CR4062G_SDS.pdf

INDEX

CR4062
CR4062CG
CR4062CP
CR4062CQ
CR4062G
CR4062P
CR4062Q

CLEARMARINEGEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue:10/13/2014 Revision date: Supersedes:
10/13/2014 EN(English US) Page 1
SECTION 1:Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product form :Mixture liquidresin
Trade name :ClearMarineGelCoat
CAS No :Mixture
Product code :CR4062CP, CR4062CQ, CR4062CG
Formula :NA
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :PRODUCTION GEL COAT
1.3. Details of the supplier of the safety data sheet
Composite Resources is supplied by Revchem Composites. 2720 South Willow Ave., Bloomington, CA 923161-800-281-4975
1.4. Emergency telephone number
Emergency number :800.424.9300
CHEMTREC: 1-800-424-9300
SECTION 2:Hazards identification
2.1. Classification of the substance or mixture
Classification (GHS-US)
Flam. Liq. 3 H226
Skin Irrit. 2 H315
Eye Irrit. 2A H319
Carc. Not classified
2.2. Label elements
GHS-US labeling
Hazard pictograms (GHS-US) :
GHS02 GHS07
Signal word (GHS-US) :Warning
Hazard statements (GHS-US) :H226-Flammable liquid and vapor
H315-Causes skin irritation
H319-Causes serious eye irritation
Precautionary statements (GHS-US) :P210-Keep away from heat, hot surfaces, open flames, sparks.-No smoking
P233-Keep container tightly closed
P240-Ground/bond container and receiving equipment
P241-Useexplosion-proof electrical, lighting, ventilating equipment
P242-Use only non-sparking tools
P243-Take precautionary measures against static discharge
P264-Wash EXPOSED AREA. thoroughly after handling
P280-Wear eye protection, protective clothing,protective gloves
P302+P352-IF ON SKIN: Wash with plenty of soap and water
P303+P361+P353-IF ON SKIN (or hair): Remove/Take off immediately all contaminated
clothing. Rinse skin with water/shower
P305+P351+P338-If in eyes: Rinse cautiously with waterfor several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P321-Specific treatment (see SEEK MEDICAL AID. on this label)
P332+P313-If skin irritation occurs: Get medical advice/attention
P337+P313-If eye irritation persists: Get medical advice/attention
P362-Take off contaminated clothing and wash before reuse
P370+P378-In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish
P403+P235-Store in a well-ventilated place. Keep cool
P501-Dispose of contents/container to LOCAL, STATE, AND NATIONAL REGULATIONS.

CLEARMARINEGEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/13/2014 EN(English US) 2/9
2.3. Other hazards
No additional information available
2.4. Unknown acute toxicity (GHS-US)
No data available
SECTION 3:Composition/information on ingredients
3.1. Substance
Not applicable
Full text of H-phrases: see section 16
3.2. Mixture
Name Product identifier % Classification (GHS-US)
Unsaturated Polyester Resin (CAS No)TRADE SECRET <= 55 Not classified styrene, inhibited (CAS No)100-42-5 <= 43 Flam. Liq. 3, H226 Acute Tox. 4 (Inhalation:vapour), H332 Skin Irrit. 2, H315 Eye Irrit. 2A, H319 Carc. 2, H351 cobalt(II) 2-ethylhexanoate (CAS No)136-52-7 <= 0.5 Carc. 2, H351 SECTION 4:First aid measures 4.1. Description of first aid measures First-aid measures general :Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation :Assure fresh air breathing. Allow the victim to rest. Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER/doctor/physician if you feel unwell. First-aid measures after skin contact :Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: wash throughly for five minutes. seek medical attention. Get medical advice/attention. Specific treatment (see seek medical attention. on this label). First-aid measures after eye contact :Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: SEEK IMMEDIATE MEDICAL ATTENTION. Get medical advice/attention. First-aid measures after ingestion :Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries :May cause genetic defects (avoid skin contact and inhalation.). May cause cancer (avoid skin contact and inhalation.). Symptoms/injuries after inhalation :Danger of serious damage to health by prolonged exposure through inhalation. Harmful if inhaled. Symptoms/injuries after skin contact :Causes skin irritation. Symptoms/injuries after eye contact :Causes serious eye irritation. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5:Firefighting measures 5.1. Extinguishing media suitable extinguishing media :Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media :Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Fire hazard :Highly flammable liquid and vapor. Explosion hazard :May form flammable/explosive vapor-air mixture. Reactivity :No reactivity hazard other than the effects described in sub-sections below. 5.3. Advice for firefighters Firefighting instructions :Use water spray or fog for cooling exposed containers. Exercise caution whenfighting any chemical fire. Avoid (reject) fire-fighting water to enter environment. Protection during firefighting :Do not enter fire area without proper protective equipment, including respiratory protection. CLEARMARINEGEL COAT Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 10/13/2014 EN(English US) 3/9 SECTION 6:Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures :Remove ignition sources. Use special care to avoid static electric charges. No naked lights. No smoking. 