by | Sep 27, 2025
STYROSAFE LAMINATING RESIN
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
05/22/2018 EN (English US) Page 1
SECTION 1: Identification
1.1. Identification
Product form : Mixtures
Trade name : STYROSAFE LAMINATING RESIN
CAS-No. : mixture
Product code : 30P-106A
Formula : na
1.2. Recommended use and restrictions on use
Use of the substance/mixture : LAMINATING RESIN FOR EPS
1.3. Supplier
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909.877.8477
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300
SECTION 2: Hazard(s) identification
2.1. Classification of the substance or mixture
GHS-US classification
Flammable liquids
Category 3
H226 Flammable liquid and vapor
Acute toxicity (inhalation)
Category 4
H332 Harmful if inhaled
Skin corrosion/irritation
Category 2
H315 Causes skin irritation
Serious eye damage/eye
irritation Category 2
H319 Causes serious eye irritation
Skin sensitization, Category
1
H317 May cause an allergic skin reaction
Carcinogenicity Category 2 H351 Suspected of causing cancer
Reproductive toxicity
Category 2
H361 Suspected of damaging fertility or the unborn child
Specific target organ
toxicity (single exposure)
Category 3
H335 May cause respiratory irritation
Specific target organ
toxicity (repeated exposure)
Category 1
H372 Causes damage to organs through prolonged or repeated exposure
Hazardous to the aquatic
environment – Acute
Hazard Category 3
H402 Harmful to aquatic life
Full text of H statements : see section 16
STYROSAFE LAMINATING RESIN
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
05/22/2018 EN (English US) 2/11
2.2. GHS Label elements, including precautionary statements
GHS-US labeling
Hazard pictograms (GHS-US) :
GHS02
GHS07
GHS08
Signal word (GHS-US) : Danger
Hazard statements (GHS-US) : H226 – Flammable liquid and vapor
H315 – Causes skin irritation
H317 – May cause an allergic skin reaction
H319 – Causes serious eye irritation
H332 – Harmful if inhaled
H335 – May cause respiratory irritation
H351 – Suspected of causing cancer
H361 – Suspected of damaging fertility or the unborn child
H372 – Causes damage to organs through prolonged or repeated exposure
H402 – Harmful to aquatic life
Precautionary statements (GHS-US) : P201 – Obtain special instructions before use
P202 – Do not handle until all safety precautions have been read and understood
P210 – Keep away from heat, hot surfaces, open flames, sparks. – No smoking
P233 – Keep container tightly closed
P240 – Ground/Bond container and receiving equipment
P241 – Use explosion-proof electrical, lighting, ventilating equipment
P242 – Use only non-sparking tools
P243 – Take precautionary measures against static discharge
P260 – Do not breathe dust/fume/gas/mist/vapors/spray
P261 – Avoid breathing dust/fume/gas/mist/vapors/spray
P264 – Wash EXPOSED AREA. thoroughly after handling
P270 – Do not eat, drink or smoke when using this product
P271 – Use only outdoors or in a well-ventilated area
P272 – Contaminated work clothing must not be allowed out of the workplace
P273 – Avoid release to the environment
P280 – Wear eye protection, protective clothing, protective gloves
P302+P352 – If on skin: Wash with plenty of water/
P303+P361+P353 – If on skin (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower
P304+P340 – If inhaled: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 – If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P308+P313 – If exposed or concerned: Get medical advice/attention
P312 – Call a poison center/doctor/ if you feel unwell
P314 – Get medical advice/attention if you feel unwell
P321 – Specific treatment (see … on this label)
P332+P313 – If skin irritation occurs: Get medical advice/attention
P333+P313 – If skin irritation or rash occurs: Get medical advice/attention
P337+P313 – If eye irritation persists: Get medical advice/attention
P362+P364 – Take off contaminated clothing and wash it before reuse
P363 – Wash contaminated clothing before reuse
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish
P403+P233 – Store in a well-ventilated place. Keep container tightly closed
P403+P235 – Store in a well-ventilated place. Keep cool
P405 – Store locked up
P501 – Dispose of contents/container to LOCAL, STATE, AND NATIONAL REGULATIONS.
2.3. Other hazards which do not result in classification
No additional information available
2.4. Unknown acute toxicity (GHS US)
Not applicable
SECTION 3: Composition/Information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
STYROSAFE LAMINATING RESIN
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
05/22/2018 EN (English US) 3/11
Name Product identifier % GHS-US classification
Unsaturated Polyester Resin
(CAS-No.) TRADE SECRET <= 72 Not classified
2-hydroxyethyl methacrylate, stabilized
(CAS-No.) 868-77-9 <= 22 Skin Irrit. 2, H315
Eye Irrit. 2, H319
Skin Sens. 1, H317
styrene, inhibited
(CAS-No.) 100-42-5 <= 11 Flam. Liq. 3, H226
Acute Tox. 4 (Inhalation), H332
Acute Tox. 4 (Inhalation:vapour), H332
Skin Irrit. 2, H315
Eye Irrit. 2A, H319
Carc. 2, H351
Repr. 2, H361
STOT SE 3, H335
STOT RE 1, H372
cobalt(II) 2-ethylhexanoate
(CAS-No.) 136-52-7 <= 0.5 Eye Irrit. 2, H319
Skin Sens. 1, H317
Carc. 2, H351
Aquatic Acute 1, H400
Aquatic Chronic 2, H411
Full text of hazard classes and H-statements : see section 16
SECTION 4: First-aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical
advice (show the label where possible). IF exposed or concerned: Get medical advice/attention.
Call a poison center/doctor/physician if you feel unwell.
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Allow victim to breathe fresh
air. Allow the victim to rest. Remove victim to fresh air and keep at rest in a position
comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Call a
poison center/doctor/physician if you feel unwell.
First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Wash
with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation
occurs: wash throughly for five minutes. seek medical attention. Get medical advice/attention.
Specific treatment (see seek medical attention. on this label). If skin irritation or rash occurs:
Get medical advice/attention.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: SEEK IMMEDIATE MEDICAL ATTENTION. Get
medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a poison
center/doctor/physician if you feel unwell.
4.2. Most important symptoms and effects (acute and delayed)
Symptoms/effects : May cause genetic defects (avoid skin contact and inhalation.). May cause cancer (avoid skin
contact and inhalation.).
Symptoms/effects after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled. May cause respiratory irritation.
Symptoms/effects after skin contact : Causes skin irritation. Irritation. May cause an allergic skin reaction.
Symptoms/effects after eye contact : Causes serious eye irritation.
4.3. Immediate medical attention and special treatment, if necessary
Treat symptomatically.
SECTION 5: Fire-fighting measures
5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Specific hazards arising from the chemical
Fire hazard : Highly flammable liquid and vapor. Flammable liquid and vapor.
Explosion hazard : May form flammable/explosive vapor-air mixture.
Reactivity : No reactivity hazard other than the effects described in sub-sections below. Flammable liquid
and vapor.
5.3. Special protective equipment and precautions for fire-fighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
STYROSAFE LAMINATING RESIN
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
05/22/2018 EN (English US) 4/11
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Do
not attempt to take action without suitable protective equipment. Self-contained breathing
apparatus. Complete protective clothing.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No
smoking.
6.1.1. For non-emergency personnel
Protective equipment : Gloves. Protective goggles. Protective clothing.
Emergency procedures : Ventilate spillage area. Evacuate unnecessary personnel. No open flames, no sparks, and no
smoking. Do not breathe dust/fume/gas/mist/vapors/spray. Avoid contact with skin and eyes.
6.1.2. For emergency responders
Protective equipment : Do not attempt to take action without suitable protective equipment. Equip cleanup crew with
proper protection. For further information refer to section 8: "Exposure controls/personal
protection".
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Dam up the liquid spill. Contain released product, pump into suitable containers.
Methods for cleaning up : Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or
diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
Notify authorities if product enters sewers or public waters.
Other information : Dispose of materials or solid residues at an authorized site.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection. For further information refer to section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapors are flammable.
Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Provide good ventilation in process area to prevent formation
of vapor. No open flames. No smoking. Use only non-sparking tools. Use only outdoors or in a
well-ventilated area. Obtain special instructions before use. Do not handle until all safety
precautions have been read and understood. Eliminate all ignition sources if safe to do so.
Take precautionary measures against static discharge. Keep away from heat, hot surfaces,
sparks, open flames and other ignition sources. No smoking. Ground/bond container and
receiving equipment. Flammable vapors may accumulate in the container. Use explosion-proof
equipment. Wear personal protective equipment. Do not breathe
dust/fume/gas/mist/vapors/spray. Avoid contact with skin and eyes.
Hygiene measures : Wash HANDS thoroughly after handling. Wash contaminated clothing before reuse.
Contaminated work clothing should not be allowed out of the workplace. Do not eat, drink or
smoke when using this product. Always wash hands after handling the product.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond
container and receiving equipment. Use explosion-proof electrical, ventilating and lighting
equipment. equipment.
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : HEAT SPARKS
OR OPEN FLAMES. Keep in fireproof place. Keep container tightly closed. Store in a well-
ventilated place. Keep cool. Store locked up.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
STYROSAFE LAMINATING RESIN
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
05/22/2018 EN (English US) 5/11
styrene, inhibited (100-42-5)
ACGIH ACGIH TWA (ppm) 20 ppm (Styrene, monomer; USA; Time-weighted
average exposure limit 8 h; TLV - Adopted Value)
ACGIH ACGIH STEL (ppm) 40 ppm (Styrene, monomer; USA; Short time value;
TLV - Adopted Value)
cobalt(II) 2-ethylhexanoate (136-52-7)
Not applicable
Unsaturated Polyester Resin (TRADE SECRET)
Not applicable
2-hydroxyethyl methacrylate, stabilized (868-77-9)
Not applicable
8.2. Appropriate engineering controls
Appropriate engineering controls : Ensure exposure is below occupational exposure limits (where available). Ensure good
ventilation of the work station.
Environmental exposure controls : Avoid release to the environment.
8.3. Individual protection measures/Personal protective equipment
Personal protective equipment:
Avoid all unnecessary exposure.
Hand protection:
Wear protective gloves
Eye protection:
Chemical goggles or safety glasses. Safety glasses
Skin and body protection:
Wear suitable protective clothing
Respiratory protection:
Wear appropriate mask. Wear respiratory
protection
Other information:
Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Color : Colourless to yellow
Odor : characteristic
Odor threshold : No data available
pH : No data available
Melting point : Not applicable
Freezing point : No data available
Boiling point : 64 C
Flash point : < 30 - 34 C
Relative evaporation rate (butyl acetate=1) : No data available
Flammability (solid, gas) : Highly flammable liquid and vapor. Flammable liquid and vapor.
Vapor pressure : No data available
Relative vapor density at 20 C : No data available
Relative density : 1.1
Solubility : No data available
STYROSAFE LAMINATING RESIN
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
05/22/2018 EN (English US) 6/11
Log Pow : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosion limits : No data available
Explosive properties : No data available
Oxidizing properties : No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below. Flammable liquid and vapor.
10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Not established. Highly flammable liquid and vapor. May form
flammable/explosive vapor-air mixture. Flammable liquid and vapor.
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Heat. Sparks. Avoid contact with hot surfaces. No flames, no sparks.
Eliminate all sources of ignition.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity : Inhalation: Harmful if inhaled.
STYROSAFE LAMINATING RESIN (mixture)
ATE US (gases) 4500.000 ppmV/4h
ATE US (vapors) 11.000 mg/l/4h
ATE US (dust, mist) 1.500 mg/l/4h
styrene, inhibited (100-42-5)
LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
LD50 dermal rat 2820 mg/kg (Rat; Literature study; OECD 402: Acute Dermal Toxicity; >2000 mg/kg
bodyweight; Rat; Experimental value)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 inhalation rat (mg/l) 12 mg/l/4h (Rat; Literature study)
LC50 inhalation rat (ppm) 2770 ppm/4h (Rat; Literature study)
ATE US (oral) 5000.000 mg/kg body weight
ATE US (dermal) 2820.000 mg/kg body weight
ATE US (gases) 2770.000 ppmV/4h
ATE US (vapors) 12.000 mg/l/4h
ATE US (dust, mist) 1.500 mg/l/4h
cobalt(II) 2-ethylhexanoate (136-52-7)
LD50 oral rat 3129 mg/kg body weight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat > 2000 mg/kg body weight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)
ATE US (oral) 3129.000 mg/kg body weight
STYROSAFE LAMINATING RESIN
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
05/22/2018 EN (English US) 7/11
2-hydroxyethyl methacrylate, stabilized (868-77-9)
LD50 oral rat 5564 mg/kg body weight (Rat; Experimental value)
LD50 dermal rabbit > 5000 mg/kg (Rabbit; Experimental value)
ATE US (oral) 5564.000 mg/kg body weight
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitization : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified
Carcinogenicity : Suspected of causing cancer.
styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans
National Toxicology Program (NTP) Status 3 – Reasonably anticipated to be Human Carcinogen
cobalt(II) 2-ethylhexanoate (136-52-7)
IARC group 2B – Possibly carcinogenic to humans
Reproductive toxicity : Suspected of damaging fertility or the unborn child.
Based on available data, the classification criteria are not met
Specific target organ toxicity single exposure : May cause respiratory irritation.
Specific target organ toxicity repeated
exposure
: Causes damage to organs through prolonged or repeated exposure.
Aspiration hazard : Not classified
Potential Adverse human health effects and
symptoms
: Harmful if inhaled. Based on available data, the classification criteria are not met.
Symptoms/effects after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled. May cause respiratory irritation.
Symptoms/effects after skin contact : Causes skin irritation. Irritation. May cause an allergic skin reaction.
Symptoms/effects after eye contact : Causes serious eye irritation.
SECTION 12: Ecological information
12.1. Toxicity
Ecology – general : Harmful to aquatic life.
cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 1 46.51 mg/l (LOEC; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 1 0.212 mg/l (NOEC; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
LC50 fish 2 54.1 mg/l (LC50; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 2 0.605 mg/l (LC50; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
Threshold limit algae 1 144 g/l (ErC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
Threshold limit algae 2 32.2 g/l (NOEC; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
2-hydroxyethyl methacrylate, stabilized (868-77-9)
LC50 fish 1 227 mg/l (LC50; 96 h)
EC50 Daphnia 1 171 mg/l (NOEC; OECD 202: Daphnia sp. Acute Immobilisation Test; 48 h; Daphnia magna;
Static system; Fresh water; Experimental value)
EC50 Daphnia 2 380 mg/l (EC50; OECD 202: Daphnia sp. Acute Immobilisation Test; 48 h; Daphnia magna;
Static system; Fresh water; Experimental value)
Threshold limit algae 1 836 mg/l (ErC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Experimental value)
Threshold limit algae 2 345 mg/l (EbC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Experimental value)
STYROSAFE LAMINATING RESIN
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
05/22/2018 EN (English US) 8/11
12.2. Persistence and degradability
STYROSAFE LAMINATING RESIN (mixture)
Persistence and degradability Not established.
styrene, inhibited (100-42-5)
Persistence and degradability Readily biodegradable in water. Not readily biodegradable in water. Forming sediments in
water. Non degradable in the soil. Adsorbs into the soil. Photodegradation in the air. Not
established.
Chemical oxygen demand (COD)
2.8 g O /g substance
ThOD
3.07 g O /g substance
BOD (% of ThOD) 0.42
cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability Readily biodegradable in water. No (test)data on mobility of the substance available.
Unsaturated Polyester Resin (TRADE SECRET)
Persistence and degradability Not established.
2-hydroxyethyl methacrylate, stabilized (868-77-9)
Persistence and degradability Readily biodegradable in water. Biodegradability in soil: no data available. Adsorbs into the
soil.
12.3. Bioaccumulative potential
STYROSAFE LAMINATING RESIN (mixture)
Bioaccumulative potential Not established.
styrene, inhibited (100-42-5)
BCF fish 1 35.5 (BCF)
Log Pow 2.96 (Experimental value; OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method; 25 C)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Not established.
cobalt(II) 2-ethylhexanoate (136-52-7)
BCF fish 1 1.2 (BCF; 131 days; Seriola quinqueradiata; Static system; Salt water; Read-across)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).
Unsaturated Polyester Resin (TRADE SECRET)
Bioaccumulative potential Not established.
2-hydroxyethyl methacrylate, stabilized (868-77-9)
BCF fish 1 1.3 - 1.5 (BCF)
Log Pow -0.55 - 0.49
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).
12.4. Mobility in soil
styrene, inhibited (100-42-5)
Surface tension 0.032 N/m (19 C)
Log Koc Koc,352; Estimated value; log Koc; 2.55; Estimated value
cobalt(II) 2-ethylhexanoate (136-52-7)
Surface tension 0.064 N/m (20 C; 1 g/l)
12.5. Other adverse effects
Effect on the global warming : No known effects from this product.
GWPmix comment : No known effects from this product.
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations
13.1. Disposal methods
Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions.
Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to approved disposal site.
STYROSAFE LAMINATING RESIN
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
05/22/2018 EN (English US) 9/11
Additional information : Handle empty containers with care because residual vapors are flammable. Flammable vapors
may accumulate in the container.
Ecology - waste materials : Avoid release to the environment.
SECTION 14: Transport information
Department of Transportation (DOT)
In accordance with DOT
Proper Shipping Name (DOT) : RESIN SOLUTION
Class (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120
Packing group (DOT) : III - Minor Danger
Hazard labels (DOT) : 3 - Flammable liquid
Other information : No supplementary information available.
Transportation of Dangerous Goods
Transport by sea
Transport document description (IMDG) : UN 1866 RESIN SOLUTION, 3, III
UN-No. (IMDG) : 1866
Proper Shipping Name (IMDG) : RESIN SOLUTION
Class (IMDG) : 3 - Flammable liquids
Packing group (IMDG) : III - substances presenting low danger
Air transport
Transport document description (IATA) : UN 1866 RESIN SOLUTION, 3, III
UN-No. (IATA) : 1866
Proper Shipping Name (IATA) : RESIN SOLUTION
Class (IATA) : 3 - Flammable Liquids
Packing group (IATA) : III - Minor Danger
SECTION 15: Regulatory information
15.1. US Federal regulations
styrene, inhibited (100-42-5)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
CERCLA RQ 1000 lb
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Reactive hazard
Fire hazard
Delayed (chronic) health hazard
cobalt(II) 2-ethylhexanoate (136-52-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Unsaturated Polyester Resin (TRADE SECRET)
Not listed on the United States TSCA (Toxic Substances Control Act) inventory
2-hydroxyethyl methacrylate, stabilized (868-77-9)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
STYROSAFE LAMINATING RESIN
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
05/22/2018 EN (English US) 10/11
15.2. International regulations
CANADA
styrene, inhibited (100-42-5)
Listed on the Canadian DSL (Domestic Substances List)
cobalt(II) 2-ethylhexanoate (136-52-7)
Listed on the Canadian DSL (Domestic Substances List)
Unsaturated Polyester Resin (TRADE SECRET)
Not listed on the Canadian DSL (Domestic Substances List)/NDSL (Non-Domestic Substances List)
2-hydroxyethyl methacrylate, stabilized (868-77-9)
Listed on the Canadian DSL (Domestic Substances List)
EU-Regulations
No additional information available
National regulations
styrene, inhibited (100-42-5)
Listed on IARC (International Agency for Research on Cancer)
Listed as carcinogen on NTP (National Toxicology Program)
15.3. US State regulations
styrene, inhibited (100-42-5)
U.S. - California -
Proposition 65 -
Carcinogens List
U.S. - California -
Proposition 65 -
Developmental Toxicity
U.S. - California -
Proposition 65 -
Reproductive Toxicity -
Female
U.S. - California -
Proposition 65 -
Reproductive Toxicity -
Male
No significant risk
level (NSRL)
Yes No No No 0.1 g/day
styrene, inhibited (100-42-5)
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) List
SECTION 16: Other information
Other information : None.
STYROSAFE LAMINATING RESIN
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
05/22/2018 EN (English US) 11/11
Full text of H-phrases:
---
---
H226 Flammable liquid and vapor
---
---
H315 Causes skin irritation
---
---
H317 May cause an allergic skin reaction
---
---
H319 Causes serious eye irritation
---
---
H332 Harmful if inhaled
---
---
H335 May cause respiratory irritation
---
---
H351 Suspected of causing cancer
---
---
H361 Suspected of damaging fertility or the unborn child
---
---
H372 Causes damage to organs through prolonged or repeated exposure
---
---
H400 Very toxic to aquatic life
---
---
H402 Harmful to aquatic life
---
---
H411 Toxic to aquatic life with long lasting effects
NFPA health hazard : 2 - Materials that, under emergency conditions, can cause
temporary incapacitation or residual injury.
NFPA fire hazard : 3 - Liquids and solids (including finely divided suspended
solids) that can be ignited under almost all ambient
temperature conditions.
NFPA reactivity : 2 - Materials that readily undergo violent chemical change
at elevated temperatures and pressures.
Hazard Rating
Health : 2 Moderate Hazard - Temporary or minor injury may occur
Flammability : 3 Serious Hazard - Materials capable of ignition under almost all normal temperature
conditions. Includes flammable liquids with flash points below 73 F and boiling points above
100 F. as well as liquids with flash points between 73 F and 100 F. (Classes IB & IC)
Physical : 1 Slight Hazard - Materials that are normally stable but can become unstable (self-react) at high
temperatures and pressures. Materials may react non-violently with water or undergo
hazardous polymerization in the absence of inhibitors.
