Material Safety DataSheet
Page1of5 Spabond 340LV resin
1 Productandcompanyidentification
Material identification:Spabond 340LV Resin
Applicati onofthesubstance/pr eparation:Epoxyresinadhesive
Supplier/Manu facturer :Gurit(Canada)Inc
175,rueP ladeau
Magog,Qu bec,J1X7L1
Canada
Tel:+1819847-2182
Fortranspo rtation emergencie s,call:Chemt rec:1-800-424-9300orCanutec (Canada): 613-996-6666
Foradditional informati on:Health,Safety andEnvironm entdepartment
Email:christian.moreau@gur it.com
Dateofissue:15/04/10
2 Hazardsidentifi cation
Emergency overview : Viscousliquid material containsepoxyconstituent s.
Hazardous status: Thismaterial isclassified hazardous under OSHA29CFR1910.1200 andunder
theCanadianContro lledProductsRegulati ons
Warning statement : WARNING!
CAUSESEYEANDSKIN IRRITA TION
MAYCAUSE RESPIRATORY TRACT IRRITATION
MAYCAUSE SENSITIZA TION BYSKINCONTACT
Avoidcontact withskinandclothing. Donotbreathevapor,useonlywithadequate
ventilation.
Wash thoroughly whenappropriate
Potential acutehealth effects:Eyes:Irritanttoeyes
Skin:Irritant toskinandmucus membranes .
Inhalation: Maycauserespiratorytractirritation.
Ingestion: Maycauseillness.
Potential chronichealth effects:Prolonged skincontact cancausesensitization.
3 Composi tion/information oningredients
Description :Mixture ofthesubstanc eslistedbelow withnonhaz ardousadditions .
Chem icalname CASnumber %Conce ntration
Propane, 2,2-bis[p-(2,3-epoxypr opoxy)phenyl] -,polymers 25085 -99-8 60 100%
Alkyl (C12,C14)GlycidylEther 68609 -97-2 5 10%
1,4-Butanediol Diglycidy lEther 2425-79-8 5 10%
Phenol, polymer withformaldehyde, GlycidylEther 28064 -14-4 1 5%
Material Safety DataSheet
Page2of5 Spabond 340LV resin
4 Firstaidmeasures
Eyecontact: Rinse immediatelywithplenty ofwater.Ifsymptom spersist, consultadoctor.
Skincontact : Immediat elywashwithsoapandrinsethoroughly .Remove clothing soiledbytheproduct.
Ingestion: Donotinduce vomiting.Rinse outmouth anddrinkplentyofwater.Callformedical help.
Inhalation : Removeindividualtofreshair.Consult adoctor ifsymptomspersist.
6 Accide ntalreleas emeasures
Person alprecautions : Wearprotectiveclothing toavoidcontact witheyesandskin.
Environm entalprecaution s: Prevent materialfromenteringwaterways, sewerssurface orground water.
Measuresforcleaning up: Scoop upspilled material.
5 Fire-fighting measures
Suitableextinguishi ngmedia:Waterhaze,foam, fire-extinguishing powder, carbon dioxide.
Notsuitab leextinguishi ngmedia:Waterwithfulljet.
Special exposurehazards: Formation oftoxicgaseswilloccurduring overheating orincaseoffire.
Protective equipment : Wearfullyprotective suitwithselfcontained breathing apparatus
(SCBA)withaface-pieceoperatedinpositivepressure mode.
7 Handling andstorage
Handling: Wearappropriatepersonalprotection whenhandling. Avoidinhalationofvapors.
Storage: Storeinacool,dryplaceintightly closed receptacles. Keepawayfromheat.
Dateofissue:15/04/10
Material Safety DataSheet
Page3of5 Spabond 340LV resin
9 Physical andchemical properties
Physicalstate: Pasty
Color: Yellow
Odor: Characterist ic(slight)
Flash point: >101
o
C(>214
o
F)
Melting point: Notavailable
Boilingpoint: >200
o
C(>392
o
F)
Ignition temperature : 460
o
C(860
o
F);Product isnotself-igniting
Vapor pressure (20
o
C(68
o
F): 0.075mmHg
Relative density : Notdeterm ined
Solubili tyinwater: Notmiscible
8 Expos urecontrols andpersonalprotection
Componen tswithlimitvaluesthatrequire monitoring attheworkp lace:Noneestablished
Enginee ringmeasures:Useonlywithadequateventilation oruserespiratoryprotection.
