23PA133PMMN5_SDS.pdf

by | Sep 27, 2025

COR-Grip Cmpd
Unsaturated Polyester Resin Adhesive
Liquid.
SAFETY DATA SHEET
GHS product identifier
Other means of identification
Product type
Emergency telephone
number (with hours of
operation)
Section 1. Identification
:
:
:
:
Supplier’s details :INTERPLASTIC CORPORATION
1225 Willow Lake Boulevard
St. Paul, MN 55110-5145
651.481.6860
COR-Grip Cmpd
Relevant identified uses of the substance or mixture and uses advised against
Product code :PA-133-PMMN
Industrial applications.
CHEMTREC 24-Hour Emergency Telephone
US and Canada 800.424.9300
Outside US and Canada +1 703.741.5970
Section 2. Hazards identification
FLAMMABLE LIQUIDS – Category 3
ACUTE TOXICITY (inhalation) – Category 4
SKIN IRRITATION – Category 2
EYE IRRITATION – Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) – Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs,
respiratory system) – Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard statements :Flammable liquid and vapor.
Harmful if inhaled.
Causes serious eye irritation.
Causes skin irritation.
May cause respiratory irritation.
Causes damage to organs through prolonged or repeated exposure. (hearing organs,
respiratory system)
Hazard pictograms :
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown oral toxicity: 10.4%
Percentage of the mixture consisting of ingredient(s) of unknown dermal toxicity: 47.1%
Percentage of the mixture consisting of ingredient(s) of unknown inhalation toxicity: 21.
2%
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Date of issue/Date of revision :1/27/2021 Date of previous issue :6/3/2019 Version:2 1/14

COR-Grip Cmpd PA-133-PMMN
Section 2. Hazards identification
Precautionary statements
Prevention :Wear protective gloves. Wear eye or face protection. Keep away from heat, hot
surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-
proof electrical, ventilating, lighting and all material-handling equipment. Use only non-
sparking tools. Take precautionary measures against static discharge. Keep container
tightly closed. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Do
not eat, drink or smoke when using this product. Wash hands thoroughly after handling.
Response :Get medical attention if you feel unwell. IF INHALED: Remove person to fresh air and
keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell.
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water or shower. IF ON SKIN: Wash with plenty of soap and water. Take off
contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical
attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get
medical attention.
Storage :Store in a well-ventilated place. Keep cool. Store containers in a safe place.
Disposal :Dispose of contents and container in accordance with all local, regional, national and
international regulations. Do not pressurize, cut, weld, braze, solder, drill, grind or
expose containers to heat or sources of ignition.
Hazards not otherwise
classified
:None known.
Section 3. Composition/information on ingredients
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Other means of
identification
:Unsaturated Polyester Resin Adhesive
Substance/mixture :
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Any concentration shown as exact is based on formula.
VOC content is listed in Section 9.
Environmental composition is shown in Section 15.
styrene <= 26.0 100-42-5 Man-made mineral fibers <= 20.0 65997-17-3 talc (none asbestiform) <= 15.0 14807-96-6 Ingredient name % CAS number Section 4. First aid measures Eye contact : Description of necessary first aid measures Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Buffered baby shampoo will aid in removal of resin. Date of issue/Date of revision :1/27/2021 Date of previous issue :6/3/2019 Version:2 2/14 COR-Grip Cmpd PA-133-PMMN Section 4. First aid measures Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention following exposure or if feeling unwell. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Remove contaminated clothing and shoes. Flush contaminated skin with plenty of water. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Skin contact Inhalation Ingestion : : : Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments :No specific treatment. Most important symptoms/effects, acute and delayed Inhalation :Harmful if inhaled. May cause respiratory irritation. No known significant effects or critical hazards.:Ingestion Skin contact :Causes skin irritation. Causes serious eye irritation.:Eye contact Over-exposure signs/symptoms Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing No specific data. Adverse symptoms may include the following: irritation redness : : : Eye contact :Adverse symptoms may include the following: pain or irritation watering redness Potential acute health effects See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Date of issue/Date of revision :1/27/2021 Date of previous issue :6/3/2019 Version:2 3/14 COR-Grip Cmpd PA-133-PMMN Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide metal oxide/oxides Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use dry chemical, CO , water spray (fog) or foam. Extinguishing media : : : Do not use water jet. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures : :No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Contain and collect spillage with non- combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Wear appropriate respiratory protection. Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. Absorb with an inert material and transfer the spilled material and absorbent to an appropriate waste disposal container. Wear appropriate respirator when ventilation is inadequate. Wear eye/face protection. Date of issue/Date of revision :1/27/2021 Date of previous issue :6/3/2019 Version:2 4/14 COR-Grip Cmpd PA-133-PMMN Section 6. Accidental release measures Wear protective clothing and eye or face protection: Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Do not store above the following temperature: 38 C (100.4 F). Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. Store containers in a safe place. : : Protective measures Put on appropriate personal protective equipment (see Section 8). Do not breathe vapor or mist. Do not ingest. Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. : Precautions for safe handling styrene ACGIH TLV (United States, 3/2019). TWA: 20 ppm 8 hours. STEL: 40 ppm 15 minutes. OSHA PEL 1989 (United States, 3/1989). TWA: 50 ppm 8 hours. TWA: 215 mg/m 8 hours. STEL: 100 ppm 15 minutes. STEL: 425 mg/m 15 minutes. OSHA PEL Z2 (United States, 2/2013). TWA: 100 ppm 8 hours. CEIL: 200 ppm AMP: 600 ppm 5 minutes. NIOSH REL (United States, 10/2016). TWA: 50 ppm 10 hours. TWA: 215 mg/m 10 hours. STEL: 100 ppm 15 minutes. STEL: 425 mg/m 15 minutes. Man-made mineral fibers NIOSH REL (United States, 10/2016). TWA: 3 f/cc 10 hours. Form: Fibers of spec length Section 8. Exposure controls/personal protection Ingredient name Exposure limits Control parameters Occupational exposure limits Date of issue/Date of revision :1/27/2021 Date of previous issue :6/3/2019 Version:2 5/14 COR-Grip Cmpd PA-133-PMMN Section 8. Exposure controls/personal protection TWA: 3 f/cc 10 hours. TWA: 5 mg/m 10 hours. Form: Total ACGIH TLV (United States, 3/2019). TWA: 5 mg/m 8 hours. Form: Inhalable fraction TWA: 1 f/cc 8 hours. Form: Respirable fibers: length greater than 5 uM; aspect ratio equal to or greater than 3:1 as determined by the membrane filter method at 400-450X magnification (4-mm objective) phase contrast illumination. talc (none asbestiform) OSHA PEL 1989 (United States, 3/1989). TWA: 2 mg/m 8 hours. Form: Respirable dust NIOSH REL (United States, 10/2016). TWA: 2 mg/m 10 hours. Form: Respirable fraction ACGIH TLV (United States, 3/2019). TWA: 2 mg/m 8 hours. Form: Respirable fraction Hand protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Environmental exposure controls :Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls :Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Other skin protection :Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Date of issue/Date of revision :1/27/2021 Date of previous issue :6/3/2019 Version:2 6/14 COR-Grip Cmpd PA-133-PMMN Section 9. Physical and chemical properties Physical state Melting point Vapor pressure Relative density Vapor density Solubility Liquid. Not available. 0.9 to 1.3 3.6 [Air = 1] 0.67 kPa (5 mm Hg) [room temperature] Not available. Sweetish.Odor pH Tan. [Light]Color Evaporation rate <1 (butyl acetate = 1) Auto-ignition temperature Flash point Not available. Closed cup: 31 C (87.8 F) Not available. Not applicable. Viscosity Not available. 0.1 ppmOdor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance Boiling point :145 C (293 F) Lower and upper explosive (flammable) limits :Lower: 0.9% Upper: 6.8% Solubility in water :Not applicable. VOC content :25.9 % (w/w) As shipped, including monomers and additives. Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability Reactive or incompatible with the following materials: oxidizing materials : : : Incompatible materials : Possibility of hazardous reactions :Hazardous reactions or instability may occur under certain conditions of storage or use. Reactivity :No specific test data related to reactivity available for this product or its ingredients. Polymerization may occur under certain conditions of storage and use. Keep away from heat and flame. Keep away from oxidizing agents. Reactive or incompatible with the following materials: acids and alkalis. Incompatible with alkali metals. Incompatible with some alkalis. Incompatible with some strong acids. Date of issue/Date of revision :1/27/2021 Date of previous issue :6/3/2019 Version:2 7/14 COR-Grip Cmpd PA-133-PMMN Section 11. Toxicological information Acute toxicity styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours LC50 Inhalation Vapor Rat 11800 mg/m 4 hours LD50 Oral Rat 2650 mg/kg - Product/ingredient name Result Species Dose Exposure Carcinogenicity Not available. Conclusion/Summary : Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. Irritation/Corrosion styrene Eyes - Mild irritant Human - 50 ppm - Eyes - Moderate irritantRabbit - 24 hours 100 mg - Eyes - Severe irritantRabbit - 100 mg - Skin - Mild irritant Rabbit - 500 mg - Skin - Moderate irritantRabbit - 100 % - talc (none asbestiform) Skin - Mild irritant Human - 72 hours 300 ug I - Product/ingredient name Result Score Exposure Observation Sensitization Not available. Species Specific target organ toxicity (single exposure) styrene Category 3 Not applicable.Respiratory tract irritation Man-made mineral fibers Category 3 Not applicable.Respiratory tract irritation Name Category Route of exposure Target organs Information on toxicological effects Classification styrene - 2A Reasonably anticipated to be a human carcinogen. Man-made mineral fibers - 3 - talc (none asbestiform) - 3 - Product/ingredient name NTPIARCOSHA Styrene manufacturers have determined that the weight of evidence for the carcinogenicity of this substance does not meet the criteria for classification. In 2018, styrene was listed by IARC as a probable carcinogen to humans (Group 2A) based on hazard assessment data. The United States NTP listed styrene as reasonably anticipated to be a human carcinogen based on "limited evidence" from studies in humans, "sufficient evidence" from studies in experimental animals, and supporting data on mechanisms of carcinogenesis. The significance of these results for humans has not been established through risk assessment. Date of issue/Date of revision :1/27/2021 Date of previous issue :6/3/2019 Version:2 8/14 COR-Grip Cmpd PA-133-PMMN Section 11. Toxicological information Not available. Information on the likely routes of exposure Inhalation :Harmful if inhaled. May cause respiratory irritation. No known significant effects or critical hazards.:Ingestion Skin contact :Causes skin irritation. Causes serious eye irritation.:Eye contact Causes damage to organs through prolonged or repeated exposure.General : No known significant effects or critical hazards.Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : Symptoms related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing No specific data. Adverse symptoms may include the following: irritation redness : : : Eye contact :Adverse symptoms may include the following: pain or irritation watering redness Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Specific target organ toxicity (repeated exposure) Name Category styrene Category 1 Inhalation hearing organs Man-made mineral fibers Category 1 Not determinedrespiratory system talc (none asbestiform) Category 1 Inhalation Not determined Aspiration hazard Name Result styrene ASPIRATION HAZARD - Category 1 Route of exposure Target organs :Not available. Potential acute health effects Potential immediate effects :Not available. Short term exposure Potential delayed effects:Not available. Potential immediate effects :Not available. Long term exposure Potential delayed effects:Not available. A study of long term effects of workers exposed to styrene levels in the range of 25-35 ppm for an 8-hour TWA indicated a possible mild hearing loss. Date of issue/Date of revision :1/27/2021 Date of previous issue :6/3/2019 Version:2 9/14 COR-Grip Cmpd PA-133-PMMN Section 11. Toxicological information No known significant effects or critical hazards.Teratogenicity : Developmental effects :No known significant effects or critical hazards. Fertility effects :No known significant effects or critical hazards. Numerical measures of toxicity Oral 8148.2 mg/kg Inhalation (gases) 8454.3 ppm Inhalation (vapors) 36.01 mg/l Route ATE value Acute toxicity estimates Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Other adverse effects :No known significant effects or critical hazards. Product/ingredient name styrene 0.35 13.49 low Product/ingredient name Aquatic half-life Photolysis Biodegradability styrene - - Readily Toxicity styrene Acute EC50 1400 g/l Fresh water Algae - Pseudokirchneriella subcapitata 72 hours Acute EC50 720 g/l Fresh water Algae - Pseudokirchneriella subcapitata 96 hours Acute EC50 4700 g/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 52 mg/l Marine water Crustaceans - Artemia salina48 hours Acute LC50 4020 g/l Fresh water Fish - Pimephales promelas 96 hours Chronic NOEC 63 g/l Fresh water Algae - Pseudokirchneriella subcapitata 96 hours Product/ingredient name SpeciesResult Exposure Persistence and degradability styrene OECD 70 % - Readily - 28 days - - Product/ingredient name Test DoseResult Inoculum Soil/water partition coefficient (KOC) :Not available. Mobility in soil Date of issue/Date of revision :1/27/2021 Date of previous issue :6/3/2019 Version:2 10/14 COR-Grip Cmpd PA-133-PMMN Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. :Disposal methods Section 14. Transport information RESIN SOLUTION 3 III RESIN SOLUTION 3 III RESIN SOLUTION UN1866 3 III UN1866 UN1866 Reportable quantity 3875.7 lbs / 1759.6 kg [422.57 gal / 1599.6 L]. Package sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity) transportation requirements. DOT Classification IMDGIATA UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards Special precautions for user Transport in bulk according to Annex II of MARPOL and the IBC Code No. No.No. Transport within user s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. :Not available. : Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.18-2.19 (Class 3). Mexico Classification UN1866 RESIN SOLUTION 3 III No. DOT Classification TDG Classification : : TDG Classification UN1866 RESIN SOLUTION 3 III No. Date of issue/Date of revision :1/27/2021 Date of previous issue :6/3/2019 Version:2 11/14 COR-Grip Cmpd PA-133-PMMN Section 15. Regulatory information U.S. Federal regulations The following components are listed: STYRENE; PHENYLETHYLENE; FIBROUS GLASS; MAGNESITE DUST; TALC; SOAPSTONE Clean Water Act (CWA) 307: Naphthenic acids, copper salts; 2-ethylhexanoic acid, copper salt Clean Water Act (CWA) 311: styrene; propionic acid Massachusetts : : SARA 313 Product name CAS number % SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed. Styrene Form R - Reporting requirements Supplier notification California Prop. 65 Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs) : Clean Air Act Section 602 Class I Substances :Not listed Clean Air Act Section 602 Class II Substances :Not listed New York :The following components are listed: Styrene New Jersey :The following components are listed: STYRENE MONOMER; BENZENE, ETHENYL-; MAGNESITE; CARBONIC ACID, MAGNESIUM SALT (1:1); SOAPSTONE Pennsylvania :The following components are listed: BENZENE, ETHENYL-; TALC; SOAPSTONE DUST State regulations TSCA 8(a) PAIR: 4-tert-butylpyrocatechol; triethyl phosphate TSCA 8(a) CDR Exempt/Partial exemption: Not determined TSCA 8(c) calls for record of SAR: triethyl phosphate SARA 302/304 SARA 304 RQ :3332000.5 lbs / 1512728.2 kg [363291.4 gal / 1375207.5 L] 1,4-dihydroxybenzene <0.1 Yes.500 / 10000- 100 - Composition/information on ingredients Name % EHS(lbs) (lbs)(gallons) (gallons) SARA 302 TPQ SARA 304 RQ SARA 311/312 Classification :FLAMMABLE LIQUIDS - Category 3 ACUTE TOXICITY (inhalation) - Category 4 SKIN IRRITATION - Category 2 EYE IRRITATION - Category 2A SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs, respiratory system) - Category 1 :The following components are listed. For more information go to www.P65Warnings.ca.gov. styrene 100-42-5 <= 26.0 styrene 100-42-5 25.80 Any concentration shown as exact is based on formula. Listed If components are "Listed", and additional information is required, contact Supplier using email in Section 16. Date of issue/Date of revision :1/27/2021 Date of previous issue :6/3/2019 Version:2 12/14 COR-Grip Cmpd PA-133-PMMN Section 15. Regulatory information Inventory list Australia :Not determined. Canada :At least one component is not listed in DSL but all such components are listed in NDSL. China :All components are listed or exempted. Europe :Not determined. Japan :Japan inventory (ENCS): Not determined. Japan inventory (ISHL): Not determined. Republic of Korea :All components are listed or exempted. Malaysia :Not determined. New Zealand :Not determined. Philippines :Not determined. Taiwan :All components are listed or exempted. Turkey :Not determined. United States :All components are listed or exempted. Thailand :Not determined. Viet Nam :All components are listed or exempted. Section 16. Other information Hazardous Material Information System (U.S.A.) 2 3 1 1 3 2 * National Fire Protection Association (U.S.A.) Health Special Instability/Reactivity Flammability Health Flammability Physical hazards Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service mark of the American Coatings Association, Inc. The customer is responsible for determining the PPE code for this material. For more information on HMIS Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual. Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. Procedure used to derive the classification Date of issue/Date of revision :1/27/2021 Date of previous issue :6/3/2019 Version:2 13/14 COR-Grip Cmpd PA-133-PMMN Section 16. Other information 1/27/2021 History Date of printing Date of issue/Date of revision Version Prepared by To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Notice to reader Date of previous issue : : : : : Indicates information that has changed from previously issued version. References : Key to abbreviations :ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations 1/27/2021 6/3/2019 2 Classification Justification FLAMMABLE LIQUIDS - Category 3 On basis of test data ACUTE TOXICITY (inhalation) - Category 4 Calculation method SKIN IRRITATION - Category 2 Calculation method EYE IRRITATION - Category 2A Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 Calculation method SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs, respiratory system) - Category 1 Calculation method Health, Safety and Environmental Department For questions about the SDS, contact :iasafety@ip-corporation.com 29 CFR 1910.1200 Hazard Communication Standard, March 2012 CCR Title 27 Division 4 Office of Environmental Health Hazard Assessment (California Prop. 65) American Composites Manufacturers Association Styrene Information and Research Center New form 08-2018 Date of issue/Date of revision :1/27/2021 Date of previous issue :6/3/2019 Version:2 14/14

23OL2C60A0_SDS.pdf

by | Sep 27, 2025

Crestomer Advantage 60 (380ml)
Liquid.
SAFETY DATA SHEET
GHS product identifier
Product type
Section 1. Identification
:
:
Supplier’s details :
Crestomer Advantage 60 (380ml)
Relevant identified uses of the substance or mixture and uses advised against
Adhesive.
Identified uses
Scott Bader Inc
4280 Hudson Drive
Stow, Ohio 44224
USA
Tel: +1 330 920 4410
SB – US
Emergency telephone
number (with hours of
operation)
:
SDS@scottbader.com:e-mail address of person
responsible for this SDS
+1 215 207 0061 (NCEC, Geographic) 24h
+1 866 928 0789 (NCEC, Toll free) 24h
Section 2. Hazards identification
FLAMMABLE LIQUIDS – Category 3
ACUTE TOXICITY (inhalation) – Category 4
SKIN IRRITATION – Category 2
EYE IRRITATION – Category 2A
SKIN SENSITIZATION – Category 1
CARCINOGENICITY – Category 2
TOXIC TO REPRODUCTION (Unborn child) – Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) – Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) –
Category 1
AQUATIC HAZARD (ACUTE) – Category 2
AQUATIC HAZARD (LONG-TERM) – Category 3
Classification of the
substance or mixture
:
Signal word :Danger
Hazard statements :H226 – Flammable liquid and vapor.
H332 – Harmful if inhaled.
H319 – Causes serious eye irritation.
H315 – Causes skin irritation.
H317 – May cause an allergic skin reaction.
H361 – Suspected of damaging the unborn child.
H351 – Suspected of causing cancer.
H335 – May cause respiratory irritation.
Hazard pictograms :
GHS label elements
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Date of issue/Date of revision :4/15/2019Date of previous issue :6/4/2017 Version:1.02 1/16

