appropriate for risk of exposure.
Contact glove manufacturer for specific information.
Other
If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn.
Respiratory protection
Wear appropriate thermal protective clothing, when necessary.Thermal hazards
Observe any medical surveillance requirements. Always observe good personal hygiene
measures, such as washing after handling the material and before eating, drinking, and/or
smoking. Routinely wash work clothing and protective equipment to remove contaminants.
General hygiene
considerations
9. Physical and chemical properties
Appearance
Solid.Physical state
Paste.Form
Not available.Color
Not available.Odor
Odor threshold Not available.
pH Not applicable.
Melting point/freezing pointNot available.
Initial boiling point and boiling
range
Not available.
Flash point > 140.0 F (> 60.0 C) (Estimated)
Evaporation rate Not applicable.
Not available.Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit – lower
(%)
Not available.
Flammability limit – upper
(%)
Not available.
Vapor pressure Not applicable.
Vapor density Not applicable.
Relative density Not available.
Solubility(ies)
Solubility (water) Not available.
Partition coefficient
(n-octanol/water)
Not available.
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not applicable.
Other information
Not explosive.Explosive properties
TR-309 & 307 Rubbing Compound SDS US
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Not oxidizing.Oxidizing properties
10. Stability and reactivity
The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity
Material is stable under normal conditions.Chemical stability
No dangerous reaction known under conditions of normal use.Possibility of hazardous
reactions
Contact with incompatible materials.Conditions to avoid
Strong oxidizers, strong acids, and strong bases. Amines.Incompatible materials
Thermal decomposition of this product can generate carbon monoxide and carbon dioxide.
Nitrogen oxides.
Hazardous decomposition
products
11. Toxicological information
Information on likely routes of exposure
Inhalation May cause irritation to the respiratory system.
Skin contact Causes severe skin burns.
Prolonged or repeated exposure may cause liver and kidney damage. These effects have not
been observed in humans.
Eye contact Causes serious eye damage.
Ingestion Causes digestive tract burns.
Symptoms related to the
physical, chemical and
toxicological characteristics
Burning pain and severe corrosive skin damage. Causes serious eye damage. Symptoms may
include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including
blindness could result. May cause respiratory irritation. Coughing. Discomfort in the chest.
Shortness of breath. Causes digestive tract burns. Prolonged exposure may cause chronic
effects.
Information on toxicological effects
Acute toxicity Not expected to be acutely toxic.
Test ResultsComponents Species
Quartz (CAS 14808-60-7)
Inhalation
Chronic
LOEC Human 0.0563 mg/m3
Causes severe skin burns and eye damage.Skin corrosion/irritation
Causes serious eye damage.Serious eye damage/eye
irritation
Respiratory or skin sensitization
Respiratory sensitizationNot a respiratory sensitizer.
This product is not expected to cause skin sensitization.Skin sensitization
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Germ cell mutagenicity
Carcinogenicity May cause cancer.
IARC Monographs. Overall Evaluation of Carcinogenicity
Quartz (CAS 14808-60-7) 1 Carcinogenic to humans.
NTP Report on Carcinogens
Quartz (CAS 14808-60-7) Known To Be Human Carcinogen.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Quartz (CAS 14808-60-7) Cancer
This product is not expected to cause reproductive or developmental effects.Reproductive toxicity
Specific target organ toxicity –
single exposure
May cause respiratory irritation.
Specific target organ toxicity –
repeated exposure
May cause damage to organs (Lung) through prolonged or repeated exposure.
Aspiration hazard Due to the physical form of the product it is not expected to be an aspiration hazard.
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Chronic effects May cause damage to organs through prolonged or repeated exposure. May be harmful if
absorbed through skin. Prolonged exposure may cause chronic effects.
Prolonged or repeated exposure may cause liver and kidney damage. These effects have not
been observed in humans.
Further information Symptoms may be delayed. May be absorbed through the skin.
12. Ecological information
The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Ecotoxicity
No data is available on the degradability of any ingredients in the mixture. Persistence and degradability
Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)
2-Aminoethanol (CAS 141-43-5) -1.31
No data available for this product.Mobility in soil
Other adverse effects Substantial amounts of the product may lead to a local change in acidity in small water systems
which may have adverse effects on aquatic organisms.
13. Disposal considerations
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Incinerate the
material under controlled conditions in an approved incinerator. Dispose of contents/container in
accordance with local/regional/national/international regulations.
