Page 1/12
Safety Data Sheet
acc. to OSHA HCS
Printing date 04/18/2019 Reviewed on 09/11/2018
49.0
1 Identification
Product identifier
Trade name: TCC5220A Resin
Article number:I079066
Application of the substance / the mixturePolyurethane resin
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
ehs-us@axson.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
2 Hazard(s) identification
Classification of the substance or mixture
GHS08 Health hazard
Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure.
GHS07
Acute Tox. 4 H332 Harmful if inhaled.
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
STOT SE 3 H335 May cause respiratory irritation.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
(Contd. on page 2) US
Page 2/12
Safety Data Sheet
acc. to OSHA HCS
Printing date 04/18/2019 Reviewed on 09/11/2018
Trade name: TCC5220A Resin
(Contd. of page 1)
49.0
Hazard pictograms
GHS07GHS08
Signal wordDanger
Hazard-determining components of labeling:
diphenylmethanediisocyanate,isomeres and homologues
4,4′-methylenediphenyl diisocyanate
methylenediphenyl diisocyanate
Hazard statements
Harmful if inhaled.
Causes skin irritation.
Causes serious eye irritation.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause an allergic skin reaction.
May cause respiratory irritation.
May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Do not breathe dust/fume/gas/mist/vapors/spray.
Wear protective gloves / eye protection / face protection.
[In case of inadequate ventilation] wear respiratory protection.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Call a poison center/doctor if you feel unwell.
If experiencing respiratory symptoms: Call a poison center/doctor.
Wash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
2
0
0
Health = 2
Fire = 0
Reactivity = 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
*2
0
0
Health = *2
Fire = 0
Reactivity = 0
(Contd. on page 3)
US
Page 3/12
Safety Data Sheet
acc. to OSHA HCS
Printing date 04/18/2019 Reviewed on 09/11/2018
Trade name: TCC5220A Resin
(Contd. of page 2)
49.0
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 9016-87-9 diphenylmethanediisocyanate,isomeres and homologues 50-100%
CAS: 101-68-8
EINECS: 202-966-0
4,4′-methylenediphenyl diisocyanate 20-50%
CAS: 26447-40-5
EINECS: 247-714-0
methylenediphenyl diisocyanate 1-<5%
CAS: 67762-90-7 Silicones and siloxanes, dimethyl-, reaction products with silica 1-5%
4 First-aid measures
Description of first aid measures
General information:
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing:If symptoms persist consult doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray.
Use fire fighting measures that suit the environment.
(Contd. on page 4)
US
Page 4/12
Safety Data Sheet
acc. to OSHA HCS
Printing date 04/18/2019 Reviewed on 09/11/2018
Trade name: TCC5220A Resin
(Contd. of page 3)
49.0
Special hazards arising from the substance or mixture
During heating or in case of fire poisonous gases are produced.
Nitrogen oxides (NOx)
Hydrogen cyanide (HCN)
Advice for firefighters
Protective equipment:
Mouth respiratory protective device.
Wear self-contained respiratory protective device.
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
6 Accidental release measures
Personal precautions, protective equipment and emergency proceduresMount respiratory protective device.
Environmental precautions:Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
9016-87-9 diphenylmethanediisocyanate,isomeres and homologues 0.15 mg/m
101-68-8 4,4'-methylenediphenyl diisocyanate 0.45 mg/m
26447-40-5 methylenediphenyl diisocyanate 29 mg/m
67762-90-7 Silicones and siloxanes, dimethyl-, reaction products with silica 120 mg/m
PAC-2:
9016-87-9 diphenylmethanediisocyanate,isomeres and homologues 3.6 mg/m
101-68-8 4,4'-methylenediphenyl diisocyanate 5 mg/m
26447-40-5 methylenediphenyl diisocyanate 40 mg/m
67762-90-7 Silicones and siloxanes, dimethyl-, reaction products with silica 1,300 mg/m
PAC-3:
9016-87-9 diphenylmethanediisocyanate,isomeres and homologues 22 mg/m
101-68-8 4,4'-methylenediphenyl diisocyanate 55 mg/m
26447-40-5 methylenediphenyl diisocyanate 240 mg/m
67762-90-7 Silicones and siloxanes, dimethyl-, reaction products with silica 7,900 mg/m
US
(Contd. on page 5)
Page 5/12
Safety Data Sheet
acc. to OSHA HCS
Printing date 04/18/2019 Reviewed on 09/11/2018
Trade name: TCC5220A Resin
(Contd. of page 4)
49.0
7 Handling and storage
Handling:
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
Information about protection against explosions and fires:Keep respiratory protective device available.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:Keep receptacle tightly sealed.
