80TC1570-F_SDS.pdf
80SP340LVC_SDS.pdf
Material Safety DataSheet
Page1of5 Spabond 340LV resin
1 Productandcompanyidentification
Material identification:Spabond 340LV Resin
Applicati onofthesubstance/pr eparation:Epoxyresinadhesive
Supplier/Manu facturer :Gurit(Canada)Inc
175,rueP ladeau
Magog,Qu bec,J1X7L1
Canada
Tel:+1819847-2182
Fortranspo rtation emergencie s,call:Chemt rec:1-800-424-9300orCanutec (Canada): 613-996-6666
Foradditional informati on:Health,Safety andEnvironm entdepartment
Email:christian.moreau@gur it.com
Dateofissue:15/04/10
2 Hazardsidentifi cation
Emergency overview : Viscousliquid material containsepoxyconstituent s.
Hazardous status: Thismaterial isclassified hazardous under OSHA29CFR1910.1200 andunder
theCanadianContro lledProductsRegulati ons
Warning statement : WARNING!
CAUSESEYEANDSKIN IRRITA TION
MAYCAUSE RESPIRATORY TRACT IRRITATION
MAYCAUSE SENSITIZA TION BYSKINCONTACT
Avoidcontact withskinandclothing. Donotbreathevapor,useonlywithadequate
ventilation.
Wash thoroughly whenappropriate
Potential acutehealth effects:Eyes:Irritanttoeyes
Skin:Irritant toskinandmucus membranes .
Inhalation: Maycauserespiratorytractirritation.
Ingestion: Maycauseillness.
Potential chronichealth effects:Prolonged skincontact cancausesensitization.
3 Composi tion/information oningredients
Description :Mixture ofthesubstanc eslistedbelow withnonhaz ardousadditions .
Chem icalname CASnumber %Conce ntration
Propane, 2,2-bis[p-(2,3-epoxypr opoxy)phenyl] -,polymers 25085 -99-8 60 100%
Alkyl (C12,C14)GlycidylEther 68609 -97-2 5 10%
1,4-Butanediol Diglycidy lEther 2425-79-8 5 10%
Phenol, polymer withformaldehyde, GlycidylEther 28064 -14-4 1 5%
Material Safety DataSheet
Page2of5 Spabond 340LV resin
4 Firstaidmeasures
Eyecontact: Rinse immediatelywithplenty ofwater.Ifsymptom spersist, consultadoctor.
Skincontact : Immediat elywashwithsoapandrinsethoroughly .Remove clothing soiledbytheproduct.
Ingestion: Donotinduce vomiting.Rinse outmouth anddrinkplentyofwater.Callformedical help.
Inhalation : Removeindividualtofreshair.Consult adoctor ifsymptomspersist.
6 Accide ntalreleas emeasures
Person alprecautions : Wearprotectiveclothing toavoidcontact witheyesandskin.
Environm entalprecaution s: Prevent materialfromenteringwaterways, sewerssurface orground water.
Measuresforcleaning up: Scoop upspilled material.
5 Fire-fighting measures
Suitableextinguishi ngmedia:Waterhaze,foam, fire-extinguishing powder, carbon dioxide.
Notsuitab leextinguishi ngmedia:Waterwithfulljet.
Special exposurehazards: Formation oftoxicgaseswilloccurduring overheating orincaseoffire.
Protective equipment : Wearfullyprotective suitwithselfcontained breathing apparatus
(SCBA)withaface-pieceoperatedinpositivepressure mode.
7 Handling andstorage
Handling: Wearappropriatepersonalprotection whenhandling. Avoidinhalationofvapors.
Storage: Storeinacool,dryplaceintightly closed receptacles. Keepawayfromheat.
Dateofissue:15/04/10
Material Safety DataSheet
Page3of5 Spabond 340LV resin
9 Physical andchemical properties
Physicalstate: Pasty
Color: Yellow
Odor: Characterist ic(slight)
Flash point: >101
o
C(>214
o
F)
Melting point: Notavailable
Boilingpoint: >200
o
C(>392
o
F)
Ignition temperature : 460
o
C(860
o
F);Product isnotself-igniting
Vapor pressure (20
o
C(68
o
F): 0.075mmHg
Relative density : Notdeterm ined
Solubili tyinwater: Notmiscible
8 Expos urecontrols andpersonalprotection
Componen tswithlimitvaluesthatrequire monitoring attheworkp lace:Noneestablished
Enginee ringmeasures:Useonlywithadequateventilation oruserespiratoryprotection.
General measu res: Keepproductawayfromfoodandbeverage s.
Washhands before eatingandwhenever appropriate .
Immediately remove allsoiled andcontaminated clothing .
Avoidcontact witheyesandskin.
Person alprotection equipments:Eyes:Wearsafetyglasses
Skin:Weargloves andprotecti veworkclothes
Suitablegloves:Nitrilerubber(NBR).Selection ofgloves should takeinconsidera tionthequalityaspect
(thickness,strength, etc.)whichvariesfrommanufactu rertomanufacturer .
Dateofissue:15/04/10
Material Safety DataSheet
Page4of5 Spabond 340LV resin
10 Stability andreactivity
Stabilityandreactivity :Thisproductisstable.
Dangerous reaction : Nodanger ousreactions known.
Incompatibility withothersubstances: Strongoxidizers, strong acidsandbases,amines.
Hazardous decomposition products: Decomposit ionproducts includebutarenotlimitedto:Carbon
monoxide, Carbon dioxideandtoxicpyrolysis product s.
12 Ecologi calinformation
General notes:Toxictosomeaquaticorganisms. Prevent material toreachground water, waterways or
sewagesystem.
Ecotoxicitydata:Notavailabl e
Persistence andbiodegrad ability:Notavailable
Mobility:Notavailab le
13 Disposalconsideration
Wastedispos al:Disposal mustbeinaccordance withapplicableFederal, Stateandlocalregulatio ns.
Remarks : Donotallowmaterialtoenterdrains, sewers orsurface water.
Dateofissue:15/04/10
11 Toxicol ogical information
Toxicolog icalinformation
Ingredient name Test Result Route /species
Propane, 2,2-bis[p-(2,3-poxypr opoxy) phenyl] -,polymers LD50 >5000mg/kg Oralrat
Alkyl (C12,C14)GlycidylEther LD50 >5000mg/kg Oralrat
1,4-Butanediol Diglycidy lEther LD50 >1000mg/kg Oralrat
Phenol, polymer withformaldehyde, GlycidylEther LD50 >5000mg/kg Oralrat
Acute toxicity: Irritanttoeyes.
Irritanttoskinandmucous membranes.
Maycauserespirator ytractirritation.
Maycauseillness ifingested.
Sensitization: Sensitization possiblethrough skincontact.
Mutagenic effects :Notavailable
Teratogenic effects :Notavailab le
Carcin ogeniceffects:Notlistedascarcinogenic byACGIH ,OSHA, IARC andNTP.
Material Safety DataSheet
Page5of5 Spabond 340LV resin
15 Regul atoryinformation
U.S.Federa lregulat ions:
TSCA :Allcomponen tslisted.
SARA 302;304;311/312;313:Noneoftheingredient listed.
U.S.Stateregulations :
California Proposition65:Noneoftheingredient listed.
Canadian regulatio ns:
DSL:Allcompone ntslisted
WHMI Sclassification :D2B-Toxicmaterials causing othereffects;
1
0
HEALTH
FLAMMABIL ITY
PHYSIC ALHAZARDS
HMIS-rating Hazar drating
0-Minimal
1-Slight
2-Moderat e
3-Serious
4-Extreme
NFPA-rating
2
1
0
Health
Flammability
Reactivity
*2
Regulatorystatus
(UN/IMDG/ IATA;DOT/TDG) :Notregulated fortransport
16 Other information
References: AINSIZ400.1,MSDS Standard,2004;
29CFR 1910.1200 OSHA Hazard Communication Standard ;
Controlledproducts regulations(DORS/88 -66)Canada.
Noticetothereader:
Tothebestofourknowle dge,theinformationcontained hereinisaccurate atthedateofitspublication.However ,
thisshallnotconstitu teaguarant eeforanyspecificproduct features andshallnotestablish alegallyvalid
contractualrelationshi p.Thedatarelatesonlytothespecificproduct designated anddoesnotrelatetouseofthe
productinanyprocess orincombination withanyothermaterial.
14 Transport information
Dateofissue:15/04/10
Page 1/7
Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 05/06/2008 Reviewed on 05/06/2008
D R
* 1 Identification of substance
Product details
Trade name: Spabond 340 Extra Slow Hardener
Application of the substance / the preparationEpoxy curing agent
Manufacturer/Supplier:
GURIT (UK) Ltd GURIT (Canada) Inc.
St. CROSS BUSINESS PARK 175, rue P ladeau
NEWPORT I.O.W. Magog (Qu bec)
PO30 5WU J1X 5G9
UNITED KINGDOM Canada
TEL:+44(0)1983 828000 T: +1 819 847 2182
FAX:+44(0)1983 828100 F: +1 819 847 2572
Information department:Product safety department.
Emergency information:Contact as above
* 2 Composition/Data on components
Chemical characterization
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
9046-10-0 Polyoxyalkyleneamine 25-50%
2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine 10-25%
100-51-6 Benzyl alcohol 2.5-10%
3 Hazards identification
Hazard description:
C Corrosive
Information pertaining to particular dangers for man and environment:
The product has to be labelled due to the calculation procedure of the “General Classification guideline for
preparations of the EU” in the latest valid version.
Causes burns.
May cause sensitization by skin contact.
Classification system:
The classification was made according to the latest editions of international substances lists, and expanded
upon from company and literature data.
NFPA ratings (scale 0 – 4)
3
1
0
Health = 3
Fire = 1
Reactivity = 0
(Contd. on page 2)
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Material Safety Data Sheet
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Trade name: Spabond 340 Extra Slow Hardener
(Contd. of page 1)
D R
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
3
1
0
Health = 3
Fire = 1
Reactivity = 0
4 First aid measures
General information:Immediately remove any clothing soiled by the product.
After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:
Immediately wash with water and soap and rinse thoroughly.
Immediately rinse with water.
After eye contact:Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing:
Do not induce vomiting; immediately call for medical help.
A person vomiting while lying on their back should be turned onto their side.
Administer medicinal carbon
Rinse out mouth and then drink plenty of water.
5 Fire fighting measures
Suitable extinguishing agents:
Water haze
Foam
Fire-extinguishing powder
Carbon dioxide
For safety reasons unsuitable extinguishing agents:Water with full jet
Special hazards caused by the material, its products of combustion or resulting gases:
Formation of toxic gases is possible during heating or in case of fire.
Protective equipment:
Mount respiratory protective device.
Wear fully protective suit.
6 Accidental release measures
Person-related safety precautions:Wear protective equipment. Keep unprotected persons away.
Measures for environmental protection:Do not allow to enter sewers/ surface or ground water.
Measures for cleaning/collecting:
Pick up mechanically.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
7 Handling and storage
Handling:
Information for safe handling:
Store in cool, dry place in tightly closed receptacles.
(Contd. on page 3)
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Material Safety Data Sheet
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Trade name: Spabond 340 Extra Slow Hardener
(Contd. of page 2)
D R
Keep away from heat and direct sunlight.
Information about protection against explosions and fires:No special measures required.
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:Keep receptacle tightly sealed.
8 Exposure controls and personal protection
Additional information about design of technical systems:No further data; see item 7.
Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be
monitored at the workplace.
Additional information:The lists that were valid during the creation were used as basis.
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Breathing equipment:Use suitable respiratory protective device in case of insufficient ventilation.
Protection of hands:
Protective gloves
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to
the application.
Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
For the permanent contact of a maximum of 15 minutes gloves made of the following materials are
suitable:
Nitrile rubber, NBR
Eye protection:Safety glasses
Body protection:Protective work clothing
9 Physical and chemical properties
General Information
Form: Pasty
Color: Blue
Odor: Amine-like
Change in condition
Melting point/Melting range:Undetermined.
