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Safety Data Sheet Revision: 09/15/2015
Section 1: Identification
Product Name: LH-102 BLUE
Identification: Poly Amine Curing Agent
Manufacturer: Resin Services Inc.
5959 18 Mile Road
Sterling Heights MI 48314 USA
Ph (586)254-6770 Fax(586)-254-6947
Emergency Overview
For chemical emergency, spill, leak, fire, exposure, or accident call CHEMTREC day or night
Within USA and Canada: 1-800-424-9300
Outside USA or Canada: +1-703-527-3887
Section 2: Hazard Identification
Potential Health Effects
Classification of the
Substance or mixture : ACUTE TOXICITY: oral Category 4
ACUTE TOXICITY: inhalation Category 4
SKIN CORROSION/IRRITATION Category 1
SERIOUS EYE DAMAGE/EYE IRRITATION- Category 1
RESPIRATORY SENSITATION Category 1
SKIN SENSITIZATION Category 1
TOXIC TO REPRODUCTION Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
[central nervous system (CNS), eyes] Category 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
[Narcotic effects] Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
[Respiratory tract irritation] Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEAT EXPOSURE)
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[Blood system, lungs, skin, respiratory tract, liver, kidneys] Category 1
GHS LABEL ELEMENTS
HAZARD PICTOGRAMS :
Signal Word : Danger
Hazard Statements : H302 Harmful if swallowed
H312 Harmful in contact with skin
H332 Harmful if inhaled
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
H334 May cause allergy or asthma symptoms or breathing difficulties
If inhaled
H317 May cause an allergic skin reaction
H361 f Suspected of damaging fertility
H361 d Suspected of damaging the unborn child
H335 May cause respiratory irritation
H370 Causes damage to organs (central nervous system (CNS),eyes)
H336 May cause drowsiness and dizziness
H372 Causes damage to organs through prolonged or repeated exposure:
(blood system, skin, respiratory tract, liver, kidneys)
PRECAUTIONARY STATEMENTS
Prevention : Obtain special instruction before use
Do not handle until all safety precautions have been read and understood
Use personal protection equipment as required
Wear protective gloves
Wear eye or face protection
Wear protective clothing
In case of inadequate ventilation wear respiratory protection
Use only outdoor or in well-ventilated area
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Do not breathe vapor
Do not eat, drink or smoke when using this product
Wash hands thoroughly after handling
Contaminated work clothing should not be allowed out of workplace
Response : Get medical attention if you fell unwell
IF EXPOSED: Call a POSION CONTROL or physician
IF INHALED: Remove victim to fresh air and keep at rest in a position
Comfortable for breathing. Immediately call a POISON CENTER or physician
If experiencing respiratory symptoms. Call a POISON CENTER or physician
IF SWALLOWED: Immediately call POSION CENTER or physician
Rinse mouth. Do NOT induce vomiting.
IF ON SKIN (or hair): Take off immediately all contaminated clothing
Rinse skin with water or shower. Wash contaminated clothing before reuse.
Immediately call a POISON CENTER or physician
IF ON SKIN: Wash with plenty of soap and water. If skin, irritation or rash
. occurs. Get medical attention
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
Lenses, if present and easy to do. Continue rinsing. Immediately call a
POISON CENTER or physician.
Storage : Store locked up
Disposal : Dispose of contents and container in accordance with all local,
Regional, national and international regulations.
Hazards Material Information System (United States):
Health 3
Flammability 1
Physical Hazard 0
Hazard Codes: 0= Chronic Hazard, 0= Minimal Hazard, 1= Slight Hazard, 2= Moderate Hazard, 3= Serious Hazard,
4= Severe Hazard
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Section 3 Composition/Information on Ingredients
Ingredient Name CAS Number % wt or %
vol
TRIETHYLENETETRAMINE 0112-24-3 40-60
POLYOXYPROPYLENEDIAMINE 9046-10-0 20-30
DIETHYLENETRIAMINE 111-40-0 20-30
2-ETHYL-4-METHYLIMIDAZOLE 931-36-2 1-2
BLUE PIGMENT ********* -1
Section 4 First-Aid Measures
Inhalation: REMOVE VICTIM TO FRESH AIR AND PROVIDE OXYGEN IF BREATHING IS DIFFICULT. GIVE
ARTIFICIAL RESPIRATION IF NOT BREATHING. GET MEDICAL ATTENTION.
Eye Contact: FLUSH EYES WITH PLENTY OF WATER FOR 30 MINUTES WHILE HOLDING EYELIDS OPEN.
GET MEDICAL ATTENTION.
Skin Contact: REMOVE CONTAMINATED CLOTHING/SHOES AND WIPE EXCESS FROM SKIN. FLUSH SKIN
WITH WATER. FOLLOW BY WASHING WITH SOAP AND WATER. IF IRRITATION OCCURS, GET MEDICAL ATTENTION. DO
NOT REUSE CLOTHING UNTIL CLEANED. CONTAMINATED LEATHER ARTICLES,
INCLUDING SHOES, CANNOT BE DECONTAMINATED AND SHOULD BE DESTROYED TO PREVENT REUSE.
