Safety Data Sheet
Product Name: SMC Resin
Product identifier: 100865
Revision Date: 08-19-2016
Replaces:
Page 1 of 10
1. Identification
Product identifier used on the label:
Product Name:SMC Resin
Product identifier:100865
Other means of identification
Synonyms:No data available
Recommended use of the
chemical and restrictions on
use:
Polyester Resin
Name, address, and telephone number of the chemical manufacturer, importer, or other responsible party
Chemical Manufacturer /
Importer / Distributor:
ITW Evercoat
a division of Illinois Tool Works Inc.
6600 Cornell Road
Cincinnati, OH 45242
513-489-7600
Emergency phone number:CHEMTREC: 1-800-424-9300
CANUTEC: 1-613-996-6666
2. Hazard(s) identification
Classification of the chemical in accordance with paragraph (d) of 1910.1200;
GHS Hazard
Symbols:
GHS Classification:Skin Sensitisation Category 1
Reproductive Toxicity Category 1B
Specific Target Organ Systemic Toxicity (STOT) – Single Exposure Category 1
Specific Target Organ Systemic Toxicity (STOT) – Repeated Exposure Category 1
Skin Corrosion/Irritation Category 2
Serious Eye Damage/Eye Irritation Category 2A
Germ Cell Mutagenicity Category 2
Carcinogenicity Category 2
Hazardous to the aquatic environment – Acute Category 2
Flammable Liquid Category 3
Acute Toxicity – Inhalation Dust / Mist Category 4
Safety Data Sheet
Product Name: SMC Resin
Product identifier: 100865
Revision Date: 08-19-2016
Replaces:
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GHS Signal Word:Danger
GHS Hazard Statements:Flammable liquid and vapour.
Causes skin irritation.
May cause an allergic skin reaction.
Causes serious eye irritation.
Harmful if inhaled.
Suspected of causing genetic defects.
Suspected of causing cancer.
May damage fertility or the unborn child.
Causes damage to organs.
Causes damage to organs through prolonged or repeated exposure.
Toxic to aquatic life.
GHS Precautionary Statements:
Safety Precautions:Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Keep away from heat/sparks/open flames/hot surfaces. No smoking.
Keep container tightly closed.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Do not breathe dust/fume/gas/mist/vapours/spray.
Avoid breathing dust/fume/gas/mist/vapours/spray.
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
Use only outdoors or in a well-ventilated area.
Contaminated work clothing should not be allowed out of the workplace.
Avoid release to the environment.
Wear protective gloves/protective clothing/eye protection/face protection.
First Aid Measures:IF ON SKIN: Wash with plenty of soap and water.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing.
Rinse skin with water/shower.
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable
for breathing.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing.
IF exposed: Call a POISON CENTER or doctor/physician.
IF exposed or concerned: Get medical advice/attention.
Call a POISON CENTER or doctor/physician if you feel unwell.
Get medical advice/attention if you feel unwell.
Specific treatment (see on this label).
If skin irritation occurs: Get medical advice/attention.
If skin irritation or rash occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
Wash contaminated clothing before reuse.
Safety Data Sheet
Product Name: SMC Resin
Product identifier: 100865
Revision Date: 08-19-2016
Replaces:
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In case of fire: Use appropriate media to extinguish.
Storage:Keep container tightly closed.
Store in a well-ventilated place. Keep cool.
Store locked up.
Disposal:Dispose of contents/container in accordance with
local/regional/national/international regulation for hazardous wastes.
Hazards not otherwise
classified:
Reports have associated repeated and prolonged occupational overexposure to
solvents with permanent brain and nervous system damage.
3. Composition/information on ingredients
Chemical Component: CAS number and other
unique identifiers
% (or range) of ingredient
Styrene100-42-515 – 40
Methyl methacrylate80-62-65 – 10
Amorphous Silica112945-52-50.5 – 1.5
Dimethylaniline (DMA)121-69-70.1 – 1
The specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a
trade secret.