(Contd. on page 4)
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Material Safety Data Sheet
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Trade name: Spabond 340 Extra Slow Hardener
(Contd. of page 3)
D R
Boiling point/Boiling range:247 C (477 F)
Flash point: 117 C (243 F)
Ignition temperature: 240.0 C (464 F)
Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Density at 20 C (68 F): 1.090 g/cm
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Viscosity:
Dynamic at 20 C (68 F): 260000 mPas
Solvent content:
Organic solvents: 0.0 %
Water: 0.0 %
Solids content: 17.0 %
10 Stability and reactivity
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Dangerous reactionsNo dangerous reactions known.
Dangerous products of decomposition:Danger of toxic pyrolysis products.
11 Toxicological information
Acute toxicity:
LD/LC50 values that are relevant for classification:
9046-10-0 Polyoxyalkyleneamine
Oral LD50 2855 mg/kg (rat)
Dermal LD50 2980 mg/kg (rab)
Primary irritant effect:
on the skin:Caustic effect on skin and mucous membranes.
on the eye:Strong caustic effect.
Sensitization:Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for
preparations:
Corrosive
Irritant
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of
esophagus and stomach.
12 Ecological information
General notes:
Water hazard class 1 (Self-assessment): slightly hazardous for water
(Contd. on page 5)
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Trade name: Spabond 340 Extra Slow Hardener
(Contd. of page 4)
D R
Do not allow product to reach ground water, water course or sewage system.
* 13 Disposal considerations
Product:
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:
Packagings that cannot be cleansed are to be disposed of in the same manner as the product.
14 Transport information
DOT regulations:
Hazard class: 8
Identification number: UN3259
Packing group: II
Proper shipping name (technical name):P O L Y A M I N E S , S O L I D , C O R R O S I V E , N . O . S .
(Polyoxyalkyleneamine, ISOPHORONEDIAMINE)
Label 8
Land transport ADR/RID (cross-border):
ADR/RID class: 8 Corrosive substances
Danger code (Kemler): 80
UN-Number: 3259
Packaging group: II
Description of goods: 32 59 PO L YAMINES , SO L ID, CO RRO S IVE , N.O . S.
(Polyoxyalkyleneamine, ISOPHORONEDIAMINE)
Maritime transport IMDG:
IMDG Class: 8
UN Number: 3259
Label 8
Packaging group: II
EMS Number: F-A,S-B
Marine pollutant: No
(Contd. on page 6)
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Trade name: Spabond 340 Extra Slow Hardener
(Contd. of page 5)
D R
Propper shipping name: P O L Y A M I N E S , S O L I D , C O R R O S I V E , N . O . S .
(Polyoxyalkyleneamine, ISOPHORONEDIAMINE)
Air transport ICAO-TI and IATA-DGR:
ICAO/IATA Class: 8
UN/ID Number: 3259
Label 8
Packaging group: II
Propper shipping name: P O L Y A M I N E S , S O L I D , C O R R O S I V E , N . O . S .
(Polyoxyalkyleneamine, ISOPHORONEDIAMINE)
* 15 Regulations
Sara
Section 355 (extremely hazardous substances):
None of the ingredient is listed.
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
TSCA (Toxic Substances Control Act):
All ingredients are listed.
Proposition 65
Chemicals known to cause cancer:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Cancerogenity categories
EPA (Environmental Protection Agency)
None of the ingredients is listed.
IARC (International Agency for Research on Cancer)
7631-86-9 silicon dioxide, chemically prepared 3
NTP (National Toxicology Program)
None of the ingredients is listed.
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
MAK (German Maximum Workplace Concentration)
None of the ingredients is listed.
(Contd. on page 7)
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Trade name: Spabond 340 Extra Slow Hardener
(Contd. of page 6)
D R
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
Product related hazard informations:
The product has been classified and marked in accordance with directives on hazardous materials.
Hazard symbols:
C Corrosive
Hazard-determining components of labelling:
3-aminomethyl-3,5,5-trimethylcyclohexylamine
Benzyl alcohol
Polyoxyalkyleneamine
Risk phrases:
Causes burns.
May cause sensitization by skin contact.
Safety phrases:
When using do not eat or drink.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
After contact with skin, wash immediately with plenty of water
Wear suitable protective clothing, gloves and eye/face protection.
In case of accident or if you feel unwell, seek medical advice immediately.
This material and its container must be disposed of as hazardous waste.
National regulations:
All components in this formulation are listed in the EPA TSCA chemical inventory. They comply with
applicable rules and orders of the regulations.
Technical instructions (air):
Class Share in %
II 3.9
Water hazard class:Water hazard class 1 (Self-assessment): slightly hazardous for water.
* 16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Department issuing MSDS:Health, Safety & Environmental department.
Contact:SIMON RHODES
* Data compared to the previous version altered.
USA
80SC180-D_SDS.pdf
Page 1/12
Safety Data Sheet
acc. to OSHA HCS
Printing date 03/24/2019 Reviewed on 03/22/2019
48.1.41
1 Identification
Product identifier
Trade name: SC180 NA Part A Resin
Article number:I026072
Application of the substance / the mixtureEpoxy resin
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
ehs-us@axson.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
* 2 Hazard(s) identification
Classification of the substance or mixture
GHS09 Environment
Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
Aquatic Acute 2 H401 Toxic to aquatic life.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
(Contd. on page 2) US
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Trade name: SC180 NA Part A Resin
(Contd. of page 1)
48.1.41
Hazard pictograms
GHS07GHS09
Signal wordWarning
Hazard-determining components of labeling:
Reaction Product of Bisphenol A and Epichlorohydrin
1,6-Bis(2,3-epoxypropoxy)hexane
Dipentaerythritol Pentaacrylate esters
2,3-epoxypropyl neodecanoate
Hazard statements
Causes skin irritation.
Causes serious eye irritation.
May cause an allergic skin reaction.
Toxic to aquatic life.
Toxic to aquatic life with long lasting effects.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Avoid breathing dust/fume/gas/mist/vapors/spray
Avoid release to the environment.
Wear protective gloves / eye protection / face protection.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Take off contaminated clothing and wash it before reuse.
If skin irritation or rash occurs: Get medical advice/attention.
Specific treatment (see on this label).
If eye irritation persists: Get medical advice/attention.
Wash contaminated clothing before reuse.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
2
1
0
Health = 2
Fire = 1
Reactivity = 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
2
1
0
Health = 2
Fire = 1
Reactivity = 0
(Contd. on page 3)
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(Contd. of page 2)
48.1.41
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 25068-38-6
NLP: 500-033-5
Reaction Product of Bisphenol A and Epichlorohydrin 25- 50%
CAS: 28064-14-4 Epoxy phenol novolac resin
Reaction product of Phenol-Formaldehyde Novolac with Epichlorohydrin
10-20%
CAS: 16096-31-4 1,6-Bis(2,3-epoxypropoxy)hexane 1-5%
CAS: 60506-81-2 Dipentaerythritol Pentaacrylate esters 1-<2.5%
CAS: 26761-45-5
EINECS: 247-979-2
2,3-epoxypropyl neodecanoate 0.1-<0.25%
* 4 First-aid measures
Description of first aid measures
General information:Immediately remove any clothing soiled by the product.
After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing:If symptoms persist consult doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Special hazards arising from the substance or mixtureNo further relevant information available.
(Contd. on page 4)
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(Contd. of page 3)
48.1.41
Advice for firefighters
Protective equipment:Wear self-contained respiratory protective device.
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
* 6 Accidental release measures
Personal precautions, protective equipment and emergency proceduresNot required.
Environmental precautions:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 90 mg/m
28064-14-4 Epoxy phenol novolac resin
Reaction product of Phenol-Formaldehyde Novolac with Epichlorohydrin
30 mg/m
PAC-2:
25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 990 mg/m
28064-14-4 Epoxy phenol novolac resin
Reaction product of Phenol-Formaldehyde Novolac with Epichlorohydrin
330 mg/m
PAC-3:
25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 5,900 mg/m
28064-14-4 Epoxy phenol novolac resin
Reaction product of Phenol-Formaldehyde Novolac with Epichlorohydrin
2,000 mg/m
* 7 Handling and storage
Handling:
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
Information about protection against explosions and fires:No special measures required.
(Contd. on page 5)
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48.1.41
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:Keep receptacle tightly sealed.
Specific end use(s)No further relevant information available.
8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at
the workplace.
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
(Contd. on page 6)
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48.1.41
Eye protection:
Tightly sealed goggles
* 9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Pasty
Color: Grey
Odor: Light
Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range:Undetermined.
Boiling point/Boiling range:>200 C (>392 F)
Flash point: >94 C (>201.2 F)
Flammability (solid, gaseous):Not applicable.
Decomposition temperature: Not determined.
Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: Not determined.
Upper: Not determined.
Vapor pressure: Not determined.
Density at 20 C (68 F): 0.75 g/cm (6.26 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
(Contd. on page 7)
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Kinematic: Not determined.
Solvent content:
Organic solvents: 0.4 %
VOC content: 0.39 %
2.9 g/l / 0.02 lb/gal
Solids content: 39.0 %
Other information No further relevant information available.
* 10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:Carbon monoxide and carbon dioxide
11 Toxicological information
Information on toxicological effects
Acute toxicity:
Primary irritant effect:
on the skin:Irritant to skin and mucous membranes.
on the eye:Irritating effect.
Sensitization:Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Irritant
Carcinogenic categories
IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
US
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12 Ecological information
Toxicity
Aquatic toxicity:No further relevant information available.
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Ecotoxical effects:
Remark:Toxic for fish
Additional ecological information:
General notes:
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic for aquatic organisms
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
* 14 Transport information
UN-Number
DOT not regulated
IMDG, IATA UN3082
UN proper shipping name
DOT not regulated
IMDG, IATA ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (Epoxy phenol novolac resin)
(Contd. on page 9)
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Transport hazard class(es)
DOT
Class not regulated
IMDG
Class 9 Miscellaneous dangerous substances and articles
Label 9
IATA
Class 9 Miscellaneous dangerous substances and articles
Label 9
Packing group
DOT not regulated
IMDG, IATA III
Environmental hazards:
Special marking (IATA): Symbol (fish and tree)
Special precautions for user Warning: Miscellaneous dangerous substances and articles
EMS Number: F-A,S-F
Stowage Category A
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
UN “Model Regulation”: UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LIQUID, N.O.S. (EPOXY PHENOL NOVOLAC RESIN), 9, III
* 15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
(Contd. on page 10)
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Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
TSCA (Toxic Substances Control Act): (Substances not listed)
All ingredients are listed.
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
Hazardous Air Pollutants
None of the ingredients is listed.
Proposition 65
Chemicals known to cause cancer:
1317-65-3 Calcium Carbonate
14808-60-7 Quartz (SiO2)
1333-86-4 Carbon black
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Carcinogenic categories
EPA (Environmental Protection Agency)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS07GHS09
Signal wordWarning
(Contd. on page 11)
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Hazard-determining components of labeling:
Reaction Product of Bisphenol A and Epichlorohydrin
1,6-Bis(2,3-epoxypropoxy)hexane
Dipentaerythritol Pentaacrylate esters
2,3-epoxypropyl neodecanoate
Hazard statements
Causes skin irritation.
Causes serious eye irritation.
May cause an allergic skin reaction.
Toxic to aquatic life.
Toxic to aquatic life with long lasting effects.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Avoid release to the environment.
Wear protective gloves / eye protection / face protection.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Take off contaminated clothing and wash it before reuse.
If skin irritation or rash occurs: Get medical advice/attention.
Specific treatment (see on this label).
If eye irritation persists: Get medical advice/attention.
Wash contaminated clothing before reuse.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision03/22/2019 / 7
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Skin Irrit. 2: Skin corrosion/irritation Category 2
(Contd. on page 12)
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Eye Irrit. 2A: Serious eye damage/eye irritation Category 2A
Skin Sens. 1: Skin sensitisation Category 1
Aquatic Acute 2: Hazardous to the aquatic environment – acute aquatic hazard Category 2
Aquatic Chronic 2: Hazardous to the aquatic environment – long-term aquatic hazard Category 2
* Data compared to the previous version altered.