General measu res: Keepproductawayfromfoodandbeverage s.
Washhands before eatingandwhenever appropriate .
Immediately remove allsoiled andcontaminated clothing .
Avoidcontact witheyesandskin.
Person alprotection equipments:Eyes:Wearsafetyglasses
Skin:Weargloves andprotecti veworkclothes
Suitablegloves:Nitrilerubber(NBR).Selection ofgloves should takeinconsidera tionthequalityaspect
(thickness,strength, etc.)whichvariesfrommanufactu rertomanufacturer .
Dateofissue:15/04/10
Material Safety DataSheet
Page4of5 Spabond 340LV resin
10 Stability andreactivity
Stabilityandreactivity :Thisproductisstable.
Dangerous reaction : Nodanger ousreactions known.
Incompatibility withothersubstances: Strongoxidizers, strong acidsandbases,amines.
Hazardous decomposition products: Decomposit ionproducts includebutarenotlimitedto:Carbon
monoxide, Carbon dioxideandtoxicpyrolysis product s.
12 Ecologi calinformation
General notes:Toxictosomeaquaticorganisms. Prevent material toreachground water, waterways or
sewagesystem.
Ecotoxicitydata:Notavailabl e
Persistence andbiodegrad ability:Notavailable
Mobility:Notavailab le
13 Disposalconsideration
Wastedispos al:Disposal mustbeinaccordance withapplicableFederal, Stateandlocalregulatio ns.
Remarks : Donotallowmaterialtoenterdrains, sewers orsurface water.
Dateofissue:15/04/10
11 Toxicol ogical information
Toxicolog icalinformation
Ingredient name Test Result Route /species
Propane, 2,2-bis[p-(2,3-poxypr opoxy) phenyl] -,polymers LD50 >5000mg/kg Oralrat
Alkyl (C12,C14)GlycidylEther LD50 >5000mg/kg Oralrat
1,4-Butanediol Diglycidy lEther LD50 >1000mg/kg Oralrat
Phenol, polymer withformaldehyde, GlycidylEther LD50 >5000mg/kg Oralrat
Acute toxicity: Irritanttoeyes.
Irritanttoskinandmucous membranes.
Maycauserespirator ytractirritation.
Maycauseillness ifingested.
Sensitization: Sensitization possiblethrough skincontact.
Mutagenic effects :Notavailable
Teratogenic effects :Notavailab le
Carcin ogeniceffects:Notlistedascarcinogenic byACGIH ,OSHA, IARC andNTP.
Material Safety DataSheet
Page5of5 Spabond 340LV resin
15 Regul atoryinformation
U.S.Federa lregulat ions:
TSCA :Allcomponen tslisted.
SARA 302;304;311/312;313:Noneoftheingredient listed.
U.S.Stateregulations :
California Proposition65:Noneoftheingredient listed.
Canadian regulatio ns:
DSL:Allcompone ntslisted
WHMI Sclassification :D2B-Toxicmaterials causing othereffects;
1
0
HEALTH
FLAMMABIL ITY
PHYSIC ALHAZARDS
HMIS-rating Hazar drating
0-Minimal
1-Slight
2-Moderat e
3-Serious
4-Extreme
NFPA-rating
2
1
0
Health
Flammability
Reactivity
*2
Regulatorystatus
(UN/IMDG/ IATA;DOT/TDG) :Notregulated fortransport
16 Other information
References: AINSIZ400.1,MSDS Standard,2004;
29CFR 1910.1200 OSHA Hazard Communication Standard ;
Controlledproducts regulations(DORS/88 -66)Canada.
Noticetothereader:
Tothebestofourknowle dge,theinformationcontained hereinisaccurate atthedateofitspublication.However ,
thisshallnotconstitu teaguarant eeforanyspecificproduct features andshallnotestablish alegallyvalid
contractualrelationshi p.Thedatarelatesonlytothespecificproduct designated anddoesnotrelatetouseofthe
productinanyprocess orincombination withanyothermaterial.
14 Transport information
Dateofissue:15/04/10
Page 1/7
Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 05/06/2008 Reviewed on 05/06/2008
D R
* 1 Identification of substance
Product details
Trade name: Spabond 340 Extra Slow Hardener
Application of the substance / the preparationEpoxy curing agent
Manufacturer/Supplier:
GURIT (UK) Ltd GURIT (Canada) Inc.
