ACE-262-SDS.pdf

by | Sep 27, 2025

SAFETY DATA SHEET
Last Revised: 22OCT19

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: ……………………………………… PRO-SET

ACE-262 Hardener
APPLICABLE PRODUCT CODES: ………………. ACE-262, ACE-262-1, ACE-262-2, ACE-262-4, ACE-262-G
CHEMICAL FAMILY: ………………………………….. Polyamine mixture.
INTENDED PRODUCT USES: ……………………… Curing agent for epoxy resins.
PRODUCT RESTRICTIONS: ……………………….. None identified.
SDS VERSION: …………………………………………. ACE-262-2019a

MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS):
Gougeon Brothers, Inc. Transportation
100 Patterson Ave. CHEMTREC: ……………….. 800-424-9300 (U.S.)
Bay City, MI 48706, U.S.A. 703-527-3887 (International)
Phone: 888-377-6738 or 989-684-7286 Non-transportation
www.prosetepoxy.com Poison Hotline: …………….. 800-222-1222

2. HAZARDS IDENTIFICATION

Classification of Substance or Mixture

Acute Toxicity, Oral, Category 4
Skin corrosion/irritation, Category 1B
Skin sensitizer, Category 1
Eye damage/irritation, Category 1
Acute aquatic toxicity, Category 3
Chronic aquatic toxicity, Category 3

Label Elements

Hazard Pictogram(s):

Signal Word:
DANGER

Hazard Statements:
H302 Harmful if swallowed
H314 Causes severe skin burns and eye damage
H317 May cause an allergic skin reaction
H412 Harmful to aquatic life with long lasting effects

Precautionary Statements:
Prevention
P260 Do not breathe dust/fume/mist/gas/vapors/spray
P264 Wash hands thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P272 Contaminated work clothing should not be allowed out of the workplace
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection
Response
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse or wash skin with soap and water (or
shower).
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P310 Immediately call POISON CONTROL CENTER or doctor
P313 + P333 If skin irritation or rash occurs: Get medical attention/advice
P362 + P364 Take off contaminated clothing and wash it before reuse
Storage
P405 Store locked up.
Disposal
P501 Dispose of contents and container according to local, state, national and International regulations

Other Hazards
None known.

PRO-SET

ACE-262 Hardener
Page 2 of 6 Last Revised: 22OCT19

3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS

INGREDIENT NAME CAS # CONCENTRATION (%)
Trimethylhexane-1,6-diamine 25620-58-0 10-30
Benzyl alcohol 100-51-6 10-30
1,3-cyclohexanedimethanamine 2579-20-6 10-30
Phenol, 4,4′-(1-methylethylidene) bis-, polymer with 2-(chromethyl) oxirane and
1,3-cyclohexanedimethanamine

60112-98-3

10- 30
Polymer of epichlorohydrin, bisphenol A, and trimethylhexane-1,6-diamine 111850-23-8 3-7
3,3′-(Oxybis(2,1-ethane-diyloxy))bis-1-propanamine 4246-51-9 1-5
Decanedioic acid, 1, 10-bis(1,2,2,6,6-pentamethyl-4-piperidinyl) ester 41556-26-7 0.1-1.5

The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information
(CBI). Any ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may
be present at a level below its disclosure threshold.

4. FIRST AID MEASURES

FIRST AID FOR EYES ……………………………………………………………… SYMPTOMS: Causes eye burns and eye damage. RESPONSE: Flush
immediately with water for at least 15 minutes. Remove contact lenses if present and easy to do. Immediately call a POISON CONTROL CENTER
or doctor.

FIRST AID FOR SKIN ………………………………………………………………. SYMPTOMS: Causes skin burns, redness and irritation. May cause allergic
skin reaction and sensitization. RESPONSE: Immediately wash skin with soap and water. Immediately call a POISON CONTROL CENTER or
doctor.

FIRST AID FOR INHALATION…………………………………………………… SYMPTOMS: Can cause respiratory irritation, shortness of breath or cough.
RESPONSE: Remove to fresh air if effects occur and keep comfortable for breathing. Immediately call POISON CONTROL CENTER or doctor.

FIRST AID FOR INGESTION …………………………………………………….. SYMPTOMS: May cause gastrointestinal irritation or ulceration. May
cause burns of the mouth and throat. RESPONSE: Rinse mouth with water. DO NOT induce vomiting. If vomiting should occur, keep airway
clear. Immediately call POISON CONTROL CENTER or doctor.
Notes to physician: Use of gastric lavage or emesis is contraindicated. Possible perforation of stomach or esophagus should be investigated. Do
not give chemical antidotes. Asphyxia from glottal edema may occur. Marked decrease in blood pressure may occur with moist rales, frothy
sputum, and high pulse pressure. Treat symptomatically.

5. FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA: ………………………………………………………… SUITABLE: Foam, carbon dioxide (CO2), dry chemical. NON-SUITABLE:
Direct water stream.

FIRE AND EXPLOSION HAZARDS: ………………………………………….. During a fire, smoke may contain the original materials in addition to
combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to: oxides
of nitrogen, carbon monoxide, carbon dioxide, volatile amines, ammonia, nitric acid, aldehydes, nitrosamines, phenolics. When mixed with
sawdust, wood chips, or other cellulosic material, spontaneous combustion can occur under certain conditions. Heat is generated as the air
oxidizes the amine. If the heat is not dissipated quickly enough, it can ignite the sawdust.

SPECIAL FIRE FIGHTING PROCEDURES: ………………………………… Use full-body protective gear and a self-contained breathing apparatus.
Use of water may generate toxic aqueous solutions. Do not allow water run-off from fighting fire to enter drains or other water courses.

6. ACCIDENTAL RELEASE MEASURES

EMERGENCY MEASURES : ……………………………………………………… Keep unnecessary and unprotected personnel from entering area. Use
appropriate safety and personal protective equipment as indicated in Section 8.

MITIGATION AND CLEAN UP PROCEDURES: …………………………… Stop leak without additional risk. Isolate area. Dike and absorb with inert
material (e.g., sand) and collect in a suitable, closed container. Do not use sawdust, wood chips or other cellulosic materials to absorb the spill, as
the possibility for spontaneous combustion exists. Warm, soapy water may be used to clean residual.

ENVIRONMENTAL PRECAUTIONS:………………………………………….. Prevent from entering into soil, ditches, sewers, waterways and
groundwater. See Section 12 for environmental impact information.

7. HANDLING AND STORAGE

STORAGE TEMPERATURE (min./max.): …………………………………… 40 F (4 C) / 90 F (32 C).

PRO-SET

ACE-262 Hardener
Page 3 of 6 Last Revised: 22OCT19
STORAGE: …………………………………………………………………………….. Store in cool, dry place away from high temperatures and moisture. Keep
container tightly closed. Store in a secure location with restricted access or store locked up.

HANDLING PRECAUTIONS: ……………………………………………………. Use with adequate ventilation. Do not breathe vapors or mists from heated
material. Avoid exposure to concentrated vapors. Avoid skin contact and eye contact. Wash hands thoroughly after handling. When mixed with
epoxy resin this product causes an exothermic reaction, which in large masses, can produce enough heat to damage or ignite surrounding
materials and emit fumes and vapors that vary widely in composition and toxicity.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

ENGINEERING CONTROLS: .. Use with adequate general ventilation and/or local ventilation to keep
exposures below established limits.

EYE PROTECTION GUIDELINES: …………………………………………….. Chemical splash-proof goggles or face shield.

SKIN PROTECTION GUIDELINES: ……………………………………………. Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, neoprene,
butyl rubber or natural rubber) and full body-covering clothing.

RESPIRATORY PROTECTION GUIDELINES: …………………………….. When ventilation cannot be made adequate enough to keep exposures
below established limits, use a NIOSH approved respirator with organic vapor, organic vapor + P100, or multi-contaminant cartridge, depending on
specific workplace conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator and cartridge based on
ingredients listed in Section 3 and specific workplace conditions. Use and select a respirator according the guidelines established in OSHA
1910.134 or other applicable respiratory protection standard.

ADDITIONAL PROTECTIVE MEASURES: ………………………………….. Use where there is immediate access to safety shower and emergency eye
wash. Wash thoroughly after use. Contact lens should not be worn when working with this material. Generally speaking, working cleanly and
following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use conditions.

OCCUPATIONAL EXPOS URE LIMITS: ……………………………………… Exposure limits may not be established for this product as a whole. For
established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.

Ingredient Name CAS# Exposure Limit Information
Trimethylhexane-1,6-diamine 25620-58-0 No data available
Benzyl alcohol 100-51-6 10 ppm (AIHA-WEEL)
1,3-cyclohexanedimethanamine 2579-20-6 No data available
Phenol, 4,4′-(1-methylethylidene) bis-,
polymer with 2-(chromethyl) oxirane and 1,3-
cyclohexanedimethanamine

60112-98-3

No data available
Polymer of epichlorohydrin, bisphenol A, and
trimethylhexane-1,6-diamine

111850-23-8

No data available
Decanedioic acid, 1, 10-bis(1,2,2,6,6-
pentamethyl-4-piperidinyl) ester

41556-26-7

1mg/m
3
CELING

9. PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL FORM: ………………………………………………………………….. Liquid.
COLOR: ………………………………………………………………………………… Clear
ODOR: …………………………………………………………………………………… Ammonia-like
ODOR THRESHOLD: ………………………………………………………………. No data available
pH …………………………………………………………………………………………. 12.28
MELTING POINT / FREEZING POINT ………………………………………… No data.
BOILING POINT (760mm/Hg): ………………………………………………….. > 400 F (204 C)
FLASH POINT: ……………………………………………………………………….. Estimated > 200

F (93 C) estimated based similar product.
AUTO IGNITION TEMPERATURE ……………………………………………… No data.
LOWER EXPLOSIVE LIMIT (LEL) ……………………………………………… No data.
UPPER EXPLOSIVE LIMIT (UEL) ……………………………………………… No data.
VAPOR PRESSURE ………………………………………………………………… No data.
SPECIFIC GRAVITY/DENSITY (water = 1)………………………………….. 0.99
BULK DENSITY………………………………………………………………………. 8.25 lbs./gal. (0.99 kg/L)
VAPOR DENSITY (air = 1) ……………………………………………………….. No data.
EVAPORATIOIN RATE (Butyl Acetate = 1) ………………………………… No data.
WATER SOLUBILITY (% BY WT.) …………………………………………….. No data.
PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ………… No data.
KINEMATIC VISCOSITY: …………………………………………………………. 108 (mm
2
/s @ 20

C)
DECOMPOSITION TEMPERATURE : …………………………………………. No data available.
% VOLATILE BY WEIGHT: ………………………………………………………. ASTM 2369-07 was used to determine the Volatile Matter Content of mixed
epoxy resin and hardener. The combined VOC content for the resin and hardener system is listed below.

VOC Content
Resin/Hardener (g/L) (lbs/gal)
ACE-166 / ACE-262 ………………………………………………………….. 11.03 0.09

10. STABILITY AND REACTIVITY

PRO-SET

ACE-262 Hardener
Page 4 of 6 Last Revised: 22OCT19

STABILITY: ……………………………………………………………………………. Product is stable at normal temperatures and pressures.

REACTIVITY/HAZARDOUS REACTIONS: ………………………………….. Product will not react by itself. A mass of more than one pound of product
mixed with an epoxy resin will cause irreversible polymerization with significant heat buildup. Strong acids, bases, amines and mercaptans can
cause polymerization.

INCOMPATIBILITIES: ……………………………………………………………… Avoid acids, oxidizing materials, halogenated organic compounds (e.g.,
methylene chloride). External heating or self-heating could result in rapid temperature increase and pressure build up. If such a condition were to
occur in a drum, the drum could expand and rupture violently.

CONDITIONS TO AVOID: ………………………………………………………… Avoid excessive heat.

DECOMPOSITION PRO DUCTS: ……………………………………………….. Very toxic fumes and gases when burned or otherwise heated to
decomposition. Decomposition products may include, but not limited to: oxides of nitrogen, volatile amines, ammonia, nitric acid, nitrosamines,
phenolics.

11. TOXICOLOGICAL INFORMATION

Ingredient Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation
Trimethylhexane-1,6-diamine 25620-58-0 910 mg/kg No data No data
Benzyl alcohol 100-51-6 1620 mg/kg No data >4.18 mg/l
4 h aerosol
1,3-cyclohexanedimethanamine 2579-20-6 700-780 mg/kg 1700 mg/kg No data
Phenol, 4,4′-(1-methylethylidene) bis-,
polymer with 2-(chromethyl) oxirane and
1,3-cyclohexanedimethanamine

60112-98-3

Refer to 1,3-cyclohexanedimethanamine for this data.
Polymer of epichlorohydrin, bisphenol A,
and trimethylhexane-1,6-diamine

111850-23-8

No data

No data

No data
Decanedioic acid, 1, 10-bis(1,2,2,6,6-
pentamethyl-4-piperidinyl) ester

41556-26-7

No data

No data

No data

ACUTE TOXICITY: …………………………………………………………… No specific toxicity data exists for this mixture. Classification is
based on acute toxicity estimation methods using ingredient data.
Oral: ……………………………………………………………………….. Category 4 – Harmful if swallowed. May result in gastrointestinal
tract irritation, pain and possible burns.
Dermal: …………………………………………………………………… Not classified. Based on available data does not meet
classification criteria.
Inhalation:………………………………………………………………… Not classified. Based on available data does not meet
classification criteria.

SKIN CORROSION / IRRITATION: …………………………………….. Category 1A – Causes severe skin burns. Effects may be
immediate.

SERIOUS EYE DAMAGE / IRRITATION: …………………………….. Category 1 – Causes serious eye damage.

RESPIRATORY SENSITIZATION : ……………………………………… Not classified. Based on available data does not meet
classification criteria.

SKIN SENSITZIATION: …………………………………………………….. Category 1 – May cause allergic skin reaction.

REPRODUCTIVE TOXICITY: …………………………………………….. Not classified. Based on available data does not meet classification criteria.

MUTAGENICITY: …………………………………………………………….. Not classified. Based on available data does not meet classification criteria.

CARCINOGENICITY: ……………………………………………………….. Not classified. Based on available data does not meet classification criteria.

SPECIFIC TARGET ORGAN TOXICIT Y (Single Exposure): ….. Not classified. Based on available data does not meet classification criteria.

SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure): Not classified. Based on available data does not meet classification criteria.

ASPIRATION HAZARD : ……………………………………………………. Not classified. Based on available data does not meet classification criteria.

OTHER HEALTH HAZARD INFORMATION : ………………………… This product is corrosive to skin and mucous membrane tissues. As a result
of this identified hazard, it is anticipated that excessive inhalation of vapors/aerosol/mist may also be corrosive to the respiratory system.

12. ECOLOGICAL INFORMATION

ACUTE AQUATIC TOXICITY : ……………………………………………. No specific test data available for the mixture. Calculated
Estimate: Aquatic Acute Category 3. Harmful to aquatic life. Avoid release to the environment.

PRO-SET

ACE-262 Hardener
Page 5 of 6 Last Revised: 22OCT19
CHRONIC AQUATIC TOXICITY : ………………………………………… No specific test data available for the mixture. Calculated
Estimate: Aquatic Chronic Category 3. Harmful to aquatic life with long lasting effects. Avoid release to the environment.

PERSISTANCE AND BIODEG RADABILITY: ……………………….. No specific test data available for the mixture.

MOBILITY IN SOIL: ………………………………………………………….. No specific test data available for the mixture.

ADDITIONAL ECOTOXICITY INFORMATION :……………………… In the liquid, uncured state, this product may be harmful to
aquatic life with long lasting effects. Prevent release to the environment, sewers and natural waters.

Ingredient CAS# Ecotoxicity Classification Information
Trimethylhexane-1,6-diamine 25620-58-0 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
Benzyl alcohol 100-51-6 Not classified
1,3-cyclohexanedimethanamine 2579-20-6 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
Phenol, 4,4′-(1-methylethylidene) bis-,
polymer with 2-(chromethyl) oxirane and 1,3-
cyclohexanedimethanamine

60112-98-3

Refer to 1,3-cyclohexanedimethanamine for this data.
Polymer of epichlorohydrin, bisphenol A, and
trimethylhexane-1,6-diamine

111850-23-8

Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
Decanedioic acid, 1, 10-bis(1,2,2,6,6-
pentamethyl-4-piperidinyl) ester

41556-26-7

Acute Aquatic Cat. 1; Chronic Aquatic Cat. 1

13. DISPOSAL CONSIDERATIONS

WASTE DISPOSAL METHOD: ………………………………………………….. Evaluation of this product using RCRA criteria shows that it is not a
hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal
methods.

Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations.

14. TRANSPORTATION INFORMATION

US DOT
UN NUMBER: …………………………………………………………………………. UN 2735
SHIPPING NAME: ……………………………………………………………………. Polyamines, liquid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. 1,3-cyclohexanedimethanamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
MARINE POLLUTANT: …………………………………………………………….. No

CANADA TDG
UN NUMBER: …………………………………………………………………………. UN 2735
SHIPPING NAME: ……………………………………………………………………. Polyamines, liquid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. 1,3-cyclohexanedimethanamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
MARINE POLLUTANT: …………………………………………………………….. No

IMDG
UN NUMBER: …………………………………………………………………………. UN 2735
SHIPPING NAME: ……………………………………………………………………. Polyamines, liquid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. 1,3-cyclohexanedimethanamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
EmS Number: ………………………………………………………………………… F-A, S-B
MARINE POLLUTANT ……………………………………………………………… No

ICAO/IATA
UN NUMBER: …………………………………………………………………………. UN 2735
SHIPPING NAME: ……………………………………………………………………. Polyamines, liquid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. 1,3-cyclohexanedimethanamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
MARINE POLLUTANT: …………………………………………………………….. No

15. REGULATORY INFORMATION

COUNTRY INVENTORY LIST STATUS
United States TSCA All ingredients are listed or otherwise compliant.
Europe EINECS (or REACH) No data available on CAS# 60112-98-3
Canada CEPA (DSL/NDSL) CAS# 60112-98-3 listed on NDSL only.
Australia AICS No data available on CAS# 60112-98-3
Japan ENCS No data available on CAS# 60112-98-3

PRO-SET

ACE-262 Hardener
Page 6 of 6 Last Revised: 22OCT19
South Korea KECI No data available on CAS# 60112-98-3
China IECSC All ingredients are listed or otherwise compliant.
Philippines PICCS No data available on CAS# 60112-98-3

US EPA TSCA Specific Requirements: …………………………………….. No data available.

Canada WHMIS Confidential Business Information (CBI): ………….. No data available.

US EPA SARA TITLE III Reporting and Notification Requirements:
Subject to Section 302 (TPQ) ……………………………………………… No data available.
Subject to Section 304 (RQ) ……………………………………………….. No data available.
Subject to Section 311 or 312 …………………………………………….. Refer to the health and physical classifications in section 2..
Subject to Section 313 ………………………………………………………. No data available.

US STATE REGULATORY INFORMATION:
The following chemicals may be specifically regulated by individual states. For details on state regulatory requirements you should contact the
appropriate state agency.

COMPONENT NAME
/CAS NUMBER STATE CODE
Benzyl alcohol
100-51-6 MA, PA, NJ
1,3-cyclohexanedimethanamine
2579-20-6 PA, NJ

16. OTHER INFORMATION

REASON FOR ISSUE:……………………………………………………………… New product.
PREPARED BY: ……………………………………………………………………… Gougeon Brothers, Inc.
SDS CONTACT: ……………………………………………………………………… safety@gougeon.com
TITLE: …………………………………………………………………………………… Health, Safety & Environmental Manager
APPROVAL DATE: …………………………………………………………………. October 22, 2019
SUPERSEDES DATE: ……………………………………………………………… N/A
SDS VERSION: ………………………………………………………………………. ACE-262-2019a

OTHER HAZARD INFORMATION AND RATING SYSTEMS:

HMIS RATING NFPA 704 CODES

HEALTH: 3
FLAMMABILITY: 1
PHYSICAL HAZARD: 0
PERSONAL PROTECTION:

Approximate HMIS and NFPA Risk Ratings Legend:
0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe

Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers,
Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or
reliance upon these data.
3 0
1

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* O D V V ) D E U L F
Not available.
Solid.
GHS product identifier
Other means of
identification
Product type
Section 1. Identification
:
:
Relevant identified uses of the substance or mixture and uses advised against
SAFETY DATA SHEET
* O D V V ) D E U L F
Product use :Glass fibres
Area of application :Professional applications.
vS0nPd0fnnndPS0o9F2tEmergency telephone
number (with hours of
operation)
Supplier/Manufacturer
e-mail address of person
responsible for this SDS
:
Product code :
Section 2. Hazards identification
Classification of the
substance or mixture
:
Signal word :No signal word.
Hazard statements :No known significant effects or critical hazards.
Precautionary statements
Prevention :Not applicable.
Response :Not applicable.
Storage :Not applicable.
Disposal :Not applicable.
GHS label elements
OSHA/HCS status :While this material is not considered hazardous by the OSHA Hazard Communication
Standard (29 CFR 1910.1200), this SDS contains valuable information critical to the
safe handling and proper use of the product. This SDS should be retained and available
for employees and other users of this product.
Hazards not otherwise
classified
:None known.
Not classified.
Date of issue/Date of revision :11/29/2022Date of previous issue :No previous validationVersion:1 1/11
United States
Not available.
L Q I R # F K H P L F D O F K H F N G H N V F K Q X U E X V F K # F K H P L F D O F K H F N G H
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Website: www. V D H U W H [.com
:
:
:

* O D V V ) D E U L F
Section 3. Composition/information on ingredients
titanium dioxide – 1 13463-67-7
Ingredient name CAS number%
Other means of
identification
:Not available.
Substance/mixture :Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Other names
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified and hence require reporting in this section.
Wash out mouth with water. If material has been swallowed and the exposed person is
conscious, give small quantities of water to drink. Do not induce vomiting unless
directed to do so by medical personnel. Get medical attention if symptoms occur.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Get medical attention if irritation
occurs.
Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Get medical attention if symptoms occur.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get
medical attention if symptoms occur.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Description of necessary first aid measures
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact :No specific data.
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Date of issue/Date of revision :11/29/2022Date of previous issue :No previous validationVersion:1 2/11
United States

* O D V V ) D E U L F
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides
No specific fire or explosion hazard.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
In case of fire, use water spray (fog), foam, dry chemical or CO .
Extinguishing media
:
:
:
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Move containers from spill area. Prevent entry into sewers, water courses, basements
or confined areas. Vacuum or sweep up material and place in a designated, labeled
waste container. Dispose of via a licensed waste disposal contractor. Note: see
Section 1 for emergency contact information and Section 13 for waste disposal.
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Put on appropriate personal
protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Move containers from spill area. Vacuum or sweep up material and place in a
designated, labeled waste container. Dispose of via a licensed waste disposal
contractor.Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in “For non-
emergency personnel”.
Section 7. Handling and storage
Protective measures Put on appropriate personal protective equipment (see Section 8).:
Precautions for safe handling
Date of issue/Date of revision :11/29/2022Date of previous issue :No previous validationVersion:1 3/11
United States

* O D V V ) D E U L F
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Store between the following temperatures: 20 to 25 C (68 to 77 F). Store in accordance
with local regulations. Store in original container protected from direct sunlight in a dry,
cool and well-ventilated area, away from incompatible materials (see Section 10) and
food and drink. Keep container tightly closed and sealed until ready for use. Containers
that have been opened must be carefully resealed and kept upright to prevent leakage.
Do not store in unlabeled containers. Use appropriate containment to avoid
environmental contamination. See Section 10 for incompatible materials before
handling or use.
:
:
titanium dioxide OSHA PEL (United States, 5/2018).
TWA: 15 mg/m 8 hours. Form: Total dust
ACGIH TLV (United States, 1/2022).
TWA: 2.5 mg/m 8 hours. Form: respirable fraction,
finescale particles
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. 4 – 8 hours (breakthrough time): Protective/insulated gloves. If applicable
Rubber gloves. Butyl gloves. Neoprene gloves./ polychloroprene gloves. Nitrile gloves.
(>=0.5 mm)
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: safety glasses with side-
shields.
Eye/face protection
:
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Good general ventilation should be sufficient to control worker exposure to airborne
contaminants.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Control parameters
Individual protection measures
Occupational exposure limits
Skin protection
Recommended: Protective hand cream
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United States

* O D V V ) D E U L F
Section 8. Exposure controls/personal protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Respiratory protection :
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.:
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point/freezing point
Relative density
Solid.
Not available.
Not available.
Characteristic.Odor
pH
According to specificationColor
Evaporation rate Not available.
Not available.
Not available.Odor threshold
:
:
:
:
:
:
:
:
Appearance
SADT Not available.:
Decomposition temperature:Not available.
Viscosity Not applicable.:
Flow time (ISO 2431) :Not available.
Density Not available.:
The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.
Flash point Not applicable.:
Boiling point, initial boiling
point, and boiling range
:Not available.
Vapor pressure
Relative vapor density Not applicable.
Not applicable.:
:
Flammability :Not available.
Lower and upper explosion
limit/flammability limit
:Not applicable.
Auto-ignition temperature Not applicable.
Not applicable.Partition coefficient: n-
octanol/water
:
:
Miscible with water :No.
Particle characteristics
Median particle size :Not available.
Other information
Solubility(ies) :Media Result
hot water Not soluble
cold water Not soluble
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United States

* O D V V ) D E U L F
Section 9. Physical and chemical properties
Physical/chemical
properties comments
:No additional information.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid No specific data.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability :
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Under normal conditions of storage and use, hazardous polymerization will not occur.
No specific data.
Section 11. Toxicological information
Acute toxicity
titanium dioxide LC50 Inhalation Dusts and mistsRat – Male,
Female
5.09 mg/l 4 hours
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Conclusion/Summary :Not available.
Mutagenicity
Conclusion/Summary :Not available.
Teratogenicity
Conclusion/Summary :Not available.
Reproductive toxicity
Conclusion/Summary :Not available.
Irritation/Corrosion
titanium dioxide Skin – Mild irritant Human – 72 hours 300
ug I
–
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Information on toxicological effects
Classification
titanium dioxide – 2B –
Product/ingredient name NTPIARCOSHA
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United States

* O D V V ) D E U L F
Section 11. Toxicological information
Information on the likely
routes of exposure
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
No known significant effects or critical hazards.General :
No known significant effects or critical hazards.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Reproductive toxicity :
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact :No specific data.
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Not available.
Not available.
Numerical measures of toxicity
Aspiration hazard
Not available.
:Routes of entry anticipated: Oral, Dermal, Inhalation, Eyes.
Potential acute health effects
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
Acute toxicity estimates
Product/ingredient name
titanium dioxide N/A N/A N/A N/A 5.09
Oral (mg/
kg)
Dermal
(mg/kg)
Inhalation
(gases)
(ppm) Inhalation
(vapors)
(mg/l) Inhalation
(dusts and
mists) (mg/
l)
Date of issue/Date of revision :11/29/2022Date of previous issue :No previous validationVersion:1 7/11
United States

* O D V V ) D E U L F
Section 11. Toxicological information
Section 12. Ecological information
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Not available.
Toxicity
titanium dioxide Acute LC50 3 mg/l Fresh water Crustaceans – Ceriodaphnia
dubia – Neonate
48 hours
Acute LC50 6.5 mg/l Fresh water Daphnia – Daphnia pulex –
Neonate
48 hours
Acute LC50 >1000000 g/l Marine waterFish – Fundulus heteroclitus96 hours
Product/ingredient name SpeciesResult Exposure
Conclusion/Summary :Not available.
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Not available.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Empty containers or liners may retain some product residues. Avoid
dispersal of spilled material and runoff and contact with soil, waterways, drains and
sewers.
:Disposal methods
Section 14. Transport information
–
–
–
–
–
Not regulated.
–
Not regulated. Not regulated.
DOT Classification IMDG IATA
UN number
UN proper
shipping name
Transport
hazard class(es)
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* O D V V ) D E U L F
Section 14. Transport information
– – -Packing group
Environmental
hazards
Special precautions for user
No. No. No.
Transport within user s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
:
Additional information
Transport in bulk according
to IMO instruments
:Not available.
Section 15. Regulatory information
U.S. Federal regulations
The following components are listed: FIBROUS GLASSMassachusetts
:
:
SARA 313
California Prop. 65
Clean Air Act Section 112
(b) Hazardous Air
Pollutants (HAPs) :Listed
Clean Air Act Section 602
Class I Substances
:Not listed
Clean Air Act Section 602
Class II Substances
:Not listed
DEA List I Chemicals
(Precursor Chemicals)
:Not listed
DEA List II Chemicals
(Essential Chemicals)
:Not listed
New York :None of the components are listed.
New Jersey :None of the components are listed.
Pennsylvania :None of the components are listed.
State regulations
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
United States inventory (TSCA 8b): Not determined.
SARA 302/304
SARA 304 RQ :Not applicable.
No products were found.
Composition/information on ingredients
Not applicable.
SARA 311/312
Classification :Not applicable.
titanium dioxide 1 CARCINOGENICITY – Category 2
Name % Classification
Composition/information on ingredients
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United States

