SAFETY DATA SHEET
Last Revised: 08SEP22
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: ……………………………………… PRO-SET
ADV-273-QC HARDENER
APPLICABLE PRODUCT CODE S: ………………. ADV-273-QC, ADV-273-QC-0, ADV-273-QC-1, ADV-273-QC-2, ADV-273-QC-4
CHEMICAL FAMILY: ………………………………….. Polyamine mixture.
INTENDED PRODUCT USES: ……………………… Curing agent for epoxy adhesive resins.
PRODUCT RESTRICTIONS: ……………………….. None identified.
SDS VERSION: …………………………………………. ADV-273-QC-2022b
MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS):
Gougeon Brothers, Inc. Transportation
100 Patterson Ave. CHEMTREC: ……………….. 800-424-9300 (U.S.)
Bay City, MI 48706, U.S.A. 703-527-3887 (International)
Phone: 888-377-6738 or 989-684-7286 Non-transportation
www.prosetepoxy.com Poison Hotline: 800-222-1222
2. HAZARDS IDENTIFICATION
Classification of Substance or Mixture
Acute toxicity Oral, Category 4
Acute toxicity Inhalation, Category 4
Skin corrosion/irritation, Category 1B
Respiratory sensitizer, Category 1
Skin sensitizer, Category 1
Eye damage/irritation, Category 1
Germ cell mutagenicity, Category 2
Reproductive toxicity, Category 2
Specific target organ toxicity single exposure, Category 3
Specific target organ toxicity repeated exposure, Category 2
Acute aquatic toxicity, Category 2
Chronic aquatic toxicity, Category 2
Label Elements
Hazard Pictogram(s):
Signal Word:
DANGER
Hazard Statements:
H302 Harmful if swallowed
H332 Harmful if inhaled
H314 Causes severe skin burns and eye damage
H317 May cause an allergic skin reaction
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335 May cause respiratory irritation
H341 Suspected of causing genetic defects
H361 Suspected of damaging fertility or the unborn child
H373 May cause damage to organs through prolonged or repeated exposure
H411 Toxic to aquatic life with long lasting effects
Precautionary Statements:
Prevention
P201 Obtain special instruction before use
P202 Do not handle until all safety precautions have been read and understood
P260 Do not breathe dusts/fumes/gas/mists/vapors/spray
P264 Wash hands thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P271 Use only outdoors or in a well ventilated area
P272 Contaminated work clothing should not be allowed out of the workplace
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection
P284 In case of inadequate ventilation wear respiratory protection
Response
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P301 + P330 + 331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse or wash skin with soap and water (or
shower).
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical attention or advice
P310 Immediately call a POISON CONTROL CENTER or doctor
P333 + P313 If skin irritation or rash occurs: Get medical attention/advice
P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor
P362 + P364 Take off contaminated clothing and wash it before reuse.
P391 Collect spillage
Storage
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
Disposal
P501 Dispose of contents and container according to local, state, national and International regulations
Other Hazards
None known.
3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS
INGREDIENT NAME CAS # CONCENTRATION (%)
Triethylenetetramine, reaction products with phenol and formaldehyde 32610-77-8 10-30
Benzyl alcohol 100-51-6 10-30
“Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy-, ether with
2,2-bis(hydroxymethyl)-1,3-propanediol (4:1), 2-hydroxy-3-mercaptopropyl ether”
72244-98-5 10-30
Triethylenetetramine 112-24-3 1-7
Fatty acids, C18-unsat’d., dimerms, reaction products with 1-
piperazineethanamine and tall oil
206565-89-1 5-10
Benzene-1,3-dimethanamine, reaction products with phenol and formaldehyde 57214-10-5 3-7
Synthetic amorphous, pyrogenic silica 112945-52-5 5-10
2-Piperazin-1-yiethylamine 140-31-8 5-10
Hydroxybenzene 108-95-2 1-10
Polymer of epichlorohydrin / bisphenol A and diethylenetriamine 31326-29-1 1-5
Polyoxypropylenediamine 9046-10-0 1-10
4-tert-butylphenol 98-54-4 1-10
Benzene-1,3-dimethanamine 1477-55-0 1-5
Diethylenetriamine 111-40-0 0.5-1.5
The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information (CBI).
Any ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may be present
at a level below its disclosure threshold.