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* 1 Identification
Product identifier
Trade name: SC180 Hardener Orange
Article number:I026146
Application of the substance / the mixtureEpoxy curing agent
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
advancedresins.ehs@us.sika.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
* 2 Hazard(s) identification
Classification of the substance or mixture
GHS08 Health hazard
STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure.
GHS05 Corrosion
Skin Corr. 1C H314 Causes severe skin burns and eye damage.
Eye Dam. 1 H318 Causes serious eye damage.
GHS07
Acute Tox. 4 H302 Harmful if swallowed.
Skin Sens. 1 H317 May cause an allergic skin reaction.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
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Hazard pictograms
GHS05GHS07GHS08
Signal wordDanger
Hazard-determining components of labeling:
Fatty acids, C18-unsat., dimers, reaction products with polyethylenepolyamines
Cycloaliphatic amine, Proprietary
Benzyl alcohol
tetraethylenepentamine
Tertiary Amine
3,6-diazaoctanethylenediamin
Hazard statements
Harmful if swallowed.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Do not breathe dusts or mists.
Wear protective gloves/protective clothing/eye protection/face protection.
If swallowed: Call a poison center/doctor if you feel unwell.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment (see on this label).
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
3
1
0
Health = 3
Fire = 1
Reactivity = 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
*3
1
0
Health = *3
Fire = 1
Reactivity = 0
(Contd. on page 3)
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Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
* 3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 68410-23-1 Fatty acids, C18-unsat., dimers, reaction products with polyethylenepolyamines 5-<10%
CAS: 100-51-6
EINECS: 202-859-9
Benzyl alcohol 5-10%
Cycloaliphatic amine, Proprietary 3-<5%
CAS: 112-57-2
EINECS: 203-986-2
tetraethylenepentamine 1-<5%
Tertiary Amine 1-<3%
CAS: 112-24-3
EINECS: 203-950-6
3,6-diazaoctanethylenediamin 0.1-<1%
* 4 First-aid measures
Description of first aid measures
General information:
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing:Immediately call a doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
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* 5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Special hazards arising from the substance or mixture
During heating or in case of fire poisonous gases are produced.
Advice for firefighters
Protective equipment:
Mouth respiratory protective device.
Wear self-contained respiratory protective device.
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
* 6 Accidental release measures
Personal precautions, protective equipment and emergency procedures
Mount respiratory protective device.
Wear protective equipment. Keep unprotected persons away.
Environmental precautions:
Dilute with plenty of water.
Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Use neutralizing agent.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
68410-23-1 Fatty acids, C18-unsat., dimers, reaction products with polyethylenepolyamines 30 mg/m
100-51-6 Benzyl alcohol 30 ppm
112-57-2 tetraethylenepentamine 15 mg/m
112-24-3 3,6-diazaoctanethylenediamin 3 ppm
PAC-2:
68410-23-1 Fatty acids, C18-unsat., dimers, reaction products with polyethylenepolyamines 330 mg/m
100-51-6 Benzyl alcohol 52 ppm
112-57-2 tetraethylenepentamine 130 mg/m
112-24-3 3,6-diazaoctanethylenediamin 14 ppm
(Contd. on page 5)
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PAC-3:
68410-23-1 Fatty acids, C18-unsat., dimers, reaction products with polyethylenepolyamines 2,000 mg/m
100-51-6 Benzyl alcohol 740 ppm
112-57-2 tetraethylenepentamine 790 mg/m
112-24-3 3,6-diazaoctanethylenediamin 83 ppm
* 7 Handling and storage
Handling:
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
Information about protection against explosions and fires:Keep respiratory protective device available.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:Keep receptacle tightly sealed.
Specific end use(s)No further relevant information available.
* 8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
The following constituents are the only constituents of the product which have a PEL, TLV or other recommended
exposure limit.
At this time, the other constituents have no known exposure limits.
100-51-6 Benzyl alcohol
WEEL Long-term value: 10 ppm
112-57-2 tetraethylenepentamine
WEEL Long-term value: 5 mg/m
Skin; DSEN
112-24-3 3,6-diazaoctanethylenediamin
WEEL Long-term value: 6 mg/m , 1 ppm
Skin
Additional information:The lists that were valid during the creation were used as basis.
(Contd. on page 6)
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Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Tightly sealed goggles
* 9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Pasty
Color: Orange
Odor: Amine-like
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Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range:Undetermined.
Boiling point/Boiling range:205.4 C (401.7 F)
Flash point: 94 C (201.2 F)
Flammability (solid, gaseous):Not applicable.
Ignition temperature: 435 C (815 F)
Decomposition temperature: Not determined.
Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: Not determined.
Upper: Not determined.
Vapor pressure at 20 C (68 F):1 hPa (0.8 mm Hg)
Density at 20 C (68 F): 0.77 g/cm (6.43 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Fully miscible.
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Solvent content:
Organic solvents: 6.6 %
VOC content: 6.57 %
50.4 g/l / 0.42 lb/gal
Solids content: 53.2 %
Other information No further relevant information available.
* 10 Stability and reactivity
ReactivityNo further relevant information available.
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Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:Carbon monoxide and carbon dioxide
* 11 Toxicological information
Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
25322-69-4 Polypropylene glycol
Oral LD50 541 mg/kg (rat)
Dermal LD50 >10,000 mg/kg (rabbit)
112-57-2 tetraethylenepentamine
Oral LD50 2,140 mg/kg (rat)
Dermal LD50 660 mg/kg (rabbit)
38640-62-9 Diisopropyl naphthalene
Oral LD50 >4,000 mg/kg (mouse)
Dermal LD50 >4,000 mg/kg (rat)
Inhalative LC50/6 h (dynamic) >5.6 mg/l (rat) (Test Guideline 402)
Primary irritant effect:
on the skin:No irritant effect.
on the eye:Strong irritant with the danger of severe eye injury.
Sensitization:Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Harmful
Irritant
Carcinogenic categories
IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
US
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12 Ecological information
Toxicity
Aquatic toxicity:
38640-62-9 Diisopropyl naphthalene
48 hr EC50 0.16 mg/l (daphnia)
96 hr LC50 0.5 mg/l (Fish)
72 or 96 hr ErC50 0.15 mg/l (Algea)
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Additional ecological information:
General notes:
Water hazard class 1 (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
Must not reach bodies of water or drainage ditch undiluted or unneutralized.
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
* 13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
Recommended cleansing agent:Water, if necessary with cleansing agents.
14 Transport information
UN-Number
DOT, ADN, IMDG, IATA not regulated
UN proper shipping name
DOT, ADN, IMDG, IATA not regulated
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Transport hazard class(es)
DOT, ADN, IMDG, IATA
Class not regulated
Packing group
DOT, IMDG, IATA not regulated
Environmental hazards: Not applicable.
Special precautions for user Not applicable.
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
UN “Model Regulation”: not regulated
* 15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
TSCA (Toxic Substances Control Act):
471-34-1 calcium carbonate ACTIVE
25322-69-4 Polypropylene glycol ACTIVE
1317-65-3 Calcium Carbonate ACTIVE
68410-23-1 Fatty acids, C18-unsat., dimers, reaction products with polyethylenepolyamines ACTIVE
100-51-6 Benzyl alcohol ACTIVE
Cycloaliphatic amine, Proprietary ACTIVE
112-57-2 tetraethylenepentamine ACTIVE
38742-70-0 2-Propenoic acid, 2-methyl-, methyl ester, polymer with 2-methyl-2-propenenitrile and 2-
propenenitrile
*
Tertiary Amine ACTIVE
57-11-4 stearic acid, pure ACTIVE
Aromatic amino polyol-Orange ACTIVE
112-24-3 3,6-diazaoctanethylenediamin ACTIVE
78-78-4 isopentane ACTIVE
Organic acid ACTIVE
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38640-62-9 Diisopropyl naphthalene ACTIVE
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
Hazardous Air Pollutants
None of the ingredients is listed.
Proposition 65
Chemicals known to cause cancer:
1317-65-3 Calcium Carbonate
14808-60-7 Quartz (SiO2)
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Carcinogenic categories
EPA (Environmental Protection Agency)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS05GHS07GHS08
Signal wordDanger
Hazard-determining components of labeling:
Fatty acids, C18-unsat., dimers, reaction products with polyethylenepolyamines
Cycloaliphatic amine, Proprietary
Benzyl alcohol
tetraethylenepentamine
Tertiary Amine
(Contd. on page 12)
US
Page 12/12
Safety Data Sheet
acc. to OSHA HCS
Printing date 06/05/2020 Reviewed on 06/05/2020
Trade name: SC180 Hardener Orange
(Contd. of page 11)
51.0.8
3,6-diazaoctanethylenediamin
Hazard statements
Harmful if swallowed.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
Do not breathe dusts or mists.
Wear protective gloves/protective clothing/eye protection/face protection.
If swallowed: Call a poison center/doctor if you feel unwell.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment (see on this label).
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision06/05/2020 / 8
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Acute Tox. 4: Acute toxicity Category 4
Skin Corr. 1C: Skin corrosion/irritation Category 1C
Eye Dam. 1: Serious eye damage/eye irritation Category 1
Skin Sens. 1: Skin sensitisation Category 1
STOT RE 2: Specific target organ toxicity (repeated exposure) Category 2
* Data compared to the previous version altered.
US
80RSC301XB-F_SDS.pdf
80POLYTEX2_SDS.pdf
80LS-19B-G_SDS.pdf
Clear Laminating Hardener
Safety Data Sheet 80LS-19B
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue: 07/13/2015 Revision date: 07/13/2015 Version: 1.0
07/13/2015 EN (English) SDS ID: 80LS-19B Page 1
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product form : Mixture
Trade name : Clear Laminating Hardener
CAS No : Mixture
Product code : 80LS-19B
Other means of identification : DISTRIBUTED BY REVCHEM COMPOSITES, INC
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Clear Laminating Hardener
1.3. Details of the supplier of the safety data sheet
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909.877.8477
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
GHS-US classification
Acute Tox. 4 (Oral) H302
Acute Tox. 4 (Inhalation:gas) H332
Skin Corr. 1B H314
Eye Dam. 1 H318
Skin Sens. 1A H317
Repr. 2 H361
Aquatic Chronic 2 H411
2.2. Label elements
GHS-US labelling
Hazard pictograms (GHS-US) :
GHS05
GHS07
GHS08
GHS09
Signal word (GHS-US) : Danger
Hazard statements (GHS-US) : H302+H332 – Harmful if swallowed or if inhaled
H314 – Causes severe skin burns and eye damage
H317 – May cause an allergic skin reaction
H318 – Causes serious eye damage
H361 – Suspected of damaging fertility or the unborn child
H411 – Toxic to aquatic life with long lasting effects
Precautionary statements (GHS-US) : P201 – Obtain special instructions before use
P202 – Do not handle until all safety precautions have been read and understood
P260 – Do not breathe dust/fume/gas/mist/vapours/spray
P261 – Avoid breathing dust/fume/gas/mist/vapours/spray
P264 – Wash … thoroughly after handling
P270 – Do not eat, drink or smoke when using this product
P271 – Use only outdoors or in a well-ventilated area
P272 – Contaminated work clothing should not be allowed out of the workplace
P273 – Avoid release to the environment
P280 – Wear protective gloves/protective clothing/eye protection/face protection
P301+P312 – IF SWALLOWED: call a POISON CENTER or doctor/physician if you feel unwell
Clear Laminating Hardener
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
07/13/2015 EN (English) SDS ID: 80LS-19B 2/9
P301+P330+P331 – IF SWALLOWED: rinse mouth. Do NOT induce vomiting
P302+P352 – IF ON SKIN: Wash with plenty of soap and water
P303+P361+P353 – IF ON SKIN (or hair): Remove/Take off immediately all contaminated
clothing. Rinse skin with water/shower
P304+P340 – IF INHALED: remove victim to fresh air and keep at rest in a position comfortable
for breathing
P305+P351+P338 – If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P308+P313 – IF exposed or concerned: Get medical advice/attention
P310 – Immediately call a POISON CENTER or doctor/physician
P312 – Call a POISON CENTER or doctor/physician if you feel unwell
P321 – Specific treatment (see … on this label)
P330 – If swallowed, rinse mouth
P333+P313 – If skin irritation or rash occurs: Get medical advice/attention
P362+P364 – Take off contaminated clothing and wash it before reuse
P363 – Wash contaminated clothing before reuse
P391 – Collect spillage
P405 – Store locked up
P501 – Dispose of contents/container to an approved waste disposal plant.
