SAFETY DATA SHEET
DOWSIL TB/TL/CER Sealant Clear
Version
3.0
Revision Date:
10/16/2017
SDS Number:
1291572-00010
Date of last issue: 04/24/2017
Date of first issue: 02/10/2015
1 / 11
SECTION 1. IDENTIFICATION
Product name
: DOWSIL TB/TL/CER Sealant Clear
Product code
: 04045036
Manufacturer or supplier’s details
Company Identification
: THE DOW CHEMICAL COMPANY
2030 WILLARD H DOW CENTER
MIDLAND MI 48674-0000
UNITED STATES
Telephone
: 800-258-2436
24-Hour Emergency Contact
: Chemtrec +1 800-424-9300
Local Emergency Number
: 800-424-9300
E-mail address : SDSQuestion@dow.com
Recommended use of the chemical and restrictions on use
Recommended use
: Adhesive, binding agents
SECTION 2. HAZARDS IDENTIFICATION
GHS classification in accordance with 29 CFR 1910.1200
Not a hazardous substance or mixture.
GHS label elements
Not a hazardous substance or mixture.
Precautionary Statements
:
Prevention:
P271 Use only outdoors or in a well-ventilated area.
Other hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture
: Mixture
Chemical nature
: Silicone elastomer
Hazardous ingredients
Chemical name CAS-No. Concentration (% w/w)
Silicon dioxide 7631-86-9 >= 8 – <= 9
SECTION 4. FIRST AID MEASURES
SAFETY DATA SHEET
DOWSIL TB/TL/CER Sealant Clear
Version
3.0
Revision Date:
10/16/2017
SDS Number:
1291572-00010
Date of last issue: 04/24/2017
Date of first issue: 02/10/2015
2 / 11
If inhaled
: If inhaled, remove to fresh air.
Get medical attention if symptoms occur.
In case of skin contact
: Wash with water and soap as a precaution.
Get medical attention if symptoms occur.
In case of eye contact
: Flush eyes with water as a precaution.
Get medical attention if irritation develops and persists.
If swallowed
: If swallowed, DO NOT induce vomiting.
Get medical attention if symptoms occur.
Rinse mouth thoroughly with water.
Most important symptoms
and effects, both acute and
delayed
: None known.
Protection of first-aiders
: No special precautions are necessary for first aid responders.
Notes to physician
: Treat symptomatically and supportively.
SECTION 5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
: Water spray
Alcohol-resistant foam
Carbon dioxide (CO2)
Dry chemical
Unsuitable extinguishing
media
: None known.
Specific hazards during fire
fighting
: Exposure to combustion products may be a hazard to health.
Hazardous combustion prod-
ucts
: Carbon oxides
Silicon oxides
Formaldehyde
Specific extinguishing meth-
ods
: Use extinguishing measures that are appropriate to local cir-
cumstances and the surrounding environment.
Use water spray to cool unopened containers.
Remove undamaged containers from fire area if it is safe to do
so.
Evacuate area.
Special protective equipment
for fire-fighters
: Wear self-contained breathing apparatus for firefighting if
necessary.
Use personal protective equipment.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protec-
tive equipment and emer-
: Follow safe handling advice and personal protective
equipment recommendations.
SAFETY DATA SHEET
DOWSIL TB/TL/CER Sealant Clear
Version
3.0
Revision Date:
10/16/2017
SDS Number:
1291572-00010
Date of last issue: 04/24/2017
Date of first issue: 02/10/2015
3 / 11
gency procedures
Environmental precautions
: Discharge into the environment must be avoided.
Prevent further leakage or spillage if safe to do so.
Retain and dispose of contaminated wash water.
Local authorities should be advised if significant spillages
cannot be contained.
Methods and materials for
containment and cleaning up
: Soak up with inert absorbent material.
For large spills, provide diking or other appropriate
containment to keep material from spreading. If diked material
can be pumped, store recovered material in appropriate
container.
Clean up remaining materials from spill with suitable
absorbent.
Local or national regulations may apply to releases and
disposal of this material, as well as those materials and items
employed in the cleanup of releases. You will need to
determine which regulations are applicable.
Sections 13 and 15 of this SDS provide information regarding
certain local or national requirements.
SECTION 7. HANDLING AND STORAGE
Technical measures
: See Engineering measures under EXPOSURE
CONTROLS/PERSONAL PROTECTION section.
Local/Total ventilation
: Use only with adequate ventilation.
Advice on safe handling
: Handle in accordance with good industrial hygiene and safety
practice.
Take care to prevent spills, waste and minimize release to the
environment.
Conditions for safe storage
: Keep in properly labeled containers.
Store in accordance with the particular national regulations.
