SAFETY DATA SHEET
STAN-MASK 21651 CITRUS SWEET GRAS
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product identifier
Product Name STAN-MASK 21651 CITRUS SWEET GRAS
Other means of identification
CAS No Mixture
Synonyms None
Recommended use of the chemical and restrictions on use
Recommended Use Fragrances
Uses advised against No information available
Details of the supplier of the safety data sheet
Manufactured for and Supplied by Harwick Standard Distribution Corporation
P.O. Box 9360
60 S. Seiberling Street
Akron, OH 44305 USA
(330) 798-9300
www.harwickstandard.com
2. HAZARDS IDENTIFICATION
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Skin corrosion/irritation – Category 2
Skin sensitization – Category 1B
Aspiration toxicity – Category 1
Label elements Physical hazards – Flammable liquids – Category 3
Signal word – Danger
Hazard statements
Causes skin irritation
May cause an allergic skin reaction
May be fatal if swallowed and enters airways
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Product Name: STAN-MASK 21651 CITRUS SWEET GRAS
Flammable liquid and vapor
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Precautionary Statements
Wash face, hands and any exposed skin thoroughly after handling
Avoid breathing dust/fume/gas/mist/vapors/spray
Contaminated work clothing must not be allowed out of the workplace
Keep away from heat/sparks/open flames/hot surfaces. – No smoking
Keep container tightly closed
Ground/bond container and receiving equipment
Use explosion-proof electrical/ ventilating / lighting/ .? / equipment
Use only non-sparking tools
Take precautionary measures against static discharge
Wear protective gloves/eye protection/face protection
Specific treatment (see .? on this label)
If skin irritation or rash occurs: Get medical advice/attention
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower
Wash contaminated clothing before reuse
IF SWALLOWED: Immediately call a POISON CENTER or doctor
Do NOT induce vomiting
In case of fire: Use CO2, dry chemical, or foam to extinguish
Precautionary Statements – Storage
Store locked up
Store in a well-ventilated place. Keep cool
Precautionary Statements – Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Not applicable Other Information
May be harmful if swallowed May be harmful in contact with skin Toxic to aquatic life with long lasting effects Toxic to aquatic life Unknown acute toxicity 1.9 % of the mixture consists of ingredient(s) of unknown toxicity
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance
Chemical name CAS No Weight-% Trade secret
ORANGE TERPENES 68647-72-3 80 – 90 *
BENZALDEHYDE 100-52-7 1 – 10 *
ANETHOLE 4180-23-8 1 – 10 *
CINNAMIC ALCOHOL 104-54-1 1 – 10 *
ALDEHYDE C-12 LAURIC 112-54-9 <1 *
Appearanceclear liquid Physical State @20 C liquid Odor Characteristic
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Product Name: STAN-MASK 21651 CITRUS SWEET GRAS
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*The exact percentage (concentration) of composition has been withheld as a trade secret.
4. FIRST AID MEASURES
Description of first aid measures
Inhalation Remove to fresh air.
Eye contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids.
Consult a physician.
Skin contact Wash skin with soap and water.
Ingestion Clean mouth with water and drink afterwards plenty of water.
Most important symptoms and effects, both acute and delayed
Symptoms No information available.
Indication of any immediate medical attention and special treatment needed
Note to physicians Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media Use ex
tinguishing measures that are appropriate to local circumstances and the
surrounding environment.
Unsuitable extinguishing media CAUTION: Use of water spray when fighting fire may be inefficient.
Specific hazards arising from the chemical
No information available.
Explosion data
Sensitivity to Mechanical ImpactNone.
Sensitivity to Static DischargeNone.
Special protective equipment for fire-fighters
Firefighters should wear self-contained breathing apparatus and full firefighting turnout gear. Use personal protection equipment.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions Ensure adequate ventilation.
Environmental precautions
Environmental precautions See Section 12 for additional Ecological Information.
Methods and material for containment and cleaning up
Methods for containment Prevent further leakage or spillage if safe to do so.
Methods for cleaning up Pick up and transfer to properly labeled containers.
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Product Name: STAN-MASK 21651 CITRUS SWEET GRAS
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Prevention of secondary hazardsClean contaminated objects and areas thoroughly observing environmental regulations.
7. HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling Handle in accordance with good industrial hygiene and safety practice.
Conditions for safe storage, including any incompatibilities
Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Limits The following ingredients are the only ingredients of the product above the cut-off level (or
level that contributes to the hazard classification of the mixture) which have an exposure
limit applicable in the region for which this safety data sheet is intended or other
recommended limit. At this time, the other relevant constituents have no known exposure
limits from the sources listed here.
Appropriate engineering controls
Engineering controls Showers Eyewash stations Ventilation systems.
Individual protection measures, such as personal protective equipment
Eye/face protection No special protective equipment required.
Skin and body protection No special protective equipment required.
Respiratory protection No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required.
General hygiene considerations Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical State @20 C liquid
Appearance clear liquid
Odor Characteristic
Color Colorless - Pale Yellow
Odor threshold No information available
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Product Name: STAN-MASK 21651 CITRUS SWEET GRAS
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Specific gravity 0.8590-0.8790
Refractive Index 1.4740-1.4940
Explosive properties No information available
Oxidizing properties No information available
Softening point No information available
Molecular weight No information available
VOC Content (%) No information available
Density VALUE No information available
Bulk density No information available
10. STABILITY AND REACTIVITY
Reactivity No information av
ailable.
Chemical stability Stable under normal conditions.
Possibility of hazardous reactionsNone under normal processing.
Conditions to avoid None known based on information supplied.
Incompatible materials None known based on information supplied.
Hazardous decomposition productsNone known based on information supplied.
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Product Information
Inhalation Specific test data for the substance or mixture is not available.
Eye contact Specific test data for the substance or mixture is not available.
Skin contact Specific test data for the substance or mixture is not available.
Property Values
pH No data available
Melting point / freezing point No data available
Boiling point / boiling range > 35 C / 95 F
Flash point 51 C / 124 F
Evaporation rate No data available
Flammability (solid, gas) No data available
Flammability Limit in Air
Upper flammability limit: No data available
Lower flammability limit: No data available
Vapor pressure No data available
Vapor density No data available
Relative density No data available
Water solubility No data available
Solubility in other solvents No data available
Partition coefficient No data available
Autoignition temperature No data available
Decomposition temperature No data available
Kinematic viscosity No data available
Dynamic viscosity
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Product Name: STAN-MASK 21651 CITRUS SWEET GRAS
No data available
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Ingestion Specific test data for the substance or mixture is not available.
Information on toxicological effects
Symptoms No information available.
Numerical measures of toxicity
Acute toxicity
The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral) 4,266.00 mg/kg
ATEmix (dermal) 4,280.00 mg/kg mg/l
ATEmix (inhalation-dust/mist)33.30 mg/l
ATEmix (inhalation-vapor) 244.00 mg/l
Unknown acute toxicity 1.9 % of the mixture consists of ingredient(s) of unknown toxicity
Component Information
Chemical name Oral LD50 LD50/dermal/rat – NO UNITS
(Wizards mg/kg)
Inhalation LC50
BENZALDEHYDE
100-52-7
= 1292 mg/kg ( Rat ) > 1250 mg/kg ( Rabbit ) –
ANETHOLE
4180-23-8
= 2090 mg/kg ( Rat ) – –
CINNAMIC ALCOHOL
104-54-1
= 2 g/kg ( Rat ) > 5 g/kg ( Rabbit ) –
ALDEHYDE C-12 LAURIC
112-54-9
= 23 g/kg ( Rat ) – –
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Skin corrosion/irritation No information available.
Serious eye damage/eye irritationNo information available.
Respiratory or skin sensitizationNo information available.
Germ cell mutagenicity No information available.
Carcinogenicity No information available.
Reproductive toxicity No information available.
STOT – single exposure No information available.
STOT – repeated exposure No information available.
Aspiration hazard No information available.
12. ECOLOGICAL INFORMATION
Ecotoxicity The env
ironmental impact of this product has not been fully investigated.Chemical name Algae/aquatic plants Fish Toxicity to
microorganisms
Crustacea
BENZALDEHYDE
100-52-7
– 0.8 – 1.44: 96 h Lepomis
macrochirus mg/L LC50
flow-through 10.6 – 11.8:
– 50: 24 h Daphnia magna
mg/L EC50
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Product Name: STAN-MASK 21651 CITRUS SWEET GRAS
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96 h Oncorhynchus
mykiss mg/L LC50
flow-through 6.8 – 8.53:
96 h Pimephales
promelas mg/L LC50
flow-through 12.69: 96 h
Oncorhynchus mykiss
mg/L LC50 static 7.5: 96
h Lepomis macrochirus
mg/L LC50 static
Persistence and degradability No information available.