Specific end use(s)No further relevant information available.
8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
The following constituent is the only constituent of the product which has a PEL, TLV or other recommended
exposure limit.
At this time, the other constituents have no known exposure limits.
101-68-8 4,4'-methylenediphenyl diisocyanate
PEL Ceiling limit value: 0.2 mg/m , 0.02 ppm
REL Long-term value: 0.05 mg/m , 0.005 ppm
Ceiling limit value: 0.2* mg/m , 0.02* ppm
*10-min
TLV Long-term value: 0.051 mg/m , 0.005 ppm
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
(Contd. on page 6)
US
Page 6/12
Safety Data Sheet
acc. to OSHA HCS
Printing date 04/18/2019 Reviewed on 09/11/2018
Trade name: TCC5220A Resin
(Contd. of page 5)
49.0
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Tightly sealed goggles
9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Color: Light brown
Odor: Odorless
Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range:Undetermined.
Boiling point/Boiling range:190 C (374 F)
Flash point: Not applicable.
Flammability (solid, gaseous):Not applicable.
Ignition temperature: 400 C (752 F)
Decomposition temperature: Not determined.
(Contd. on page 7)
US
Page 7/12
Safety Data Sheet
acc. to OSHA HCS
Printing date 04/18/2019 Reviewed on 09/11/2018
Trade name: TCC5220A Resin
(Contd. of page 6)
49.0
Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: 0.4 Vol %
Upper: Not determined.
Vapor pressure: Not determined.
Density at 20 C (68 F): 1.25 g/cm (10.43 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Solvent content:
VOC content: 0.00 %
0.0 g/l / 0.00 lb/gal
Solids content: 90.9 %
Other information No further relevant information available.
10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactions
Violent reactions with -NHx, -OH and -SH- groups.
In the presence of water or humidity gas (CO2) is porduced and/or uncontrolled polymerization, possibly leading
to internal pressure rises and consequent risk of container breach.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:
Nitrogen oxides
Carbon monoxide and carbon dioxide
(possible HCN)
US
(Contd. on page 8)
Page 8/12
Safety Data Sheet
acc. to OSHA HCS
Printing date 04/18/2019 Reviewed on 09/11/2018
Trade name: TCC5220A Resin
(Contd. of page 7)
49.0
11 Toxicological information
Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
Oral LD50 >5,000 mg/kg (rat)
Inhalative LC50/4 h 0.00049 mg/l (rat)
101-68-8 4,4′-methylenediphenyl diisocyanate
Oral LD50 2,200 mg/kg (mouse)
Dermal LD50 >9,400 mg/kg (rabbit)
Primary irritant effect:
on the skin:Irritant to skin and mucous membranes.
on the eye:Irritating effect.
Sensitization:
Sensitization possible through inhalation.
Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Harmful
Irritant
Carcinogenic categories
IARC (International Agency for Research on Cancer)
9016-87-9 diphenylmethanediisocyanate,isomeres and homologues 3
101-68-8 4,4′-methylenediphenyl diisocyanate 3
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
12 Ecological information
Toxicity
Aquatic toxicity:
48 hr EC50 >1,000 mg/l (daphnia)
96 hr LC50 >1,000 mg/l (Fish)
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
(Contd. on page 9)
US
Page 9/12
Safety Data Sheet
acc. to OSHA HCS
Printing date 04/18/2019 Reviewed on 09/11/2018
Trade name: TCC5220A Resin
(Contd. of page 8)
49.0
Additional ecological information:
General notes:
Water hazard class 1 (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
14 Transport information
UN-Number
DOT, ADN, IMDG, IATA not regulated
UN proper shipping name
DOT, ADN, IMDG, IATA not regulated
Transport hazard class(es)
DOT, ADN, IMDG, IATA
Class not regulated
Packing group
DOT, IMDG, IATA not regulated
Environmental hazards:
Marine pollutant: No
Special precautions for user Not applicable.