Materials to avoid
: Do not store with the following product types:
Strong oxidizing agents
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Ingredients with workplace control parameters
Ingredients CAS-No. Value type
(Form of
exposure)
Control parame-
ters / Permissible
concentration
Basis
Silicon dioxide 7631-86-9 TWA (Dust) 20 Million
particles per cubic
foot
(Silica)
OSHA Z-3
TWA (Dust) 80 mg/m3
/ %SiO2
OSHA Z-3
SAFETY DATA SHEET
DOWSIL TB/TL/CER Sealant Clear
Version
3.0
Revision Date:
10/16/2017
SDS Number:
1291572-00010
Date of last issue: 04/24/2017
Date of first issue: 02/10/2015
4 / 11
(Silica)
TWA 6 mg/m
(Silica)
NIOSH REL
These substance(s) are inextricably bound in the product and therefore do not contribute
to a dust inhalation hazard.
Silicon dioxide
Engineering measures : Processing may form hazardous compounds (see section
10).
Ensure adequate ventilation, especially in confined areas.
Minimize workplace exposure concentrations.
Personal protective equipment
Respiratory protection
: No personal respiratory protective equipment normally
required.
Hand protection
Remarks
: Wash hands before breaks and at the end of workday.
Eye protection
: Wear the following personal protective equipment:
Safety glasses
Skin and body protection
: Skin should be washed after contact.
Hygiene measures
: Ensure that eye flushing systems and safety showers are
located close to the working place.
When using do not eat, drink or smoke.
Wash contaminated clothing before re-use.
These precautions are for room temperature handling. Use at
elevated temperature or aerosol/spray applications may
require added precautions.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
: paste
Color
: colorless
Odor
: Acetic acid
Odor Threshold
: No data available
pH
: Not applicable
Melting point/freezing point
: No data available
Initial boiling point and boiling
range
: Not applicable
Flash point : Not applicable
SAFETY DATA SHEET
DOWSIL TB/TL/CER Sealant Clear
Version
3.0
Revision Date:
10/16/2017
SDS Number:
1291572-00010
Date of last issue: 04/24/2017
Date of first issue: 02/10/2015
5 / 11
Evaporation rate
: Not applicable
Flammability (solid, gas)
: Not classified as a flammability hazard
Self-ignition : The substance or mixture is not classified as pyrophoric. The
substance or mixture is not classified as self heating.
Upper explosion limit / Upper
flammability limit
: No data available
Lower explosion limit / Lower
flammability limit
: No data available
Vapor pressure
: Not applicable
Relative vapor density
: No data available
Relative density
: 1.04
Solubility(ies)
Water solubility
: No data available
Partition coefficient: n-
octanol/water
: No data available
Autoignition temperature
: No data available
Decomposition temperature
: No data available
Viscosity
Viscosity, dynamic
: Not applicable
Explosive properties
: Not explosive
Oxidizing properties
: The substance or mixture is not classified as oxidizing.
Molecular weight
: No data available
Particle size
: No data available
SECTION 10. STABILITY AND REACTIVITY
Reactivity
: Not classified as a reactivity hazard.
Chemical stability
: Stable under normal conditions.
Possibility of hazardous reac-
tions
: Use at elevated temperatures may form highly hazardous
compounds.
Can react with strong oxidizing agents.
Acetic acid is formed upon contact with water or humid air.
Hazardous decomposition products will be formed at elevated
temperatures.
SAFETY DATA SHEET
DOWSIL TB/TL/CER Sealant Clear
Version
3.0
Revision Date:
10/16/2017
SDS Number:
1291572-00010
Date of last issue: 04/24/2017
Date of first issue: 02/10/2015
6 / 11
Conditions to avoid
: None known.
Incompatible materials
: Oxidizing agents
Hazardous decomposition products
Thermal decomposition
: Formaldehyde
SECTION 11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Skin contact
Ingestion
Eye contact
Acute toxicity
Not classified based on available information.
Ingredients:
Silicon dioxide:
Acute oral toxicity
: LD50 (Rat): > 3,300 mg/kg
Assessment: The substance or mixture has no acute oral tox-
icity
Remarks: Information taken from reference works and the
literature.
Acute inhalation toxicity
: LC50 (Rat): > 2.08 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Assessment: The substance or mixture has no acute inhala-
tion toxicity
Remarks: Information taken from reference works and the
literature.
Acute dermal toxicity
: LD50 (Rabbit): > 5,000 mg/kg
Assessment: The substance or mixture has no acute dermal
toxicity
Remarks: Information taken from reference works and the
literature.
Skin corrosion/irritation
Not classified based on available information.
Ingredients:
Silicon dioxide:
Result: No skin irritation
Remarks: Information taken from reference works and the literature.
Serious eye damage/eye irritation
Not classified based on available information.