Personal protection : H
H - Splash goggles, Gloves, Synthetic apron, Vapor respirator
SDS US (GHS HazCom 2012)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied
warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.
by | Sep 27, 2025
Page: 1
SAFETY DATA SHEET
Revision Date: 03/19/2024
Print Date: 3/22/2024
SDS Number: 000000179671
Derakane 510 B-400 epoxy vinyl ester resin
Trademark, INEOS or its subsidiaries, registered
in various countries
747899
Version: 1.15
1 / 21
29 CFR 1910.1200 (OSHA HazCom 2012)
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Product identifier
Trade name : Derakane 510 B-400
epoxy vinyl ester resin
Trademark, INEOS or its subsidiaries, registered in
various countries
Relevant identified uses of the substance or mixture and uses advised against
Recommended use
: Industrial chemical
Details of the supplier of the safety data
sheet
INEOS Composites US LLC
5220 Blazer Parkway
Dublin, OH 43017
United States of America (USA)
+1-614-790-9299 (in US)
sds.composites@ineos.com
Emergency telephone number
1-800-424-9300 (+1-703-527-3887 for direct
dial)
Regulatory Information Number
+1-614-790-9299 (in US), or contact your local
customer service representative
Product Information
+1-614-790-9299 (in US)
SECTION 2. HAZARDS IDENTIFICATION
GHS Classification
Flammable liquids
: Category 3
Combustible Dust
:
Skin irritation
: Category 2
Eye irritation
: Category 2A
Specific target organ toxicity
– single exposure
: Category 3 (Respiratory system)
Specific target organ toxicity
– repeated exposure
(Inhalation)
: Category 1 (Auditory system)
GHS label elements
Page: 2
SAFETY DATA SHEET
Revision Date: 03/19/2024
Print Date: 3/22/2024
SDS Number: 000000179671
Derakane 510 B-400 epoxy vinyl ester resin
Trademark, INEOS or its subsidiaries, registered
in various countries
747899
Version: 1.15
2 / 21
Hazard pictograms
:
Signal Word
: Danger
Hazard Statements
: Flammable liquid and vapor.
May form combustible dust concentrations in air.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Causes damage to organs (Auditory system) through prolonged
or repeated exposure if inhaled.
Precautionary Statements
: Prevention:
Keep away from heat/ sparks/ open flames/ hot surfaces. No
smoking.
Keep container tightly closed.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ ventilating/ lighting/ equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Do not breathe mist or vapors.
Wash skin thoroughly after handling.
Do not eat, drink or smoke when using this product.
Use only outdoors or in a well-ventilated area.
Wear protective gloves/ eye protection/ face protection.
Keep dust/air mixtures away from ignition sources.
Hazardous polymerization can occur under certain conditions.
Avoid excessive heat, direct sunlight, peroxides, and other
polymerization catalysts. Store in a cool place and maintain
proper concentrations of inhibitor and oxygen.
Response:
IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water/ shower.
IF INHALED: Remove person to fresh air and keep comfortable
for breathing. Call a POISON CENTER/ doctor if you feel
Page: 3
SAFETY DATA SHEET
Revision Date: 03/19/2024
Print Date: 3/22/2024
SDS Number: 000000179671
Derakane 510 B-400 epoxy vinyl ester resin
Trademark, INEOS or its subsidiaries, registered
in various countries
747899
Version: 1.15
3 / 21
unwell.
IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue
rinsing.
Get medical advice/ attention if you feel unwell.
If skin irritation occurs: Get medical advice/ attention.
If eye irritation persists: Get medical advice/ attention.
Take off contaminated clothing and wash before reuse.
In case of fire: Use dry sand, dry chemical or alcohol-resistant
foam to extinguish.
Storage:
Store in a well-ventilated place. Keep container tightly closed.
Store in a well-ventilated place. Keep cool.
Store locked up.
Disposal:
Dispose of contents/ container to an approved waste disposal
plant.
Other hazards
Static Accumulating liquid
Hazardous polymerization may occur.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture
: Mixture
Hazardous components
Chemical name CAS-No. Classification Concentration (%)
Styrene 100-42-5 Flam. Liq. 3; H226
Acute Tox. 4; H332
Skin Irrit. 2; H315
Eye Irrit. 2A; H319
STOT SE 3; H335
STOT RE 1; H372
Asp. Tox. 1; H304
39.3632
Page: 4
SAFETY DATA SHEET
Revision Date: 03/19/2024
Print Date: 3/22/2024
SDS Number: 000000179671
Derakane 510 B-400 epoxy vinyl ester resin
Trademark, INEOS or its subsidiaries, registered
in various countries
747899
Version: 1.15
4 / 21
SECTION 4. FIRST AID MEASURES
General advice
: Move out of dangerous area.
Call a POISON CENTRE or doctor/physician if exposed or
you feel unwell.
Show this safety data sheet to the doctor in attendance.
Do not leave the victim unattended.
If inhaled
: Move to fresh air.
IF INHALED: Call a POISON CENTER/ doctor if you feel
unwell.
Keep patient warm and at rest.
If unconscious, place in recovery position and seek medical
advice.
In case of skin contact
: Remove contaminated clothing. If irritation develops, get
medical attention.
If on skin, rinse well with water.
Wash contaminated clothing before re-use.
If on clothes, remove clothes.
In case of eye contact
: Immediately flush eye(s) with plenty of water.
Remove contact lenses.
Protect unharmed eye.
If swallowed
: Obtain medical attention.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
Most important symptoms
and effects, both acute and
delayed
: Signs and symptoms of exposure to this material through
breathing, swallowing, and/or passage of the material through
the skin may include:
stomach or intestinal upset (nausea, vomiting, diarrhea)
irritation (nose, throat, airways)
confusion
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Causes damage to organs through prolonged or repeated
exposure if inhaled.
Notes to physician
: No hazards which require special first aid measures.
Page: 5
SAFETY DATA SHEET
Revision Date: 03/19/2024
Print Date: 3/22/2024
SDS Number: 000000179671
Derakane 510 B-400 epoxy vinyl ester resin
Trademark, INEOS or its subsidiaries, registered
in various countries
747899
Version: 1.15
5 / 21
SECTION 5. FIREFIGHTING MEASURES
Suitable extinguishing media
: Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Water spray
Foam
Alcohol-resistant foam
Carbon dioxide (CO2)
Dry chemical
Unsuitable extinguishing
media
: High volume water jet
Specific hazards during
firefighting
: Organic dusts at sufficient concentration can form explosive
mixtures in air.
Never use welding or cutting torch on or near drum (even
empty) because product (even just residue) can ignite
explosively.
Beware of vapours accumulating to form explosive
concentrations. Vapours can accumulate in low areas.
Do not allow run-off from fire fighting to enter drains or water
courses.
Hazardous combustion
products
: Carbon dioxide (CO2)
Carbon monoxide
Hydrocarbons
Specific extinguishing
methods
:
Product is compatible with standard fire-fighting agents.
Further information : Do not use a solid water stream as it may scatter and spread
fire.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
Use a water spray to cool fully closed containers.
Polymerization will take place under fire conditions. If
polymerization occurs in a closed container, there is a
possibility it will rupture violently. Cool storage container with
water, if exposed to fire.
Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
Page: 6
SAFETY DATA SHEET
Revision Date: 03/19/2024
Print Date: 3/22/2024
SDS Number: 000000179671
Derakane 510 B-400 epoxy vinyl ester resin
Trademark, INEOS or its subsidiaries, registered
in various countries
747899
Version: 1.15
6 / 21
for firefighters
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions,
protective equipment and
emergency procedures
: Evacuate personnel to safe areas.
Remove all sources of ignition.
Use personal protective equipment.
Ensure adequate ventilation.
Beware of vapours accumulating to form explosive
concentrations. Vapours can accumulate in low areas.
Persons not wearing protective equipment should be excluded
from area of spill until clean-up has been completed.
Environmental precautions
: Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.
Methods and materials for
containment and cleaning up
: Contain spillage, and then collect with non-combustible
absorbent material, (e.g. sand, earth, diatomaceous earth,
vermiculite) and place in container for disposal according to
local / national regulations (see section 13).
Other information
: Comply with all applicable federal, state, and local regulations.
Suppress (knock down) gases/vapours/mists with a water
spray jet.
SECTION 7. HANDLING AND STORAGE
Advice on protection against
fire and explosion
: Take necessary action to avoid static electricity discharge
(which might cause ignition of organic vapours).
No sparking tools should be used.
Keep away from open flames, hot surfaces and sources of
ignition.
Use only explosion-proof equipment.
Static ignition hazard can result from handling and use.
Electrically bond and ground all containers, personnel and
equipment before transfer or use of material. Special
precautions may be necessary to dissipate static electricity for
non-conductive containers. Use proper bonding and
grounding during product transfer as described in National
Fire Protection Association document NFPA 77.
Page: 7
SAFETY DATA SHEET
Revision Date: 03/19/2024
Print Date: 3/22/2024
SDS Number: 000000179671
Derakane 510 B-400 epoxy vinyl ester resin
Trademark, INEOS or its subsidiaries, registered
in various countries
747899
Version: 1.15
7 / 21
Advice on safe handling
: Open drum carefully as content may be under pressure.
Avoid formation of aerosol.
Provide sufficient air exchange and/or exhaust in work rooms.
Do not breathe vapours/dust.
Do not smoke.
Container hazardous when empty.
Take precautionary measures against static discharges.
Avoid exposure – obtain special instructions before use.
Avoid contact with skin and eyes.
Smoking, eating and drinking should be prohibited in the
application area.
For personal protection see section 8.
Dispose of rinse water in accordance with local and national
regulations.
Secondary operations, such as grinding and sanding, may
produce dust.
Maintain good housekeeping. Do not permit dust layers to
accumulate, for example, on floors, ledges, and equipment, in
order to avoid any potential for dust explosion hazards.
For further guidance on prevention of dust explosions, refer to
National Fire Protection Association (NFPA) 654: Standard
for the Prevention of Fire and Dust Explosions, from the
Manufacturing, Processing and Handling of Combustible
Particulate Solids .
Conditions for safe storage
: Keep container tightly closed in a dry and well-ventilated
place.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.
Observe label precautions.
No smoking.
Further information on
storage stability
: No decomposition if stored and applied as directed.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
Components CAS-No. Value type
(Form of
exposure)
Control
parameters /
Permissible
concentration
Basis
Styrene 100-42-5 TWA 50 ppm
215 mg/m3
NIOSH REL
Page: 8
SAFETY DATA SHEET
Revision Date: 03/19/2024
Print Date: 3/22/2024
SDS Number: 000000179671
Derakane 510 B-400 epoxy vinyl ester resin
Trademark, INEOS or its subsidiaries, registered
in various countries
747899
Version: 1.15
8 / 21
ST 100 ppm
425 mg/m3
NIOSH REL
TWA 100 ppm OSHA Z-2
CEIL 200 ppm OSHA Z-2
Peak 600 ppm OSHA Z-2
TWA 50 ppm
215 mg/m3
OSHA P0
STEL 100 ppm
425 mg/m3
OSHA P0
C 500 ppm CAL PEL
PEL 50 ppm
215 mg/m3
CAL PEL
STEL 100 ppm
425 mg/m3
CAL PEL
TWA 10 ppm ACGIH
STEL 20 ppm ACGIH
Biological occupational exposure limits
Components CAS-No. Control
parameters
Biological
specimen
Sampling
time
Permissible
concentrati
on
Basis
Styrene 100-42-5 Mandelic
acid plus
phenylglyox
ylic acid
Urine End of
shift (As
soon as
possible
after
exposure
ceases)
150 mg/g
creatinine
ZUS_A
CGIHB
Remarks: Nonspecific, 2023 adoption
Styrene Urine End of
shift (As
soon as
possible
after
exposure
ceases)
20 g/l ZUS_A
CGIHB
Remarks: 2023 adoption
Engineering measures : Provide sufficient mechanical (general and/or local exhaust)
ventilation to maintain exposure below exposure guidelines (if
applicable) or below levels that cause known, suspected or
apparent adverse effects.
Provide appropriate exhaust ventilation at places where dust
is formed.
Personal protective equipment
Respiratory protection : In the case of vapour formation use a respirator with an
Page: 9
SAFETY DATA SHEET
Revision Date: 03/19/2024
Print Date: 3/22/2024
SDS Number: 000000179671
Derakane 510 B-400 epoxy vinyl ester resin
Trademark, INEOS or its subsidiaries, registered
in various countries
747899
Version: 1.15
9 / 21
approved filter.
Filter type : Organic vapour type
Hand protection
Material : Laminate (Barrier or Silvershield )
Break through time : 480 min
Glove thickness : > 0.5 mm
Remarks : The exact break through time can be obtained from the
protective glove producer and this has to be observed. Gloves
should be discarded and replaced if there is any indication of
degradation or chemical breakthrough.
The suitability for a specific workplace should be discussed
with the producers of the protective gloves.
Eye protection : Wear chemical splash goggles when there is the potential for
exposure of the eyes to liquid, vapor or mist.
Skin and body protection : Wear as appropriate:
Impervious clothing
Safety shoes
Flame-resistant clothing
Choose body protection according to the amount and
concentration of the dangerous substance at the work place.
Discard gloves that show tears, pinholes, or signs of wear.
Wear resistant gloves (consult your safety equipment
supplier).
Hygiene measures : Wash hands before breaks and at the end of workday.
When using do not eat or drink.
When using do not smoke.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state
: liquid
Odour
: aromatic
Odour Threshold
: No data available
pH
: Not applicable
Melting point/freezing point
: not determined
Boiling point/boiling range : 293 F / 145 C
Page: 10
SAFETY DATA SHEET
Revision Date: 03/19/2024
Print Date: 3/22/2024
SDS Number: 000000179671
Derakane 510 B-400 epoxy vinyl ester resin
Trademark, INEOS or its subsidiaries, registered
in various countries
747899
Version: 1.15
10 / 21
Value for Component
Flash point
: 29.4 C
Method: ASTM D 56
Evaporation rate
: No data available
Flammability (solid, gas)
: May form combustible dust concentrations in air (during
processing).
Flammability (liquids) :
Flammability (liquids) : Static Accumulating liquid
Upper explosion limit
: Upper flammability limit
6.1 %(V)
Value for Component
Lower explosion limit
: Lower flammability limit
1.1 %(V)
Value for Component
Vapour pressure
: 6.67 hPa (20 C)
Value for Component
Relative vapour density
: No data available
Relative density
: No data available
Density
: 1.15 g/cm3 (25 C)
Solubility(ies)
Water solubility
: insoluble
Solubility in other solvents
: No data available
Partition coefficient: n-
octanol/water
: No data available
Thermal decomposition
: No data available
Viscosity
Viscosity, dynamic
: 300 – 500 mPa.s (25 C)
Viscosity, kinematic
: > 20.5 mm2/s (40 C)
Page: 11
SAFETY DATA SHEET
Revision Date: 03/19/2024
Print Date: 3/22/2024
SDS Number: 000000179671
Derakane 510 B-400 epoxy vinyl ester resin
Trademark, INEOS or its subsidiaries, registered
in various countries
747899
Version: 1.15
11 / 21
Oxidizing properties
: No data available
SECTION 10. STABILITY AND REACTIVITY
Reactivity
: No decomposition if stored and applied as directed.
Chemical stability
: Stable under recommended storage conditions.
Possibility of hazardous
reactions
: Hazardous polymerisation may occur.
Vapours may form explosive mixture with air.
This product does not present a dust explosion hazard as
delivered. However, fine dust dispersed in air in sufficient
concentrations, and in the presence of an ignition source, is a
potential dust explosion hazard.
Conditions to avoid
: Exposure to air.
Exposure to sunlight.
Heat, flames and sparks.
Incompatible materials
: Acids
aluminum
aluminum chloride
Bases
Copper
Copper alloys
halogens
iron chloride
metal salts
Strong oxidizing agents
Peroxides
Hazardous decomposition
products
Hydrocarbons
Acetone
Carbon dioxide (CO2)
Carbon monoxide
SECTION 11. TOXICOLOGICAL INFORMATION
Information on likely routes of
exposure
: Inhalation
Skin contact
Eye Contact
Page: 12
SAFETY DATA SHEET
Revision Date: 03/19/2024
Print Date: 3/22/2024
SDS Number: 000000179671
Derakane 510 B-400 epoxy vinyl ester resin
Trademark, INEOS or its subsidiaries, registered
in various countries
747899
Version: 1.15
12 / 21
Ingestion
Acute toxicity
Not classified based on available information.
Components:
Styrene:
Acute oral toxicity
: LD50 (Rat): > 2,000 mg/kg
Acute inhalation toxicity
: LC50 (Rat): 11.8 mg/l, 2770 ppm
Exposure time: 4 h
Test atmosphere: vapour
No observed adverse effect level (Humans): 100 ppm
Exposure time: 7 h
Test atmosphere: vapour
Acute dermal toxicity
: LD50 (Rat): > 2,000 mg/kg
Method: OECD Test Guideline 402
Assessment: No adverse effect has been observed in acute
dermal toxicity tests.
Skin corrosion/irritation
Causes skin irritation.
Product:
Remarks: May cause skin irritation and/or dermatitis.
Result: Repeated exposure may cause skin dryness or cracking.
Components:
Styrene:
Species: Rabbit
Result: Irritating to skin.
Species: human skin
Result: No skin irritation
Serious eye damage/eye irritation
Causes serious eye irritation.
Product:
Remarks: Vapours may cause irritation to the eyes, respiratory system and the skin., Causes
serious eye irritation.
Components:
Styrene:
Result: Irritating to eyes.
Remarks: Vapour during processing may be irritating to the respiratory tract and to the eyes.
Page: 13
SAFETY DATA SHEET
Revision Date: 03/19/2024
Print Date: 3/22/2024
SDS Number: 000000179671
Derakane 510 B-400 epoxy vinyl ester resin
Trademark, INEOS or its subsidiaries, registered
in various countries
747899
Version: 1.15
13 / 21
Respiratory or skin sensitisation
Skin sensitisation: Not classified based on available information.
Respiratory sensitisation: Not classified based on available information.
Components:
Styrene:
Exposure routes: Skin contact
Species: Guinea pig
Assessment: Does not cause skin sensitisation.
Result: negative
Exposure routes: inhalation (vapour)
Species: Humans
Assessment: Does not cause respiratory sensitisation.
Result: negative
Germ cell mutagenicity
Not classified based on available information.
Carcinogenicity
Not classified based on available information.
Product:
Carcinogenicity –
Assessment
: Styrene has been tested for carcinogenicity in rats and mice.
Styrene caused lung tumors in mice only. These tumors are
not considered to be relevant to humans.
Reproductive toxicity
Not classified based on available information.
STOT – single exposure
May cause respiratory irritation.
Components:
Styrene:
Assessment: May cause respiratory irritation.
STOT – repeated exposure
Causes damage to organs (Auditory system) through prolonged or repeated exposure if inhaled.
Components:
Styrene:
Exposure routes: inhalation (vapour)
Target Organs: Auditory system
Assessment: Causes damage to organs through prolonged or repeated exposure.
Repeated dose toxicity
Components:
Styrene:
Species: Human
85 mg/m3
Application Route: inhalation (vapour)
Page: 14
SAFETY DATA SHEET
Revision Date: 03/19/2024
Print Date: 3/22/2024
SDS Number: 000000179671
Derakane 510 B-400 epoxy vinyl ester resin
Trademark, INEOS or its subsidiaries, registered
in various countries
747899
Version: 1.15
14 / 21
Species: Human
615 mg/kg
Application Route: Skin contact
Aspiration toxicity
Not classified based on available information.
Components:
Styrene:
May be fatal if swallowed and enters airways.
Further information
Product:
Remarks: Solvents may degrease the skin.
Carcinogenicity:
IARC
Group 2A: Probably carcinogenic to humans
Styrene
100-42-5
OSHA
No component of this product present at levels greater than or
equal to 0.1% is on OSHA s list of regulated carcinogens.
NTP
Reasonably anticipated to be a human carcinogen
Styrene
100-42-5
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Product:
Ecotoxicology Assessment
Short-term (acute) aquatic
hazard
: Acute aquatic toxicity Category 2; Toxic to aquatic life.
Long-term (chronic) aquatic
hazard
: Not classified based on available information.
Components:
Styrene:
Toxicity to fish
: LC50 (Pimephales promelas (fathead minnow)): 4.02 mg/l
Exposure time: 96 h
Toxicity to daphnia and other
aquatic invertebrates
: EC50 (Daphnia magna (Water flea)): 4.7 mg/l
Exposure time: 48 h
Page: 15
SAFETY DATA SHEET
Revision Date: 03/19/2024
Print Date: 3/22/2024
SDS Number: 000000179671
Derakane 510 B-400 epoxy vinyl ester resin
Trademark, INEOS or its subsidiaries, registered
in various countries
747899
Version: 1.15
15 / 21
Toxicity to algae
: ErC50 (Pseudokirchneriella subcapitata (green algae)): 4.9
mg/l
Exposure time: 72 h
Toxicity to daphnia and other
aquatic invertebrates
(Chronic toxicity)
: NOEC (Daphnia magna (Water flea)): 1.01 mg/l
Exposure time: 21 d
Toxicity to bacteria
: EC50 (activated sludge): ca. 500 mg/l
Exposure time: 0.5 h
Toxicity to soil dwelling
organisms
: NOEC (Eisenia fetida (earthworms)): 34 mg/kg
Exposure time: 14 d
Method: OECD Test Guideline 207
Persistence and degradability
Components:
Styrene:
Biodegradability
: Result: Readily biodegradable.