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
UN “Model Regulation”: not regulated
US
(Contd. on page 10)
Page 10/12
Safety Data Sheet
acc. to OSHA HCS
Printing date 04/18/2019 Reviewed on 09/11/2018
Trade name: TCC5220A Resin
(Contd. of page 9)
49.0
15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
9016-87-9 diphenylmethanediisocyanate,isomeres and homologues
101-68-8 4,4′-methylenediphenyl diisocyanate
TSCA (Toxic Substances Control Act): (Substances not listed)
All ingredients are listed.
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
Hazardous Air Pollutants
101-68-8 4,4′-methylenediphenyl diisocyanate
Proposition 65
Chemicals known to cause cancer:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Carcinogenic categories
EPA (Environmental Protection Agency)
9016-87-9 diphenylmethanediisocyanate,isomeres and homologues CBD
101-68-8 4,4′-methylenediphenyl diisocyanate D, CBD
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
(Contd. on page 11)
US
Page 11/12
Safety Data Sheet
acc. to OSHA HCS
Printing date 04/18/2019 Reviewed on 09/11/2018
Trade name: TCC5220A Resin
(Contd. of page 10)
49.0
Hazard pictograms
GHS07GHS08
Signal wordDanger
Hazard-determining components of labeling:
diphenylmethanediisocyanate,isomeres and homologues
4,4′-methylenediphenyl diisocyanate
methylenediphenyl diisocyanate
Hazard statements
Harmful if inhaled.
Causes skin irritation.
Causes serious eye irritation.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause an allergic skin reaction.
May cause respiratory irritation.
May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
Do not breathe dust/fume/gas/mist/vapors/spray.
Wear protective gloves / eye protection / face protection.
[In case of inadequate ventilation] wear respiratory protection.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Call a poison center/doctor if you feel unwell.
If experiencing respiratory symptoms: Call a poison center/doctor.
Wash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision09/11/2018 / 2
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
(Contd. on page 12)
US
Page 12/12
Safety Data Sheet
acc. to OSHA HCS
Printing date 04/18/2019 Reviewed on 09/11/2018
Trade name: TCC5220A Resin
(Contd. of page 11)
49.0
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Acute Tox. 4: Acute toxicity Category 4
Skin Irrit. 2: Skin corrosion/irritation Category 2
Eye Irrit. 2A: Serious eye damage/eye irritation Category 2A
Resp. Sens. 1: Respiratory sensitisation Category 1
Skin Sens. 1: Skin sensitisation Category 1
STOT SE 3: Specific target organ toxicity (single exposure) Category 3
STOT RE 2: Specific target organ toxicity (repeated exposure) Category 2
US
Page 1/8
Safety Data Sheet
acc. to OSHA HCS
Printing date 04/18/2019 Reviewed on 09/11/2018
49.0
1 Identification
Product identifier
Trade name: TCC5220B Hardener
Article number:I079067
Application of the substance / the mixturePolyurethane resin
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
ehs-us@axson.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
2 Hazard(s) identification
Classification of the substance or mixture
The product is not classified, according to the Globally Harmonized System (GHS).
Label elements
GHS label elementsVoid
Hazard pictogramsVoid
Signal wordVoid
Hazard statementsVoid
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Avoid breathing dust/fume/gas/mist/vapors/spray
Wear protective gloves/protective clothing/eye protection/face protection.
In case of inadequate ventilation wear respiratory protection.
Classification system:
NFPA ratings (scale 0 – 4)
0
1
0
Health = 0
Fire = 1
Reactivity = 0
(Contd. on page 2)
US
Page 2/8
Safety Data Sheet
acc. to OSHA HCS
Printing date 04/18/2019 Reviewed on 09/11/2018
Trade name: TCC5220B Hardener
(Contd. of page 1)
49.0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
0
1
0
Health = 0
Fire = 1
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
67762-90-7 Silicones and siloxanes, dimethyl-, reaction products with silica 1-5%
4 First-aid measures
Description of first aid measures
General information:No special measures required.
After inhalation:Supply fresh air; consult doctor in case of complaints.
After skin contact:Generally the product does not irritate the skin.
After eye contact:Rinse opened eye for several minutes under running water.
After swallowing:If symptoms persist consult doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:Use fire fighting measures that suit the environment.
Special hazards arising from the substance or mixtureNo further relevant information available.
Advice for firefighters
Protective equipment:Wear self-contained respiratory protective device.
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
US
(Contd. on page 3)
Page 3/8
Safety Data Sheet
acc. to OSHA HCS
Printing date 04/18/2019 Reviewed on 09/11/2018
Trade name: TCC5220B Hardener
(Contd. of page 2)
49.0
6 Accidental release measures
Personal precautions, protective equipment and emergency proceduresNot required.