2.3. Other hazards
No additional information available
2.4. Unknown acute toxicity (GHS-US)
No data available
SECTION 3: Composition/information on ingredients
3.1. Substance
Not applicable
Full text of H-phrases: see section 16
3.2. Mixture
Name Product identifier % GHS-US classification
isophorone diamine (CAS No) 2855-13-2 < 35 Acute Tox. 4 (Oral), H302
Skin Corr. 1A, H314
1,3-bis(aminomethyl)cyclohexane (CAS No) 2579-20-6 <= 25 Acute Tox. 4 (Oral), H302
4-tert-butylphenol (CAS No) 98-54-4 < 20 Not classified
benzyl alcohol (CAS No) 100-51-6 < 15 Not classified
CYCLOALIPHATIC AMINE (CAS No) TRADE SECRET < 15 Skin Corr. 1C, H314
Eye Irrit. 2B, H320
Skin Sens. 1, H317
salicylic acid (CAS No) 69-72-7 < 8 Acute Tox. 4 (Oral), H302
SECTION 4: First aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. IF exposed or concerned: Get medical
advice/attention.
First-aid measures after inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a
POISON CENTER or doctor/physician if you feel unwell. Immediately call a POISON CENTER or
doctor/physician.
First-aid measures after skin contact : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
Immediately call a POISON CENTER or doctor/physician.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Call a POISON CENTER or doctor/physician if you feel
unwell. Immediately call a POISON CENTER or doctor/physician.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries : Causes severe skin burns and eye damage. Suspected of damaging fertility or the unborn child.
Symptoms/injuries after inhalation : Harmful if inhaled. Danger of serious damage to health by prolonged exposure through
inhalation.
Symptoms/injuries after skin contact : Causes skin irritation. Caustic burns/corrosion of the skin.
Symptoms/injuries after eye contact : Causes eye irritation. May cause severe irritation. Causes serious eye damage.
Symptoms/injuries after ingestion : Swallowing a small quantity of this material will result in serious health hazard.
Clear Laminating Hardener
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
07/13/2015 EN (English) SDS ID: 80LS-19B 3/9
4.3. Indication of any immediate medical attention and special treatment needed
Until victim can be cared for by specialized staff:
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Heating increases the fire hazard. Heating may cause a fire. Heating may cause a fire or
explosion. Insufficient data available on direct fire hazard (flashpoint > 100 C). Self-heating in
large quantities; may catch fire. Temperature above flashpoint: higher fire/explosion hazard.
Reactivity : Thermal decomposition generates : Corrosive vapours.
5.3. Advice for firefighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect
spillage. Store away from other materials.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Provide good ventilation in process area to prevent formation of
vapour. Use only outdoors or in a well-ventilated area. Avoid breathing
dust/fume/gas/mist/vapours/spray. Do not breathe dust/fume/gas/mist/vapours/spray. Obtain
special instructions before use. Do not handle until all safety precautions have been read and
understood.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash … thoroughly after handling. Wash
contaminated clothing before reuse.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Comply with applicable regulations.
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Keep container
closed when not in use.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight.
7.3. Specific end use(s)
No additional information available
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
No additional information available
Clear Laminating Hardener
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
07/13/2015 EN (English) SDS ID: 80LS-19B 4/9
8.2. Exposure controls
Personal protective equipment : Avoid all unnecessary exposure.
Hand protection : Wear protective gloves.
Eye protection : Chemical goggles or face shield.
Skin and body protection : Wear suitable protective clothing.
Respiratory protection : Wear appropriate mask.
Other information : Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Appearance : Clear, colorless liquid.
Colour : clear.
Odour : characteristic.
Odour threshold : No data available
pH : No data available
Relative evaporation rate (butylacetate=1) : No data available
Relative evaporation rate (ether=1) : < 1 slower than ether Melting point : No data available Freezing point : No data available Boiling point : 140 - 152 C Initial Boiling Point for Styrene @ 760.00 mm Hg Flash point : 110 C for Volatile Component (230 Deg F) Auto-ignition temperature : No data available Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapour pressure : 4.3 mm Hg Relative vapour density at 20 C : No data available Relative density : No data available Density : 1.002 g/l Solubility : No data available Log Pow : No data available Log Kow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosive properties : No data available Oxidising properties : No data available Explosive limits : No data available 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity Thermal decomposition generates : Corrosive vapours. 10.2. Chemical stability Stable under normal conditions. Not established. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. 10.5. Incompatible materials Strong acids. Strong bases. Clear Laminating Hardener Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 07/13/2015 EN (English) SDS ID: 80LS-19B 5/9 10.6. Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. Thermal decomposition generates : Corrosive vapours. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Harmful if swallowed. Harmful if inhaled. Clear Laminating Hardener ( f )Mixture ATE CLP (oral) 500.000 mg/kg bodyweight ATE CLP (dermal) 1100.000 mg/kg bodyweight 1,3-bis(aminomethyl)cyclohexane (2579-20-6) LD50 oral rat 880 mg/kg (Rat) ATE CLP (oral) 880.000 mg/kg bodyweight 4-tert-butylphenol (98-54-4) LD50 oral rat 3370 mg/kg (Rat) LD50 dermal rabbit 2621 mg/kg (Rabbit) LC50 inhalation rat (mg/l) > 5.6 mg/l/4h (Rat)
isophorone diamine (2855-13-2)
LD50 oral rat 1030 mg/kg (Rat; OECD 401: Acute Oral Toxicity; Experimental value)
LD50 dermal rat > 2000 mg/kg bodyweight (Rat; Experimental value; OECD 402: Acute Dermal Toxicity)
LC50 inhalation rat (mg/l) > 5.01 mg/l/4h (Rat; Experimental value)
benzyl alcohol (100-51-6)
LD50 oral rat 1620 mg/kg bw/day (Rat; Experimental value)
LD50 dermal rabbit > 2000 mg/kg (Rabbit; Experimental value)
salicylic acid (69-72-7)
LD50 oral rat 891 mg/kg bodyweight (Rat; OECD 401: Acute Oral Toxicity; Experimental value)
LD50 dermal rat > 2000 mg/kg (Rat)
LD50 dermal rabbit > 10000 mg/kg (Rabbit)
Skin corrosion/irritation : Causes severe skin burns and eye damage.
Serious eye damage/irritation : Causes serious eye damage.
Respiratory or skin sensitisation : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified
Based on available data, the classification criteria are not met
Carcinogenicity : Not classified
Reproductive toxicity : Suspected of damaging fertility or the unborn child.
Based on available data, the classification criteria are not met
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated
exposure)
: Not classified
Based on available data, the classification criteria are not met
Aspiration hazard : Not classified
Based on available data, the classification criteria are not met
Potential adverse human health effects and
symptoms
: Based on available data, the classification criteria are not met. Harmful if swallowed. Harmful if
inhaled.
Symptoms/injuries after inhalation : Harmful if inhaled. Danger of serious damage to health by prolonged exposure through
inhalation.
Symptoms/injuries after skin contact : Causes skin irritation. Caustic burns/corrosion of the skin.
Symptoms/injuries after eye contact : Causes eye irritation. May cause severe irritation. Causes serious eye damage.
Symptoms/injuries after ingestion : Swallowing a small quantity of this material will result in serious health hazard.
Likely routes of exposure : Inhalation
Clear Laminating Hardener
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
07/13/2015 EN (English) SDS ID: 80LS-19B 6/9
SECTION 12: Ecological information
12.1. Toxicity
Ecology – water : Toxic to aquatic life with long lasting effects.
1,3-bis(aminomethyl)cyclohexane (2579-20-6)
LC50 fish 1 130 mg/l (96 h; Leuciscus idus; GLP)
EC50 Daphnia 1 65.4 mg/l (48 h; Daphnia magna; GLP)
Threshold limit algae 1 56.7 mg/l (72 h; Pseudokirchneriella subcapitata; Growth rate)
Threshold limit algae 2 13.7 mg/l (72 h; Pseudokirchneriella subcapitata; Growth rate)
4-tert-butylphenol (98-54-4)
LC50 fish 1 1.6 mg/l (48 h; Leuciscus idus; Measured concentration)
EC50 Daphnia 1 3.9 mg/l (48 h; Daphnia magna)
LC50 fish 2 5.14 mg/l (96 h; Pimephales promelas)
EC50 Daphnia 2 4.8 mg/l (24 h; Daphnia magna)
Threshold limit algae 1 > 10 mg/l (Scenedesmus quadricauda)
Threshold limit algae 2 11.2 mg/l (72 h; Scenedesmus subspicatus; Growth rate)
isophorone diamine (2855-13-2)
LC50 fish 1 110 mg/l (96 h; Brachydanio rerio; GLP)
EC50 Daphnia 1 42 – 44 mg/l (24 h; Daphnia magna; GLP)
LC50 fish 2 110 mg/l (96 h; Leuciscus idus; GLP)
EC50 Daphnia 2 23 mg/l (48 h; Daphnia magna)
Threshold limit algae 1 1.5 mg/l (72 h; Scenedesmus subspicatus)
Threshold limit algae 2 10.14 mg/l (Algae)
benzyl alcohol (100-51-6)
LC50 fish 1 460 mg/l (96 h; Pimephales promelas; Nominal concentration)
EC50 Daphnia 1 400 mg/l (48 h; Daphnia magna; GLP)
LC50 fish 2 10 ppm (96 h; Lepomis macrochirus)
EC50 Daphnia 2 230 mg/l (48 h; Daphnia magna)
Threshold limit other aquatic organisms 1 < 658 mg/l (16 h; Pseudomonas putida)
Threshold limit algae 1 640 ppm (96 h; Scenedesmus quadricauda)
Threshold limit algae 2 2600 mg/l (72 h; Algae)
salicylic acid (69-72-7)
LC50 fish 1 90 mg/l (48 h; Leuciscus idus)
EC50 Daphnia 1 105 - 180 mg/l (24 h; Daphnia magna; Nominal concentration)
EC50 Daphnia 2 230 mg/l (24 h; Daphnia magna)
Threshold limit algae 1 > 100 mg/l (72 h; Desmodesmus subspicatus)
12.2. Persistence and degradability
Clear Laminating Hardener (Mixture)
Persistence and degradability May cause long-term adverse effects in the environment.
1,3-bis(aminomethyl)cyclohexane (2579-20-6)
Persistence and degradability Not readily biodegradable in water. Biodegradability in soil: no data available. Not established.
4-tert-butylphenol (98-54-4)
Persistence and degradability Readily biodegradable in water. Photolysis in the air.
ThOD 2.77 g O /g substance
isophorone diamine (2855-13-2)
Persistence and degradability Not readily biodegradable in water. Low potential for adsorption in soil.
benzyl alcohol (100-51-6)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. No (test)data on mobility of the
substance available.
Biochemical oxygen demand (BOD) 1.6 g O /g substance
Chemical oxygen demand (COD) 2.4 g O /g substance
ThOD 2.5 g O /g substance
Clear Laminating Hardener
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
07/13/2015 EN (English) SDS ID: 80LS-19B 7/9
salicylic acid (69-72-7)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil.
Biochemical oxygen demand (BOD) 0.95 g O /g substance
Chemical oxygen demand (COD) 1.58 g O /g substance
ThOD 1.623 g O /g substance
BOD (% of ThOD) 0.41 – 0.60 % ThOD
CYCLOALIPHATIC AMINE (TRADE SECRET)
Persistence and degradability Not established.
12.3. Bioaccumulative potential
Clear Laminating Hardener (Mixture)
Bioaccumulative potential Not established.