Biodegradation: > 60 %
Exposure time: 10 d
No data available
Bioaccumulative potential
Components:
Styrene:
Bioaccumulation
: Bioconcentration factor (BCF): < 100
Partition coefficient: n-
octanol/water
: log Pow: 2.96 (25 C)
No data available
Mobility in soil
Components:
Styrene:
Distribution among
environmental compartments
: Koc: 352
No data available
Other adverse effects
Product:
Regulation
40 CFR Protection of Environment; Part 82 Protection of
Stratospheric Ozone - CAA Section 602 Class I Substances
Remarks
This product neither contains, nor was manufactured with a
Class I or Class II ODS as defined by the U.S. Clean Air Act
Section 602 (40 CFR 82, Subpt. A, App.A + B).
Page: 16
SAFETY DATA SHEET
Revision Date: 03/19/2024
Print Date: 3/22/2024
SDS Number: 000000179671
Derakane 510 B-400 epoxy vinyl ester resin
Trademark, INEOS or its subsidiaries, registered
in various countries
747899
Version: 1.15
16 / 21
Additional ecological
information
: An environmental hazard cannot be excluded in the event of
unprofessional handling or disposal., Toxic to aquatic life.
Components:
Styrene:
Results of PBT and vPvB
assessment
: This substance is not considered to be persistent,
bioaccumulating and toxic (PBT). This substance is not
considered to be very persistent and very bioaccumulating
(vPvB).
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
General advice : The product should not be allowed to enter drains, water
courses or the soil.
Do not contaminate ponds, waterways or ditches with
chemical or used container.
Send to a licensed waste management company.
Dispose of in accordance with all applicable local, state and
federal regulations.
Contaminated packaging : Empty remaining contents.
Dispose of as unused product.
Empty containers should be taken to an approved waste
handling site for recycling or disposal.
Do not re-use empty containers.
Do not burn, or use a cutting torch on, the empty drum.
SECTION 14. TRANSPORT INFORMATION
International transport regulations
REGULATION
ID NUMBER PROPER SHIPPING NAME *HAZARD
CLASS
SUBSIDIARY
HAZARDS
PACKING
GROUP
MARINE
POLLUTANT /
LTD. QTY.
MX_DG
UN 1866 RESIN SOLUTION 3 III
INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER
Page: 17
SAFETY DATA SHEET
Revision Date: 03/19/2024
Print Date: 3/22/2024
SDS Number: 000000179671
Derakane 510 B-400 epoxy vinyl ester resin
Trademark, INEOS or its subsidiaries, registered
in various countries
747899
Version: 1.15
17 / 21
UN 1866 Resin solution 3 III
INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO
UN 1866 Resin solution 3 III
INTERNATIONAL MARITIME DANGEROUS GOODS
UN 1866 RESIN SOLUTION 3 III
TDG_INWT_C
UN 1866 RESIN SOLUTION 3 III
TDG_RAIL_C
UN 1866 RESIN SOLUTION 3 III
TDG_ROAD_C
UN 1866 RESIN SOLUTION 3 III
U.S. DOT - INLAND WATERWAYS
UN 1866 Resin solution 3 III
CFR_RAIL_C
UN 1866 Resin solution 3 III
U.S. DOT - ROAD
UN 1866 Resin solution 3 III
*ORM = ORM-D, CBL = COMBUSTIBLE LIQUID
Marine pollutant no
Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific
exceptions that can be applied. Consult shipping documents for descriptions that are specific to the
shipment.
Page: 18
SAFETY DATA SHEET
Revision Date: 03/19/2024
Print Date: 3/22/2024
SDS Number: 000000179671
Derakane 510 B-400 epoxy vinyl ester resin
Trademark, INEOS or its subsidiaries, registered
in various countries
747899
Version: 1.15
18 / 21
SECTION 15. REGULATORY INFORMATION
TSCA list
No substances are subject to a Significant New Use Rule.
No substances are subject to TSCA 12(b) export notification requirements.
EPCRA - Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity
Components CAS-No. Component RQ
(lbs)
Calculated product RQ
(lbs)
Styrene 100-42-5 1000 2540
SARA 304 Extremely Hazardous Substances Reportable Quantity
Components CAS-No. Component RQ
(lbs)
Calculated product RQ
(lbs)
HYDROQUINONE 123-31-9 100 *
*: Calculated RQ exceeds reasonably attainable upper limit.
SARA 311/312 Hazards : Flammable (gases, aerosols, liquids, or solids)
Combustible Dust
Hazard not otherwise classified (physical hazards)
Skin corrosion or irritation
Serious eye damage or eye irritation
Specific target organ toxicity (single or repeated exposure)
SARA 302 : This material does not contain any components with a section
302 EHS TPQ.
SARA 313 The following components are subject to reporting levels
established by SARA Title III, Section 313. For components
displaying a value of 0%, the level is below 1ppm or has been
reported to us from a supplier as a trace component with an
indeterminate value:
Styrene
100-42-5 39.3632%
TETRABROMOBISPHEN
OL A
79-94-7 0.0196%
Page: 19
SAFETY DATA SHEET
Revision Date: 03/19/2024
Print Date: 3/22/2024
SDS Number: 000000179671
Derakane 510 B-400 epoxy vinyl ester resin
Trademark, INEOS or its subsidiaries, registered
in various countries
747899
Version: 1.15
19 / 21
California Prop. 65
WARNING: This product can expose you to chemicals including styrene, ethylbenzene,
tetrabromobisphenol-A, benzene, which is/are known to the State of California to cause cancer,
and ethylene glycol, toluene, benzene, which is/are known to the State of California to cause birth
defects or other reproductive harm. For more information go to www.P65Warnings.ca.gov.
The components of this product are reported in the following inventories:
TCSI
: Not in compliance with the inventory
TSCA
: On or in compliance with the active portion of the TSCA
inventory
AIIC
: On the inventory, or in compliance with the inventory
DSL
: This product contains one or several components that are not
on the Canadian DSL and have annual quantity limits.
ENCS
: Not in compliance with the inventory
ISHL
: Not in compliance with the inventory
KECI
: On the inventory, or in compliance with the inventory
PICCS
: Not in compliance with the inventory
IECSC
: On the inventory, or in compliance with the inventory
NZIoC
: Not in compliance with the inventory
Inventories
AIIC (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL
(Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TECI
(Thailand), TSCA (USA)
SECTION 16. OTHER INFORMATION
Further information
Revision Date: 03/19/2024
NFPA: HMIS III:
Page: 20
SAFETY DATA SHEET
Revision Date: 03/19/2024
Print Date: 3/22/2024
SDS Number: 000000179671
Derakane 510 B-400 epoxy vinyl ester resin
Trademark, INEOS or its subsidiaries, registered
in various countries
747899
Version: 1.15
20 / 21
NFPA Flammable and Combustible Liquids Classification
Flammable Liquid Class IC
Full text of H-Statements
H226 Flammable liquid and vapor.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H372 Causes damage to organs through prolonged or repeated exposure if
inhaled.
Sources of key data used to compile the Safety Data Sheet
INEOS internal data including own and sponsored test reports
The UNECE administers regional agreements implementing harmonised classification for
labelling (GHS) and transport.
The information accumulated herein is believed to be accurate but is not warranted to be whether
originating with the company or not. Recipients are advised to confirm in advance of need that the
information is current, applicable, and suitable to their circumstances. This SDS has been
prepared by INEOS's Environmental Health and Safety Department +1-614-790-9299 (in US).
Flammability
Health
Instability
2
3
2
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
3
2
2*
Special hazard
0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic
Page: 21
SAFETY DATA SHEET
Revision Date: 03/19/2024
Print Date: 3/22/2024
SDS Number: 000000179671
Derakane 510 B-400 epoxy vinyl ester resin
Trademark, INEOS or its subsidiaries, registered
in various countries
747899
Version: 1.15
21 / 21
Full text of other abbreviations
AIIC - Australian Inventory of Industrial Chemicals; ASTM - American Society for the Testing of
Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response,
Compensation, and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN -
Standard of the German Institute for Standardisation; DOT - Department of Transportation; DSL -
Domestic Substances List (Canada); ECx - Concentration associated with x% response; EHS -
Extremely Hazardous Substance; ELx - Loading rate associated with x% response; EmS -
Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx -
Concentration associated with x% growth rate response; ERG - Emergency Response Guide;
GHS - Globally Harmonized System; GLP - Good Laboratory Practice; HMIS - Hazardous
Materials Identification System; IARC - International Agency for Research on Cancer; IATA -
International Air Transport Association; IBC - International Code for the Construction and
Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory
concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing
Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO -
International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO -
International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 -
Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population
(Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from
Ships; MSHA - Mine Safety and Health Administration; n.o.s. - Not Otherwise Specified; NFPA -
National Fire Protection Association; NO(A)EC - No Observed (Adverse) Effect Concentration;
NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate;
NTP - National Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD -
Organization for Economic Co-operation and Development; OPPTS - Office of Chemical Safety
and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS -
Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure
Activity Relationship; RCRA - Resource Conservation and Recovery Act; REACH - Regulation
(EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration,
Evaluation, Authorisation and Restriction of Chemicals; RQ - Reportable Quantity; SADT - Self-
Accelerating Decomposition Temperature; SARA - Superfund Amendments and Reauthorization
Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TECI - Thailand
Existing Chemicals Inventory; TSCA - Toxic Substances Control Act (United States); UN - United
Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods;
vPvB - Very Persistent and Very Bioaccumulative
by | Sep 27, 2025
SURBOARD LAMINATING RESIN
Unsaturated Polyester Resin
Liquid.
SAFETY DATA SHEET
GHS product identifier
Other means of identification
Product type
Emergency telephone
number (with hours of
operation)
Section 1. Identification
:
:
:
:
Supplier’s details :INTERPLASTIC CORPORATION
1225 Willow Lake Boulevard
St. Paul, MN 55110-5145
651.481.6860
SURBOARD LAMINATING RESIN
Relevant identified uses of the substance or mixture and uses advised against
Product code :SIL66BE-2880FN
Industrial applications.
CHEMTREC 24-Hour Emergency Telephone
US and Canada 800.424.9300
Outside US and Canada +1 703.741.5970
Section 2. Hazards identification
FLAMMABLE LIQUIDS – Category 2
ACUTE TOXICITY (inhalation) – Category 4
SKIN IRRITATION – Category 2
EYE IRRITATION – Category 2A
SKIN SENSITIZATION – Category 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) – Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) –
Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard statements :Highly flammable liquid and vapor.
Harmful if inhaled.
Causes serious eye irritation.
Causes skin irritation.
May cause an allergic skin reaction.
May cause respiratory irritation.
Causes damage to organs through prolonged or repeated exposure. (hearing organs)
Hazard pictograms :
Precautionary statements
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown dermal toxicity: 34.3%
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Date of issue/Date of revision :9/7/2018 Date of previous issue :No previous validationVersion:1 1/15
SURBOARD LAMINATING RESIN SIL66BE-2880FN
Section 2. Hazards identification
Prevention :Wear protective gloves. Wear eye or face protection. Keep away from heat, hot
surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-
proof electrical, ventilating, lighting and all material-handling equipment. Use only non-
sparking tools. Take precautionary measures against static discharge. Keep container
tightly closed. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Do
not eat, drink or smoke when using this product. Wash hands thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.
Response :Get medical attention if you feel unwell. IF INHALED: Remove person to fresh air and
keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell.
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water or shower. IF ON SKIN: Wash with plenty of soap and water. Wash
contaminated clothing before reuse. If skin irritation or rash occurs: Get medical
attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get
medical attention.
Storage :Store in a well-ventilated place. Keep cool. Store containers in a safe place.
Disposal :Dispose of contents and container in accordance with all local, regional, national and
international regulations. Do not pressurize, cut, weld, braze, solder, drill, grind or
expose containers to heat or sources of ignition.
Hazards not otherwise
classified
:None known.
Section 3. Composition/information on ingredients
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Other means of
identification
:Unsaturated Polyester Resin
Substance/mixture :
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Any concentration shown as exact is based on formula.
VOC content is listed in Section 9.
Environmental composition is shown in Section 15.
styrene <= 35.0 100-42-5
methyl methacrylate <= 5.0 80-62-6
Ingredient name % CAS number
Section 4. First aid measures
Eye contact :
Description of necessary first aid measures
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention. Buffered baby shampoo will aid in removal of resin.
Date of issue/Date of revision :9/7/2018 Date of previous issue :No previous validationVersion:1 2/15
SURBOARD LAMINATING RESIN SIL66BE-2880FN
Section 4. First aid measures
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention following
exposure or if feeling unwell. Never give anything by mouth to an unconscious person.
If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Get medical attention. In the event of any
complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean
shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Skin contact
Inhalation
Ingestion :
:
:
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Date of issue/Date of revision :9/7/2018 Date of previous issue :No previous validationVersion:1 3/15
SURBOARD LAMINATING RESIN SIL66BE-2880FN
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard.
In a fire or if heated, a pressure increase will occur and the container may burst, with the
risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along
the ground. Vapors may accumulate in low or confined areas or travel a considerable
distance to a source of ignition and flash back.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use dry chemical, CO , water spray (fog) or foam.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and
place in container for disposal according to local regulations (see Section 13). Dispose
of via a licensed waste disposal contractor. Contaminated absorbent material may pose
the same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal. Wear appropriate respiratory protection.
Wear protective clothing and eye or face protection:
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dispose of via a licensed waste disposal contractor.
Absorb with an inert material and transfer the spilled material and absorbent to an
appropriate waste disposal container. Wear appropriate respirator when ventilation is
inadequate. Wear eye/face protection.
Date of issue/Date of revision :9/7/2018 Date of previous issue :No previous validationVersion:1 4/15
SURBOARD LAMINATING RESIN SIL66BE-2880FN
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Do not store above the following temperature: 38 C (100.4 F). Store in accordance with
local regulations. Store in a segregated and approved area. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area, away from
incompatible materials (see Section 10) and food and drink. Eliminate all ignition
sources. Separate from oxidizing materials. Keep container tightly closed and sealed
until ready for use. Containers that have been opened must be carefully resealed and
kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate
containment to avoid environmental contamination. See Section 10 for incompatible
materials before handling or use. Store containers in a safe place.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Do not get in eyes or on skin or clothing. Do not breathe vapor or
mist. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator
when ventilation is inadequate. Do not enter storage areas and confined spaces unless
adequately ventilated. Keep in the original container or an approved alternative made
from a compatible material, kept tightly closed when not in use. Store and use away
from heat, sparks, open flame or any other ignition source. Use explosion-proof
electrical (ventilating, lighting and material handling) equipment. Use only non-sparking
tools. Take precautionary measures against electrostatic discharges. Empty containers
retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
styrene ACGIH TLV (United States, 3/2017).
TWA: 20 ppm 8 hours.
TWA: 85 mg/m 8 hours.
STEL: 40 ppm 15 minutes.
STEL: 170 mg/m 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
TWA: 50 ppm 8 hours.
TWA: 215 mg/m 8 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
OSHA PEL Z2 (United States, 2/2013).
TWA: 100 ppm 8 hours.
CEIL: 200 ppm
AMP: 600 ppm 5 minutes.
NIOSH REL (United States, 10/2016).
TWA: 50 ppm 10 hours.
TWA: 215 mg/m 10 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
methyl methacrylate ACGIH TLV (United States, 3/2017). Skin sensitizer.
TWA: 50 ppm 8 hours.
STEL: 100 ppm 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
Date of issue/Date of revision :9/7/2018 Date of previous issue :No previous validationVersion:1 5/15
SURBOARD LAMINATING RESIN SIL66BE-2880FN
Section 8. Exposure controls/personal protection
TWA: 100 ppm 8 hours.
TWA: 410 mg/m 8 hours.
NIOSH REL (United States, 10/2016).
TWA: 100 ppm 10 hours.
TWA: 410 mg/m 10 hours.
OSHA PEL (United States, 6/2016).
TWA: 100 ppm 8 hours.
TWA: 410 mg/m 8 hours.
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Date of issue/Date of revision :9/7/2018 Date of previous issue :No previous validationVersion:1 6/15
SURBOARD LAMINATING RESIN SIL66BE-2880FN
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
0.9 to 1.3
3.5 to 3.6 [Air = 1]
0.67 to 3.7 kPa (5 to 28 mm Hg) [room temperature]
Not available.
Aromatic. Sweetish.Odor
pH
Dark purple.Color
Evaporation rate 0.5 to 3.1 (butyl acetate = 1)
Auto-ignition temperature
Flash point
Not available.
Closed cup: 10 to 31 C (50 to 87.8 F)
Not available.
Not applicable.
Viscosity Not available.
0.1 ppmOdor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point :100 to 145 C (212 to 293 F)
Lower and upper explosive
(flammable) limits
:Lower: 0.9%
Upper: 12.5%
Solubility in water :Not applicable.
VOC content :39.4 % (w/w) As shipped, including monomers and additives.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Hazardous reactions or instability may occur under certain conditions of storage or use.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Hazardous polymerization may occur under certain conditions of storage or use. Keep
away from heat and direct sunlight. Keep away from heat and flame. Keep away from
oxidizing agents.
Reactive or incompatible with the following materials: metals, acids and alkalis.
Incompatible with alkali metals. Incompatible with some alkalis. Incompatible with some
strong acids. Incompatible with copper alloys, brass.
Date of issue/Date of revision :9/7/2018 Date of previous issue :No previous validationVersion:1 7/15
SURBOARD LAMINATING RESIN SIL66BE-2880FN
Section 11. Toxicological information
Acute toxicity
styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours
LC50 Inhalation Vapor Rat 11800 mg/m 4 hours
LD50 Oral Rat 2650 mg/kg -
methyl methacrylate LC50 Inhalation Vapor Rat 78000 mg/m 4 hours
LD50 Dermal Rabbit >5 g/kg –
LD50 Oral Rat 7872 mg/kg –
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Not available.
Conclusion/Summary :
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
styrene Eyes – Mild irritant Human – 50 parts per
million
–
Eyes – Moderate irritantRabbit – 24 hours 100
milligrams
–
Eyes – Severe irritantRabbit – 100
milligrams
–
Skin – Mild irritant Rabbit – 500
milligrams
–
Skin – Moderate irritantRabbit – 100 Percent-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
Information on toxicological effects
Classification
styrene – 2B Reasonably anticipated to be a human carcinogen.
methyl methacrylate – 3 –
Product/ingredient name NTPIARCOSHA
Styrene manufacturers have determined that the weight of evidence for the
carcinogenicity of this substance does not meet the criteria for classification.
Styrene is listed by IARC as a possible carcinogen to humans (Group 2B) based on
“limited evidence” in humans, “limited evidence” in animals and “other relevant data”.
The United States NTP listed styrene as reasonably anticipated to be a human
carcinogen based on “limited evidence” from studies in humans, “sufficient evidence”
from studies in experimental animals, and supporting data on mechanisms of
carcinogenesis. The significance of these results for humans has not been established
through risk assessment.
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SURBOARD LAMINATING RESIN SIL66BE-2880FN
Section 11. Toxicological information
Information on the likely
routes of exposure
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Specific target organ toxicity (repeated exposure)
styrene Category 3 Not applicable.Respiratory tract
irritation
methyl methacrylate Category 3 Not applicable.Respiratory tract
irritation
Name Category
Name Category
styrene Category 1 Inhalation hearing organs
Aspiration hazard
Name Result
styrene ASPIRATION HAZARD – Category 1
Route of
exposure
Target organs
Route of
exposure
Target organs
:Not available.
Potential acute health effects
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
A study of long term effects of workers exposed to styrene levels in the range of 25-35 ppm for an 8-hour TWA indicated
a possible mild hearing loss.
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SURBOARD LAMINATING RESIN SIL66BE-2880FN
Section 11. Toxicological information
Not available.
Causes damage to organs through prolonged or repeated exposure. Once sensitized, a
severe allergic reaction may occur when subsequently exposed to very low levels.
General :
No known significant effects or critical hazards.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Numerical measures of toxicity
Oral 7723.5 mg/kg
Inhalation (gases) 8073.3 ppm
Inhalation (vapors) 34.39 mg/l
Route ATE value
Acute toxicity estimates
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Product/ingredient name
styrene 0.35 13.49 low
methyl methacrylate 1.38 – low
Product/ingredient name Aquatic half-life Photolysis Biodegradability
styrene – – Readily
Toxicity
styrene Acute EC50 1400 g/l Fresh water Algae – Pseudokirchneriella
subcapitata
72 hours
Acute EC50 720 g/l Fresh water Algae – Pseudokirchneriella
subcapitata
96 hours
Acute EC50 4700 g/l Fresh water Daphnia – Daphnia magna 48 hours
Acute LC50 52 mg/l Marine water Crustaceans – Artemia salina48 hours
Acute LC50 4020 g/l Fresh water Fish – Pimephales promelas 96 hours
Chronic NOEC 63 g/l Fresh water Algae – Pseudokirchneriella
subcapitata
96 hours
methyl methacrylate Acute LC50 130000 g/l Fresh waterFish – Pimephales promelas –
Adult
96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
styrene OECD 70 % – Readily – 28 days – –
Product/ingredient name Test DoseResult Inoculum
Mobility in soil
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SURBOARD LAMINATING RESIN SIL66BE-2880FN
Section 12. Ecological information
Other adverse effects :No known significant effects or critical hazards.