* O D V V ) D E U L F
Section 15. Regulatory information
International regulations
WARNING: This product can expose you to Titanium dioxide, which is known to the State of California to cause
cancer. For more information go to www.P65Warnings.ca.gov.
Titanium dioxide – –
Ingredient name No significant risk levelMaximum acceptable dosage
level
Chemical Weapon Convention List Schedules I, II & III Chemicals
Montreal Protocol
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
Not listed.
Section 16. Other information
History
Date of issue/Date of
revision
Date of previous issue
:
:
11/29/2022
No previous validation
Hazardous Material Information System (U.S.A.)
0
0
0
National Fire Protection Association (U.S.A.)
Health Instability/Reactivity
Flammability
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS
ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS
Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual.
/0
0
0
Special hazards
Procedure used to derive the classification
Classification Justification
Not classified.
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United States

* O D V V ) D E U L F
Section 16. Other information
Chemical Check GmbH
Version
Prepared by
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Notice to reader
:
:
References :HCS (U.S.A.)- Hazard Communication Standard
International transport regulations
Key to abbreviations :
1
ATE = Acute Toxicity Estimate
AMP = Acceptable maximum peak above the acceptable ceiling concentration for an
8-hr shift
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. (“Marpol” = marine pollution)
N/A = Not available
UN = United Nations
Indicates information that has changed from previously issued version.
Date of issue/Date of revision :11/29/2022Date of previous issue :No previous validationVersion:1 11/11
United States

90000000042_SDS.pdf

by | Sep 27, 2025

SAFETY DATA SHEET
1. Identification
TR-309 & 307 Rubbing CompoundProduct identifier
Other means of identification
309, 307Product code
Polish.Recommended use
Workers (and your customers or users in the case of resale) should be informed of the potential
presence of respirable dust and respirable crystalline silica as well as their potential hazards.
Appropriate training in the proper use and handling of this material should be provided as required
under applicable regulations.
Recommended restrictions
Manufacturer/Importer/Supplier/Distributor information
TR Industries a Division of Granitize Products Inc.Manufacturer/Supplier
11022 Vulcan StreetAddress
South Gate, CA 90280-0893 United States
(562) 923-5438Telephone:
CHEMTREC: (800) 424-9300Emergency
CHEMTREC International: 00 1-703-527-3887
2. Hazard(s) identification
Not classified.Physical hazards
Category 1Skin corrosion/irritationHealth hazards
Category 1Serious eye damage/eye irritation
Category 1ACarcinogenicity
Category 3 respiratory tract irritationSpecific target organ toxicity, single exposure
Category 2 (Lung)Specific target organ toxicity, repeated
exposure
Not classified.OSHA defined hazards
Label elements
Signal word Danger
Hazard statement Causes severe skin burns and eye damage. May cause cancer. May cause respiratory irritation.
May cause damage to organs (Lung) through prolonged or repeated exposure.
Precautionary statement
Prevention Do not breathe dust/fume/gas/mist/vapors/spray. Wash thoroughly after handling. Wear protective
gloves/protective clothing/eye protection/face protection. Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood. Use only outdoors or in
a well-ventilated area.
Response If swallowed: Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all
contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. If
inhaled: Remove person to fresh air and keep comfortable for breathing. Immediately call a
poison center/doctor. If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise
classified (HNOC)
None known.
Supplemental information None.
TR-309 & 307 Rubbing Compound SDS US
3627 Version #: 01 Revision date: – Issue date: 03-September-2018 1 / 8

3. Composition/information on ingredients
Mixtures
7732-18-5 35 – 40Water
CAS number %Chemical name
64742-96-7 30 – 35Solvent Naphtha (petroleum),
Heavy Aliphatic
14808-60-7 15 – 20Quartz
61790-12-3 5 – 10Tall Oil, Fatty Acids
141-43-5 1 – 52-Aminoethanol
8002-09-3 1 – 5Pine Oil
All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in
percent by volume.
Composition comments
4. First-aid measures
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison
center or doctor/physician if you feel unwell.
Inhalation
Take off immediately all contaminated clothing. Rinse skin with water/shower. Call a physician or
poison control center immediately. Chemical burns must be treated by a physician.
Skin contact
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Call a physician or poison control center immediately.
Eye contact
Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If
vomiting occurs, keep head low so that stomach content doesn’t get into the lungs.
Ingestion
Burning pain and severe corrosive skin damage. Causes permanent skin damage (scarring).
Causes serious eye damage. Symptoms may include stinging, tearing, redness, swelling, and
blurred vision. Permanent eye damage including blindness could result. Ingestion may produce
burns to the lips, oral cavity, upper airway, esophagus and possibly the digestive tract. May cause
respiratory irritation. Coughing. Wheezing. Difficulty in breathing. Shortness of breath. Prolonged
exposure may cause chronic effects. Causes digestive tract burns.
Most important
symptoms/effects, acute and
delayed
Provide general supportive measures and treat symptomatically. Chemical burns: Flush with water
immediately. While flushing, remove clothes which do not adhere to affected area. Call an
ambulance. Continue flushing during transport to hospital. Keep victim under observation.
Symptoms may be delayed.
Indication of immediate
medical attention and special
treatment needed
IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice
(show the label where possible). Ensure that medical personnel are aware of the material(s)
involved, and take precautions to protect themselves.
General information
5. Fire-fighting measures
Alcohol resistant foam. Carbon dioxide (CO2).Suitable extinguishing media
Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing
media
Fire may produce irritating, corrosive and/or toxic gases.Specific hazards arising from
the chemical
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipment
and precautions for firefighters
In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do
so without risk. Cool containers exposed to heat with water spray and remove container, if no risk
is involved. Use standard firefighting procedures and consider the hazards of other involved
materials.
Fire fighting
equipment/instructions
Material will burn in a fire.General fire hazards
6. Accidental release measures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear
appropriate protective equipment and clothing during clean-up. Do not touch damaged containers
or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation.
Local authorities should be advised if significant spillages cannot be contained. For personal
protection, see section 8 of the SDS.
Personal precautions,
protective equipment and
emergency procedures
TR-309 & 307 Rubbing Compound SDS US
3627 Version #: 01 Revision date: – Issue date: 03-September-20182 / 8

Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product
recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re-use. Put material in suitable, covered, labeled
containers. For waste disposal, see section 13 of the SDS.
Methods and materials for
containment and cleaning up
Avoid discharge into drains, water courses or onto the ground.Environmental precautions
7. Handling and storage
Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Do not breathe mist or vapor. Do not get in eyes, on skin, or on clothing. Avoid
prolonged exposure. Should be handled in closed systems, if possible. Use only in well-ventilated
areas. Wear appropriate personal protective equipment. Observe good industrial hygiene
practices.
Precautions for safe handling
Store locked up. Keep away from heat and sources of ignition. Store in original tightly closed
container. Store away from incompatible materials (see Section 10 of the SDS).
Conditions for safe storage,
including any incompatibilities
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
FormValueComponents Type
PEL 6 mg/m32-Aminoethanol (CAS
141-43-5)
3 ppm
PEL 0.05 mg/m3 Respirable dust.Quartz (CAS 14808-60-7)
PEL 400 mg/m3Solvent Naphtha
(petroleum), Heavy
Aliphatic (CAS 64742-96-7)
100 ppm
US. OSHA Table Z-3 (29 CFR 1910.1000)
FormValueComponents Type
TWA 0.1 mg/m3 Respirable.Quartz (CAS 14808-60-7)
2.4 mppcf Respirable.
US. ACGIH Threshold Limit Values
FormValueComponents Type
STEL 6 ppm2-Aminoethanol (CAS
141-43-5)
TWA 3 ppm
TWA 0.025 mg/m3 Respirable fraction.Quartz (CAS 14808-60-7)
TWA 200 mg/m3 Non-aerosol.Solvent Naphtha
(petroleum), Heavy
Aliphatic (CAS 64742-96-7)
US. NIOSH: Pocket Guide to Chemical Hazards
FormValueComponents Type
STEL 15 mg/m32-Aminoethanol (CAS
141-43-5)
6 ppm
TWA 8 mg/m3
3 ppm
TWA 0.05 mg/m3 Respirable dust.Quartz (CAS 14808-60-7)
No biological exposure limits noted for the ingredient(s).Biological limit values
Occupational exposure to nuisance dust (total and respirable) and respirable crystalline silica
should be monitored and controlled. Occupational Exposure Limits are not relevant to the current
physical form of the product.
Exposure guidelines
TR-309 & 307 Rubbing Compound SDS US
3627 Version #: 01 Revision date: – Issue date: 03-September-2018 3 / 8

US ACGIH Threshold Limit Values: Skin designation
Solvent Naphtha (petroleum), Heavy Aliphatic (CAS
64742-96-7)
Can be absorbed through the skin.
Good general ventilation should be used. Ventilation rates should be matched to conditions. If
applicable, use process enclosures, local exhaust ventilation, or other engineering controls to
maintain airborne levels below recommended exposure limits. If exposure limits have not been
established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency
shower must be available when handling this product.
Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Wear safety glasses with side shields (or goggles) and a face shield.Eye/face protection
Skin protection
Wear appropriate chemical resistant gloves. Be aware that the liquid may penetrate the gloves.
Frequent change is advisable. Suitable gloves can be recommended by the glove supplier.
Hand protection
Skin protection
Wear chemical-resistant gloves, footwear and protective clothing appropriate for risk of exposure.
Contact glove manufacturer for specific information.
Other
If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn.
Respiratory protection
Wear appropriate thermal protective clothing, when necessary.Thermal hazards
Observe any medical surveillance requirements. Always observe good personal hygiene
measures, such as washing after handling the material and before eating, drinking, and/or
smoking. Routinely wash work clothing and protective equipment to remove contaminants.
General hygiene
considerations
9. Physical and chemical properties
Appearance
Solid.Physical state
Paste.Form
Not available.Color
Not available.Odor
Odor threshold Not available.
pH Not applicable.
Melting point/freezing pointNot available.
Initial boiling point and boiling
range
Not available.
Flash point > 140.0 F (> 60.0 C) (Estimated)
Evaporation rate Not applicable.
Not available.Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit – lower
(%)
Not available.
Flammability limit – upper
(%)
Not available.
Vapor pressure Not applicable.
Vapor density Not applicable.
Relative density Not available.
Solubility(ies)
Solubility (water) Not available.
Partition coefficient
(n-octanol/water)
Not available.
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not applicable.
Other information
Not explosive.Explosive properties
TR-309 & 307 Rubbing Compound SDS US
3627 Version #: 01 Revision date: – Issue date: 03-September-2018 4 / 8

Not oxidizing.Oxidizing properties
10. Stability and reactivity
The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity
Material is stable under normal conditions.Chemical stability
No dangerous reaction known under conditions of normal use.Possibility of hazardous
reactions
Contact with incompatible materials.Conditions to avoid
Strong oxidizers, strong acids, and strong bases. Amines.Incompatible materials
Thermal decomposition of this product can generate carbon monoxide and carbon dioxide.
Nitrogen oxides.
Hazardous decomposition
products
11. Toxicological information
Information on likely routes of exposure
Inhalation May cause irritation to the respiratory system.
Skin contact Causes severe skin burns.
Prolonged or repeated exposure may cause liver and kidney damage. These effects have not
been observed in humans.
Eye contact Causes serious eye damage.
Ingestion Causes digestive tract burns.
Symptoms related to the
physical, chemical and
toxicological characteristics
Burning pain and severe corrosive skin damage. Causes serious eye damage. Symptoms may
include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including
blindness could result. May cause respiratory irritation. Coughing. Discomfort in the chest.
Shortness of breath. Causes digestive tract burns. Prolonged exposure may cause chronic
effects.
Information on toxicological effects
Acute toxicity Not expected to be acutely toxic.
Test ResultsComponents Species
Quartz (CAS 14808-60-7)
Inhalation
Chronic
LOEC Human 0.0563 mg/m3
Causes severe skin burns and eye damage.Skin corrosion/irritation
Causes serious eye damage.Serious eye damage/eye
irritation
Respiratory or skin sensitization
Respiratory sensitizationNot a respiratory sensitizer.
This product is not expected to cause skin sensitization.Skin sensitization
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Germ cell mutagenicity
Carcinogenicity May cause cancer.
IARC Monographs. Overall Evaluation of Carcinogenicity
Quartz (CAS 14808-60-7) 1 Carcinogenic to humans.
NTP Report on Carcinogens
Quartz (CAS 14808-60-7) Known To Be Human Carcinogen.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Quartz (CAS 14808-60-7) Cancer
This product is not expected to cause reproductive or developmental effects.Reproductive toxicity
Specific target organ toxicity –
single exposure
May cause respiratory irritation.
Specific target organ toxicity –
repeated exposure
May cause damage to organs (Lung) through prolonged or repeated exposure.
Aspiration hazard Due to the physical form of the product it is not expected to be an aspiration hazard.
TR-309 & 307 Rubbing Compound SDS US
3627 Version #: 01 Revision date: – Issue date: 03-September-2018 5 / 8

