* O D V V ) D E U L F
Not available.
Solid.
GHS product identifier
Other means of
identification
Product type
Section 1. Identification
:
:
Relevant identified uses of the substance or mixture and uses advised against
SAFETY DATA SHEET
* O D V V ) D E U L F
Product use :Glass fibres
Area of application :Professional applications.
vS0nPd0fnnndPS0o9F2tEmergency telephone
number (with hours of
operation)
Supplier/Manufacturer
e-mail address of person
responsible for this SDS
:
Product code :
Section 2. Hazards identification
Classification of the
substance or mixture
:
Signal word :No signal word.
Hazard statements :No known significant effects or critical hazards.
Precautionary statements
Prevention :Not applicable.
Response :Not applicable.
Storage :Not applicable.
Disposal :Not applicable.
GHS label elements
OSHA/HCS status :While this material is not considered hazardous by the OSHA Hazard Communication
Standard (29 CFR 1910.1200), this SDS contains valuable information critical to the
safe handling and proper use of the product. This SDS should be retained and available
for employees and other users of this product.
Hazards not otherwise
classified
:None known.
Not classified.
Date of issue/Date of revision :11/29/2022Date of previous issue :No previous validationVersion:1 1/11
United States
Not available.
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Website: www. V D H U W H [.com
:
:
:
* O D V V ) D E U L F
Section 3. Composition/information on ingredients
titanium dioxide – 1 13463-67-7
Ingredient name CAS number%
Other means of
identification
:Not available.
Substance/mixture :Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Other names
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified and hence require reporting in this section.
Wash out mouth with water. If material has been swallowed and the exposed person is
conscious, give small quantities of water to drink. Do not induce vomiting unless
directed to do so by medical personnel. Get medical attention if symptoms occur.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Get medical attention if irritation
occurs.
Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Get medical attention if symptoms occur.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get
medical attention if symptoms occur.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Description of necessary first aid measures
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact :No specific data.
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Date of issue/Date of revision :11/29/2022Date of previous issue :No previous validationVersion:1 2/11
United States
* O D V V ) D E U L F
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides
No specific fire or explosion hazard.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
In case of fire, use water spray (fog), foam, dry chemical or CO .
Extinguishing media
:
:
:
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Move containers from spill area. Prevent entry into sewers, water courses, basements
or confined areas. Vacuum or sweep up material and place in a designated, labeled
waste container. Dispose of via a licensed waste disposal contractor. Note: see
Section 1 for emergency contact information and Section 13 for waste disposal.
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Put on appropriate personal
protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Move containers from spill area. Vacuum or sweep up material and place in a
designated, labeled waste container. Dispose of via a licensed waste disposal
contractor.Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in “For non-
emergency personnel”.
Section 7. Handling and storage
Protective measures Put on appropriate personal protective equipment (see Section 8).:
Precautions for safe handling
Date of issue/Date of revision :11/29/2022Date of previous issue :No previous validationVersion:1 3/11
United States
* O D V V ) D E U L F
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Store between the following temperatures: 20 to 25 C (68 to 77 F). Store in accordance
with local regulations. Store in original container protected from direct sunlight in a dry,
cool and well-ventilated area, away from incompatible materials (see Section 10) and
food and drink. Keep container tightly closed and sealed until ready for use. Containers
that have been opened must be carefully resealed and kept upright to prevent leakage.
Do not store in unlabeled containers. Use appropriate containment to avoid
environmental contamination. See Section 10 for incompatible materials before
handling or use.
:
:
titanium dioxide OSHA PEL (United States, 5/2018).
TWA: 15 mg/m 8 hours. Form: Total dust
ACGIH TLV (United States, 1/2022).
TWA: 2.5 mg/m 8 hours. Form: respirable fraction,
finescale particles
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. 4 – 8 hours (breakthrough time): Protective/insulated gloves. If applicable
Rubber gloves. Butyl gloves. Neoprene gloves./ polychloroprene gloves. Nitrile gloves.
(>=0.5 mm)
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: safety glasses with side-
shields.
Eye/face protection
:
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Good general ventilation should be sufficient to control worker exposure to airborne
contaminants.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Control parameters
Individual protection measures
Occupational exposure limits
Skin protection
Recommended: Protective hand cream
Date of issue/Date of revision :11/29/2022Date of previous issue :No previous validationVersion:1 4/11
United States
* O D V V ) D E U L F
Section 8. Exposure controls/personal protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Respiratory protection :
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.:
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point/freezing point
Relative density
Solid.
Not available.
Not available.
Characteristic.Odor
pH
According to specificationColor
Evaporation rate Not available.
Not available.
Not available.Odor threshold
:
:
:
:
:
:
:
:
Appearance
SADT Not available.:
Decomposition temperature:Not available.
Viscosity Not applicable.:
Flow time (ISO 2431) :Not available.
Density Not available.:
The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.
Flash point Not applicable.:
Boiling point, initial boiling
point, and boiling range
:Not available.
Vapor pressure
Relative vapor density Not applicable.
Not applicable.:
:
Flammability :Not available.
Lower and upper explosion
limit/flammability limit
:Not applicable.
Auto-ignition temperature Not applicable.
Not applicable.Partition coefficient: n-
octanol/water
:
:
Miscible with water :No.
Particle characteristics
Median particle size :Not available.
Other information
Solubility(ies) :Media Result
hot water Not soluble
cold water Not soluble
Date of issue/Date of revision :11/29/2022Date of previous issue :No previous validationVersion:1 5/11
United States
* O D V V ) D E U L F
Section 9. Physical and chemical properties
Physical/chemical
properties comments
:No additional information.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid No specific data.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability :
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Under normal conditions of storage and use, hazardous polymerization will not occur.