Soil/water partition
coefficient (KOC)
:Not available.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
United States – RCRA Toxic hazardous waste “U” List
Methyl methacrylate (I,T); 2-Propenoic acid, 2-methyl-, methyl ester (I,T)80-62-6 Listed U162
Ingredient CAS # Status Reference
number
Section 14. Transport information
RESIN
SOLUTION
3
III
RESIN
SOLUTION
3
III
RESIN
SOLUTION
UN1866
3
III
UN1866 UN1866
Reportable quantity 2914.5 lbs / 1323.2 kg [317.78 gal / 1202.9 L]. Package sizes
shipped in quantities less than the product reportable quantity are not subject to the RQ
(reportable quantity) transportation requirements.
DOT
Classification
IMDGIATA
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional information
Environmental
hazards
No. No.No.
Product classified as per the following sections of the Transportation of Dangerous
Goods Regulations: 2.18-2.19 (Class 3).
Mexico
Classification
UN1866
RESIN
SOLUTION
3
III
No.
DOT Classification
TDG Classification
:
:
TDG
Classification
UN1866
RESIN
SOLUTION
3
III
No.
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SURBOARD LAMINATING RESIN SIL66BE-2880FN
Section 14. Transport information
Special precautions for user
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
Transport within user s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
:Not available.
:
Section 15. Regulatory information
U.S. Federal regulations
Clean Water Act (CWA) 307: Naphthenic acids, copper salts
Clean Water Act (CWA) 311: styrene; methyl methacrylate
:
SARA 313
Product name CAS number %
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
Form R – Reporting
requirements
Supplier notification
Clean Air Act Section 112
(b) Hazardous Air
Pollutants (HAPs)
:
Clean Air Act Section 602
Class I Substances
:Not listed
Clean Air Act Section 602
Class II Substances
:Not listed
TSCA 8(a) PAIR: Poly(oxy-1,2-ethanediyl), -[4-(1,1,3,3-tetramethylbutyl)phenyl]- –
hydroxy-; triethyl phosphate
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
TSCA 8(c) calls for record of SAR: triethyl phosphate
SARA 302/304
SARA 304 RQ :1446121.8 lbs / 656539.3 kg [157672.1 gal / 596853.9 L]
1,4-dihydroxybenzene <0.1 Yes.500 / 10000- 100 -
Composition/information on ingredients
Name % EHS(lbs) (lbs)(gallons) (gallons)
SARA 302 TPQ SARA 304 RQ
SARA 311/312
Classification :FLAMMABLE LIQUIDS - Category 2
ACUTE TOXICITY (inhalation) - Category 4
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SKIN SENSITIZATION - Category 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) -
Category 1
Styrene
Cobalt Compounds
Methyl methacrylate
Hydroquinone
styrene 100-42-5 <= 35.0
methyl methacrylate 80-62-6 <= 5.0
styrene 100-42-5 34.31
methyl methacrylate 80-62-6 5.00
Any concentration shown as exact is based on formula.
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SURBOARD LAMINATING RESIN SIL66BE-2880FN
Section 15. Regulatory information
The following components are listed: STYRENE; PHENYLETHYLENE; METHYL
METHACRYLATE
Massachusetts :
Styrene
California Prop. 65
New York :The following components are listed: Styrene; Methyl methacrylate; 2-Propenoic acid,
2-methyl-, methyl ester
New Jersey :The following components are listed: STYRENE MONOMER; BENZENE, ETHENYL-;
METHYL METHACRYLATE; 2-PROPENOIC ACID, 2-METHYL-, METHYL ESTER
Pennsylvania :The following components are listed: BENZENE, ETHENYL-; 2-PROPENOIC ACID,
2-METHYL-, METHYL ESTER
State regulations
Inventory list
Australia :All components are listed or exempted.
Canada :All components are listed or exempted.
China :All components are listed or exempted.
Europe :Not determined.
Japan :Japan inventory (ENCS): Not determined.
Japan inventory (ISHL): Not determined.
Republic of Korea :All components are listed or exempted.
Malaysia :Not determined.
New Zealand :All components are listed or exempted.
Philippines :Not determined.
Taiwan :All components are listed or exempted.
Turkey :Not determined.
United States :All components are listed or exempted.
Thailand :Not determined.
Viet Nam :Not determined.
:The following components are listed. For more information go to www.P65Warnings.ca.gov.
Section 16. Other information
Hazardous Material Information System (U.S.A.)
2
3
1
*
National Fire Protection Association (U.S.A.)
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS
ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS
Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual.
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SURBOARD LAMINATING RESIN SIL66BE-2880FN
Section 16. Other information
9/7/2018
History
Date of printing
Date of issue/Date of
revision
Version
Prepared by
Notice to reader
Date of previous issue
:
:
:
:
:
Indicates information that has changed from previously issued version.
References :
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
9/7/2018
No previous validation
1
1
3
2
Health
Special
Instability/Reactivity
Flammability
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Procedure used to derive the classification
Classification Justification
FLAMMABLE LIQUIDS - Category 2 On basis of test data
ACUTE TOXICITY (inhalation) - Category 4 Calculation method
SKIN IRRITATION - Category 2 Calculation method
EYE IRRITATION - Category 2A Calculation method
SKIN SENSITIZATION - Category 1 Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) -
Category 1
Calculation method
Health, Safety and Environmental Department
For questions about the
SDS, contact
:iasafety@ip-corporation.com
29 CFR 1910.1200 Hazard Communication Standard, March 2012
CCR Title 27 Division 4 Office of Environmental Health Hazard Assessment (California
Prop. 65)
American Composites Manufacturers Association
Styrene Information and Research Center
New form 08-2018
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SURBOARD LAMINATING RESIN SIL66BE-2880FN
Section 16. Other information
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Date of issue/Date of revision :9/7/2018 Date of previous issue :No previous validationVersion:1 15/15
by | Sep 27, 2025
SURBOARD LAMINATING RESIN
Unsaturated Polyester Resin
Liquid.
SAFETY DATA SHEET
GHS product identifier
Other means of identification
Product type
Emergency telephone
number (with hours of
operation)
Section 1. Identification
:
:
:
:
Supplier’s details :INTERPLASTIC CORPORATION
1225 Willow Lake Boulevard
St. Paul, MN 55110-5145
651.481.6860
SURBOARD LAMINATING RESIN
Relevant identified uses of the substance or mixture and uses advised against
Product code :SIL66BE-2880FN
Industrial applications.
CHEMTREC 24-Hour Emergency Telephone
US and Canada 800.424.9300
Outside US and Canada +1 703.741.5970
Section 2. Hazards identification
FLAMMABLE LIQUIDS – Category 2
ACUTE TOXICITY (inhalation) – Category 4
SKIN IRRITATION – Category 2
EYE IRRITATION – Category 2A
SKIN SENSITIZATION – Category 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) – Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) –
Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard statements :Highly flammable liquid and vapor.
Harmful if inhaled.
Causes serious eye irritation.
Causes skin irritation.
May cause an allergic skin reaction.
May cause respiratory irritation.
Causes damage to organs through prolonged or repeated exposure. (hearing organs)
Hazard pictograms :
Precautionary statements
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown dermal toxicity: 34.3%
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
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SURBOARD LAMINATING RESIN SIL66BE-2880FN
Section 2. Hazards identification
Prevention :Wear protective gloves. Wear eye or face protection. Keep away from heat, hot
surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-
proof electrical, ventilating, lighting and all material-handling equipment. Use only non-
sparking tools. Take precautionary measures against static discharge. Keep container
tightly closed. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Do
not eat, drink or smoke when using this product. Wash hands thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.
Response :Get medical attention if you feel unwell. IF INHALED: Remove person to fresh air and
keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell.
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water or shower. IF ON SKIN: Wash with plenty of soap and water. Wash
contaminated clothing before reuse. If skin irritation or rash occurs: Get medical
attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get
medical attention.
Storage :Store in a well-ventilated place. Keep cool. Store containers in a safe place.
Disposal :Dispose of contents and container in accordance with all local, regional, national and
international regulations. Do not pressurize, cut, weld, braze, solder, drill, grind or
expose containers to heat or sources of ignition.
Hazards not otherwise
classified
:None known.
Section 3. Composition/information on ingredients
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Other means of
identification
:Unsaturated Polyester Resin
Substance/mixture :
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Any concentration shown as exact is based on formula.
VOC content is listed in Section 9.
Environmental composition is shown in Section 15.
styrene <= 35.0 100-42-5
methyl methacrylate <= 5.0 80-62-6
Ingredient name % CAS number
Section 4. First aid measures
Eye contact :
Description of necessary first aid measures
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention. Buffered baby shampoo will aid in removal of resin.
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SURBOARD LAMINATING RESIN SIL66BE-2880FN
Section 4. First aid measures
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention following
exposure or if feeling unwell. Never give anything by mouth to an unconscious person.
If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Get medical attention. In the event of any
complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean
shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Skin contact
Inhalation
Ingestion :
:
:
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
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SURBOARD LAMINATING RESIN SIL66BE-2880FN
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard.
In a fire or if heated, a pressure increase will occur and the container may burst, with the
risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along
the ground. Vapors may accumulate in low or confined areas or travel a considerable
distance to a source of ignition and flash back.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use dry chemical, CO , water spray (fog) or foam.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and
place in container for disposal according to local regulations (see Section 13). Dispose
of via a licensed waste disposal contractor. Contaminated absorbent material may pose
the same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal. Wear appropriate respiratory protection.
Wear protective clothing and eye or face protection:
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dispose of via a licensed waste disposal contractor.
Absorb with an inert material and transfer the spilled material and absorbent to an
appropriate waste disposal container. Wear appropriate respirator when ventilation is
inadequate. Wear eye/face protection.
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SURBOARD LAMINATING RESIN SIL66BE-2880FN
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Do not store above the following temperature: 38 C (100.4 F). Store in accordance with
local regulations. Store in a segregated and approved area. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area, away from
incompatible materials (see Section 10) and food and drink. Eliminate all ignition
sources. Separate from oxidizing materials. Keep container tightly closed and sealed
until ready for use. Containers that have been opened must be carefully resealed and
kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate
containment to avoid environmental contamination. See Section 10 for incompatible
materials before handling or use. Store containers in a safe place.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Do not get in eyes or on skin or clothing. Do not breathe vapor or
mist. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator
when ventilation is inadequate. Do not enter storage areas and confined spaces unless
adequately ventilated. Keep in the original container or an approved alternative made
from a compatible material, kept tightly closed when not in use. Store and use away
from heat, sparks, open flame or any other ignition source. Use explosion-proof
electrical (ventilating, lighting and material handling) equipment. Use only non-sparking
tools. Take precautionary measures against electrostatic discharges. Empty containers
retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
styrene ACGIH TLV (United States, 3/2017).
TWA: 20 ppm 8 hours.
TWA: 85 mg/m 8 hours.
STEL: 40 ppm 15 minutes.
STEL: 170 mg/m 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
TWA: 50 ppm 8 hours.
TWA: 215 mg/m 8 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
OSHA PEL Z2 (United States, 2/2013).
TWA: 100 ppm 8 hours.
CEIL: 200 ppm
AMP: 600 ppm 5 minutes.
NIOSH REL (United States, 10/2016).
TWA: 50 ppm 10 hours.
TWA: 215 mg/m 10 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
methyl methacrylate ACGIH TLV (United States, 3/2017). Skin sensitizer.
TWA: 50 ppm 8 hours.
STEL: 100 ppm 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
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SURBOARD LAMINATING RESIN SIL66BE-2880FN
Section 8. Exposure controls/personal protection
TWA: 100 ppm 8 hours.
TWA: 410 mg/m 8 hours.
NIOSH REL (United States, 10/2016).
TWA: 100 ppm 10 hours.
TWA: 410 mg/m 10 hours.
OSHA PEL (United States, 6/2016).
TWA: 100 ppm 8 hours.
TWA: 410 mg/m 8 hours.
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
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SURBOARD LAMINATING RESIN SIL66BE-2880FN
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
0.9 to 1.3
3.5 to 3.6 [Air = 1]
0.67 to 3.7 kPa (5 to 28 mm Hg) [room temperature]
Not available.
Aromatic. Sweetish.Odor
pH
Dark purple.Color
Evaporation rate 0.5 to 3.1 (butyl acetate = 1)
Auto-ignition temperature
Flash point
Not available.
Closed cup: 10 to 31 C (50 to 87.8 F)
Not available.
Not applicable.
Viscosity Not available.
0.1 ppmOdor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point :100 to 145 C (212 to 293 F)
Lower and upper explosive
(flammable) limits
:Lower: 0.9%
Upper: 12.5%
Solubility in water :Not applicable.
VOC content :39.4 % (w/w) As shipped, including monomers and additives.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Hazardous reactions or instability may occur under certain conditions of storage or use.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Hazardous polymerization may occur under certain conditions of storage or use. Keep
away from heat and direct sunlight. Keep away from heat and flame. Keep away from
oxidizing agents.
Reactive or incompatible with the following materials: metals, acids and alkalis.
Incompatible with alkali metals. Incompatible with some alkalis. Incompatible with some
strong acids. Incompatible with copper alloys, brass.
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SURBOARD LAMINATING RESIN SIL66BE-2880FN
Section 11. Toxicological information
Acute toxicity
styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours
LC50 Inhalation Vapor Rat 11800 mg/m 4 hours
LD50 Oral Rat 2650 mg/kg -
methyl methacrylate LC50 Inhalation Vapor Rat 78000 mg/m 4 hours
LD50 Dermal Rabbit >5 g/kg –
LD50 Oral Rat 7872 mg/kg –
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Not available.
Conclusion/Summary :
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
styrene Eyes – Mild irritant Human – 50 parts per
million
–
Eyes – Moderate irritantRabbit – 24 hours 100
milligrams
–
Eyes – Severe irritantRabbit – 100
milligrams
–
Skin – Mild irritant Rabbit – 500
milligrams
–
Skin – Moderate irritantRabbit – 100 Percent-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
Information on toxicological effects
Classification
styrene – 2B Reasonably anticipated to be a human carcinogen.
methyl methacrylate – 3 –
Product/ingredient name NTPIARCOSHA
Styrene manufacturers have determined that the weight of evidence for the
carcinogenicity of this substance does not meet the criteria for classification.
Styrene is listed by IARC as a possible carcinogen to humans (Group 2B) based on
“limited evidence” in humans, “limited evidence” in animals and “other relevant data”.
The United States NTP listed styrene as reasonably anticipated to be a human
carcinogen based on “limited evidence” from studies in humans, “sufficient evidence”
from studies in experimental animals, and supporting data on mechanisms of
carcinogenesis. The significance of these results for humans has not been established
through risk assessment.
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SURBOARD LAMINATING RESIN SIL66BE-2880FN
Section 11. Toxicological information
Information on the likely
routes of exposure
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Specific target organ toxicity (repeated exposure)
styrene Category 3 Not applicable.Respiratory tract
irritation
methyl methacrylate Category 3 Not applicable.Respiratory tract
irritation
Name Category
Name Category
styrene Category 1 Inhalation hearing organs
Aspiration hazard
Name Result
styrene ASPIRATION HAZARD – Category 1
Route of
exposure
Target organs
Route of
exposure
Target organs
:Not available.
Potential acute health effects
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
A study of long term effects of workers exposed to styrene levels in the range of 25-35 ppm for an 8-hour TWA indicated
a possible mild hearing loss.
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SURBOARD LAMINATING RESIN SIL66BE-2880FN
Section 11. Toxicological information
Not available.
Causes damage to organs through prolonged or repeated exposure. Once sensitized, a
severe allergic reaction may occur when subsequently exposed to very low levels.
General :
No known significant effects or critical hazards.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Numerical measures of toxicity
Oral 7723.5 mg/kg
Inhalation (gases) 8073.3 ppm
Inhalation (vapors) 34.39 mg/l
Route ATE value
Acute toxicity estimates
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Product/ingredient name
styrene 0.35 13.49 low
methyl methacrylate 1.38 – low
Product/ingredient name Aquatic half-life Photolysis Biodegradability
styrene – – Readily
Toxicity
styrene Acute EC50 1400 g/l Fresh water Algae – Pseudokirchneriella
subcapitata
72 hours
Acute EC50 720 g/l Fresh water Algae – Pseudokirchneriella
subcapitata
96 hours
Acute EC50 4700 g/l Fresh water Daphnia – Daphnia magna 48 hours
Acute LC50 52 mg/l Marine water Crustaceans – Artemia salina48 hours
Acute LC50 4020 g/l Fresh water Fish – Pimephales promelas 96 hours
Chronic NOEC 63 g/l Fresh water Algae – Pseudokirchneriella
subcapitata
96 hours
methyl methacrylate Acute LC50 130000 g/l Fresh waterFish – Pimephales promelas –
Adult
96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
styrene OECD 70 % – Readily – 28 days – –
Product/ingredient name Test DoseResult Inoculum
Mobility in soil
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SURBOARD LAMINATING RESIN SIL66BE-2880FN
Section 12. Ecological information
Other adverse effects :No known significant effects or critical hazards.
Soil/water partition
coefficient (KOC)
:Not available.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
United States – RCRA Toxic hazardous waste “U” List
Methyl methacrylate (I,T); 2-Propenoic acid, 2-methyl-, methyl ester (I,T)80-62-6 Listed U162
Ingredient CAS # Status Reference
number
Section 14. Transport information
RESIN
SOLUTION
3
III
RESIN
SOLUTION
3
III
RESIN
SOLUTION
UN1866
3
III
UN1866 UN1866
Reportable quantity 2914.5 lbs / 1323.2 kg [317.78 gal / 1202.9 L]. Package sizes
shipped in quantities less than the product reportable quantity are not subject to the RQ
(reportable quantity) transportation requirements.
DOT
Classification
IMDGIATA
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional information
Environmental
hazards
No. No.No.
Product classified as per the following sections of the Transportation of Dangerous
Goods Regulations: 2.18-2.19 (Class 3).
Mexico
Classification
UN1866
RESIN
SOLUTION
3
III
No.
DOT Classification
TDG Classification
:
:
TDG
Classification
UN1866
RESIN
SOLUTION
3
III
No.
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SURBOARD LAMINATING RESIN SIL66BE-2880FN
Section 14. Transport information
Special precautions for user
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
Transport within user s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
:Not available.
:
Section 15. Regulatory information
U.S. Federal regulations
Clean Water Act (CWA) 307: Naphthenic acids, copper salts
Clean Water Act (CWA) 311: styrene; methyl methacrylate
:
SARA 313
Product name CAS number %
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
Form R – Reporting
requirements
Supplier notification
Clean Air Act Section 112
(b) Hazardous Air
Pollutants (HAPs)
:
Clean Air Act Section 602
Class I Substances
:Not listed
Clean Air Act Section 602
Class II Substances
:Not listed
TSCA 8(a) PAIR: Poly(oxy-1,2-ethanediyl), -[4-(1,1,3,3-tetramethylbutyl)phenyl]- –
hydroxy-; triethyl phosphate
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
TSCA 8(c) calls for record of SAR: triethyl phosphate
SARA 302/304
SARA 304 RQ :1446121.8 lbs / 656539.3 kg [157672.1 gal / 596853.9 L]
1,4-dihydroxybenzene <0.1 Yes.500 / 10000- 100 -
Composition/information on ingredients
Name % EHS(lbs) (lbs)(gallons) (gallons)
SARA 302 TPQ SARA 304 RQ
SARA 311/312
Classification :FLAMMABLE LIQUIDS - Category 2
ACUTE TOXICITY (inhalation) - Category 4
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SKIN SENSITIZATION - Category 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) -
Category 1
Styrene
Cobalt Compounds
Methyl methacrylate
Hydroquinone
styrene 100-42-5 <= 35.0
methyl methacrylate 80-62-6 <= 5.0
styrene 100-42-5 34.31
methyl methacrylate 80-62-6 5.00
Any concentration shown as exact is based on formula.
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SURBOARD LAMINATING RESIN SIL66BE-2880FN
Section 15. Regulatory information
The following components are listed: STYRENE; PHENYLETHYLENE; METHYL
METHACRYLATE
Massachusetts :
Styrene
California Prop. 65
New York :The following components are listed: Styrene; Methyl methacrylate; 2-Propenoic acid,
2-methyl-, methyl ester
New Jersey :The following components are listed: STYRENE MONOMER; BENZENE, ETHENYL-;
METHYL METHACRYLATE; 2-PROPENOIC ACID, 2-METHYL-, METHYL ESTER
Pennsylvania :The following components are listed: BENZENE, ETHENYL-; 2-PROPENOIC ACID,
2-METHYL-, METHYL ESTER
State regulations
Inventory list
Australia :All components are listed or exempted.
Canada :All components are listed or exempted.
China :All components are listed or exempted.
Europe :Not determined.
Japan :Japan inventory (ENCS): Not determined.
Japan inventory (ISHL): Not determined.
Republic of Korea :All components are listed or exempted.
Malaysia :Not determined.