Ingestion: DO NOT INDUCE VOMITING , CALL A PHYSICIAN.
After first aid, get appropriate in-plant, paramedic, or community medical support.
Special Precautions/Procedures: STORE IN COOL, DRY PLACE WITH ADEQUATE VENTILATION. KEEP AWAY
FROM OPEN FLAMES AND HIGH TEMPERATURES.
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Section 5 Fire-Fighting Measures
Extinguishing Media: USE WATER FOG, ALCOHOL FOAM DRY CHEMICAL OR C02.
Unusual Fire or Explosion Hazards: NO UNUSUAL HAZARDS.
Hazardous Combustion Products: NO UNUSUAL HAZARDS.
Fire-Fighting Instructions: Do not release runoff from fire control methods to sewer or waterways.
Fire-Fighting Equipment: Because fire may produce toxic thermal decomposition products, wear a self-contained
breathing apparatus (SCBA) with full face piece operated in pressure-demand or positive-pressure mode.
Section 6 Accidental Release Measures
Spill /Leak Procedures: MAY BURN ALTHOUGH NOT READILY IGNITABLE.
Small Spills: TAKE UP WITH AN ABSORBENT MATERIAL AND DISPOSE OF PROPERLY.
Large Spills DIKE AND CONTAIN. REMOVE WITH VACUUM TRUCKS OR PUMP TO STORAGE/SALVAGE
MATERIAL; DISPOSE OF PROPERLY.
Containment: For large spills, dike far ahead of liquid spill for later disposal. Do not release into sewers or
waterways.
Cleanup: FLUSH AREA WITH WATER TO REMOVE TRACE RESIDUE.
Regulatory Requirements: Follow applicable OSHA regulations (29 CFR 1910.120).
Section 7 Handling and Storage
Handling Precautions: MINIMIZE ALL CONTACT WITH MATERIAL. WASH WITH SOAP AND WATER BEFORE
EATING, DRINKING, SMOKING, APPLYING COSMETICS OR USING TOILET FACILITIES.
Storage Requirements: STORE IN COOL, DRY PLACE WITH ADEQUATE VENTILATION.
Regulatory Requirements: NONE
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Section 8 Exposure Controls/Personal Protection
Engineering Controls:
Ventilation: Provide general or local exhaust ventilation systems to maintain airborne concentrations below OSHA
PELs (Sec. 2). Local exhaust ventilation is preferred because it prevents contaminant dispersion into the work area
by controlling it at its source.
Administrative Controls:
Respiratory Protection: Seek professional advice prior to respirator selection and use. Follow OSHA respirator
regulations (29 CFR 1910.134) and, if necessary, wear a MSHA/NIOSH-approved respirator. Select respirator based
on its suitability to provide adequate worker protection for given working conditions, level of airborne
contamination, and presence of sufficient oxygen. For emergency or non routine operations (cleaning spills, reactor
vessels, or storage tanks), wear an SCBA. Warning! Air-purifying respirators do not protect workers in oxygen-
deficient atmospheres. If respirators are used, OSHA requires a written respiratory protection program that includes
at least: medical certification, training, fit-testing, periodic environmental monitoring, maintenance, inspection,
cleaning, and convenient, sanitary storage areas.
Protective Clothing/Equipment: Wear chemically protective gloves, boots, aprons, and gauntlets to prevent
prolonged or repeated skin contact. Wear protective eyeglasses or chemical safety goggles, per OSHA eye- and face-
protection regulations (29 CFR 1910.133). Contact lenses are not eye protective devices. Appropriate eye protection
must be worn instead of, or in conjunction with contact lenses.
Safety Stations: Make emergency eyewash stations, safety/quick-drench showers, and washing facilities available in
work area.
Contaminated Equipment: Separate contaminated work clothes from street clothes. Launder before reuse. Remove
this material from your shoes and clean personal protective equipment.
Comments: Never eat, drink, or smoke in work areas. Practice good personal hygiene after using this material, especially
before eating, drinking, smoking, using the toilet, or applying cosmetics
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Sections 9 Physical and Chemical Properties
Physical State: LIQUID
Appearance and Odor: BLUE ; FAINT AMINE – LIKE
ODOR
Vapor Pressure: 0.015 mm Hg at F (20 C)
Vapor Density (Air=1): NOT VOLATILE
Density: 7.8 W.P.G.
Specific Gravity (H2O=1, at 4 C): .94
Water Solubility: APPRECIABLE
Boiling Point: 477 F {247 C}
Freezing/Melting Point: N/A
Flash Point: 234 F (112 C)
% Volatile: NOT VOLATILE
Evaporation Rate: NOT VOLATILE
Section 10 Stability and Reactivity
Stability: Stable at room temperature in closed containers under normal storage and handling conditions.
Polymerization: Hazardous polymerization cannot occur.
