SAFETY DATA SHEET
1. Identification
TR-500 One Step PolishProduct identifier
Other means of identification
MR-500 One Step PolishSynonyms
Industrial use. Cleaner Polish / Sealer.Recommended use
None known.Recommended restrictions
Manufacturer/Importer/Supplier/Distributor information
TR Industries a Division of Granitize Products Inc.Company name
11022 Vulcan StreetAddress
South Gate, CA 90280-0893
United States
(562) 923-5438Telephone
CHEMTREC: (800) 424-9300Emergency telephone
CHEMTREC International: 00 1-703-527-3887
2. Hazard(s) identification
Category 3Flammable liquidsPhysical hazards
Category 2Skin corrosion/irritationHealth hazards
Category 2ASerious eye damage/eye irritation
Category 1ACarcinogenicity (inhalation)
Category 3 narcotic effectsSpecific target organ toxicity, single exposure
Category 2 (lungs)Specific target organ toxicity, repeated
exposure (inhalation)
Category 1Aspiration hazard
Not classified.OSHA defined hazards
Label elements
Signal word Danger
Hazard statement Flammable liquid and vapor. May be fatal if swallowed and enters airways. Causes skin irritation.
Causes serious eye irritation. May cause drowsiness or dizziness. May cause cancer by
inhalation. May cause damage to organs (lungs) through prolonged or repeated exposure by
inhalation.
Precautionary statement
Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Keep away from heat/sparks/open flames/hot surfaces. – No smoking. Keep
container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof
electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary
measures against static discharge. Do not breathe mist/vapors. Wash thoroughly after handling.
Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye
protection/face protection.
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Response If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. If on skin (or hair):
Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation
occurs: Get medical advice/attention. If inhaled: Remove person to fresh air and keep comfortable
for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
If exposed or concerned: Get medical advice/attention. Take off contaminated clothing and wash
it before reuse. In case of fire: Use water fog, alcohol resistant foam, dry chemical powder, carbon
dioxide (CO2) to extinguish.
Storage Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise
classified (HNOC)
None known.
Supplemental information None.
3. Composition/information on ingredients
Mixtures
CAS number %Chemical name
64742-48-9Naphtha (petroleum), hydrotreated
heavy
50 – 55
67-63-0Propan-2-ol 1 – 5
14808-60-7Quartz (SiO2) 1 – 5
110-91-8Morpholine 1 – 2
All concentrations are in percent by weight unless otherwise indicated. Components not listed are
either non-hazardous or are below reportable limits.
Composition comments
4. First-aid measures
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison
center or doctor/physician if you feel unwell.
Inhalation
Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation
occurs: Get medical advice/attention.
Skin contact
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Eye contact
Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If
vomiting occurs, keep head low so that stomach content doesn’t get into the lungs.
Ingestion
Aspiration may cause pulmonary edema and pneumonitis. May cause drowsiness or dizziness.
Headache. Nausea, vomiting. Severe eye irritation. Symptoms may include stinging, tearing,
redness, swelling, and blurred vision. Skin irritation. May cause redness and p
Most important
symptoms/effects, acute and
delayed
Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water
immediately. While flushing, remove clothes which do not adhere to affected area. Call an
ambulance. Continue flushing during transport to hospital. Keep victim und
Indication of immediate
medical attention and special
treatment needed
Take off all contaminated clothing immediately. IF exposed or concerned: Get medical
advice/attention. If you feel unwell, seek medical advice (show the label where possible). Ensure
that medical personnel are aware of the material(s) involved, and take preca
General information
5. Fire-fighting measures
Water fog. Alcohol resistant foam. Dry chemical powder. Carbon dioxide (CO2).Suitable extinguishing media
Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing
media
Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source
of ignition and flash back. During fire, gases hazardous to health may be formed.
Specific hazards arising from
the chemical
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipment
and precautions for firefighters
In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do
so without risk.