New Zealand :All components are listed or exempted.
Philippines :Not determined.
Taiwan :All components are listed or exempted.
Turkey :Not determined.
United States :All components are listed or exempted.
Thailand :Not determined.
Viet Nam :Not determined.
:The following components are listed. For more information go to www.P65Warnings.ca.gov.
Section 16. Other information
Hazardous Material Information System (U.S.A.)
2
3
1
*
National Fire Protection Association (U.S.A.)
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS
ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS
Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual.
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SURBOARD LAMINATING RESIN SIL66BE-2880FN
Section 16. Other information
9/7/2018
History
Date of printing
Date of issue/Date of
revision
Version
Prepared by
Notice to reader
Date of previous issue
:
:
:
:
:
Indicates information that has changed from previously issued version.
References :
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
9/7/2018
No previous validation
1
1
3
2
Health
Special
Instability/Reactivity
Flammability
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Procedure used to derive the classification
Classification Justification
FLAMMABLE LIQUIDS - Category 2 On basis of test data
ACUTE TOXICITY (inhalation) - Category 4 Calculation method
SKIN IRRITATION - Category 2 Calculation method
EYE IRRITATION - Category 2A Calculation method
SKIN SENSITIZATION - Category 1 Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) -
Category 1
Calculation method
Health, Safety and Environmental Department
For questions about the
SDS, contact
:iasafety@ip-corporation.com
29 CFR 1910.1200 Hazard Communication Standard, March 2012
CCR Title 27 Division 4 Office of Environmental Health Hazard Assessment (California
Prop. 65)
American Composites Manufacturers Association
Styrene Information and Research Center
New form 08-2018
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SURBOARD LAMINATING RESIN SIL66BE-2880FN
Section 16. Other information
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Date of issue/Date of revision :9/7/2018 Date of previous issue :No previous validationVersion:1 15/15
by | Sep 27, 2025
SURBOARD LAMINATING RESIN
Unsaturated Polyester Resin
Liquid.
SAFETY DATA SHEET
GHS product identifier
Other means of identification
Product type
Emergency telephone
number (with hours of
operation)
Section 1. Identification
:
:
:
:
Supplier’s details :INTERPLASTIC CORPORATION
1225 Willow Lake Boulevard
St. Paul, MN 55110-5145
651.481.6860
SURBOARD LAMINATING RESIN
Relevant identified uses of the substance or mixture and uses advised against
Product code :SIL66BE-2880FN
Industrial applications.
CHEMTREC 24-Hour Emergency Telephone
US and Canada 800.424.9300
Outside US and Canada +1 703.741.5970
Section 2. Hazards identification
FLAMMABLE LIQUIDS – Category 2
ACUTE TOXICITY (inhalation) – Category 4
SKIN IRRITATION – Category 2
EYE IRRITATION – Category 2A
SKIN SENSITIZATION – Category 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) – Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) –
Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard statements :Highly flammable liquid and vapor.
Harmful if inhaled.
Causes serious eye irritation.
Causes skin irritation.
May cause an allergic skin reaction.
May cause respiratory irritation.
Causes damage to organs through prolonged or repeated exposure. (hearing organs)
Hazard pictograms :
Precautionary statements
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown dermal toxicity: 34.3%
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
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SURBOARD LAMINATING RESIN SIL66BE-2880FN
Section 2. Hazards identification
Prevention :Wear protective gloves. Wear eye or face protection. Keep away from heat, hot
surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-
proof electrical, ventilating, lighting and all material-handling equipment. Use only non-
sparking tools. Take precautionary measures against static discharge. Keep container
tightly closed. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Do
not eat, drink or smoke when using this product. Wash hands thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.
Response :Get medical attention if you feel unwell. IF INHALED: Remove person to fresh air and
keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell.
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water or shower. IF ON SKIN: Wash with plenty of soap and water. Wash
contaminated clothing before reuse. If skin irritation or rash occurs: Get medical
attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get
medical attention.
Storage :Store in a well-ventilated place. Keep cool. Store containers in a safe place.
Disposal :Dispose of contents and container in accordance with all local, regional, national and
international regulations. Do not pressurize, cut, weld, braze, solder, drill, grind or
expose containers to heat or sources of ignition.
Hazards not otherwise
classified
:None known.
Section 3. Composition/information on ingredients
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Other means of
identification
:Unsaturated Polyester Resin
Substance/mixture :
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Any concentration shown as exact is based on formula.
VOC content is listed in Section 9.
Environmental composition is shown in Section 15.
styrene <= 35.0 100-42-5
methyl methacrylate <= 5.0 80-62-6
Ingredient name % CAS number
Section 4. First aid measures
Eye contact :
Description of necessary first aid measures
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention. Buffered baby shampoo will aid in removal of resin.
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SURBOARD LAMINATING RESIN SIL66BE-2880FN
Section 4. First aid measures
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention following
exposure or if feeling unwell. Never give anything by mouth to an unconscious person.
If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Get medical attention. In the event of any
complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean
shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Skin contact
Inhalation
Ingestion :
:
:
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
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SURBOARD LAMINATING RESIN SIL66BE-2880FN
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard.
In a fire or if heated, a pressure increase will occur and the container may burst, with the
risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along
the ground. Vapors may accumulate in low or confined areas or travel a considerable
distance to a source of ignition and flash back.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use dry chemical, CO , water spray (fog) or foam.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and
place in container for disposal according to local regulations (see Section 13). Dispose
of via a licensed waste disposal contractor. Contaminated absorbent material may pose
the same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal. Wear appropriate respiratory protection.
Wear protective clothing and eye or face protection:
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dispose of via a licensed waste disposal contractor.
Absorb with an inert material and transfer the spilled material and absorbent to an
appropriate waste disposal container. Wear appropriate respirator when ventilation is
inadequate. Wear eye/face protection.
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SURBOARD LAMINATING RESIN SIL66BE-2880FN
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Do not store above the following temperature: 38 C (100.4 F). Store in accordance with
local regulations. Store in a segregated and approved area. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area, away from
incompatible materials (see Section 10) and food and drink. Eliminate all ignition
sources. Separate from oxidizing materials. Keep container tightly closed and sealed
until ready for use. Containers that have been opened must be carefully resealed and
kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate
containment to avoid environmental contamination. See Section 10 for incompatible
materials before handling or use. Store containers in a safe place.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Do not get in eyes or on skin or clothing. Do not breathe vapor or
mist. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator
when ventilation is inadequate. Do not enter storage areas and confined spaces unless
adequately ventilated. Keep in the original container or an approved alternative made
from a compatible material, kept tightly closed when not in use. Store and use away
from heat, sparks, open flame or any other ignition source. Use explosion-proof
electrical (ventilating, lighting and material handling) equipment. Use only non-sparking
tools. Take precautionary measures against electrostatic discharges. Empty containers
retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
styrene ACGIH TLV (United States, 3/2017).
TWA: 20 ppm 8 hours.
TWA: 85 mg/m 8 hours.
STEL: 40 ppm 15 minutes.
STEL: 170 mg/m 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
TWA: 50 ppm 8 hours.
TWA: 215 mg/m 8 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
OSHA PEL Z2 (United States, 2/2013).
TWA: 100 ppm 8 hours.
CEIL: 200 ppm
AMP: 600 ppm 5 minutes.
NIOSH REL (United States, 10/2016).
TWA: 50 ppm 10 hours.
TWA: 215 mg/m 10 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
methyl methacrylate ACGIH TLV (United States, 3/2017). Skin sensitizer.
TWA: 50 ppm 8 hours.
STEL: 100 ppm 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
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SURBOARD LAMINATING RESIN SIL66BE-2880FN
Section 8. Exposure controls/personal protection
TWA: 100 ppm 8 hours.
TWA: 410 mg/m 8 hours.
NIOSH REL (United States, 10/2016).
TWA: 100 ppm 10 hours.
TWA: 410 mg/m 10 hours.
OSHA PEL (United States, 6/2016).
TWA: 100 ppm 8 hours.
TWA: 410 mg/m 8 hours.
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
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SURBOARD LAMINATING RESIN SIL66BE-2880FN
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
0.9 to 1.3
3.5 to 3.6 [Air = 1]
0.67 to 3.7 kPa (5 to 28 mm Hg) [room temperature]
Not available.
Aromatic. Sweetish.Odor
pH
Dark purple.Color
Evaporation rate 0.5 to 3.1 (butyl acetate = 1)
Auto-ignition temperature
Flash point
Not available.
Closed cup: 10 to 31 C (50 to 87.8 F)
Not available.
Not applicable.
Viscosity Not available.
0.1 ppmOdor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point :100 to 145 C (212 to 293 F)
Lower and upper explosive
(flammable) limits
:Lower: 0.9%
Upper: 12.5%
Solubility in water :Not applicable.
VOC content :39.4 % (w/w) As shipped, including monomers and additives.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Hazardous reactions or instability may occur under certain conditions of storage or use.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Hazardous polymerization may occur under certain conditions of storage or use. Keep
away from heat and direct sunlight. Keep away from heat and flame. Keep away from
oxidizing agents.
Reactive or incompatible with the following materials: metals, acids and alkalis.
Incompatible with alkali metals. Incompatible with some alkalis. Incompatible with some
strong acids. Incompatible with copper alloys, brass.
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SURBOARD LAMINATING RESIN SIL66BE-2880FN
Section 11. Toxicological information
Acute toxicity
styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours
LC50 Inhalation Vapor Rat 11800 mg/m 4 hours
LD50 Oral Rat 2650 mg/kg -
methyl methacrylate LC50 Inhalation Vapor Rat 78000 mg/m 4 hours
LD50 Dermal Rabbit >5 g/kg –
LD50 Oral Rat 7872 mg/kg –
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Not available.
Conclusion/Summary :
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
styrene Eyes – Mild irritant Human – 50 parts per
million
–
Eyes – Moderate irritantRabbit – 24 hours 100
milligrams
–
Eyes – Severe irritantRabbit – 100
milligrams
–
Skin – Mild irritant Rabbit – 500
milligrams
–
Skin – Moderate irritantRabbit – 100 Percent-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
Information on toxicological effects
Classification
styrene – 2B Reasonably anticipated to be a human carcinogen.
methyl methacrylate – 3 –
Product/ingredient name NTPIARCOSHA
Styrene manufacturers have determined that the weight of evidence for the
carcinogenicity of this substance does not meet the criteria for classification.
Styrene is listed by IARC as a possible carcinogen to humans (Group 2B) based on
“limited evidence” in humans, “limited evidence” in animals and “other relevant data”.
The United States NTP listed styrene as reasonably anticipated to be a human
carcinogen based on “limited evidence” from studies in humans, “sufficient evidence”
from studies in experimental animals, and supporting data on mechanisms of
carcinogenesis. The significance of these results for humans has not been established
through risk assessment.
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SURBOARD LAMINATING RESIN SIL66BE-2880FN
Section 11. Toxicological information
Information on the likely
routes of exposure
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Specific target organ toxicity (repeated exposure)
styrene Category 3 Not applicable.Respiratory tract
irritation
methyl methacrylate Category 3 Not applicable.Respiratory tract
irritation
Name Category
Name Category
styrene Category 1 Inhalation hearing organs
Aspiration hazard
Name Result
styrene ASPIRATION HAZARD – Category 1
Route of
exposure
Target organs
Route of
exposure
Target organs
:Not available.
Potential acute health effects
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
A study of long term effects of workers exposed to styrene levels in the range of 25-35 ppm for an 8-hour TWA indicated
a possible mild hearing loss.
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SURBOARD LAMINATING RESIN SIL66BE-2880FN
Section 11. Toxicological information
Not available.
Causes damage to organs through prolonged or repeated exposure. Once sensitized, a
severe allergic reaction may occur when subsequently exposed to very low levels.
General :
No known significant effects or critical hazards.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Numerical measures of toxicity
Oral 7723.5 mg/kg
Inhalation (gases) 8073.3 ppm
Inhalation (vapors) 34.39 mg/l
Route ATE value
Acute toxicity estimates
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Product/ingredient name
styrene 0.35 13.49 low
methyl methacrylate 1.38 – low
Product/ingredient name Aquatic half-life Photolysis Biodegradability
styrene – – Readily
Toxicity
styrene Acute EC50 1400 g/l Fresh water Algae – Pseudokirchneriella
subcapitata
72 hours
Acute EC50 720 g/l Fresh water Algae – Pseudokirchneriella
subcapitata
96 hours
Acute EC50 4700 g/l Fresh water Daphnia – Daphnia magna 48 hours
Acute LC50 52 mg/l Marine water Crustaceans – Artemia salina48 hours
Acute LC50 4020 g/l Fresh water Fish – Pimephales promelas 96 hours
Chronic NOEC 63 g/l Fresh water Algae – Pseudokirchneriella
subcapitata
96 hours
methyl methacrylate Acute LC50 130000 g/l Fresh waterFish – Pimephales promelas –
Adult
96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
styrene OECD 70 % – Readily – 28 days – –
Product/ingredient name Test DoseResult Inoculum
Mobility in soil
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SURBOARD LAMINATING RESIN SIL66BE-2880FN
Section 12. Ecological information
Other adverse effects :No known significant effects or critical hazards.
Soil/water partition
coefficient (KOC)
:Not available.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
United States – RCRA Toxic hazardous waste “U” List
Methyl methacrylate (I,T); 2-Propenoic acid, 2-methyl-, methyl ester (I,T)80-62-6 Listed U162
Ingredient CAS # Status Reference
number
Section 14. Transport information
RESIN
SOLUTION
3
III
RESIN
SOLUTION
3
III
RESIN
SOLUTION
UN1866
3
III
UN1866 UN1866
Reportable quantity 2914.5 lbs / 1323.2 kg [317.78 gal / 1202.9 L]. Package sizes
shipped in quantities less than the product reportable quantity are not subject to the RQ
(reportable quantity) transportation requirements.
DOT
Classification
IMDGIATA
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional information
Environmental
hazards
No. No.No.
Product classified as per the following sections of the Transportation of Dangerous
Goods Regulations: 2.18-2.19 (Class 3).
Mexico
Classification
UN1866
RESIN
SOLUTION
3
III
No.
DOT Classification
TDG Classification
:
:
TDG
Classification
UN1866
RESIN
SOLUTION
3
III
No.
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SURBOARD LAMINATING RESIN SIL66BE-2880FN
Section 14. Transport information
Special precautions for user
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
Transport within user s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
:Not available.
:
Section 15. Regulatory information
U.S. Federal regulations
Clean Water Act (CWA) 307: Naphthenic acids, copper salts
Clean Water Act (CWA) 311: styrene; methyl methacrylate
:
SARA 313
Product name CAS number %
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
Form R – Reporting
requirements
Supplier notification
Clean Air Act Section 112
(b) Hazardous Air
Pollutants (HAPs)
:
Clean Air Act Section 602
Class I Substances
:Not listed
Clean Air Act Section 602
Class II Substances
:Not listed
TSCA 8(a) PAIR: Poly(oxy-1,2-ethanediyl), -[4-(1,1,3,3-tetramethylbutyl)phenyl]- –
hydroxy-; triethyl phosphate
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
TSCA 8(c) calls for record of SAR: triethyl phosphate
SARA 302/304
SARA 304 RQ :1446121.8 lbs / 656539.3 kg [157672.1 gal / 596853.9 L]
1,4-dihydroxybenzene <0.1 Yes.500 / 10000- 100 -
Composition/information on ingredients
Name % EHS(lbs) (lbs)(gallons) (gallons)
SARA 302 TPQ SARA 304 RQ
SARA 311/312
Classification :FLAMMABLE LIQUIDS - Category 2
ACUTE TOXICITY (inhalation) - Category 4
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SKIN SENSITIZATION - Category 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) -
Category 1
Styrene
Cobalt Compounds
Methyl methacrylate
Hydroquinone
styrene 100-42-5 <= 35.0
methyl methacrylate 80-62-6 <= 5.0
styrene 100-42-5 34.31
methyl methacrylate 80-62-6 5.00
Any concentration shown as exact is based on formula.
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SURBOARD LAMINATING RESIN SIL66BE-2880FN
Section 15. Regulatory information
The following components are listed: STYRENE; PHENYLETHYLENE; METHYL
METHACRYLATE
Massachusetts :
Styrene
California Prop. 65
New York :The following components are listed: Styrene; Methyl methacrylate; 2-Propenoic acid,
2-methyl-, methyl ester
New Jersey :The following components are listed: STYRENE MONOMER; BENZENE, ETHENYL-;
METHYL METHACRYLATE; 2-PROPENOIC ACID, 2-METHYL-, METHYL ESTER
Pennsylvania :The following components are listed: BENZENE, ETHENYL-; 2-PROPENOIC ACID,
2-METHYL-, METHYL ESTER
State regulations
Inventory list
Australia :All components are listed or exempted.
Canada :All components are listed or exempted.
China :All components are listed or exempted.
Europe :Not determined.
Japan :Japan inventory (ENCS): Not determined.
Japan inventory (ISHL): Not determined.
Republic of Korea :All components are listed or exempted.
Malaysia :Not determined.
New Zealand :All components are listed or exempted.
Philippines :Not determined.
Taiwan :All components are listed or exempted.
Turkey :Not determined.
United States :All components are listed or exempted.
Thailand :Not determined.
Viet Nam :Not determined.
:The following components are listed. For more information go to www.P65Warnings.ca.gov.
Section 16. Other information
Hazardous Material Information System (U.S.A.)
2
3
1
*
National Fire Protection Association (U.S.A.)
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS
ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS
Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual.
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SURBOARD LAMINATING RESIN SIL66BE-2880FN
Section 16. Other information
9/7/2018
History
Date of printing
Date of issue/Date of
revision
Version
Prepared by
Notice to reader
Date of previous issue
:
:
:
:
:
Indicates information that has changed from previously issued version.
References :
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
9/7/2018
No previous validation
1
1
3
2
Health
Special
Instability/Reactivity
Flammability
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Procedure used to derive the classification
Classification Justification
FLAMMABLE LIQUIDS - Category 2 On basis of test data
ACUTE TOXICITY (inhalation) - Category 4 Calculation method
SKIN IRRITATION - Category 2 Calculation method
EYE IRRITATION - Category 2A Calculation method
SKIN SENSITIZATION - Category 1 Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) -
Category 1
Calculation method
Health, Safety and Environmental Department
For questions about the
SDS, contact
:iasafety@ip-corporation.com
29 CFR 1910.1200 Hazard Communication Standard, March 2012
CCR Title 27 Division 4 Office of Environmental Health Hazard Assessment (California
Prop. 65)
American Composites Manufacturers Association
Styrene Information and Research Center
New form 08-2018
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SURBOARD LAMINATING RESIN SIL66BE-2880FN
Section 16. Other information
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Date of issue/Date of revision :9/7/2018 Date of previous issue :No previous validationVersion:1 15/15
by | Sep 27, 2025
SURFBOARD RESIN
Unsaturated Polyester Resin
Liquid.
SAFETY DATA SHEET
GHS product identifier
Other means of
identification
Product type
Emergency telephone
number (with hours of
operation)
Section 1. Identification
:
:
:
:
Supplier’s details :INTERPLASTIC CORPORATION
1225 Willow Lake Boulevard
St. Paul, MN 55110-5145
651.481.6860
SURFBOARD RESIN
Material uses
Product code :SIL66BF-250ALH
Product use :Industrial applications.
CHEMTREC 24-Hour Emergency Telephone 800.424.9300
Section 2. Hazards identification
FLAMMABLE LIQUIDS – Category 3
ACUTE TOXICITY: INHALATION – Category 4
SKIN CORROSION/IRRITATION – Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION – Category 2A
CARCINOGENICITY – Category 2
Classification of the
substance or mixture
:
Signal word :Warning
Hazard statements :Flammable liquid and vapor.
Harmful if inhaled.
Causes serious eye irritation.
Causes skin irritation.
Suspected of causing cancer.
Hazard pictograms :
Precautionary statements
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 66.3%
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Date of issue/Date of revision :12/21/2014.Date of previous issue :8/17/2014. Version:2 1/14
SURFBOARD RESINSIL66BF-250ALH
Section 2. Hazards identification
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Use personal protective equipment as required. Wear
protective gloves. Wear eye or face protection. Keep away from heat, sparks, open
flames and hot surfaces. – No smoking. Use explosion-proof electrical, ventilating,
lighting and all material-handling equipment. Use only non-sparking tools. Take
precautionary measures against static discharge. Keep container tightly closed. Use
only outdoors or in a well-ventilated area. Avoid breathing vapor. Wash hands
thoroughly after handling.
Response :IF exposed or concerned: Get medical attention. IF INHALED: Remove victim to fresh
air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or
physician if you feel unwell. IF ON SKIN (or hair): Take off immediately all
contaminated clothing. Rinse skin with water or shower. IF ON SKIN: Wash with
plenty of soap and water. Take off contaminated clothing. If skin irritation occurs: Get
medical attention. IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation
persists: Get medical attention.
Storage :Store containers in a safe place. Store in a well-ventilated place. Keep cool.
Disposal :Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise
classified
:None known.
Section 3. Composition/information on ingredients
Styrene 31.0 – 34.0 100-42-5
Ingredient name CAS number%
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Other means of
identification
:Unsaturated Polyester Resin
CAS number :Not applicable.
Substance/mixture
Product code :SIL66BF-250ALH
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation. Any concentration shown as
exact is based on formula.