4. FIRST AID MEASURES
FIRST AID FOR EYES ……………………………………………………………… SYMPTOMS: Causes eye burns and eye damage. RESPONSE: Flush
immediately with water for at least 15 minutes. Remove contact lenses if present and easy to do. Immediately call a POISON CONTROL CENTER
or doctor.
FIRST AID FOR SKIN ………………………………………………………………. SYMPTOMS: Causes skin burns, redness and irritation. May cause allergic
skin reaction and sensitization. RESPONSE: Immediately wash skin with soap and water. Immediately call a POISON CONTROL CENTER or
doctor.
FIRST AID FOR INHALATION…………………………………………………… SYMPTOMS: Can cause respiratory irritation, shortness of breath or cough.
May give off gas, vapor or mist that is very irritating or corrosive to the respiratory system. May cause allergy, asthma symptoms or breathing
difficulties if inhaled. Serious effects may be delayed following exposure. RESPONSE: Remove to fresh air if effects occur and keep comfortable
for breathing. Immediately call a POISON CONTROL CENTER or doctor if symptoms develop and persist.
FIRST AID FOR INGESTION …………………………………………………….. SYMPTOMS: May cause gastrointestinal irritation or ulceration. May
cause burns of the mouth and throat. RESPONSE: Rinse mouth with water. DO NOT induce vomiting. If vomiting should occur, keep airway
clear. Immediately call POISON CONTROL CENTER or doctor.
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5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: ………………………………………………………… SUITABLE: Foam, carbon dioxide (CO2), dry chemical. NON-SUITABLE:
Direct, hight-pressure water stream.
FIRE AND EXPLOSION HAZARDS: ………………………………………….. During a fire, smoke may contain the original materials in addition to
combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to: oxides
of nitrogen, carbon monoxide, carbon dioxide, volatile amines, ammonia, nitric acid, aldehydes, nitrosamines. When mixed with sawdust, wood
chips, or other cellulosic material, spontaneous combustion can occur under certain conditions. Heat is generated as the air oxidizes the amine. If
the heat is not dissipated quickly enough, it can ignite the sawdust.
SPECIAL FIRE FIGHTING PROCEDURES: ………………………………… Use full-body protective gear and a self-contained breathing apparatus.
Use of water may generate toxic aqueous solutions. Do not allow water run-off from fighting fire to enter drains or other water courses.
6. ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES : …………………………………………………. Keep unnecessary and unprotected personnel from entering area. Use
appropriate safety and personal protective equipment as indicated in Section 8.
MITIGATION AND CLEAN UP PROCEDURES: …………………………… Stop leak without additional risk. Isolate area. Dike and absorb with inert
material (e.g., sand) and collect in a suitable, closed container. Do not use sawdust, wood chips or other cellulosic materials to absorb the spill, as
the possibility for spontaneous combustion exists. Warm, soapy water may be used to clean residual.
ENVIRONMENTAL PRECAUTIONS: ………………………………………….. Prevent from entering into soil, ditches, sewers, waterways and
groundwater. See Section 12 for environmental impact information.
7. HANDLING AND STORAGE
STORAGE TEMPERATURE (min./max.): …………………………………… 40 F (4 C) / 90 F (32 C).
STORAGE: …………………………………………………………………………….. Store in a cool, dry and well-ventilated place away from high temperatures
and moisture. Keep container tightly closed. Store in a secure location with restricted access or store locked up.
HANDLING PRECAUTIONS: ……………………………………………………. Do not handle until all safety precautions have been read and understood.
Use only with adequate ventilation. Do not breathe vapors or mists from heated material. Avoid exposure to concentrated vapors. Avoid skin and
eye contact. Wash thoroughly after handling. When mixed with epoxy resin this product causes an exothermic reaction, which in large masses,
can produce enough heat to damage or ignite surrounding materials and emit fumes and vapors that vary widely in composition and toxicity.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: ……………………………………………………. Use with adequate general ventilation and/or local ventilation to keep
exposures below established limits.
EYE PROTECTION GUIDELINES: …………………………………………….. Chemical splash-proof goggles or face shield.
SKIN PROTECTION GUIDELINES: ……………………………………………. Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, neoprene,
butyl rubber or natural rubber) and full body-covering clothing. Persons with a history of skin sensitization problems may need to avoid using this
product entirely.