Fire fighting
equipment/instructions
Use standard firefighting procedures and consider the hazards of other involved materials.Specific methods
Flammable liquid and vapor.General fire hazards
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6. Accidental release measures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Eliminate all
ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate
protective equipment and clothing during clean-up. Do not breathe mist/
Personal precautions,
protective equipment and
emergency procedures
Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep
combustibles (wood, paper, oil, etc.) away from spilled material. Take precautionary measures
against static discharge. Use only non-sparking tools.
Large Spills
Methods and materials for
containment and cleaning up
Avoid discharge into drains, water courses or onto the ground.Environmental precautions
7. Handling and storage
Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Do not handle, store or open near an open flame, sources of heat or sources of
ignition. Protect material from direct sunlight. When using do not
Precautions for safe handling
Keep away from heat, sparks and open flame. Prevent electrostatic charge build-up by using
common bonding and grounding techniques. Store in a cool, dry place out of direct sunlight. Store
in tightly closed container. Store in a well-ventilated place. Store a
Conditions for safe storage,
including any incompatibilities
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
ValueComponents Type
TWA 0.05 mg/m3Quartz (SiO2) (CAS
14808-60-7)
US. OSHA Table Z-1 Permissible Exposure Limits (PEL) for Air Contaminants (29 CFR 1910.1000)
ValueComponents Type
PEL 70 mg/m3Morpholine (CAS 110-91-8)
20 ppm
PEL 980 mg/m3Propan-2-ol (CAS 67-63-0)
400 ppm
US. OSHA Table Z-3 Permissible Exposure Limits (PEL) for Mineral Dusts (29 CFR 1910.1000)
FormValueComponents Type
TWA 0.1 mg/m3 Respirable.Quartz (SiO2) (CAS
14808-60-7)
2.4 mppcf Respirable.
US. ACGIH Threshold Limit Values (TLV)
FormValueComponents Type
TWA 20 ppmMorpholine (CAS 110-91-8)
STEL 400 ppmPropan-2-ol (CAS 67-63-0)
TWA 200 ppm
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US. ACGIH Threshold Limit Values (TLV)
FormValueComponents Type
TWA 0.025 mg/m3 Respirable fraction.Quartz (SiO2) (CAS
14808-60-7)
NIOSH. Immediately Dangerous to Life or Health (IDLH) Values, as amended
ValueComponents Type
IDLH 2 %Propan-2-ol (CAS 67-63-0)
2000 ppm
IDLH 50 mg/m3Quartz (SiO2) (CAS
14808-60-7)
US. NIOSH: Pocket Guide to Chemical Hazards
FormValueComponents Type
STEL 105 mg/m3Morpholine (CAS 110-91-8)
30 ppm
TWA 70 mg/m3
20 ppm
STEL 1225 mg/m3Propan-2-ol (CAS 67-63-0)
500 ppm
TWA 980 mg/m3
400 ppm
TWA 0.05 mg/m3 Respirable dust.Quartz (SiO2) (CAS
14808-60-7)
Biological limit values
ACGIH Biological Exposure Indices (BEI)
ValueComponents Determinant Specimen Sampling Time
40 mg/l Acetone Urine *Propan-2-ol (CAS 67-63-0)
* – For sampling details, please see the source document.
Exposure guidelines
US – California OELs: Skin designation
Morpholine (CAS 110-91-8) Can be absorbed through the skin.
US – Minnesota Haz Subs: Skin designation applies
Morpholine (CAS 110-91-8) Skin designation applies.
US – Tennessee OELs: Skin designation
Morpholine (CAS 110-91-8) Can be absorbed through the skin.
US ACGIH Threshold Limit Values: Skin designation
Morpholine (CAS 110-91-8) Danger of cutaneous absorption
US. NIOSH: Pocket Guide to Chemical Hazards
Morpholine (CAS 110-91-8) Can be absorbed through the skin.
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Morpholine (CAS 110-91-8) Can be absorbed through the skin.