6.1.1.For non-emergency personnel Protective equipment :Gloves. Protective goggles. Protective clothing. Emergency procedures :Evacuate unnecessary personnel. 6.1.2.For emergency responders Protective equipment :Equip cleanup crew with proper protection. Emergency procedures :Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up For containment :Dam up the liquid spill. Contain released substance, pump into suitable containers. Methods for cleaning up :Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7:Handling and storage 7.1. Precautions for safe handling Additional hazards when processed :Handle empty containers with care because residual vapors are flammable. Precautions for safe handling :Wash hands and other exposed areas with mild soap and water before eat, drink or smoke and when leaving work. Provide good ventilation in process area to prevent formation of vapor. No naked lights. No smoking. Use only non-sparking tools. Use only outdoors or in a well-ventilated area. Avoid breathing DUST, FUMES, MIST, OR VAPORS. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Eliminate all ignition sources if safe to do so. Hygiene measures :Wash HANDS thoroughly after handling. 7.2. Conditions for safe storage, including any incompatibilities Technical measures :Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical, ventilating and lighting equipment. equipment. Storage conditions :Keep only in the original container in a cool, well ventilated place away from : HEAT SPARKS OR OPEN FLAMES. Keep in fireproof place. Keep container tightly closed. Incompatible products :Strong bases. strong acids. Incompatible materials :Sources of ignition. Direct sunlight. Heat sources. 7.3. Specific end use(s) No additional information available SECTION 8:Exposure controls/personal protection 8.1. Control parameters styrene, inhibited (100-42-5) USA ACGIH ACGIH TWA (ppm) 20 ppm USA ACGIH ACGIH STEL (ppm) 40 ppm 8.2. Exposure controls Appropriate engineering controls :Ensure exposure is below occupational exposure limits (where available). Personal protective equipment :Avoid all unnecessary exposure. Hand protection :Wear protective gloves. Eye protection :Chemical goggles or safety glasses. Skin and body protection :Wear suitable protective clothing. Respiratory protection :Wear approved mask. Other information :When using, do not eat, drink or smoke. CLEARMARINEGEL COAT Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 10/13/2014 EN(English US) 4/9 SECTION 9:Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state :Liquid Color :Clear Odor :Characteristic Odor threshold :No data available pH :No data available Relative evaporation rate (butyl acetate=1):No data available Melting point :No data available Freezing point :No data available Boiling point : 64 C Flash point :30-34 C Auto-ignition temperature :No data available Decomposition temperature :No data available Flammability (solid, gas) :No data available Vapor pressure :No data available Relative vapor density at 20 C :No data available Relative density : 1.1 Solubility :No data available Log Pow :No data available Log Kow :No data available Viscosity, kinematic :No data available Viscosity, dynamic :No data available Explosive properties :No data available Oxidizing properties :No data available Explosive limits :No data available 9.2. Other information No additional information available SECTION 10:Stability and reactivity 10.1.Reactivity No reactivity hazard other than theeffects described in sub-sections below. 10.2.Chemical stability Polymerization can result in formation of solid deposits, even in vapour space. Not established. Highly flammable liquid andvapor. May form flammable/explosive vapor-air mixture. 10.3.Possibility of hazardous reactions Not established. 10.4.Conditions to avoid Direct sunlight. Extremely high or low temperatures. Open flame. 10.5.Incompatible materials strong acids. Strong bases. 10.6.Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. May release flammable gases. SECTION 11:Toxicological information 11.1.Information on toxicological effects Acute toxicity :Not classified ULTRA CLEAR GEL COAT (f )mixture ATE CLP (dust, mist) 1.500 mg/l/4h styrene, inhibited (100-42-5) LD50 oral rat 5000 mg/kg (>6000 mg/kg bodyweight; Rat; Rat)

CLEARMARINEGEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/13/2014 EN(English US) 5/9
styrene, inhibited (100-42-5)
LD50 dermal rat 2820 mg/kg (>2000 mg/kg bodyweight; Rat; Rat; Experimental value)
LD50 dermal rabbit 5010 mg/kg (Rabbit)
LC50 inhalation rat (mg/l) 12 mg/l/4h (Rat)
LC50 inhalation rat (ppm) 2770 ppm/4h (Rat)
ATE CLP (oral) 5000.000 mg/kg
ATE CLP (dermal) 5010.000 mg/kg
Skin corrosion/irritation :Causes skin irritation.