RESPIRATORY PROTECTION GUIDELINES: …………………………….. When ventilation cannot be made adequate enough to keep exposures
below established limits, use a NIOSH approved respirator with an organic vapor cartridge, organic vapor cartridge + P100, or a multi-contaminant
cartridge, depending on specific workplace conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator
and cartridge based on ingredients listed in Section 3 and specific workplace conditions. Use and select a respirator according the guidelines
established in OSHA 1910.134 or other applicable respiratory protection standard. Persons with a history of asthma, allergies or chronic or
recurrent respiratory disease should not be employed in any process in which this product is used.
ADDITIONAL PROTECTIVE MEASURES: ………………………………….. Use where there is immediate access to safety shower and emergency eye
wash. Wash thoroughly after use. Contact lens should not be worn when working with this material. Generally speaking, working cleanly and
following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use conditions.
OCCUPATIONAL EXPOSURE LIMITS: ……………………………………… Exposure limits may not be established for this product as a whole. For
established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.
Ingredient Name CAS# Exposure Limit Information
Triethylenetetramine, reaction products with
phenol and formaldehyde
32610-77-8
No data available
Benzyl alcohol 100-51-6 10 ppm TWA (WEEL)
“Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-
.omega.-hydroxy-, ether with 2,2-
bis(hydroxymethyl)-1,3-propanediol (4:1), 2-
hydroxy-3-mercaptopropyl ether”
72244-98-5 No data available
Triethylenetetramine 112-24-3 AIHA WEEL: 1 ppm ; 6 mg/ m
3
; Absorbed via skin
Fatty acids, C18-unsat’d., dimerms, reaction 206565-89-1 No data available
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products with 1-piperazineethanamine and tall oil
Benzene-1,3-dimethanamine, reaction products
with phenol and formaldehyde
57214-10-5
No data available
Synthetic amorphous, pyrogenic silica 112945-52-5 Amorphous silica: OSHA PEL 6 mg/m
3
Dust and PNOS: ACGIH 10mg/m
3
, TWA, Inhalable; 3
mg/m
3
, TWA, Respirable; OSHA PEL 15 mg/m
3
, TWA, total
dust; 5 mg/m
3
, TWA, Respirable
2-Piperazin-1-yiethylamine 140-31-8 No data available
Hydroxybenzene 108-95-2 ACGIH TWA: 5 ppm; 19 mg/kg
NIOSH REL: 5 ppm; 19 mg/kg
OSHA PEL: 5 ppm; 19 mg/kg
NIOSH CEILING: 15.6 ppm; 60 mg/kg
Polymer of epichlorohydrin / bisphenol A and
diethylenetriamine
31326-29-1
No data available (reference Diethylenetriamine)
Polyoxypropylenediamine 9046-10-0 No data available
4-tert-butylphenol 98-54-4 No data available
Benzene-1,3-dimethanamine 1477-55-0 NIOSH CEILING: 0.1 mg/m3; Remarks: Potential for dermal
absorption.
ACGIH TLV CEILING: 0.1 mg/m3; SKIN
OSHA CEILING: 0.1 mg/m3; Table Z 1A
Diethylenetriamine 111-40-0 ACGIH TWA 1ppm; SKIN
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL FORM: ………………………………………………………………….. Gel.
COLOR: ………………………………………………………………………………… Blue.
ODOR: …………………………………………………………………………………… Ammonia-like
ODOR THRESHOLD: ………………………………………………………………. No data available
pH …………………………………………………………………………………………. 11.2
MELTING POINT / FREEZING POINT ………………………………………… No data.
BOILING POINT (760mm/Hg): ………………………………………………….. > 400 F (204 C) estimated based on similar product.
FLASH POINT: ……………………………………………………………………….. Estimated > 200
F (93 C) estimated based similar product.
AUTO IGNITION TEMPERATURE ……………………………………………… No data.
LOWER EXPLOSIVE LIMIT (LEL) ……………………………………………… No data.
UPPER EXPLOSIVE LIMIT (UEL) ……………………………………………… No data.
VAPOR PRESSURE ………………………………………………………………… < 1 mmHg @ 20 C (estimated based on ingredient data).
SPECIFIC GRAVITY/DENSITY (water = 1)......................................... 1.05
BULK DENSITY.................................................................................. 8.75 lbs./gal. (1.05kg/L)
VAPOR DENSITY (air = 1) ................................................................. No data.