Good general ventilation should be used. Ventilation rates should be matched to conditions. If
applicable, use process enclosures, local exhaust ventilation, or other engineering controls to
maintain airborne levels below recommended exposure limits. Explosio
Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Wear safety glasses with side shields (or goggles).Eye/face protection
Skin protection
Wear appropriate chemical resistant gloves. Neoprene, butyl rubber, nitrile or Viton gloves are
recommended. Be aware that the liquid may penetrate the gloves. Frequent change is advisable.
Hand protection
Skin protection
Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.Other
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If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn. Check with resp
Respiratory protection
Wear appropriate thermal protective clothing, when necessary.Thermal hazards
Observe any medical surveillance requirements. When using do not smoke. Always observe good
personal hygiene measures, such as washing after handling the material and before eating,
drinking, and/or smoking. Routinely wash work clothing and protective equipm
General hygiene
considerations
9. Physical and chemical properties
Appearance
Liquid.Physical state
Viscous liquid. Emulsion.Form
White.Color
Solvent.Odor
Odor threshold Not available.
pH Not measured.
Melting point/freezing pointNot measured.
Initial boiling point and boiling
range
Not measured.
Flash point > 100.4 F (> 38 C) (Estimated)
Evaporation rate Not available.
Not applicable.Flammability (solid, gas)
Upper/lower flammability or explosive limits
Explosive limit – lower (%)Not measured.
Explosive limit – upper (%)Not measured.
Vapor pressure Not measured.
Vapor density Not measured.
Relative density Not measured.
Solubility(ies)
Solubility (water) Not measured.
Partition coefficient
(n-octanol/water)
Not applicable, product is a mixture.
Auto-ignition temperature Not measured.
Decomposition temperature Not measured.
Viscosity Not available.
Other information
Density Not measured.
Not explosive.Explosive properties
Kinematic viscosity Not measured.
Not oxidizing.Oxidizing properties
10. Stability and reactivity
The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity
Material is stable under normal conditions.Chemical stability
No dangerous reaction known under conditions of normal use.Possibility of hazardous
reactions
Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the
flash point. Contact with incompatible materials. Protect against direct sunlight.
Conditions to avoid
Strong oxidizing agents. Acids. Chlorine. Fluorine. Isocyanates.Incompatible materials
Thermal decomposition of this product can generate carbon monoxide and carbon dioxide.
Nitrogen oxides. Silicon oxide fumes.
Hazardous decomposition
products
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11. Toxicological information
Information on likely routes of exposure
Inhalation May cause damage to organs through prolonged or repeated exposure by inhalation. May cause
drowsiness or dizziness. May cause cancer by inhalation.
Skin contact Causes skin irritation.
Eye contact Causes serious eye irritation.
Ingestion Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious
chemical pneumonia.
Symptoms related to the
physical, chemical and
toxicological characteristics
Aspiration may cause pulmonary edema and pneumonitis. May cause drowsiness or dizziness.
Headache. Nausea, vomiting. Severe eye irritation. Symptoms may include stinging, tearing,
redness, swelling, and blurred vision. Skin irritation. May cause redness and pain.
Information on toxicological effects
Acute toxicity Not expected to be acutely toxic.
Test ResultsComponents Species
Morpholine (CAS 110-91-8)
Dermal
Acute
LD50 Rabbit 500 mg/kg
Inhalation
LC50 Rat 8000 ppm, 8 hours
Oral
LD50 Rat 1050 mg/kg
Propan-2-ol (CAS 67-63-0)
Dermal
Acute
LD50 Rabbit 12870 mg/kg
Inhalation
LC50 Rat 72.6 mg/l, 4 hours
Vapor
Oral
LD50 Rat 4710 mg/kg
Quartz (SiO2) (CAS 14808-60-7)
Inhalation
Chronic
LOEC Human 0.0563 mg/m3
Causes skin irritation.Skin corrosion/irritation
Causes serious eye irritation.Serious eye damage/eye
irritation
Respiratory or skin sensitization
Respiratory sensitizationNot a respiratory sensitizer.