4. First-aid measures
Description of necessary measures, subdivided according to the different routes of exposure, i.e., inhalation, skin
and eye contact, and ingestion:
Eye Contact: Flush eyes with plenty of water for at least 20 minutes retracting
eyelids often. Tilt the head to prevent chemical from transferring to
the uncontaminated eye. Get immediate medical attention. Flush
eyes gently with water for at least 15 minutes, lifting upper & lower
eye lids. Seek immediate medical attention.
Skin Contact:Wash with soap and water. Get medical attention if irritation
develops or persists. Remove contaminated clothing and continue
flushing with water. Wash affected area thoroughly with soap and
water. Seek medical advice if symptoms persist Wash clothing
before reuse.
Inhalation: Remove to fresh air. If breathing is difficult, have a trained
individual administer oxygen. If not breathing, give artificial
respiration and have a trained individual administer oxygen. Get
medical attention immediately If symptoms develop, immediately
move individual away from exposure and into fresh air. Get medical
attention immediately. Keep the victim warm and quiet. If the
victim has stopped breathing open airway, loosen collar and belt,
and administer artificial respiration. If breathing is difficult, oxygen
may be beneficial if administered by trained personnel, preferably
on a doctor’s advice.
Safety Data Sheet
Product Name: SMC Resin
Product identifier: 100865
Revision Date: 08-19-2016
Replaces:
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Ingestion:Do not induce vomiting and seek medical attention immediately.
Drink two glasses of water or milk to dilute. Provide medical care
provider with this MSDS. Call a physician or poison control center
immediately. Do not induce vomiting unless directed to do so by
medical personnel. If individual is drowsy or unconscious, do not
give anything by mouth; place individual on left side with head
down. If possible, do not leave individual unattended.
Most important symptoms/effects, acute and delayed:
Most important
symptoms/effects (Acute):
No data available
Most important
symptoms/effects (Delayed):
No data available
Indication of immediate medical
attention and special treatment
needed, if necessary:
No additional first aid information available
5. Fire-fighting measures
Suitable (and unsuitable) extinguishing media:
Suitable extinguishing media: Use alcohol resistant foam, carbon dioxide, or dry chemical
extinguishing agents. Water may be ineffective but water spray can
be used extinguish a fire if swept across the base of the flames.
Water can absorb heat and keep exposed material from being
damaged by fire. Regular foam Carbon dioxide Dry chemical
Unsuitable extinguishing media:
No data available
Specific hazards arising from the chemical (e.g., nature of any hazardous combustion products):
Fire and/or Explosion
Hazards:
Vapors may be ignited by sparks, flames or other sources of ignition
if material is above the flash point giving rise to a fire (Class B).
Vapors are heavier than air and may travel to a source of ignition
and flash back.
Hazardous Combustion
Products:
Toxic and corrosive gases,, Carbon dioxide, Carbon monoxide,
Styrene oxide, Aniline, oxides of nitrogen, Hydrocarbons
Special protective equipment
and precautions for fire-
fighters:
Do not enter fire area without proper protection including self-
contained breathing apparatus and full protective equipment. Fight
fire from a safe distance and a protected location due to the
potential of hazardous vapors and decomposition products. Water
may be used to cool closed containers to prevent pressure build-up
and possible auto ignition or explosion when exposed to extreme
heat.
Wear a self contained breathing apparatus (NIOSH approved) with
a full face piece operated in the positive pressure demand mode
Safety Data Sheet
Product Name: SMC Resin
Product identifier: 100865
Revision Date: 08-19-2016
Replaces:
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with appropriate turn-out gear and chemical resistant personal
protective equipment.
6. Accidental release measures
Personal precautions,
protective equipment, and
emergency procedures:
No health affects expected from the clean-up of this material if
contact can be avoided. Follow personal protective equipment
recommendations found in Section VIII of this MSDS
Methods and materials for
containment and cleaning up:
No special spill clean-up considerations. Collect and discard in
regular trash. Shut off ignition sources; including electrical
equipment and flames. Do not allow smoking in the area. Activate
available exhaust ventilation equipment in the immediate spill area.