Date of issue/Date of revision :12/21/2014.Date of previous issue :8/17/2014. Version:2 2/14
SURFBOARD RESINSIL66BF-250ALH
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway. Loosen tight clothing
such as a collar, tie, belt or waistband.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Description of necessary first aid measures
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :Harmful if inhaled.
Irritating to mouth, throat and stomach.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
Indication of immediate medical attention and special treatment needed, if necessary
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SURFBOARD RESINSIL66BF-250ALH
Section 4. First aid measures
See toxicological information (Section 11)
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and
the container may burst, with the risk of a subsequent explosion. The vapor/gas is
heavier than air and will spread along the ground. Vapors may accumulate in low or
confined areas or travel a considerable distance to a source of ignition and flash back.
Runoff to sewer may create fire or explosion hazard.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use dry chemical, CO , water spray (fog) or foam.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialised clothing is required to deal with the spillage, take note of any information
in Section 8 on suitable and unsuitable materials. See also the information in “For non-
emergency personnel”.
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SURFBOARD RESINSIL66BF-250ALH
Section 6. Accidental release measures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
Large spill :
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Do not store above the following temperature: 38 C (100.4 F). Store in accordance with
local regulations. Store in a segregated and approved area. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area, away from
incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate
all ignition sources. Separate from oxidizing materials. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure –
obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not ingest.
Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate
respirator when ventilation is inadequate. Do not enter storage areas and confined
spaces unless adequately ventilated. Keep in the original container or an approved
alternative made from a compatible material, kept tightly closed when not in use. Store
and use away from heat, sparks, open flame or any other ignition source. Use
explosion-proof electrical (ventilating, lighting and material handling) equipment. Use
only non-sparking tools. Take precautionary measures against electrostatic discharges.
Empty containers retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
Styrene ACGIH TLV (United States, 4/2014).
TWA: 20 ppm 8 hours.
TWA: 85 mg/m 8 hours.
STEL: 40 ppm 15 minutes.
STEL: 170 mg/m 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
TWA: 50 ppm 8 hours.
TWA: 215 mg/m 8 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
OSHA PEL Z2 (United States, 2/2013).
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
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SURFBOARD RESINSIL66BF-250ALH
Section 8. Exposure controls/personal protection
TWA: 100 ppm 8 hours.
CEIL: 200 ppm
AMP: 600 ppm 5 minutes.
NIOSH REL (United States, 10/2013).
TWA: 50 ppm 10 hours.
TWA: 215 mg/m 10 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
Hand protection
Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Date of issue/Date of revision :12/21/2014.Date of previous issue :8/17/2014. Version:2 6/14
SURFBOARD RESINSIL66BF-250ALH
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
1.01 to 1.3
3.6 [Air = 1]
0.57 kPa (4.3 mm Hg) [room temperature]
Not available.
Characteristic.Odor
pH
VariousColor
Evaporation rate <1 (ether (anhydrous) = 1)
Auto-ignition temperature
Flash point
Not available.
Closed cup: 31.1 C (88 F)
Not available.
Not available.
Viscosity Not available.
Not available.Odor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point :145.2 C (293.4 F)
Flammability (solid, gas):Not available.
Lower and upper explosive
(flammable) limits
:Lower: 1.1%
Upper: 6.1%
Burning rate Not applicable.:
Burning time :Not applicable.
SADT Not available.:
Decomposition temperature:Not available.
Solubility in water :Not available.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Hazardous reactions or instability may occur under certain conditions of storage or use.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Reactive or incompatible with the following materials: acids and alkalis.
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SURFBOARD RESINSIL66BF-250ALH
Section 11. Toxicological information
Acute toxicity
Styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours
LC50 Inhalation Vapor Rat 11800 mg/m 4 hours
LD50 Oral Rat 2650 mg/kg -
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Not available.
Conclusion/Summary :
Mutagenicity
Not available.
Irritation/Corrosion
Styrene Eyes - Mild irritant Human - 50 parts per
million
-
Eyes - Moderate irritantRabbit - 24 hours 100
milligrams
-
Eyes - Severe irritantRabbit - 100
milligrams
-
Skin - Mild irritant Rabbit - 500
milligrams
-
Skin - Moderate irritantRabbit - 100 Percent-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Information on toxicological effects
Styrene manufacturers have determined that the GHS hazard classification criteria has
not been met.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Information on the likely
routes of exposure
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Not available.
Not available.
Aspiration hazard
Not available.
:Not available.
Classification
Styrene - 2B Reasonably anticipated to be a human carcinogen.
Product/ingredient name NTPIARCOSHA
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SURFBOARD RESINSIL66BF-250ALH
Section 11. Toxicological information
Not available.
Inhalation :Harmful if inhaled.
Irritating to mouth, throat and stomach.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
No known significant effects or critical hazards.General :
Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Oral 2693.3 mg/kg
Inhalation (gases) 2815.2 ppm
Inhalation (vapors) 11.99 mg/l
Route ATE value
Acute toxicity estimates
Potential acute health effects
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
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SURFBOARD RESINSIL66BF-250ALH
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Product/ingredient name
Styrene 0.35 13.49 low
Toxicity
Styrene Acute EC50 1400 g/l Fresh water Algae - Pseudokirchneriella
subcapitata
72 hours
Acute EC50 720 g/l Fresh water Algae - Pseudokirchneriella
subcapitata
96 hours
Acute EC50 4700 g/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 13000 g/l Fresh water Crustaceans - Hyalella azteca48 hours
Acute LC50 4020 g/l Fresh water Fish - Pimephales promelas 96 hours
Chronic NOEC 63 g/l Fresh water Algae - Pseudokirchneriella
subcapitata
96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Not available.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
Section 14. Transport information
RESIN
SOLUTION
RESIN
SOLUTION
RESIN
SOLUTION
UN1866UN1866 UN1866
DOT
Classification
IMDG IATA
UN number
UN proper
shipping name
Mexico
Classification
UN1866
RESIN
SOLUTION
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SURFBOARD RESINSIL66BF-250ALH
Section 14. Transport information
Special precautions for user
Transport in bulk according
to Annex II of MARPOL
73/78 and the IBC Code
Transport within user s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
:Not available.
:
3
III
3
III
3
III
Reportable
quantity
3015.8 lbs /
1369.2 kg [313.
16 gal / 1185.4
L]
Package sizes
shipped in
quantities less
than the
product
reportable
quantity are
not subject to
the RQ
(reportable
quantity)
transportation
requirements.
- -
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
Yes. Yes. No.
3
III
Yes.
-
Section 15. Regulatory information
U.S. Federal regulations
Clean Water Act (CWA) 307: Naphthenic acids, copper salts
Clean Water Act (CWA) 311: styrene
:TSCA 5(a)2 final significant new use rules: UNSATURATED POLYESTER RESIN
TSCA 8(a) PAIR: 4-tert-butylpyrocatechol; triethyl phosphate
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
TSCA 8(c) calls for record of SAR: triethyl phosphate
TSCA 12(b) one-time export: 1,2-Benzenedicarboxylic acid, mixed esters with benzyl
alc., cyclohexanol, 2-ethyl-1-hexanol, fumaric acid and propylene glycol
United States inventory (TSCA 8b): All components are listed or exempted.
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SURFBOARD RESINSIL66BF-250ALH
Section 15. Regulatory information
1,4-dihydroxybenzene 0.01 Yes.500 / 10000- 100 -
The following components are listed: STYRENE MONOMERMassachusetts :
SARA 313
Product name CAS number %
styrene 100-42-5 33.16
styrene 100-42-5 33.16
Form R - Reporting
requirements
Supplier notification
Clean Air Act Section 112
(b) Hazardous Air
Pollutants (HAPs)
:Listed
Clean Air Act Section 602
Class I Substances
:Not listed
Clean Air Act Section 602
Class II Substances
:Not listed
New York :The following components are listed: Styrene
New Jersey :The following components are listed: STYRENE MONOMER; BENZENE, ETHENYL-
Pennsylvania :The following components are listed: BENZENE, ETHENYL-
State regulations
SARA 302/304
SARA 304 RQ :1633164.7 lbs / 741456.8 kg [169586.3 gal / 641953.9 L]
Composition/information on ingredients
Name % EHS(lbs) (lbs)(gallons) (gallons)
SARA 302 TPQ SARA 304 RQ
SARA 311/312
Classification :Fire hazard
Immediate (acute) health hazard
Delayed (chronic) health hazard
Canada inventory :Not determined.
Australia inventory (AICS): Not determined.
China inventory (IECSC): Not determined.
Japan inventory: Not determined.
Korea inventory: Not determined.
Malaysia Inventory (EHS Register): Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
Taiwan inventory (CSNN): Not determined.
International regulations
International lists :
Date of issue/Date of revision :12/21/2014.Date of previous issue :8/17/2014. Version:2 12/14
SURFBOARD RESINSIL66BF-250ALH
Section 16. Other information
12/21/2014.
History
Date of printing
Date of issue/Date of
revision
Version
Prepared by
Notice to reader
Date of previous issue
:
:
:
:
Indicates information that has changed from previously issued version.
References :OSHA Hazard Communication Standard, March 2012 (29 CFR 1910.1200)
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
12/21/2014.
8/17/2014.
2
Hazardous Material Information System (U.S.A.)
2
3
1
1
3
2
*
National Fire Protection Association (U.S.A.)
Health
Special
Instability/Reactivity
Flammability
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS ratings are not required on SDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS ratings are to be used with a fully implemented HMIS
program. HMIS is a registered mark of the National Paint & Coatings Association (NPCA). HMIS materials
may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Health, Safety and Environmental Department
Email :For questions regarding the SDS contact iasafety@ip-corporation.com
Date of issue/Date of revision :12/21/2014.Date of previous issue :8/17/2014. Version:2 13/14
SURFBOARD RESINSIL66BF-250ALH
Section 16. Other information
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Date of issue/Date of revision :12/21/2014.Date of previous issue :8/17/2014. Version:2 14/14
by | Sep 27, 2025
SURFBOARD RESIN
Unsaturated Polyester Resin
Liquid.
SAFETY DATA SHEET
GHS product identifier
Other means of
identification
Product type
Emergency telephone
number (with hours of
operation)
Section 1. Identification
:
:
:
:
Supplier’s details :INTERPLASTIC CORPORATION
1225 Willow Lake Boulevard
St. Paul, MN 55110-5145
651.481.6860
SURFBOARD RESIN
Material uses
Product code :SIL66BF-250ALH
Product use :Industrial applications.
CHEMTREC 24-Hour Emergency Telephone 800.424.9300
Section 2. Hazards identification
FLAMMABLE LIQUIDS – Category 3
ACUTE TOXICITY: INHALATION – Category 4
SKIN CORROSION/IRRITATION – Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION – Category 2A
CARCINOGENICITY – Category 2
Classification of the
substance or mixture
:
Signal word :Warning
Hazard statements :Flammable liquid and vapor.
Harmful if inhaled.
Causes serious eye irritation.
Causes skin irritation.
Suspected of causing cancer.
Hazard pictograms :
Precautionary statements
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 66.3%
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Date of issue/Date of revision :12/21/2014.Date of previous issue :8/17/2014. Version:2 1/14
SURFBOARD RESINSIL66BF-250ALH
Section 2. Hazards identification
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Use personal protective equipment as required. Wear
protective gloves. Wear eye or face protection. Keep away from heat, sparks, open
flames and hot surfaces. – No smoking. Use explosion-proof electrical, ventilating,
lighting and all material-handling equipment. Use only non-sparking tools. Take
precautionary measures against static discharge. Keep container tightly closed. Use
only outdoors or in a well-ventilated area. Avoid breathing vapor. Wash hands
thoroughly after handling.
Response :IF exposed or concerned: Get medical attention. IF INHALED: Remove victim to fresh
air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or
physician if you feel unwell. IF ON SKIN (or hair): Take off immediately all
contaminated clothing. Rinse skin with water or shower. IF ON SKIN: Wash with
plenty of soap and water. Take off contaminated clothing. If skin irritation occurs: Get
medical attention. IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation
persists: Get medical attention.
Storage :Store containers in a safe place. Store in a well-ventilated place. Keep cool.
Disposal :Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise
classified
:None known.
Section 3. Composition/information on ingredients
Styrene 31.0 – 34.0 100-42-5
Ingredient name CAS number%
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Other means of
identification
:Unsaturated Polyester Resin
CAS number :Not applicable.
Substance/mixture
Product code :SIL66BF-250ALH
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation. Any concentration shown as
exact is based on formula.
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SURFBOARD RESINSIL66BF-250ALH
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway. Loosen tight clothing
such as a collar, tie, belt or waistband.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Description of necessary first aid measures
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :Harmful if inhaled.
Irritating to mouth, throat and stomach.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
Indication of immediate medical attention and special treatment needed, if necessary
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SURFBOARD RESINSIL66BF-250ALH
Section 4. First aid measures
See toxicological information (Section 11)
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and
the container may burst, with the risk of a subsequent explosion. The vapor/gas is
heavier than air and will spread along the ground. Vapors may accumulate in low or
confined areas or travel a considerable distance to a source of ignition and flash back.
Runoff to sewer may create fire or explosion hazard.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use dry chemical, CO , water spray (fog) or foam.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialised clothing is required to deal with the spillage, take note of any information
in Section 8 on suitable and unsuitable materials. See also the information in “For non-
emergency personnel”.
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SURFBOARD RESINSIL66BF-250ALH
Section 6. Accidental release measures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
Large spill :
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Do not store above the following temperature: 38 C (100.4 F). Store in accordance with
local regulations. Store in a segregated and approved area. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area, away from
incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate
all ignition sources. Separate from oxidizing materials. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure –
obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not ingest.
Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate
respirator when ventilation is inadequate. Do not enter storage areas and confined
spaces unless adequately ventilated. Keep in the original container or an approved
alternative made from a compatible material, kept tightly closed when not in use. Store
and use away from heat, sparks, open flame or any other ignition source. Use
explosion-proof electrical (ventilating, lighting and material handling) equipment. Use
only non-sparking tools. Take precautionary measures against electrostatic discharges.
Empty containers retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
Styrene ACGIH TLV (United States, 4/2014).
TWA: 20 ppm 8 hours.
TWA: 85 mg/m 8 hours.
STEL: 40 ppm 15 minutes.
STEL: 170 mg/m 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
TWA: 50 ppm 8 hours.
TWA: 215 mg/m 8 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
OSHA PEL Z2 (United States, 2/2013).
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
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SURFBOARD RESINSIL66BF-250ALH
Section 8. Exposure controls/personal protection
TWA: 100 ppm 8 hours.
CEIL: 200 ppm
AMP: 600 ppm 5 minutes.
NIOSH REL (United States, 10/2013).
TWA: 50 ppm 10 hours.
TWA: 215 mg/m 10 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
Hand protection
Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
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SURFBOARD RESINSIL66BF-250ALH
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
1.01 to 1.3
3.6 [Air = 1]
0.57 kPa (4.3 mm Hg) [room temperature]
Not available.
Characteristic.Odor
pH
VariousColor
Evaporation rate <1 (ether (anhydrous) = 1)
Auto-ignition temperature
Flash point
Not available.
Closed cup: 31.1 C (88 F)
Not available.
Not available.
Viscosity Not available.
Not available.Odor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point :145.2 C (293.4 F)
Flammability (solid, gas):Not available.
Lower and upper explosive
(flammable) limits
:Lower: 1.1%
Upper: 6.1%
Burning rate Not applicable.:
Burning time :Not applicable.
SADT Not available.:
Decomposition temperature:Not available.
Solubility in water :Not available.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Hazardous reactions or instability may occur under certain conditions of storage or use.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Reactive or incompatible with the following materials: acids and alkalis.
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SURFBOARD RESINSIL66BF-250ALH
Section 11. Toxicological information
Acute toxicity
Styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours
LC50 Inhalation Vapor Rat 11800 mg/m 4 hours
LD50 Oral Rat 2650 mg/kg -
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Not available.
Conclusion/Summary :
Mutagenicity
Not available.
Irritation/Corrosion
Styrene Eyes - Mild irritant Human - 50 parts per
million
-
Eyes - Moderate irritantRabbit - 24 hours 100
milligrams
-
Eyes - Severe irritantRabbit - 100
milligrams
-
Skin - Mild irritant Rabbit - 500
milligrams
-
Skin - Moderate irritantRabbit - 100 Percent-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Information on toxicological effects
Styrene manufacturers have determined that the GHS hazard classification criteria has
not been met.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Information on the likely
routes of exposure
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Not available.
Not available.
Aspiration hazard
Not available.
:Not available.
Classification
Styrene - 2B Reasonably anticipated to be a human carcinogen.
Product/ingredient name NTPIARCOSHA
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SURFBOARD RESINSIL66BF-250ALH
Section 11. Toxicological information
Not available.
Inhalation :Harmful if inhaled.
Irritating to mouth, throat and stomach.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
No known significant effects or critical hazards.General :
Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Oral 2693.3 mg/kg
Inhalation (gases) 2815.2 ppm
Inhalation (vapors) 11.99 mg/l
Route ATE value
Acute toxicity estimates
Potential acute health effects
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
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SURFBOARD RESINSIL66BF-250ALH
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Product/ingredient name
Styrene 0.35 13.49 low
Toxicity
Styrene Acute EC50 1400 g/l Fresh water Algae - Pseudokirchneriella
subcapitata
72 hours
Acute EC50 720 g/l Fresh water Algae - Pseudokirchneriella
subcapitata
96 hours
Acute EC50 4700 g/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 13000 g/l Fresh water Crustaceans - Hyalella azteca48 hours
Acute LC50 4020 g/l Fresh water Fish - Pimephales promelas 96 hours
Chronic NOEC 63 g/l Fresh water Algae - Pseudokirchneriella
subcapitata
96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Not available.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
Section 14. Transport information
RESIN
SOLUTION
RESIN
SOLUTION
RESIN
SOLUTION
UN1866UN1866 UN1866
DOT
Classification
IMDG IATA
UN number
UN proper
shipping name
Mexico
Classification
UN1866
RESIN
SOLUTION
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SURFBOARD RESINSIL66BF-250ALH
Section 14. Transport information
Special precautions for user
Transport in bulk according
to Annex II of MARPOL
73/78 and the IBC Code
Transport within user s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
:Not available.
:
3
III
3
III
3
III
Reportable
quantity
3015.8 lbs /
1369.2 kg [313.
16 gal / 1185.4
L]
Package sizes
shipped in
quantities less
than the
product
reportable
quantity are
not subject to
the RQ
(reportable
quantity)
transportation
requirements.
- -
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
Yes. Yes. No.
3
III
Yes.
-
Section 15. Regulatory information
U.S. Federal regulations
Clean Water Act (CWA) 307: Naphthenic acids, copper salts
Clean Water Act (CWA) 311: styrene
:TSCA 5(a)2 final significant new use rules: UNSATURATED POLYESTER RESIN
TSCA 8(a) PAIR: 4-tert-butylpyrocatechol; triethyl phosphate
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
TSCA 8(c) calls for record of SAR: triethyl phosphate
TSCA 12(b) one-time export: 1,2-Benzenedicarboxylic acid, mixed esters with benzyl
alc., cyclohexanol, 2-ethyl-1-hexanol, fumaric acid and propylene glycol
United States inventory (TSCA 8b): All components are listed or exempted.
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SURFBOARD RESINSIL66BF-250ALH
Section 15. Regulatory information
1,4-dihydroxybenzene 0.01 Yes.500 / 10000- 100 -
The following components are listed: STYRENE MONOMERMassachusetts :
SARA 313
Product name CAS number %
styrene 100-42-5 33.16
styrene 100-42-5 33.16
Form R - Reporting
requirements
Supplier notification
Clean Air Act Section 112
(b) Hazardous Air
Pollutants (HAPs)
:Listed
Clean Air Act Section 602
Class I Substances
:Not listed
Clean Air Act Section 602
Class II Substances
:Not listed
New York :The following components are listed: Styrene
New Jersey :The following components are listed: STYRENE MONOMER; BENZENE, ETHENYL-
Pennsylvania :The following components are listed: BENZENE, ETHENYL-
State regulations
SARA 302/304
SARA 304 RQ :1633164.7 lbs / 741456.8 kg [169586.3 gal / 641953.9 L]
Composition/information on ingredients
Name % EHS(lbs) (lbs)(gallons) (gallons)
SARA 302 TPQ SARA 304 RQ
SARA 311/312
Classification :Fire hazard
Immediate (acute) health hazard
Delayed (chronic) health hazard
Canada inventory :Not determined.
Australia inventory (AICS): Not determined.
China inventory (IECSC): Not determined.
Japan inventory: Not determined.
Korea inventory: Not determined.
Malaysia Inventory (EHS Register): Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
Taiwan inventory (CSNN): Not determined.
International regulations
International lists :
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SURFBOARD RESINSIL66BF-250ALH
Section 16. Other information
12/21/2014.
History
Date of printing
Date of issue/Date of
revision
Version
Prepared by
Notice to reader
Date of previous issue
:
:
:
:
Indicates information that has changed from previously issued version.
References :OSHA Hazard Communication Standard, March 2012 (29 CFR 1910.1200)
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
12/21/2014.
8/17/2014.
2
Hazardous Material Information System (U.S.A.)
2
3
1
1
3
2
*
National Fire Protection Association (U.S.A.)