St. CROSS BUSINESS PARK 175, rue P ladeau
NEWPORT I.O.W. Magog (Qu bec)
PO30 5WU J1X 5G9
UNITED KINGDOM Canada
TEL:+44(0)1983 828000 T: +1 819 847 2182
FAX:+44(0)1983 828100 F: +1 819 847 2572
Information department:Product safety department.
Emergency information:Contact as above
* 2 Composition/Data on components
Chemical characterization
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
9046-10-0 Polyoxyalkyleneamine 25-50%
2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine 10-25%
100-51-6 Benzyl alcohol 2.5-10%
3 Hazards identification
Hazard description:
C Corrosive
Information pertaining to particular dangers for man and environment:
The product has to be labelled due to the calculation procedure of the “General Classification guideline for
preparations of the EU” in the latest valid version.
Causes burns.
May cause sensitization by skin contact.
Classification system:
The classification was made according to the latest editions of international substances lists, and expanded
upon from company and literature data.
NFPA ratings (scale 0 – 4)
3
1
0
Health = 3
Fire = 1
Reactivity = 0
(Contd. on page 2)
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 05/06/2008 Reviewed on 05/06/2008
Trade name: Spabond 340 Extra Slow Hardener
(Contd. of page 1)
D R
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
3
1
0
Health = 3
Fire = 1
Reactivity = 0
4 First aid measures
General information:Immediately remove any clothing soiled by the product.
After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:
Immediately wash with water and soap and rinse thoroughly.
Immediately rinse with water.
After eye contact:Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing:
Do not induce vomiting; immediately call for medical help.
A person vomiting while lying on their back should be turned onto their side.
Administer medicinal carbon
Rinse out mouth and then drink plenty of water.
5 Fire fighting measures
Suitable extinguishing agents:
Water haze
Foam
Fire-extinguishing powder
Carbon dioxide
For safety reasons unsuitable extinguishing agents:Water with full jet
Special hazards caused by the material, its products of combustion or resulting gases:
Formation of toxic gases is possible during heating or in case of fire.
Protective equipment:
Mount respiratory protective device.
Wear fully protective suit.
6 Accidental release measures
Person-related safety precautions:Wear protective equipment. Keep unprotected persons away.
Measures for environmental protection:Do not allow to enter sewers/ surface or ground water.
Measures for cleaning/collecting:
Pick up mechanically.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
7 Handling and storage
Handling:
Information for safe handling:
Store in cool, dry place in tightly closed receptacles.
(Contd. on page 3)
USA
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 05/06/2008 Reviewed on 05/06/2008
Trade name: Spabond 340 Extra Slow Hardener
(Contd. of page 2)
D R
Keep away from heat and direct sunlight.
Information about protection against explosions and fires:No special measures required.
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:Keep receptacle tightly sealed.
8 Exposure controls and personal protection
Additional information about design of technical systems:No further data; see item 7.
Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be
monitored at the workplace.
Additional information:The lists that were valid during the creation were used as basis.
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Breathing equipment:Use suitable respiratory protective device in case of insufficient ventilation.
Protection of hands:
Protective gloves
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to
the application.
Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
For the permanent contact of a maximum of 15 minutes gloves made of the following materials are
suitable:
Nitrile rubber, NBR
Eye protection:Safety glasses
Body protection:Protective work clothing
9 Physical and chemical properties
General Information
Form: Pasty
Color: Blue
Odor: Amine-like
Change in condition
Melting point/Melting range:Undetermined.
(Contd. on page 4)
USA
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 05/06/2008 Reviewed on 05/06/2008
Trade name: Spabond 340 Extra Slow Hardener
(Contd. of page 3)
D R
Boiling point/Boiling range:247 C (477 F)
Flash point: 117 C (243 F)
Ignition temperature: 240.0 C (464 F)
Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Density at 20 C (68 F): 1.090 g/cm
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Viscosity:
Dynamic at 20 C (68 F): 260000 mPas
Solvent content:
Organic solvents: 0.0 %
Water: 0.0 %
Solids content: 17.0 %
10 Stability and reactivity
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Dangerous reactionsNo dangerous reactions known.
Dangerous products of decomposition:Danger of toxic pyrolysis products.