Crestomer Advantage 60 (380ml)
Section 2. Hazards identification
H372 – Causes damage to organs through prolonged or repeated exposure. (hearing
organs)
H401 – Toxic to aquatic life.
H412 – Harmful to aquatic life with long lasting effects.
Precautionary statements
Prevention :P201 – Obtain special instructions before use.
P202 – Do not handle until all safety precautions have been read and understood.
P280 – Wear protective gloves. Wear eye or face protection. Wear protective clothing.
P210 – Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
P241 – Use explosion-proof electrical, ventilating, lighting and all material-handling
equipment.
P242 – Use only non-sparking tools.
P243 – Take precautionary measures against static discharge.
P233 – Keep container tightly closed.
P271 – Use only outdoors or in a well-ventilated area.
P273 – Avoid release to the environment.
P260 – Do not breathe vapor.
P270 – Do not eat, drink or smoke when using this product.
P264 – Wash hands thoroughly after handling.
P272 (OSHA) – Contaminated work clothing must not be allowed out of the workplace.
Response :P314 – Get medical attention if you feel unwell.
P308 + P313 – IF exposed or concerned: Get medical attention.
P304 + P340 + P312 – IF INHALED: Remove person to fresh air and keep comfortable
for breathing. Call a POISON CENTER or physician if you feel unwell.
P303 + P361 + P353 – IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water or shower.
P302 + P352 + P363 – IF ON SKIN: Wash with plenty of soap and water. Wash
contaminated clothing before reuse.
P333 + P313 – If skin irritation or rash occurs: Get medical attention.
P305 + P351 + P338 – IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 – If eye irritation persists: Get medical attention.
Storage :P405 – Store locked up.
P403 – Store in a well-ventilated place.
P235 – Keep cool.
Disposal :P501 – Dispose of contents and container in accordance with all local, regional, national
and international regulations.
Hazards not otherwise
classified
:None known.
Section 3. Composition/information on ingredients
styrene 40.354 100-42-5
2-hydroxyethyl acrylate >2.2644 818-61-1
Distillates (petroleum), hydrotreated light paraffinic <1.35 64742-55-8 dibenzoyl peroxide 0.63584 94-36-0 xylene 0.52299 1330-20-7 ethylbenzene 0.17433 100-41-4 1,4-naphthoquinone 0.012312 - 0.02052130-15-4 Ingredient name CAS number% Other means of identification :Not available. CAS number :Not applicable. Substance/mixture Product code :OL2C6000 CAS number/other identifiers :Mixture Any concentration shown as a range is to protect confidentiality or is due to batch variation. Date of issue/Date of revision :4/15/2019Date of previous issue :6/4/2017 Version:1.02 2/16 Crestomer Advantage 60 (380ml) Section 3. Composition/information on ingredients There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important symptoms/effects, acute and delayed Inhalation :Harmful if inhaled. May cause respiratory irritation. No known significant effects or critical hazards.:Ingestion Skin contact :Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation.:Eye contact Over-exposure signs/symptoms Skin contact Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : Eye contact :Adverse symptoms may include the following: pain or irritation watering redness Potential acute health effects Date of issue/Date of revision :4/15/2019Date of previous issue :6/4/2017 Version:1.02 3/16 Crestomer Advantage 60 (380ml) Section 4. First aid measures Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments :No specific treatment. Ingestion Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations : See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide metal oxide/oxides Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. This material is toxic to aquatic life. This material is harmful to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use dry chemical, CO , water spray (fog) or foam. Extinguishing media : : : Do not use water jet. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures : :No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. For non-emergency personnel For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Date of issue/Date of revision :4/15/2019Date of previous issue :6/4/2017 Version:1.02 4/16 Crestomer Advantage 60 (380ml) Section 6. Accidental release measures Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. : : Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. : Precautions for safe handling styrene ACGIH TLV (United States, 3/2016). TWA: 20 ppm 8 hours. TWA: 85 mg/m 8 hours. STEL: 40 ppm 15 minutes. STEL: 170 mg/m 15 minutes. OSHA PEL 1989 (United States, 3/1989). TWA: 50 ppm 8 hours. TWA: 215 mg/m 8 hours. Section 8. Exposure controls/personal protection Ingredient name Exposure limits Control parameters Occupational exposure limits Date of issue/Date of revision :4/15/2019Date of previous issue :6/4/2017 Version:1.02 5/16 Crestomer Advantage 60 (380ml) Section 8. Exposure controls/personal protection STEL: 100 ppm 15 minutes. STEL: 425 mg/m 15 minutes. OSHA PEL Z2 (United States, 2/2013). TWA: 100 ppm 8 hours. CEIL: 200 ppm AMP: 600 ppm 5 minutes. NIOSH REL (United States, 10/2016). TWA: 50 ppm 10 hours. TWA: 215 mg/m 10 hours. STEL: 100 ppm 15 minutes. STEL: 425 mg/m 15 minutes. Distillates (petroleum), hydrotreated light paraffinic OSHA PEL (United States, 6/2016). TWA: 5 mg/m 8 hours. ACGIH TLV (United States, 3/2016). TWA: 5 mg/m 8 hours. Form: Inhalable fraction NIOSH REL (United States, 10/2016). TWA: 5 mg/m 10 hours. Form: Mist STEL: 10 mg/m 15 minutes. Form: Mist dibenzoyl peroxide ACGIH TLV (United States, 3/2016). TWA: 5 mg/m 8 hours. OSHA PEL 1989 (United States, 3/1989). TWA: 5 mg/m 8 hours. NIOSH REL (United States, 10/2016). TWA: 5 mg/m 10 hours. OSHA PEL (United States, 6/2016). TWA: 5 mg/m 8 hours. xylene ACGIH TLV (United States, 3/2016). TWA: 100 ppm 8 hours. TWA: 434 mg/m 8 hours. STEL: 150 ppm 15 minutes. STEL: 651 mg/m 15 minutes. OSHA PEL 1989 (United States, 3/1989). TWA: 100 ppm 8 hours. TWA: 435 mg/m 8 hours. STEL: 150 ppm 15 minutes. STEL: 655 mg/m 15 minutes. OSHA PEL (United States, 6/2016). TWA: 100 ppm 8 hours. TWA: 435 mg/m 8 hours. ethylbenzene ACGIH TLV (United States, 3/2016). TWA: 20 ppm 8 hours. OSHA PEL 1989 (United States, 3/1989). TWA: 100 ppm 8 hours. TWA: 435 mg/m 8 hours. STEL: 125 ppm 15 minutes. STEL: 545 mg/m 15 minutes. NIOSH REL (United States, 10/2016). TWA: 100 ppm 10 hours. TWA: 435 mg/m 10 hours. STEL: 125 ppm 15 minutes. STEL: 545 mg/m 15 minutes. OSHA PEL (United States, 6/2016). TWA: 100 ppm 8 hours. TWA: 435 mg/m 8 hours. Appropriate engineering controls :Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Date of issue/Date of revision :4/15/2019Date of previous issue :6/4/2017 Version:1.02 6/16 Crestomer Advantage 60 (380ml) Section 8. Exposure controls/personal protection Hand protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Environmental exposure controls :Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Other skin protection :Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Section 9. Physical and chemical properties Physical state Melting point Vapor pressure Vapor density Liquid. Not available. Not available. Not available. SolventOdor pH Off-white.Color Evaporation rate Not available. Flash point Closed cup: 32 C (89.6 F) Not available. Not available.Odor threshold : : : : : : : : : : Appearance Boiling point :Not available. Flammability (solid, gas):Not available. Lower and upper explosive (flammable) limits :Not available. Burning rate Not applicable.: Burning time :Not applicable. Date of issue/Date of revision :4/15/2019Date of previous issue :6/4/2017 Version:1.02 7/16 Crestomer Advantage 60 (380ml) Section 9. Physical and chemical properties Relative density Solubility 1.1 to 1.2 Not available. Auto-ignition temperature Not available. Not available. Viscosity Kinematic (40 C (104 F)): >0.4 cm
2
/s (>40 cSt)
Partition coefficient: n-
octanol/water
:
:
:
:
:
SADT Not available.:
Decomposition temperature:Not available.
Aerosol product
Solubility in water :Not available.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours
LC50 Inhalation Vapor Rat 11800 mg/m 4 hours
LD50 Dermal Rat >2000 mg/kg –
LD50 Oral Rat 2650 mg/kg –
2-hydroxyethyl acrylate LD50 Dermal Rabbit 298 mg/kg –
LD50 Oral Rat 548 mg/kg –
dibenzoyl peroxide LC50 Inhalation Dusts and mistsRat >24300 mg/m 4 hours
LD50 Oral Rat 6400 mg/kg –
xylene LD50 Oral Rat 4300 mg/kg –
ethylbenzene LD50 Dermal Rabbit >5000 mg/kg –
LD50 Oral Rat 3500 mg/kg –
1,4-naphthoquinone LC50 Inhalation Vapor Rat 0.046 mg/l 4 hours
LD50 Dermal Rat 202 mg/kg –
LD50 Oral Rat 190 mg/kg –
Product/ingredient name Result Species Dose Exposure
Irritation/Corrosion
Information on toxicological effects
Date of issue/Date of revision :4/15/2019Date of previous issue :6/4/2017 Version:1.02 8/16

Crestomer Advantage 60 (380ml)
Section 11. Toxicological information
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
styrene Eyes – Mild irritant Human – 50 parts per
million
–
Eyes – Moderate irritantRabbit – 24 hours 100
milligrams
–
Eyes – Severe irritantRabbit – 100
milligrams
–
Skin – Mild irritant Rabbit – 500
milligrams
–
Skin – Moderate irritantRabbit – 100 Percent-
2-hydroxyethyl acrylate Skin – Mild irritant Rabbit – 24 hours 10
milligrams
–
Skin – Moderate irritantRabbit – 500
milligrams
–
Eyes – Moderate irritantRabbit – 24 hours 20
milligrams
–
Eyes – Severe irritantRabbit – 1 milligrams-
xylene Eyes – Mild irritant Rabbit – 87 milligrams-
Eyes – Severe irritantRabbit – 24 hours 5
milligrams
–
Skin – Mild irritant Rat – 8 hours 60
microliters
–
Skin – Moderate irritantRabbit – 24 hours 500
milligrams
–
Skin – Moderate irritantRabbit – 100 Percent-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
styrene Category 3 Not applicable.Respiratory tract
irritation
xylene Category 3 Not applicable.Respiratory tract
irritation
1,4-naphthoquinone Category 3 Not applicable.Respiratory tract
irritation
Name Category Route of
exposure
Target organs
Classification
styrene – 2B Reasonably anticipated to be a human carcinogen.
dibenzoyl peroxide – 3 –
xylene – 3 –
ethylbenzene – 2B –
Product/ingredient name NTPIARCOSHA
Date of issue/Date of revision :4/15/2019Date of previous issue :6/4/2017 Version:1.02 9/16

Crestomer Advantage 60 (380ml)
Section 11. Toxicological information
Information on the likely
routes of exposure
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Name Category
styrene Category 1 Inhalation hearing organs
xylene Category 2 Inhalation Not determined
ethylbenzene Category 2 Not determinedhearing organs
Aspiration hazard
Name Result
styrene ASPIRATION HAZARD – Category 1
Distillates (petroleum), hydrotreated light paraffinic ASPIRATION HAZARD – Category 1
xylene ASPIRATION HAZARD – Category 1
ethylbenzene ASPIRATION HAZARD – Category 1
Route of
exposure
Target organs
:Not available.
Potential acute health effects
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
Date of issue/Date of revision :4/15/2019Date of previous issue :6/4/2017 Version:1.02 10/16

Crestomer Advantage 60 (380ml)
Section 11. Toxicological information
styrene Chronic NOAEL Dermal Rat 615 mg/kg –
Chronic NOAEL Inhalation
Gas.
Rat 20 ppm 8 hours
Product/ingredient name Result Species Dose Exposure
Causes damage to organs through prolonged or repeated exposure. Once sensitized, a
severe allergic reaction may occur when subsequently exposed to very low levels.
General :
Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
Suspected of damaging the unborn child.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Numerical measures of toxicity
Oral 5154.3 mg/kg
Dermal 13030.2 mg/kg
Inhalation (gases) 6864.3 ppm
Inhalation (vapors) 29.24 mg/l
Route ATE value
Acute toxicity estimates
Section 12. Ecological information
Toxicity
styrene Acute EC50 1400 g/l Fresh water Algae – Pseudokirchneriella
subcapitata
72 hours
Acute EC50 33 mg/l Fresh water Algae – Pseudokirchneriella
subcapitata
96 hours
Acute EC50 4700 g/l Fresh water Daphnia – Daphnia magna 48 hours
Acute LC50 52 mg/l Marine water Crustaceans – Artemia salina48 hours
Acute LC50 4020 g/l Fresh water Fish – Pimephales promelas 96 hours
Chronic NOEC 1.01 mg/l Daphnia 21 days
2-hydroxyethyl acrylate Acute LC50 4800 g/l Fresh water Fish – Pimephales promelas –
Juvenile (Fledgling, Hatchling,
Weanling)
96 hours
dibenzoyl peroxide EC50 0.06 mg/l Algae 72 hours
EC50 0.11 mg/l Daphnia 48 hours
LC50 0.06 mg/l Fish 96 hours
xylene Acute LC50 8500 g/l Marine water Crustaceans – Palaemonetes
pugio
48 hours
Acute LC50 13400 g/l Fresh water Fish – Pimephales promelas 96 hours
ethylbenzene Acute EC50 4.6 mg/l Algae 72 hours
Acute EC50 2.96 to 4.4 mg/l Daphnia 48 hours
Acute LC50 4.2 mg/l Fish 96 hours
1,4-naphthoquinone Acute IC50 0.011 mg/l Algae 72 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
1,4-naphthoquinone – 35 % – 5 days – –
Product/ingredient name Test DoseResult Inoculum
Date of issue/Date of revision :4/15/2019Date of previous issue :6/4/2017 Version:1.02 11/16

Crestomer Advantage 60 (380ml)
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Product/ingredient name
styrene 0.35 13.49 low
2-hydroxyethyl acrylate -0.17 – low
dibenzoyl peroxide 3.2 – low
xylene 3.12 8.1 to 25.9 low
ethylbenzene 3.6 – low
1,4-naphthoquinone 1.71 – low
Product/ingredient name Aquatic half-life Photolysis Biodegradability
styrene – – Readily
dibenzoyl peroxide – – Inherent
xylene – – Readily
ethylbenzene – – Readily
1,4-naphthoquinone – – Inherent
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
Section 14. Transport information
Adhesives
3
III
ADHESIVES
3
III
Adhesives
UN1133
3
III
UN1133 UN1133
DOT
Classification
IMDG IATA
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
TDG
Classification
UN1133
ADHESIVES
3
III
ADR/RID
UN1133
ADHESIVES
3
III
Mexico
Classification
UN1133
ADHESIVOS
3
III
Date of issue/Date of revision :4/15/2019Date of previous issue :6/4/2017 Version:1.02 12/16

Crestomer Advantage 60 (380ml)
Section 14. Transport information
Reportable
quantity 2478.
1 lbs / 1125.1
kg [258.44 gal /
978.31 L].
Package sizes
shipped in
quantities less
than the
product
reportable
quantity are
not subject to
the RQ
(reportable
quantity)
transportation
requirements.
Limited
quantity Yes.
Packaging
instruction
Exceptions:
150. Non-bulk:
173. Bulk: 242.
Quantity
limitation
Passenger
aircraft/rail: 60
L. Cargo
aircraft: 220 L.
Special
provisions B1,
B52, IB3, T2,
TP1
Emergency
schedules F-E,
S-D
Special
provisions
223, 955
The
environmentally
hazardous
substance
mark may
appear if
required by
other
transportation
regulations.
Quantity
limitation
Passenger and
Cargo Aircraft:
60 L.
Packaging
instructions:
355. Cargo
Aircraft Only:
220 L.
Packaging
instructions:
366. Limited
Quantities –
Passenger
Aircraft: 10 L.
Packaging
instructions:
Y344.
Special
provisions A3
Additional
information
Environmental
hazards
Special precautions for user
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
No. No. No.
Transport within user s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
:Not available.
:
No.
Product
classified as
per the
following
sections of the
Transportation
of Dangerous
Goods
Regulations: 2.
18-2.19 (Class
3).
Explosive
Limit and
Limited
Quantity Index
5
Passenger
Carrying
Road or Rail
Index 60
Special
provisions 83
No.
The
environmentally
hazardous
substance
mark is not
required when
transported in
sizes of 5 L or
5 kg.
Hazard
identification
number 30
Limited
quantity 5 L
Special
provisions
640E
Tunnel code
(D/E)
No.
Special
provisions 223
Section 15. Regulatory information
U.S. Federal regulations :
Clean Air Act Section 112
(b) Hazardous Air
Pollutants (HAPs)
:Listed
Clean Air Act Section 602
Class I Substances
:Not listed
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
Date of issue/Date of revision :4/15/2019Date of previous issue :6/4/2017 Version:1.02 13/16