Health
Special
Instability/Reactivity
Flammability
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS ratings are not required on SDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS ratings are to be used with a fully implemented HMIS
program. HMIS is a registered mark of the National Paint & Coatings Association (NPCA). HMIS materials
may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Health, Safety and Environmental Department
Email :For questions regarding the SDS contact iasafety@ip-corporation.com
Date of issue/Date of revision :12/21/2014.Date of previous issue :8/17/2014. Version:2 13/14
SURFBOARD RESINSIL66BF-250ALH
Section 16. Other information
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Date of issue/Date of revision :12/21/2014.Date of previous issue :8/17/2014. Version:2 14/14
by | Sep 27, 2025
SURFBOARD RESIN
Unsaturated Polyester Resin
Liquid.
SAFETY DATA SHEET
GHS product identifier
Other means of
identification
Product type
Emergency telephone
number (with hours of
operation)
Section 1. Identification
:
:
:
:
Supplier’s details :INTERPLASTIC CORPORATION
1225 Willow Lake Boulevard
St. Paul, MN 55110-5145
651.481.6860
SURFBOARD RESIN
Material uses
Product code :SIL66BQ-249A
Product use :Industrial applications.
CHEMTREC 24-Hour Emergency Telephone 800.424.9300
Section 2. Hazards identification
FLAMMABLE LIQUIDS – Category 3
ACUTE TOXICITY: INHALATION – Category 4
SKIN CORROSION/IRRITATION – Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION – Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) [Respiratory tract
irritation] – Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): INHALATION
[ears] – Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard statements :Flammable liquid and vapor.
Harmful if inhaled.
Causes serious eye irritation.
Causes skin irritation.
May cause respiratory irritation.
Causes damage to organs through prolonged or repeated exposure if inhaled. (ears)
Hazard pictograms :
Precautionary statements
GHS label elements
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
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SURFBOARD RESINSIL66BQ-249A
Section 2. Hazards identification
Prevention :Wear protective gloves. Wear eye or face protection. Keep away from heat, sparks,
open flames and hot surfaces. – No smoking. Use explosion-proof electrical, ventilating,
lighting and all material-handling equipment. Use only non-sparking tools. Take
precautionary measures against static discharge. Keep container tightly closed. Use
only outdoors or in a well-ventilated area. Do not breathe vapor. Do not eat, drink or
smoke when using this product. Wash hands thoroughly after handling.
Response :Get medical attention if you feel unwell. IF INHALED: Remove victim to fresh air and
keep at rest in a position comfortable for breathing. Call a POISON CENTER or
physician if you feel unwell. IF ON SKIN (or hair): Take off immediately all
contaminated clothing. Rinse skin with water or shower. IF ON SKIN: Wash with
plenty of soap and water. Take off contaminated clothing. If skin irritation occurs: Get
medical attention. IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation
persists: Get medical attention.
Storage :Store containers in a safe place. Store in a well-ventilated place. Keep cool.
Disposal :Dispose of contents and container in accordance with all local, regional, national and
international regulations. Do not pressurize, cut, weld, braze, solder, drill, grind or
expose containers to heat or sources of ignition.
Hazards not otherwise
classified
:None known.
Section 3. Composition/information on ingredients
styrene <= 36.0 100-42-5
Ingredient name CAS number%
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations
applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
Other means of
identification
:Unsaturated Polyester Resin
CAS number :Not applicable.
Substance/mixture
Product code :SIL66BQ-249A
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation. Any concentration shown as
exact is based on formula.
See Section 9 for VOC content. See Section 15 for HAP information.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Section 4. First aid measures
Eye contact :
Description of necessary first aid measures
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SURFBOARD RESINSIL66BQ-249A
Section 4. First aid measures
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention following
exposure or if feeling unwell. Never give anything by mouth to an unconscious person.
If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Skin contact
Inhalation
Ingestion :
:
:
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :Harmful if inhaled. May cause respiratory irritation.
Irritating to mouth, throat and stomach.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
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SURFBOARD RESINSIL66BQ-249A
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and
the container may burst, with the risk of a subsequent explosion. The vapor/gas is
heavier than air and will spread along the ground. Vapors may accumulate in low or
confined areas or travel a considerable distance to a source of ignition and flash back.
Runoff to sewer may create fire or explosion hazard.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use dry chemical, CO , water spray (fog) or foam.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialised clothing is required to deal with the spillage, take note of any information
in Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
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SURFBOARD RESINSIL66BQ-249A
Section 6. Accidental release measures
information and Section 13 for waste disposal.
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Do not store above the following temperature: 38 C (100.4 F). Store in accordance with
local regulations. Store in a segregated and approved area. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area, away from
incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate
all ignition sources. Separate from oxidizing materials. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Do not breathe
vapor or mist. Do not ingest. Avoid contact with eyes, skin and clothing. Use only with
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do
not enter storage areas and confined spaces unless adequately ventilated. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Store and use away from heat, sparks, open flame or
any other ignition source. Use explosion-proof electrical (ventilating, lighting and
material handling) equipment. Use only non-sparking tools. Take precautionary
measures against electrostatic discharges. Empty containers retain product residue
and can be hazardous. Do not reuse container.
:
Precautions for safe handling
styrene ACGIH TLV (United States, 3/2015).
TWA: 20 ppm 8 hours.
TWA: 85 mg/m 8 hours.
STEL: 40 ppm 15 minutes.
STEL: 170 mg/m 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
TWA: 50 ppm 8 hours.
TWA: 215 mg/m 8 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
OSHA PEL Z2 (United States, 2/2013).
TWA: 100 ppm 8 hours.
CEIL: 200 ppm
AMP: 600 ppm 5 minutes.
NIOSH REL (United States, 10/2013).
TWA: 50 ppm 10 hours.
TWA: 215 mg/m 10 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
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SURFBOARD RESINSIL66BQ-249A
Section 8. Exposure controls/personal protection
Hand protection
Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point
Liquid.
Not available.
Characteristic. Aromatic. Sweetish.Odor
pH
VariousColor
Not applicable.
0.1 ppmOdor threshold
:
:
:
:
:
:
Appearance
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SURFBOARD RESINSIL66BQ-249A
Section 9. Physical and chemical properties
Vapor pressure
Relative density
Vapor density
0.9 to 1.3
3.6 [Air = 1]
0.57 kPa (4.3 mm Hg) [room temperature]
Evaporation rate <1 (butyl acetate = 1)
Auto-ignition temperature
Flash point
Not available.
Closed cup: 31.1 C (88 F)
Not available.
Viscosity Not available.
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
Boiling point :145.2 C (293.4 F)
Lower and upper explosive
(flammable) limits
:Lower: 1.1%
Upper: 6.1%
Decomposition temperature:Not available.
Solubility in water :Not applicable.
VOC content (industrial use)35.3 % (w/w) As shipped. Including monomer.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Hazardous reactions or instability may occur under certain conditions of storage or use.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Reactive or incompatible with the following materials: acids and alkalis.
Incompatible with alkali metals. Incompatible with some alkalis. Incompatible with some
strong acids.
Hazardous polymerization may occur under certain conditions of storage or use. Keep
away from heat and direct sunlight. Keep away from heat and flame. Keep away from
oxidizing agents.
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SURFBOARD RESINSIL66BQ-249A
Section 11. Toxicological information
Acute toxicity
styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours
LC50 Inhalation Vapor Rat 11800 mg/m 4 hours
LD50 Oral Rat 2650 mg/kg -
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Not available.
Conclusion/Summary :
Mutagenicity
Not available.
Irritation/Corrosion
styrene Eyes - Mild irritant Human - 50 parts per
million
-
Eyes - Moderate irritantRabbit - 24 hours 100
milligrams
-
Eyes - Severe irritantRabbit - 100
milligrams
-
Skin - Mild irritant Rabbit - 500
milligrams
-
Skin - Moderate irritantRabbit - 100 Percent-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Information on toxicological effects
Styrene manufacturers have determined that the weight of evidence for the
carcinogenicity of this substance does not meet the criteria for classification.
Styrene is listed by IARC as a possible carcinogen to humans (Group 2B) based on
"limited evidence" in humans, "limited evidence" in animals and "other relevant data".
The United States NTP listed styrene as reasonably anticipated to be a human
carcinogen based on "limited evidence" from studies in humans, "sufficient evidence"
from studies in experimental animals, and supporting data on mechanisms of
carcinogenesis. The significance of these results for humans has not been established
through risk assessment.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Specific target organ toxicity (single exposure)
Classification
styrene - 2B Reasonably anticipated to be a human carcinogen.
Product/ingredient name NTPIARCOSHA
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SURFBOARD RESINSIL66BQ-249A
Section 11. Toxicological information
Not available.
Information on the likely
routes of exposure
Inhalation :Harmful if inhaled. May cause respiratory irritation.
Irritating to mouth, throat and stomach.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
Causes damage to organs through prolonged or repeated exposure if inhaled.General :
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Specific target organ toxicity (repeated exposure)
styrene Category 3 Not applicable.Respiratory tract
irritation
Name Category
Name Category
styrene Category 1 Inhalation ears
Aspiration hazard
Name Result
styrene ASPIRATION HAZARD - Category 1
Route of
exposure
Target organs
Route of
exposure
Target organs
:Not available.
Potential acute health effects
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
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SURFBOARD RESINSIL66BQ-249A
Section 11. Toxicological information
No known significant effects or critical hazards.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Numerical measures of toxicity
Oral 7518 mg/kg
Inhalation (gases) 7858.4 ppm
Inhalation (vapors) 33.48 mg/l
Route ATE value
Acute toxicity estimates
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Product/ingredient name
styrene 0.35 13.49 low
Toxicity
styrene Acute EC50 1400 g/l Fresh water Algae - Pseudokirchneriella
subcapitata
72 hours
Acute EC50 720 g/l Fresh water Algae - Pseudokirchneriella
subcapitata
96 hours
Acute EC50 4700 g/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 52000 g/l Marine waterCrustaceans - Artemia salina -
Nauplii
48 hours
Acute LC50 4020 g/l Fresh water Fish - Pimephales promelas 96 hours
Chronic NOEC 63 g/l Fresh water Algae - Pseudokirchneriella
subcapitata
96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Not available.
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SURFBOARD RESINSIL66BQ-249A
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
Section 14. Transport information
RESIN
SOLUTION
3
III
RESIN
SOLUTION
3
III
RESIN
SOLUTION
UN1866
3
III
UN1866 UN1866
Reportable
quantity
2837 lbs / 1288
kg [309.32 gal /
1170.9 L]
Package sizes
shipped in
quantities less
than the
product
reportable
quantity are
not subject to
the RQ
(reportable
quantity)
transportation
requirements.
- -
DOT
Classification
IMDG IATA
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
No. No. No.
Mexico
Classification
UN1866
RESIN
SOLUTION
3
III
No.
-
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SURFBOARD RESINSIL66BQ-249A
Section 14. Transport information
Special precautions for user
Transport in bulk according
to Annex II of MARPOL
73/78 and the IBC Code
Transport within user s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
:Not available.
:
1,4-dihydroxybenzene 0.00 Yes.500 / 10000- 100 -
Section 15. Regulatory information
U.S. Federal regulations
The following components are listed: STYRENE MONOMER
Clean Water Act (CWA) 307: Naphthenic acids, copper salts
Clean Water Act (CWA) 311: styrene
Massachusetts
:
:
SARA 313
Product name CAS number %
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
styrene 100-42-5 <= 36.0
styrene 100-42-5 35.25
Form R - Reporting
requirements
Supplier notification
Clean Air Act Section 112
(b) Hazardous Air
Pollutants (HAPs)
:
Clean Air Act Section 602
Class I Substances
:Not listed
Clean Air Act Section 602
Class II Substances
:Not listed
New York :The following components are listed: Styrene
New Jersey :The following components are listed: STYRENE MONOMER; BENZENE, ETHENYL-
Pennsylvania :The following components are listed: BENZENE, ETHENYL-
State regulations
TSCA 8(a) PAIR: 4-tert-butylpyrocatechol
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
United States inventory (TSCA 8b): All components are listed or exempted.
SARA 302/304
SARA 304 RQ :4900692.4 lbs / 2224914.4 kg [534327.4 gal / 2022649.4 L]
Composition/information on ingredients
Name % EHS(lbs) (lbs)(gallons) (gallons)
SARA 302 TPQ SARA 304 RQ
SARA 311/312
Classification :Fire hazard
Immediate (acute) health hazard
Delayed (chronic) health hazard
styrene
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SURFBOARD RESINSIL66BQ-249A
Section 15. Regulatory information
WARNING: This product contains a chemical known to the State of California to cause cancer.
styrene Yes. No. No. No.
Ingredient name Cancer Reproductive No significant risk
level
Maximum
acceptable dosage
level
California Prop. 65
Canada inventory :All components are listed or exempted.
Australia inventory (AICS): All components are listed or exempted.
China inventory (IECSC): All components are listed or exempted.
Japan inventory: Not determined.
Korea inventory: All components are listed or exempted.
Malaysia Inventory (EHS Register): Not determined.
New Zealand Inventory of Chemicals (NZIoC): All components are listed or exempted.
Philippines inventory (PICCS): Not determined.
Taiwan inventory (CSNN): All components are listed or exempted.
International regulations
International lists :
Section 16. Other information
8/29/2016.
History
Date of printing :
Hazardous Material Information System (U.S.A.)
2
3
1
1
3
2
*
National Fire Protection Association (U.S.A.)
Health
Special
Instability/Reactivity
Flammability
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS ratings are not required on SDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS ratings are to be used with a fully implemented HMIS
program. HMIS is a registered mark of the National Paint & Coatings Association (NPCA). HMIS materials
may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
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SURFBOARD RESINSIL66BQ-249A
Section 16. Other information
Date of issue/Date of
revision
Version
Prepared by
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Notice to reader
Date of previous issue
:
:
:
Indicates information that has changed from previously issued version.
References :OSHA Hazard Communication Standard, March 2012 (29 CFR 1910.1200)
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
8/29/2016.
1/20/2016.
4.01
Health, Safety and Environmental Department
Email :For questions regarding the SDS contact:iasafety@ip-corporation.com
Date of issue/Date of revision :8/29/2016.Date of previous issue :1/20/2016. Version:4.01 14/14
by | Sep 27, 2025
SURFBOARD RESIN
Unsaturated Polyester Resin
Liquid.
SAFETY DATA SHEET
GHS product identifier
Other means of
identification
Product type
Emergency telephone
number (with hours of
operation)
Section 1. Identification
:
:
:
:
Supplier’s details :INTERPLASTIC CORPORATION
1225 Willow Lake Boulevard
St. Paul, MN 55110-5145
651.481.6860
SURFBOARD RESIN
Material uses
Product code :SIL66BQ-249A
Product use :Industrial applications.
CHEMTREC 24-Hour Emergency Telephone 800.424.9300
Section 2. Hazards identification
FLAMMABLE LIQUIDS – Category 3
ACUTE TOXICITY: INHALATION – Category 4
SKIN CORROSION/IRRITATION – Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION – Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) [Respiratory tract
irritation] – Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): INHALATION
[ears] – Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard statements :Flammable liquid and vapor.
Harmful if inhaled.
Causes serious eye irritation.
Causes skin irritation.
May cause respiratory irritation.
Causes damage to organs through prolonged or repeated exposure if inhaled. (ears)
Hazard pictograms :
Precautionary statements
GHS label elements
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
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SURFBOARD RESINSIL66BQ-249A
Section 2. Hazards identification
Prevention :Wear protective gloves. Wear eye or face protection. Keep away from heat, sparks,
open flames and hot surfaces. – No smoking. Use explosion-proof electrical, ventilating,
lighting and all material-handling equipment. Use only non-sparking tools. Take
precautionary measures against static discharge. Keep container tightly closed. Use
only outdoors or in a well-ventilated area. Do not breathe vapor. Do not eat, drink or
smoke when using this product. Wash hands thoroughly after handling.
Response :Get medical attention if you feel unwell. IF INHALED: Remove victim to fresh air and
keep at rest in a position comfortable for breathing. Call a POISON CENTER or
physician if you feel unwell. IF ON SKIN (or hair): Take off immediately all
contaminated clothing. Rinse skin with water or shower. IF ON SKIN: Wash with
plenty of soap and water. Take off contaminated clothing. If skin irritation occurs: Get
medical attention. IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation
persists: Get medical attention.
Storage :Store containers in a safe place. Store in a well-ventilated place. Keep cool.
Disposal :Dispose of contents and container in accordance with all local, regional, national and
international regulations. Do not pressurize, cut, weld, braze, solder, drill, grind or
expose containers to heat or sources of ignition.
Hazards not otherwise
classified
:None known.
Section 3. Composition/information on ingredients
styrene <= 36.0 100-42-5
Ingredient name CAS number%
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations
applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
Other means of
identification
:Unsaturated Polyester Resin
CAS number :Not applicable.
Substance/mixture
Product code :SIL66BQ-249A
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation. Any concentration shown as
exact is based on formula.
See Section 9 for VOC content. See Section 15 for HAP information.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Section 4. First aid measures
Eye contact :
Description of necessary first aid measures
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SURFBOARD RESINSIL66BQ-249A
Section 4. First aid measures
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention following
exposure or if feeling unwell. Never give anything by mouth to an unconscious person.
If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Skin contact
Inhalation
Ingestion :
:
:
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :Harmful if inhaled. May cause respiratory irritation.
Irritating to mouth, throat and stomach.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
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SURFBOARD RESINSIL66BQ-249A
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and
the container may burst, with the risk of a subsequent explosion. The vapor/gas is
heavier than air and will spread along the ground. Vapors may accumulate in low or
confined areas or travel a considerable distance to a source of ignition and flash back.
Runoff to sewer may create fire or explosion hazard.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use dry chemical, CO , water spray (fog) or foam.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialised clothing is required to deal with the spillage, take note of any information
in Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
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SURFBOARD RESINSIL66BQ-249A
Section 6. Accidental release measures
information and Section 13 for waste disposal.
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Do not store above the following temperature: 38 C (100.4 F). Store in accordance with
local regulations. Store in a segregated and approved area. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area, away from
incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate
all ignition sources. Separate from oxidizing materials. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Do not breathe
vapor or mist. Do not ingest. Avoid contact with eyes, skin and clothing. Use only with
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do
not enter storage areas and confined spaces unless adequately ventilated. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Store and use away from heat, sparks, open flame or
any other ignition source. Use explosion-proof electrical (ventilating, lighting and
material handling) equipment. Use only non-sparking tools. Take precautionary
measures against electrostatic discharges. Empty containers retain product residue
and can be hazardous. Do not reuse container.
:
Precautions for safe handling
styrene ACGIH TLV (United States, 3/2015).
TWA: 20 ppm 8 hours.
TWA: 85 mg/m 8 hours.
STEL: 40 ppm 15 minutes.
STEL: 170 mg/m 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
TWA: 50 ppm 8 hours.
TWA: 215 mg/m 8 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
OSHA PEL Z2 (United States, 2/2013).
TWA: 100 ppm 8 hours.
CEIL: 200 ppm
AMP: 600 ppm 5 minutes.
NIOSH REL (United States, 10/2013).
TWA: 50 ppm 10 hours.
TWA: 215 mg/m 10 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
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SURFBOARD RESINSIL66BQ-249A
Section 8. Exposure controls/personal protection
Hand protection
Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point
Liquid.
Not available.
Characteristic. Aromatic. Sweetish.Odor
pH
VariousColor
Not applicable.
0.1 ppmOdor threshold
:
:
:
:
:
:
Appearance
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SURFBOARD RESINSIL66BQ-249A
Section 9. Physical and chemical properties
Vapor pressure
Relative density
Vapor density
0.9 to 1.3
3.6 [Air = 1]
0.57 kPa (4.3 mm Hg) [room temperature]
Evaporation rate <1 (butyl acetate = 1)
Auto-ignition temperature
Flash point
Not available.
Closed cup: 31.1 C (88 F)
Not available.
Viscosity Not available.
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
Boiling point :145.2 C (293.4 F)
Lower and upper explosive
(flammable) limits
:Lower: 1.1%
Upper: 6.1%
Decomposition temperature:Not available.
Solubility in water :Not applicable.
VOC content (industrial use)35.3 % (w/w) As shipped. Including monomer.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Hazardous reactions or instability may occur under certain conditions of storage or use.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Reactive or incompatible with the following materials: acids and alkalis.
Incompatible with alkali metals. Incompatible with some alkalis. Incompatible with some
strong acids.
Hazardous polymerization may occur under certain conditions of storage or use. Keep
away from heat and direct sunlight. Keep away from heat and flame. Keep away from
oxidizing agents.
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SURFBOARD RESINSIL66BQ-249A
Section 11. Toxicological information
Acute toxicity
styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours
LC50 Inhalation Vapor Rat 11800 mg/m 4 hours
LD50 Oral Rat 2650 mg/kg -
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Not available.
Conclusion/Summary :
Mutagenicity
Not available.
Irritation/Corrosion
styrene Eyes - Mild irritant Human - 50 parts per
million
-
Eyes - Moderate irritantRabbit - 24 hours 100
milligrams
-
Eyes - Severe irritantRabbit - 100
milligrams
-
Skin - Mild irritant Rabbit - 500
milligrams
-
Skin - Moderate irritantRabbit - 100 Percent-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Information on toxicological effects
Styrene manufacturers have determined that the weight of evidence for the
carcinogenicity of this substance does not meet the criteria for classification.