Chronic effects May cause damage to organs through prolonged or repeated exposure. May be harmful if
absorbed through skin. Prolonged exposure may cause chronic effects.
Prolonged or repeated exposure may cause liver and kidney damage. These effects have not
been observed in humans.
Further information Symptoms may be delayed. May be absorbed through the skin.
12. Ecological information
The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Ecotoxicity
No data is available on the degradability of any ingredients in the mixture. Persistence and degradability
Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)
2-Aminoethanol (CAS 141-43-5) -1.31
No data available for this product.Mobility in soil
Other adverse effects Substantial amounts of the product may lead to a local change in acidity in small water systems
which may have adverse effects on aquatic organisms.
13. Disposal considerations
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Incinerate the
material under controlled conditions in an approved incinerator. Dispose of contents/container in
accordance with local/regional/national/international regulations.
Disposal instructions
Dispose in accordance with all applicable regulations.Local disposal regulations
D002: Waste Corrosive material [pH <=2 or =>12.5, or corrosive to steel]
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Hazardous waste code
Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Waste from residues / unused
products
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.
Contaminated packaging
14. Transport information
DOT
UN2491UN number
Ethanolamine solutionsUN proper shipping name
8Class
Transport hazard class(es)
-Subsidiary risk
8Label(s)
IIIPacking group
NoMarine pollutant
Environmental hazards
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
IB3, T4, TP1Special provisions
154Packaging exceptions
203Packaging non bulk
241Packaging bulk
IATA
UN2491UN number
Ethanolamine solutionUN proper shipping name
8Class
Transport hazard class(es)
-Subsidiary risk
8Label(s)
IIIPacking group
NoEnvironmental hazards
8LERG Code
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
TR-309 & 307 Rubbing Compound SDS US
3627 Version #: 01 Revision date: – Issue date: 03-September-2018 6 / 8

IMDG
UN2491UN number
ETHANOLAMINE SOLUTIONUN proper shipping name
8Class
Transport hazard class(es)
-Subsidiary risk
IIIPacking group
NoMarine pollutant
Environmental hazards
F-A, S-BEmS
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
Not applicable.Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
15. Regulatory information
This product is a “Hazardous Chemical” as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Quartz (CAS 14808-60-7) Cancer
lung effects
immune system effects
kidney effects
SARA 302 Extremely hazardous substance
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Not listed.
YesSARA 311/312 Hazardous
chemical
Skin corrosion or irritation
Serious eye damage or eye irritation
Carcinogenicity
Specific target organ toxicity (single or repeated exposure)
Classified hazard
categories
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Not regulated.Safe Drinking Water Act
(SDWA)
US state regulations
US. Massachusetts RTK – Substance List
2-Aminoethanol (CAS 141-43-5)
Quartz (CAS 14808-60-7)
US. New Jersey Worker and Community Right-to-Know Act
2-Aminoethanol (CAS 141-43-5)
Pine Oil (CAS 8002-09-3)
Quartz (CAS 14808-60-7)
Solvent Naphtha (petroleum), Heavy Aliphatic (CAS 64742-96-7)
TR-309 & 307 Rubbing Compound SDS US
3627 Version #: 01 Revision date: – Issue date: 03-September-2018 7 / 8

US. Pennsylvania Worker and Community Right-to-Know Law
2-Aminoethanol (CAS 141-43-5)
Quartz (CAS 14808-60-7)
US. Rhode Island RTK
2-Aminoethanol (CAS 141-43-5)
Quartz (CAS 14808-60-7)
California Proposition 65
This product can expose you to Quartz, which is known to the State of California to cause cancer.
For more information go to www.P65Warnings.ca.gov.
WARNING:
California Proposition 65 – CRT: Listed date/Carcinogenic substance
Quartz (CAS 14808-60-7) Listed: October 1, 1988
US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3,
subd. (a))
Quartz (CAS 14808-60-7)
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australian Inventory of Chemical Substances (AICS) YesAustralia
Domestic Substances List (DSL) YesCanada
Non-Domestic Substances List (NDSL) NoCanada
Inventory of Existing Chemical Substances in China (IECSC) YesChina
European Inventory of Existing Commercial Chemical
Substances (EINECS)
NoEurope
European List of Notified Chemical Substances (ELINCS) NoEurope
Inventory of Existing and New Chemical Substances (ENCS) NoJapan
Existing Chemicals List (ECL) YesKorea
New Zealand Inventory YesNew Zealand
Philippine Inventory of Chemicals and Chemical Substances
(PICCS)
YesPhilippines
Taiwan Chemical Substance Inventory (TCSI) YesTaiwan
*A “Yes” indicates this product complies with the inventory requirements administered by the governing country(s).
A “No” indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico
16. Other information, including date of preparation or last revision
03-September-2018Issue date
-Revision date
Version # 01
NFPA ratings
03
1
List of abbreviations PEL: Permissible Exposure Limit.
STEL: Short-Term Exposure Limit.
TWA: Time Weighted Average Value.
TR Industries cannot anticipate all conditions under which this information and its product, or the
products of other manufacturers in combination with its product, may be used. It is the user s
responsibility to ensure safe conditions for handling, storage and disposal of the product, and to
assume liability for loss, injury, damage or expense due to improper use. The information in the
sheet was written based on the best knowledge and experience currently available.
Disclaimer
TR-309 & 307 Rubbing Compound SDS US
3627 Version #: 01 Revision date: – Issue date: 03-September-2018 8 / 8

90000000041_SDS.pdf

by | Sep 27, 2025

SAFETY DATA SHEET

NOROX

MEKP-9H DDDD RED

Version
1.1
Revision Date:
06/14/2023
SDS Number:
600000001059
Date of last issue: 06/02/2023
Date of first issue: 06/02/2023

1 / 28
SECTION 1. IDENTIFICATION
Trade name

: NOROX

MEKP-9H DDDD RED

Manufacturer or supplier’s details
Company name of supplier

: United Initiators, Inc.

Address

: 555 Garden Street
Elyria OH 44035 USA

Telephone

: +1-440-323-3112

Telefax

: +1-440-323-2659

Emergency telephone

: CHEMTREC US (24h): +1-800-424-9300
CHEMTREC WORLD (24h): +1-703-527-3887

E-mail address of person
responsible for the SDS

: cs-initiators.nafta@united-in.com

Recommended use of the chemical and restrictions on use
Recommended use

: polymerization initiators
Curing chemical

SECTION 2. HAZARDS IDENTIFICATION
GHS classification in accordance with the OSHA Hazard Communication Standard (29 CFR
1910.1200)
Flammable liquids

: Category 4
Organic peroxides

: Type D
Acute toxicity (Oral)

: Category 4
Acute toxicity (Inhalation)

: Category 4
Skin corrosion

: Category 1B
Serious eye damage

: Category 1
Reproductive toxicity

: Category 2
Short-term (acute) aquatic
hazard

: Category 2
GHS label elements

SAFETY DATA SHEET

NOROX

MEKP-9H DDDD RED

Version
1.1
Revision Date:
06/14/2023
SDS Number:
600000001059
Date of last issue: 06/02/2023
Date of first issue: 06/02/2023

2 / 28
Hazard pictograms

:

Signal Word

: Danger

Hazard Statements

: H227 Combustible liquid.
H242 Heating may cause a fire.
H302 + H332 Harmful if swallowed or if inhaled.
H314 Causes severe skin burns and eye damage.
H361 Suspected of damaging fertility or the unborn child.
H401 Toxic to aquatic life.

Precautionary Statements

:
Prevention:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read
and understood.
P210 Keep away from heat/ sparks/ open flames/ hot surfaces.
No smoking.
P220 Keep/Store away from clothing/ strong acids, bases,
heavy metal salts and other reducing substances /combustible
materials.
P234 Keep only in original container.
P261 Avoid breathing mist or vapors.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/
face protection.
Response:
P301 + P312 + P330 IF SWALLOWED: Call a POISON
CENTER/ doctor if you feel unwell. Rinse mouth.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT
induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately
all contaminated clothing. Rinse skin with water/ shower.
P304 + P340 + P310 IF INHALED: Remove person to fresh air
and keep comfortable for breathing. Immediately call a POISON
CENTER/ doctor.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON
CENTER/ doctor.
P308 + P313 IF exposed or concerned: Get medical advice/
attention.
P363 Wash contaminated clothing before reuse.
P370 + P378 In case of fire: Use water spray, alcohol-resistant
foam, dry chemical or carbon dioxide to extinguish.

SAFETY DATA SHEET

NOROX

MEKP-9H DDDD RED

Version
1.1
Revision Date:
06/14/2023
SDS Number:
600000001059
Date of last issue: 06/02/2023
Date of first issue: 06/02/2023

3 / 28
Storage:
P405 Store locked up.
P410 Protect from sunlight.
P411 + P235 Store at temperatures not exceeding < 100 F/ < 38 C. Keep cool. P420 Store away from other materials. Disposal: P501 Dispose of contents/ container to an approved waste dis- posal plant. Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Chemical nature : Organic Peroxide Liquid mixture Components Chemical name CAS-No. Concentration (% w/w) dimethyl phthalate 131-11-3 >= 40 – < 45 2-Butanone, peroxide 1338-23-4 >= 35 – < 40 Trimethylpentanediol isobutyrate 6846-50-0 >= 15 – < 20 Butanone 78-93-3 >= 1 – < 5 Hydrogen peroxide 7722-84-1 >= 1 – < 5 2-Naphthalenol, 1-[2-[4-(2- phenyldiazenyl)phenyl]diazenyl]-, ar- heptyl ar',ar''-Me derivs. 92257-31-3 >= 0.1 – < 1 Actual concentration is withheld as a trade secret SECTION 4. FIRST AID MEASURES General advice : Take off contaminated clothing and shoes immediately. Call a physician immediately. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and seek medical advice. Move out of dangerous area. Show this material safety data sheet to the doctor in attendance. Do not leave the victim unattended. SAFETY DATA SHEET NOROX MEKP-9H DDDD RED Version 1.1 Revision Date: 06/14/2023 SDS Number: 600000001059 Date of last issue: 06/02/2023 Date of first issue: 06/02/2023 4 / 28 Symptoms of poisoning may appear several hours later. If inhaled : Administer oxygen if breathing is difficult or cyanosis is observed. Call a physician immediately. If breathed in, move person into fresh air. If not breathing, give artificial respiration. Respiratory tract burning possible if aerosols are inhaled. Call a physician or poison control center immediately. If unconscious, place in recovery position and seek medical advice. Keep respiratory tract clear. In case of skin contact : If symptoms persist, call a physician. Immediate medical treatment is necessary as untreated wounds from corrosion of the skin heal slowly and with difficulty. In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash contaminated clothing before re-use. If on skin, rinse well with water. If on clothes, remove clothes. In case of eye contact : Small amounts splashed into eyes can cause irreversible tissue damage and blindness. In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Continue rinsing eyes during transport to hospital. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. If swallowed : Call a physician immediately. Rinse mouth thoroughly with water. Keep respiratory tract clear. Do NOT induce vomiting. If symptoms persist, call a physician. Most important symptoms and effects, both acute and delayed : Harmful if swallowed or if inhaled. Causes serious eye damage. Suspected of damaging fertility or the unborn child. Causes severe burns. Protection of first-aiders : First Aid responders should pay attention to self-protection and use the recommended protective clothing Notes to physician : Treat symptomatically and supportively. SECTION 5. FIRE-FIGHTING MEASURES SAFETY DATA SHEET NOROX MEKP-9H DDDD RED Version 1.1 Revision Date: 06/14/2023 SDS Number: 600000001059 Date of last issue: 06/02/2023 Date of first issue: 06/02/2023 5 / 28 Suitable extinguishing media : Water spray jet Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical Unsuitable extinguishing media : High volume water jet Specific hazards during fire fighting : Risk of explosion if heated under confinement. Possible emission of gaseous decomposition products may lead to a dangerous pressure build-up. Avoid confinement. Contact with incompatible materials or exposure to temperatures exceeding SADT may result in a self- accelerating decomposition reaction with release of flammable vapors which may auto-ignite. The product burns violently. Flash back possible over considerable distance. Do not allow run-off from fire fighting to enter drains or water courses. Vapors may form explosive mixtures with air. The product will float on water and can be reignited on surface water. Cool closed containers exposed to fire with water spray. Specific extinguishing meth- ods : Do not use a solid water stream as it may scatter and spread fire. Remove undamaged containers from fire area if it is safe to do so. Use water spray to cool unopened containers. Further information : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use a water spray to cool fully closed containers. Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Special protective equipment for fire-fighters : Wear self-contained breathing apparatus for firefighting if necessary. Use personal protective equipment. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protec- tive equipment and emer- gency procedures : Follow safe handling advice and personal protective equipment recommendations. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas. Use personal protective equipment. SAFETY DATA SHEET NOROX MEKP-9H DDDD RED Version 1.1 Revision Date: 06/14/2023 SDS Number: 600000001059 Date of last issue: 06/02/2023 Date of first issue: 06/02/2023 6 / 28 Remove all sources of ignition. Never return spills in original containers for re-use. Treat recovered material as described in the section "Disposal considerations". Environmental precautions : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. Methods and materials for containment and cleaning up : Contact with incompatible substances can cause decomposition at or below SADT. Clear spills immediately. Suppress (knock down) gases/vapors/mists with a water spray jet. To clean the floor and all objects contaminated by this material, use plenty of water. Soak up with inert absorbent material. Isolate waste and do not reuse. Non-sparking tools should be used. Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable. SECTION 7. HANDLING AND STORAGE Technical measures : See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section. Advice on protection against fire and explosion : Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapors). Keep away from heat and sources of ignition. Use only explosion-proof equipment. Keep away from open flames, hot surfaces and sources of ignition. Keep away from combustible material. Do not spray on a naked flame or any incandescent material. Advice on safe handling : Open drum carefully as content may be under pressure. Protect from contamination. Do not swallow. Do not breathe vapors/dust. Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. Avoid formation of aerosol. Take precautionary measures against static discharges. Never return any product to the container from which it was originally removed. Provide sufficient air exchange and/or exhaust in work rooms. SAFETY DATA SHEET NOROX MEKP-9H DDDD RED Version 1.1 Revision Date: 06/14/2023 SDS Number: 600000001059 Date of last issue: 06/02/2023 Date of first issue: 06/02/2023 7 / 28 Avoid confinement. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Smoking, eating and drinking should be prohibited in the application area. Wash thoroughly after handling. For personal protection see section 8. Conditions for safe storage : Store in original container. Keep containers tightly closed in a cool, well-ventilated place. Store in cool place. Keep in a well-ventilated place. Contamination may result in dangerous pressure increases - closed containers may rupture. Observe label precautions. Store in accordance with the particular national regulations. Avoid impurities (e.g. rust, dust, ash), risk of decomposition. Electrical installations / working materials must comply with the technological safety standards. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Materials to avoid : Keep away from strong acids, bases, heavy metal salts and other reducing substances. Recommended storage tem- perature : < 100 F < 38 C Further information on stor- age stability : No decomposition if stored normally. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingredients with workplace control parameters Components CAS-No. Value type (Form of exposure) Control parame- ters / Permissible concentration Basis dimethyl phthalate 131-11-3 TWA 5 mg/m3 ACGIH TWA 5 mg/m3 NIOSH REL TWA 5 mg/m3 OSHA Z-1 TWA 5 mg/m3 OSHA P0 2-Butanone, peroxide 1338-23-4 C 0.2 ppm ACGIH C 0.2 ppm 1.5 mg/m3 NIOSH REL C 0.7 ppm 5 mg/m3 OSHA P0 Butanone 78-93-3 TWA 200 ppm ACGIH STEL 300 ppm ACGIH SAFETY DATA SHEET NOROX MEKP-9H DDDD RED Version 1.1 Revision Date: 06/14/2023 SDS Number: 600000001059 Date of last issue: 06/02/2023 Date of first issue: 06/02/2023 8 / 28 TWA 200 ppm 590 mg/m3 NIOSH REL ST 300 ppm 885 mg/m3 NIOSH REL TWA 200 ppm 590 mg/m3 OSHA Z-1 TWA 200 ppm 590 mg/m3 OSHA P0 STEL 300 ppm 885 mg/m3 OSHA P0 Hydrogen peroxide 7722-84-1 TWA 1 ppm ACGIH TWA 1 ppm 1.4 mg/m3 NIOSH REL TWA 1 ppm 1.4 mg/m3 OSHA Z-1 TWA 1 ppm 1.4 mg/m3 OSHA P0 Biological occupational exposure limits Components CAS-No. Control parameters Biological specimen Sam- pling time Permissible concentra- tion Basis Butanone 78-93-3 methyl ethyl ketone Urine End of shift (As soon as possible after exposure ceases) 2 mg/l ACGIH BEI Engineering measures : Minimize workplace exposure concentrations. Personal protective equipment Respiratory protection : In the case of dust or aerosol formation use respirator with an approved filter. Filter type : ABEK-filter Use NIOSH approved respiratory protection. Hand protection Material : butyl-rubber Break through time : <= 480 min Glove thickness : 0.5 mm Material : Nitrile rubber Break through time : < 30 min Glove thickness : 0.4 mm Remarks : The data about break through time/strength of material are SAFETY DATA SHEET NOROX MEKP-9H DDDD RED Version 1.1 Revision Date: 06/14/2023 SDS Number: 600000001059 Date of last issue: 06/02/2023 Date of first issue: 06/02/2023 9 / 28 standard values! The exact break through time/strength of material has to be obtained from the producer of the protective glove. Choose gloves to protect hands against chemicals depending on the concentration and quantity of the hazardous substance and specific to place of work. For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Wash hands before breaks and at the end of workday. Eye protection : Ensure that eyewash stations and safety showers are close to the workstation location. Please follow all applicable local/national requirements when selecting protective measures for a specific workplace. Always wear eye protection when the potential for inadvertent eye contact with the product cannot be excluded. Tightly fitting safety goggles Please wear suitable protective goggles. Also wear face protection if there is a splash hazard. Skin and body protection : Select appropriate protective clothing based on chemical resistance data and an assessment of the local exposure potential. Additional body garments should be used based upon the task being performed (e.g., sleevelets, apron, gauntlets, disposable suits) to avoid exposed skin surfaces. Wear as appropriate: Flame retardant antistatic protective clothing. Protective measures : The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Hygiene measures : Avoid contact with skin, eyes and clothing. Keep away from food and drink. When using do not eat or drink. When using do not smoke. Wash hands before breaks and immediately after handling the product. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Color : red Odor : slight SAFETY DATA SHEET NOROX MEKP-9H DDDD RED Version 1.1 Revision Date: 06/14/2023 SDS Number: 600000001059 Date of last issue: 06/02/2023 Date of first issue: 06/02/2023 10 / 28 Odor Threshold : not determined pH : Not applicable Melting point/range : No data available Boiling point/boiling range : not determined Flash point : > 76 C