Crestomer Advantage 60 (380ml)
Section 15. Regulatory information
The following components are listed: STYRENE; PHENYLETHYLENE; MINERAL OIL,
PETROLEUM DISTILLATES, HYDROTREATED LIGHT PARAFFINIC; ETHYLENE
GLYCOL MONOACRYLATE; 2-HYDROXYETHYL ACRYLATE; TITANIUM DIOXIDE;
TIN DIOXIDE DUST
WARNING: This product contains a chemical known to the State of California to cause cancer.
Massachusetts :
SARA 313
Product name CAS number %
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
styrene 100-42-5 40.354
ethylbenzene 100-41-4 0.17433
styrene 100-42-5 40.354
ethylbenzene 100-41-4 0.17433
Form R – Reporting
requirements
Supplier notification
California Prop. 65
Clean Air Act Section 602
Class II Substances
:Not listed
DEA List I Chemicals
(Precursor Chemicals)
:Not listed
DEA List II Chemicals
(Essential Chemicals)
:Not listed
New York :The following components are listed: Styrene; Ethylbenzene
New Jersey :The following components are listed: STYRENE MONOMER; BENZENE, ETHENYL-;
MINERAL OIL (UNTREATED and MILDLY TREATED); 2-HYDROXYETHYL
ACRYLATE; 2-PROPENOIC ACID, 2-HYDROXYETHYL ESTER; ETHYL BENZENE;
BENZENE, ETHYL-; TITANIUM DIOXIDE; TITANIUM OXIDE (TiO2)
Pennsylvania :The following components are listed: BENZENE, ETHENYL-; 2-PROPENOIC ACID,
2-HYDROXYETHYL ESTER; BENZENE, ETHYL-; TITANIUM OXIDE
State regulations
SARA 302/304
SARA 304 RQ :203388451.6 lbs / 92338357 kg [21211489.8 gal / 80294223.5 L]
sulphuric acid <0.0005463Yes.1000 66.3 1000 66.3 Composition/information on ingredients Name % EHS(lbs) (lbs)(gallons) (gallons) SARA 302 TPQ SARA 304 RQ SARA 311/312 Classification :Fire hazard Immediate (acute) health hazard Delayed (chronic) health hazard styrene 40.354 Yes. No. No. Yes. Yes. 2-hydroxyethyl acrylate >2.2644 No. No. No. Yes. No.
dibenzoyl peroxide 0.63584 No. No. Yes. Yes. No.
xylene 0.52299 Yes. No. No. Yes. Yes.
ethylbenzene 0.17433 Yes. No. No. Yes. Yes.
1,4-naphthoquinone 0.012312 –
0.02052
No. No. No. Yes. No.
Name % Fire
hazard
Sudden
release of
pressure
Reactive Immediate
(acute)
health
hazard
Delayed
(chronic)
health
hazard
Composition/information on ingredients
Date of issue/Date of revision :4/15/2019Date of previous issue :6/4/2017 Version:1.02 14/16

Crestomer Advantage 60 (380ml)
Section 15. Regulatory information
titanium dioxide Yes. No. – –
styrene Yes. No. – –
ethylbenzene Yes. No. Yes. –
sulphuric acid Yes. No. – –
1,4-naphthoquinone Yes. No. – –
Ingredient name Cancer Reproductive No significant risk
level
Maximum
acceptable dosage
level
International regulations
Montreal Protocol (Annexes A, B, C, E)
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
International lists
National inventoryNot determined
Section 16. Other information
Hazardous Material Information System (U.S.A.)
3
3
0
0
3
2
*
National Fire Protection Association (U.S.A.)
Health
Special
Instability/Reactivity
Flammability
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS
ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS
Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual.
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Date of issue/Date of revision :4/15/2019Date of previous issue :6/4/2017 Version:1.02 15/16

Crestomer Advantage 60 (380ml)
Section 16. Other information
4/15/2019
History
Date of printing
Date of issue/Date of
revision
Version
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Notice to reader
Date of previous issue
:
:
:
:
Indicates information that has changed from previously issued version.
References :Not available.
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. (“Marpol” = marine pollution)
UN = United Nations
4/15/2019
6/4/2017
1.02
Date of issue/Date of revision :4/15/2019Date of previous issue :6/4/2017 Version:1.02 16/16

23OL2715A0_SDS.pdf

by | Sep 27, 2025

Crestabond M7-15 Cart 400ml
Liquid.
SAFETY DATA SHEET
GHS product identifier
Product type
Section 1. Identification
:
:
Supplier’s details :
Crestabond M7-15 Cart 400ml
Relevant identified uses of the substance or mixture and uses advised against
Scott Bader Inc
4280 Hudson Drive
Stow, Ohio 44224
USA
Tel: +1 330 920 4410
SB – US
Emergency telephone
number (with hours of
operation)
:
SDS@scottbader.com:e-mail address of person
responsible for this SDS
+1 215 207 0061 (NCEC, Geographic) 24h
+1 866 928 0789 (NCEC, Toll free) 24h
Adhesive.
Identified uses
Section 2. Hazards identification
FLAMMABLE LIQUIDS – Category 2
SKIN IRRITATION – Category 2
EYE IRRITATION – Category 2A
SKIN SENSITIZATION – Category 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) – Category 3
AQUATIC HAZARD (ACUTE) – Category 2
AQUATIC HAZARD (LONG-TERM) – Category 2
Classification of the
substance or mixture
:
Signal word :
Hazard statements :H225 – Highly flammable liquid and vapor.
H315 – Causes skin irritation.
H317 – May cause an allergic skin reaction.
H319 – Causes serious eye irritation.
H335 – May cause respiratory irritation.
H411 – Toxic to aquatic life with long lasting effects.
Hazard pictograms :
Precautionary statements
GHS label elements
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Danger
Date of issue/Date of revision :10/12/2020 Date of previous issue :19/10/2020 Version:2.01 1/14

Crestabond M7-15 Cart 400ml
Section 2. Hazards identification
Prevention :P280 – Wear protective gloves, protective clothing and eye or face protection.
P210 – Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
P241 – Use explosion-proof electrical, ventilating or lighting equipment.
P242 – Use non-sparking tools.
P243 – Take action to prevent static discharges.
P271 – Use only outdoors or in a well-ventilated area.
P273 – Avoid release to the environment.
P261 – Avoid breathing vapor.
P264 – Wash thoroughly after handling.
Response :P391 – Collect spillage.
P304 + P340, P312 – IF INHALED: Remove person to fresh air and keep comfortable
for breathing. Call a POISON CENTER or doctor if you feel unwell.
P303 + P361 + P353 – IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water.
P363 – Wash contaminated clothing before reuse.
P302 + P352 – IF ON SKIN: Wash with plenty of water.
P333 + P313 – If skin irritation or rash occurs: Get medical advice or attention.
P305 + P351 + P338 – IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 – If eye irritation persists: Get medical advice or attention.
Storage :P405 – Store locked up.
P403 + P233 – Store in a well-ventilated place. Keep container tightly closed.
P403 + P235 – Keep cool.
Disposal :P501 – Dispose of contents and container in accordance with all local, regional, national
and international regulations.
Supplemental label
elements
:Do not taste or swallow. Wash thoroughly after handling.
Hazards not otherwise
classified
:Causes severe digestive tract burns.
Section 3. Composition/information on ingredients
methyl methacrylate 57.022 80-62-6
oxydipropyl dibenzoate 4.9245 27138-31-4
methacrylic acid 2 79-41-4
3,5-diethyl-1,2-dihydro-1-phenyl-2-propylpyridine >0.8274 34562-31-7
maleic acid 0.75 110-16-7
rosin <0.2475 8050-09-7 Ingredient name CAS number% There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Other means of identification :Not available. CAS number :Not applicable. Substance/mixture Product code :OL271500 CAS number/other identifiers : Occupational exposure limits, if available, are listed in Section 8. Mixture Any concentration shown as a range is to protect confidentiality or is due to batch variation. Date of issue/Date of revision :10/12/2020 Date of previous issue :19/10/2020 Version:2.01 2/14 Crestabond M7-15 Cart 400ml Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Description of necessary first aid measures Specific treatments :No specific treatment. Most important symptoms/effects, acute and delayed Inhalation :May cause respiratory irritation. Severely corrosive to the digestive tract. Causes severe burns.:Ingestion Skin contact :Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation.:Eye contact Over-exposure signs/symptoms Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing Adverse symptoms may include the following: stomach pains Adverse symptoms may include the following: irritation redness : : : Eye contact :Adverse symptoms may include the following: pain or irritation watering redness Potential acute health effects Indication of immediate medical attention and special treatment needed, if necessary Date of issue/Date of revision :10/12/2020 Date of previous issue :19/10/2020 Version:2.01 3/14 Crestabond M7-15 Cart 400ml Section 4. First aid measures See toxicological information (Section 11) Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide halogenated compounds Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. This material is toxic to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use dry chemical, CO , water spray (fog) or foam. Extinguishing media : : : Do not use water jet. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : :No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Collect spillage. Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Date of issue/Date of revision :10/12/2020 Date of previous issue :19/10/2020 Version:2.01 4/14 Crestabond M7-15 Cart 400ml Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. : : Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapor or mist. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. : Precautions for safe handling methyl methacrylate ACGIH TLV (United States, 3/2019). Skin sensitizer. TWA: 50 ppm 8 hours. STEL: 100 ppm 15 minutes. OSHA PEL 1989 (United States, 3/1989). TWA: 100 ppm 8 hours. TWA: 410 mg/m 8 hours. NIOSH REL (United States, 10/2016). TWA: 100 ppm 10 hours. TWA: 410 mg/m 10 hours. OSHA PEL (United States, 5/2018). TWA: 100 ppm 8 hours. TWA: 410 mg/m 8 hours. methacrylic acid ACGIH TLV (United States, 3/2019). TWA: 20 ppm 8 hours. TWA: 70 mg/m 8 hours. OSHA PEL 1989 (United States, 3/1989). Absorbed through skin. TWA: 20 ppm 8 hours. TWA: 70 mg/m 8 hours. NIOSH REL (United States, 10/2016). Absorbed through skin. TWA: 20 ppm 10 hours. TWA: 70 mg/m 10 hours. rosin ACGIH TLV (United States, 3/2019). Skin sensitizer. Inhalation sensitizer. Section 8. Exposure controls/personal protection Ingredient name Exposure limits Control parameters Occupational exposure limits Date of issue/Date of revision :10/12/2020 Date of previous issue :19/10/2020 Version:2.01 5/14 Crestabond M7-15 Cart 400ml Section 8. Exposure controls/personal protection Hand protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Environmental exposure controls :Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls :Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Other skin protection :Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Section 9. Physical and chemical properties Physical state Melting point Liquid. Not available. Strong AcrylicOdor pH Off-white.Color Evaporation rate Not available. Flash point Closed cup: 10 C (50 F) Not available. Not available.Odor threshold : : : : : : : : Appearance Boiling point :Not available. Flammability (solid, gas):Not available. Burning rate Not applicable.: Burning time :Not applicable. Date of issue/Date of revision :10/12/2020 Date of previous issue :19/10/2020 Version:2.01 6/14 Crestabond M7-15 Cart 400ml Section 9. Physical and chemical properties Vapor pressure Relative density Vapor density Solubility 1 to 1.03 Not available. Not available. Not available. Auto-ignition temperature Not available. Not available. Viscosity Kinematic (40 C (104 F)): >0.4 cm
2
/s (>40 cSt)
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
Lower and upper explosive
(flammable) limits
:Not available.
SADT Not available.:
Decomposition temperature:Not available.
Solubility in water :Not available.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
methyl methacrylate LC50 Inhalation Vapor Rat 78000 mg/m 4 hours
LD50 Dermal Rabbit >5 g/kg –
LD50 Oral Rat 7872 mg/kg –
oxydipropyl dibenzoate LC50 Inhalation Dusts and mistsRat >200 mg/l 4 hours
LD50 Dermal Rabbit >2000 mg/kg –
LD50 Oral Rat 3295 mg/kg –
methacrylic acid LD50 Oral Rat 1060 mg/kg –
3,5-diethyl-1,2-dihydro-
1-phenyl-2-propylpyridine
LD50 Dermal Rabbit >1000 mg/kg –
LD50 Oral Rat 1620 mg/kg –
maleic acid LD50 Oral Rat 708 mg/kg –
rosin LD50 Oral Rat 7600 mg/kg –
Product/ingredient name Result Species Dose Exposure
Irritation/Corrosion
maleic acid Eyes – Severe irritantRabbit – 2 minutes 1 %-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Information on toxicological effects
Date of issue/Date of revision :10/12/2020 Date of previous issue :19/10/2020 Version:2.01 7/14

Crestabond M7-15 Cart 400ml
Section 11. Toxicological information
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Information on the likely
routes of exposure
Inhalation :May cause respiratory irritation.
Severely corrosive to the digestive tract. Causes severe burns.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
Adverse symptoms may include the following:
stomach pains
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Delayed and immediate effects and also chronic effects from short and long term exposure
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
methyl methacrylate Category 3 – Respiratory tract
irritation
methacrylic acid Category 3 – Respiratory tract
irritation
maleic acid Category 3 – Respiratory tract
irritation
Name Category
Not available.
Aspiration hazard
Not available.
Route of
exposure
Target organs
:Not available.
Potential acute health effects
Short term exposure
Classification
methyl methacrylate – 3 –
Product/ingredient name NTPIARCOSHA
Date of issue/Date of revision :10/12/2020 Date of previous issue :19/10/2020 Version:2.01 8/14

Crestabond M7-15 Cart 400ml
Section 11. Toxicological information
oxydipropyl dibenzoate Chronic NOAEL Oral Rat 1000 mg/kg 90 days
methacrylic acid Chronic NOAEL Inhalation
Gas.
Rat 300 ppm 90 days
Chronic NOAEL Inhalation
Gas.
Rat 100 ppm 90 days
Product/ingredient name Result Species Dose Exposure
Once sensitized, a severe allergic reaction may occur when subsequently exposed to
very low levels.
General :
No known significant effects or critical hazards.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
Potential chronic health effects
Potential immediate
effects
:Not available.
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
No known significant effects or critical hazards.Reproductive toxicity :
Numerical measures of toxicity
Acute toxicity estimates
Product/ingredient name
Crestabond M7-15 Cart 400ml 24142.2 36863.1 N/A N/A 56
methyl methacrylate 7872 N/A N/A 78 N/A
oxydipropyl dibenzoate 3295 2500 N/A N/A N/A
methacrylic acid 1060 N/A N/A N/A 1.5
3,5-diethyl-1,2-dihydro-1-phenyl-2-propylpyridine1620 N/A N/A N/A N/A
maleic acid 708 N/A N/A N/A N/A
rosin 7600 N/A N/A N/A N/A
Oral (mg/
kg)
Dermal
(mg/kg)
Inhalation
(gases)
(ppm)
Inhalation
(vapors)
(mg/l)
Inhalation
(dusts and
mists) (mg/
l)
Section 12. Ecological information
Toxicity
methyl methacrylate Acute LC50 130000 g/l Fresh waterFish – Pimephales promelas –
Adult
96 hours
methacrylic acid Chronic NOEC 53 mg/l Fresh water Daphnia – Daphnia magna –
Neonate
21 days
maleic acid EC50 160 mg/l Daphnia 48 hours
LC50 106 mg/l Fish 96 hours
rosin Acute EC50 911 mg/l Daphnia 48 hours
Acute LC50 >1000 mg/l Fish 96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
oxydipropyl dibenzoate – 87 % – 28 days – –
methacrylic acid – 86 % – 28 days – –
rosin – 64 % – 28 days – –
Product/ingredient name Test DoseResult Inoculum
Date of issue/Date of revision :10/12/2020 Date of previous issue :19/10/2020 Version:2.01 9/14

Crestabond M7-15 Cart 400ml
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Product/ingredient name
methyl methacrylate 1.38 – low
oxydipropyl dibenzoate 3.9 – low
methacrylic acid 0.93 – low
maleic acid -1.3 – low
rosin 1.9 to 7.7 56.3 low
Product/ingredient name Aquatic half-life Photolysis Biodegradability
oxydipropyl dibenzoate – – Readily
methacrylic acid – – Readily
rosin – – Readily
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
United States – RCRA Toxic hazardous waste “U” List
Methyl methacrylate (I,T); 2-Propenoic acid, 2-methyl-, methyl ester (I,T)80-62-6 Listed U162
Ingredient CAS # Status Reference
number
Section 14. Transport information
Adhesives
3
III
ADHESIVES
3
III
Adhesives
UN1133
3
III
UN1133 UN1133
DOT
Classification
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
UN1133
ADHESIVES
3
III
UN1133
ADHESIVOS
3
III
TDG
Classification
Mexico
Classification
IMDG IATA
Date of issue/Date of revision :10/12/2020 Date of previous issue :19/10/2020 Version:2.01 10/14

Crestabond M7-15 Cart 400ml
Section 14. Transport information
Reportable quantity 1753.7 lbs / 796.18 kg [207.22 gal / 784.41 L]. Package sizes
shipped in quantities less than the product reportable quantity are not subject to the RQ
(reportable quantity) transportation requirements.
Limited quantity Yes.
Packaging instruction Exceptions: 150. Non-bulk: 173. Bulk: 242.
Quantity limitation Passenger aircraft/rail: 60 L. Cargo aircraft: 220 L.
Special provisions B1, B52, IB3, T2, TP1
The marine pollutant mark is not required when transported in sizes of 5 L or 5 kg.
Emergency schedules F-E, S-D
Special provisions 223, 955
The environmentally hazardous substance mark may appear if required by other
transportation regulations.
Quantity limitation Passenger and Cargo Aircraft: 60 L. Packaging instructions: 355.
Cargo Aircraft Only: 220 L. Packaging instructions: 366. Limited Quantities – Passenger
Aircraft: 10 L. Packaging instructions: Y344.
Special provisions A3
Additional information
Environmental
hazards
Special precautions for user
No. Yes. Yes. The
environmentally
hazardous
substance mark is
not required.
Transport within user s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
:
Yes.
Product classified as per the following sections of the Transportation of Dangerous
Goods Regulations: 2.18-2.19 (Class 3), 2.7 (Marine pollutant mark).
The marine pollutant mark is not required when transported by road or rail.
Explosive Limit and Limited Quantity Index 5
Passenger Carrying Road or Rail Index 60
Special provisions 83
Yes. The
environmentally
hazardous
substance mark is
not required.
Special provisions 223
DOT Classification
TDG Classification
Mexico Classification
IMDG
IATA
:
:
:
:
:
Transport in bulk according
to IMO instruments
:Not available.
Section 15. Regulatory information
U.S. Federal regulations :
Clean Air Act Section 112
(b) Hazardous Air
Pollutants (HAPs)
:Listed
Clean Air Act Section 602
Class I Substances
:Not listed
Clean Air Act Section 602
Class II Substances
:Not listed
DEA List I Chemicals
(Precursor Chemicals)
:Not listed
DEA List II Chemicals
(Essential Chemicals)
:Not listed
TSCA 8(a) PAIR: mequinol; disulfiram; 2-phenylpropan-2-ol; (2-methoxymethylethoxy)
propanol
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
Date of issue/Date of revision :10/12/2020 Date of previous issue :19/10/2020 Version:2.01 11/14

