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40511023G_SDS.pdf

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DURA-KOTE PIGMENT ALL TAN DISPERSIONS
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue: 01/04/2016 Revision date: 01/04/2016 Supersedes: 09/10/2014

01/07/2016 EN (English US) Page 1

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Product form : Mixture
Trade name : DURA-KOTE PIGMENT ALL TAN DISPERSIONS
CAS No : mixture
Product code : 511-XXX
Formula : na

1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : PIGMENT DISPERSION

1.3. Details of the supplier of the safety data sheet
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316

909.877.8477
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887

1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
GHS-US classification
Carc. 2 H351

2.2. Label elements
GHS-US labeling
Hazard pictograms (GHS-US) :

GHS08

Signal word (GHS-US) : Warning
Hazard statements (GHS-US) : H351 – Suspected of causing cancer
Precautionary statements (GHS-US) : P201 – Obtain special instructions before use
P202 – Do not handle until all safety precautions have been read and understood
P280 – Wear protective gloves/protective clothing/eye protection/face protection
P308+P313 – IF exposed or concerned: Get medical advice/attention
P405 – Store locked up
P501 – Dispose of contents/container to …

2.3. Other hazards
No additional information available
2.4. Unknown acute toxicity (GHS-US)
No data available
SECTION 3: Composition/Information on ingredients

3.1. Substance
Not applicable
Full text of H-phrases: see section 16

3.2. Mixture

DURA-KOTE PIGMENT ALL TAN DISPERSIONS
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

01/07/2016 EN (English US) 2/7

Name Product identifier % GHS-US classification
Unsaturated Polyester Resin (CAS No) TRADE SECRET 30 – 85 Not classified
titanium(IV) oxide (CAS No) 13463-67-7 0 – 18 Carc. 2, H351
LEAD FREE ORGANIC PIGMENT (CAS No) Proprietary 0 – 15 Not classified
LEAD FREE INORGANIC PIGMENT (CAS No) Proprietary 0 – 15 Not classified
carbon black (CAS No) 1333-86-4 0 – 5 Carc. 2, H351

SECTION 4: First aid measures

4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice
(show the label where possible).
First-aid measures after inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a
POISON CENTER or doctor/physician if you feel unwell. Allow victim to breathe fresh air. Allow
the victim to rest.
First-aid measures after skin contact : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
First-aid measures after eye contact : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness
persist.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.

4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries : May cause genetic defects (avoid skin contact and inhalation.). May cause cancer (avoid skin
contact and inhalation.). Not expected to present a significant hazard under anticipated
conditions of normal use.
Symptoms/injuries after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled.

4.3. Indication of any immediate medical attention and special treatment needed
No additional information available
SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.

5.2. Special hazards arising from the substance or mixture
Fire hazard : Highly flammable liquid and vapor. Flammable liquid and vapor.
Explosion hazard : May form flammable/explosive vapor-air mixture.
Reactivity : No reactivity hazard other than the effects described in sub-sections below.

5.3. Advice for firefighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No
smoking.
6.1.1. For non-emergency personnel
Protective equipment : Gloves. Protective goggles. Protective clothing.
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Ventilate area.

6.2. Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.

6.3. Methods and material for containment and cleaning up
For containment : Dam up the liquid spill. Contain released substance, pump into suitable containers.

DURA-KOTE PIGMENT ALL TAN DISPERSIONS
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

01/07/2016 EN (English US) 3/7

Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect
spillage. Store away from other materials.

6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.
SECTION 7: Handling and storage

7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapors are flammable.
Precautions for safe handling : Use only outdoors or in a well-ventilated area. Avoid breathing DUST, FUMES, MIST, OR
VAPORS. Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Eliminate all ignition sources if safe to do so. Wash hands and other
exposed areas with mild soap and water before eating, drinking or smoking and when leaving
work. Provide good ventilation in process area to prevent formation of vapor. No open flames. No
smoking. Take precautionary measures against static discharge. Use only non-sparking tools.

7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond
container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/
equipment.
Storage conditions : Keep in fireproof place. Keep only in the original container in a cool, well ventilated place away
from : Keep container tightly closed.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.

