80TC1611-F_SDS.pdf

INDEX

80TC1611
80TC1611-F
80TC1611-G
80TC1611-Q

SAFETY DATA SHEET
Date Prepared : 04/15/2015
SDS No : TC-1611 PART A
TC-1611 PART A
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: TC-1611 PART A
GENERAL USE: Epoxy resin
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450

CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Skin Irritation, Category 2
Eye Irritation, Category 2A
Skin Sensitization, Category 1
Environmental:
Chronic Hazards to the Aquatic Environment, Category 2
GHS LABEL
Exclamation
mark
Environment
SIGNAL WORD: WARNING
HAZARD STATEMENTS
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H317: May cause an allergic skin reaction.
H411: Toxic to aquatic life with long lasting effects.
PRECAUTIONARY STATEMENTS
Prevention:
P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
P264: Wash thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P272: Contaminated work clothing should not be allowed out of the workplace.
P273: Avoid release to the environment.
Response:
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P321: Specific treatment (see on this label).
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
Page 1 of 8

P362: Take off contaminated clothing and wash before reuse.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P337+P313: If eye irritation persists: Get medical advice/attention.
P391: Collect spillage.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
EMERGENCY OVERVIEW
PHYSICAL APPEARANCE: Black paste-like with a slight odor.
IMMEDIATE CONCERNS: Avoid eye and skin contact. Avoid breathing vapors. Causes eye and skin irritation. May cause allergic skin
reaction. May be harmful if swallowed. Use in well ventilated areas.
POTENTIAL HEALTH EFFECTS
EYES: Causes serious eye irritation.
SKIN: Causes skin irritation. May cause an allergic skin reaction.
INGESTION: May be harmful if swallowed.
INHALATION: May cause respiratory irritation.
MEDICAL CONDITIONS AGGRAVATED: Pre-existing skin conditions may be aggravated by exposure.
ROUTES OF ENTRY: Eye and skin contact, inhalation of vapors, or accidental ingestion.
SENSITIZATION: May cause allergic skin reaction.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
Barium sulfate 30 – 607727-43-7
Epoxy phenol novolac resin 15 – 4028064-14-4
Glycidyl ether, Aliphatic, Modifier 1 – 514228-73-0
Carbon Black 1 – 51333-86-4
Silica, Amorphous 0.5 – 1.57631-86-9
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes.
Get immediate medical attention.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or
oxygen by trained personnel. Get immediate medical attention.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be
monitored for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, aldehydes, hydrocarbons, and phenolics.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
Page 2 of 8
TC-1611 PART A

unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major spill should wear
full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or waterways. Neutralize
small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top
drums or plastic bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly
dispose of residues. Notify applicable government authorities if release is reportable. (See CERCLA in Section 15).
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains or rivers.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over
open containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a
manner consistent with good industrial/manufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contact.
Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 12 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Page 3 of 8
TC-1611 PART A

EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
OSHA PEL ACGIH TLV Supplier OEL
Chemical Name ppm mg/m
3
ppm mg/m
3
ppm mg/m
3
Barium sulfate
TWA NE
[1]
15T,5R

[1]
NE 10 NE
[2]
10T,5R

[2]
STEL NE NE NE NE NE NE
Epoxy phenol novolac resin
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Glycidyl ether, Aliphatic, Modifier
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Carbon Black
TWA NE 3.5 NE 3.5 NE
[2]
3.5
[2]
STEL NE NE NE NE NE NE
Silica, Amorphous
TWA
20
mppcf
[4]
80
%SiO2
[4]
NE
10 Total
Dust
NE
[2]
6
[2]
STEL NE NE NE NE NE NE
Footnotes:
1. T = Total, R = Respirable
2. NIOSH REL, T = Total, R = Respirable
3. NIOSH REL
4. Mineral Dusts
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with ‘Guidelines for the Selection of Chemical
Protective Clothing’ published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Paste-like
ODOR: Slight
COLOR: Black
pH: Not Established
PERCENT VOLATILE: 0.07
Page 4 of 8
TC-1611 PART A