1,3-bis(aminomethyl)cyclohexane (2579-20-6)
Log Pow 0.69 – 0.78 (Experimental value; OECD 107: Partition Coefficient (n-octanol/water): Shake
Flask Method; 21.5 – 24.7 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
4-tert-butylphenol (98-54-4)
BCF fish 1 120 (3 h; Leuciscus idus)
BCF fish 2 20 - 88 (Cyprinus carpio; Test duration: 8 weeks)
BCF other aquatic organisms 1 34 (24 h; Chlorella sp.; Fresh weight)
BCF other aquatic organisms 2 240 (5 h; Bacteria; Activated sludge)
Log Pow 3.29 (OECD 107: Partition Coefficient (n-octanol/water): Shake Flask Method)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).
isophorone diamine (2855-13-2)
Log Pow 0.99 (Experimental value; OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method; 23 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
benzyl alcohol (100-51-6)
Log Pow 1.05 (Experimental value; Other; 20 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
salicylic acid (69-72-7)
BCF other aquatic organisms 1 > 1000 (96 h; Scenedesmus subspicatus)
Log Pow 2.25 (Experimental value; Equivalent or similar to OECD 117; 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
CYCLOALIPHATIC AMINE (TRADE SECRET)
Bioaccumulative potential Not established.
12.4. Mobility in soil
benzyl alcohol (100-51-6)
Surface tension 0.04 N/m (20 C)
12.5. Other adverse effects
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to an approved waste disposal plant.
Ecology - waste materials : Avoid release to the environment.
SECTION 14: Transport information
In accordance with DOT
UN-No.(DOT) : 2735
Proper Shipping Name (DOT) : UN2735, AMINES, LIQUID, CORROSIVE, N.O.S. (CYCLOALIPHATIC AMINES )
Clear Laminating Hardener
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
07/13/2015 EN (English) SDS ID: 80LS-19B 8/9
Hazard Classes (DOT) : 8 - Class 8 - Corrosive material 49 CFR 173.136
Packing group (DOT) : II - Medium Danger
Additional information
Other information : No supplementary information available.
Transport by sea
UN-No.(IMDG) : 2735
Proper Shipping Name (IMDG) : UN2735, AMINES, LIQUID, CORROSIVE, N.O.S. (CYCLOALIPHATIC AMINES )
Hazard Classes (IMDG) : 8 - Class 8 - Corrosive material 49 CFR 173.136
Packing group (IMDG) : II - Medium Danger
Air transport
UN-No.(IATA) : 2735
Proper Shipping Name (IATA) : UN2735, AMINES, LIQUID, CORROSIVE, N.O.S. (CYCLOALIPHATIC AMINES )
Hazard Classes (IATA) : 8 - Class 8 - Corrosive material 49 CFR 173.136
Packing group (IATA) : II - Medium Danger
SECTION 15: Regulatory information
15.1. US Federal regulations
Clear Laminating Hardener (Mixture)
SARA Section 311/312 Hazard Classes Delayed (chronic) health hazard
15.2. International regulations
CANADA
No additional information available
EU-Regulations
No additional information available
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute Tox. 4 (Oral) H302
Acute Tox. 4 (Dermal) H312
Skin Corr. 1B H314
Skin Sens. 1 H317
Aquatic Chronic 3 H412
Full text of H-phrases: see section 16
Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]
Xn; R21/22
C; R34
R43
R52/53
Full text of R-phrases: see section 16
15.2.2. National regulations
No additional information available
15.3. US State regulations
No additional information available
Clear Laminating Hardener
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
07/13/2015 EN (English) SDS ID: 80LS-19B 9/9
SECTION 16: Other information
Other information : None.
Full text of H-phrases: see section 16:
------ Acute Tox. 4 (Inhalation:gas) Acute toxicity (inhalation:gas) Category 4
------ Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4
------ Aquatic Chronic 2 Hazardous to the aquatic environment Chronic Hazard, Category
2
------ Eye Dam. 1 Serious eye damage/eye irritation, Category 1
------ Eye Irrit. 2B Serious eye damage/eye irritation, Category 2B
------ Repr. 2 Reproductive toxicity, Category 2
------ Skin Corr. 1A Skin corrosion/irritation, Category 1A
------ Skin Corr. 1B Skin corrosion/irritation, Category 1B
------ Skin Corr. 1C Skin corrosion/irritation, Category 1C
------ Skin Sens. 1 Sensitisation Skin, category 1
------ Skin Sens. 1A Sensitisation Skin, category 1A
------ H302 Harmful if swallowed
------ H314 Causes severe skin burns and eye damage
------ H317 May cause an allergic skin reaction
------ H318 Causes serious eye damage
------ H320 Causes eye irritation
------ H332 Harmful if inhaled
------ H361 Suspected of damaging fertility or the unborn child
------ H411 Toxic to aquatic life with long lasting effects
SDS US (GHS HazCom 2012)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied
warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.
80NPPN638_SDS.pdf
Safety Data Sheet
Page 1/5
NAN YA
Ident No.PN638 Revision:2017/05/31
1. IDENTIFICATION OF THE PRODUCT AND OF THE COMPANY
Trade name:
NPPN-638
Company identification:
NAN YA Plastics Corporation
201, Tung Hwa North Road, Taipei, Taiwan, R.O.C.
Telephone: 886-2-27178258
Telefax: 886-2-27182258
Emergency telephone: 886-2-26806311 EXT2724
2. HAZARDS IDENTIFICATION OF THE PRODUCT
GHS Classification
Skin corrosion/irritation: Category 3
Serious eye damage/eye irritation: Category 2B
Skin sensitizer: Category 1
Hazard Symbol:
Signal Word: WARNING
Hazard Statements:
H316 Cause mild skin irritating.
H320 Cause eye irritating.
H317 May cause allergic skin reaction.
Precautionary Statements:
P280 Wear protective gloves/clothing and eye/face protection.
P332+P337+P352+P313 If skin/eyes irritation occurs, wash with plenty of
soap and water and get medical advice/attention.
P404+P403 Store container tightly closed in well-ventilated place.
3. COMPOSITION / INFORMATION OF INGREDIENTS
Ingredients CAS No. Concentration
Phenolic novolac type epoxy resin 28064-14-4 >99.9%
4. FIRST AID MEASURES
After skin contact:
Rinse with plenty of water and soap.
After eye contact:
Rinse immediately with plenty of water for at least 15 minutes, and seek medical
advice.
After inhalation:
Safety Data Sheet
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NAN YA
Ident No.PN638 Revision:2017/05/31
Move to fresh air. Seek medical advice if symptoms persist.
After ingestion:
Do not vomiting; instantly seek medical advice.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media:
Foam, dry powder, carbon dioxide, water spray jet.
Unsuitable extinguishing media:
High pressure water jet.
Special protective equipment for firefighters:
Wear self-contained breathing apparatus.
Wear protective equipment.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions
Keep away ignition sources.
Wear suitable protective equipment.
Environmental precautions
Do not allow to enter drainage system, surface or ground water.
Method for cleaning up
Sweep and scrape into container for proper disposal.
7. HANDLING AND STORAGE
Handing:
Ensure good ventilation/suction at the workplace.
Avoid open flames and sources of ignition.
Storage:
Keep away from food and drink.
Keep container tightly sealed.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering controls:
Ensure for good ventilation/suction.
Control parameters:
None
Personal protection equipment
Respiratory protection: suitable breathing mask when there is inadequate
ventilation.
Hand protection: suitable protective gloves.
Eye protection: protective goggles.
Skin and body protection: suitable protective clothes.
Safety Data Sheet
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Ident No.PN638 Revision:2017/05/31
9. PHYSISCAL AND CHEMICAL PROPERTIES
a)Appearance Semi-solid
b)Color Yellow or brown
c)Odor Not applicable
d)pH Not applicable
e)Melting point No data available
f)Boiling point Not applicable
g)Flash point >150
h)Evaporation rate Not applicable
i)Flammability (solid, gas) No data available
j)Explosive limits Not applicable
k)Vapor pressure Not applicable
l)Vapor density Not applicable
m)Relative density (20 ) 1.21~1.23g/cm
3
n)Solubility (20 ) practically insoluble in water
o)Partition coefficient Not applicable
p)Auto-ignition temperature Not applicable
q)Decomposition temperature Not applicable
10. STABILITY AND REACTIVITY
Conditions to avoid:
Avoid static electricity discharge.
Material to avoid:
Strong acid, strong base, strong oxidizer and amines.
Hazardous decomposition products
In fire toxic fumes may be generated.
11. TOXICOLOGICAL INFORMATION
Ingestion:
Acute oral toxicity: LD50 10000~11400mg/kg body weight.
Skin contact:
Safety Data Sheet
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NAN YA
Ident No.PN638 Revision:2017/05/31
Irritating.
Eye contact:
Irritating.
12. ECOLOGICAL INFORMATION
Biological degradability :
Not readily biodegradable.
Bioaccumulation :
No information available.
Ecotoxicity :
No information available.
13. DISPOSAL CONSIDERATIONS
Dispose of according to regulations.
14. TRANSPORT INFORMATION
Transport over land ADR/RID
UN Number:-
Proper Shipping Name: –
Class:- Packing group:-
Transport over sea IMDG
Class:- Packing group:-
Transport by air ICAO/IATA
Class:- Packing group:-
15. REGULATORY INFORMATIONS
Hazard label:-
R phrase :-
S phrase :S26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
S28 After contact with skin, wash immediately with plenty of
water and soap.
S37/39 wear suitable gloves and eye/face protection.
16. OTHER INFORMATION
This information is based on our current level of knowledge and relates to the
Safety Data Sheet
Page 5/5
NAN YA
Ident No.PN638 Revision:2017/05/31
products in the states in which it is delivered. It is intended to describe our products
from the point of view of safety requirements and is not intended to guarantee any
particular properties.
80LS-19B-F_SDS.pdf
Clear Laminating Hardener
Safety Data Sheet 80LS-19B
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue: 07/13/2015 Revision date: 07/13/2015 Version: 1.0
07/13/2015 EN (English) SDS ID: 80LS-19B Page 1
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product form : Mixture
Trade name : Clear Laminating Hardener
CAS No : Mixture
Product code : 80LS-19B
Other means of identification : DISTRIBUTED BY REVCHEM COMPOSITES, INC
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Clear Laminating Hardener
1.3. Details of the supplier of the safety data sheet
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909.877.8477
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
GHS-US classification
Acute Tox. 4 (Oral) H302
Acute Tox. 4 (Inhalation:gas) H332
Skin Corr. 1B H314
Eye Dam. 1 H318
Skin Sens. 1A H317
Repr. 2 H361
Aquatic Chronic 2 H411
2.2. Label elements
GHS-US labelling
Hazard pictograms (GHS-US) :
GHS05
GHS07
GHS08
GHS09
Signal word (GHS-US) : Danger
Hazard statements (GHS-US) : H302+H332 – Harmful if swallowed or if inhaled
H314 – Causes severe skin burns and eye damage
H317 – May cause an allergic skin reaction
H318 – Causes serious eye damage
H361 – Suspected of damaging fertility or the unborn child
H411 – Toxic to aquatic life with long lasting effects
Precautionary statements (GHS-US) : P201 – Obtain special instructions before use
P202 – Do not handle until all safety precautions have been read and understood
P260 – Do not breathe dust/fume/gas/mist/vapours/spray
P261 – Avoid breathing dust/fume/gas/mist/vapours/spray
P264 – Wash … thoroughly after handling
P270 – Do not eat, drink or smoke when using this product
P271 – Use only outdoors or in a well-ventilated area
P272 – Contaminated work clothing should not be allowed out of the workplace
P273 – Avoid release to the environment
P280 – Wear protective gloves/protective clothing/eye protection/face protection
P301+P312 – IF SWALLOWED: call a POISON CENTER or doctor/physician if you feel unwell
Clear Laminating Hardener
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
07/13/2015 EN (English) SDS ID: 80LS-19B 2/9
P301+P330+P331 – IF SWALLOWED: rinse mouth. Do NOT induce vomiting
P302+P352 – IF ON SKIN: Wash with plenty of soap and water
P303+P361+P353 – IF ON SKIN (or hair): Remove/Take off immediately all contaminated
clothing. Rinse skin with water/shower
P304+P340 – IF INHALED: remove victim to fresh air and keep at rest in a position comfortable
for breathing
P305+P351+P338 – If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P308+P313 – IF exposed or concerned: Get medical advice/attention
P310 – Immediately call a POISON CENTER or doctor/physician
P312 – Call a POISON CENTER or doctor/physician if you feel unwell
P321 – Specific treatment (see … on this label)
P330 – If swallowed, rinse mouth
P333+P313 – If skin irritation or rash occurs: Get medical advice/attention
P362+P364 – Take off contaminated clothing and wash it before reuse
P363 – Wash contaminated clothing before reuse
P391 – Collect spillage
P405 – Store locked up
P501 – Dispose of contents/container to an approved waste disposal plant.