All personnel in the area should be protected as in Section 8. Avoid
breathing vapors. Use an inert absorbent such as sand or
vermiculite. Place in properly labeled closed container.
7. Handling and storage
Precautions for safe handling: Mildly irritating material. Avoid unnecessary exposure. All hazard
precautions given in the data sheet must be observed. Do not get in
eyes, on skin and clothing Wash hands before eating Use with
adequate ventilation Avoid contact with material, avoid breathing
dusts or fumes, use only in a well ventilated area. Do not take
internally. Keep container closed when not in use. Keep out of the
reach of children.
Conditions for safe storage, including any incompatibilities
Conditions for safe storage: Store in a cool dry ventilated location. Isolate from incompatible
materials and conditions. Keep container(s) closed. Store in a cool
dry place For maximum product quality, avoid prolonged storage at
temperatures above 75 F (25 C). Keep away from heat, sparks,
and flame Store in a tightly closed container Avoid contact with
incompatible materials.
Materials to Avoid/Chemical
Incompatibility:
Peroxides Strong acids Strong oxidizing agents Strong alkalies
Polymerization catalysts
Safety Data Sheet
Product Name: SMC Resin
Product identifier: 100865
Revision Date: 08-19-2016
Replaces:
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8. Exposure controls/personal protection
OSHA permissible exposure limit (PEL), American Conference of Governmental Industrial Hygienists (ACGIH)
Threshold Limit Value (TLV), and any other exposure limit used or recommended by the chemical manufacturer,
importer, or employer preparing the safety data sheet, where available:
Chemical Component OSHA PEL ACGIH TLV-TWA ACGIH STEL
Styrene100 ppm20 ppm40 ppm STEL; 170
mg/m3 STEL
Methyl methacrylate100 ppm50 ppmNo data available
Amorphous Silica20 mppcfNo data availableNo data available
Dimethylaniline (DMA)5 ppm5 ppmNo data available
Appropriate engineering
controls:
No exposure limits exist for the constituents of this product. Use
local exhaust ventilation or other engineering controls to minimize
exposures and maintain operator comfort. General or local
ventilation or isolation may prove adequate to keep airborne
exposures below exposure limits. Explosion proof exhaust
ventilation should be used.
Individual protection measures, such as personal protective equipment:
Eye Protection: Wear chemically resistant safety glasses with side shields when
handling this product. Do not wear contact lenses. Splash proof
chemical goggles are recommended to protect against the splash of
product.
Skin Protection: Not normally considered a skin hazard. Where use can result in skin
contact, practice good personal hygiene and wear a barrier cream
and/or impervious surgical style gloves. Wash hands and other
exposed areas with mild soap and water before eating, drinking,
and when leaving work. Protective gloves and proper clothing
should be worn to prevent skin contact. Gloves should be made of
neoprene or natural rubber. To prevent repeated or prolonged skin
contact, wear impervious clothing and boots
Respiratory Protection: Respiratory protection may be required to avoid overexposure
when handling this product. General or local exhaust ventilation is
the preferred means of protection. Use a respirator if general room
ventilation is not available or sufficient to eliminate symptoms. Use
a NIOSH approved respirator designed to remove particulate
matter and organic solvent vapors.
