M A T E R I A L S A F E T Y D A T A S H E E T
PRODUCT NAME: Clear Laminating Resin HARDENER HMIS CODES: H F R P
PRODUCT CODE: CR-8050SBG 2 1 1 H
D.O.T. PROPER SHIPPING NAME:UN2735,AMINES,LIQUID,CORROSIVE,N.O.S,8,PGII(MIXTURE AMINES)
================== SECTION I – MANUFACTURER IDENTIFICATION =================
MANUFACTURER’S NAME: Composites Resource
ADDRESS : 2720 SOUTH WILLOW AVE.
BLOOMINGTON, CA 92316
EMERGENCY PHONE : 800-424-9300 DATE PRINTED : 03/21/2014
INFORMATION PHONE : 909-877-8477 NAME OF PREPARER : SYED MAKKI
========== SECTION II – HAZARDOUS INGREDIENTS/SARA III INFORMATION =========
VAPOR PRESSURE WEIGHT
REPORTABLE COMPONENTS CAS NUMBER mm Hg @ TEMP PERCENT
———————————————————————————————
1,3 Cyclohexane Di Methane Amine 2579-20-6 <0.5 77 F 18-28
Isophrone di amine (IPD) 2855-13-2 <2.0 77 F 20-38
Cycloaliphatic Amine Mixture amines <3.0 77 F <15.0
Benzyl Alcohol 100-51-6 <2.0 77 F 10-30
Benzoic acid 2 hydroxy (salicylic acid) 69-72-7 <2.0 77 F <10.0
=============== SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS ============
BOILING RANGE: 400 F SPECIFIC GRAVITY (H2O=1): 1.018
VAPOR DENSITY: HEAVIER THAN AIR EVAPORATION RATE: SLOWER THAN ETHER
COATING VOC: 0.00 lb/gl
MATERIAL V.O.C.: 0.00 lb/gl
NO DATA
SOLUBILITY IN WATER: negligible
APPEARANCE AND ODOR: EPOXY HARDENER .
================= SECTION IV - FIRE AND EXPLOSION HAZARD DATA ==============
FLASH POINT: >200 F METHOD USED: PMCC
FLAMMABLE LIMITS IN AIR BY VOLUME- LOWER: n/a UPPER: n/a
EXTINGUISHING MEDIA: FOAM, CO2, DRY CHEMICAL, WATER FOG
SPECIAL FIREFIGHTING PROCEDURES
Wear full protective equipment including SELF-CONTAINED BREATHING APPARATUS. If
water is used, fog nozzles are preferable. Water may be used to cool containers
to prevent pressure build-up or auto ignition. Water spray may be ineffective.
WARNING: Burning liquid chemicals are usually lighter than water and will float
spreading flames as the water flows from the site of the fire fighting efforts.
WARNING!: Stay away from hot drums due to explosion hazard.
UNUSUAL FIRE AND EXPLOSION HAZARDS
At high temperatures this material may self polymerize. If polymerization
occurs, there is the possibility of violent rupture of sealed containers. Keep
storage containers tightly closed and isolated from heat, electrical equipment,
M A T E R I A L S A F E T Y D A T A S H E E T
sparks and flames.
======================== SECTION V – REACTIVITY DATA =======================
STABILITY: STABLE
CONDITIONS TO AVOID
AVOID HEAT, Sparks or open flames.
INCOMPATIBILITY (MATERIALS TO AVOID)
Avoid contact with strong acids, oxidizers (bleaches), and strong bases (caustic
soda).
HAZARDOUS DECOMPOSITION OR BYPRODUCTS
If ignited this product will release carbon dioxide, carbon monoxide, and some
organic acids. Do not breath fumes.
HAZARDOUS POLYMERIZATION: MAY OCCUR
==================== SECTION VI – HEALTH HAZARD DATA =======================
INHALATION HEALTH RISKS AND SYMPTOMS OF OVEREXPOSURE
The excessive inhalation of vapors may cause nasal and respiratory irritation,
dizziness, weakness, fatigue, nausea, and headaches. The symptoms of inhalation
exposure are very similar to common complaints caused by colds and other minor
medical problems and must be monitored scrupulously to detect the appearance of
overexposure.
NO DATA
SKIN AND EYE CONTACT HEALTH RISKS AND SYMPTOMS OF OVEREXPOSURE
EYE CONTACT: This material can be irritating to the eyes. The symptoms of this
are tearing, redness, and discomfort. SKIN CONTACT: This material may cause
severe skin irritation. Symptoms include redness, burning drying and cracking.
SKIN ABSORPTION HEALTH RISKS AND SYMPTOMS OF OVEREXPOSURE
Exposure by skin contact can cause severe skin irritation. Prolonged or
repeated exposure may induce redness, burning, and cracking of the skin. Skin
absorption is possible but no adverse effects are expected from this route of
exposure under normal conditions of handling and use.
INGESTION HEALTH RISKS AND SYMPTOMS OF OVEREXPOSURE
Swallowing can cause gastrointestinal irritation, nausea, vomiting and
diarrhea. Aspiration of the liquid material can cause pneumonitis which can be
FATAL. Care should be taken that such aspiration DOES NOT OCCUR SHOULD THE
VICTIM VOMIT.