2.3. Other hazards
No additional information available
2.4. Unknown acute toxicity (GHS-US)
No data available
SECTION 3: Composition/information on ingredients
3.1. Substance
Not applicable
Full text of H-phrases: see section 16
3.2. Mixture
Name Product identifier % GHS-US classification
isophorone diamine (CAS No) 2855-13-2 < 35 Acute Tox. 4 (Oral), H302
Skin Corr. 1A, H314
1,3-bis(aminomethyl)cyclohexane (CAS No) 2579-20-6 <= 25 Acute Tox. 4 (Oral), H302
4-tert-butylphenol (CAS No) 98-54-4 < 20 Not classified
benzyl alcohol (CAS No) 100-51-6 < 15 Not classified
CYCLOALIPHATIC AMINE (CAS No) TRADE SECRET < 15 Skin Corr. 1C, H314
Eye Irrit. 2B, H320
Skin Sens. 1, H317
salicylic acid (CAS No) 69-72-7 < 8 Acute Tox. 4 (Oral), H302
SECTION 4: First aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. IF exposed or concerned: Get medical
advice/attention.
First-aid measures after inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a
POISON CENTER or doctor/physician if you feel unwell. Immediately call a POISON CENTER or
doctor/physician.
First-aid measures after skin contact : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
Immediately call a POISON CENTER or doctor/physician.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Call a POISON CENTER or doctor/physician if you feel
unwell. Immediately call a POISON CENTER or doctor/physician.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries : Causes severe skin burns and eye damage. Suspected of damaging fertility or the unborn child.
Symptoms/injuries after inhalation : Harmful if inhaled. Danger of serious damage to health by prolonged exposure through
inhalation.
Symptoms/injuries after skin contact : Causes skin irritation. Caustic burns/corrosion of the skin.
Symptoms/injuries after eye contact : Causes eye irritation. May cause severe irritation. Causes serious eye damage.
Symptoms/injuries after ingestion : Swallowing a small quantity of this material will result in serious health hazard.
Clear Laminating Hardener
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
07/13/2015 EN (English) SDS ID: 80LS-19B 3/9
4.3. Indication of any immediate medical attention and special treatment needed
Until victim can be cared for by specialized staff:
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Heating increases the fire hazard. Heating may cause a fire. Heating may cause a fire or
explosion. Insufficient data available on direct fire hazard (flashpoint > 100 C). Self-heating in
large quantities; may catch fire. Temperature above flashpoint: higher fire/explosion hazard.
Reactivity : Thermal decomposition generates : Corrosive vapours.
5.3. Advice for firefighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect
spillage. Store away from other materials.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Provide good ventilation in process area to prevent formation of
vapour. Use only outdoors or in a well-ventilated area. Avoid breathing
dust/fume/gas/mist/vapours/spray. Do not breathe dust/fume/gas/mist/vapours/spray. Obtain
special instructions before use. Do not handle until all safety precautions have been read and
understood.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash … thoroughly after handling. Wash
contaminated clothing before reuse.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Comply with applicable regulations.
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Keep container
closed when not in use.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight.
7.3. Specific end use(s)
No additional information available
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
No additional information available
Clear Laminating Hardener
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
07/13/2015 EN (English) SDS ID: 80LS-19B 4/9
8.2. Exposure controls
Personal protective equipment : Avoid all unnecessary exposure.
Hand protection : Wear protective gloves.
Eye protection : Chemical goggles or face shield.
Skin and body protection : Wear suitable protective clothing.
Respiratory protection : Wear appropriate mask.
Other information : Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Appearance : Clear, colorless liquid.
Colour : clear.
Odour : characteristic.
Odour threshold : No data available
pH : No data available
Relative evaporation rate (butylacetate=1) : No data available
Relative evaporation rate (ether=1) : < 1 slower than ether Melting point : No data available Freezing point : No data available Boiling point : 140 - 152 C Initial Boiling Point for Styrene @ 760.00 mm Hg Flash point : 110 C for Volatile Component (230 Deg F) Auto-ignition temperature : No data available Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapour pressure : 4.3 mm Hg Relative vapour density at 20 C : No data available Relative density : No data available Density : 1.002 g/l Solubility : No data available Log Pow : No data available Log Kow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosive properties : No data available Oxidising properties : No data available Explosive limits : No data available 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity Thermal decomposition generates : Corrosive vapours. 10.2. Chemical stability Stable under normal conditions. Not established. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. 10.5. Incompatible materials Strong acids. Strong bases. Clear Laminating Hardener Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 07/13/2015 EN (English) SDS ID: 80LS-19B 5/9 10.6. Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. Thermal decomposition generates : Corrosive vapours. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Harmful if swallowed. Harmful if inhaled. Clear Laminating Hardener ( f )Mixture ATE CLP (oral) 500.000 mg/kg bodyweight ATE CLP (dermal) 1100.000 mg/kg bodyweight 1,3-bis(aminomethyl)cyclohexane (2579-20-6) LD50 oral rat 880 mg/kg (Rat) ATE CLP (oral) 880.000 mg/kg bodyweight 4-tert-butylphenol (98-54-4) LD50 oral rat 3370 mg/kg (Rat) LD50 dermal rabbit 2621 mg/kg (Rabbit) LC50 inhalation rat (mg/l) > 5.6 mg/l/4h (Rat)
isophorone diamine (2855-13-2)
LD50 oral rat 1030 mg/kg (Rat; OECD 401: Acute Oral Toxicity; Experimental value)
LD50 dermal rat > 2000 mg/kg bodyweight (Rat; Experimental value; OECD 402: Acute Dermal Toxicity)
LC50 inhalation rat (mg/l) > 5.01 mg/l/4h (Rat; Experimental value)
benzyl alcohol (100-51-6)
LD50 oral rat 1620 mg/kg bw/day (Rat; Experimental value)
LD50 dermal rabbit > 2000 mg/kg (Rabbit; Experimental value)
salicylic acid (69-72-7)
LD50 oral rat 891 mg/kg bodyweight (Rat; OECD 401: Acute Oral Toxicity; Experimental value)
LD50 dermal rat > 2000 mg/kg (Rat)
LD50 dermal rabbit > 10000 mg/kg (Rabbit)
Skin corrosion/irritation : Causes severe skin burns and eye damage.
Serious eye damage/irritation : Causes serious eye damage.
Respiratory or skin sensitisation : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified
Based on available data, the classification criteria are not met
Carcinogenicity : Not classified
Reproductive toxicity : Suspected of damaging fertility or the unborn child.
Based on available data, the classification criteria are not met
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated
exposure)
: Not classified
Based on available data, the classification criteria are not met
Aspiration hazard : Not classified
Based on available data, the classification criteria are not met
Potential adverse human health effects and
symptoms
: Based on available data, the classification criteria are not met. Harmful if swallowed. Harmful if
inhaled.
Symptoms/injuries after inhalation : Harmful if inhaled. Danger of serious damage to health by prolonged exposure through
inhalation.
Symptoms/injuries after skin contact : Causes skin irritation. Caustic burns/corrosion of the skin.
Symptoms/injuries after eye contact : Causes eye irritation. May cause severe irritation. Causes serious eye damage.
Symptoms/injuries after ingestion : Swallowing a small quantity of this material will result in serious health hazard.
Likely routes of exposure : Inhalation
Clear Laminating Hardener
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
07/13/2015 EN (English) SDS ID: 80LS-19B 6/9
SECTION 12: Ecological information
12.1. Toxicity
Ecology – water : Toxic to aquatic life with long lasting effects.
1,3-bis(aminomethyl)cyclohexane (2579-20-6)
LC50 fish 1 130 mg/l (96 h; Leuciscus idus; GLP)
EC50 Daphnia 1 65.4 mg/l (48 h; Daphnia magna; GLP)
Threshold limit algae 1 56.7 mg/l (72 h; Pseudokirchneriella subcapitata; Growth rate)
Threshold limit algae 2 13.7 mg/l (72 h; Pseudokirchneriella subcapitata; Growth rate)
4-tert-butylphenol (98-54-4)
LC50 fish 1 1.6 mg/l (48 h; Leuciscus idus; Measured concentration)
EC50 Daphnia 1 3.9 mg/l (48 h; Daphnia magna)
LC50 fish 2 5.14 mg/l (96 h; Pimephales promelas)
EC50 Daphnia 2 4.8 mg/l (24 h; Daphnia magna)
Threshold limit algae 1 > 10 mg/l (Scenedesmus quadricauda)
Threshold limit algae 2 11.2 mg/l (72 h; Scenedesmus subspicatus; Growth rate)
isophorone diamine (2855-13-2)
LC50 fish 1 110 mg/l (96 h; Brachydanio rerio; GLP)
EC50 Daphnia 1 42 – 44 mg/l (24 h; Daphnia magna; GLP)
LC50 fish 2 110 mg/l (96 h; Leuciscus idus; GLP)
EC50 Daphnia 2 23 mg/l (48 h; Daphnia magna)
Threshold limit algae 1 1.5 mg/l (72 h; Scenedesmus subspicatus)
Threshold limit algae 2 10.14 mg/l (Algae)
benzyl alcohol (100-51-6)
LC50 fish 1 460 mg/l (96 h; Pimephales promelas; Nominal concentration)
EC50 Daphnia 1 400 mg/l (48 h; Daphnia magna; GLP)
LC50 fish 2 10 ppm (96 h; Lepomis macrochirus)
EC50 Daphnia 2 230 mg/l (48 h; Daphnia magna)
Threshold limit other aquatic organisms 1 < 658 mg/l (16 h; Pseudomonas putida)
Threshold limit algae 1 640 ppm (96 h; Scenedesmus quadricauda)
Threshold limit algae 2 2600 mg/l (72 h; Algae)
salicylic acid (69-72-7)
LC50 fish 1 90 mg/l (48 h; Leuciscus idus)
EC50 Daphnia 1 105 - 180 mg/l (24 h; Daphnia magna; Nominal concentration)
EC50 Daphnia 2 230 mg/l (24 h; Daphnia magna)
Threshold limit algae 1 > 100 mg/l (72 h; Desmodesmus subspicatus)
12.2. Persistence and degradability
Clear Laminating Hardener (Mixture)
Persistence and degradability May cause long-term adverse effects in the environment.
1,3-bis(aminomethyl)cyclohexane (2579-20-6)
Persistence and degradability Not readily biodegradable in water. Biodegradability in soil: no data available. Not established.
4-tert-butylphenol (98-54-4)
Persistence and degradability Readily biodegradable in water. Photolysis in the air.
ThOD 2.77 g O /g substance
isophorone diamine (2855-13-2)
Persistence and degradability Not readily biodegradable in water. Low potential for adsorption in soil.
benzyl alcohol (100-51-6)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. No (test)data on mobility of the
substance available.
Biochemical oxygen demand (BOD) 1.6 g O /g substance
Chemical oxygen demand (COD) 2.4 g O /g substance
ThOD 2.5 g O /g substance
Clear Laminating Hardener
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
07/13/2015 EN (English) SDS ID: 80LS-19B 7/9
salicylic acid (69-72-7)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil.
Biochemical oxygen demand (BOD) 0.95 g O /g substance
Chemical oxygen demand (COD) 1.58 g O /g substance
ThOD 1.623 g O /g substance
BOD (% of ThOD) 0.41 – 0.60 % ThOD
CYCLOALIPHATIC AMINE (TRADE SECRET)
Persistence and degradability Not established.
12.3. Bioaccumulative potential
Clear Laminating Hardener (Mixture)
Bioaccumulative potential Not established.