Crestabond M7-15 Cart 400ml
Section 15. Regulatory information
The following components are listed: METHYL METHACRYLATE; METHACRYLIC
ACID
Massachusetts :
SARA 313
Product name CAS number %
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
methyl methacrylate 80-62-6 57.022
methyl methacrylate 80-62-6 57.022
Form R – Reporting
requirements
Supplier notification
California Prop. 65
New York :The following components are listed: Methyl methacrylate; 2-Propenoic acid, 2-methyl-,
methyl ester
New Jersey :The following components are listed: METHYL METHACRYLATE; 2-PROPENOIC
ACID, 2-METHYL-, METHYL ESTER; METHACRYLIC ACID; 2-PROPENOIC ACID,
2-METHYL-; ISOPROPENYL BENZENE; alpha-METHYLSTYRENE
Pennsylvania :The following components are listed: 2-PROPENOIC ACID, 2-METHYL-, METHYL
ESTER; 2-PROPENOIC ACID, 2-METHYL-
State regulations
SARA 302/304
SARA 304 RQ :Not applicable.
No products were found.
Composition/information on ingredients
SARA 311/312
Composition/information on ingredients
WARNING: This product can expose you to chemicals including -Methyl styrene, cumene and 1,4-naphthoquinone,
which are known to the State of California to cause cancer. For more information go to www.P65Warnings.ca.gov.
Classification :FLAMMABLE LIQUIDS – Category 2
SKIN IRRITATION – Category 2
EYE IRRITATION – Category 2A
SKIN SENSITIZATION – Category 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) – Category 3
HNOC – Corrosive to digestive tract [severe]
methyl methacrylate 50 – 60 FLAMMABLE LIQUIDS – Category 2
SKIN IRRITATION – Category 2
SKIN SENSITIZATION – Category 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) – Category 3
methacrylic acid 2.9 FLAMMABLE LIQUIDS – Category 4
ACUTE TOXICITY (oral) – Category 4
ACUTE TOXICITY (inhalation) – Category 4
SKIN CORROSION – Category 1A
SERIOUS EYE DAMAGE – Category 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) – Category 3
HNOC – Corrosive to digestive tract [severe]
maleic acid <1 ACUTE TOXICITY (oral) - Category 4 SKIN IRRITATION - Category 2 EYE IRRITATION - Category 2A SKIN SENSITIZATION - Category 1 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 rosin 0.3 SKIN SENSITIZATION - Category 1 Name % Classification Date of issue/Date of revision :10/12/2020 Date of previous issue :19/10/2020 Version:2.01 12/14 Crestabond M7-15 Cart 400ml Section 15. Regulatory information International lists -Methyl styrene - - cumene - - 1,4-naphthoquinone - - Ingredient name No significant risk level Maximum acceptable dosage level International regulations Chemical Weapon Convention List Schedules I, II & III Chemicals Montreal Protocol Not listed. Stockholm Convention on Persistent Organic Pollutants Not listed. Rotterdam Convention on Prior Informed Consent (PIC) Not listed. UNECE Aarhus Protocol on POPs and Heavy Metals Not listed. Not listed. National inventory Not determined: Section 16. Other information 12/10/2020 History Date of printing Date of issue/Date of revision Version Date of previous issue : : : : 10/12/2020(M/D/YYYY^)) 19/10/2020(M/D/YYYY^)) 2.01 Hazardous Material Information System (U.S.A.) 4 3 0 4 3 3 / National Fire Protection Association (U.S.A.) Health Special hazards Instability/Reactivity Flammability Health Flammability Physical hazards Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service mark of the American Coatings Association, Inc. The customer is responsible for determining the PPE code for this material. For more information on HMIS Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual. Date of issue/Date of revision :10/12/2020 Date of previous issue :19/10/2020 Version:2.01 13/14 Crestabond M7-15 Cart 400ml Section 16. Other information To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Notice to reader Indicates information that has changed from previously issued version. References :Not available. Key to abbreviations :ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) N/A = Not available SGG = Segregation Group UN = United Nations Date of issue/Date of revision :10/12/2020 Date of previous issue :19/10/2020 Version:2.01 14/14

23MRP80006_SDS.pdf

by | Sep 27, 2025

Print Date 03/10/2022
Page 1 of 9
SAFETY DATA SHEET

H.B. Fuller APS GEL
Version 1.1 Revision Date 01/05/2022

1 / 9

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : H.B. Fuller APS GEL
Product code : 100000009540
Manufacturer or supplier’s details
Company : H.B. Fuller Engineering Adhesives

Address : 9001 W Fey Drive
Frankfort, IL, 60423
Telephone : 1-815-464-5606

Medical Emergency Phone Number (24 Hours): 1-888-853-1758

Transport Emergency Phone Number (CHEMTREC): 1-800-424-9300

Recommended use of the chemical and restrictions on use
Recommended use : Cyanoacrylate Adhesive

Restrictions on use : For industrial use only.

SECTION 2. HAZARDS IDENTIFICATION

Emergency Overview
Appearance gel
Color clear
Odor characteristic

GHS Classification
Flammable liquids : Category 4
Skin irritation : Category 2
Eye irritation : Category 2A
Specific target organ toxicity –
single exposure
: Category 3 (Respiratory system)
GHS label elements
Hazard pictograms :

Signal Word : Warning

Hazard Statements:
H227 Combustible liquid. H315 Causes skin irritation. H319 Causes serious eye irritation. H335
May cause respiratory irritation.

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Version 1.1 Revision Date 01/05/2022

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Precautionary Statements:
Prevention: P210 Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking. P261
Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. P264 Wash skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/ eye protection/
face protection.
Response: P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P304 + P340 + P312 IF
INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON
CENTER/ doctor if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P332 +
P313 If skin irritation occurs: Get medical advice/ attention. P337 + P313 If eye irritation persists:
Get medical advice/ attention. P362 Take off contaminated clothing and wash before reuse. P370 +
P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
Storage: P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235
Store in a well-ventilated place. Keep cool. P405 Store locked up.
Disposal: P501 Dispose of contents/ container to an approved waste disposal plant.
Potential Health Effects

Carcinogenicity:
IARC No ingredient of this product present at levels greater than or
equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.
OSHA No component of this product present at levels greater than or
equal to 0.1% is on OSHA s list of regulated carcinogens.
NTP No ingredient of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

Hazardous ingredients
Chemical name CAS-No. Concentration [%]
ethyl 2-cyanoacrylate 7085-85-0 90 – 100
Actual concentration is withheld as a trade secret

SECTION 4. FIRST AID MEASURES

General advice : Show this material safety data sheet to the doctor in
attendance.

If inhaled : Move to fresh air.
If not breathing, give artificial respiration.
Keep patient warm and at rest.
Consult a physician after significant exposure.

In case of skin contact : Wash off immediately with soap and plenty of water.
Call a physician if irritation develops or persists.
Cyanoacrylate. Danger. Bonds skin and eyes in seconds.

Print Date 03/10/2022
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Keep out of the reach of children.

In case of eye contact : Rinse immediately with plenty of water, also under the eyelids.
Seek medical advice.

If swallowed : If swallowed, call a poison control center or doctor
immediately.
Do not induce vomiting without medical advice.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or
carbon dioxide.

Unsuitable extinguishing
media
: Water spray jet

Hazardous combustion
products
: Nitrogen oxides (NOx)
Specific extinguishing
methods
:
Further information : Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.

Special protective equipment
for fire-fighters
: Wear an approved positive pressure self-contained breathing
apparatus in addition to standard fire fighting gear.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions,
protective equipment and
emergency procedures
: Refer to protective measures listed in sections 7 and 8.
Ensure adequate ventilation.

Environmental precautions : Prevent product from entering drains.
Do not flush into surface water or sanitary sewer system.

Methods and materials for
containment and cleaning up
: Allow to solidify.
Pick up and transfer to properly labeled containers.
Ventilate the area.

SECTION 7. HANDLING AND STORAGE

Local/Total ventilation : Use only with adequate ventilation.

Advice on safe handling : Wear personal protective equipment.
Do not get on skin or clothing.
Use only in an area equipped with a safety shower.

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SAFETY DATA SHEET

H.B. Fuller APS GEL
Version 1.1 Revision Date 01/05/2022

4 / 9

Conditions for safe storage : Keep containers tightly closed in a dry, cool and well-
ventilated place.
Store in original container.

Materials to avoid : Do not store together with oxidizing and self-igniting products.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters
Components CAS-No. Value type
(Form of
exposure)
Control
parameters /
Permissible
concentration
Basis
ethyl 2-cyanoacrylate 7085-85-0 PEL 0.2 ppm
1.02 mg/m3
CAL PEL
TWA 0.2 ppm ACGIH
STEL 1 ppm ACGIH

Personal protective equipment
Respiratory protection : Use respiratory protection unless adequate local exhaust
ventilation is provided or exposure assessment demonstrates
that exposures are within recommended exposure guidelines.

Filter type : Combined particulates and organic vapor type

Hand protection
Material : Nitrile rubber
Remarks : Do not wear cotton or natural fiber gloves.

Eye protection : Tightly fitting safety goggles
Ensure that eyewash stations and safety showers are close to
the workstation location.

Skin and body protection : Long sleeved clothing
Preventive skin protection

Protective measures : Avoid contact with skin.

Hygiene measures : Avoid contact with skin, eyes and clothing.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : gel
Color : clear
Odor : characteristic
Odor Threshold : no data available

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SAFETY DATA SHEET

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pH : is not determined
Melting point/freezing point : is not determined
Boiling point/boiling range : is not determined
Flash point : > 81 CMethod: closed cup
Not applicable
Evaporation rate : is not determined
Flammability (solid, gas) : Not classified as a flammability hazard

Upper explosion limit : Upper flammability limit
is not determined
Lower explosion limit : Lower flammability limit
is not determined
Vapor pressure : is not determined
Density : 1.10 g/cm3
Solubility(ies)
Water solubility : is not determined
Partition coefficient: n-
octanol/water
: no data available
Autoignition temperature : is not determined
Viscosity
Viscosity, kinematic : is not determined

SECTION 10. STABILITY AND REACTIVITY

Chemical stability : The product is chemically stable.

Hazardous decomposition
products
: Stable under normal conditions.

SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity
No data available
Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitization
No data available
Germ cell mutagenicity

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SAFETY DATA SHEET

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Version 1.1 Revision Date 01/05/2022

6 / 9

No data available
Carcinogenicity
No data available
Reproductive toxicity
No data available
STOT-single exposure
No data available
STOT-repeated exposure
No data available
Aspiration toxicity
No data available

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

No data available
Persistence and degradability
No data available
Bioaccumulative potential
Mobility in soil
No data available
Other adverse effects
No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : Do not dispose of together with household waste.
Do not dispose of waste into sewer.
To the best of our knowledge, this product does not meet the
definition of hazardous waste under the U.S. EPA Hazardous
Waste Regulations 40 CFR 261. Disposal via incineration at
an approved facility is recommended, as industry best
practice. Consult state, local or provincial authorities for more
restrictive requirements.

Print Date 03/10/2022
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SAFETY DATA SHEET

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Version 1.1 Revision Date 01/05/2022

7 / 9

SECTION 14. TRANSPORT INFORMATION
International Regulations
UNRTDG
Not regulated as a dangerous good
IATA-DGR
Not regulated as a dangerous good
IMDG-Code
Not regulated as a dangerous good
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Domestic regulation
49 CFR
UN/ID/NA number : NA 1993
Proper shipping name : Combustible liquid, n.o.s.
(ethyl 2-cyanoacrylate)
Class : CBL
Packing group : III
ERG Code : 128
Marine pollutant : no
Special precautions for user
The transport classification(s) provided herein are for informational purposes only, and solely
based upon the properties of the unpackaged material as it is described within this Safety Data
Sheet. Transportation classifications may vary by mode of transportation, package sizes, and
variations in regional or country regulations.

SECTION 15. REGULATORY INFORMATION

SARA 311/312 Hazards : Flammable (gases, aerosols, liquids, or solids)
Skin corrosion or irritation
Serious eye damage or eye irritation
Specific target organ toxicity (single or repeated exposure)

SARA 302 : This material does not contain any components with a section 302
EHS TPQ.

SARA 313 : This material does not contain any chemical components with known
CAS numbers that exceed the threshold (De Minimis) reporting levels
established by SARA Title III, Section 313.

Clean Air Act

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Page 8 of 9
SAFETY DATA SHEET

H.B. Fuller APS GEL
Version 1.1 Revision Date 01/05/2022

8 / 9

This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean
Air Act Section 112 (40 CFR 61).

US State Regulations
California Prop 65 : Please contact Supplier for more information.

The ingredients of this product are reported in the following inventories:
TSCA All substances listed as active on the TSCA inventory

DSL All components of this product are on the Canadian DSL

AIIC On the inventory, or in compliance with the inventory

ENCS On the inventory, or in compliance with the inventory

KECI On the inventory, or in compliance with the inventory

PICCS On the inventory, or in compliance with the inventory

IECSC On the inventory, or in compliance with the inventory
Inventories LegendTSCA (USA), DSL (Canada), REACH(Europe), AIIC (Australia), NZIoC (New
Zealand), ENCS (Japan), KECI (Korea), PICCS (Philippines), IECSC (China), TWINV (Taiwan)

SECTION 16. OTHER INFORMATION

Prepared by: Global Regulatory Office – phone: 1-651-236-5842 – email: msds.request@hbfuller.com

Further information

NFPA: HMIS III:

The information and recommendations set forth herein are believed to be accurate. Because some of
the information is derived from information provided to the H.B. Fuller Company from its suppliers, and
because the H.B. Fuller Company has no control over the conditions of handling and use, the H.B.
Flammability

Health

Instability

2
2

0

Special hazard
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
2

0

2

0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic

Print Date 03/10/2022
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SAFETY DATA SHEET

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Version 1.1 Revision Date 01/05/2022

9 / 9

Fuller Company makes no warranty, expressed or implied, regarding the accuracy of the data or the
results to be obtained from the use thereof. The information is supplied solely for your information and
consideration, and the H.B. Fuller Company assumes no responsibility for use or reliance thereon. It is
the responsibility of the user of H.B. Fuller Company products to comply with all applicable federal,
state and local laws and regulations.

23MRP24060_SDS.pdf

by | Sep 27, 2025

Print Date 07/25/2023
Page 1 of 9
SAFETY DATA SHEET

H.B. Fuller RP-2400
Version 1.1 Revision Date 10/26/2021

1 / 9

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : H.B. Fuller RP-2400
Product code : 100000009750
Manufacturer or supplier’s details
Company : H.B. Fuller Engineering Adhesives

Address : 9001 W Fey Drive
Frankfort, IL, 60423
Telephone : 1-815-464-5606

Medical Emergency Phone Number (24 Hours): 1-888-853-1758

Transport Emergency Phone Number (CHEMTREC): 1-800-424-9300

Recommended use of the chemical and restrictions on use
Recommended use : Cyanoacrylate Adhesive

Restrictions on use : For industrial use only.

SECTION 2. HAZARDS IDENTIFICATION

Emergency Overview
Appearance liquid
Color Clear liquid, light yellow to light green in color
Odor characteristic

GHS Classification
Flammable liquids : Category 4
Skin irritation : Category 2
Eye irritation : Category 2A
Skin sensitization : Category 1
Carcinogenicity : Category 2
Specific target organ toxicity –
single exposure
: Category 3 (Respiratory system)
GHS label elements
Hazard pictograms :

Signal Word : Warning

Hazard Statements:

Print Date 07/25/2023
Page 2 of 9
SAFETY DATA SHEET

H.B. Fuller RP-2400
Version 1.1 Revision Date 10/26/2021

2 / 9

H227 Combustible liquid. H315 Causes skin irritation. H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation. H335 May cause respiratory irritation. H351 Suspected of
causing cancer.
Precautionary Statements:
Prevention: P201 Obtain special instructions before use. P202 Do not handle until all safety
precautions have been read and understood. P210 Keep away from heat/ sparks/ open flames/ hot
surfaces. No smoking. P261 Avoid breathing mist or vapors. P264 Wash skin thoroughly after
handling. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing
must not be allowed out of the workplace. P280 Wear protective gloves/ protective clothing/ eye
protection/ face protection.
Response: P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P304 + P340 + P312 IF
INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON
CENTER/ doctor if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 +
P313 IF exposed or concerned: Get medical advice/ attention. P333 + P313 If skin irritation or rash
occurs: Get medical advice/ attention. P337 + P313 If eye irritation persists: Get medical advice/
attention. P362 Take off contaminated clothing and wash before reuse. P370 + P378 In case of fire:
Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
Storage: P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235
Store in a well-ventilated place. Keep cool. P405 Store locked up.
Disposal: P501 Dispose of contents/ container to an approved waste disposal plant.
Potential Health Effects

Carcinogenicity:
IARC No ingredient of this product present at levels greater than or
equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.
OSHA No component of this product present at levels greater than or
equal to 0.1% is on OSHA s list of regulated carcinogens.
NTP No ingredient of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

Hazardous ingredients
Chemical name CAS-No. Concentration [%]
ethyl 2-cyanoacrylate 7085-85-0 70 – 90
hydroquinone 123-31-9 0.1 – 1
Actual concentration is withheld as a trade secret

SECTION 4. FIRST AID MEASURES

General advice : Show this material safety data sheet to the doctor in
attendance.

If inhaled : Move to fresh air.

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H.B. Fuller RP-2400
Version 1.1 Revision Date 10/26/2021

3 / 9

If not breathing, give artificial respiration.
Keep patient warm and at rest.
Consult a physician after significant exposure.

In case of skin contact : Wash off immediately with soap and plenty of water.
Call a physician if irritation develops or persists.
Cyanoacrylate. Danger. Bonds skin and eyes in seconds.
Keep out of the reach of children.

In case of eye contact : Rinse immediately with plenty of water, also under the eyelids.
Seek medical advice.

If swallowed : If swallowed, call a poison control center or doctor
immediately.
Do not induce vomiting without medical advice.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or
carbon dioxide.

Unsuitable extinguishing
media
: Water spray jet

Hazardous combustion
products
: Nitrogen oxides (NOx)
Specific extinguishing
methods
:
Further information : Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.

Special protective equipment
for fire-fighters
: Wear an approved positive pressure self-contained breathing
apparatus in addition to standard fire fighting gear.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions,
protective equipment and
emergency procedures
: Refer to protective measures listed in sections 7 and 8.
Ensure adequate ventilation.

Environmental precautions : Prevent product from entering drains.
Do not flush into surface water or sanitary sewer system.

Methods and materials for
containment and cleaning up
: Allow to solidify.
Pick up and transfer to properly labeled containers.
Ventilate the area.

SECTION 7. HANDLING AND STORAGE

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4 / 9

Local/Total ventilation : Use only with adequate ventilation.

Advice on safe handling : Wear personal protective equipment.
Do not get on skin or clothing.
Use only in an area equipped with a safety shower.

Conditions for safe storage : Keep containers tightly closed in a dry, cool and well-
ventilated place.
Store in original container.

Materials to avoid : Do not store together with oxidizing and self-igniting products.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters
Components CAS-No. Value type
(Form of
exposure)
Control
parameters /
Permissible
concentration
Basis
ethyl 2-cyanoacrylate 7085-85-0 PEL 0.2 ppm
1.02 mg/m3
CAL PEL
TWA 0.2 ppm ACGIH
STEL 1 ppm ACGIH
hydroquinone 123-31-9 TWA 1 mg/m3 ACGIH
TWA 2 mg/m3 OSHA Z-1
TWA 2 mg/m3 OSHA P0
PEL 2 mg/m3 CAL PEL

Personal protective equipment
Respiratory protection : Use respiratory protection unless adequate local exhaust
ventilation is provided or exposure assessment demonstrates
that exposures are within recommended exposure guidelines.

Filter type : Combined particulates and organic vapor type

Hand protection
Material : Nitrile rubber
Remarks : Do not wear cotton or natural fiber gloves.

Eye protection : Tightly fitting safety goggles
Ensure that eyewash stations and safety showers are close to
the workstation location.