This product is not expected to cause skin sensitization.Skin sensitization
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Germ cell mutagenicity
Carcinogenicity May cause cancer by inhalation.
IARC Monographs. Overall Evaluation of Carcinogenicity
Morpholine (CAS 110-91-8) 3 Not classifiable as to carcinogenicity to humans.
Naphtha (petroleum), hydrotreated heavy
(CAS 64742-48-9)
3 Not classifiable as to carcinogenicity to humans.
Propan-2-ol (CAS 67-63-0) 3 Not classifiable as to carcinogenicity to humans.
Quartz (SiO2) (CAS 14808-60-7) 1 Carcinogenic to humans.
NTP Report on Carcinogens
Quartz (SiO2) (CAS 14808-60-7) Known To Be Human Carcinogen.
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OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Quartz (SiO2) (CAS 14808-60-7) Cancer
This product is not expected to cause reproductive or developmental effects.Reproductive toxicity
Specific target organ toxicity –
single exposure
May cause drowsiness or dizziness.
Specific target organ toxicity –
repeated exposure
May cause damage to organs (lungs) through prolonged or repeated exposure by inhalation.
Aspiration hazard May be fatal if swallowed and enters airways.
Chronic effects Prolonged inhalation may be harmful. May cause damage to organs through prolonged or
repeated exposure. Prolonged exposure may cause chronic effects.
Further information Symptoms may be delayed.
12. Ecological information
Based on available data, the classification criteria are not met for hazardous to the aquatic
environment, acute hazard.
Ecotoxicity
Components Test ResultsSpecies
Propan-2-ol (CAS 67-63-0)
Aquatic
Acute
LC50Crustacea > 10000 mg/l, 24 hoursDaphnia magna
LC50Fish 9640 mg/l, 96 hoursPimephales promelas
Chronic
EC50Crustacea > 100 mg/l, 21 daysDaphnia magna
NOEC 141 mg/l, 16 daysDaphnia magna
30 mg/l, 21 days
No data is available on the degradability of this product.Persistence and degradability
Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)
Morpholine (CAS 110-91-8) -0.86
Propan-2-ol (CAS 67-63-0) 0.05
No data available for this product.Mobility in soil
Other adverse effects The product contains volatile organic compounds which have a photochemical ozone creation
potential.
13. Disposal considerations
Dispose of this material and its container to hazardous or special waste collection point. Incinerate
the material under controlled conditions in an approved incinerator. Do not incinerate sealed
containers. If discarded, this product is considered a RCRA ign
Disposal instructions
Dispose in accordance with all applicable regulations.Local disposal regulations
D001: Waste Flammable material with a flash point <140 F
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Hazardous waste code
Dispose in accordance with local regulations. Dispose of in accordance with local regulations.
Empty containers or liners may retain some product residues. This material and its container must
be disposed of in a safe manner.
Waste from residues / unused
products
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.
Contaminated packaging
14. Transport information
DOT
UN1268UN number
Petroleum products, n.o.s.UN proper shipping name
3Class
Transport hazard class(es)
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-Subsidiary risk
3Label(s)
IIIPacking group
NoMarine pollutant
Environmental hazards
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
144, B1, IB3, T4, TP1, TP29Special provisions
150Packaging exceptions
203Packaging non bulk
242Packaging bulk
IATA
UN1268UN number
Petroleum products, n.o.s.UN proper shipping name
3Class
Transport hazard class(es)
-Subsidiary risk
3Label(s)
IIIPacking group
NoEnvironmental hazards
3LERG Code
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
IMDG
UN1268UN number
PETROLEUM PRODUCTS, N.O.S.UN proper shipping name
3Class
Transport hazard class(es)
-Subsidiary risk
IIIPacking group
NoMarine pollutant
Environmental hazards
F-E, S-EEmS
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
Not applicable.Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
15. Regulatory information
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Morpholine (CAS 110-91-8) Listed.