1,3-bis(aminomethyl)cyclohexane (2579-20-6)
Log Pow 0.69 – 0.78 (Experimental value; OECD 107: Partition Coefficient (n-octanol/water): Shake
Flask Method; 21.5 – 24.7 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
4-tert-butylphenol (98-54-4)
BCF fish 1 120 (3 h; Leuciscus idus)
BCF fish 2 20 - 88 (Cyprinus carpio; Test duration: 8 weeks)
BCF other aquatic organisms 1 34 (24 h; Chlorella sp.; Fresh weight)
BCF other aquatic organisms 2 240 (5 h; Bacteria; Activated sludge)
Log Pow 3.29 (OECD 107: Partition Coefficient (n-octanol/water): Shake Flask Method)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).
isophorone diamine (2855-13-2)
Log Pow 0.99 (Experimental value; OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method; 23 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
benzyl alcohol (100-51-6)
Log Pow 1.05 (Experimental value; Other; 20 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
salicylic acid (69-72-7)
BCF other aquatic organisms 1 > 1000 (96 h; Scenedesmus subspicatus)
Log Pow 2.25 (Experimental value; Equivalent or similar to OECD 117; 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
CYCLOALIPHATIC AMINE (TRADE SECRET)
Bioaccumulative potential Not established.
12.4. Mobility in soil
benzyl alcohol (100-51-6)
Surface tension 0.04 N/m (20 C)
12.5. Other adverse effects
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to an approved waste disposal plant.
Ecology - waste materials : Avoid release to the environment.
SECTION 14: Transport information
In accordance with DOT
UN-No.(DOT) : 2735
Proper Shipping Name (DOT) : UN2735, AMINES, LIQUID, CORROSIVE, N.O.S. (CYCLOALIPHATIC AMINES )
Clear Laminating Hardener
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
07/13/2015 EN (English) SDS ID: 80LS-19B 8/9
Hazard Classes (DOT) : 8 - Class 8 - Corrosive material 49 CFR 173.136
Packing group (DOT) : II - Medium Danger
Additional information
Other information : No supplementary information available.
Transport by sea
UN-No.(IMDG) : 2735
Proper Shipping Name (IMDG) : UN2735, AMINES, LIQUID, CORROSIVE, N.O.S. (CYCLOALIPHATIC AMINES )
Hazard Classes (IMDG) : 8 - Class 8 - Corrosive material 49 CFR 173.136
Packing group (IMDG) : II - Medium Danger
Air transport
UN-No.(IATA) : 2735
Proper Shipping Name (IATA) : UN2735, AMINES, LIQUID, CORROSIVE, N.O.S. (CYCLOALIPHATIC AMINES )
Hazard Classes (IATA) : 8 - Class 8 - Corrosive material 49 CFR 173.136
Packing group (IATA) : II - Medium Danger
SECTION 15: Regulatory information
15.1. US Federal regulations
Clear Laminating Hardener (Mixture)
SARA Section 311/312 Hazard Classes Delayed (chronic) health hazard
15.2. International regulations
CANADA
No additional information available
EU-Regulations
No additional information available
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute Tox. 4 (Oral) H302
Acute Tox. 4 (Dermal) H312
Skin Corr. 1B H314
Skin Sens. 1 H317
Aquatic Chronic 3 H412
Full text of H-phrases: see section 16
Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]
Xn; R21/22
C; R34
R43
R52/53
Full text of R-phrases: see section 16
15.2.2. National regulations
No additional information available
15.3. US State regulations
No additional information available
Clear Laminating Hardener
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
07/13/2015 EN (English) SDS ID: 80LS-19B 9/9
SECTION 16: Other information
Other information : None.
Full text of H-phrases: see section 16:
------ Acute Tox. 4 (Inhalation:gas) Acute toxicity (inhalation:gas) Category 4
------ Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4
------ Aquatic Chronic 2 Hazardous to the aquatic environment Chronic Hazard, Category
2
------ Eye Dam. 1 Serious eye damage/eye irritation, Category 1
------ Eye Irrit. 2B Serious eye damage/eye irritation, Category 2B
------ Repr. 2 Reproductive toxicity, Category 2
------ Skin Corr. 1A Skin corrosion/irritation, Category 1A
------ Skin Corr. 1B Skin corrosion/irritation, Category 1B
------ Skin Corr. 1C Skin corrosion/irritation, Category 1C
------ Skin Sens. 1 Sensitisation Skin, category 1
------ Skin Sens. 1A Sensitisation Skin, category 1A
------ H302 Harmful if swallowed
------ H314 Causes severe skin burns and eye damage
------ H317 May cause an allergic skin reaction
------ H318 Causes serious eye damage
------ H320 Causes eye irritation
------ H332 Harmful if inhaled
------ H361 Suspected of damaging fertility or the unborn child
------ H411 Toxic to aquatic life with long lasting effects
SDS US (GHS HazCom 2012)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied
warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.
80LS-19B-D_SDS.pdf
Clear Laminating Hardener
Safety Data Sheet 80LS-19B
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue: 07/13/2015 Revision date: 07/13/2015 Version: 1.0
07/13/2015 EN (English) SDS ID: 80LS-19B Page 1
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product form : Mixture
Trade name : Clear Laminating Hardener
CAS No : Mixture
Product code : 80LS-19B
Other means of identification : DISTRIBUTED BY REVCHEM COMPOSITES, INC
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Clear Laminating Hardener
1.3. Details of the supplier of the safety data sheet
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909.877.8477
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
GHS-US classification
Acute Tox. 4 (Oral) H302
Acute Tox. 4 (Inhalation:gas) H332
Skin Corr. 1B H314
Eye Dam. 1 H318
Skin Sens. 1A H317
Repr. 2 H361
Aquatic Chronic 2 H411
2.2. Label elements
GHS-US labelling
Hazard pictograms (GHS-US) :
GHS05
GHS07
GHS08
GHS09
Signal word (GHS-US) : Danger
Hazard statements (GHS-US) : H302+H332 – Harmful if swallowed or if inhaled
H314 – Causes severe skin burns and eye damage
H317 – May cause an allergic skin reaction
H318 – Causes serious eye damage
H361 – Suspected of damaging fertility or the unborn child
H411 – Toxic to aquatic life with long lasting effects
Precautionary statements (GHS-US) : P201 – Obtain special instructions before use
P202 – Do not handle until all safety precautions have been read and understood
P260 – Do not breathe dust/fume/gas/mist/vapours/spray
P261 – Avoid breathing dust/fume/gas/mist/vapours/spray
P264 – Wash … thoroughly after handling
P270 – Do not eat, drink or smoke when using this product
P271 – Use only outdoors or in a well-ventilated area
P272 – Contaminated work clothing should not be allowed out of the workplace
P273 – Avoid release to the environment
P280 – Wear protective gloves/protective clothing/eye protection/face protection
P301+P312 – IF SWALLOWED: call a POISON CENTER or doctor/physician if you feel unwell
Clear Laminating Hardener
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
07/13/2015 EN (English) SDS ID: 80LS-19B 2/9
P301+P330+P331 – IF SWALLOWED: rinse mouth. Do NOT induce vomiting
P302+P352 – IF ON SKIN: Wash with plenty of soap and water
P303+P361+P353 – IF ON SKIN (or hair): Remove/Take off immediately all contaminated
clothing. Rinse skin with water/shower
P304+P340 – IF INHALED: remove victim to fresh air and keep at rest in a position comfortable
for breathing
P305+P351+P338 – If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P308+P313 – IF exposed or concerned: Get medical advice/attention
P310 – Immediately call a POISON CENTER or doctor/physician
P312 – Call a POISON CENTER or doctor/physician if you feel unwell
P321 – Specific treatment (see … on this label)
P330 – If swallowed, rinse mouth
P333+P313 – If skin irritation or rash occurs: Get medical advice/attention
P362+P364 – Take off contaminated clothing and wash it before reuse
P363 – Wash contaminated clothing before reuse
P391 – Collect spillage
P405 – Store locked up
P501 – Dispose of contents/container to an approved waste disposal plant.
2.3. Other hazards
No additional information available
2.4. Unknown acute toxicity (GHS-US)
No data available
SECTION 3: Composition/information on ingredients
3.1. Substance
Not applicable
Full text of H-phrases: see section 16
3.2. Mixture
Name Product identifier % GHS-US classification
isophorone diamine (CAS No) 2855-13-2 < 35 Acute Tox. 4 (Oral), H302
Skin Corr. 1A, H314
1,3-bis(aminomethyl)cyclohexane (CAS No) 2579-20-6 <= 25 Acute Tox. 4 (Oral), H302
4-tert-butylphenol (CAS No) 98-54-4 < 20 Not classified
benzyl alcohol (CAS No) 100-51-6 < 15 Not classified
CYCLOALIPHATIC AMINE (CAS No) TRADE SECRET < 15 Skin Corr. 1C, H314
Eye Irrit. 2B, H320
Skin Sens. 1, H317
salicylic acid (CAS No) 69-72-7 < 8 Acute Tox. 4 (Oral), H302
SECTION 4: First aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. IF exposed or concerned: Get medical
advice/attention.
First-aid measures after inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a
POISON CENTER or doctor/physician if you feel unwell. Immediately call a POISON CENTER or
doctor/physician.
First-aid measures after skin contact : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
Immediately call a POISON CENTER or doctor/physician.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Call a POISON CENTER or doctor/physician if you feel
unwell. Immediately call a POISON CENTER or doctor/physician.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries : Causes severe skin burns and eye damage. Suspected of damaging fertility or the unborn child.
Symptoms/injuries after inhalation : Harmful if inhaled. Danger of serious damage to health by prolonged exposure through
inhalation.
Symptoms/injuries after skin contact : Causes skin irritation. Caustic burns/corrosion of the skin.
Symptoms/injuries after eye contact : Causes eye irritation. May cause severe irritation. Causes serious eye damage.
Symptoms/injuries after ingestion : Swallowing a small quantity of this material will result in serious health hazard.
Clear Laminating Hardener
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
07/13/2015 EN (English) SDS ID: 80LS-19B 3/9
4.3. Indication of any immediate medical attention and special treatment needed
Until victim can be cared for by specialized staff:
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Heating increases the fire hazard. Heating may cause a fire. Heating may cause a fire or
explosion. Insufficient data available on direct fire hazard (flashpoint > 100 C). Self-heating in
large quantities; may catch fire. Temperature above flashpoint: higher fire/explosion hazard.
Reactivity : Thermal decomposition generates : Corrosive vapours.
5.3. Advice for firefighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect
spillage. Store away from other materials.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Provide good ventilation in process area to prevent formation of
vapour. Use only outdoors or in a well-ventilated area. Avoid breathing
dust/fume/gas/mist/vapours/spray. Do not breathe dust/fume/gas/mist/vapours/spray. Obtain
special instructions before use. Do not handle until all safety precautions have been read and
understood.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash … thoroughly after handling. Wash
contaminated clothing before reuse.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Comply with applicable regulations.
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Keep container
closed when not in use.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight.
7.3. Specific end use(s)
No additional information available
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
No additional information available
Clear Laminating Hardener
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
07/13/2015 EN (English) SDS ID: 80LS-19B 4/9
8.2. Exposure controls
Personal protective equipment : Avoid all unnecessary exposure.
Hand protection : Wear protective gloves.
Eye protection : Chemical goggles or face shield.
Skin and body protection : Wear suitable protective clothing.
Respiratory protection : Wear appropriate mask.
Other information : Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Appearance : Clear, colorless liquid.
Colour : clear.
Odour : characteristic.