EVAPORATIOIN RATE (Butyl Acetate = 1) ....................................... No data.
WATER SOLUBILITY (% BY WT.) ..................................................... No data.
PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ............ No data.
KINEMATIC VISCOSITY: ................................................................... Gel. (mm
2
/s @ 20
C)
DECOMPOSITION TEMPERATURE : ................................................. No data available.
% VOLATILE BY WEIGHT: ................................................................ ASTM 2369-07 was used to determine the Volatile Matter Content of mixed
epoxy resin and hardener. The combined VOC content for the resin and hardener system is listed below.
VOC Content
Resin/Hardener (g/L) (lb/gal)
ADV-175 / ADV-273 .................................................................... 8.65 0.07
10. STABILITY AND REACTIVITY
STABILITY: ........................................................................................ Product is stable at normal temperatures and pressures.
REACTIVITY/HAZARDOUS REACTIONS : ......................................... Product will not react by itself. A mass of more than one pound of product
plus an epoxy resin will cause irreversible polymerization with significant heat buildup and pressure.
INCOMPATIBILITIES: ........................................................................ Avoid acids, oxidizing materials, halogenated organic compounds (e.g.,
methylene chloride). External heating could result in rapid temperature increase and pressure build up. If such a condition were to occur in a
drum, the drum could expand and rupture violently.
CONDITIONS TO AVOID: .................................................................. Avoid heating or processing at temperatures greater than 120
F (48
C).
DECOMPOSITION PRODUCTS: ........................................................ Very toxic fumes and gases when burned or otherwise heated to
decomposition. Decomposition products may include, but not limited to: oxides of nitrogen, carbon monoxide, carbon dioxide, volatile amines,
ammonia, nitric acid, aldehydes, nitrosamines.
11. TOXICOLOGICAL INFORMATION
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Ingredient Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation
Triethylenetetramine, reaction products with
phenol and formaldehyde
32610-77-8
No data available No data available No data available
Benzyl alcohol
100-51-6
1620 mg/kg
No data available
>4.18 mg/l
4h aerosol
“Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-
.omega.-hydroxy-, ether with 2,2-
bis(hydroxymethyl)-1,3-propanediol (4:1), 2-
hydroxy-3-mercaptopropyl ether”
72244-98-5 No data available No data available No data available
Triethylenetetramine 112-24-3 1716 mg/kg 1465 mg/kg No data
Fatty acids, C18-unsat’d., dimerms, reaction
products with 1-piperazineethanamine and tall oil
206565-89-1
No data available
No data available
No data available
Benzene-1,3-dimethanamine, reaction products
with phenol and formaldehyde
57214-10-5
No data available
No data available
No data available
Synthetic amorphous, pyrogenic silica 112945-52-5 >5000 mg/kg >2000 mg/kg No data available
2-Piperazin-1-yiethylamine 140-31-8 2097 mg/kg 866 mg/kg No data
Hydroxybenzene 108-95-2 317 mg/kg 630 mg/kg (solid) 900 mg/m3; 8h (solid)
Polymer of epichlorohydrin / bisphenol A and
diethylenetriamine
31326-29-1
1620 mg/kg
No data available
No data available
Polyoxypropylenediamine 9046-10-0 3069 mg/kg ATE 3170 mg/kg ATE >0.74
4-tert-butylphenol 98-54-4 >2000 mg/kg No data available No data available
Benzene-1,3-dimethanamine 1477-55-0 980 mg/kg 2000 mg/kg 1.34 mg/l 4h dust/mist
Diethylenetriamine
111-40-0
1080 mg/kg
1090 mg/kg
0.07-0.3 mg/l 4h
mist/aerosol
ACUTE TOXICITY: ………………………………………………………………….. No specific toxicity data exists for this mixture. Classification is
based on acute toxicity estimation methods using ingredient data.
Oral: ……………………………………………………………………….. Category 4. Harmful if swallowed .
Dermal: …………………………………………………………………… Not classified. Based on available data this product does not
meet classification criteria. However, product contains materials that are readily absorbed through the skin. Absorption of phenolic
solutions through the skin may be very rapid and can cause damage to the kidneys, liver, pancreas, spleen, and cause edema of the
lungs.
Inhalation:………………………………………………………………… Category 4. Harmful if inhaled. Can cause respiratory irritation,
shortness of breath or cough. May give off gas, vapor or mist that is very irritating or corrosive to the respiratory system.