11 Toxicological information
Acute toxicity:
LD/LC50 values that are relevant for classification:
9046-10-0 Polyoxyalkyleneamine
Oral LD50 2855 mg/kg (rat)
Dermal LD50 2980 mg/kg (rab)
Primary irritant effect:
on the skin:Caustic effect on skin and mucous membranes.
on the eye:Strong caustic effect.
Sensitization:Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for
preparations:
Corrosive
Irritant
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of
esophagus and stomach.
12 Ecological information
General notes:
Water hazard class 1 (Self-assessment): slightly hazardous for water
(Contd. on page 5)
USA
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 05/06/2008 Reviewed on 05/06/2008
Trade name: Spabond 340 Extra Slow Hardener
(Contd. of page 4)
D R
Do not allow product to reach ground water, water course or sewage system.
* 13 Disposal considerations
Product:
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:
Packagings that cannot be cleansed are to be disposed of in the same manner as the product.
14 Transport information
DOT regulations:
Hazard class: 8
Identification number: UN3259
Packing group: II
Proper shipping name (technical name):P O L Y A M I N E S , S O L I D , C O R R O S I V E , N . O . S .
(Polyoxyalkyleneamine, ISOPHORONEDIAMINE)
Label 8
Land transport ADR/RID (cross-border):
ADR/RID class: 8 Corrosive substances
Danger code (Kemler): 80
UN-Number: 3259
Packaging group: II
Description of goods: 32 59 PO L YAMINES , SO L ID, CO RRO S IVE , N.O . S.
(Polyoxyalkyleneamine, ISOPHORONEDIAMINE)
Maritime transport IMDG:
IMDG Class: 8
UN Number: 3259
Label 8
Packaging group: II
EMS Number: F-A,S-B
Marine pollutant: No
(Contd. on page 6)
USA
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 05/06/2008 Reviewed on 05/06/2008
Trade name: Spabond 340 Extra Slow Hardener
(Contd. of page 5)
D R
Propper shipping name: P O L Y A M I N E S , S O L I D , C O R R O S I V E , N . O . S .
(Polyoxyalkyleneamine, ISOPHORONEDIAMINE)
Air transport ICAO-TI and IATA-DGR:
ICAO/IATA Class: 8
UN/ID Number: 3259
Label 8
Packaging group: II
Propper shipping name: P O L Y A M I N E S , S O L I D , C O R R O S I V E , N . O . S .
(Polyoxyalkyleneamine, ISOPHORONEDIAMINE)
* 15 Regulations
Sara
Section 355 (extremely hazardous substances):
None of the ingredient is listed.
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
TSCA (Toxic Substances Control Act):
All ingredients are listed.
Proposition 65
Chemicals known to cause cancer:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Cancerogenity categories
EPA (Environmental Protection Agency)
None of the ingredients is listed.
IARC (International Agency for Research on Cancer)
7631-86-9 silicon dioxide, chemically prepared 3
NTP (National Toxicology Program)
None of the ingredients is listed.
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
MAK (German Maximum Workplace Concentration)
None of the ingredients is listed.
(Contd. on page 7)
USA
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 05/06/2008 Reviewed on 05/06/2008
Trade name: Spabond 340 Extra Slow Hardener
(Contd. of page 6)
D R
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
Product related hazard informations:
The product has been classified and marked in accordance with directives on hazardous materials.
Hazard symbols:
C Corrosive
Hazard-determining components of labelling:
3-aminomethyl-3,5,5-trimethylcyclohexylamine
Benzyl alcohol
Polyoxyalkyleneamine
Risk phrases:
Causes burns.
May cause sensitization by skin contact.
Safety phrases:
When using do not eat or drink.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
After contact with skin, wash immediately with plenty of water
Wear suitable protective clothing, gloves and eye/face protection.
In case of accident or if you feel unwell, seek medical advice immediately.
This material and its container must be disposed of as hazardous waste.
National regulations:
All components in this formulation are listed in the EPA TSCA chemical inventory. They comply with
applicable rules and orders of the regulations.
Technical instructions (air):
Class Share in %
II 3.9
Water hazard class:Water hazard class 1 (Self-assessment): slightly hazardous for water.
* 16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Department issuing MSDS:Health, Safety & Environmental department.
Contact:SIMON RHODES
* Data compared to the previous version altered.
USA