7.3. Specific end use(s)
No additional information available
SECTION 8: Exposure controls/personal protection

8.1. Control parameters

titanium(IV) oxide (13463-67-7)
USA ACGIH ACGIH TWA (mg/m ) 10 mg/m

carbon black (1333-86-4)
USA ACGIH ACGIH TWA (mg/m ) 3 mg/m

8.2. Exposure controls
Appropriate engineering controls : Ensure exposure is below occupational exposure limits (where available).
Personal protective equipment : Avoid all unnecessary exposure.
Hand protection : Wear protective gloves.
Eye protection : Chemical goggles or safety glasses.
Respiratory protection : Wear appropriate mask.
Other information : Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : Liquid

Color : TAN.

Odor : characteristic.

Odor threshold : No data available

pH : No data available

Relative evaporation rate (butyl acetate=1) : No data available

Melting point : No data available

Freezing point : No data available

Boiling point : >= 146 C

Flash point : >= 146 C

Auto-ignition temperature : No data available

Decomposition temperature : No data available

Flammability (solid, gas) : No data available

DURA-KOTE PIGMENT ALL TAN DISPERSIONS
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

01/07/2016 EN (English US) 4/7

Vapor pressure : No data available

Relative vapor density at 20 C : No data available

Relative density : No data available

Specific gravity / density : 1 – 2.2
Solubility : No data available

Log Pow : No data available

Log Kow : No data available

Viscosity, kinematic : No data available

Viscosity, dynamic : No data available

Explosive properties : No data available

Oxidizing properties : No data available

Explosive limits : No data available

9.2. Other information
No additional information available
SECTION 10: Stability and reactivity

10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.

10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Highly flammable liquid and vapor. Not established. Flammable liquid and
vapor. May form flammable/explosive vapor-air mixture.

10.3. Possibility of hazardous reactions
Not established.

10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Heat. Sparks.

10.5. Incompatible materials
Strong acids. Strong bases.

10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity : Not classified

titanium(IV) oxide (13463-67-7)
LD50 oral rat > 10000 mg/kg (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure; Experimental
value; > 5000 mg/kg bodyweight; Rat; Experimental value)
LD50 dermal rabbit > 10000 mg/kg (Rabbit; Experimental value)
LC50 inhalation rat (mg/l) > 6.8 mg/l/4h (Rat; Experimental value)

carbon black (1333-86-4)
LD50 oral rat > 8000 mg/kg (Rat; OECD 401: Acute Oral Toxicity; Experimental value)
LD50 dermal rabbit > 3000 mg/kg (Rabbit)

Skin corrosion/irritation : Not classified
Serious eye damage/irritation : Not classified
Respiratory or skin sensitization : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Suspected of causing cancer.

titanium(IV) oxide (13463-67-7)
IARC group 2B – Possibly carcinogenic to humans

carbon black (1333-86-4)
IARC group 2B – Possibly carcinogenic to humans

DURA-KOTE PIGMENT ALL TAN DISPERSIONS
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

01/07/2016 EN (English US) 5/7

Reproductive toxicity : Not classified
Based on available data, the classification criteria are not met
Specific target organ toxicity (single exposure) : Not classified

Specific target organ toxicity (repeated
exposure)
: Not classified
Based on available data, the classification criteria are not met

Aspiration hazard : Not classified
Based on available data, the classification criteria are not met
Potential Adverse human health effects and
symptoms
: Harmful if inhaled. Based on available data, the classification criteria are not met.
Symptoms/injuries after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled.
SECTION 12: Ecological information

12.1. Toxicity

titanium(IV) oxide (13463-67-7)
LC50 fish 1 > 1000 mg/l (96 h; Pimephales promelas)
EC50 Daphnia 1 < 1000 mg/l (432 h; Daphnia magna; Static system) LC50 fish 2 > 1 g/l (96 h; Leuciscus idus)
EC50 Daphnia 2 < 500 mg/l (720 h; Daphnia magna; Static system) Threshold limit algae 1 61 mg/l (72 h; Pseudokirchneriella subcapitata) carbon black (1333-86-4) LC50 fish 1 > 1000 mg/l (96 h; Brachydanio rerio)
EC50 Daphnia 1 > 5600 mg/l (24 h; Daphnia magna)

12.2. Persistence and degradability
DURA-KOTE PIGMENT ALL BROWN DISPERSIONS (mixture)
Persistence and degradability Not established.