Skin and body protection : Long sleeved clothing
Preventive skin protection

Protective measures : Avoid contact with skin.

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Hygiene measures : Avoid contact with skin, eyes and clothing.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid
Color : Clear liquid, light yellow to light green in color
Odor : characteristic
Odor Threshold : No data available
pH : is not determined
Melting point/freezing point : is not determined
Boiling point/boiling range : is not determined
Flash point : 83 C
Not applicable
Evaporation rate : is not determined
Flammability (solid, gas) : Not classified as a flammability hazard

Upper explosion limit : Upper flammability limit
is not determined
Lower explosion limit : Lower flammability limit
is not determined
Vapor pressure : is not determined
Density : 1.06 g/cm3
Solubility(ies)
Water solubility : is not determined
Partition coefficient: n-
octanol/water
: No data available
Autoignition temperature : is not determined
Viscosity
Viscosity, kinematic : is not determined

SECTION 10. STABILITY AND REACTIVITY

Chemical stability : The product is chemically stable.

Hazardous decomposition
products
: Stable under normal conditions.

SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity
Product:

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Acute dermal toxicity : Acute toxicity estimate : > 5,000 mg/kg
Method: Calculation method

Components:
hydroquinone:
Acute oral toxicity : LD50 Oral Rat: 320 mg/kg

Acute dermal toxicity : LD50 Dermal Rat: > 900 mg/kg

Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitization
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
No data available
Reproductive toxicity
No data available
STOT-single exposure
No data available
STOT-repeated exposure
No data available
Aspiration toxicity
No data available

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

Components:
hydroquinone :
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 0.044 mg/l
Exposure time: 96 h
Test Method: flow-through test

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 0.29 mg/l

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aquatic invertebrates Exposure time: 48 h
Test Method: static test

Toxicity to algae : EC50 (Pseudokirchneriella subcapitata (microalgae)): 0.335
mg/l
Exposure time: 72 h
Test Type: flow-through test

Persistence and degradability
No data available
Bioaccumulative potential
Mobility in soil
No data available
Other adverse effects
No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : Do not dispose of together with household waste.
Do not dispose of waste into sewer.
To the best of our knowledge, this product does not meet the
definition of hazardous waste under the U.S. EPA Hazardous
Waste Regulations 40 CFR 261. Disposal via incineration at
an approved facility is recommended, as industry best
practice. Consult state, local or provincial authorities for more
restrictive requirements.

SECTION 14. TRANSPORT INFORMATION
International Regulations
UNRTDG
Not regulated as a dangerous good
IATA-DGR
Not regulated as a dangerous good
IMDG-Code
Not regulated as a dangerous good
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Domestic regulation
49 CFR
UN/ID/NA number : NA 1993

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8 / 9

Proper shipping name : Combustible liquid, n.o.s.
(ethyl 2-cyanoacrylate)
Class : CBL
Packing group : III
ERG Code : 128
Marine pollutant : no
Special precautions for user
The transport classification(s) provided herein are for informational purposes only, and solely
based upon the properties of the unpackaged material as it is described within this Safety Data
Sheet. Transportation classifications may vary by mode of transportation, package sizes, and
variations in regional or country regulations.

SECTION 15. REGULATORY INFORMATION

SARA 311/312 Hazards : Flammable (gases, aerosols, liquids, or solids)
Respiratory or skin sensitization
Carcinogenicity
Skin corrosion or irritation
Serious eye damage or eye irritation
Specific target organ toxicity (single or repeated exposure)

SARA 302 : This material does not contain any components with a section 302
EHS TPQ.

SARA 313 : This material does not contain any chemical components with known
CAS numbers that exceed the threshold (De Minimis) reporting levels
established by SARA Title III, Section 313.

Clean Air Act

The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 112 (40 CFR
61):
hydroquinone 123-31-9

US State Regulations
California Prop 65 Please contact Supplier for more information.

The ingredients of this product are reported in the following inventories:
TSCA All substances listed as active on the TSCA inventory
DSL All components of this product are on the Canadian DSL
AIIC On the inventory, or in compliance with the inventory
KECI On the inventory, or in compliance with the inventory
PICCS On the inventory, or in compliance with the inventory
IECSC On the inventory, or in compliance with the inventory

Print Date 07/25/2023
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Inventories LegendTSCA (USA), DSL (Canada), REACH(Europe), AIIC (Australia), NZIoC (New
Zealand), ENCS (Japan), KECI (Korea), PICCS (Philippines), IECSC (China), TWINV (Taiwan)

SECTION 16. OTHER INFORMATION

Prepared by: Global Regulatory Office – phone: 1-651-236-5842 – email: msds.request@hbfuller.com

Further information

NFPA: HMIS III:

The information and recommendations set forth herein are believed to be accurate. Because some of
the information is derived from information provided to the H.B. Fuller Company from its suppliers, and
because the H.B. Fuller Company has no control over the conditions of handling and use, the H.B.
Fuller Company makes no warranty, expressed or implied, regarding the accuracy of the data or the
results to be obtained from the use thereof. The information is supplied solely for your information and
consideration, and the H.B. Fuller Company assumes no responsibility for use or reliance thereon. It is
the responsibility of the user of H.B. Fuller Company products to comply with all applicable federal,
state and local laws and regulations.

Flammability

Health

Instability

2
2

0

Special hazard
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
2

0

2*

0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic

23MP5523-49_SDS.pdf

by | Sep 27, 2025

Print Date 05/12/2021
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SAFETY DATA SHEET

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SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : ASI MP-55320-A
Product code : 100000007520
Manufacturer or supplier’s details
Company : H.B. Fuller Engineering Adhesives

Address : 9001 W Fey Drive
Frankfort, IL, 60423
Telephone : 1-815-464-5606

Medical Emergency Phone Number (24 Hours): 1-888-853-1758

Transport Emergency Phone Number (CHEMTREC): 1-800-424-9300

Recommended use of the chemical and restrictions on use
Recommended use : Adhesive

Restrictions on use : For industrial use only.

SECTION 2. HAZARDS IDENTIFICATION

Emergency Overview
Appearance liquid
Color No data available
Odor characteristic

GHS Classification
Flammable liquids : Category 2
Skin corrosion : Category 1A
Serious eye damage : Category 1
Skin sensitization : Category 1
Specific target organ toxicity –
single exposure
: Category 3 (Respiratory system)
GHS label elements
Hazard pictograms :

Signal Word : Danger

Hazard Statements:
H225 Highly flammable liquid and vapor. H314 Causes severe skin burns and eye damage. H317

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May cause an allergic skin reaction. H335 May cause respiratory irritation.
Precautionary Statements:
Prevention: P210 Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking. P233
Keep container tightly closed. P240 Ground/bond container and receiving equipment. P241 Use
explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use only non-sparking tools. P243
Take precautionary measures against static discharge. P261 Avoid breathing dust/ fume/ gas/ mist/
vapors/ spray. P264 Wash skin thoroughly after handling. P271 Use only outdoors or in a well-
ventilated area. P272 Contaminated work clothing must not be allowed out of the workplace. P280
Wear protective gloves/ protective clothing/ eye protection/ face protection.
Response: P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 +
P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water/ shower. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep
comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 +
P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Immediately call a POISON CENTER. P333 + P313 If
skin irritation or rash occurs: Get medical advice/ attention. P363 Wash contaminated clothing
before reuse. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to
extinguish.
Storage: P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235
Store in a well-ventilated place. Keep cool. P405 Store locked up.
Disposal: P501 Dispose of contents/ container to an approved waste disposal plant.
Potential Health Effects

Carcinogenicity:
IARC Group 2B: Possibly carcinogenic to humans
N,N-dimethyl-p-toluidine

99-97-8
OSHA No component of this product present at levels greater than or
equal to 0.1% is on OSHA s list of regulated carcinogens.
NTP No ingredient of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

Hazardous ingredients
Chemical name CAS-No. Concentration [%]
methyl methacrylate 80-62-6 50 – 70
methacrylic acid 79-41-4 5 – 10
N,N-dimethyl-p-toluidine 99-97-8 0.1 – 1
Rosin 8050-09-7 0.1 – 1
2-Propenoic acid, 2-methyl-, 2-hydroxyethyl ester,
phosphate
52628-03-2 0.1 – 1
Actual concentration is withheld as a trade secret

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SECTION 4. FIRST AID MEASURES

General advice : Show this material safety data sheet to the doctor in
attendance.

If inhaled : Move to fresh air.
Keep patient warm and at rest.
Consult a physician after significant exposure.

In case of skin contact : Wash off immediately with soap and plenty of water.
Call a physician if irritation develops or persists.

In case of eye contact : Rinse immediately with plenty of water, also under the eyelids.
Seek medical advice.

If swallowed : If swallowed, call a poison control center or doctor
immediately.
Do not induce vomiting without medical advice.
Drink plenty of water.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Carbon dioxide (CO2)
Sand
Foam

Unsuitable extinguishing
media
: Water

Hazardous combustion
products
: No hazardous combustion products are known
Specific extinguishing
methods
:
Further information : Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.

Special protective equipment
for fire-fighters
: Wear an approved positive pressure self-contained breathing
apparatus in addition to standard fire fighting gear.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions,
protective equipment and
emergency procedures
: Refer to protective measures listed in sections 7 and 8.
Ensure adequate ventilation.

Environmental precautions : Prevent product from entering drains.
Do not flush into surface water or sanitary sewer system.

Methods and materials for
containment and cleaning up
: Ventilate the area.
Soak up with inert absorbent material.

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Use neutralizing agents.
Shovel or sweep up.

SECTION 7. HANDLING AND STORAGE

Local/Total ventilation : Use only with adequate ventilation.

Advice on safe handling : Wear personal protective equipment.
Do not get on skin or clothing.
Keep away from heat and flame.

Conditions for safe storage : Keep containers tightly closed in a dry, cool and well-
ventilated place.
Store in original container.

Materials to avoid : Do not store together with oxidizing and self-igniting products.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters
Components CAS-No. Value type
(Form of
exposure)
Control
parameters /
Permissible
concentration
Basis
methyl methacrylate 80-62-6 TWA 50 ppm ACGIH
STEL 100 ppm ACGIH
TWA 100 ppm
410 mg/m3
OSHA Z-1
TWA 100 ppm
410 mg/m3
OSHA P0
PEL 50 ppm
205 mg/m3
CAL PEL
STEL 100 ppm
410 mg/m3
CAL PEL
methacrylic acid 79-41-4 TWA 20 ppm ACGIH
TWA 20 ppm
70 mg/m3
OSHA P0
PEL 20 ppm
70 mg/m3
CAL PEL

Personal protective equipment
Respiratory protection : Use respiratory protection unless adequate local exhaust
ventilation is provided or exposure assessment demonstrates
that exposures are within recommended exposure guidelines.

Filter type : Combined particulates and organic vapor type

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Hand protection
Material : Impervious gloves

Eye protection : Tightly fitting safety goggles
Ensure that eyewash stations and safety showers are close to
the workstation location.

Skin and body protection : Long sleeved clothing
Preventive skin protection

Protective measures : Avoid contact with skin.

Hygiene measures : Avoid contact with skin, eyes and clothing.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid
Color : No data available
Odor : characteristic
Odor Threshold : No data available
Melting point/freezing point : is not determined
Boiling point/boiling range : is not determined
Flash point : 11 C
Evaporation rate : is not determined
Flammability (solid, gas) : Not classified as a flammability hazard

Upper explosion limit : Upper flammability limit
is not determined
Lower explosion limit : Lower flammability limit
is not determined
Vapor pressure : is not determined
Density : 0.94 g/cm3
Solubility(ies)
Water solubility : is not determined
Partition coefficient: n-
octanol/water
: No data available
Autoignition temperature : is not determined
Viscosity
Viscosity, kinematic : is not determined

SECTION 10. STABILITY AND REACTIVITY

Chemical stability : The product is chemically stable.

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Hazardous decomposition
products
: Nitrogen oxides (NOx)
Sulfur oxides

SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity
Product:
Acute oral toxicity : Acute toxicity estimate : > 5,000 mg/kg
Method: Calculation method

Acute inhalation toxicity : Acute toxicity estimate : 5.02 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Method: Calculation method

Acute dermal toxicity : Acute toxicity estimate : > 5,000 mg/kg
Method: Calculation method

Components:
methyl methacrylate:
Acute inhalation toxicity : LC50 Rat: 4632 ppm
Exposure time: 4 h
Test atmosphere: vapor

methacrylic acid:
Acute inhalation toxicity : LC50 Rat: 7.1 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist

Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitization
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
No data available
Reproductive toxicity

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No data available
STOT-single exposure
No data available
STOT-repeated exposure
No data available
Aspiration toxicity
No data available

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

Components:
methyl methacrylate :
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): > 79 mg/l
Exposure time: 96 h
Test Method: flow-through test

Toxicity to daphnia and other
aquatic invertebrates
: EC50 (Daphnia magna (Water flea)): 69 mg/l
Exposure time: 48 h
Test Method: static test

N,N-dimethyl-p-toluidine :
Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 42 – 50.5 mg/l
Exposure time: 96 h
Test Method: flow-through test

Rosin :
Toxicity to daphnia and other
aquatic invertebrates
: EC50 (Daphnia magna (Water flea)): 3.8 – 5.4 mg/l
Exposure time: 48 h
Test Method: static test

Persistence and degradability
No data available
Bioaccumulative potential
Mobility in soil
No data available
Other adverse effects
No data available

SECTION 13. DISPOSAL CONSIDERATIONS

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Version 1.2 Revision Date 05/11/2021

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Disposal methods
Waste from residues : Do not dispose of together with household waste.
Do not dispose of waste into sewer.
To the best of our knowledge, this product does not meet the
definition of hazardous waste under the U.S. EPA Hazardous
Waste Regulations 40 CFR 261. Disposal via incineration at
an approved facility is recommended, as industry best
practice. Consult state, local or provincial authorities for more
restrictive requirements.

SECTION 14. TRANSPORT INFORMATION
International Regulations
IATA-DGR
UN/ID No. : UN 2920
Proper shipping name : Corrosive liquid, flammable, n.o.s.
(METHACRYLIC ACID, METHYLMETHACRYLATE )
Class : 8
Subsidiary risk : 3
Packing group : II
Labels : Corrosive, Flammable Liquids
Packing instruction (cargo
aircraft)
: 855
Packing instruction
(passenger aircraft)
: 851
IMDG-Code
UN number : UN 2920
Proper shipping name : CORROSIVE LIQUID, FLAMMABLE, N.O.S.
(METHACRYLIC ACID, METHYLMETHACRYLATE )
Class : 8
Subsidiary risk : 3
Packing group : II
Labels : 8 (3)
EmS Code : F-E, S-C
Marine pollutant : no
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Domestic regulation
49 CFR
UN/ID/NA number : UN 2920
Proper shipping name : Corrosive liquids, flammable, n.o.s.
(METHACRYLIC ACID, METHYLMETHACRYLATE )
Class : 8
Subsidiary risk : 3
Packing group : II
Labels : CORROSIVE, FLAMMABLE LIQUID
ERG Code : 132

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Marine pollutant : no
Special precautions for user
The transport classification(s) provided herein are for informational purposes only, and solely
based upon the properties of the unpackaged material as it is described within this Safety Data
Sheet. Transportation classifications may vary by mode of transportation, package sizes, and
variations in regional or country regulations.

SECTION 15. REGULATORY INFORMATION

SARA 311/312 Hazards : Flammable (gases, aerosols, liquids, or solids)
Respiratory or skin sensitization
Skin corrosion or irritation
Serious eye damage or eye irritation
Specific target organ toxicity (single or repeated exposure)

SARA 302 : This material does not contain any components with a section 302
EHS TPQ.

SARA 313 : The following components are subject to reporting levels established
by SARA Title III, Section 313:
methyl methacrylate 80-62-6

Clean Air Act

The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 112 (40 CFR
61):
methyl methacrylate 80-62-6

US State Regulations
California Prop 65 Please contact Supplier for more information.

The ingredients of this product are reported in the following inventories:
TSCA All substances listed as active on the TSCA inventory
DSL All components of this product are on the Canadian DSL
AIIC On the inventory, or in compliance with the inventory
KECI On the inventory, or in compliance with the inventory
Inventories LegendTSCA (USA), DSL (Canada), REACH(Europe), AICS (Australia), NZIoC
(New Zealand), ENCS (Japan), KECI (Korea), PICCS (Philippines), IECSC (China), TWINV
(Taiwan)

SECTION 16. OTHER INFORMATION

Print Date 05/12/2021
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SAFETY DATA SHEET

ASI MP-55320-A
Version 1.2 Revision Date 05/11/2021

10 / 10

Prepared by: Global Regulatory Department – phone: 1-651-236-5842 – email:
msds.request@hbfuller.com

Further information

NFPA: HMIS III:

The information and recommendations set forth herein are believed to be accurate. Because some of
the information is derived from information provided to the H.B. Fuller Company from its suppliers, and
because the H.B. Fuller Company has no control over the conditions of handling and use, the H.B.
Fuller Company makes no warranty, expressed or implied, regarding the accuracy of the data or the
results to be obtained from the use thereof. The information is supplied solely for your information and
consideration, and the H.B. Fuller Company assumes no responsibility for use or reliance thereon. It is
the responsibility of the user of H.B. Fuller Company products to comply with all applicable federal,
state and local laws and regulations.

Flammability

Health

Instability

3
3

0

Special hazard
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
3

0

3*

0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic

Print Date 05/12/2021
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SAFETY DATA SHEET

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Version 1.1 Revision Date 04/23/2021

1 / 12

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : ASI MP-55320-B
Product code : 100000007007
Manufacturer or supplier’s details
Company : H.B. Fuller Engineering Adhesives

Address : 9001 W Fey Drive
Frankfort, IL, 60423
Telephone : 1-815-464-5606

Medical Emergency Phone Number (24 Hours): 1-888-853-1758

Transport Emergency Phone Number (CHEMTREC): 1-800-424-9300

Recommended use of the chemical and restrictions on use
Recommended use : Activator

Restrictions on use : For industrial use only.