Disposal instructions
Dispose in accordance with all applicable regulations.Local disposal regulations
D002: Waste Corrosive material [pH <=2 or =>12.5, or corrosive to steel]
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Hazardous waste code
Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Waste from residues / unused
products
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.
Contaminated packaging
14. Transport information
DOT
UN2491UN number
Ethanolamine solutionsUN proper shipping name
8Class
Transport hazard class(es)
-Subsidiary risk
8Label(s)
IIIPacking group
NoMarine pollutant
Environmental hazards
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
IB3, T4, TP1Special provisions
154Packaging exceptions
203Packaging non bulk
241Packaging bulk
IATA
UN2491UN number
Ethanolamine solutionUN proper shipping name
8Class
Transport hazard class(es)
-Subsidiary risk
8Label(s)
IIIPacking group
NoEnvironmental hazards
8LERG Code
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
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IMDG
UN2491UN number
ETHANOLAMINE SOLUTIONUN proper shipping name
8Class
Transport hazard class(es)
-Subsidiary risk
IIIPacking group
NoMarine pollutant
Environmental hazards
F-A, S-BEmS
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
Not applicable.Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
15. Regulatory information
This product is a “Hazardous Chemical” as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Quartz (CAS 14808-60-7) Cancer
lung effects
immune system effects
kidney effects
SARA 302 Extremely hazardous substance
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Not listed.
YesSARA 311/312 Hazardous
chemical
Skin corrosion or irritation
Serious eye damage or eye irritation
Carcinogenicity
Specific target organ toxicity (single or repeated exposure)
Classified hazard
categories
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Not regulated.Safe Drinking Water Act
(SDWA)
US state regulations
US. Massachusetts RTK – Substance List
2-Aminoethanol (CAS 141-43-5)
Quartz (CAS 14808-60-7)
US. New Jersey Worker and Community Right-to-Know Act
2-Aminoethanol (CAS 141-43-5)
Pine Oil (CAS 8002-09-3)
Quartz (CAS 14808-60-7)
Solvent Naphtha (petroleum), Heavy Aliphatic (CAS 64742-96-7)
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US. Pennsylvania Worker and Community Right-to-Know Law
2-Aminoethanol (CAS 141-43-5)
Quartz (CAS 14808-60-7)
US. Rhode Island RTK
2-Aminoethanol (CAS 141-43-5)
Quartz (CAS 14808-60-7)
California Proposition 65
This product can expose you to Quartz, which is known to the State of California to cause cancer.
For more information go to www.P65Warnings.ca.gov.
WARNING:
California Proposition 65 – CRT: Listed date/Carcinogenic substance
Quartz (CAS 14808-60-7) Listed: October 1, 1988
US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3,
subd. (a))
Quartz (CAS 14808-60-7)
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australian Inventory of Chemical Substances (AICS) YesAustralia
Domestic Substances List (DSL) YesCanada
Non-Domestic Substances List (NDSL) NoCanada
Inventory of Existing Chemical Substances in China (IECSC) YesChina
European Inventory of Existing Commercial Chemical
Substances (EINECS)
NoEurope
European List of Notified Chemical Substances (ELINCS) NoEurope
Inventory of Existing and New Chemical Substances (ENCS) NoJapan
Existing Chemicals List (ECL) YesKorea
New Zealand Inventory YesNew Zealand
Philippine Inventory of Chemicals and Chemical Substances
(PICCS)
YesPhilippines
Taiwan Chemical Substance Inventory (TCSI) YesTaiwan
*A “Yes” indicates this product complies with the inventory requirements administered by the governing country(s).
A “No” indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico
16. Other information, including date of preparation or last revision
03-September-2018Issue date
-Revision date
Version # 01
NFPA ratings
03
1
List of abbreviations PEL: Permissible Exposure Limit.
STEL: Short-Term Exposure Limit.
TWA: Time Weighted Average Value.
TR Industries cannot anticipate all conditions under which this information and its product, or the
products of other manufacturers in combination with its product, may be used. It is the user s
responsibility to ensure safe conditions for handling, storage and disposal of the product, and to
assume liability for loss, injury, damage or expense due to improper use. The information in the
sheet was written based on the best knowledge and experience currently available.
Disclaimer
TR-309 & 307 Rubbing Compound SDS US
3627 Version #: 01 Revision date: – Issue date: 03-September-2018 8 / 8