Flammability (solid, gas)

: Not applicable

Upper explosion limit / Upper
flammability limit

: No data available

Lower explosion limit / Lower
flammability limit

: No data available

Vapor pressure

: No data available

Relative vapor density

: > 1

Density

: 1.1 g/cm3

Solubility(ies)
Water solubility

: slightly soluble

Partition coefficient: n-
octanol/water

: No data available

Self-Accelerating decomposi-
tion temperature (SADT)

: ca. 60 C
SADT-Self Accelerating Decomposition Temperature. Lowest
temperature at which the tested package size will undergo a
self-accelerating decomposition reaction.

Viscosity
Viscosity, dynamic

: No data available

Viscosity, kinematic

: not determined

Oxidizing properties

: The substance or mixture is not classified as oxidizing.
Organic peroxide

SECTION 10. STABILITY AND REACTIVITY
Reactivity

: Stable under recommended storage conditions.
Heating may cause a fire or explosion.

SAFETY DATA SHEET

NOROX

MEKP-9H DDDD RED

Version
1.1
Revision Date:
06/14/2023
SDS Number:
600000001059
Date of last issue: 06/02/2023
Date of first issue: 06/02/2023

11 / 28

Chemical stability

: Stable under recommended storage conditions.
No decomposition if stored normally.

Possibility of hazardous reac-
tions

: Vapors may form explosive mixture with air.

Conditions to avoid

: Protect from contamination.
Heat, flames and sparks.
Avoid confinement.

Incompatible materials

: Accelerators, strong acids and bases, heavy metals and
heavy metal salts, reducing agents

Hazardous decomposition
products
: Irritant, caustic, flammable, noxious/toxic gases and vapours
can develop in the case of fire and decomposition

SECTION 11. TOXICOLOGICAL INFORMATION
Acute toxicity
Harmful if swallowed or if inhaled.
Product:
Acute oral toxicity

: Acute toxicity estimate: 1,372 mg/kg
Method: Calculation method

Acute inhalation toxicity

: Acute toxicity estimate: 4.17 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Method: Calculation method

Acute dermal toxicity

: Acute toxicity estimate: > 5,000 mg/kg
Method: Calculation method

Components:
dimethyl phthalate:
Acute oral toxicity

: LD50 (Rat): > 5,000 mg/kg

Acute inhalation toxicity

: (Rat): > 10.4 mg/l
Exposure time: 6 h
Test atmosphere: vapor
Remarks: No mortality observed at this dose.

Acute dermal toxicity

: LD50 (Rabbit): > 12,000 mg/kg

2-Butanone, peroxide:
Acute oral toxicity

: Acute toxicity estimate: 500 mg/kg
Method: Expert judgment

SAFETY DATA SHEET

NOROX

MEKP-9H DDDD RED

Version
1.1
Revision Date:
06/14/2023
SDS Number:
600000001059
Date of last issue: 06/02/2023
Date of first issue: 06/02/2023

12 / 28

Acute inhalation toxicity

: Acute toxicity estimate: 1.5 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Method: Expert judgment
Assessment: The component/mixture is moderately toxic after
short term inhalation.
Remarks: Based on data from similar materials

Acute dermal toxicity

: Acute toxicity estimate: 2,500 mg/kg
Method: Expert judgment

Trimethylpentanediol isobutyrate:
Acute oral toxicity

: LD50 (Rat): > 2,000 mg/kg
Method: Expert judgment
Assessment: The substance or mixture has no acute oral tox-
icity

Acute inhalation toxicity

: LCLo (Rat): > 0.12 mg/l
Exposure time: 6 h
Test atmosphere: vapor
Method: Expert judgment
Assessment: The substance or mixture has no acute inhala-
tion toxicity
Remarks: No mortality observed at this dose.

Acute dermal toxicity

: LD50 (Guinea pig): > 2,000 mg/kg
Method: Expert judgment
Assessment: The substance or mixture has no acute dermal
toxicity

Butanone:
Acute oral toxicity

: LD50 (Rat): 2,193 mg/kg
Method: OECD Test Guideline 423

Acute inhalation toxicity

: Remarks: No data available

Acute dermal toxicity

: LD50 (Rabbit): > 5,000 mg/kg
Method: OECD Test Guideline 402
Remarks: Based on available data, the classification criteria
are not met.

Hydrogen peroxide:
Acute oral toxicity

: Acute toxicity estimate: 500.0 mg/kg
Method: Converted acute toxicity point estimate
Assessment: The component/mixture is moderately toxic after
single ingestion.

Acute inhalation toxicity

: LC50 (Rat): > 0.17 mg/l
Exposure time: 4 h

SAFETY DATA SHEET

NOROX

MEKP-9H DDDD RED

Version
1.1
Revision Date:
06/14/2023
SDS Number:
600000001059
Date of last issue: 06/02/2023
Date of first issue: 06/02/2023

13 / 28
Test atmosphere: dust/mist
Assessment: The component/mixture is moderately toxic after
short term inhalation.
Remarks: Based on harmonised classification in EU regulation
1272/2008, Annex VI

Acute dermal toxicity

: LD50 (Rabbit): > 6,500 mg/kg

2-Naphthalenol, 1-[2-[4-(2-phenyldiazenyl)phenyl]diazenyl]-, ar-heptyl ar’,ar”-Me derivs.:
Acute oral toxicity

: LD50 (Rat): > 5,000 mg/kg

Skin corrosion/irritation
Causes severe burns.
Product:
Remarks : Extremely corrosive and destructive to tissue.

Components:
dimethyl phthalate:
Species : Rabbit
Method : Draize Test
Result : No skin irritation

2-Butanone, peroxide:
Species : Rabbit
Result : Causes burns.

Trimethylpentanediol isobutyrate:
Species : Guinea pig
Exposure time : 24 h
Result : No skin irritation
Remarks : Based on available data, the classification criteria are not met.

Butanone:
Species : Rabbit
Assessment : Repeated exposure may cause skin dryness or cracking.
Method : OECD Test Guideline 404
Result : No skin irritation

Hydrogen peroxide:
Result : Corrosive after 3 minutes or less of exposure

Remarks : Extremely corrosive and destructive to tissue.

2-Naphthalenol, 1-[2-[4-(2-phenyldiazenyl)phenyl]diazenyl]-, ar-heptyl ar’,ar”-Me derivs.:

SAFETY DATA SHEET

NOROX

MEKP-9H DDDD RED

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1.1
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SDS Number:
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Date of last issue: 06/02/2023
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Result : No skin irritation

Serious eye damage/eye irritation
Causes serious eye damage.
Product:
Remarks : May cause irreversible eye damage.

Components:
dimethyl phthalate:
Species : Rabbit
Result : No eye irritation
Method : OECD Test Guideline 405

2-Butanone, peroxide:
Result : Irreversible effects on the eye

Trimethylpentanediol isobutyrate:
Species : Rabbit
Result : No eye irritation
Exposure time : 24 h

Butanone:
Species : Rabbit
Result : Eye irritation
Method : OECD Test Guideline 405

Hydrogen peroxide:
Result : Irreversible effects on the eye

Remarks : May cause irreversible eye damage.

Respiratory or skin sensitization
Skin sensitization
Not classified based on available information.
Respiratory sensitization
Not classified based on available information.
Components:
dimethyl phthalate:
Species : Mouse
Method : OECD Test Guideline 429
Result : Does not cause skin sensitization.

SAFETY DATA SHEET

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MEKP-9H DDDD RED

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SDS Number:
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Date of last issue: 06/02/2023
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2-Butanone, peroxide:
Species : Guinea pig
Method : OECD Test Guideline 406
Result : Does not cause skin sensitization.

Assessment : Harmful if swallowed., Harmful if inhaled.

Trimethylpentanediol isobutyrate:
Species : Guinea pig
Result : Does not cause skin sensitization.

Butanone:
Routes of exposure : Skin contact
Species : Guinea pig
Method : OECD Test Guideline 406
Result : Does not cause skin sensitization.

Germ cell mutagenicity
Not classified based on available information.
Components:
dimethyl phthalate:
Genotoxicity in vitro

: Method: OECD Test Guideline 471
Result: negative

Method: OECD Test Guideline 473
Result: negative

Method: OECD Test Guideline 476
Result: positive

Genotoxicity in vivo

: Test Type: Chromosomal aberration
Species: Rat
Application Route: Intraperitoneal
Result: negative

Test Type: Micronucleus test
Species: Mouse
Application Route: Intraperitoneal injection
Result: negative

2-Butanone, peroxide:
Genotoxicity in vitro

: Method: OECD Test Guideline 473
Result: negative

Method: OECD Test Guideline 471
Result: negative

SAFETY DATA SHEET

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MEKP-9H DDDD RED

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1.1
Revision Date:
06/14/2023
SDS Number:
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Date of last issue: 06/02/2023
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Method: OECD Test Guideline 476
Result: negative

Trimethylpentanediol isobutyrate:
Genotoxicity in vitro

: Test Type: In vitro mammalian cell gene mutation test
Method: OECD Test Guideline 476
Result: negative

Test Type: Ames test
Method: Regulation (EC) No. 440/2008, Annex, B.13/14
(Ames test)
Result: negative

Test Type: Chromosome aberration test in vitro
Method: OECD Test Guideline 473
Result: negative

Butanone:
Genotoxicity in vitro

: Method: OECD Test Guideline 471
Result: negative

Method: OECD Test Guideline 476
Result: negative

Method: OECD Test Guideline 473
Result: negative

Genotoxicity in vivo

: Species: Mouse
Application Route: Intraperitoneal
Method: OECD Test Guideline 474
Result: negative

Hydrogen peroxide:
Genotoxicity in vitro

: Test Type: Ames test
Result: negative

Genotoxicity in vivo

: Test Type: Mammalian erythrocyte micronucleus test (in vivo
cytogenetic assay)
Species: Mouse
Result: negative

Carcinogenicity
Not classified based on available information.
Components:
dimethyl phthalate:
Species : Rat
Application Route : Skin contact

SAFETY DATA SHEET

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MEKP-9H DDDD RED

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SDS Number:
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Date of last issue: 06/02/2023
Date of first issue: 06/02/2023

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Method : OECD Test Guideline 451
Result : negative
Remarks : Based on data from similar materials

2-Butanone, peroxide:
Remarks : This information is not available.

Hydrogen peroxide:
Carcinogenicity – Assess-
ment

: Carcinogenicity classification not possible from current data.

IARC No ingredient of this product present at levels greater than or equal to 0.1% is
identified as probable, possible or confirmed human carcinogen by IARC.