Environmental precautions:Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
67762-90-7 Silicones and siloxanes, dimethyl-, reaction products with silica 120 mg/m
PAC-2:
67762-90-7 Silicones and siloxanes, dimethyl-, reaction products with silica 1,300 mg/m
PAC-3:
67762-90-7 Silicones and siloxanes, dimethyl-, reaction products with silica 7,900 mg/m
7 Handling and storage
Handling:
Precautions for safe handlingNo special measures required.
Information about protection against explosions and fires:No special measures required.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:None.
Specific end use(s)No further relevant information available.
8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at
the workplace.
Additional information:The lists that were valid during the creation were used as basis.
(Contd. on page 4)
US
Page 4/8
Safety Data Sheet
acc. to OSHA HCS
Printing date 04/18/2019 Reviewed on 09/11/2018
Trade name: TCC5220B Hardener
(Contd. of page 3)
49.0
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
The usual precautionary measures for handling chemicals should be followed.
Breathing equipment:Not required.
Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:Goggles recommended during refilling.
9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Color: Red
Odor: Odorless
Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range:Undetermined.
Boiling point/Boiling range:Undetermined.
Flash point: 104 C (219.2 F)
Flammability (solid, gaseous):Not applicable.
Decomposition temperature: Not determined.
Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: Not determined.
(Contd. on page 5)
US
Page 5/8
Safety Data Sheet
acc. to OSHA HCS
Printing date 04/18/2019 Reviewed on 09/11/2018
Trade name: TCC5220B Hardener
(Contd. of page 4)
49.0
Upper: Not determined.
Vapor pressure: Not determined.
Density at 20 C (68 F): 1.07 g/cm (8.93 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Solvent content:
VOC content: 0.00 %
0.0 g/l / 0.00 lb/gal
Solids content: 5.5 %
Other information No further relevant information available.
10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:Carbon monoxide and carbon dioxide
11 Toxicological information
Information on toxicological effects
Acute toxicity:
Primary irritant effect:
on the skin:No irritant effect.
on the eye:No irritating effect.
Sensitization:No sensitizing effects known.
Additional toxicological information:
The product is not subject to classification according to internally approved calculation methods for
preparations:
(Contd. on page 6)
US
Page 6/8
Safety Data Sheet
acc. to OSHA HCS
Printing date 04/18/2019 Reviewed on 09/11/2018
Trade name: TCC5220B Hardener
(Contd. of page 5)
49.0
When used and handled according to specifications, the product does not have any harmful effects according to
our experience and the information provided to us.
Carcinogenic categories
IARC (International Agency for Research on Cancer)
1318-02-1 zeolites 3
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
12 Ecological information
Toxicity
Aquatic toxicity:No further relevant information available.
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Additional ecological information:
General notes:
Water hazard class 1 (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
13 Disposal considerations
Waste treatment methods
Recommendation:Smaller quantities can be disposed of with household waste.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
14 Transport information
UN-Number
DOT, ADN, IMDG, IATA not regulated
(Contd. on page 7)
US
Page 7/8
Safety Data Sheet
acc. to OSHA HCS
Printing date 04/18/2019 Reviewed on 09/11/2018
Trade name: TCC5220B Hardener
(Contd. of page 6)
49.0
UN proper shipping name
DOT, ADN, IMDG, IATA not regulated
Transport hazard class(es)
DOT, ADN, IMDG, IATA
Class not regulated
Packing group
DOT, IMDG, IATA not regulated
Environmental hazards:
Marine pollutant: No
Special precautions for user Not applicable.
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
UN “Model Regulation”: not regulated
15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
TSCA (Toxic Substances Control Act): (Substances not listed)
All ingredients are listed.
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
Hazardous Air Pollutants
None of the ingredients is listed.
Proposition 65
Chemicals known to cause cancer:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
(Contd. on page 8)
US
Page 8/8
Safety Data Sheet
acc. to OSHA HCS
Printing date 04/18/2019 Reviewed on 09/11/2018
Trade name: TCC5220B Hardener
(Contd. of page 7)
49.0
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Carcinogenic categories
EPA (Environmental Protection Agency)
None of the ingredients is listed.
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsVoid
Hazard pictogramsVoid
Signal wordVoid
Hazard statementsVoid
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision09/11/2018 / 1
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
US