HEALTH HAZARDS (ACUTE AND CHRONIC)
Repeated skin contact may cause a persistent irritation or dermatitis. Repeated
inhalation may cause lung damage. Overexposure to vapor or mist may aggravate
existing respiratory conditions such as ashma, bronchitis, and inflammatory or
fibrotic respiratory disease. This material has not been tested as a whole for
health effects. WARNING! Although all intentional PROP 65 chemicals will be
listed, THERE MAY BE DETECTABLE LEVELS OF UNINTENTIONAL CHEMICALS WHICH ARE
KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS, OR OTHER
REPRODUCTIVE HARM PRESENT IN THIS PRODUCT.
TARGET ORGAN INFORMATION:
NO DATA
CARCINOGENICITY:
NTP CARCINOGEN: No IARC MONOGRAPHS: No OSHA REGULATED: No
PROPOSITION 65: YES
THIS MATERIAL CONTAINS OSHA REGULATED HAZARDOUS MATERIALS.
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
Respiratory problems such as asthma; Skin disorders such as dermatitis; eye
disorders or overly sensitive eyes.
EMERGENCY AND FIRST AID PROCEDURES
FOR ANY OVEREXPOSURE MOVE VICTIM TO FRESH AIR AND SEEK MEDICAL AID. EYE CONTACT:
Immediately flush eyes with warm clean water. If symptoms persists seek medical
attention. SKIN CONTACT: Immediately flush contaminated skin with water using
mild soap if necessary. Remove all contaminated clothing and do not reuse
clothes until thoroughly clean. INHALATION OVEREXPOSURE: Where breathing has
stopped give artificial respiration. If breathing is difficult have qualified
persons give medical oxygen. INGESTION: Give victim water to dilute chemical.
M A T E R I A L S A F E T Y D A T A S H E E T
NEVER induce vomiting in an unconscious or convulsing victim. aspiration of
this material may occur during vomiting and can lead to lung damage or death.
Seek immediate medical help
=========== SECTION VII – PRECAUTIONS FOR SAFE HANDLING AND USE ============
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Evacuate personnel, remove sources of ignition, provide ventilation, equip
cleanup crew with safety equipment, contain the spill with dikes, then use an
absorbent or vacuum equipment to remove material. Store waste in a sealed
container. Use only nonsparking tools during clean up. Do not allow this
material to flow into the environment. If the spill exceeds the reportable
quantity notify EPA and DOT officials.
WASTE DISPOSAL METHOD
Dispose of in accordance with Local, State and Federal regulations. Closed
containers may explode if incinerated and all wastes should be incinerated in
approved facilities only. In it’s uncatalyzed liquid state this material is a
hazardous waste due to it’s flammability and should not be released into the
environment. The preferred waste management option is to send material that has
been declared waste to a licensed or permitted recycler, reclaimer, or
incinerator. Use proper waste manifests and permitted haulers for transportation
of and material which has been declared a waste. Waste disposal and
characterization are the responsibility of the waste generator.
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING
Do not store above 120 deg. F. Store large quantities in buildings designed to
comply with Osha, EPA, and local fire department regulations. KEEP AWAY FROM
HEAT, SPARKS AND FLAMES. Keep containers closed and upright when not in use to
prevent the escape of fumes and liquid into the work or storage area.
Inspect containers frequently to detect any possible damage or deterioration
which might cause release of the material to the environment.
Polymerization of this coating during storage may cause the container to burst
explosively. STORE IN COOL DRY AREA.
OTHER PRECAUTIONS
Empty containers retain all of the hazardous
characteristics of the material itself and should be handled carefully until
they are thoroughly clean or destroyed. Large quantities of this material
should be stored only in buildings which conform to OSHA standards. If any
materials (such as catalysts, colorants, or thinners)_ are added to this product
read all relevant MSDS as the mixture will retain ALL of the hazardous
characteristics of the chemicals added.
===================== SECTION VIII – CONTROL MEASURES ======================
RESPIRATORY PROTECTION
During the application of this product or at any time vapors escape into the
work space, exposed persons should use appropriate cartridge respirators
(NIOSH/MSHA approved) or in instances of high concentrations, air provided
breathing apparatus. Refer to OSHA regulations to maintain workspace safety. If
respirators are required, employees must be trained to use the respirators, the
fit of the respirator must be tested, and the employee’s lung capacity must be
tested for ability to use the respirator. If Respirators are required they must
be carefully selected according to the conditions present at customers location.
VENTILATION
Clean air dilution and local exhaust may be used to maintain the vapor
concentration below current exposure limits and 20% below the LEL, except in
confined areas where forced ventilation may be necessary. Refer to OSHA
guidelines for handling these types of materials.
PROTECTIVE GLOVES
M A T E R I A L S A F E T Y D A T A S H E E T
Solvent impermeable gloves should be worn to prevent physical contact with the
product.
EYE PROTECTION
To protect your eyes, wear safety glasses with side shields, chemical goggles,
or face shields.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT
Solvent impermeable, protective clothing should be worn to minimize skin contact
with this product. Emergency showers and eye wash stations should be provided in
the work space. Wear steel toed shoes when handling heavy objects.
WORK/HYGIENIC PRACTICES
Inspect Fire extinguishers at regular intervals. Keep work space clean. Retain
safety features on all equipment.
================ SECTION IX – OTHER REGULATORY INFORMATION ================
WHMIS INFO.: MODERATE EYE/SKIN IRRIT.
========================= SECTION X – DISCLAIMER ==========================
To the best of our knowledge this MSDS is accurate. To the extent allowed by
law, this statement is made in lieu of any other warranties, expressed or
implied including but not limited to any implied warranty of merchantability or
fitness for a particular purpose and is in lieu of any other obligations or
liability on the part of Composites Resource.