Other Protective Equipment:Splash proof chemical goggles are recommended to protect against
the splash of product. Protective gloves and proper clothing should
be worn to prevent skin contact. Gloves should be made of
neoprene or natural rubber. To prevent repeated or prolonged skin
contact, wear impervious clothing and boots
Safety Data Sheet
Product Name: SMC Resin
Product identifier: 100865
Revision Date: 08-19-2016
Replaces:
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9. Physical and chemical properties
Appearance (physical state, color, etc.):
Appearance (physical state):Liquid
Color:Clear Yellow
Odor: Aromatic
Odor threshold:No data available
pH:Neutral
Melting Point/Freezing Point ( C): No data available
Initial Boiling Point and Boiling Range ( C): 100
Flash Point ( C): 33.8
Evaporation Rate: No data available
Flammability (solid, gas): No data available
Upper/lower flammability or explosive limits:
Upper Flammable/Explosive Limit (%): 12.5
Lower Flammable/Explosive Limit (%): 1.1
Vapor Pressure:No data available
Vapor Density: Heavier than air. Vapors that evolve from this product
will tend to settle and accumulate near the floor.
Relative Density: 1.09
Solubility(ies): Insoluble
Partition coefficient: n-octanol/water:No data available
Auto-ignition Temperature ( C): No data available
Decomposition Temperature: No data available
Viscosity: No data available
VOC (as packaged-less exempts and water):3.8 lbs/gal or 456 g/L
VOC (as applied*- 2% by wt hardener- less
exempts and water):
3.26 lbs/gal or 391 g/L
Percent Solids by weight as packaged: 58.20
Percent Solids by weight as applied* – 2%
by wt hardener:
64.10
VHAP Content by weight as packaged:44.2
VHAP Content by weight as applied* – 2%
by weight hardener:
37.9
10. Stability and reactivity
Reactivity:No data available
Chemical stability: Stable under normal conditions.
Possibility of hazardous
reactions:
No data available
Conditions to avoid (e.g., static
discharge, shock, or vibration):
No data available
Incompatible materials: Peroxides Strong acids Strong oxidizing agents Strong alkalies
Safety Data Sheet
Product Name: SMC Resin
Product identifier: 100865
Revision Date: 08-19-2016
Replaces:
Page 8 of 10
Polymerization catalysts
Hazardous decomposition
products:
Carbon dioxide Carbon monoxide Styrene oxide oxides of nitrogen
Aniline Hydrocarbons
11. Toxicological information
Information on the likely routes
of exposure (inhalation,
ingestion, skin and eye contact):
Ingestion, Skin contact, Eye contact, Absorption
Symptoms related to the
physical, chemical and
toxicological characteristics:
No data available
Delayed and immediate effects and also chronic effects from short- and long-term exposure:
Immediate (Acute) Health Effects by Route of Exposure:
Inhalation Irritation:Can cause moderate respiratory irritation, dizziness, weakness, fatigue, nausea and
headache. Excessive inhalation of vapors may cause nasal and respiratory irritation,
acute nervous system depression, fatigue, weakness, nausea, headache and
dizziness.
Airborne overexposure well above the PEL may result additionally in eye irritation,
headache, chemical bronchitis, asthma-like findings or pulmonary edema.
Skin Contact:Can cause minor skin irritation, defatting, and dermatitis.
Skin Absorption: Causes severe skin irritation. Contact may cause irritation and possible dermatitis
or sensitization. Symptoms may include redness, burning, drying and cracking of
skin, and skin burns
Eye Contact:Can cause moderate irritation, tearing and reddening, but not likely to permanently
injure eye tissue. Contact with liquid or vapor may result in irritation, redness,
tearing, and blurred vision.
Ingestion Irritation:Irritating to mouth, throat, and stomach. Can cause abdominal discomfort, nausea,
vomiting and diarrhea. Causes gastrointestinal tract irritation, nausea, vomiting,
diarrhea and possible ulcerations to mucous membranes. Aspiration of material into
the lungs can cause chemical pneumonitis which can be fatal.
Ingestion Toxicity:Harmful if swallowed. May cause systemic poisoning.
Long-Term (Chronic) Health Effects:
Carcinogenicity: Suspected of causing cancer. The International Agency for Research on Cancer
(IARC) has classified styrene as a group 2B carcinogen (possibly carcinogenic to
humans).
Reproductive and
Developmental Toxicity:
May damage fertility or the unborn child.