Unsaturated Polyester Resin (TRADE SECRET)
Persistence and degradability Not established.

titanium(IV) oxide (13463-67-7)
Persistence and degradability Biodegradability: not applicable. Low potential for mobility in soil.
Biochemical oxygen demand (BOD) Not applicable
Chemical oxygen demand (COD) Not applicable
ThOD Not applicable
BOD (% of ThOD) Not applicable

carbon black (1333-86-4)
Persistence and degradability Biodegradability: not applicable. Biodegradability in soil: not applicable. Adsorbs into the soil.
Biochemical oxygen demand (BOD) Not applicable
Chemical oxygen demand (COD) Not applicable
ThOD Not applicable
BOD (% of ThOD) Not applicable

LEAD FREE ORGANIC PIGMENT (Proprietary)
Persistence and degradability Not established.

LEAD FREE INORGANIC PIGMENT (Proprietary)
Persistence and degradability Not established.

12.3. Bioaccumulative potential
DURA-KOTE PIGMENT ALL BROWN DISPERSIONS (mixture)
Bioaccumulative potential Not established.

Unsaturated Polyester Resin (TRADE SECRET)
Bioaccumulative potential Not established.

DURA-KOTE PIGMENT ALL TAN DISPERSIONS
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

01/07/2016 EN (English US) 6/7

titanium(IV) oxide (13463-67-7)
Bioaccumulative potential Not bioaccumulative.

carbon black (1333-86-4)
Bioaccumulative potential Not bioaccumulative.

LEAD FREE ORGANIC PIGMENT (Proprietary)
Bioaccumulative potential Not established.

LEAD FREE INORGANIC PIGMENT (Proprietary)
Bioaccumulative potential Not established.

12.4. Mobility in soil

carbon black (1333-86-4)
Ecology – soil Not toxic to plants. Not toxic to animals.

12.5. Other adverse effects
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations

13.1. Waste treatment methods
Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to …
Additional information : Handle empty containers with care because residual vapors are flammable.
Ecology – waste materials : Avoid release to the environment.
SECTION 14: Transport information

In accordance with DOT
Not regulated for transport
Additional information
Other information : No supplementary information available.

ADR
Transport document description :
Transport by sea
No additional information available
Air transport
No additional information available
SECTION 15: Regulatory information

15.1. US Federal regulations
No additional information available

15.2. International regulations
CANADA
No additional information available

EU-Regulations
No additional information available

Classification according to Regulation (EC) No. 1272/2008 [CLP]
Not classified

DURA-KOTE PIGMENT ALL TAN DISPERSIONS
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

01/07/2016 EN (English US) 7/7

Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]
Carc.Cat.2; R45
Muta.Cat.2; R46
F; R11
Xn; R20
Xi; R36/38
Full text of R-phrases: see section 16
15.2.2. National regulations
No additional information available

15.3. US State regulations
DURA-KOTE PIGMENT ALL BROWN DISPERSIONS (mixture)
State or local regulations U.S. – Pennsylvania – RTK (Right to Know) List
U.S. – Pennsylvania – RTK (Right to Know) – Environmental Hazard List
U.S. – New Jersey – TCPA – Extraordinarily Hazardous Substances (EHS)
U.S. – New Jersey – Right to Know Hazardous Substance List
U.S. – Massachusetts – Right To Know List

SECTION 16: Other information

Other information : None.

Full text of H-phrases: see section 16:
—— Carc. 2 Carcinogenicity Category 2
—— H351 Suspected of causing cancer

NFPA health hazard : 1 – Exposure could cause irritation but only minor residual
injury even if no treatment is given.

NFPA fire hazard : 2 – Must be moderately heated or exposed to relatively high
temperature before ignition can occur.
NFPA reactivity : 1 – Normally stable, but can become unstable at elevated
temperatures and pressures or may react with water with
some release of energy, but not violently.

HMIS III Rating

Health : 1 Slight Hazard – Irritation or minor reversible injury possible
Flammability : 1 Slight Hazard
Physical : 1 Slight Hazard
Personal Protection : H

SDS US (GHS HazCom 2012)

To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied
warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.

40511022G_SDS.pdf