FLASH POINT AND METHOD: > 93.3 C (200 F) Closed Cup
VAPOR PRESSURE: Not Established
VAPOR DENSITY: Not Established
BOILING POINT: Not Established
SOLUBILITY IN WATER: Insoluble
SPECIFIC GRAVITY: 1.85 (water=1) at 25 C (77 F)
VISCOSITY: Paste-like
(VOC): < 1.300 g/l Calculated. Theoretical VOC minus water and exempt solvents. 10. STABILITY AND REACTIVITY REACTIVITY: Hazardous reactions will not occur under normal transport or storage conditions. HAZARDOUS POLYMERIZATION: Product can undergo hazardous polymerization. This product will autopolymerize at very high temperatures. STABILITY: This product is stable under normal ambient conditions of temperature and pressure. CONDITIONS TO AVOID: High temperatures and sources of ignition. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, aldehydes, and phenolics. INCOMPATIBLE MATERIALS: Strong acids, bases, oxidizing agents, and amines. 11. TOXICOLOGICAL INFORMATION ACUTE Chemical Name ORAL LD50 DERMAL LD50 INHALATION LC 50 Barium sulfate Not Established Not Established Not Established Epoxy phenol novolac resin > 2000 mg/kg > 2000 mg/kg Not Established
Glycidyl ether, Aliphatic, Modifier 2450 mg/kg 2500 mg/kg Not Established
Carbon Black > 8000 g/kg Not Established Not Established
Silica, Amorphous Not Established Not Established Not Established
CARCINOGENICITY
Chemical Name
IARC
Status
Carbon Black 2B
Silica, Amorphous 3
IARC: This product contains substances that are classified as carcinogens to humans.
IRRITATION: Causes eye and skin irritation.
SENSITIZATION: May cause sensitization by skin contact.
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: This product may cause risk of hazardous effects to the environment.
ECOTOXICOLOGICAL INFORMATION: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Avoid release to the environment.
BIOACCUMULATION/ACCUMULATION: No data available
DISTRIBUTION: No data available
CHEMICAL FATE INFORMATION: No data available
Page 5 of 8
TC-1611 PART A

13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain
some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements
of environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION)
PROPER SHIPPING NAME: Environmentally hazardous substance, liquid, n.o.s. (See Note)
TECHNICAL NAME: Epoxy phenol novolac resin
PRIMARY HAZARD CLASS/DIVISION: 9
UN/NA NUMBER: UN3082
PACKING GROUP: III
NAERG: 171
LABEL: Class 9 (miscellaneous hazardous materials)
MARINE POLLUTANT #1: Yes
OTHER SHIPPING INFORMATION: Only regulated for bulk and vessel shipments, per 49CFR171.4 (c) Exceptions. Except when all or
part of the transportation is by vessel, the requirements of this subchapter specific to marine pollutants do not apply to non-bulk
packagings transported by motor vehicle, rail car, or aircraft.
ROAD AND RAIL (ADR/RID)
PROPER SHIPPING NAME: Environmentally hazardous substance, liquid, n.o.s. (Epoxy phenol novolac resin)
UN NUMBER: UN3082
HAZARD CLASS: 9
PACKING GROUP: III
LABEL: Class 9 (miscellaneous hazardous materials)
AIR (ICAO/IATA)
SHIPPING NAME: Environmentally hazardous substance, liquid, n.o.s. (See Note)
TECHNICAL NAME: Epoxy phenol novolac resin
UN/NA NUMBER: UN3082
PRIMARY HAZARD CLASS/DIVISION: 9
PACKING GROUP: III
ERG: 9L
LABEL: Class 9 (miscellaneous hazardous materials)
NOTE: Only regulated for bulk and vessel shipments, per 49CFR171.4 (c) Exceptions. Except when all or part of the transportation is by
vessel, the requirements of this subchapter specific to marine pollutants do not apply to non-bulk packagings transported by motor vehicle,
rail car, or aircraft.
VESSEL (IMO/IMDG)
SHIPPING NAME: Environmentally hazardous substance, liquid, n.o.s.
TECHNICAL NAME: Epoxy phenol novolac resin
UN/NA NUMBER: UN3082
PRIMARY HAZARD CLASS/DIVISION: 9
PACKING GROUP: III
EmS: F-A, S-F
MARINE POLLUTANT #1: Yes
Page 6 of 8
TC-1611 PART A