Mutagenicity: Suspected of causing genetic defects.
Inhalation:Upon prolonged and/or repeated exposure, can cause moderate respiratory
irritation, dizziness, weakness, fatigue, nausea and headache.
Skin Contact:Upon prolonged or repeated contact, can cause minor skin irritation, defatting, and
dermatitis.
Safety Data Sheet
Product Name: SMC Resin
Product identifier: 100865
Revision Date: 08-19-2016
Replaces:
Page 9 of 10
Numerical measures of toxicity (such as acute toxicity estimates)
Component Toxicology Data
Chemical Component Oral LD50 Dermal LD50 Inhalation LC50
Styrene
Oral LD50 Rat 5000
mg/kg
Inhalation LC50 (4h) Rat 24
g/m3
Methyl methacrylate
Oral LD50 Rat 7872
mg/kg
Inhalation LC50 Rat 3750 ppm
Dimethylaniline (DMA)
Oral LD50 Rat 1410
mg/kg
Whether the hazardous chemical is listed in the National Toxicology Program (NTP) Report on Carcinogens (latest
edition) or has been found to be a potential carcinogen in the International Agency for Research on Cancer (IARC)
Monographs (latest edition), or by OSHA
Chemical Name OSHA Carcinogen IARC CarcinogenNTP Carcinogen
StyreneNYY
12. Ecological information
Ecotoxicity (aquatic and
terrestrial, where available):
Toxic to aquatic life. Styrene and Methyl Methacrylate are toxic to
aquatic organisms and should not be released to sewage, draining
systems or any body of water exceeding concentrations of approved
limits under applicable regulations and permits.
Persistence and degradability: No data available
Bioaccumulative potential: No data
Mobility in soil: No data available
Other adverse effects (such as
hazardous to the ozone layer):
No data available
Ecological Toxicity Data
Chemical Component Aquatic EC50 Crustacea Aquatic ERC50 Algae Aquatic LC50 Fish
No data available
13. Disposal considerations
Description of waste residues and information on their safe handling and methods of disposal, including the
disposal of any contaminated packaging
Description of waste residues: Spent or discarded material is a hazardous waste.
Safe Handling of Waste: This material as supplied, if discarded, would be regulated as a
hazardous waste under RCRA (40 CFR 261).
Waste treatment methods
(including packaging):
Dispose of by incineration following Federal, State, Local, or
Provincial regulations.
Waste Disposal Code(s): D001
Safety Data Sheet
Product Name: SMC Resin
Product identifier: 100865
Revision Date: 08-19-2016
Replaces:
Page 10 of 10
14. Transport information
UN number: UN3269
UN proper shipping name: POLYESTER RESIN KIT
Transport hazard class(es): 3
Packing group: III
The shipper is responsible for following all applicable regulations. The transportation classification provided is based
on ITW Evercoat original packaging, which is suitable for domestic ground transport only.
15. Regulatory information
Safety, health and environmental regulations specific for the product in question
TSCA Status: A component or components of this product are listed on the
TSCA Inventory of Existing Chemical Substances.
Regulated Components
Chemical Component CAS number
and other
unique
identifiers
CERCLA SARA EHSSARA 313
California
Prop 65
Styrene100-42-5NNYY
Methyl methacrylate80-62-6NNYN
Dimethylaniline (DMA)121-69-7NNYN
Aniline62-53-3NNYY
Styrene Oxide96-09-3NNYY
1,4-Dioxane123-91-1NNNY
Ethylene oxide75-21-8NNNY
Acetaldehyde75-07-0NNNY
16. Other information, including date of preparation or last revision.
Revision Date:08-19-2016
Revision Number:15
Disclaimer: NOTICE: The information accumulated herein is believed to be correct as of the date issued from
sources, which are believed to be accurate and reliable. Since it is not possible to anticipate all circumstances of use,
recipients are advised to confirm, in advance of need, that the information is current, applicable and suitable to their
circumstances