Bioaccumulation There is no data for this product.
Component Information
Chemical name Partition coefficient
BENZALDEHYDE
100-52-7
1.48
CINNAMIC ALCOHOL
104-54-1
1.9
Other adverse effects No information available.
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Waste from residues/unused
products
Dispose of in accordance with local regulations. Dispose of waste in accordance with
environmental legislation.
Contaminated packaging Do not reuse empty containers.
14. TRANSPORT INFORMATION
DOT Not regulated
IATA
UN/ID no UN1169
Proper Shipping Name EXTRACTS, AROMATIC, LIQUID
Hazard Class 3
Packing group III
ERG Code 3L
Description UN1169, EXTRACTS, AROMATIC, LIQUID, 3, III
IMDG
UN/ID no UN1169
Proper Shipping Name EXTRACTS, AROMATIC, LIQUID
Hazard Class 3
Packing group III
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Product Name: STAN-MASK 21651 CITRUS SWEET GRAS
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EmS No. F-E, S-D
Special Provisions 223, 955
Marine pollutant This product contains a chemical which is listed as a marine pollutant according to
IMDG/IMO
Description UN1169, EXTRACTS, AROMATIC, LIQUID, 3, III, (51 C C.C.)
ADR
UN/ID no UN1169
Proper Shipping Name EXTRACTS, AROMATIC, LIQUID
Hazard Class 3
Packing group III
Classification code F1
Tunnel restriction code D/E
Special Provisions 601, 640E
Description UN1169, EXTRACTS, AROMATIC, LIQUID, 3, III
ADR/RID-Labels 3
15. REGULATORY INFORMATION
International Inventories
TSCA Complies
DSL/NDSL Complies
EINECS/ELINCS Complies
ENCS Complies
IECSC Complies
KECL Complies
PICCS Complies
NZIoC Complies
AICS Complies
Legend: TSCA – United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL – Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS – European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS – Japan Existing and New Chemical Substances
IECSC – China Inventory of Existing Chemical Substances
KECL – Korean Existing and Evaluated Chemical Substances
PICCS – Philippines Inventory of Chemicals and Chemical Substances
NZIoC – New Zealand Inventory of Chemicals
AICS – Australian Inventory of Chemical Substances
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.
SARA 311/312 Hazard Categories
Acute health hazard Yes
Chronic Health Hazard Yes
Fire hazard Yes
Sudden release of pressure hazard No
Reactive Hazard No
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42).
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Product Name: STAN-MASK 21651 CITRUS SWEET GRAS
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CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material.
US State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations
US State Regulations This product does not contain any substances regulated by state right-to-know regulations
Chemical name New Jersey Massachusetts Pennsylvania
BENZALDEHYDE
100-52-7
X X X
ETHYL BENZOATE
93-89-0
– – X
U.S. EPA Label Information
EPA Pesticide Registration NumberNot applicable
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION
Issue Date:
Revision Date:
Version #:
07-22-2015
08-03-2017
02
Disclaimer: The information and recommendations contained herein are based upon data that are believed to be accurate
and reliable. Application and performance information are provided only as a guide, since the conditions of use are
beyond the control of Harwick Standard Distribution Corporation. Consequently, Harwick Standard makes no warranties,
express or implied, with respect to the goods or use of the goods or the performance of the goods and makes no
warranties of fitness for a particular purpose or merchantability. Buyer acknowledges that Harwick Standard will not be
liable for consequential, incidental, direct or special damages arising, directly or indirectly, in respect to such goods or
the use or failure thereof, whether based on breach of warranty, negligence, strict liability in tort or otherwise.
End of Safety Data Sheet
NFPA Health hazards 2 Flammability 2 Instability 0 Physical and chemical
properties –
HMIS Health hazards 2 Flammability 2 Physical hazards 0 Personal protection X
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Product Name: STAN-MASK 21651 CITRUS SWEET GRAS