SECTION 2. HAZARDS IDENTIFICATION

Emergency Overview
Appearance solid
Color yellow
Odor characteristic

GHS Classification
Skin irritation : Category 2
Eye irritation : Category 2A
Skin sensitization : Category 1
Carcinogenicity : Category 2
Reproductive toxicity : Category 1B
Specific target organ toxicity –
repeated exposure
: Category 2
GHS label elements
Hazard pictograms :

Signal Word : Danger

Hazard Statements:

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SAFETY DATA SHEET

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H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye
irritation. H351 Suspected of causing cancer. H360 May damage fertility or the unborn child. H373
May cause damage to organs through prolonged or repeated exposure.
Precautionary Statements:
Prevention: P201 Obtain special instructions before use. P202 Do not handle until all safety
precautions have been read and understood. P260 Do not breathe dust/ fume/ gas/ mist/ vapors/
spray. P264 Wash skin thoroughly after handling. P272 Contaminated work clothing must not be
allowed out of the workplace. P280 Wear protective gloves/ protective clothing/ eye protection/ face
protection.
Response: P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P305 + P351 + P338 IF
IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/ attention.
P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention. P337 + P313 If eye
irritation persists: Get medical advice/ attention. P362 Take off contaminated clothing and wash
before reuse.
Storage: P405 Store locked up.
Disposal: P501 Dispose of contents/ container to an approved waste disposal plant.
Potential Health Effects

Carcinogenicity:
IARC Group 2B: Possibly carcinogenic to humans
cumene

98-82-8
OSHA No component of this product present at levels greater than or
equal to 0.1% is on OSHA s list of regulated carcinogens.
NTP Reasonably anticipated to be a human carcinogen
cumene

98-82-8

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

Hazardous ingredients
Chemical name CAS-No. Concentration [%]
dibenzoyl peroxide 94-36-0 20 – 30
Epoxy resin 25068-38-6 10 – 20
dibutyl phthalate 84-74-2 10 – 20
zinc distearate 557-05-1 1 – 5
calcium sulfate 7778-18-9 1 – 5
, -dimethylbenzyl hydroperoxide 80-15-9 1 – 3
Silica, amorphous fumed 112945-52-5 1 – 5
2,6-di-tert-butyl-p-cresol 128-37-0 1 – 5
cumene 98-82-8 0.1 – 1

SECTION 4. FIRST AID MEASURES

General advice : Show this material safety data sheet to the doctor in

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attendance.

If inhaled : Move to fresh air.
Keep patient warm and at rest.
Consult a physician after significant exposure.

In case of skin contact : Wash off immediately with soap and plenty of water.
Call a physician if irritation develops or persists.

In case of eye contact : Rinse immediately with plenty of water, also under the eyelids.
Seek medical advice.

If swallowed : If swallowed, call a poison control center or doctor
immediately.
Do not induce vomiting without medical advice.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Carbon dioxide (CO2)
Sand
Foam

Unsuitable extinguishing
media
: Water

Hazardous combustion
products
: No hazardous combustion products are known
Specific extinguishing
methods
:
Further information : Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.

Special protective equipment
for fire-fighters
: Wear an approved positive pressure self-contained breathing
apparatus in addition to standard fire fighting gear.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions,
protective equipment and
emergency procedures
: Refer to protective measures listed in sections 7 and 8.
Ensure adequate ventilation.

Environmental precautions : Prevent product from entering drains.
Do not flush into surface water or sanitary sewer system.

Methods and materials for
containment and cleaning up
: Ventilate the area.
Soak up with inert absorbent material.
Do not flush with water.
Shovel or sweep up.

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SECTION 7. HANDLING AND STORAGE

Local/Total ventilation : Use only with adequate ventilation.

Advice on safe handling : Wear personal protective equipment.
Do not get on skin or clothing.
Keep away from heat and flame.

Conditions for safe storage : Keep containers tightly closed in a dry, cool and well-
ventilated place.
Store in original container.

Materials to avoid : Do not store together with oxidizing and self-igniting products.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters
Components CAS-No. Value type
(Form of
exposure)
Control
parameters /
Permissible
concentration
Basis
dibenzoyl peroxide 94-36-0 TWA 5 mg/m3 ACGIH
TWA 5 mg/m3 NIOSH REL
TWA 5 mg/m3 OSHA Z-1
TWA 5 mg/m3 OSHA P0
PEL 5 mg/m3 CAL PEL
dibutyl phthalate 84-74-2 TWA 5 mg/m3 ACGIH
TWA 5 mg/m3 OSHA Z-1
TWA 5 mg/m3 OSHA P0
PEL 5 mg/m3 CAL PEL
zinc distearate 557-05-1 TWA (total
dust)
15 mg/m3 OSHA Z-1
TWA
(respirable
fraction)
5 mg/m3 OSHA Z-1
TWA (Total) 10 mg/m3 OSHA P0
TWA
(Respirable
fraction)
5 mg/m3 OSHA P0
TWA 10 mg/m3 ACGIH
TWA (Total
dust)
10 mg/m3 OSHA P0
TWA
(respirable
dust fraction)
5 mg/m3 OSHA P0
PEL 10 mg/m3 CAL PEL
TWA
(Inhalable
10 mg/m3 ACGIH

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particulate
matter)
TWA
(Respirable
particulate
matter)
3 mg/m3 ACGIH
calcium sulfate 7778-18-9 TWA (total
dust)
15 mg/m3 OSHA Z-1
TWA
(respirable
fraction)
5 mg/m3 OSHA Z-1
TWA (Total) 15 mg/m3 OSHA P0
TWA
(Respirable
fraction)
5 mg/m3 OSHA P0
TWA
(Inhalable
particulate
matter)
10 mg/m3 ACGIH
TWA (Total
dust)
15 mg/m3 OSHA P0
TWA
(respirable
dust fraction)
5 mg/m3 OSHA P0
PEL (Total
dust)
10 mg/m3 CAL PEL
PEL
(respirable
dust fraction)
5 mg/m3 CAL PEL
TWA
(Inhalable
particulate
matter)
10 mg/m3 ACGIH
Silica, amorphous fumed 112945-52-5 TWA (Dust) 20 Million
particles per cubic
foot
OSHA Z-3
TWA (Dust) 80 mg/m3
/ %SiO2
OSHA Z-3
TWA (Dust) 20 Million
particles per cubic
foot
OSHA Z-3
TWA (Dust) 80 mg/m3
/ %SiO2
OSHA Z-3
2,6-di-tert-butyl-p-cresol 128-37-0 TWA
(Inhalable
fraction and
vapor)
2 mg/m3 ACGIH
TWA 10 mg/m3 OSHA P0
PEL 10 mg/m3 CAL PEL
cumene 98-82-8 TWA 50 ppm ACGIH
TWA 50 ppm
245 mg/m3
NIOSH REL

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TWA 50 ppm
245 mg/m3
OSHA Z-1
TWA 50 ppm
245 mg/m3
OSHA P0
PEL 50 ppm
245 mg/m3
CAL PEL

Personal protective equipment
Respiratory protection : Use respiratory protection unless adequate local exhaust
ventilation is provided or exposure assessment demonstrates
that exposures are within recommended exposure guidelines.

Filter type : Combined particulates and organic vapor type

Hand protection
Material : Impervious gloves

Eye protection : Tightly fitting safety goggles
Ensure that eyewash stations and safety showers are close to
the workstation location.

Skin and body protection : Long sleeved clothing
Preventive skin protection

Protective measures : Avoid contact with skin.

Hygiene measures : Avoid contact with skin, eyes and clothing.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : solid
Color : yellow
Odor : characteristic
Odor Threshold : No data available
Melting point/freezing point : is not determined
Boiling point/boiling range : is not determined
Evaporation rate : is not determined
Flammability (solid, gas) : Not classified as a flammability hazard

Upper explosion limit : Upper flammability limit
is not determined
Lower explosion limit : Lower flammability limit
is not determined
Vapor pressure : is not determined
Density : 0.94 g/cm3
Solubility(ies)

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Water solubility : is not determined
Partition coefficient: n-
octanol/water
: No data available
Autoignition temperature : is not determined
Viscosity
Viscosity, kinematic : is not determined

SECTION 10. STABILITY AND REACTIVITY

Chemical stability : The product is chemically stable.

Hazardous decomposition
products
: Nitrogen oxides (NOx)
Sulfur oxides

SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity
Product:
Acute oral toxicity : Acute toxicity estimate : > 5,000 mg/kg
Method: Calculation method

Acute inhalation toxicity : Acute toxicity estimate : 175.15 mg/l
Exposure time: 4 h
Test atmosphere: vapor
Method: Calculation method

Acute dermal toxicity : Acute toxicity estimate : > 5,000 mg/kg
Method: Calculation method

Components:
, -dimethylbenzyl hydroperoxide:
Acute oral toxicity : LD50 Oral Rat: 382 mg/kg

Acute inhalation toxicity : LC50 Rat: 220 ppm
Exposure time: 4 h
Test atmosphere: vapor

Acute dermal toxicity : LD50 Dermal Rat: 500 mg/kg

2,6-di-tert-butyl-p-cresol:
Acute oral toxicity : LD50 Oral Rat: 6,000 mg/kg

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cumene:
Acute oral toxicity : LD50 Oral Rat: 1,400 mg/kg

Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitization
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
No data available
Reproductive toxicity
No data available
STOT-single exposure
No data available
STOT-repeated exposure
No data available
Aspiration toxicity
No data available

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

Components:
dibutyl phthalate :
Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 0.31 – 5.45
mg/l
Exposure time: 96 h
Test Method: static test

Toxicity to daphnia and other
aquatic invertebrates
: EC50 (Daphnia magna (Water flea)): 2.99 mg/l
Exposure time: 48 h
Test Method: static test

Toxicity to algae : EC50 (Pseudokirchneriella subcapitata (microalgae)): 0.4 mg/l
Exposure time: 96 h
Test Type: static test

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calcium sulfate :
Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): > 1,970 mg/l
Exposure time: 96 h
Test Method: static test

, -dimethylbenzyl hydroperoxide :
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 3.9 mg/l
Exposure time: 96 h
Test Method: static test

Toxicity to daphnia and other
aquatic invertebrates
: EC50 (Daphnia magna (Water flea)): 7 mg/l
Exposure time: 24 h
Test Method: static test

2,6-di-tert-butyl-p-cresol :
Toxicity to fish : LC50 (Oryzias latipes (Japanese medaka)): 5 mg/l
Exposure time: 48 h
Test Method: static test

Toxicity to algae : EC50 (Desmodesmus subspicatus (green algae)): > 0.42 mg/l
Exposure time: 72 h
Test Type: flow-through test

cumene :
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 2.7 mg/l
Exposure time: 96 h
Test Method: semi-static test

Toxicity to daphnia and other
aquatic invertebrates
: EC50 (Daphnia magna (Water flea)): 0.6 mg/l
Exposure time: 48 h
Test Method: static test

Toxicity to algae : EC50 (Pseudokirchneriella subcapitata (microalgae)): 2.6 mg/l
Exposure time: 72 h
Test Type: flow-through test

Persistence and degradability
No data available
Bioaccumulative potential
Mobility in soil
No data available
Other adverse effects
No data available

SECTION 13. DISPOSAL CONSIDERATIONS

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Disposal methods
Waste from residues : Do not dispose of together with household waste.
Do not dispose of waste into sewer.
To the best of our knowledge, this product does not meet the
definition of hazardous waste under the U.S. EPA Hazardous
Waste Regulations 40 CFR 261. Disposal via incineration at
an approved facility is recommended, as industry best
practice. Consult state, local or provincial authorities for more
restrictive requirements.

SECTION 14. TRANSPORT INFORMATION
International Regulations
IATA-DGR
UN/ID No. : UN 3077
Proper shipping name : Environmentally hazardous substance, solid, n.o.s.
(DIBUTYL PHTHALATE, EPOXY RESIN)
Class : 9
Packing group : III
Labels : Miscellaneous,
Packing instruction (cargo
aircraft)
: 956
Packing instruction
(passenger aircraft)
: 956
Remarks : PACKAGES <5 L NOT REGULATED, IATA 4.4, SP A197 IMDG-Code UN number : UN 3077 Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (DIBUTYL PHTHALATE, EPOXY RESIN ) Class : 9 Subsidiary risk : ENVIRONM. Packing group : III Labels : 9 (ENVIRONM.) EmS Code : F-A, S-F Marine pollutant : yes Remarks : PACKAGES <5 L NOT REGULATED, IMDG 3.3 SP 969 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. Domestic regulation 49 CFR UN/ID/NA number : UN 3077 Proper shipping name : Environmentally hazardous substance, solid, n.o.s. (DIBUTYL PHTHALATE) Class : 9 Packing group : III Labels : CLASS 9 Print Date 05/12/2021 Page 11 of 12 SAFETY DATA SHEET ASI MP-55320-B Version 1.1 Revision Date 04/23/2021 11 / 12 ERG Code : 171 Marine pollutant : yes Remarks : PACKAGES <450 L NOT REGULATED, CFR 172.102 SP 149 Special precautions for user The transport classification(s) provided herein are for informational purposes only, and solely based upon the properties of the unpackaged material as it is described within this Safety Data Sheet. Transportation classifications may vary by mode of transportation, package sizes, and variations in regional or country regulations. SECTION 15. REGULATORY INFORMATION SARA 311/312 Hazards : Skin corrosion or irritation Serious eye damage or eye irritation Respiratory or skin sensitization Carcinogenicity Reproductive toxicity Specific target organ toxicity (single or repeated exposure) SARA 302 : This material does not contain any components with a section 302 EHS TPQ. SARA 313 : The following components are subject to reporting levels established by SARA Title III, Section 313: dibenzoyl peroxide 94-36-0 dibutyl phthalate 84-74-2 zinc distearate 557-05-1 , -dimethylbenzyl hydroperoxide 80-15-9 cumene 98-82-8 Clean Air Act The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 112 (40 CFR 61): dibutyl phthalate 84-74-2 cumene 98-82-8 US State Regulations California Prop 65 Please contact Supplier for more information. The ingredients of this product are reported in the following inventories: TSCA All substances listed as active on the TSCA inventory DSL All components of this product are on the Canadian DSL AIIC On the inventory, or in compliance with the inventory Print Date 05/12/2021 Page 12 of 12 SAFETY DATA SHEET ASI MP-55320-B Version 1.1 Revision Date 04/23/2021 12 / 12 KECI On the inventory, or in compliance with the inventory IECSC On the inventory, or in compliance with the inventory Inventories LegendTSCA (USA), DSL (Canada), REACH(Europe), AICS (Australia), NZIoC (New Zealand), ENCS (Japan), KECI (Korea), PICCS (Philippines), IECSC (China), TWINV (Taiwan) SECTION 16. OTHER INFORMATION Prepared by: Global Regulatory Department - phone: 1-651-236-5842 - email: msds.request@hbfuller.com Further information NFPA: HMIS III: The information and recommendations set forth herein are believed to be accurate. Because some of the information is derived from information provided to the H.B. Fuller Company from its suppliers, and because the H.B. Fuller Company has no control over the conditions of handling and use, the H.B. Fuller Company makes no warranty, expressed or implied, regarding the accuracy of the data or the results to be obtained from the use thereof. The information is supplied solely for your information and consideration, and the H.B. Fuller Company assumes no responsibility for use or reliance thereon. It is the responsibility of the user of H.B. Fuller Company products to comply with all applicable federal, state and local laws and regulations. Flammability Health Instability 2 1 0 Special hazard FLAMMABILITY PHYSICAL HAZARD HEALTH 1 0 2* 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic

23METYFIX3_SDS.pdf

by | Sep 27, 2025

Note: The hazard category numbers found in GHS classification in section 2
of this SDSs are NOT to be used to fill in the NFPA 704 diamond. Blue =
Health Red = Fire Yellow = Reactivity White = Special (Oxidizer or water
reactive substances)
METYFIX 3 SPRAY ADHESIVE AEROSOL, MULTI-PURPOSE SPRAY ADHESIVE
Chemwatch Hazard Alert Code: 4
METYX USA, INC.
Version No: 7.8
Safety Data Sheet according to OSHA HazCom Standard (2012) requirements
Issue Date: 20/03/2023
Print Date: 20/03/2023
S.GHS.USA.EN
SECTION 1 Identification
Product Identifier
Product name METYFIX 3 SPRAY ADHESIVE AEROSOL, MULTI-PURPOSE SPRAY ADHESIVE
Synonyms Not Available
Proper shipping name Aerosols, flammable, (each not exceeding 1 L capacity)
Other means of identificationNot Available
Recommended use of the chemical and restrictions on use
Relevant identified usesApplication is by spray atomisation from a hand held aerosol pack
Name, address, and telephone number of the chemical manufacturer, importer, or other responsible party
Registered company name METYX USA, INC.
Address 2504 Lowell Rd, Gastonia North Carolina 28054 United States
Telephone +1 (704) 824-1030
Fax Not Available
Website
Email info@metyxusa.com
Emergency phone number
Association / OrganisationCHEMWATCH EMERGENCY RESPONSE (24/7)
Emergency telephone
numbers
+1 855-237-5573
Other emergency telephone
numbers
+61 3 9573 3188
Once connected and if the message is not in your preferred language then please dial 01
Una vez conectado y si el mensaje no est en su idioma preferido, por favor marque 02
SECTION 2 Hazard(s) identification
Classification of the substance or mixture
Classification
Serious Eye Damage/Eye Irritation Category 2A, Specific Target Organ Toxicity – Single Exposure (Narcotic Effects) Category 3, Aerosols
Category 1, Skin Corrosion/Irritation Category 2, Hazardous to the Aquatic Environment Long-Term Hazard Category 3
Label elements
Hazard pictogram(s)
Signal word Danger
Hazard statement(s)
Not Available Page 1 continued…