Chemical Incompatibilities: STRONG OXIDANTS , ACIDS
Conditions to Avoid: N/A
Hazardous Decomposition Products: Thermal oxidative decomposition can produce AMMONIA , BURNING WILL
PRODUCE TOXIC FUMES ; CO , NITRIC OXIDES , THERMAL DECOMPOSITION TEMPERATURE : 500 F {260 C}
Section 11 Toxicological Information
Likely routes of exposure: N/A
Symptoms related to the physical, chemical and toxicological characteristics:
Ingestion: Ingestion may cause gastrointestinal irritation or ulceration. Ingestion may cause burns of mouth and throat. Aspiration
into the lungs may occur during ingestion or vomiting, causing tissue damage or lung injury.
Skin Contact: Prolong or widespread skin contact may result in absorption of harmful amounts.
Irritation:
Skin: Brief contact may cause severe skin burns. Symptoms may include pain, serve local redness and tissue damage. Skin contact
has caused allergic skin reactions in certain sensitized individuals.
Eyes: May cause pain disproportionate to the level of irritation to eye tissues. May cause severe irritation with corneal injury which
may result in permanent impairment of vision, even blindness. Chemical burns may occur.
Inhalation: May cause allergic respiratory response.
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Excessive exposure may cause irritation to upper respiratory tract (nose and throat).
Delayed and immediate effects and also chronic effects from short and long term exposure:
Carcinogen: This product contains no materials that are reported as known or suspect carcinogens in levels above 0.1%.
Mutagen: This product contains no materials that are reported as known or suspect mutagens in levels above 0.1%.
Reproductive Hazard: This product contains no materials that are reported as known or suspected of causing a reproductive hazard
in levels above 0.1%
Numerical measures of toxicity: The finished product has not been tested to determine individual toxicological/ ecological limits.
Section 12 Ecological Information
Ecotoxicity: Individual components of this mixture have been independently tested by the raw material suppliers and any known
results have been presented in section 3. The results for the individual components may not be representative of the ecological toxicity
of this finished product. This finished product has not been tested to determine individual toxicological/ ecological limits. Great caution
should be taken to prevent release to the environment. See section 13 for further information.
Persistence and degradability: N/A
Bioaccumulative potential: N/A
Mobility in soil: N/A
Other adverse effects: N/A
Section 13 Disposal Considerations
Disposal Methods: Preferred method of disposal includes incineration under controlled conditions in accordance with all
local and national laws and regulations. The generation of waste should be avoided or minimized wherever possible.
Untreated material is not suitable for disposal. Waste, even small quantities, should never be poured down drains, sewers
or watercourses. Waste must be disposed of in accordance with federal, state and local environmental control
regulations. This material, when properly mixed and cured with its resin components at the proper mix ratio, may be
safely landfilled.
Contaminated packaging: Empty containers can only be disposed of when the remaining product adhering to the
container walls have been removed. Hazard warning labels should be removed from container only after it has been
properly emptied.
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Section 14 Transport Information
D.O.T. AIR/ROAD/RAIL ICAO/IATA AIR TRANSPORT IMDG SEA TRANSPORT
TRANSPORT(49CFR)
UN NUMBER: UN1760 UN NUMBER: UN1760 UN NUMBER: UN1760
Proper Shipping Name: Proper Shipping Name: Proper Shipping Name:
CORROSIVE, LIQUID,N.O.S. CORROSIVE, LIQUID,N.O.S. CORROSIVE, LIQUID,N.O.S.
(TRIETHYLENETETRAMINE, (TRIETHYLENETETRAMINE, (TRIETHYLENETETRAMINE,
DIETHYLENETRIAMINE) DIETHYLENETRIAMINE) DIETHYLENETRIAMINE)
Transport Hazard Class: 8 Transport Hazard Class: 8 Transport Hazard Class: 8
Packing Group: II Packing Group: II Packing Group: II
Section 15 Regulatory Information
Safety, health and environmental regulations:
TSCA: This product is manufactured in compliance with all provisions of the Toxic Substances Control Act, 15 U.S.C.
2601 et. Seq. This product contains a chemical substance that is subject to export notification under Section 12(b) of the
Toxic Substance Control Act, 15 U.S.C. 2601 et.seq.
Toxic Substance Control Act (TSCA) 12(b) Components: None known
OSHA Hazard Communication Standard (29CFR1910. 1200) hazard class(es). Corrosive, Toxic by skin Absorption,
Dangerous for the Environment.
EPA SARA Title III section 302 (40CFR370) Hazard Class: Immediate Health Hazard, Delayed Health Hazard
EPA SARA Title III section313 (40CFR372) Toxic Chemicals above de minimus levels: None
CALIFORNIA PROPOSITION 65: SUBSTANCE (component(s) know to the State of California to cause cancer and/ or
reproductive and subject to warning and discharge requirements under the Safe Drinking Water and Toxic
Enforcement Act of 1986 ) NONE
Section 16 Other information
Company policy or disclaimer- To the best of our knowledge, the information contained herein is accurate.
Final determination of the suitability of any material is sole responsibility of the users. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards which exist.
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