No specific data.
Section 11. Toxicological information
Acute toxicity
titanium dioxide LC50 Inhalation Dusts and mistsRat – Male,
Female
5.09 mg/l 4 hours
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Conclusion/Summary :Not available.
Mutagenicity
Conclusion/Summary :Not available.
Teratogenicity
Conclusion/Summary :Not available.
Reproductive toxicity
Conclusion/Summary :Not available.
Irritation/Corrosion
titanium dioxide Skin – Mild irritant Human – 72 hours 300
ug I
–
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Information on toxicological effects
Classification
titanium dioxide – 2B –
Product/ingredient name NTPIARCOSHA
Date of issue/Date of revision :11/29/2022Date of previous issue :No previous validationVersion:1 6/11
United States
* O D V V ) D E U L F
Section 11. Toxicological information
Information on the likely
routes of exposure
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
No known significant effects or critical hazards.General :
No known significant effects or critical hazards.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Reproductive toxicity :
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact :No specific data.
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Not available.
Not available.
Numerical measures of toxicity
Aspiration hazard
Not available.
:Routes of entry anticipated: Oral, Dermal, Inhalation, Eyes.
Potential acute health effects
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
Acute toxicity estimates
Product/ingredient name
titanium dioxide N/A N/A N/A N/A 5.09
Oral (mg/
kg)
Dermal
(mg/kg)
Inhalation
(gases)
(ppm) Inhalation
(vapors)
(mg/l) Inhalation
(dusts and
mists) (mg/
l)
Date of issue/Date of revision :11/29/2022Date of previous issue :No previous validationVersion:1 7/11
United States
* O D V V ) D E U L F
Section 11. Toxicological information
Section 12. Ecological information
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Not available.
Toxicity
titanium dioxide Acute LC50 3 mg/l Fresh water Crustaceans – Ceriodaphnia
dubia – Neonate
48 hours
Acute LC50 6.5 mg/l Fresh water Daphnia – Daphnia pulex –
Neonate
48 hours
Acute LC50 >1000000 g/l Marine waterFish – Fundulus heteroclitus96 hours
Product/ingredient name SpeciesResult Exposure
Conclusion/Summary :Not available.
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Not available.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Empty containers or liners may retain some product residues. Avoid
dispersal of spilled material and runoff and contact with soil, waterways, drains and
sewers.
:Disposal methods
Section 14. Transport information
–
–
–
–
–
Not regulated.
–
Not regulated. Not regulated.
DOT Classification IMDG IATA
UN number
UN proper
shipping name
Transport
hazard class(es)
Date of issue/Date of revision :11/29/2022Date of previous issue :No previous validationVersion:1 8/11
United States
* O D V V ) D E U L F
Section 14. Transport information
– – -Packing group
Environmental
hazards
Special precautions for user
No. No. No.
Transport within user s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
:
Additional information
Transport in bulk according
to IMO instruments
:Not available.
Section 15. Regulatory information
U.S. Federal regulations
The following components are listed: FIBROUS GLASSMassachusetts
:
:
SARA 313
California Prop. 65
Clean Air Act Section 112
(b) Hazardous Air
Pollutants (HAPs) :Listed
Clean Air Act Section 602
Class I Substances
:Not listed
Clean Air Act Section 602
Class II Substances
:Not listed
DEA List I Chemicals
(Precursor Chemicals)
:Not listed
DEA List II Chemicals
(Essential Chemicals)
:Not listed
New York :None of the components are listed.
New Jersey :None of the components are listed.
Pennsylvania :None of the components are listed.
State regulations
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
United States inventory (TSCA 8b): Not determined.
SARA 302/304
SARA 304 RQ :Not applicable.
No products were found.
Composition/information on ingredients
Not applicable.
SARA 311/312
Classification :Not applicable.
titanium dioxide 1 CARCINOGENICITY – Category 2
Name % Classification
Composition/information on ingredients
Date of issue/Date of revision :11/29/2022Date of previous issue :No previous validationVersion:1 9/11
United States
* O D V V ) D E U L F
Section 15. Regulatory information
International regulations
WARNING: This product can expose you to Titanium dioxide, which is known to the State of California to cause
cancer. For more information go to www.P65Warnings.ca.gov.
Titanium dioxide – –
Ingredient name No significant risk levelMaximum acceptable dosage
level
Chemical Weapon Convention List Schedules I, II & III Chemicals
Montreal Protocol
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
Not listed.
Section 16. Other information
History
Date of issue/Date of
revision
Date of previous issue
:
:
11/29/2022
No previous validation
Hazardous Material Information System (U.S.A.)
0
0
0
National Fire Protection Association (U.S.A.)
Health Instability/Reactivity
Flammability
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS
ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS
Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual.
/0
0
0
Special hazards
Procedure used to derive the classification
Classification Justification
Not classified.
Date of issue/Date of revision :11/29/2022Date of previous issue :No previous validationVersion:1 10/11
United States
* O D V V ) D E U L F
Section 16. Other information
Chemical Check GmbH
Version
Prepared by
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Notice to reader
:
:
References :HCS (U.S.A.)- Hazard Communication Standard
International transport regulations
Key to abbreviations :
1
ATE = Acute Toxicity Estimate
AMP = Acceptable maximum peak above the acceptable ceiling concentration for an
8-hr shift
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. (“Marpol” = marine pollution)
N/A = Not available
UN = United Nations
Indicates information that has changed from previously issued version.
Date of issue/Date of revision :11/29/2022Date of previous issue :No previous validationVersion:1 11/11
United States