SAFETY DATA SHEET
DOWSIL TB/TL/CER Sealant Clear
Version
3.0
Revision Date:
10/16/2017
SDS Number:
1291572-00010
Date of last issue: 04/24/2017
Date of first issue: 02/10/2015
7 / 11
Ingredients:
Silicon dioxide:
Result: No eye irritation
Remarks: Information taken from reference works and the literature.
Respiratory or skin sensitization
Skin sensitization
Not classified based on available information.
Respiratory sensitization
Not classified based on available information.
Ingredients:
Silicon dioxide:
Assessment: Does not cause skin sensitization.
Test Type: Skin: test type not specified
Species: Guinea pig
Result: negative
Remarks: Information taken from reference works and the literature.
Germ cell mutagenicity
Not classified based on available information.
Ingredients:
Silicon dioxide:
Genotoxicity in vitro
: Result: negative
Remarks: Information taken from reference works and the
literature.
Genotoxicity in vivo
: Application Route: Ingestion
Result: negative
Remarks: Information taken from reference works and the
literature.
Germ cell mutagenicity –
Assessment
: Animal testing did not show any mutagenic effects.
Carcinogenicity
Not classified based on available information.
IARC
No ingredient of this product present at levels greater than or
equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.
OSHA
No component of this product present at levels greater than or
equal to 0.1% is on OSHA s list of regulated carcinogens.
NTP
No ingredient of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.
SAFETY DATA SHEET
DOWSIL TB/TL/CER Sealant Clear
Version
3.0
Revision Date:
10/16/2017
SDS Number:
1291572-00010
Date of last issue: 04/24/2017
Date of first issue: 02/10/2015
8 / 11
Reproductive toxicity
Not classified based on available information.
STOT-single exposure
Not classified based on available information.
STOT-repeated exposure
Not classified based on available information.
Aspiration toxicity
Not classified based on available information.
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
No data available
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Other adverse effects
No data available
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Resource Conservation and
Recovery Act (RCRA)
: This product has been evaluated for RCRA characteristics
and does not meet the criteria of hazardous waste if discarded
in its purchased form.
Waste from residues : Dispose of in accordance with local regulations.
Contaminated packaging : Empty containers should be taken to an approved waste
handling site for recycling or disposal.
If not otherwise specified: Dispose of as unused product.
SECTION 14. TRANSPORT INFORMATION
International Regulations
UNRTDG
Not regulated as a dangerous good
IATA-DGR
Not regulated as a dangerous good
IMDG-Code
SAFETY DATA SHEET
DOWSIL TB/TL/CER Sealant Clear
Version
3.0
Revision Date:
10/16/2017
SDS Number:
1291572-00010
Date of last issue: 04/24/2017
Date of first issue: 02/10/2015
9 / 11
Not regulated as a dangerous good
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Domestic regulation
49 CFR
Not regulated as a dangerous good
SECTION 15. REGULATORY INFORMATION
EPCRA – Emergency Planning and Community Right-to-Know
CERCLA Reportable Quantity
Ingredients CAS-No. Component RQ
(lbs)
Calculated product RQ
(lbs)
Acetic acid 64-19-7 5000 *
Acetic anhydride 108-24-7 5000 *
*: Calculated RQ exceeds reasonably attainable upper limit.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
SARA 302 Extremely Hazardous Substances Threshold Planning Quantity
This material does not contain any components with a section 302 EHS TPQ.
SARA 311/312 Hazards
: No SARA Hazards
SARA 313
: This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.
US State Regulations
Pennsylvania Right To Know
Dimethyl siloxane, hydroxy-terminated 70131-67-8
Silicon dioxide 7631-86-9
Acetic acid 64-19-7
Acetic anhydride 108-24-7
California Prop. 65
This product does not contain any chemicals known to the State of California to cause cancer,
birth, or any other reproductive defects.
California Permissible Exposure Limits for Chemical Contaminants
Silicon dioxide 7631-86-9
The ingredients of this product are reported in the following inventories:
NZIoC
: All ingredients listed or exempt.
AICS
: All ingredients listed or exempt.
IECSC
: All ingredients listed or exempt.
PICCS : All ingredients listed or exempt.
SAFETY DATA SHEET
DOWSIL TB/TL/CER Sealant Clear
Version
3.0
Revision Date:
10/16/2017
SDS Number:
1291572-00010
Date of last issue: 04/24/2017
Date of first issue: 02/10/2015
10 / 11
DSL
: All chemical substances in this product comply with the CEPA
1999 and NSNR and are on or exempt from listing on the
Canadian Domestic Substances List (DSL).
REACH
: For purchases from Dow Chemical EU legal entities, all
ingredients are currently pre/registered or exempt under
REACH. Please refer to section 1 for recommended uses. For
purchases from non-EU Dow Chemical legal entities with the
intention to export into EEA please contact your DC
representative/local office.
TSCA
: All chemical substances in this product are either listed on the
TSCA Inventory or are in compliance with a TSCA Inventory
exemption.