OSHA No component of this product present at levels greater than or equal to 0.1% is
on OSHA s list of regulated carcinogens.

NTP No ingredient of this product present at levels greater than or equal to 0.1% is
identified as a known or anticipated carcinogen by NTP.

Reproductive toxicity
Suspected of damaging fertility or the unborn child.
Components:
dimethyl phthalate:
Effects on fertility

: Species: Rat
Application Route: oral (gavage)
Method: OECD Test Guideline 440
Result: negative

Effects on fetal development

: Species: Rat
Application Route: Ingestion
General Toxicity Maternal: NOAEL: 840 mg/kg body weight
Developmental Toxicity: NOAEL: 3,570 mg/kg body weight
Method: OECD Test Guideline 414

2-Butanone, peroxide:
Effects on fertility

: Species: Rat
Application Route: oral (gavage)
General Toxicity Parent: NOAEL: 50 mg/kg body weight
Method: OECD Test Guideline 421
Result: negative

Trimethylpentanediol isobutyrate:
Effects on fetal development

: Test Type: One-generation reproduction toxicity study
Species: Rat
Application Route: Ingestion
Method: OECD Test Guideline 414

SAFETY DATA SHEET

NOROX

MEKP-9H DDDD RED

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1.1
Revision Date:
06/14/2023
SDS Number:
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Date of last issue: 06/02/2023
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Result: negative

Reproductive toxicity – As-
sessment

: Suspected of damaging fertility or the unborn child., Some
evidence of adverse effects on sexual function and fertility,
and/or on development, based on animal experiments.

Butanone:
Effects on fertility

: Species: Rat
Application Route: oral (drinking water)
General Toxicity Parent: NOAEL: 10,000 mg/l
General Toxicity F1: NOAEL: 10,000 mg/l
Method: OECD Test Guideline 416
Remarks: Based on data from similar materials

Species: Rat
Application Route: oral (drinking water)
General Toxicity Parent: LOAEL: 20,000 mg/l
Method: OECD Test Guideline 416
Remarks: Based on data from similar materials

Effects on fetal development

: Species: Rat
Application Route: Inhalation
General Toxicity Maternal: NOAEC: ca. 1,002 mg/kg body
weight
Teratogenicity: NOAEC Parent: ca. 1,002 mg/kg body weight
Method: OECD Test Guideline 414
Result: negative

2-Naphthalenol, 1-[2-[4-(2-phenyldiazenyl)phenyl]diazenyl]-, ar-heptyl ar’,ar”-Me derivs.:
Reproductive toxicity – As-
sessment

: Some evidence of adverse effects on sexual function and
fertility, and/or on development, based on animal experiments.

STOT-single exposure
Not classified based on available information.
Components:
Butanone:
Assessment : May cause drowsiness or dizziness.

Hydrogen peroxide:
Assessment : May cause respiratory irritation.

STOT-repeated exposure
Not classified based on available information.

SAFETY DATA SHEET

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MEKP-9H DDDD RED

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1.1
Revision Date:
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SDS Number:
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Date of last issue: 06/02/2023
Date of first issue: 06/02/2023

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Repeated dose toxicity
Components:
dimethyl phthalate:
Species : Rat
NOAEL : 770 mg/kg
Application Route : Oral
Exposure time : 16 w
Method : OECD Test Guideline 408

2-Butanone, peroxide:
Species : Rat
NOAEL : 200 mg/kg
Application Route : oral (gavage)
Exposure time : 28 d
Method : OECD Test Guideline 407

Repeated dose toxicity –
Assessment

: Harmful if swallowed., Harmful if inhaled.

Hydrogen peroxide:
Species : Mouse
Application Route : Ingestion
Exposure time : 90 d
Symptoms : No adverse effects.

Aspiration toxicity
Not classified based on available information.
Components:
dimethyl phthalate:
No aspiration toxicity classification

Trimethylpentanediol isobutyrate:
Not classified due to data which are conclusive although insufficient for classification.

Further information
Product:
Remarks : No data available

Components:
dimethyl phthalate:
Remarks : No data available

SAFETY DATA SHEET

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MEKP-9H DDDD RED

Version
1.1
Revision Date:
06/14/2023
SDS Number:
600000001059
Date of last issue: 06/02/2023
Date of first issue: 06/02/2023

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Trimethylpentanediol isobutyrate:
Remarks : No data available

SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Components:
dimethyl phthalate:
Toxicity to fish

: LC50 (Pimephales promelas (fathead minnow)): 39 mg/l
Exposure time: 96 h

Toxicity to daphnia and other
aquatic invertebrates

: LC50 (Daphnia magna (Water flea)): > 52 mg/l
Exposure time: 48 h

Toxicity to algae/aquatic
plants

: EC50 (Desmodesmus subspicatus (green algae)): 260 mg/l
Exposure time: 72 h

Toxicity to fish (Chronic tox-
icity)

: NOEC (Oncorhynchus mykiss (rainbow trout)): 11 mg/l
Exposure time: 102 d
Method: OECD Test Guideline 210

LOEC (Oncorhynchus mykiss (rainbow trout)): 24 mg/l
Exposure time: 102 d
Method: OECD Test Guideline 210

Toxicity to daphnia and other
aquatic invertebrates (Chron-
ic toxicity)

: NOEC (Daphnia magna (Water flea)): 9.6 mg/l
Exposure time: 21 d

LOEC (Daphnia magna (Water flea)): 23 mg/l
Exposure time: 21 d

Toxicity to microorganisms

: EC50: 4,100 mg/l
Exposure time: 0.5 h
Method: OECD Test Guideline 209

2-Butanone, peroxide:
Toxicity to fish

: LC50 (Poecilia reticulata (guppy)): 44.2 mg/l
Exposure time: 96 h
Method: OECD Test Guideline 203

NOEC (Poecilia reticulata (guppy)): 18 mg/l
Exposure time: 96 h
Method: OECD Test Guideline 203

Toxicity to daphnia and other
aquatic invertebrates

: EC50 (Daphnia magna (Water flea)): 39 mg/l
Exposure time: 48 h
Method: OECD Test Guideline 202

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SDS Number:
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Date of last issue: 06/02/2023
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NOEC (Daphnia magna (Water flea)): 26.7 mg/l
Method: OECD Test Guideline 202

Toxicity to algae/aquatic
plants

: EC50 (Pseudokirchneriella subcapitata (green algae)): 5.6
mg/l
Exposure time: 72 h
Method: OECD Test Guideline 201

NOEC (Pseudokirchneriella subcapitata (green algae)): 2.1
mg/l
Exposure time: 72 h
Method: OECD Test Guideline 201

Toxicity to microorganisms

: EC50 (Bacteria): 48 mg/l
Exposure time: 0.5 h
Method: OECD Test Guideline 209

Trimethylpentanediol isobutyrate:
Toxicity to fish

: NOEC (Fish): >= 6 mg/l
Exposure time: 96 h
Method: OECD Test Guideline 203

Toxicity to daphnia and other
aquatic invertebrates

: EC50 (Daphnia): >= 1.46 mg/l
Exposure time: 48 h

NOEC (Daphnia): 0.7 mg/l
Exposure time: 21 d

Toxicity to algae/aquatic
plants

: EC50 (Chlorella pyrenoidosa): > 7.49 mg/l
Exposure time: 72 h
Method: OECD Test Guideline 201

Toxicity to daphnia and other
aquatic invertebrates (Chron-
ic toxicity)

: LOEC (Daphnia magna (Water flea)): 0.7 mg/l
Exposure time: 21 d

Ecotoxicology Assessment
Acute aquatic toxicity

: This product has no known ecotoxicological effects.

Chronic aquatic toxicity

: Harmful to aquatic life with long lasting effects.

Butanone:
Toxicity to fish

: LC50 (Pimephales promelas (fathead minnow)): 2,993 mg/l
Exposure time: 96 h
Method: OECD Test Guideline 203

Toxicity to daphnia and other
aquatic invertebrates

: EC50 (Daphnia magna (Water flea)): 308 mg/l
Exposure time: 48 h
Method: OECD Test Guideline 202

SAFETY DATA SHEET

NOROX

MEKP-9H DDDD RED

Version
1.1
Revision Date:
06/14/2023
SDS Number:
600000001059
Date of last issue: 06/02/2023
Date of first issue: 06/02/2023

22 / 28

Toxicity to algae/aquatic
plants

: EC50 (Pseudokirchneriella subcapitata (green algae)): 2,029
mg/l
Exposure time: 96 h
Method: OECD Test Guideline 201

Toxicity to microorganisms

: NOEC (Pseudomonas putida): 1,150 mg/l
Exposure time: 16 h
Method: DIN 38 412 Part 8

Hydrogen peroxide:
Toxicity to fish

: LC50 (Pimephales promelas (fathead minnow)): 16.4 mg/l
Exposure time: 96 h

Toxicity to daphnia and other
aquatic invertebrates

: LC50 (Daphnia pulex (Water flea)): 2.4 mg/l
Exposure time: 48 h

Toxicity to algae/aquatic
plants

: EC50 (Skeletonema costatum (marine diatom)): 1.38 mg/l
Exposure time: 72 h

NOEC (Skeletonema costatum (marine diatom)): 0.63 mg/l
Exposure time: 72 h

Toxicity to daphnia and other
aquatic invertebrates (Chron-
ic toxicity)

: NOEC (Daphnia magna (Water flea)): 0.63 mg/l
Exposure time: 21 d

Persistence and degradability
Components:
dimethyl phthalate:
Biodegradability

: Result: Readily biodegradable.
Method: OECD Test Guideline 301E

2-Butanone, peroxide:
Biodegradability

: Result: Readily biodegradable.
Method: OECD Test Guideline 301D

Trimethylpentanediol isobutyrate:
Biodegradability

: Result: rapidly biodegradable
Exposure time: 28 d
Method: OECD Test Guideline 301B

Butanone:
Biodegradability

: Result: Readily biodegradable.
Method: OECD Test Guideline 301D

SAFETY DATA SHEET

NOROX

MEKP-9H DDDD RED

Version
1.1
Revision Date:
06/14/2023
SDS Number:
600000001059
Date of last issue: 06/02/2023
Date of first issue: 06/02/2023

23 / 28
Hydrogen peroxide:
Biodegradability

: Result: Readily biodegradable.