LABEL: Class 9 (miscellaneous hazardous materials)
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HAZARD CATEGORIES: Acute health hazard. Chronic health hazard
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section
313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
None
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPE NSATION, AND LIABILITY ACT)
CERCLA REGULATORY: For this/these chemicals, release of more than the Reportable Quantity to the environment in a 24-hour
period requires notification to the National Response Center (800-424-8802 or 202-426-2675):
None
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product contains chemical(s) subject to TSCA Section 12(b) export notification:
None
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119—PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in
this product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: This product contains chemical(s) which are known to the State of California to cause cancer, birth
defects or other reproductive harm, and may be subject to the requirements of California Proposition 65 (CA Health & Safety Code
Section 25249.5):
Chemical Name Wt.% Listed
Carbon Black 1 – 5 Cancer
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS HAZARD SYMBOL AND CLASSIFICATION
D2A – Very
Toxic
D2B – Toxic
WHMIS CLASSIFICATION
Class D2A: Poisonous and infectious material (Very toxic).
Class D2B: Poisonous and infectious material (Toxic).
WHMIS HEALTH EFFECTS CRITERIA
D2A – Chronic toxicity
D2A – Carcinogenicity
D2B – Mutagenicity
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic
Substances List (DSL) or the Non-Domestic Substances List (NDSL).
GENERAL COMMENTS: No data available
16. OTHER INFORMATION
Page 7 of 8
TC-1611 PART A

REASON FOR ISSUE: Revised format
Date Prepared: 04/15/2015
HMIS RATING
HEALTH * 2
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA CODES

1
2 0

HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc.
assumes no legal responsibility for use or reliance upon this data.
Page 8 of 8
TC-1611 PART A

SAFETY DATA SHEET
Date Prepared : 04/15/2015
SDS No : TC-1611 PART B
TC-1611 PART B
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: TC-1611 PART B
GENERAL USE: Epoxy curing agent
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450

CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Acute Toxicity (Oral), Category 4
Acute Toxicity (Dermal), Category 4
Skin Corrosion, Category 1
Serious Eye Damage, Category 1
Skin Sensitization, Category 1
Target Organ Toxicity (Repeated exposure), Category 2
Environmental:
Chronic Hazards to the Aquatic Environment, Category 2
GHS LABEL
Exclamation
mark
CorrosionEnvironment
SIGNAL WORD: DANGER
HAZARD STATEMENTS
H302: Harmful if swallowed.
H312: Harmful in contact with skin.
H314: Causes severe skin burns and eye damage.
H318: Causes serious eye damage.
H317: May cause an allergic skin reaction.
H373: May cause damage to organs through prolonged or repeated exposure .
H411: Toxic to aquatic life with long lasting effects.
PRECAUTIONARY STATEMENTS
Prevention:
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P264: Wash thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P272: Contaminated work clothing should not be allowed out of the workplace.
Page 1 of 8

P280: Wear protective gloves/protective clothing/eye protection/face protection.
P273: Avoid release to the environment.
Response:
P301+P330+P331: IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P303+P361+P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
P363: Wash contaminated clothing before reuse.
P304+P340: IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see on this label).
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P391: Collect spillage.
Storage:
P405: Store locked up.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
EMERGENCY OVERVIEW
PHYSICAL APPEARANCE: Amber liquid with an ammoniacal odor.
IMMEDIATE CONCERNS: Corrosive. Causes eye and skin burns. Causes respiratory tract irritation. May cause allergic skin reaction.
May be harmful if absorbed through skin. Contains material that may cause target organ damage, based on animal data. Do not breathe
vapor or mist. Do not get in eyes or on skin or clothing. Use only with adequate ventilation. Keep container tightly closed and sealed until
ready for use. Wash thoroughly after handling.
POTENTIAL HEALTH EFFECTS
EYES: Causes eye burns. May cause blindness. Severe eye irritation.
SKIN: Causes severe skin burns. May cause an allergic skin reaction.
INGESTION: Harmful if swallowed. If ingested, severe burns of the mouth and throat, as well as a danger of perforation of the oesophagus
and the stomach.
INHALATION: May be harmful if inhaled. May cause respiratory tract irritation.
CARCINOGENICITY: This product contains ingredients that are considered to be probable or suspected human carcinogens.
MEDICAL CONDITIONS AGGRAVATED: Pre-existing eye and skin conditions may be aggravated by exposure.
ROUTES OF ENTRY: Eye and skin contact, inhalation of vapors, or accidental ingestion.
TARGET ORGAN STATEMENT: Contains material which may cause damage to the following organs: skin, eyes, respiratory system,
reproductive system, kidney, and liver.
SENSITIZATION: May cause allergic skin reaction.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
Tetraethylenepentamine 30 – 60112-57-2
2-piperazin-1-ylethylamine 15 – 40140-31-8
Diethyltoluenediamine (DETDA) 7 – 1368479-98-1
2-Ethyl-4-methylimidazole 1 – 5931-36-2
Diethylenetriamine (DETA) 0.1 – 1111-40-0
1h-imidazole, 5-methyl- 0.1 – 1822-36-6
4. FIRST AID MEASURES
Page 2 of 8
TC-1611 PART B

EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes.
Get immediate medical attention.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention immediately. Wash
clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or
oxygen by trained personnel. Get immediate medical attention.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
CHRONIC EFFECTS: Prolonged contact may result in chemical burns and permanent damage. May cause allergic skin reaction.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be
monitored for at least 48 hours.
5. FIRE FIGHTING MEASURES
GENERAL HAZARD: May generate ammonia gas. May generate nitrogen oxide gases. Incomplete combustion may form carbon monoxide.
Downwind personnel must be evacuated. Burning of material produces obnoxious and toxic fumes.
EXTINGUISHING MEDIA: Alcohol resistant foam, carbon dioxide, dry chemical, dry sand, or limestone powder.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, nitric acid, ammonia, aldehydes,
nitrosamine, and chlorine.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major spill should wear
full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or waterways. Neutralize
small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top
drums or plastic bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly
dispose of residues. Notify applicable government authorities if release is reportable. (See CERCLA in Section 15).
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains or rivers.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over
open containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Do not use sodium nitrite or other nitorsating agents in formulations containing this product. Suspected cancer causing
nitrosamines could be formed. Use appropriate personal protective equipment as specified in Section 8. Handle in a well ventilated area.
Handle and use in a manner consistent with good industrial/manufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contact.
Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 12 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Page 3 of 8
TC-1611 PART B

EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
OSHA PEL ACGIH TLV Supplier OEL
Chemical Name ppm mg/m
3
ppm mg/m
3
ppm mg/m
3
Tetraethylenepentamine
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
2-piperazin-1-ylethylamine
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Diethyltoluenediamine (DETDA)
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
2-Ethyl-4-methylimidazole
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Diethylenetriamine (DETA)
TWA NE NE 1 NE 1
[1]
4
[1]
STEL NE NE NE NE NE NE
1h-imidazole, 5-methyl-
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Footnotes:
1. NIOSH REL (skin)
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with ‘Guidelines for the Selection of Chemical
Protective Clothing’ published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Ammoniacal
COLOR: Amber
pH: Alkaline
FLASH POINT AND METHOD: > 100 C (212 F) Closed Cup
VAPOR PRESSURE: Not Established
Page 4 of 8
TC-1611 PART B