TCSI
: All ingredients listed or exempt.
SECTION 16. OTHER INFORMATION
Further information
NFPA: HMIS IV:
HMIS ratings are based on a 0-4 rating
scale, with 0 representing minimal ha-
zards or risks, and 4 representing signifi-
cant hazards or risks. The “*” represents
a chronic hazard, while the “/” represents
the absence of a chronic hazard.
Full text of other abbreviations
NIOSH REL : USA. NIOSH Recommended Exposure Limits
OSHA Z-3 : USA. Occupational Exposure Limits (OSHA) – Table Z-3 Min-
eral Dusts
NIOSH REL / TWA : Time-weighted average concentration for up to a 10-hour
workday during a 40-hour workweek
OSHA Z-3 / TWA : 8-hour time weighted average
AICS – Australian Inventory of Chemical Substances; ASTM – American Society for the Testing of
Materials; bw – Body weight; CERCLA – Comprehensive Environmental Response, Compensation,
and Liability Act; CMR – Carcinogen, Mutagen or Reproductive Toxicant; DIN – Standard of the
German Institute for Standardisation; DOT – Department of Transportation; DSL – Domestic Sub-
stances List (Canada); ECx – Concentration associated with x% response; EHS – Extremely Ha-
Flammability
Health
Instability
0
1
0
Special hazard.
FLAMMABILITY
1
PHYSICAL HAZARD
HEALTH
0
/ 0
SAFETY DATA SHEET
DOWSIL TB/TL/CER Sealant Clear
Version
3.0
Revision Date:
10/16/2017
SDS Number:
1291572-00010
Date of last issue: 04/24/2017
Date of first issue: 02/10/2015
11 / 11
zardous Substance; ELx – Loading rate associated with x% response; EmS – Emergency Sche-
dule; ENCS – Existing and New Chemical Substances (Japan); ErCx – Concentration associated
with x% growth rate response; ERG – Emergency Response Guide; GHS – Globally Harmonized
System; GLP – Good Laboratory Practice; HMIS – Hazardous Materials Identification System;
IARC – International Agency for Research on Cancer; IATA – International Air Transport Associa-
tion; IBC – International Code for the Construction and Equipment of Ships carrying Dangerous
Chemicals in Bulk; IC50 – Half maximal inhibitory concentration; ICAO – International Civil Avia-
tion Organization; IECSC – Inventory of Existing Chemical Substances in China; IMDG – Interna-
tional Maritime Dangerous Goods; IMO – International Maritime Organization; ISHL – Industrial
Safety and Health Law (Japan); ISO – International Organisation for Standardization; KECI – Ko-
rea Existing Chemicals Inventory; LC50 – Lethal Concentration to 50 % of a test population; LD50
– Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL – International Conven-
tion for the Prevention of Pollution from Ships; MSHA – Mine Safety and Health Administration;
n.o.s. – Not Otherwise Specified; NFPA – National Fire Protection Association; NO(A)EC – No Ob-
served (Adverse) Effect Concentration; NO(A)EL – No Observed (Adverse) Effect Level; NOELR –
No Observable Effect Loading Rate; NTP – National Toxicology Program; NZIoC – New Zealand
Inventory of Chemicals; OECD – Organization for Economic Co-operation and Development;
OPPTS – Office of Chemical Safety and Pollution Prevention; PBT – Persistent, Bioaccumulative
and Toxic substance; PICCS – Philippines Inventory of Chemicals and Chemical Substances;
(Q)SAR – (Quantitative) Structure Activity Relationship; RCRA – Resource Conservation and Re-
covery Act; REACH – Regulation (EC) No 1907/2006 of the European Parliament and of the
Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; RQ –
Reportable Quantity; SADT – Self-Accelerating Decomposition Temperature; SARA – Superfund
Amendments and Reauthorization Act; SDS – Safety Data Sheet; TCSI – Taiwan Chemical Sub-
stance Inventory; TSCA – Toxic Substances Control Act (United States); UN – United Nations;
UNRTDG – United Nations Recommendations on the Transport of Dangerous Goods; vPvB –
Very Persistent and Very Bioaccumulative
Sources of key data used to
compile the Material Safety
Data Sheet
: Internal technical data, data from raw material SDSs, OECD
eChem Portal search results and European Chemicals Agen-
cy, http://echa.europa.eu/
Revision Date : 10/16/2017
Items where changes have been made to the previous version are highlighted in the body of this
document by two vertical lines.
The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and
shall not be considered a warranty or quality specification of any type. The information provided
relates only to the specific material identified at the top of this SDS and may not be valid when the
SDS material is used in combination with any other materials or in any process, unless specified
in the text. Material users should review the information and recommendations in the specific
context of their intended manner of handling, use, processing and storage, including an
assessment of the appropriateness of the SDS material in the user s end product, if applicable.
US / Z8