Bioaccumulative potential
Components:
dimethyl phthalate:
Bioaccumulation

: Bioconcentration factor (BCF): 57
Method: OECD Test Guideline 305

Partition coefficient: n-
octanol/water

: log Pow: 1.54

2-Butanone, peroxide:
Partition coefficient: n-
octanol/water

: log Pow: < 0.3 (25 C / 25 C) Trimethylpentanediol isobutyrate: Bioaccumulation : Species: Fish Bioconcentration factor (BCF): 1.95 Partition coefficient: n- octanol/water : log Pow: 4.91 (25 C / 25 C) Butanone: Partition coefficient: n- octanol/water : log Pow: 0.3 (40 C / 40 C) Hydrogen peroxide: Partition coefficient: n- octanol/water : log Pow: -1.57 Remarks: Calculation Mobility in soil No data available Other adverse effects Product: Ozone-Depletion Potential : Regulation: 40 CFR Protection of Environment; Part 82 Pro- tection of Stratospheric Ozone - CAA Section 602 Class I Substances Remarks: This product neither contains, nor was manufac- tured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). Additional ecological infor- mation : An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. SAFETY DATA SHEET NOROX MEKP-9H DDDD RED Version 1.1 Revision Date: 06/14/2023 SDS Number: 600000001059 Date of last issue: 06/02/2023 Date of first issue: 06/02/2023 24 / 28 Toxic to aquatic life. Components: dimethyl phthalate: Additional ecological infor- mation : No data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Dispose of wastes in an approved waste disposal facility. The product should not be allowed to enter drains, water courses or the soil. Do not contaminate ponds, waterways or ditches with chemical or used container. Contaminated packaging : Dispose of in accordance with local regulations. Clean container with water. Dispose of contents/ container to an approved waste disposal plant. Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum. SECTION 14. TRANSPORT INFORMATION International Regulations UNRTDG UN number : UN 3105 Proper shipping name : ORGANIC PEROXIDE TYPE D, LIQUID (METHYL ETHYL KETONE PEROXIDE(S) ) Class : 5.2 Packing group : Not assigned by regulation Labels : 5.2 IATA-DGR UN/ID No. : UN 3105 Proper shipping name : Organic peroxide type D, liquid (Methyl ethyl ketone peroxide(s)) Class : 5.2 Packing group : Not assigned by regulation Labels : Organic Peroxides, Keep Away From Heat Packing instruction (cargo aircraft) : 570 Packing instruction (passen- ger aircraft) : 570 SAFETY DATA SHEET NOROX MEKP-9H DDDD RED Version 1.1 Revision Date: 06/14/2023 SDS Number: 600000001059 Date of last issue: 06/02/2023 Date of first issue: 06/02/2023 25 / 28 IMDG-Code UN number : UN 3105 Proper shipping name : ORGANIC PEROXIDE TYPE D, LIQUID (METHYL ETHYL KETONE PEROXIDE(S) ) Class : 5.2 Packing group : Not assigned by regulation Labels : 5.2 EmS Code : F-J, S-R Marine pollutant : no Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. Domestic regulation 49 CFR UN/ID/NA number : UN 3105 Proper shipping name : Organic peroxide type D, liquid (Methyl ethyl ketone peroxide(s), <=45%) Class : 5.2 Packing group : Not assigned by regulation Labels : ORGANIC PEROXIDE ERG Code : 145 Marine pollutant : no Special precautions for user The transport classification(s) provided herein are for informational purposes only, and solely based upon the properties of the unpackaged material as it is described within this Safety Data Sheet. Transportation classifications may vary by mode of transportation, package sizes, and variations in regional or country regulations. SECTION 15. REGULATORY INFORMATION CERCLA Reportable Quantity Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) 2-Butanone, peroxide 1338-23-4 10 28 SARA 304 Extremely Hazardous Substances Reportable Quantity Listed substances in the product are at low enough levels to not be expected to exceed the RQ SARA 302 Extremely Hazardous Substances Threshold Planning Quantity Components CAS-No. Component TPQ (lbs) Hydrogen peroxide 7722-84-1 1000 SARA 311/312 Hazards : Flammable (gases, aerosols, liquids, or solids) Organic peroxides Acute toxicity (any route of exposure) Reproductive toxicity Skin corrosion or irritation Serious eye damage or eye irritation SAFETY DATA SHEET NOROX MEKP-9H DDDD RED Version 1.1 Revision Date: 06/14/2023 SDS Number: 600000001059 Date of last issue: 06/02/2023 Date of first issue: 06/02/2023 26 / 28 SARA 313 : The following components are subject to reporting levels established by SARA Title III, Section 313: dimethyl phthalate 131-11-3 Clean Air Act This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 112 (40 CFR 61): dimethyl phthalate 131-11-3 This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F). The following chemical(s) are listed under the U.S. Clean Air Act Section 111 SOCMI Intermedi- ate or Final VOC's (40 CFR 60.489): Butanone 78-93-3 Clean Water Act This product contains the following toxic pollutants listed under the U.S. Clean Water Act Section 307 dimethyl phthalate 131-11-3 This product contains the following priority pollutants related to the U.S. Clean Water Act: dimethyl phthalate 131-11-3 The following Hazardous Substances are listed under the U.S. CleanWater Act, Section 311, Ta- ble 116.4A: Xylene 1330-20-7 ethylbenzene 100-41-4 The following Hazardous Chemicals are listed under the U.S. CleanWater Act, Section 311, Table 117.3: Xylene 1330-20-7 ethylbenzene 100-41-4 California Prop. 65 WARNING: This product can expose you to chemicals including ethylbenzene, which is/are known to the State of California to cause cancer. For more information go to www.P65Warnings.ca.gov. International Regulations The ingredients of this product are reported in the following inventories: TCSI (TW) : On the inventory, or in compliance with the inventory TSCA (US) : All substances listed as active on the TSCA inventory DSL (CA) : All components of this product are on the Canadian DSL KECI (KR) : On the inventory, or in compliance with the inventory PICCS (PH) : On the inventory, or in compliance with the inventory IECSC (CN) : On the inventory, or in compliance with the inventory SAFETY DATA SHEET NOROX MEKP-9H DDDD RED Version 1.1 Revision Date: 06/14/2023 SDS Number: 600000001059 Date of last issue: 06/02/2023 Date of first issue: 06/02/2023 27 / 28 TSCA list No substances are subject to a Significant New Use Rule. No substances are subject to TSCA 12(b) export notification requirements. SECTION 16. OTHER INFORMATION Further information This material safety datasheet only contains information relating to safety and does not replace any product information or product specification. These safety instructions also apply to empty packaging which may still contain product residues. The hazards on the label also apply to residues in the container. Sources of key data used to compile the Material Safety Data Sheet : Internal technical data, data from raw material SDSs, OECD eChem Portal search results and European Chemicals Agen- cy, http://echa.europa.eu/ Revision Date : 06/14/2023 Full text of other abbreviations ACGIH : USA. ACGIH Threshold Limit Values (TLV) ACGIH BEI : ACGIH - Biological Exposure Indices (BEI) NIOSH REL : USA. NIOSH Recommended Exposure Limits OSHA P0 : USA. Table Z-1-A Limits for Air Contaminants (1989 vacated values) OSHA Z-1 : USA. Occupational Exposure Limits (OSHA) - Table Z-1 Lim- its for Air Contaminants ACGIH / TWA : 8-hour, time-weighted average ACGIH / STEL : Short-term exposure limit ACGIH / C : Ceiling limit NIOSH REL / TWA : Time-weighted average concentration for up to a 10-hour workday during a 40-hour workweek NIOSH REL / ST : STEL - 15-minute TWA exposure that should not be exceeded at any time during a workday NIOSH REL / C : Ceiling value not be exceeded at any time. OSHA P0 / TWA : 8-hour time weighted average OSHA P0 / STEL : Short-term exposure limit OSHA P0 / C : Ceiling limit OSHA Z-1 / TWA : 8-hour time weighted average AIIC - Australian Inventory of Industrial Chemicals; ASTM - American Society for the Testing of Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic Sub- stances List (Canada); ECx - Concentration associated with x% response; EHS - Extremely Haz- SAFETY DATA SHEET NOROX MEKP-9H DDDD RED Version 1.1 Revision Date: 06/14/2023 SDS Number: 600000001059 Date of last issue: 06/02/2023 Date of first issue: 06/02/2023 28 / 28 ardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized Sys- tem; GLP - Good Laboratory Practice; HMIS - Hazardous Materials Identification System; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organiza- tion; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemi- cals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Convention for the Pre- vention of Pollution from Ships; MSHA - Mine Safety and Health Administration; n.o.s. - Not Oth- erwise Specified; NFPA - National Fire Protection Association; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic sub- stance; PICCS - Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quanti- tative) Structure Activity Relationship; RCRA - Resource Conservation and Recovery Act; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concern- ing the Registration, Evaluation, Authorisation and Restriction of Chemicals; RQ - Reportable Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA - Superfund Amend- ments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TECI - Thailand Existing Chemicals Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumulative The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor- mation and belief at the date of its publication. The information given is designed only as a guid- ance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. US / Z8

90000000023_SDS.pdf

by | Sep 27, 2025

SAFETY DATA SHEET
1. Identification
TR-309 & 307 Rubbing CompoundProduct identifier
Other means of identification
309, 307Product code
Polish.Recommended use
Workers (and your customers or users in the case of resale) should be informed of the potential
presence of respirable dust and respirable crystalline silica as well as their potential hazards.
Appropriate training in the proper use and handling of this material should be provided as required
under applicable regulations.
Recommended restrictions
Manufacturer/Importer/Supplier/Distributor information
TR Industries a Division of Granitize Products Inc.Manufacturer/Supplier
11022 Vulcan StreetAddress
South Gate, CA 90280-0893 United States
(562) 923-5438Telephone:
CHEMTREC: (800) 424-9300Emergency
CHEMTREC International: 00 1-703-527-3887
2. Hazard(s) identification
Not classified.Physical hazards
Category 1Skin corrosion/irritationHealth hazards
Category 1Serious eye damage/eye irritation
Category 1ACarcinogenicity
Category 3 respiratory tract irritationSpecific target organ toxicity, single exposure
Category 2 (Lung)Specific target organ toxicity, repeated
exposure
Not classified.OSHA defined hazards
Label elements
Signal word Danger
Hazard statement Causes severe skin burns and eye damage. May cause cancer. May cause respiratory irritation.
May cause damage to organs (Lung) through prolonged or repeated exposure.
Precautionary statement
Prevention Do not breathe dust/fume/gas/mist/vapors/spray. Wash thoroughly after handling. Wear protective
gloves/protective clothing/eye protection/face protection. Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood. Use only outdoors or in
a well-ventilated area.
Response If swallowed: Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all
contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. If
inhaled: Remove person to fresh air and keep comfortable for breathing. Immediately call a
poison center/doctor. If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise
classified (HNOC)
None known.
Supplemental information None.
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3. Composition/information on ingredients
Mixtures
7732-18-5 35 – 40Water
CAS number %Chemical name
64742-96-7 30 – 35Solvent Naphtha (petroleum),
Heavy Aliphatic
14808-60-7 15 – 20Quartz
61790-12-3 5 – 10Tall Oil, Fatty Acids
141-43-5 1 – 52-Aminoethanol
8002-09-3 1 – 5Pine Oil
All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in
percent by volume.
Composition comments
4. First-aid measures
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison
center or doctor/physician if you feel unwell.
Inhalation
Take off immediately all contaminated clothing. Rinse skin with water/shower. Call a physician or
poison control center immediately. Chemical burns must be treated by a physician.
Skin contact
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Call a physician or poison control center immediately.
Eye contact
Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If
vomiting occurs, keep head low so that stomach content doesn’t get into the lungs.
Ingestion
Burning pain and severe corrosive skin damage. Causes permanent skin damage (scarring).
Causes serious eye damage. Symptoms may include stinging, tearing, redness, swelling, and
blurred vision. Permanent eye damage including blindness could result. Ingestion may produce
burns to the lips, oral cavity, upper airway, esophagus and possibly the digestive tract. May cause
respiratory irritation. Coughing. Wheezing. Difficulty in breathing. Shortness of breath. Prolonged
exposure may cause chronic effects. Causes digestive tract burns.
Most important
symptoms/effects, acute and
delayed
Provide general supportive measures and treat symptomatically. Chemical burns: Flush with water
immediately. While flushing, remove clothes which do not adhere to affected area. Call an
ambulance. Continue flushing during transport to hospital. Keep victim under observation.
Symptoms may be delayed.
Indication of immediate
medical attention and special
treatment needed
IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice
(show the label where possible). Ensure that medical personnel are aware of the material(s)
involved, and take precautions to protect themselves.
General information
5. Fire-fighting measures
Alcohol resistant foam. Carbon dioxide (CO2).Suitable extinguishing media
Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing
media
Fire may produce irritating, corrosive and/or toxic gases.Specific hazards arising from
the chemical
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipment
and precautions for firefighters
In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do
so without risk. Cool containers exposed to heat with water spray and remove container, if no risk
is involved. Use standard firefighting procedures and consider the hazards of other involved
materials.
Fire fighting
equipment/instructions
Material will burn in a fire.General fire hazards
6. Accidental release measures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear
appropriate protective equipment and clothing during clean-up. Do not touch damaged containers
or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation.
Local authorities should be advised if significant spillages cannot be contained. For personal
protection, see section 8 of the SDS.
Personal precautions,
protective equipment and
emergency procedures
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Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product
recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re-use. Put material in suitable, covered, labeled
containers. For waste disposal, see section 13 of the SDS.
Methods and materials for
containment and cleaning up
Avoid discharge into drains, water courses or onto the ground.Environmental precautions
7. Handling and storage
Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Do not breathe mist or vapor. Do not get in eyes, on skin, or on clothing. Avoid
prolonged exposure. Should be handled in closed systems, if possible. Use only in well-ventilated
areas. Wear appropriate personal protective equipment. Observe good industrial hygiene
practices.
Precautions for safe handling
Store locked up. Keep away from heat and sources of ignition. Store in original tightly closed
container. Store away from incompatible materials (see Section 10 of the SDS).
Conditions for safe storage,
including any incompatibilities
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
FormValueComponents Type
PEL 6 mg/m32-Aminoethanol (CAS
141-43-5)
3 ppm
PEL 0.05 mg/m3 Respirable dust.Quartz (CAS 14808-60-7)
PEL 400 mg/m3Solvent Naphtha
(petroleum), Heavy
Aliphatic (CAS 64742-96-7)
100 ppm
US. OSHA Table Z-3 (29 CFR 1910.1000)
FormValueComponents Type
TWA 0.1 mg/m3 Respirable.Quartz (CAS 14808-60-7)
2.4 mppcf Respirable.
US. ACGIH Threshold Limit Values
FormValueComponents Type
STEL 6 ppm2-Aminoethanol (CAS
141-43-5)
TWA 3 ppm
TWA 0.025 mg/m3 Respirable fraction.Quartz (CAS 14808-60-7)
TWA 200 mg/m3 Non-aerosol.Solvent Naphtha
(petroleum), Heavy
Aliphatic (CAS 64742-96-7)
US. NIOSH: Pocket Guide to Chemical Hazards
FormValueComponents Type
STEL 15 mg/m32-Aminoethanol (CAS
141-43-5)
6 ppm
TWA 8 mg/m3
3 ppm
TWA 0.05 mg/m3 Respirable dust.Quartz (CAS 14808-60-7)
No biological exposure limits noted for the ingredient(s).Biological limit values
Occupational exposure to nuisance dust (total and respirable) and respirable crystalline silica
should be monitored and controlled. Occupational Exposure Limits are not relevant to the current
physical form of the product.
Exposure guidelines
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US ACGIH Threshold Limit Values: Skin designation
Solvent Naphtha (petroleum), Heavy Aliphatic (CAS
64742-96-7)
Can be absorbed through the skin.
Good general ventilation should be used. Ventilation rates should be matched to conditions. If
applicable, use process enclosures, local exhaust ventilation, or other engineering controls to
maintain airborne levels below recommended exposure limits. If exposure limits have not been
established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency
shower must be available when handling this product.
Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Wear safety glasses with side shields (or goggles) and a face shield.Eye/face protection
Skin protection
Wear appropriate chemical resistant gloves. Be aware that the liquid may penetrate the gloves.
Frequent change is advisable. Suitable gloves can be recommended by the glove supplier.
Hand protection
Skin protection
Wear chemical-resistant gloves, footwear and protective clothing appropriate for risk of exposure.
Contact glove manufacturer for specific information.
Other
If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn.
Respiratory protection
Wear appropriate thermal protective clothing, when necessary.Thermal hazards
Observe any medical surveillance requirements. Always observe good personal hygiene
measures, such as washing after handling the material and before eating, drinking, and/or
smoking. Routinely wash work clothing and protective equipment to remove contaminants.
General hygiene
considerations
9. Physical and chemical properties
Appearance
Solid.Physical state
Paste.Form
Not available.Color
Not available.Odor
Odor threshold Not available.
pH Not applicable.
Melting point/freezing pointNot available.
Initial boiling point and boiling
range
Not available.
Flash point > 140.0 F (> 60.0 C) (Estimated)
Evaporation rate Not applicable.
Not available.Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit – lower
(%)
Not available.
Flammability limit – upper
(%)
Not available.
Vapor pressure Not applicable.
Vapor density Not applicable.
Relative density Not available.
Solubility(ies)
Solubility (water) Not available.
Partition coefficient
(n-octanol/water)
Not available.
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not applicable.
Other information
Not explosive.Explosive properties
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Not oxidizing.Oxidizing properties
10. Stability and reactivity
The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity
Material is stable under normal conditions.Chemical stability
No dangerous reaction known under conditions of normal use.Possibility of hazardous
reactions
Contact with incompatible materials.Conditions to avoid
Strong oxidizers, strong acids, and strong bases. Amines.Incompatible materials
Thermal decomposition of this product can generate carbon monoxide and carbon dioxide.
Nitrogen oxides.
Hazardous decomposition
products
11. Toxicological information
Information on likely routes of exposure
Inhalation May cause irritation to the respiratory system.
Skin contact Causes severe skin burns.
Prolonged or repeated exposure may cause liver and kidney damage. These effects have not
been observed in humans.
Eye contact Causes serious eye damage.
Ingestion Causes digestive tract burns.
Symptoms related to the
physical, chemical and
toxicological characteristics
Burning pain and severe corrosive skin damage. Causes serious eye damage. Symptoms may
include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including
blindness could result. May cause respiratory irritation. Coughing. Discomfort in the chest.
Shortness of breath. Causes digestive tract burns. Prolonged exposure may cause chronic
effects.
Information on toxicological effects
Acute toxicity Not expected to be acutely toxic.
Test ResultsComponents Species
Quartz (CAS 14808-60-7)
Inhalation
Chronic
LOEC Human 0.0563 mg/m3
Causes severe skin burns and eye damage.Skin corrosion/irritation
Causes serious eye damage.Serious eye damage/eye
irritation
Respiratory or skin sensitization
Respiratory sensitizationNot a respiratory sensitizer.
This product is not expected to cause skin sensitization.Skin sensitization
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Germ cell mutagenicity
Carcinogenicity May cause cancer.
IARC Monographs. Overall Evaluation of Carcinogenicity
Quartz (CAS 14808-60-7) 1 Carcinogenic to humans.
NTP Report on Carcinogens
Quartz (CAS 14808-60-7) Known To Be Human Carcinogen.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Quartz (CAS 14808-60-7) Cancer
This product is not expected to cause reproductive or developmental effects.Reproductive toxicity
Specific target organ toxicity –
single exposure
May cause respiratory irritation.
Specific target organ toxicity –
repeated exposure
May cause damage to organs (Lung) through prolonged or repeated exposure.
Aspiration hazard Due to the physical form of the product it is not expected to be an aspiration hazard.
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Chronic effects May cause damage to organs through prolonged or repeated exposure. May be harmful if
absorbed through skin. Prolonged exposure may cause chronic effects.
Prolonged or repeated exposure may cause liver and kidney damage. These effects have not
been observed in humans.
Further information Symptoms may be delayed. May be absorbed through the skin.
12. Ecological information
The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Ecotoxicity
No data is available on the degradability of any ingredients in the mixture. Persistence and degradability
Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)
2-Aminoethanol (CAS 141-43-5) -1.31
No data available for this product.Mobility in soil
Other adverse effects Substantial amounts of the product may lead to a local change in acidity in small water systems
which may have adverse effects on aquatic organisms.
13. Disposal considerations
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Incinerate the
material under controlled conditions in an approved incinerator. Dispose of contents/container in
accordance with local/regional/national/international regulations.
Disposal instructions
Dispose in accordance with all applicable regulations.Local disposal regulations
D002: Waste Corrosive material [pH <=2 or =>12.5, or corrosive to steel]
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Hazardous waste code
Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Waste from residues / unused
products
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.
Contaminated packaging
14. Transport information
DOT
UN2491UN number
Ethanolamine solutionsUN proper shipping name
8Class
Transport hazard class(es)
-Subsidiary risk
8Label(s)
IIIPacking group
NoMarine pollutant
Environmental hazards
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
IB3, T4, TP1Special provisions
154Packaging exceptions
203Packaging non bulk
241Packaging bulk
IATA
UN2491UN number
Ethanolamine solutionUN proper shipping name
8Class
Transport hazard class(es)
-Subsidiary risk
8Label(s)
IIIPacking group
NoEnvironmental hazards
8LERG Code
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
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IMDG
UN2491UN number
ETHANOLAMINE SOLUTIONUN proper shipping name
8Class
Transport hazard class(es)
-Subsidiary risk
IIIPacking group
NoMarine pollutant
Environmental hazards
F-A, S-BEmS
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
Not applicable.Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
15. Regulatory information
This product is a “Hazardous Chemical” as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Quartz (CAS 14808-60-7) Cancer
lung effects
immune system effects
kidney effects
SARA 302 Extremely hazardous substance
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Not listed.
YesSARA 311/312 Hazardous
chemical
Skin corrosion or irritation
Serious eye damage or eye irritation
Carcinogenicity
Specific target organ toxicity (single or repeated exposure)
Classified hazard
categories
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Not regulated.Safe Drinking Water Act
(SDWA)
US state regulations
US. Massachusetts RTK – Substance List
2-Aminoethanol (CAS 141-43-5)
Quartz (CAS 14808-60-7)
US. New Jersey Worker and Community Right-to-Know Act
2-Aminoethanol (CAS 141-43-5)
Pine Oil (CAS 8002-09-3)
Quartz (CAS 14808-60-7)
Solvent Naphtha (petroleum), Heavy Aliphatic (CAS 64742-96-7)
TR-309 & 307 Rubbing Compound SDS US
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US. Pennsylvania Worker and Community Right-to-Know Law
2-Aminoethanol (CAS 141-43-5)
Quartz (CAS 14808-60-7)
US. Rhode Island RTK
2-Aminoethanol (CAS 141-43-5)
Quartz (CAS 14808-60-7)
California Proposition 65
This product can expose you to Quartz, which is known to the State of California to cause cancer.
For more information go to www.P65Warnings.ca.gov.
WARNING:
California Proposition 65 – CRT: Listed date/Carcinogenic substance
Quartz (CAS 14808-60-7) Listed: October 1, 1988
US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3,
subd. (a))
Quartz (CAS 14808-60-7)
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australian Inventory of Chemical Substances (AICS) YesAustralia
Domestic Substances List (DSL) YesCanada
Non-Domestic Substances List (NDSL) NoCanada
Inventory of Existing Chemical Substances in China (IECSC) YesChina
European Inventory of Existing Commercial Chemical
Substances (EINECS)
NoEurope
European List of Notified Chemical Substances (ELINCS) NoEurope
Inventory of Existing and New Chemical Substances (ENCS) NoJapan
Existing Chemicals List (ECL) YesKorea
New Zealand Inventory YesNew Zealand
Philippine Inventory of Chemicals and Chemical Substances
(PICCS)
YesPhilippines
Taiwan Chemical Substance Inventory (TCSI) YesTaiwan
*A “Yes” indicates this product complies with the inventory requirements administered by the governing country(s).
A “No” indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico
16. Other information, including date of preparation or last revision
03-September-2018Issue date
-Revision date
Version # 01
NFPA ratings
03
1
List of abbreviations PEL: Permissible Exposure Limit.
STEL: Short-Term Exposure Limit.
TWA: Time Weighted Average Value.
TR Industries cannot anticipate all conditions under which this information and its product, or the
products of other manufacturers in combination with its product, may be used. It is the user s
responsibility to ensure safe conditions for handling, storage and disposal of the product, and to
assume liability for loss, injury, damage or expense due to improper use. The information in the
sheet was written based on the best knowledge and experience currently available.
Disclaimer
TR-309 & 307 Rubbing Compound SDS US
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90000000022_SDS.pdf