VAPOR DENSITY: Not Established
BOILING POINT: > 132.2 C (270 F)
SOLUBILITY IN WATER: Moderately soluble
SPECIFIC GRAVITY: 0.98 (water=1) at 25 C (77 F)
VISCOSITY #1: 60 Centipoise at 25 C (77 F)
10. STABILITY AND REACTIVITY
REACTIVITY: Hazardous reactions will not occur under normal transport or storage conditions.
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
CONDITIONS TO AVOID: No data available
POSSIBILITY OF HAZARDOUS REACTIONS: Reaction with peroxide may resulting violent decomposition of peroxide possibly creating
an explosion. CAUTION! N-Nitrosamines, many of which are known to be potent carcinogens, may be formed when the product comes in
contact with nitrous acid, nitrites or atmospheres with high nitrous oxide concentrations.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, nitric acid, ammonia, aldehydes,
nitrosamine, and chlorine.
INCOMPATIBLE MATERIALS: Sodium hypochlorite, organic acids, mineral acids, oxidizing agents, and nitrous acid.
11. TOXICOLOGICAL INFORMATION
ACUTE
Chemical Name ORAL LD50 DERMAL LD50
INHALATION
LC
50
Tetraethylenepentamine 2140 mg/kg > 660 mg/kg Not Established
2-piperazin-1-ylethylamine Not Established Not Established Not Established
Diethyltoluenediamine (DETDA) 738 mg/kg > 2000 mg/kg Not Established
2-Ethyl-4-methylimidazole 1000 mg/kg > 400 mg/kg Not Established
Diethylenetriamine (DETA) Not Established Not Established> 0.07 mg/l (4 h)
1h-imidazole, 5-methyl- Not Established Not Established Not Established
CHRONIC: Contains material that can cause target organ damage. Once sensitized, a severe allergic reaction may occur when subsequently
exposed to very low levels.
CARCINOGENICITY
Chemical Name
IARC
Status
1h-imidazole, 5-methyl- 2B
IARC: This product contains substances that are classified as possible carcinogens to humans.
IRRITATION: Causes severe eye and skin irritation.
CORROSIVITY: Corrosive to the eyes and skin.
SENSITIZATION: May cause sensitization by skin contact.
TARGET ORGANS: Contains material which may cause damage to the following organs: skin, eyes, respiratory system, reproductive system,
kidney, and liver.
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: This product may cause risk of hazardous effects to the environment.
ECOTOXICOLOGICAL INFORMATION: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Avoid release to the environment.
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BIOACCUMULATION/ACCUMULATION: No data available
DISTRIBUTION: No data available
CHEMICAL FATE INFORMATION: No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain
some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements
of environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION)
PROPER SHIPPING NAME: Corrosive liquids, n.o.s.
TECHNICAL NAME: (tetraethylenepentamine solution)
PRIMARY HAZARD CLASS/DIVISION: 8
UN/NA NUMBER: UN1760
PACKING GROUP: III
NAERG: 154
LABEL: Corrosive
ROAD AND RAIL (ADR/RID)
PROPER SHIPPING NAME: Corrosive liquid, n.o.s. (tetraethylenepentamine solution)
UN NUMBER: UN1760
HAZARD CLASS: 8
PACKING GROUP: III
LABEL: Corrosive
AIR (ICAO/IATA)
SHIPPING NAME: Corrosive liquid, n.o.s.
TECHNICAL NAME: (tetraethylenepentamine solution)
UN/NA NUMBER: UN1760
PRIMARY HAZARD CLASS/DIVISION: 8
PACKING GROUP: III
ERG: 8L
LABEL: Corrosive
VESSEL (IMO/IMDG)
SHIPPING NAME: Corrosive liquid, n.o.s.
TECHNICAL NAME: (tetraethylenepentamine solution)
UN/NA NUMBER: UN1760
PRIMARY HAZARD CLASS/DIVISION: 8
PACKING GROUP: III
EmS: F-A, S-B
MARINE POLLUTANT #1: Yes
LABEL: Corrosive
15. REGULATORY INFORMATION
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UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HAZARD CATEGORIES: Acute health hazard. Chronic health hazard
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section
313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
None
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPE NSATION, AND LIABILITY ACT)
CERCLA REGULATORY: For this/these chemicals, release of more than the Reportable Quantity to the environment in a 24-hour
period requires notification to the National Response Center (800-424-8802 or 202-426-2675):
None
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product contains diethyltoluenediamine (DETDA) (CAS No: 68479-98-1) which is subject to TSCA
12(b), Section 4 export notification.
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119—PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in
this product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: This product contains chemical(s) which are known to the State of California to cause cancer, birth
defects or other reproductive harm, and may be subject to the requirements of California Proposition 65 (CA Health & Safety Code
Section 25249.5):
Chemical Name Wt.% Listed
1h-imidazole, 5-methyl- 0.1 – 1 Cancer
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS HAZARD SYMBOL AND CLASSIFICATION
D2B – ToxicE – Corrosive
WHMIS CLASSIFICATION
Class D2B: Poisonous and infectious material (Toxic).
Class E: Corrosive material
WHMIS HEALTH EFFECTS CRITERIA
D2B – Eye irritation
D2B – Skin Sensitization
E – Corrosive to Skin
E – TDG Class 8 – corrosive substance
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic
Substances List (DSL) or the Non-Domestic Substances List (NDSL).
GENERAL COMMENTS: No data available
16. OTHER INFORMATION
REASON FOR ISSUE: Revised format
Date Prepared: 04/15/2015
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HMIS RATING
HEALTH * 3
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA CODES

1
3 0

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