SKIN CORROSION / IRRITATION: …………………………………………….. Category 1B. Causes severe skin burns.
SERIOUS EYE DAMAGE / IRRITATION:…………………………………….. Category 1. Causes serious eye damage. May cause blurred
vision. May cause corneal damage resulting in vision impairment or even blindness.
RESPIRATORY SENSITIZATION : ……………………………………………… Category 1. A component in this product is reported to cause
allergy, asthma symptoms or breathing difficulties if inhaled. Serious effects may be delayed following exposure.
SKIN SENSITIZATION:…………………………………………………………….. Category 1. May cause allergic skin reaction.
REPRODUCTIVE TOXICITY: …………………………………………………….. Category 2. This product contains a substance that is suspected of
damaging fertility of the unborn child.
MUTAGENICITY: …………………………………………………………………….. Category 2. This product contains a substance (phenol, CAS# 108-95-2)
that is suspected of causing genetic defects.
CARCINOGENICITY: ……………………………………………………………….. Not classified. Based on available data this product does not meet
classification criteria.
SPECIFIC TARGET ORGAN TOXICITY (Single Exposure): ………….. Category 3. This product contains a substance that may cause respiratory if
inhaled.
SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure): …….. STOT Category 2. Product contains materials that are readily absorbed
through the skin. Absorption of phenolic solutions through the skin may be very rapid and can cause damage to the kidneys, liver, pancreas,
spleen, and cause edema of the lungs.
ASPIRATION HAZARD : …………………………………………………………… Not classified. Based on available data this product does not meet
classification criteria.
OTHER HEALTH HAZARD INFORMATION : ……………………………….. This product contains a component (diethylenetriamine) that is highly toxic
by inhalation when aerosolized due to spraying or when a mist is formed due to heating. It is advised that exposure not occur to product that is
sprayed or heated. While this product does not meet the classification for a respiratory sensitizer, components of this product can cause
aggravation of existing respiratory conditions, such as asthma.
12. ECOLOGICAL INFORMATION
ACUTE AQUATIC TOXICITY :……………………………………………………. Aquatic Acute Category 2. Calculated Estimate. No specific test
data available for the mixture. Toxic to aquatic life. Avoid release to the environment.
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CHRONIC AQUATIC TOXICITY : ……………………………………………….. Aquatic Chronic Category 2. Calculated Estimate. No specific
test data available for the mixture. Toxic to aquatic life with long lasting effects. Avoid release to the environment.
PERSISTANCE AND BIODEGRADABILITY : ………………………………. No specific test data available for the mixture.
MOBILITY IN SOIL: …………………………………………………………………. No specific test data available for the mixture.
ADDITIONAL ECOTOXICITY INFORMATION : …………………………….. In the liquid, uncured state, this product may be harmful to
aquatic life with long lasting effects. Prevent release to the environment, sewers and natural waters.
Ingredient CAS# Ecotoxicity Classification Information
Triethylenetetramine, reaction products with phenol and
formaldehyde
32610-77-8
Aquatic Chronic Cat. 3
Benzyl alcohol
100-51-6
No data available
“Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-
hydroxy-, ether with 2,2-bis(hydroxymethyl)-1,3-propanediol
(4:1), 2-hydroxy-3-mercaptopropyl ether”
72244-98-5 No data available
Triethylenetetramine 112-24-3 Aquatic Chronic Cat. 3
Fatty acids, C18-unsat’d., dimerms, reaction products with
1-piperazineethanamine and tall oil
206565-89-1
Acute Aquatic Cat. 1; Chronic Aquatic Cat. 1
Benzene-1,3-dimethanamine, reaction products with phenol
and formaldehyde
57214-10-5
Acute Aquatic Cat. 1; Chronic Aquatic Cat. 1
Synthetic amorphous, pyrogenic silica 112945-52-5 No data available
2-Piperazin-1-yiethylamine 140-31-8 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
Hydroxybenzene
108-95-2
Acute Aquatic Cat. 3; Chronic Aquatic Cat. 2
Polymer of epichlorohydrin / bisphenol A and
diethylenetriamine
31326-29-1
No data available
Polyoxypropylenediamine 9046-10-0 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
4-tert-butylphenol 98-54-4 Acute Aquatic Cat. 2; Chronic Aquatic Cat. 1
Benzene-1,3-dimethanamine 1477-55-0 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
Diethylenetriamine 111-40-0 No data available
13. DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: ………………………………………………….. Evaluation of this product using RCRA criteria shows that it is not a
hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal
methods.
Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations.
14. TRANSPORTATION INFORMATION
US DOT
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Triethylenetetramine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
MARINE POLLUTANT: …………………………………………………………….. No
CANADA TDG
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Triethylenetetramine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
MARINE POLLUTANT: …………………………………………………………….. No
IMDG
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Triethylenetetramine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
EmS Number: ………………………………………………………………………… F-A, S-B
MARINE POLLUTANT ……………………………………………………………… Yes
ICAO/IATA
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
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TECHNICAL SHIPPING NAME: …………………………………………………. Triethylenetetramine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
MARINE POLLUTANT: …………………………………………………………….. Yes
15. REGULATORY INFORMATION
COUNTRY INVENTORY LIST STATUS
United States TSCA All ingredients are listed or otherwise compliant.
Europe EINECS (or REACH) No data on CAS# 57214-10-5. All other ingredients are listed or otherwise compliant.
Canada CEPA (DSL/NDSL) No data on CAS# 206565-89-1. All other ingredients are listed or otherwise compliant.
Australia AICS No data on CAS# 206565-89-1. All other ingredients are listed or otherwise compliant.
Japan ENCS No data on CAS# 206565-89-1. All other ingredients are listed or otherwise compliant.
South Korea KECI No data on CAS# 206565-89-1. All other ingredients are listed or otherwise compliant.
China IECSC All ingredients are listed or otherwise compliant.
Philippines PICCS No data on CAS# 57214-10-5 and 206565-89-1. All other ingredients are listed or
otherwise compliant.
US EPA TSCA Requirements: ………………………………………………….. Reference a TSCA SNUR for CAS# 206565-89-1.
Canada WHMIS Confidential Business Information (CBI): …….. No data available.
US EPA SARA TITLE III Reporting and Notification Requirements:
Subject to Section 302 (TPQ) ……………………………………………… Phenol = 500/1000 (lbs.). TPQ = 500 lbs. if phenol is in powder form and
has a particle size of less than 100 microns or is handled in solution or molten form, or meets the criteria for a NFPA reactivity rating of 2, 3,
or 4.
Subject to Section 304 (RQ) ……………………………………………….. Phenol RQ = 1000 lbs.
Subject to Section 311 or 312 …………………………………………….. Refer to the health and physical classifications in Section 2.
Subject to Section 313 ………………………………………………………. This product contains hydroxybenzene (phenol) and is subject to the
reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
US STATE REGULATORY INFORMATION:
The following chemicals may be specifically regulated by individual states. For details on state regulatory requirements you should contact the
appropriate state agency.
COMPONENT NAME
/CAS NUMBER CONCENTRATION STATE CODE
Benzene-1,3-dimethanamine
1477-55-0 MA, PA, NJ
Hydroxybenzene
108-95-2 PA, MA, NJ, IL, RI
Diethylenetriamine
111-40-0 PA
Triethylenetetramine
112-14-3 PA, MA,
Amorphous silica
7631-86-9 or 112945-52-5 PA, NJ, MA
2-Piperazin-1-yiethylamine
140-31-8 MA, PA, NJ
4-tert-butylphenol
98-54-4 PA, NJ
16. OTHER INFORMATION
REASON FOR ISSUE:……………………………………………………………… Changes to Section 1.
PREPARED BY: ……………………………………………………………………… Gougeon Brothers, Inc.
TITLE: …………………………………………………………………………………… Health, Safety & Environmental Manager
APPROVAL DATE: …………………………………………………………………. September 8, 2022
SUPERSEDES DATE: ……………………………………………………………… January 14, 2022
SDS VERSION: ………………………………………………………………………. ADV-273-QC-2022b
OTHER HAZARD INFORMATION AND RATING SYSTEMS:
HMIS RATING NFPA 704 CODES
PRO-SET
ADV-273-QC HARDENER
Page 8 of 8 Last Revised: 08SEP22
HEALTH: 3
FLAMMABILITY: 1
PHYSICAL HAZARD: 0
PERSONAL PROTECTION:
Approximate HMIS and NFPA Risk Ratings Legend:
0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe
Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers,
Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or
reliance upon these data.
3 0
1
2