by | Sep 27, 2025

SAFETY DATA SHEET
Date issued : 05/15/2014
SDS number : SC-22
Date revised : 03/25/2024
Revision number : 3
SC-22
1. Identification
Product identifier: SC-22
Relevant identified uses: Plasticizer
Manufacturer / Supplier Emergency telephone number (24 hour)
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. Hazard identification
Classification of the substance or mixture
This product does not meet the criteria for classification.
Label elements
Not Applicable
3. Composition/information on ingredients
Chemical name % w/w CAS No.
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich 80 – 10068515-49-1
4. First-aid measures
Eye: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention if irritation develops.
Skin: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
Ingestion: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the patient
is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
Inhalation: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops.
Indication of immediate medical attention and special treatment needed, if necessary: Symptomatic and supportive therapy as needed.
Following severe exposure medical follow-up should be monitored for at least 48 hours.
5. Fire-fighting measures
Suitable extinguishing media: Foam, carbon dioxide, dry chemical, or water fog.
Hazardous combustion products: Carbon monoxide and carbon dioxide.
Fire fighting procedures: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not release runoff
from fire control methods to sewers or waterways.
Fire fighting equipment: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of unmanned
hose holders or monitor nozzles for fighting large fires.
6. Accidental release measures
Page 1 of 5

Small spill: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major spill should wear full
protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or waterways. Neutralize small spills
with a decontaminant.
Large spill: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top drums or
plastic bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly dispose of
residues. Notify applicable government authorities if release is reportable. (See CERCLA in Section 15).
Environmental precautions
Water spill: Do not discharge into drains, surface waters, or groundwater.
General procedures: Refer to section 8 of SDS for personal protection details.
Release notes: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if necessary.
7. Handling and storage
General procedures: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open containers.
Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
Precautions for safe handling: Use in a well ventilated area. Avoid heat, sparks, and open flames. Avoid breathing vapor and contact with eyes,
skin, and clothing. Use appropriate personal protective equipment as specified in Section 8. Handle and use in a manner consistent with good
industrial/manufacturing techniques and practices.
Conditions for safe storage: Keep away from heat, sparks, open flames, or other sources of ignition. Store in a cool, dry place, away from
excessive heat, in original or similar container. Avoid unnecessary contact. Protect from freezing. Containers should be tightly sealed to prevent
contamination with foreign materials.
Storage temperature: 65-80 F (18-27 C)
Shelf life: 6 months from date of shipment under manufacturers recommended storage conditions.
8. Exposure controls/personal protection
Appropriate engineering controls: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
Individual protection measures, such as personal protective equipment
Eye / face protection: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
Skin protection – hand protection: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be
used to prevent contact with eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer
maximum protection.
Respiratory protection: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may
be necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
Skin protection – other: Protective clothing should be selected and used in accordance with “Guidelines for the Selection of Chemical
Protective Clothing” published by ACGIH.
Occupational hygiene practices: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in immediate
work area should be prohibited. Wash hands before eating.
Other use precautions: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Training is
important. Follow all label precautions.
9. Physical and chemical properties
Physical state: Liquid
Color: Colorless
Odor: Mild
pH: No data available
Initial boiling point and boiling range: > 250 C (482 F)
Flash point: 223.9 C (435 F) Pensky-Martens CC
Page 2 of 5
SC-22

Evaporation rate (n-butyl acetate = 1): < 0.01 (n-BuAc=1) Vapor pressure: < 0.08 mmHg at 20 C (68 F) Relative vapor density: > 1 (Air=1)
Relative density: 0.97 (water=1) at 20 C (68 F)
Solubility: Negligible
Dynamic viscosity: 130 Centistokes at 20 C (68 F)
10. Stability and reactivity
Reactivity: Hazardous reactions will not occur under normal transport or storage conditions.
Chemical stability: This product is stable under normal ambient conditions of temperature and pressure.
Conditions to avoid: Heat, flames, and ignition sources.
Possibility of hazardous reactions: No data available
Hazardous decomposition products: Carbon monoxide and carbon dioxide.
Incompatible materials: Strong oxidizing agents.
11. Toxicological information
Acute toxicity
Chemical name
LD50 (oral)
mg/kg(rat)
LD50 (dermal)
mg/kg(rabbit)
LC50 (inhalation)
mg/l
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters,
C10-rich
> 10 g/kg Rat > 3.16 g/kg Rabbit > 0.13 mg/l Rat
Skin corrosion / irritation: No data available
Serious eye damage / irritation: No data available
Respiratory or skin sensitization: No data available
Germ cell mutagenicity: No data available
Carcinogenicity
Notes: This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
Reproductive toxicity: No data available
Specific Target Organ Toxicity – single exposure: No data available
Specific Target Organ Toxicity – repeated exposure: No data available
Aspiration hazard: No data available
12. Ecological information
Ecotoxicological information: No specific ecological data are available for this product. Refer to Section 6 for information regarding accidental
release and Section 15 for regulatory reporting information.
Persistence and degradability: No data available
Bioaccumulative potential: No data available
Environmental data: No data available
Mobility in soil: No data available
13. Disposal considerations
Disposal methods: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
Page 3 of 5
SC-22

runoff and contact with soil, waterways, drains and sewers.
14. Transport information
USA Department of Transport Regulations (DOT): Not Regulated
ICAO / IATA – air: Not Regulated
IMO / IMDG – sea: Not Regulated
15. Regulatory information
UNITED STATES
SARA Section 311/312 Hazard Categories
311/312 Health hazards: None Known
313 reportable ingredients: This product does not contain any substances subject to the reporting requirements of Section 313 of Title III of
the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
CERCLA Hazardous Substances and Reportable Quantities (RQ)
CERCLA regulatory: This product does not contain any substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
TSCA (The Toxic Substances Control Act)
TSCA regulatory: This product does not contain any substances subject to TSCA Section 12(b) export notification.
TSCA Status: This product or its components are listed in or exempt from the TSCA inventory requirements.
Occupational safety and health administration (osha)
29 cfr1910.119—process safety management of highly hazardous chemicals: None of the chemicals in this product are considered highly
hazardous by OSHA.
California Proposition 65: WARNING: This product can expose you to chemicals including [see table below], which is [are] known to the
State of California to cause birth defects or other reproductive harm. For more information, go to www.P65Warnings.ca.gov.
Chemical name % w/w Listed
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich 80 – 100Developmental Toxicity
USA OSHA Hazard Communication Standard (29CFR 1910.1200): The contents of the SDS comply with the OSHA Hazard
Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS Regulatory Status: This product has been classified according to the hazard criteria of the CPR and the SDS contains all the
information required by the CPR.
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL): All components in this product are listed in or exempted from the
Domestic Substances List (DSL) or the Non-Domestic Substances List (NDSL).
General comments: DIDP RESTRICTIONS: This product contains diisodecyl phthalate (DIDP), CAS# 68515-49-1 EINECS# 271-091-4.
In the U.S., there is no longer any restriction on the use of DIDP in toys intended for children and other child care articles [83 FR 3583, 16 CFR
PART 1307].
In the EU, DIDP shall not be used as substance or as constituents of preparations, at concentrations of greater than 0.1 percent by weight (one
thousand parts per million) of the plasticized material, in toys and child care articles which can be place in the mouth by children. Such toys and
child care articles containing DIDP in concentrations greater than the limit mentioned above shall not be placed on the market [Directive
2005/84/EC].
16. Other information
Reason for issue: Revision
Date revised: 03/25/2024
Revision summary: This SDS replaces the 09/08/2020 SDS.
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HMIS rating
Health 1
Flammability 1
Physical hazard 0
Personal protection X
NFPA codes

1
1 0

HMIS ratings notes: Personal Protection: See Section 8
Manufacturer disclaimer: This information is furnished without warranty, expressed or implied, except that is accurate to the best knowledge of
BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes no legal
responsibility for use or reliance upon this data.
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90000000021_SDS.pdf

by | Sep 27, 2025