Styrene is listed by IARC as a possible carcinogen to humans (Group 2B) based on
"limited evidence" in humans, "limited evidence" in animals and "other relevant data".
The United States NTP listed styrene as reasonably anticipated to be a human
carcinogen based on "limited evidence" from studies in humans, "sufficient evidence"
from studies in experimental animals, and supporting data on mechanisms of
carcinogenesis. The significance of these results for humans has not been established
through risk assessment.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Specific target organ toxicity (single exposure)
Classification
styrene - 2B Reasonably anticipated to be a human carcinogen.
Product/ingredient name NTPIARCOSHA
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SURFBOARD RESINSIL66BQ-249A
Section 11. Toxicological information
Not available.
Information on the likely
routes of exposure
Inhalation :Harmful if inhaled. May cause respiratory irritation.
Irritating to mouth, throat and stomach.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
Causes damage to organs through prolonged or repeated exposure if inhaled.General :
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Specific target organ toxicity (repeated exposure)
styrene Category 3 Not applicable.Respiratory tract
irritation
Name Category
Name Category
styrene Category 1 Inhalation ears
Aspiration hazard
Name Result
styrene ASPIRATION HAZARD - Category 1
Route of
exposure
Target organs
Route of
exposure
Target organs
:Not available.
Potential acute health effects
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
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SURFBOARD RESINSIL66BQ-249A
Section 11. Toxicological information
No known significant effects or critical hazards.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Numerical measures of toxicity
Oral 7518 mg/kg
Inhalation (gases) 7858.4 ppm
Inhalation (vapors) 33.48 mg/l
Route ATE value
Acute toxicity estimates
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Product/ingredient name
styrene 0.35 13.49 low
Toxicity
styrene Acute EC50 1400 g/l Fresh water Algae - Pseudokirchneriella
subcapitata
72 hours
Acute EC50 720 g/l Fresh water Algae - Pseudokirchneriella
subcapitata
96 hours
Acute EC50 4700 g/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 52000 g/l Marine waterCrustaceans - Artemia salina -
Nauplii
48 hours
Acute LC50 4020 g/l Fresh water Fish - Pimephales promelas 96 hours
Chronic NOEC 63 g/l Fresh water Algae - Pseudokirchneriella
subcapitata
96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Not available.
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SURFBOARD RESINSIL66BQ-249A
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
Section 14. Transport information
RESIN
SOLUTION
3
III
RESIN
SOLUTION
3
III
RESIN
SOLUTION
UN1866
3
III
UN1866 UN1866
Reportable
quantity
2837 lbs / 1288
kg [309.32 gal /
1170.9 L]
Package sizes
shipped in
quantities less
than the
product
reportable
quantity are
not subject to
the RQ
(reportable
quantity)
transportation
requirements.
- -
DOT
Classification
IMDG IATA
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
No. No. No.
Mexico
Classification
UN1866
RESIN
SOLUTION
3
III
No.
-
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SURFBOARD RESINSIL66BQ-249A
Section 14. Transport information
Special precautions for user
Transport in bulk according
to Annex II of MARPOL
73/78 and the IBC Code
Transport within user s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
:Not available.
:
1,4-dihydroxybenzene 0.00 Yes.500 / 10000- 100 -
Section 15. Regulatory information
U.S. Federal regulations
The following components are listed: STYRENE MONOMER
Clean Water Act (CWA) 307: Naphthenic acids, copper salts
Clean Water Act (CWA) 311: styrene
Massachusetts
:
:
SARA 313
Product name CAS number %
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
styrene 100-42-5 <= 36.0
styrene 100-42-5 35.25
Form R - Reporting
requirements
Supplier notification
Clean Air Act Section 112
(b) Hazardous Air
Pollutants (HAPs)
:
Clean Air Act Section 602
Class I Substances
:Not listed
Clean Air Act Section 602
Class II Substances
:Not listed
New York :The following components are listed: Styrene
New Jersey :The following components are listed: STYRENE MONOMER; BENZENE, ETHENYL-
Pennsylvania :The following components are listed: BENZENE, ETHENYL-
State regulations
TSCA 8(a) PAIR: 4-tert-butylpyrocatechol
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
United States inventory (TSCA 8b): All components are listed or exempted.
SARA 302/304
SARA 304 RQ :4900692.4 lbs / 2224914.4 kg [534327.4 gal / 2022649.4 L]
Composition/information on ingredients
Name % EHS(lbs) (lbs)(gallons) (gallons)
SARA 302 TPQ SARA 304 RQ
SARA 311/312
Classification :Fire hazard
Immediate (acute) health hazard
Delayed (chronic) health hazard
styrene
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SURFBOARD RESINSIL66BQ-249A
Section 15. Regulatory information
WARNING: This product contains a chemical known to the State of California to cause cancer.
styrene Yes. No. No. No.
Ingredient name Cancer Reproductive No significant risk
level
Maximum
acceptable dosage
level
California Prop. 65
Canada inventory :All components are listed or exempted.
Australia inventory (AICS): All components are listed or exempted.
China inventory (IECSC): All components are listed or exempted.
Japan inventory: Not determined.
Korea inventory: All components are listed or exempted.
Malaysia Inventory (EHS Register): Not determined.
New Zealand Inventory of Chemicals (NZIoC): All components are listed or exempted.
Philippines inventory (PICCS): Not determined.
Taiwan inventory (CSNN): All components are listed or exempted.
International regulations
International lists :
Section 16. Other information
8/29/2016.
History
Date of printing :
Hazardous Material Information System (U.S.A.)
2
3
1
1
3
2
*
National Fire Protection Association (U.S.A.)
Health
Special
Instability/Reactivity
Flammability
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS ratings are not required on SDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS ratings are to be used with a fully implemented HMIS
program. HMIS is a registered mark of the National Paint & Coatings Association (NPCA). HMIS materials
may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
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SURFBOARD RESINSIL66BQ-249A
Section 16. Other information
Date of issue/Date of
revision
Version
Prepared by
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Notice to reader
Date of previous issue
:
:
:
Indicates information that has changed from previously issued version.
References :OSHA Hazard Communication Standard, March 2012 (29 CFR 1910.1200)
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
8/29/2016.
1/20/2016.
4.01
Health, Safety and Environmental Department
Email :For questions regarding the SDS contact:iasafety@ip-corporation.com
Date of issue/Date of revision :8/29/2016.Date of previous issue :1/20/2016. Version:4.01 14/14
by | Sep 27, 2025
Surfboard Resin
Unsaturated Polyester Resin
Liquid.
SAFETY DATA SHEET
GHS product identifier
Other means of identification
Product type
Emergency telephone
number (with hours of
operation)
Section 1. Identification
:
:
:
:
Supplier’s details :INTERPLASTIC CORPORATION
1225 Willow Lake Boulevard
St. Paul, MN 55110-5145
651.481.6860
Surfboard Resin
Relevant identified uses of the substance or mixture and uses advised against
Product code :SIL66BE-249BLH
Industrial applications.
CHEMTREC 24-Hour Emergency Telephone
US and Canada 800.424.9300
Outside US and Canada +1 703.741.5970
Section 2. Hazards identification
FLAMMABLE LIQUIDS – Category 3
ACUTE TOXICITY (inhalation) – Category 4
SKIN IRRITATION – Category 2
EYE IRRITATION – Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) – Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) –
Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard statements :Flammable liquid and vapor.
Harmful if inhaled.
Causes serious eye irritation.
Causes skin irritation.
May cause respiratory irritation.
Causes damage to organs through prolonged or repeated exposure. (hearing organs)
Hazard pictograms :
Precautionary statements
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown dermal toxicity: 33.3%
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
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Surfboard Resin SIL66BE-249BLH
Section 2. Hazards identification
Prevention :Wear protective gloves. Wear eye or face protection. Keep away from heat, hot
surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-
proof electrical, ventilating, lighting and all material-handling equipment. Use only non-
sparking tools. Take precautionary measures against static discharge. Keep container
tightly closed. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Do
not eat, drink or smoke when using this product. Wash hands thoroughly after handling.
Response :Get medical attention if you feel unwell. IF INHALED: Remove person to fresh air and
keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell.
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water or shower. IF ON SKIN: Wash with plenty of soap and water. Take off
contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical
attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get
medical attention.
Storage :Store in a well-ventilated place. Keep cool. Store containers in a safe place.
Disposal :Dispose of contents and container in accordance with all local, regional, national and
international regulations. Do not pressurize, cut, weld, braze, solder, drill, grind or
expose containers to heat or sources of ignition.
Hazards not otherwise
classified
:None known.
Section 3. Composition/information on ingredients
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Other means of
identification
:Unsaturated Polyester Resin
Substance/mixture :
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Any concentration shown as exact is based on formula.
VOC content is listed in Section 9.
Environmental composition is shown in Section 15.
styrene <= 33.6 100-42-5
Ingredient name % CAS number
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Inhalation :
:
Description of necessary first aid measures
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention. Buffered baby shampoo will aid in removal of resin.
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Surfboard Resin SIL66BE-249BLH
Section 4. First aid measures
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention following
exposure or if feeling unwell. Never give anything by mouth to an unconscious person.
If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Remove contaminated clothing and shoes. Flush contaminated skin with plenty of
water. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Skin contact
Ingestion :
:
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Use dry chemical, CO , water spray (fog) or foam.
Extinguishing media
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
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Surfboard Resin SIL66BE-249BLH
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a
fire or if heated, a pressure increase will occur and the container may burst, with the risk
of a subsequent explosion. The vapor/gas is heavier than air and will spread along the
ground. Vapors may accumulate in low or confined areas or travel a considerable
distance to a source of ignition and flash back.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
:
:
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and
place in container for disposal according to local regulations (see Section 13). Dispose
of via a licensed waste disposal contractor. Contaminated absorbent material may pose
the same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal. Wear appropriate respiratory protection.
Wear protective clothing and eye or face protection:
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dispose of via a licensed waste disposal contractor.
Absorb with an inert material and transfer the spilled material and absorbent to an
appropriate waste disposal container. Wear appropriate respirator when ventilation is
inadequate. Wear eye/face protection.
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Surfboard Resin SIL66BE-249BLH
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Do not store above the following temperature: 38 C (100.4 F). Store in accordance with
local regulations. Store in a segregated and approved area. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area, away from
incompatible materials (see Section 10) and food and drink. Eliminate all ignition
sources. Separate from oxidizing materials. Keep container tightly closed and sealed
until ready for use. Containers that have been opened must be carefully resealed and
kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate
containment to avoid environmental contamination. See Section 10 for incompatible
materials before handling or use. Store containers in a safe place.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Do not breathe
vapor or mist. Do not ingest. Avoid contact with eyes, skin and clothing. Use only with
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do
not enter storage areas and confined spaces unless adequately ventilated. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Store and use away from heat, sparks, open flame or
any other ignition source. Use explosion-proof electrical (ventilating, lighting and
material handling) equipment. Use only non-sparking tools. Take precautionary
measures against electrostatic discharges. Empty containers retain product residue
and can be hazardous. Do not reuse container.
:
Precautions for safe handling
styrene ACGIH TLV (United States, 3/2019).
TWA: 20 ppm 8 hours.
STEL: 40 ppm 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
TWA: 50 ppm 8 hours.
TWA: 215 mg/m 8 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
OSHA PEL Z2 (United States, 2/2013).
TWA: 100 ppm 8 hours.
CEIL: 200 ppm
AMP: 600 ppm 5 minutes.
NIOSH REL (United States, 10/2016).
TWA: 50 ppm 10 hours.
TWA: 215 mg/m 10 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
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Surfboard Resin SIL66BE-249BLH
Section 8. Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point
Liquid.
Not available.
Characteristic.Odor
pH
VariousColor
Evaporation rate <1 (butyl acetate = 1)
Flash point Closed cup: 31.1 C (88 F)
Not applicable.
0.1 ppmOdor threshold
:
:
:
:
:
:
:
:
Appearance
Boiling point :145 C (293 F)
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Surfboard Resin SIL66BE-249BLH
Section 9. Physical and chemical properties
Vapor pressure
Relative density
Vapor density
Solubility
1.01 to 1.3
3.6 [Air = 1]
0.67 kPa (5 mm Hg) [room temperature]
Not available.
Auto-ignition temperature Not available.
Not available.
Viscosity Not available.
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
Lower and upper explosive
(flammable) limits
:Lower: 0.9%
Upper: 6.8%
Solubility in water :Not applicable.
VOC content :33.5 % (w/w) As shipped, including monomers and additives.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Hazardous reactions or instability may occur under certain conditions of storage or use.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Hazardous polymerization may occur under certain conditions of storage or use. Keep
away from heat and direct sunlight. Keep away from heat and flame. Keep away from
oxidizing agents.
Reactive or incompatible with the following materials: metals, acids and alkalis.
Incompatible with alkali metals. Incompatible with some alkalis. Incompatible with some
strong acids. Incompatible with copper alloys, brass.
Section 11. Toxicological information
Acute toxicity
styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours
LC50 Inhalation Vapor Rat 11800 mg/m 4 hours
LD50 Oral Rat 2650 mg/kg -
Product/ingredient name Result Species Dose Exposure
Irritation/Corrosion
Information on toxicological effects
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Surfboard Resin SIL66BE-249BLH
Section 11. Toxicological information
Carcinogenicity
Not available.
Conclusion/Summary :
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
styrene Eyes - Mild irritant Human - 50 ppm -
Eyes - Moderate irritantRabbit - 24 hours 100
mg
-
Eyes - Severe irritantRabbit - 100 mg -
Skin - Mild irritant Rabbit - 500 mg -
Skin - Moderate irritantRabbit - 100 % -
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
styrene Category 3 Not applicable.Respiratory tract
irritation
Name Category
Name Category
styrene Category 1 Inhalation hearing organs
Aspiration hazard
Name Result
styrene ASPIRATION HAZARD - Category 1
Route of
exposure
Target organs
Route of
exposure
Target organs
Classification
styrene - 2A Reasonably anticipated to be a human carcinogen.
Product/ingredient name NTPIARCOSHA
Styrene manufacturers have determined that the weight of evidence for the
carcinogenicity of this substance does not meet the criteria for classification.
In 2018, styrene was listed by IARC as a probable carcinogen to humans (Group 2A)
based on hazard assessment data. The United States NTP listed styrene as reasonably
anticipated to be a human carcinogen based on "limited evidence" from studies in
humans, "sufficient evidence" from studies in experimental animals, and supporting
data on mechanisms of carcinogenesis. The significance of these results for humans
has not been established through risk assessment.
A study of long term effects of workers exposed to styrene levels in the range of 25-35 ppm for an 8-hour TWA indicated
a possible mild hearing loss.
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Surfboard Resin SIL66BE-249BLH
Section 11. Toxicological information
Not available.
Information on the likely
routes of exposure
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
Causes damage to organs through prolonged or repeated exposure.General :
No known significant effects or critical hazards.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Oral 7959.2 mg/kg
Inhalation (gases) 8319.6 ppm
Inhalation (vapors) 35.44 mg/l
Route ATE value
Acute toxicity estimates
:Not available.
Potential acute health effects
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
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Surfboard Resin SIL66BE-249BLH
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Product/ingredient name
styrene 0.35 13.49 low
Product/ingredient name Aquatic half-life Photolysis Biodegradability
styrene - - Readily
Toxicity
styrene Acute EC50 1400 g/l Fresh water Algae - Pseudokirchneriella
subcapitata
72 hours
Acute EC50 720 g/l Fresh water Algae - Pseudokirchneriella
subcapitata
96 hours
Acute EC50 4700 g/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 52 mg/l Marine water Crustaceans - Artemia salina48 hours
Acute LC50 4020 g/l Fresh water Fish - Pimephales promelas 96 hours
Chronic NOEC 63 g/l Fresh water Algae - Pseudokirchneriella
subcapitata
96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
styrene OECD 70 % - Readily - 28 days - -
Product/ingredient name Test DoseResult Inoculum
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
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Surfboard Resin SIL66BE-249BLH
Section 14. Transport information
RESIN
SOLUTION
3
III
RESIN
SOLUTION
3
III
RESIN
SOLUTION
UN1866
3
III
UN1866 UN1866
Reportable quantity 3003.5 lbs / 1363.6 kg [311.88 gal / 1180.6 L]. Package sizes
shipped in quantities less than the product reportable quantity are not subject to the RQ
(reportable quantity) transportation requirements.
DOT
Classification
IMDGIATA
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional information
Environmental
hazards
Special precautions for user
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
No. No.No.
Transport within user s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
:Not available.
:
Product classified as per the following sections of the Transportation of Dangerous
Goods Regulations: 2.18-2.19 (Class 3).
Mexico
Classification
UN1866
RESIN
SOLUTION
3
III
No.
DOT Classification
TDG Classification
:
:
TDG
Classification
UN1866
RESIN
SOLUTION
3
III
No.
Section 15. Regulatory information
U.S. Federal regulations
Clean Water Act (CWA) 307: Naphthenic acids, copper salts; 2-ethylhexanoic acid,
copper salt
Clean Water Act (CWA) 311: styrene; propionic acid
:
Clean Air Act Section 112(b)
Hazardous Air Pollutants
(HAPs)
:
Clean Air Act Section 602
Class I Substances
:Not listed
TSCA 5(a)2 final significant new use rules: 1,2-Benzenedicarboxylic acid, mixed
esters with benzyl alc., cyclohexanol, 2-ethyl-1-hexanol, fumaric acid and propylene
glycol
TSCA 8(a) PAIR: triethyl phosphate
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
TSCA 8(c) calls for record of SAR: triethyl phosphate
TSCA 12(b) one-time export: 1,2-Benzenedicarboxylic acid, mixed esters with benzyl
alc., cyclohexanol, 2-ethyl-1-hexanol, fumaric acid and propylene glycol
Listed
If components are "Listed", and additional information is required, contact Supplier
using email in Section 16.
Date of issue/Date of revision :11/6/2020 Date of previous issue :9/7/2018 Version:1.01 11/14
Surfboard Resin SIL66BE-249BLH
Section 15. Regulatory information
The following components are listed: STYRENE; PHENYLETHYLENEMassachusetts :
SARA 313
Product name CAS number %
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
Styrene
Form R - Reporting
requirements
Supplier notification
California Prop. 65
Clean Air Act Section 602
Class II Substances
:Not listed
New York :The following components are listed: Styrene
New Jersey :The following components are listed: STYRENE MONOMER; BENZENE, ETHENYL-
Pennsylvania :The following components are listed: BENZENE, ETHENYL-
State regulations
SARA 302/304
SARA 304 RQ :1627096.8 lbs / 738701.9 kg [168956.2 gal / 639568.8 L]
1,4-dihydroxybenzene <0.1 Yes.500 / 10000- 100 -
Composition/information on ingredients
Name % EHS(lbs) (lbs)(gallons) (gallons)
SARA 302 TPQ SARA 304 RQ
Inventory list
Australia :Not determined.
Canada :Not determined.
China :Not determined.
Europe :Not determined.
Japan :Japan inventory (ENCS): Not determined.
Japan inventory (ISHL): Not determined.
Republic of Korea :Not determined.
Malaysia :Not determined.
New Zealand :Not determined.
Philippines :Not determined.
Taiwan :Not determined.
Thailand :Not determined.
SARA 311/312
Classification :FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (inhalation) - Category 4
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) -
Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) - Category 1
:The following components are listed. For more information go to www.P65Warnings.ca.gov.
styrene 100-42-5 <= 34.0
styrene 100-42-5 33.29
Any concentration shown as exact is based on formula.
Date of issue/Date of revision :11/6/2020 Date of previous issue :9/7/2018 Version:1.01 12/14
Surfboard Resin SIL66BE-249BLH
Section 15. Regulatory information
Turkey :Not determined.
United States :All components are listed or exempted.
Viet Nam :Not determined.
Section 16. Other information
11/6/2020
History
Date of printing
Date of issue/Date of
revision
Version
Date of previous issue
:
:
:
:
11/6/2020
9/7/2018
1.01
Hazardous Material Information System (U.S.A.)
2
3
1
1
3
2
*
National Fire Protection Association (U.S.A.)
Health
Special
Instability/Reactivity
Flammability
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS
ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS
Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual.
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Procedure used to derive the classification
Classification Justification
FLAMMABLE LIQUIDS - Category 3 On basis of test data
ACUTE TOXICITY (inhalation) - Category 4 Calculation method
SKIN IRRITATION - Category 2 Calculation method
EYE IRRITATION - Category 2A Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) -
Category 1
Calculation method
New form 08-2018
Date of issue/Date of revision :11/6/2020 Date of previous issue :9/7/2018 Version:1.01 13/14
Surfboard Resin SIL66BE-249BLH
Section 16. Other information
Prepared by
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Notice to reader
:
Indicates information that has changed from previously issued version.
References :
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
Health, Safety and Environmental Department
For questions about the
SDS, contact
:iasafety@ip-corporation.com
29 CFR 1910.1200 Hazard Communication Standard, March 2012
CCR Title 27 Division 4 Office of Environmental Health Hazard Assessment (California
Prop. 65)
American Composites Manufacturers Association
Styrene Information and Research Center
Date of issue/Date of revision :11/6/2020 Date of previous issue :9/7/2018 Version:1.01 14/14