Serious eye damage/irritation :Causes serious eye irritation.
Respiratory or skin sensitization :Not classified
Germ cell mutagenicity :Not classified
Carcinogenicity :Not classified.
styrene, inhibited (100-42-5)
IARC group 2B-Possibly Carcinogenic to Humans
cobalt(II) 2-ethylhexanoate (136-52-7)
IARC group 2B-Possibly Carcinogenic toHumans
Reproductive toxicity :Not classified
Based on available data, the classification criteria are not met
Specific target organ toxicity (single exposure):Not classified
Specific target organ toxicity (repeated
exposure)
:Not classified
Based on available data, the classification criteria are not met
Aspiration hazard :Not classified
Based on available data, the classification criteria are not met
Potential Adverse human health effects and
symptoms
:Harmful if inhaled.
Symptoms/injuries after inhalation :Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled.
Symptoms/injuries after skin contact :Causes skin irritation.
Symptoms/injuries after eye contact :Causes serious eye irritation.
SECTION 12:Ecological information
12.1.Toxicity
styrene, inhibited (100-42-5)
LC50 fish 1 25 mg/l (96 h; Lepomis macrochirus)
LC50 other aquatic organisms 1 10-100 mg/l (96 h)
EC50 Daphnia 1 23 mg/l (48 h; Daphnia magna; LOCOMOTOR EFFECT)
LC50 fish 2 32 mg/l (96 h; Pimephales promelas)
EC50 Daphnia 2 27 mg/l (24 h; Daphnia magna)
TLM fish 1 25.1 mg/l (96 h; Lepomis macrochirus; SOFT WATER)
TLM fish 2 46.4 mg/l (96 h; Pimephales promelas; SOFT WATER)
TLM other aquatic organisms 1 10-100,96 h
Threshold limit other aquatic organisms 110-100,96 h; Pseudomonas putida
Threshold limit other aquatic organisms 272 mg/l
Threshold limit algae 1 > 200 mg/l (192 h; Scenedesmus quadricauda; INHIBITORY)
Threshold limit algae 2 67 mg/l (Microcystis aeruginosa; INHIBITORY)
12.2.Persistence and degradability
ULTRA CLEAR GEL COAT (mixture)
Persistence and degradability Not established.
styrene, inhibited (100-42-5)
Persistence and degradability Readily biodegradable in water. Not readily biodegradable in water. Forming sediments in
water. Non degradable in the soil. Adsorbs into the soil. Photodegradation in the air. Not
established.

CLEARMARINEGEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/13/2014 EN(English US) 6/9
styrene, inhibited (100-42-5)
Chemical oxygen demand (COD) 2.80 g O /g substance
ThOD 3.07 g O /g substance
BOD (% of ThOD) 0.42 % ThOD
cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability Biodegradability in water: no data available.
Unsaturated Polyester Resin (TRADE SECRET)
Persistence and degradability Not established.
12.3.Bioaccumulative potential
ULTRA CLEAR GEL COAT(mixture)
Bioaccumulative potential Not established.