Odour threshold : No data available
pH : No data available
Relative evaporation rate (butylacetate=1) : No data available
Relative evaporation rate (ether=1) : < 1 slower than ether Melting point : No data available Freezing point : No data available Boiling point : 140 - 152 C Initial Boiling Point for Styrene @ 760.00 mm Hg Flash point : 110 C for Volatile Component (230 Deg F) Auto-ignition temperature : No data available Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapour pressure : 4.3 mm Hg Relative vapour density at 20 C : No data available Relative density : No data available Density : 1.002 g/l Solubility : No data available Log Pow : No data available Log Kow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosive properties : No data available Oxidising properties : No data available Explosive limits : No data available 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity Thermal decomposition generates : Corrosive vapours. 10.2. Chemical stability Stable under normal conditions. Not established. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. 10.5. Incompatible materials Strong acids. Strong bases. Clear Laminating Hardener Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 07/13/2015 EN (English) SDS ID: 80LS-19B 5/9 10.6. Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. Thermal decomposition generates : Corrosive vapours. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Harmful if swallowed. Harmful if inhaled. Clear Laminating Hardener ( f )Mixture ATE CLP (oral) 500.000 mg/kg bodyweight ATE CLP (dermal) 1100.000 mg/kg bodyweight 1,3-bis(aminomethyl)cyclohexane (2579-20-6) LD50 oral rat 880 mg/kg (Rat) ATE CLP (oral) 880.000 mg/kg bodyweight 4-tert-butylphenol (98-54-4) LD50 oral rat 3370 mg/kg (Rat) LD50 dermal rabbit 2621 mg/kg (Rabbit) LC50 inhalation rat (mg/l) > 5.6 mg/l/4h (Rat)
isophorone diamine (2855-13-2)
LD50 oral rat 1030 mg/kg (Rat; OECD 401: Acute Oral Toxicity; Experimental value)
LD50 dermal rat > 2000 mg/kg bodyweight (Rat; Experimental value; OECD 402: Acute Dermal Toxicity)
LC50 inhalation rat (mg/l) > 5.01 mg/l/4h (Rat; Experimental value)
benzyl alcohol (100-51-6)
LD50 oral rat 1620 mg/kg bw/day (Rat; Experimental value)
LD50 dermal rabbit > 2000 mg/kg (Rabbit; Experimental value)
salicylic acid (69-72-7)
LD50 oral rat 891 mg/kg bodyweight (Rat; OECD 401: Acute Oral Toxicity; Experimental value)
LD50 dermal rat > 2000 mg/kg (Rat)
LD50 dermal rabbit > 10000 mg/kg (Rabbit)
Skin corrosion/irritation : Causes severe skin burns and eye damage.
Serious eye damage/irritation : Causes serious eye damage.
Respiratory or skin sensitisation : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified
Based on available data, the classification criteria are not met
Carcinogenicity : Not classified
Reproductive toxicity : Suspected of damaging fertility or the unborn child.
Based on available data, the classification criteria are not met
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated
exposure)
: Not classified
Based on available data, the classification criteria are not met
Aspiration hazard : Not classified
Based on available data, the classification criteria are not met
Potential adverse human health effects and
symptoms
: Based on available data, the classification criteria are not met. Harmful if swallowed. Harmful if
inhaled.
Symptoms/injuries after inhalation : Harmful if inhaled. Danger of serious damage to health by prolonged exposure through
inhalation.
Symptoms/injuries after skin contact : Causes skin irritation. Caustic burns/corrosion of the skin.
Symptoms/injuries after eye contact : Causes eye irritation. May cause severe irritation. Causes serious eye damage.
Symptoms/injuries after ingestion : Swallowing a small quantity of this material will result in serious health hazard.
Likely routes of exposure : Inhalation
Clear Laminating Hardener
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
07/13/2015 EN (English) SDS ID: 80LS-19B 6/9
SECTION 12: Ecological information
12.1. Toxicity
Ecology – water : Toxic to aquatic life with long lasting effects.
1,3-bis(aminomethyl)cyclohexane (2579-20-6)
LC50 fish 1 130 mg/l (96 h; Leuciscus idus; GLP)
EC50 Daphnia 1 65.4 mg/l (48 h; Daphnia magna; GLP)
Threshold limit algae 1 56.7 mg/l (72 h; Pseudokirchneriella subcapitata; Growth rate)
Threshold limit algae 2 13.7 mg/l (72 h; Pseudokirchneriella subcapitata; Growth rate)
4-tert-butylphenol (98-54-4)
LC50 fish 1 1.6 mg/l (48 h; Leuciscus idus; Measured concentration)
EC50 Daphnia 1 3.9 mg/l (48 h; Daphnia magna)
LC50 fish 2 5.14 mg/l (96 h; Pimephales promelas)
EC50 Daphnia 2 4.8 mg/l (24 h; Daphnia magna)
Threshold limit algae 1 > 10 mg/l (Scenedesmus quadricauda)
Threshold limit algae 2 11.2 mg/l (72 h; Scenedesmus subspicatus; Growth rate)
isophorone diamine (2855-13-2)
LC50 fish 1 110 mg/l (96 h; Brachydanio rerio; GLP)
EC50 Daphnia 1 42 – 44 mg/l (24 h; Daphnia magna; GLP)
LC50 fish 2 110 mg/l (96 h; Leuciscus idus; GLP)
EC50 Daphnia 2 23 mg/l (48 h; Daphnia magna)
Threshold limit algae 1 1.5 mg/l (72 h; Scenedesmus subspicatus)
Threshold limit algae 2 10.14 mg/l (Algae)
benzyl alcohol (100-51-6)
LC50 fish 1 460 mg/l (96 h; Pimephales promelas; Nominal concentration)
EC50 Daphnia 1 400 mg/l (48 h; Daphnia magna; GLP)
LC50 fish 2 10 ppm (96 h; Lepomis macrochirus)
EC50 Daphnia 2 230 mg/l (48 h; Daphnia magna)
Threshold limit other aquatic organisms 1 < 658 mg/l (16 h; Pseudomonas putida)
Threshold limit algae 1 640 ppm (96 h; Scenedesmus quadricauda)
Threshold limit algae 2 2600 mg/l (72 h; Algae)
salicylic acid (69-72-7)
LC50 fish 1 90 mg/l (48 h; Leuciscus idus)
EC50 Daphnia 1 105 - 180 mg/l (24 h; Daphnia magna; Nominal concentration)
EC50 Daphnia 2 230 mg/l (24 h; Daphnia magna)
Threshold limit algae 1 > 100 mg/l (72 h; Desmodesmus subspicatus)
12.2. Persistence and degradability
Clear Laminating Hardener (Mixture)
Persistence and degradability May cause long-term adverse effects in the environment.
1,3-bis(aminomethyl)cyclohexane (2579-20-6)
Persistence and degradability Not readily biodegradable in water. Biodegradability in soil: no data available. Not established.
4-tert-butylphenol (98-54-4)
Persistence and degradability Readily biodegradable in water. Photolysis in the air.
ThOD 2.77 g O /g substance
isophorone diamine (2855-13-2)
Persistence and degradability Not readily biodegradable in water. Low potential for adsorption in soil.
benzyl alcohol (100-51-6)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. No (test)data on mobility of the
substance available.
Biochemical oxygen demand (BOD) 1.6 g O /g substance
Chemical oxygen demand (COD) 2.4 g O /g substance
ThOD 2.5 g O /g substance
Clear Laminating Hardener
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
07/13/2015 EN (English) SDS ID: 80LS-19B 7/9
salicylic acid (69-72-7)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil.
Biochemical oxygen demand (BOD) 0.95 g O /g substance
Chemical oxygen demand (COD) 1.58 g O /g substance
ThOD 1.623 g O /g substance
BOD (% of ThOD) 0.41 – 0.60 % ThOD
CYCLOALIPHATIC AMINE (TRADE SECRET)
Persistence and degradability Not established.
12.3. Bioaccumulative potential
Clear Laminating Hardener (Mixture)
Bioaccumulative potential Not established.
1,3-bis(aminomethyl)cyclohexane (2579-20-6)
Log Pow 0.69 – 0.78 (Experimental value; OECD 107: Partition Coefficient (n-octanol/water): Shake
Flask Method; 21.5 – 24.7 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
4-tert-butylphenol (98-54-4)
BCF fish 1 120 (3 h; Leuciscus idus)
BCF fish 2 20 - 88 (Cyprinus carpio; Test duration: 8 weeks)
BCF other aquatic organisms 1 34 (24 h; Chlorella sp.; Fresh weight)
BCF other aquatic organisms 2 240 (5 h; Bacteria; Activated sludge)
Log Pow 3.29 (OECD 107: Partition Coefficient (n-octanol/water): Shake Flask Method)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).
isophorone diamine (2855-13-2)
Log Pow 0.99 (Experimental value; OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method; 23 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
benzyl alcohol (100-51-6)
Log Pow 1.05 (Experimental value; Other; 20 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
salicylic acid (69-72-7)
BCF other aquatic organisms 1 > 1000 (96 h; Scenedesmus subspicatus)
Log Pow 2.25 (Experimental value; Equivalent or similar to OECD 117; 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
CYCLOALIPHATIC AMINE (TRADE SECRET)
Bioaccumulative potential Not established.
12.4. Mobility in soil
benzyl alcohol (100-51-6)
Surface tension 0.04 N/m (20 C)
12.5. Other adverse effects
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to an approved waste disposal plant.
Ecology - waste materials : Avoid release to the environment.
SECTION 14: Transport information
In accordance with DOT
UN-No.(DOT) : 2735
Proper Shipping Name (DOT) : UN2735, AMINES, LIQUID, CORROSIVE, N.O.S. (CYCLOALIPHATIC AMINES )
Clear Laminating Hardener
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
07/13/2015 EN (English) SDS ID: 80LS-19B 8/9
Hazard Classes (DOT) : 8 - Class 8 - Corrosive material 49 CFR 173.136
Packing group (DOT) : II - Medium Danger
Additional information
Other information : No supplementary information available.
Transport by sea
UN-No.(IMDG) : 2735
Proper Shipping Name (IMDG) : UN2735, AMINES, LIQUID, CORROSIVE, N.O.S. (CYCLOALIPHATIC AMINES )
Hazard Classes (IMDG) : 8 - Class 8 - Corrosive material 49 CFR 173.136
Packing group (IMDG) : II - Medium Danger
Air transport
UN-No.(IATA) : 2735
Proper Shipping Name (IATA) : UN2735, AMINES, LIQUID, CORROSIVE, N.O.S. (CYCLOALIPHATIC AMINES )
Hazard Classes (IATA) : 8 - Class 8 - Corrosive material 49 CFR 173.136
Packing group (IATA) : II - Medium Danger
SECTION 15: Regulatory information
15.1. US Federal regulations
Clear Laminating Hardener (Mixture)
SARA Section 311/312 Hazard Classes Delayed (chronic) health hazard
15.2. International regulations
CANADA
No additional information available
EU-Regulations
No additional information available
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute Tox. 4 (Oral) H302
Acute Tox. 4 (Dermal) H312
Skin Corr. 1B H314
Skin Sens. 1 H317
Aquatic Chronic 3 H412
Full text of H-phrases: see section 16
Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]
Xn; R21/22
C; R34
R43
R52/53
Full text of R-phrases: see section 16
15.2.2. National regulations
No additional information available
15.3. US State regulations
No additional information available
Clear Laminating Hardener
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
07/13/2015 EN (English) SDS ID: 80LS-19B 9/9
SECTION 16: Other information
Other information : None.
Full text of H-phrases: see section 16:
------ Acute Tox. 4 (Inhalation:gas) Acute toxicity (inhalation:gas) Category 4
------ Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4
------ Aquatic Chronic 2 Hazardous to the aquatic environment Chronic Hazard, Category
2
------ Eye Dam. 1 Serious eye damage/eye irritation, Category 1
------ Eye Irrit. 2B Serious eye damage/eye irritation, Category 2B
------ Repr. 2 Reproductive toxicity, Category 2
------ Skin Corr. 1A Skin corrosion/irritation, Category 1A
------ Skin Corr. 1B Skin corrosion/irritation, Category 1B
------ Skin Corr. 1C Skin corrosion/irritation, Category 1C
------ Skin Sens. 1 Sensitisation Skin, category 1
------ Skin Sens. 1A Sensitisation Skin, category 1A
------ H302 Harmful if swallowed
------ H314 Causes severe skin burns and eye damage
------ H317 May cause an allergic skin reaction
------ H318 Causes serious eye damage
------ H320 Causes eye irritation
------ H332 Harmful if inhaled
------ H361 Suspected of damaging fertility or the unborn child
------ H411 Toxic to aquatic life with long lasting effects
SDS US (GHS HazCom 2012)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied
warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.