Naphtha (petroleum), hydrotreated heavy
(CAS 64742-48-9)
Listed.
Propan-2-ol (CAS 67-63-0) Listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Quartz (SiO2) (CAS 14808-60-7) Cancer
lung effects
immune system effects
kidney effects
Toxic Substances Control Act (TSCA) All components of the mixture on the TSCA 8(b) inventory are designated
active .
SARA 302 Extremely hazardous substance
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Not listed.
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YesSARA 311/312 Hazardous
chemical
Flammable (gases, aerosols, liquids, or solids)
Skin corrosion or irritation
Serious eye damage or eye irritation
Carcinogenicity
Specific target organ toxicity (single or repeated exposure)
Aspiration hazard
Classified hazard
categories
SARA 313 (TRI reporting)
Chemical name % by wt.
CAS number
Propan-2-ol 1 - 5 67-63-0
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Not regulated.Safe Drinking Water Act
(SDWA)
FEMA Priority Substances Respiratory Health and Safety in the Flavor Manufacturing Workplace
Propan-2-ol (CAS 67-63-0) Low priority
US state regulations
US. Massachusetts RTK - Substance List
Morpholine (CAS 110-91-8)
Propan-2-ol (CAS 67-63-0)
Quartz (SiO2) (CAS 14808-60-7)
US. New Jersey Worker and Community Right-to-Know Act
Morpholine (CAS 110-91-8)
Propan-2-ol (CAS 67-63-0)
Quartz (SiO2) (CAS 14808-60-7)
US. Pennsylvania Worker and Community Right-to-Know Law
Morpholine (CAS 110-91-8)
Naphtha (petroleum), hydrotreated heavy (CAS 64742-48-9)
Propan-2-ol (CAS 67-63-0)
Quartz (SiO2) (CAS 14808-60-7)
US. Rhode Island RTK
Morpholine (CAS 110-91-8)
Propan-2-ol (CAS 67-63-0)
Quartz (SiO2) (CAS 14808-60-7)
California Proposition 65
This product can expose you to chemicals including Benzene, which is known to the State of
California to cause cancer and birth defects or other reproductive harm. For more information go
to www.P65Warnings.ca.gov.
WARNING:
California Proposition 65 - CRT: Listed date/Carcinogenic substance
Benzene (CAS 71-43-2) Listed: February 27, 1987
Quartz (SiO2) (CAS 14808-60-7) Listed: October 1, 1988
California Proposition 65 - CRT: Listed date/Developmental toxin
Benzene (CAS 71-43-2) Listed: December 26, 1997
California Proposition 65 - CRT: Listed date/Male reproductive toxin
Benzene (CAS 71-43-2) Listed: December 26, 1997
US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3,
subd. (a))
Naphtha (petroleum), hydrotreated heavy (CAS 64742-48-9)
Propan-2-ol (CAS 67-63-0)
Quartz (SiO2) (CAS 14808-60-7)
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
YesAustralia Australian Inventory of Industrial Chemicals (AICIS)
YesCanada Domestic Substances List (DSL)
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Country(s) or region Inventory name On inventory (yes/no)*
NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)
YesEurope European Inventory of Existing Commercial Chemical
Substances (EINECS)
NoEurope European List of Notified Chemical Substances (ELINCS)
YesJapan Inventory of Existing and New Chemical Substances (ENCS)
YesKorea Existing Chemicals List (ECL)
YesNew Zealand New Zealand Inventory
YesPhilippines Philippine Inventory of Chemicals and Chemical Substances
(PICCS)
YesTaiwan Taiwan Chemical Substance Inventory (TCSI)
YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other information, including date of preparation or last revision
20-June-2023Issue date
-Revision date
Version # 01
NFPA ratings
02
2
TR Industries cannot anticipate all conditions under which this information and its product, or the
products of other manufacturers in combination with its product, may be used. It is the user s
responsibility to ensure safe conditions for handling, storage
Disclaimer
TR-500 One Step Polish SDS US
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