styrene, inhibited (100-42-5)
BCF fish 1 12-77 (QSAR)
BCF fish 2 35.5 (Carassius auratus)
Log Pow 2.95-3.16 (Experimental value)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Not established. cobalt(II) 2-ethylhexanoate (136-52-7) Bioaccumulative potential No bioaccumulation data available. Unsaturated Polyester Resin (TRADE SECRET) Bioaccumulative potential Not established. 12.4.Mobility in soil styrene, inhibited (100-42-5) Surface tension 0.032 N/m (19 C) 12.5.Other adverse effects Other information :Avoid release to the environment. SECTION 13:Disposal considerations 13.1.Waste treatment methods Waste disposal recommendations :Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to approved disposal site. Additional information :Handle empty containers with care because residual vapors are flammable. Ecology-waste materials :Avoid release to the environment. SECTION 14:Transport information In accordance with DOT UN-No.(DOT) :UN1866 DOT Proper Shipping Name :RESIN SOLUTION Department of Transportation (DOT) Hazard Classes :3-Class 3-Flammable and combustible liquid49 CFR 173.120 Hazard labels (DOT) :3-Flammable liquid Packing group (DOT) :III-Minor Danger Additional information Other information :No supplementary information available. ADR Transport document description :UN 1866, 3, III, (D/E) CLEARMARINEGEL COAT Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 10/13/2014 EN(English US) 7/9 Packing group (ADR) :III Class (ADR) :3-Flammable liquid Hazard identification number (Kemler No.):33 Classification code (ADR) :F1 Danger labels (ADR) :3-Flammable liquids Orange plates : Tunnel restriction code :D/E LQ :5L Exceptedquantities (ADR) :E2 Transport by sea UN-No. (IMDG) :1866 Proper Shipping Name (IMDG) :RESIN SOLUTION Class (IMDG) :3-Flammable liquids Packing group (IMDG) :III-substances presenting low danger Air transport UN-No.(IATA) :1866 Proper Shipping Name (IATA) :RESIN SOLUTION Class (IATA) :3-Flammable Liquids Packing group (IATA) :III-Minor Danger SECTION 15:Regulatory information 15.1. US Federal regulations styrene, inhibited (100-42-5) RQ (Reportable quantity, section 304 of EPA's List of Lists) : 1000 lb SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Reactive hazard Fire hazard Delayed (chronic) health hazard 15.2. International regulations CANADA No additional information available EU-Regulations No additional information available Classification according to Regulation (EC) No. 1272/2008 [CLP] Flam. Liq. 2 H225 Acute Tox. 4 (Inhalation:dust,mist)H332 Skin Irrit. 2 H315 Eye Irrit. 2 H319 Muta. 1B H340 Carc. 1B H350 Full textof H-phrases: see section 16 CLEARMARINEGEL COAT Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 10/13/2014 EN(English US) 8/9 Classification according to Directive 67/548/EEC or 1999/45/EC Carc.Cat.2; R45 Muta.Cat.2; R46 F; R11 Xn; R20 Xi; R36/38 Full text of R-phrases: see section 16 15.2.2.National regulations styrene, inhibited (100-42-5) Listed on EPA's Hazardous Air Pollutants (HAPS) 15.3. US State regulations styrene, inhibited (100-42-5) U.S.-California- Proposition 65- Carcinogens List U.S.-California- Proposition 65- Developmental Toxicity U.S.-California- Proposition65- Reproductive Toxicity- Female U.S.-California- Proposition 65- Reproductive Toxicity-Male No significance risk level (NSRL) styrene, inhibited (100-42-5) U.S.-Massachusetts-Right To Know List U.S.-New Jersey-Right to Know Hazardous Substance List U.S.-Pennsylvania-RTK (Right to Know)-Environmental Hazard List SECTION 16:Other information Data sources :REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification,labeling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. Other information :None. Full text of H-phrases: see section 16: ------Acute Tox. 4 (Inhalation:vapour) Acute toxicity (inhalation:vapour) Category 4 ------Carc. 2 Carcinogenicity Category 2 ------Carc. Not classified Carcinogenicity Not classified ------Eye Irrit. 2A Serious eye damage/eye irritation Category 2A ------Flam. Liq. 3 Flammableliquids Category 3 ------Skin Irrit. 2 Skin corrosion/irritation Category 2 ------H226 Flammable liquid and vapor ------H315 Causes skin irritation ------H319 Causes serious eye irritation ------H332 Harmful if inhaled ------H351 Suspected ofcausing cancer NFPA health hazard :2-Intense or continued exposure could cause temporary incapacitation or possible residual injury unless prompt medical attention is given. NFPA fire hazard :3-Liquids and solids that can be ignited under almost all ambient conditions. NFPA reactivity :2-Normally unstable and readily undergo violent decomposition but do not detonate. Also: may react violently with water or may form potentially explosive mixtures with water. CLEARMARINEGEL COAT Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 10/13/2014 EN(English US) 9/9 HMIS III Rating Health :2Moderate Hazard-Temporary or minor injury may occur Flammability :3 Serious Hazard Physical :1 Slight Hazard Personal Protection :H SDS US (GHS HazCom 2012) To the best of our knowledge this SDS is accurate. The the extent allowed by law, thisstatement is made in lieu of an other warranties, expressed or implied including but not limited to any implied warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.