CAS No Name
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
H222 Extremely flammable aerosol.
H315 Causes skin irritation.
H412 Harmful to aquatic life with long lasting effects.
Hazard(s) not otherwise classified
Not Applicable
Precautionary statement(s) Prevention
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Pressurized container: Do not pierce or burn, even after use.
P271 Use only outdoors or in a well-ventilated area.
P261 Avoid breathing gas.
P273 Avoid release to the environment.
P280 Wear protective gloves, protective clothing, eye protection and face protection.
P264 Wash all exposed external body areas thoroughly after handling.
Precautionary statement(s) Response
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312 Call a POISON CENTER/doctor/physician/first aider/if you feel unwell.
P337+P313 If eye irritation persists: Get medical advice/attention.
P302+P352 IF ON SKIN: Wash with plenty of water and soap.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P332+P313 If skin irritation occurs: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash it before reuse.
Precautionary statement(s) Storage
P405 Store locked up.
P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50 C/122 F.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
Precautionary statement(s) Disposal
P501 Dispose of contents/container to authorised hazardous or special waste collection point in accordance with any local regulation.
SECTION 3 Composition / information on ingredients
Substances
See section below for composition of Mixtures
Mixtures
%[weight]
79-20-9 20-40
64742-49-0* 5-25
106-97-8. 1-10
74-98-6 5-20
75-28-5. 1-10
75-37-6 5-20
The specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a trade secret.
SECTION 4 First-aid measures
Description of first aid measures
Eye Contact
If aerosols come in contact with the eyes:
Immediately hold the eyelids apart and flush the eye continuously for at least 15 minutes with fresh running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper
and lower lids.
Transport to hospital or doctor without delay.
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
Skin Contact
If solids or aerosol mists are deposited upon the skin:
Flush skin and hair with running water (and soap if available).
Remove any adhering solids with industrial skin cleansing cream.
methyl acetate
Hydrocarbons, C6-C7, n-alkanes, isoalkanes, cyclics, <5% n-hexane butane propane iso-butane 1,1-difluoroethane Version No: 7.8 Page 2 of 18 METYFIX 3 SPRAY ADHESIVE AEROSOL, MULTI-PURPOSE SPRAY ADHESIVE Issue Date: 20/03/2023 Print Date: 20/03/2023 Continued... DO NOT use solvents. Seek medical attention in the event of irritation. Inhalation If aerosols, fumes or combustion products are inhaled: Remove to fresh air. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures. If breathing is shallow or has stopped, ensure clear airway and apply resuscitation, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary. Transport to hospital, or doctor. Ingestion Immediately give a glass of water. First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor. If spontaneous vomiting appears imminent or occurs, hold patient's head down, lower than their hips to help avoid possible aspiration of vomitus. Most important symptoms and effects, both acute and delayed See Section 11 Indication of any immediate medical attention and special treatment needed For petroleum distillates In case of ingestion, gastric lavage with activated charcoal can be used promptly to prevent absorption - decontamination (induced emesis or lavage) is controversial and should be considered on the merits of each individual case; of course the usual precautions of an endotracheal tube should be considered prior to lavage, to prevent aspiration. Individuals intoxicated by petroleum distillates should be hospitalized immediately, with acute and continuing attention to neurologic and cardiopulmonary function. Positive pressure ventilation may be necessary. Acute central nervous system signs and symptoms may result from large ingestions of aspiration-induced hypoxia. After the initial episode,individuals should be followed for changes in blood variables and the delayed appearance of pulmonary oedema and chemical pneumonitis. Such patients should be followed for several days or weeks for delayed effects, including bone marrow toxicity, hepatic and renal impairment Individuals with chronic pulmonary disease will be more seriously impaired, and recovery from inhalation exposure may be complicated. Gastrointestinal symptoms are usually minor and pathological changes of the liver and kidneys are reported to be uncommon in acute intoxications. Chlorinated and non-chlorinated hydrocarbons may sensitize the heart to epinephrine and other circulating catecholamines so that arrhythmias may occur.Careful consideration of this potential adverse effect should precede administration of epinephrine or other cardiac stimulants and the selection of bronchodilators. Treat symptomatically. for simple esters: -------------------------------------------------------------- BASIC TREATMENT -------------------------------------------------------------- Establish a patent airway with suction where necessary. Watch for signs of respiratory insufficiency and assist ventilation as necessary. Administer oxygen by non-rebreather mask at 10 to 15 l/min. Monitor and treat, where necessary, for pulmonary oedema . Monitor and treat, where necessary, for shock. DO NOT use emetics. Where ingestion is suspected rinse mouth and give up to 200 ml water (5 ml/kg recommended) for dilution where patient is able to swallow, has a strong gag reflex and does not drool. Give activated charcoal. -------------------------------------------------------------- ADVANCED TREATMENT -------------------------------------------------------------- Consider orotracheal or nasotracheal intubation for airway control in unconscious patient or where respiratory arrest has occurred. Positive-pressure ventilation using a bag-valve mask might be of use. Monitor and treat, where necessary, for arrhythmias. Start an IV D5W TKO. If signs of hypovolaemia are present use lactated Ringers solution. Fluid overload might create complications. Drug therapy should be considered for pulmonary oedema. Hypotension with signs of hypovolaemia requires the cautious administration of fluids. Fluid overload might create complications. Treat seizures with diazepam. Proparacaine hydrochloride should be used to assist eye irrigation. -------------------------------------------------------------- EMERGENCY DEPARTMENT -------------------------------------------------------------- Laboratory analysis of complete blood count, serum electrolytes, BUN, creatinine, glucose, urinalysis, baseline for serum aminotransferases (ALT and AST), calcium, phosphorus and magnesium, may assist in establishing a treatment regime. Other useful analyses include anion and osmolar gaps, arterial blood gases (ABGs), chest radiographs and electrocardiograph. Positive end-expiratory pressure (PEEP)-assisted ventilation may be required for acute parenchymal injury or adult respiratory distress syndrome. Consult a toxicologist as necessary. BRONSTEIN, A.C. and CURRANCE, P.L. EMERGENCY CARE FOR HAZARDOUS MATERIALS EXPOSURE: 2nd Ed. 1994 For acute and short term repeated exposures to methanol: Toxicity results from accumulation of formaldehyde/formic acid. Clinical signs are usually limited to CNS, eyes and GI tract Severe metabolic acidosis may produce dyspnea and profound systemic effects which may become intractable. All symptomatic patients should have arterial pH measured. Evaluate airway, breathing and circulation. Stabilise obtunded patients by giving naloxone, glucose and thiamine. Decontaminate with Ipecac or lavage for patients presenting 2 hours post-ingestion. Charcoal does not absorb well; the usefulness of cathartic is not established. Forced diuresis is not effective; haemodialysis is recommended where peak methanol levels exceed 50 mg/dL (this correlates with serum bicarbonate levels below 18 mEq/L). Ethanol, maintained at levels between 100 and 150 mg/dL, inhibits formation of toxic metabolites and may be indicated when peak methanol levels exceed 20 mg/dL. An intravenous solution of ethanol in D5W is optimal. Folate, as leucovorin, may increase the oxidative removal of formic acid. 4-methylpyrazole may be an effective adjunct in the treatment. 8.Phenytoin may be preferable to diazepam for controlling seizure. [Ellenhorn Barceloux: Medical Toxicology] Methanol poisoning can be treated with fomepizole, or if unavailable, ethanol. Both drugs act to reduce the action of alcohol dehydrogenase on methanol by means of competitive inhibition. Ethanol, the active ingredient in alcoholic beverages, acts as a competitive inhibitor by more effectively binding and saturating the alcohol dehydrogenase enzyme in the liver, thus blocking the binding of methanol. Methanol is excreted by the kidneys without being converted into the very toxic metabolites formaldehyde and formic acid. Alcohol dehydrogenase instead enzymatically converts ethanol to acetaldehyde, a much less toxic organic molecule. Additional treatment may include sodium bicarbonate for metabolic acidosis, and hemodialysis or hemodiafiltration to remove methanol and formate from the blood. Folinic acid or folic acid is also administered to enhance the metabolism of formate. BIOLOGICAL EXPOSURE INDEX - BEI Determinant Index Sampling Time Comment 1. Methanol in urine 15 mg/l End of shift B, NS 2. Formic acid in urine 80 mg/gm creatinine Before the shift at end of workweek B, NS Version No: 7.8 Page 3 of 18 METYFIX 3 SPRAY ADHESIVE AEROSOL, MULTI-PURPOSE SPRAY ADHESIVE Issue Date: 20/03/2023 Print Date: 20/03/2023 Continued... B: Background levels occur in specimens collected from subjects NOT exposed. NS: Non-specific determinant - observed following exposure to other materials. SECTION 5 Fire-fighting measures Extinguishing media Alcohol stable foam. Dry chemical powder. BCF (where regulations permit). Carbon dioxide. Water spray or fog - Large fires only. SMALL FIRE: Water spray, dry chemical or CO2 LARGE FIRE: Water spray or fog. Special hazards arising from the substrate or mixture Fire Incompatibility Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result Special protective equipment and precautions for fire-fighters Fire Fighting Fire/Explosion Hazard carbon dioxide (CO2) other pyrolysis products typical of burning organic material. Contains low boiling substance: Closed containers may rupture due to pressure buildup under fire conditions. BEWARE: Empty solvent, paint, lacquer and flammable liquid drums present a severe explosion hazard if cut by flame torch or welded. Even when thoroughly cleaned or reconditioned the drum seams may retain sufficient solvent to generate an explosive atmosphere in the drum. WARNING: Aerosol containers may present pressure related hazards. SECTION 6 Accidental release measures Personal precautions, protective equipment and emergency procedures See section 8 Environmental precautions See section 12 Methods and material for containment and cleaning up Minor Spills Clean up all spills immediately. Avoid breathing vapours and contact with skin and eyes. Wear protective clothing, impervious gloves and safety glasses. Shut off all possible sources of ignition and increase ventilation. Wipe up. If safe, damaged cans should be placed in a container outdoors, away from all ignition sources, until pressure has dissipated. Undamaged cans should be gathered and stowed safely. Major Spills Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard. May be violently or explosively reactive. Wear breathing apparatus plus protective gloves. Prevent, by any means available, spillage from entering drains or water courses No smoking, naked lights or ignition sources. Increase ventilation. Stop leak if safe to do so. Water spray or fog may be used to disperse / absorb vapour. Absorb or cover spill with sand, earth, inert materials or vermiculite. If safe, damaged cans should be placed in a container outdoors, away from ignition sources, until pressure has dissipated. Undamaged cans should be gathered and stowed safely. Collect residues and seal in labelled drums for disposal. Personal Protective Equipment advice is contained in Section 8 of the SDS. SECTION 7 Handling and storage Precautions for safe handling Safe handling The conductivity of this material may make it a static accumulator., A liquid is typically considered nonconductive if its conductivity is below 100 pS/m and is considered semi-conductive if its conductivity is below 10 000 pS/m., Whether a liquid is nonconductive or semi-conductive, the precautions are the same., A number of factors, for example liquid temperature, presence of contaminants, and anti-static additives can greatly influence the conductivity of a liquid. Radon and its radioactive decay products are hazardous if inhaled or ingested Avoid all personal contact, including inhalation. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area. Prevent concentration in hollows and sumps. DO NOT enter confined spaces until atmosphere has been checked. Avoid smoking, naked lights or ignition sources. Avoid contact with incompatible materials. Version No: 7.8 Page 4 of 18 METYFIX 3 SPRAY ADHESIVE AEROSOL, MULTI-PURPOSE SPRAY ADHESIVE Issue Date: 20/03/2023 Print Date: 20/03/2023 Continued... Source Ingredient Material name TWA STEL Peak NotesWhen handling, DO NOT eat, drink or smoke. DO NOT incinerate or puncture aerosol cans. DO NOT spray directly on humans, exposed food or food utensils. Avoid physical damage to containers. Always wash hands with soap and water after handling. Work clothes should be laundered separately. Use good occupational work practice. Observe manufacturer's storage and handling recommendations contained within this SDS. Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions are maintained. Other information Conditions for safe storage, including any incompatibilities Suitable container For low viscosity materials (i) : Drums and jerry cans must be of the non-removable head type. (ii) : Where a can is to be used as an inner package, the can must have a screwed enclosure. For materials with a viscosity of at least 2680 cSt. (23 deg. C) For manufactured product having a viscosity of at least 250 cSt. (23 deg. C) Manufactured product that requires stirring before use and having a viscosity of at least 20 cSt (25 deg. C): (i) Removable head packaging; (ii) Cans with friction closures and (iii) low pressure tubes and cartridges may be used. Where combination packages are used, and the inner packages are of glass, there must be sufficient inert cushioning material in contact with inner and outer packages In addition, where inner packagings are glass and contain liquids of packing group I there must be sufficient inert absorbent to absorb any spillage, unless the outer packaging is a close fitting moulded plastic box and the substances are not incompatible with the plastic. Aerosol dispenser. Check that containers are clearly labelled. Storage incompatibility 1,1-Difluorethane: reacts violently with strong oxidisers, barium, sodium and potassium is incompatible with powdered aluminium, liquid oxygen may form explosive compounds with divalent light metals and metallic azides attacks some metals in the presence of moisture undergoes thermal decomposition when exposed to flame or red-hot surfaces may generate electrostatic charges due to low conductivity. Methyl acetate: reacts violently with oxidisers decomposes on contact with acid or bases forming methanol is incompatible with nitrates attacks some plastics may generate electrostatic charges Low molecular weight alkanes: May react violently with strong oxidisers, chlorine, chlorine dioxide, dioxygenyl tetrafluoroborate. May react with oxidising materials, nickel carbonyl in the presence of oxygen, heat. Are incompatible with nitronium tetrafluoroborate(1-), halogens and interhalogens may generate electrostatic charges, due to low conductivity, on flow or agitation. Avoid flame and ignition sources Redox reactions of alkanes, in particular with oxygen and the halogens, are possible as the carbon atoms are in a strongly reduced condition. Reaction with oxygen (if present in sufficient quantity to satisfy the reaction stoichiometry) leads to combustion without any smoke, producing carbon dioxide and water. Free radical halogenation reactions occur with halogens, leading to the production of haloalkanes. In addition, alkanes have been shown to interact with, and bind to, certain transition metal complexes Interaction between chlorine and ethane over activated carbon at 350 deg C has caused explosions, but added carbon dioxide reduces the risk. The violent interaction of liquid chlorine injected into ethane at 80 deg C/10 bar becomes very violent if ethylene is also present A mixture prepared at -196 deg C with either methane or ethane exploded when the temp was raised to -78 deg C. Addition of nickel carbonyl to an n-butane-oxygen mixture causes an explosion at 20-40 deg C. Alkanes will react with steam in the presence of a nickel catalyst to give hydrogen. Butane/ isobutane reacts violently with strong oxidisers reacts with acetylene, halogens and nitrous oxides is incompatible with chlorine dioxide, conc. nitric acid and some plastics may generate electrostatic charges, due to low conductivity, in flow or when agitated - these may ignite the vapour. Segregate from nickel carbonyl in the presence of oxygen, heat (20-40 C) Esters react with acids to liberate heat along with alcohols and acids. Strong oxidising acids may cause a vigorous reaction with esters that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Esters may be incompatible with aliphatic amines and nitrates. Propane: reacts violently with strong oxidisers, barium peroxide, chlorine dioxide, dichlorine oxide, fluorine etc. liquid attacks some plastics, rubber and coatings may accumulate static charges which may ignite its vapours SECTION 8 Exposure controls / personal protection Control parameters Occupational Exposure Limits (OEL) INGREDIENT DATA US OSHA Permissible Exposure Limits (PELs) Table Z-1 methyl acetate Methyl acetate 200 ppm / 610 mg/m3 Not Available Not Available Not Available US NIOSH Recommended Exposure Limits (RELs) methyl acetate Methyl acetate 200 ppm / 610 mg/m3 760 mg/m3 / 250 ppm Not Available Not Available US NIOSH Recommended Exposure Limits (RELs) butane n-Butane 800 ppm / 1900 mg/m3 Not Available Not Available Not Available Version No: 7.8 Page 5 of 18 METYFIX 3 SPRAY ADHESIVE AEROSOL, MULTI-PURPOSE SPRAY ADHESIVE Issue Date: 20/03/2023 Print Date: 20/03/2023 Continued... Source Ingredient Material name TWA STEL Peak Notes Ingredient TEEL-1 TEEL-2 TEEL-3 Ingredient Original IDLH Revised IDLH Ingredient Occupational Exposure Band Rating Occupational Exposure Band Limit Notes: Occupational exposure banding is a process of assigning chemicals into specific categories or bands based on a chemical's potency and the adverse health outcomes associated with exposure. The output of this process is an occupational exposure band (OEB), which corresponds to a range of exposure concentrations that are expected to protect worker health. US OSHA Permissible Exposure Limits (PELs) Table Z-1 propane Propane 1000 ppm / 1800 mg/m3 Not Available Not Available Not Available US NIOSH Recommended Exposure Limits (RELs) propane Propane 1000 ppm / 1800 mg/m3 Not Available Not Available Not Available US NIOSH Recommended Exposure Limits (RELs) iso-butane Isobutane 800 ppm / 1900 mg/m3 Not Available Not Available Not Available Emergency Limits methyl acetate 250 ppm 1,700 ppm 10000* ppm Hydrocarbons, C6-C7, n-alkanes, isoalkanes, cyclics, <5% n-hexane 1,000 mg/m3 11,000 mg/m3 66,000 mg/m3 butane Not Available Not Available Not Available propane Not Available Not Available Not Available iso-butane 5500* ppm 17000** ppm 53000*** ppm 1,1-difluoroethane Not Available Not Available Not Available methyl acetate 3,100 ppm Not Available Hydrocarbons, C6-C7, n-alkanes, isoalkanes, cyclics, <5% n-hexane Not Available Not Available butane Not Available 1,600 ppm propane 2,100 ppm Not Available iso-butane Not Available Not Available 1,1-difluoroethane Not Available Not Available Occupational Exposure Banding Hydrocarbons, C6-C7, n-alkanes, isoalkanes, cyclics, <5% n-hexane E 0.1 ppm 1,1-difluoroethane E 0.1 ppm Exposure controls Appropriate engineering controls Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection. The basic types of engineering controls are: Process controls which involve changing the way a job activity or process is done to reduce the risk. Enclosure and/or isolation of emission source which keeps a selected hazard 'physically' away from the worker and ventilation that strategically 'adds' and 'removes' air in the work environment. Ventilation can remove or dilute an air contaminant if designed properly. The design of a ventilation system must match the particular process and chemical or contaminant in use. Employers may need to use multiple types of controls to prevent employee overexposure. General exhaust is adequate under normal conditions. If risk of overexposure exists, wear SAA approved respirator. Correct fit is essential to obtain adequate protection. Provide adequate ventilation in warehouse or closed storage areas. Air contaminants generated in the workplace possess varying 'escape' velocities which, in turn, determine the 'capture velocities' of fresh circulating air required to effectively remove the contaminant. Type of Contaminant: Speed: aerosols, (released at low velocity into zone of active generation) 0.5-1 m/s direct spray, spray painting in shallow booths, gas discharge (active generation into zone of rapid air motion)1-2.5 m/s (200-500 f/min.) Within each range the appropriate value depends on: Lower end of the range Upper end of the range 1: Room air currents minimal or favourable to capture1: Disturbing room air currents 2: Contaminants of low toxicity or of nuisance value only.2: Contaminants of high toxicity 3: Intermittent, low production. 3: High production, heavy use 4: Large hood or large air mass in motion 4: Small hood-local control only Simple theory shows that air velocity falls rapidly with distance away from the opening of a simple extraction pipe. Velocity generally decreases with the square of distance from the extraction point (in simple cases). Therefore the air speed at the extraction point should be adjusted, accordingly, after reference to distance from the contaminating source. The air velocity at the extraction fan, for example, should be a minimum of 1-2 m/s (200-400 f/min.) for extraction of solvents generated in a tank 2 meters distant from the extraction point. Other mechanical considerations, producing performance deficits within the extraction apparatus, make it essential that theoretical air velocities are multiplied by factors of 10 or more when extraction systems are installed or used. Version No: 7.8 Page 6 of 18 METYFIX 3 SPRAY ADHESIVE AEROSOL, MULTI-PURPOSE SPRAY ADHESIVE Issue Date: 20/03/2023 Print Date: 20/03/2023 Continued... Individual protection measures, such as personal protective equipment Eye and face protection Safety glasses with side shields. Chemical goggles. Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lenses or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59], [AS/NZS 1336 or national equivalent] Skin protectionSee Hand protection below Hands/feet protection For esters: Do NOT use natural rubber, butyl rubber, EPDM or polystyrene-containing materials. No special equipment needed when handling small quantities. OTHERWISE: For potentially moderate exposures: Wear general protective gloves, eg. light weight rubber gloves. For potentially heavy exposures: Wear chemical protective gloves, eg. PVC. and safety footwear. Body protection See Other protection below Other protection No special equipment needed when handling small quantities. OTHERWISE: Overalls. Skin cleansing cream. Eyewash unit. Do not spray on hot surfaces. Recommended material(s) GLOVE SELECTION INDEX Glove selection is based on a modified presentation of the: 'Forsberg Clothing Performance Index'. The effect(s) of the following substance(s) are taken into account in the computer- generated selection: METYFIX 3 SPRAY ADHESIVE AEROSOL, MULTI-PURPOSE SPRAY ADHESIVE BUTYL A PE/EVAL/PE A PVA C * CPI - Chemwatch Performance Index A: Best Selection B: Satisfactory; may degrade after 4 hours continuous immersion C: Poor to Dangerous Choice for other than short term immersion NOTE: As a series of factors will influence the actual performance of the glove, a final selection must be based on detailed observation. - * Where the glove is to be used on a short term, casual or infrequent basis, factors such as 'feel' or convenience (e.g. disposability), may dictate a choice of gloves which might otherwise be unsuitable following long-term or frequent use. A qualified practitioner should be consulted. Material CPI Respiratory protection Type AX-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent) Where the concentration of gas/particulates in the breathing zone, approaches or exceeds the 'Exposure Standard' (or ES), respiratory protection is required. Degree of protection varies with both face-piece and Class of filter; the nature of protection varies with Type of filter. Required Minimum Protection Factor Half-Face Respirator Full-Face Respirator Powered Air Respirator up to 5 x ES AX-AUS / Class 1 P2 - AX-PAPR-AUS / Class 1 P2 up to 25 x ES Air-line* AX-2 P2 AX-PAPR-2 P2 up to 50 x ES - AX-3 P2 - 50+ x ES - Air-line** - * - Continuous-flow; ** - Continuous-flow or positive pressure demand ^ - Full-face A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E = Sulfur dioxide(SO2), G = Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB = Methyl bromide, AX = Low boiling point organic compounds(below 65 degC) Cartridge respirators should never be used for emergency ingress or in areas of unknown vapour concentrations or oxygen content. The wearer must be warned to leave the contaminated area immediately on detecting any odours through the respirator. The odour may indicate that the mask is not functioning properly, that the vapour concentration is too high, or that the mask is not properly fitted. Because of these limitations, only restricted use of cartridge respirators is considered appropriate. Cartridge performance is affected by humidity. Cartridges should be changed after 2 hr of continuous use unless it is determined that the humidity is less than 75%, in which case, cartridges can be used for 4 hr. Used cartridges should be discarded daily, regardless of the length of time used Generally not applicable. Aerosols, in common with most vapours/ mists, should never be used in confined spaces without adequate ventilation. Aerosols, containing agents designed to enhance or mask smell, have triggered allergic reactions in predisposed individuals. Selection of the Class and Type of respirator will depend upon the level of breathing zone contaminant and the chemical nature of the contaminant. Protection Factors (defined as the ratio of contaminant outside and inside the mask) may also be important. Required minimum protection factor Maximum gas/vapour concentration present in air p.p.m. (by volume) Half-face Respirator Full-Face Respirator up to 10 1000 AX-AUS / Class 1 - Version No: 7.8 Page 7 of 18 METYFIX 3 SPRAY ADHESIVE AEROSOL, MULTI-PURPOSE SPRAY ADHESIVE Issue Date: 20/03/2023 Print Date: 20/03/2023 Continued... up to 50 1000 - AX-AUS / Class 1 up to 50 5000 Airline * - up to 100 5000 - AX-2 up to 100 10000 - AX-3 100+ - Airline** ** - Continuous-flow or positive pressure demand. A(All classes) = Organic vapours, B AUS or B1 = Acid gases, B2 = Acid gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E = Sulfur dioxide(SO2), G = Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB = Methyl bromide, AX = Low boiling point organic compounds(below 65 deg C) SECTION 9 Physical and chemical properties Information on basic physical and chemical properties Appearance Coloured Physical stateDissolved Gas Relative density (Water = 1)0.87 Odour Not Available Partition coefficient n-octanol / water Not Available Odour threshold Not Available Auto-ignition temperature ( C)Not Available pH (as supplied)Not Available Decomposition temperature ( C) Not Available Melting point / freezing point ( C) Not Available Viscosity (cSt)57 Initial boiling point and boiling range ( C) >57 Molecular weight (g/mol)Not Available
Flash point ( C)-26 Taste Not Available
Evaporation rateNot Available Explosive propertiesNot Available
Flammability HIGHLY FLAMMABLE. Oxidising propertiesNot Available
Upper Explosive Limit (%)16
Surface Tension (dyn/cm or
mN/m)
Not Available
Lower Explosive Limit (%)1 Volatile Component (%vol) Not Available
Vapour pressure (kPa) Not Available Gas group Not Available
Solubility in waterImmiscible pH as a solution (1%)Not Available
Vapour density (Air = 1)Not Available VOC % 592.99
SECTION 10 Stability and reactivity
ReactivitySee section 7
Chemical stability
Elevated temperatures.
Presence of open flame.
Product is considered stable.
Hazardous polymerisation will not occur.
Possibility of hazardous
reactions
See section 7
Conditions to avoidSee section 7
Incompatible materialsSee section 7
Hazardous decomposition
products
See section 5
SECTION 11 Toxicological information
Information on toxicological effects
Inhaled
The material can cause respiratory irritation in some persons. The body’s response to such irritation can cause further lung damage.
Inhalation of vapours may cause drowsiness and dizziness. This may be accompanied by sleepiness, reduced alertness, loss of reflexes, lack of
co-ordination, and vertigo.
The main effects of simple esters are irritation, stupor and insensibility. Headache, drowsiness, dizziness, coma and behavioural changes may
occur.
Isobutane produces a dose dependent action and at high concentrations may cause numbness, suffocation, exhilaration, dizziness, headache,
nausea, confusion, incoordination and unconsciousness in severe cases. Version No: 7.8 Page 8 of 18
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The paraffin gases are practically not harmful at low doses. Higher doses may produce reversible brain and nerve depression and irritation.
Exposure to methyl acetate fumes may lead to shortness of breath and an irregular heartbeat. Inhalation of methyl acetate causes severe
headache and sleepiness.
Animal testing showed a single, high-level exposure to 1,1-difluoroethane by inhalation has caused difficulty breathing, lung irritation, lethargy,
inco-ordination, and loss of consciousness, with sensitisation of the heart occurring at a concentration of 15% after adrenaline was given into a
vein. Repeated exposure caused increased urinary fluoride, reduced kidney weight and reversible kidney changes. Inhaling high concentrations
can depress the central nervous system, which may lead to inco-ordination, impaired judgment and, if exposure is prolonged, unconsciousness
and even death.
The vapour is discomforting
WARNING:Intentional misuse by concentrating/inhaling contents may be lethal.
Inhaling high concentrations of mixed hydrocarbons can cause narcosis, with nausea, vomiting and lightheadedness. Low molecular weight
(C2-C12) hydrocarbons can irritate mucous membranes and cause incoordination, giddiness, nausea, vertigo, confusion, headache, appetite
loss, drowsiness, tremors and stupor.
Central nervous system (CNS) depression may include general discomfort, symptoms of giddiness, headache, dizziness, nausea, anaesthetic
effects, slowed reaction time, slurred speech and may progress to unconsciousness. Serious poisonings may result in respiratory depression and
may be fatal.
Nerve damage can be caused by some non-ring hydrocarbons. Symptoms are temporary, and include weakness, tremors, increased saliva,
some convulsions, excessive tears with discolouration and inco-ordination lasting up to 24 hours.
Inhalation of high concentrations of gas/vapour causes lung irritation with coughing and nausea, central nervous depression with headache and
dizziness, slowing of reflexes, fatigue and inco-ordination.
Material is highly volatile and may quickly form a concentrated atmosphere in confined or unventilated areas. The vapour may displace and
replace air in breathing zone, acting as a simple asphyxiant. This may happen with little warning of overexposure.
The use of a quantity of material in an unventilated or confined space may result in increased exposure and an irritating atmosphere developing.
Before starting consider control of exposure by mechanical ventilation.
Inhalation of vapours or aerosols (mists, fumes), generated by the material during the course of normal handling, may be damaging to the health
of the individual.
Ingestion
Methanol may produce a burning or painful sensation in the mouth, throat, chest, and stomach. This may be accompanied by nausea, vomiting,
headache, dizziness, shortness of breath, weakness, fatigue, leg cramps, restlessness, confusion, drunken behaviour, visual disturbance,
drowsiness, coma and death.
Swallowing large doses of methyl acetate may result in severe cramping, intoxication and depression of the central nervous system.
A single high oral dose of 1,1-difluoroethane produced weight loss and lethargy.
The material has NOT been classified by EC Directives or other classification systems as ‘harmful by ingestion’. This is because of the lack of
corroborating animal or human evidence.
Isoparaffinic hydrocarbons cause temporary lethargy, weakness, inco-ordination and diarrhoea.
Not normally a hazard due to physical form of product.
Considered an unlikely route of entry in commercial/industrial environments
Swallowing of the liquid may cause aspiration into the lungs with the risk of chemical pneumonitis; serious consequences may result.
(ICSC13733)
Considered an unlikely route of entry in commercial/industrial environments. The liquid may produce gastrointestinal discomfort and may be
harmful if swallowed.
Accidental ingestion of the material may be damaging to the health of the individual.
Skin Contact
The material may accentuate any pre-existing dermatitis condition
Skin contact is not thought to have harmful health effects (as classified under EC Directives); the material may still produce health damage
following entry through wounds, lesions or abrasions.
Skin exposure to isoparaffins may produce slight to moderate irritation in animals and humans. Rare sensitisation reactions in humans have
occurred.
Methyl acetate has proven to cause only weak skin irritation in humans and in rabbits (no oedema, erythema with maximum grade 1 reversible
within 48 hours).
Spray mist may produce discomfort
Open cuts, abraded or irritated skin should not be exposed to this material
Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects. Examine the skin
prior to the use of the material and ensure that any external damage is suitably protected.
There is some evidence to suggest that the material may cause moderate inflammation of the skin either following direct contact or after a delay
of some time. Repeated exposure can cause contact dermatitis which is characterised by redness, swelling and blistering.
Eye
Instillation of isoparaffins into rabbit eyes produces only slight irritation.
Overexposure to methyl acetate vapour may result in a condition known as amylopia (dimming of vision) due to withering of the optic nerve.
Methyl acetate may resemble methanol in this respect. Animal testing showed that methyl acetate causes severe eye irritation, but this is
reversible after exposure ends.
This material may produce eye irritation in some persons and produce eye damage 24 hours or more after instillation. Moderate inflammation
may be expected with redness; conjunctivitis may occur with prolonged exposure.
Chronic
Long-term exposure to respiratory irritants may result in airways disease, involving difficulty breathing and related whole-body problems.
Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed.
This material can cause serious damage if one is exposed to it for long periods. It can be assumed that it contains a substance which can
produce severe defects.
Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-term occupational exposure.
Constant or exposure over long periods to mixed hydrocarbons may produce stupor with dizziness, weakness and visual disturbance, weight loss
and anaemia, and reduced liver and kidney function. Skin exposure may result in drying and cracking and redness of the skin.
Chronic effects of exposure to methyl acetate may be similar to those of methanol exposure, because methyl acetate can break down in water to
form methanol and acetic acid. The main hazard is damage to the optic nerve.
Long-term exposure to methanol vapour, at concentrations exceeding 3000 ppm, may produce cumulative effects characterised by
gastrointestinal disturbances (nausea, vomiting), headache, ringing in the ears, insomnia, trembling, unsteady gait, vertigo, conjunctivitis and
clouded or double vision. Liver and/or kidney injury may also result.
Prolonged or repeated skin contact may cause drying with cracking, irritation and possible dermatitis following.
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Not Available Not Available Version No: 7.8 Page 9 of 18
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methyl acetate
TOXICITY IRRITATION
dermal (rat) LD50: >2000 mg/kg
[2] Eye (rabbit):100 mg/24h-moderate
Oral (Rabbit) LD50; 3700 mg/kg
[2] Skin (rabbit): 20 mg/24h – mild
Skin (rabbit): 500 mg/24h – mild
Hydrocarbons, C6-C7,
n-alkanes, isoalkanes, cyclics,
<5% n-hexane TOXICITY IRRITATION Dermal (rabbit) LD50: >1900 mg/kg
[1]
Eye: no adverse effect observed (not irritating)
[1]
Inhalation(Rat) LC50: >4.42 mg/L4h
[1]
Skin: adverse effect observed (irritating)
[1]
Oral (Rat) LD50: >2000 mg/kg
[1]
butane
TOXICITY IRRITATION
Inhalation(Rat) LC50: 658 mg/l4h
[2] Not Available
propane
TOXICITY IRRITATION
Inhalation(Rat) LC50: 364726.819 ppm4h
[2] Not Available
iso-butane
TOXICITY IRRITATION
Inhalation(Rat) LC50: >13023 ppm4h
[1] Not Available
1,1-difluoroethane
TOXICITY IRRITATION
Inhalation(Rat) LC50: >437500 ppm4h
[1] Not Available
Oral (Rat) LD50: 484 mg/kg
[2]
Legend: 1. Value obtained from Europe ECHA Registered Substances – Acute toxicity 2. Value obtained from manufacturer’s SDS. Unless otherwise
specified data extracted from RTECS – Register of Toxic Effect of chemical Substances
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Asthma-like symptoms may continue for months or even years after exposure to the material ends. This may be due to a non-allergic condition
known as reactive airways dysfunction syndrome (RADS) which can occur after exposure to high levels of highly irritating compound. Main
criteria for diagnosing RADS include the absence of previous airways disease in a non-atopic individual, with sudden onset of persistent
asthma-like symptoms within minutes to hours of a documented exposure to the irritant. Other criteria for diagnosis of RADS include a reversible
airflow pattern on lung function tests, moderate to severe bronchial hyperreactivity on methacholine challenge testing, and the lack of minimal
lymphocytic inflammation, without eosinophilia. RADS (or asthma) following an irritating inhalation is an infrequent disorder with rates related to
the concentration of and duration of exposure to the irritating substance. On the other hand, industrial bronchitis is a disorder that occurs as a
result of exposure due to high concentrations of irritating substance (often particles) and is completely reversible after exposure ceases. The
disorder is characterized by difficulty breathing, cough and mucus production.
Disinfection byproducts (DBPs) are formed when disinfectants such as chlorine, chloramines and ozone react with organic and inorganic matter
in water. Animal studies have shown that some DBPs cause cancer. To date, several hundred DBPs have been identified.
Numerous haloalkanes and haloalkenes have been tested for cancer-causing and mutation-causing activities. In general, the potential to cause
genetic toxicity is dependent on the nature, number and position of halogen(s) and the size of the molecule.
Haloalkenes are of concern because of the potential to generate genetically toxic intermediates after epoxidation. The concern for haloalkenes
may be diminished if the double bond is internal or sterically hindered.
The cancer concern levels of the 14 haloalkenes and haloalkanes, have been rated, based on available screening cancer bioassays and data on
genetic toxicity. Some individuals may be genetically more susceptible to brominated THMs than others.
Six, two and one haloalkanes/haloalkenes have been given low-moderate, marginal and low concern, respectively.
Generally,linear and branched-chain alkyl esters are hydrolysed to their component alcohols and carboxylic acids in the intestinal tract, blood and
most tissues throughout the body. Following hydrolysis the component alcohols and carboxylic acids are metabolized
Oral acute toxicity studies have been reported for 51 of the 67 esters of aliphatic acyclic primary alcohols and aliphatic linear saturated carboxylic
acids. The very low oral acute toxicity of this group of esters is demonstrated by oral LD50 values greater than 1850 mg/kg bw
Genotoxicity studies have been performed in vitro using the following esters of aliphatic acyclic primary alcohols and aliphatic linear saturated
carboxylic acids: methyl acetate, butyl acetate, butyl stearate and the structurally related isoamyl formate and demonstrates that these
substances are not genotoxic.
The JEFCA Committee concluded that the substances in this group would not present safety concerns at the current levels of intake the esters of
aliphatic acyclic primary alcohols and aliphatic linear saturated carboxylic acids are generally used as flavouring substances up to average
maximum levels of 200 mg/kg. Higher levels of use (up to 3000 mg/kg) are permitted in food categories such as chewing gum and hard candy. In
Europe the upper use levels for these flavouring substances are generally 1 to 30 mg/kg foods and in special food categories like candy and
alcoholic beverages up to 300 mg/kg foods
Internationl Program on Chemical Safety: the Joint FAO/WHO Expert Committee on Food Additives (JECFA)
Esters of Aliphatic acyclic primary alcohols with aliphatic linear saturated carboxylic acids.; 1998
METHYL ACETATE
The material may produce moderate eye irritation leading to inflammation. Repeated or prolonged exposure to irritants may produce
conjunctivitis.
The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of
vesicles, scaling and thickening of the skin.
Hydrocarbons, C6-C7,
n-alkanes, isoalkanes, cyclics,
<5% n-hexane For Low Boiling Point Naphthas (LBPNs): Acute toxicity: LBPNs generally have low acute toxicity by the oral (median lethal dose [LD50] in rats > 2000 mg/kg-bw), inhalation (LD50 in rats > 5000 mg/m3)
and dermal (LD50 in rabbits > 2000 mg/kg-bw) routes of exposure
Most LBPNs are mild to moderate eye and skin irritants in rabbits, with the exception of heavy catalytic cracked and heavy catalytic reformed
naphthas, which have higher primary skin irritation indices.
Sensitisation:
LBPNs do not appear to be skin sensitizers, but a poor response in the positive control was also noted in these studies Version No: 7.8 Page 10 of 18
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Repeat dose toxicity:
The lowest-observed-adverse-effect concentration (LOAEC) and lowest-observed-adverse-effect level (LOAEL) values identified following
short-term (2-89 days) and subchronic (greater than 90 days) exposure to the LBPN substances. These values were determined for a variety of
endpoints after considering the toxicity data for all LBPNs in the group. Most of the studies were carried out by the inhalation route of exposure.
Renal effects, including increased kidney weight, renal lesions (renal tubule dilation, necrosis) and hyaline droplet formation, observed in male
rats exposed orally or by inhalation to most LBPNs, were considered species- and sex-specific These effects were determined to be due to a
mechanism of action not relevant to humans -specifically, the interaction between hydrocarbon metabolites and alpha-2-microglobulin, an
enzyme not produced in substantial amounts in female rats, mice and other species, including humans. The resulting nephrotoxicity and
subsequent carcinogenesis in male rats were therefore not considered in deriving LOAEC/LOAEL values.
Only a limited number of studies of short-term and subchronic duration were identified for site-restricted LBPNs. The lowest LOAEC identified in
these studies, via the inhalation route, is 5475 mg/m3, based on a concentration-related increase in liver weight in both male and female rats
following a 13-week exposure to light catalytic cracked naphtha. Shorter exposures of rats to this test substance resulted in nasal irritation at
9041 mg/m3
No systemic toxicity was reported following dermal exposure to light catalytic cracked naphtha, but skin irritation and accompanying
histopathological changes were increased, in a dose-dependent manner, at doses as low as 30 mg/kg-bw per day when applied 5 days per week
for 90 days in rats
No non-cancer chronic toxicity studies (= 1 year) were identified for site-restricted LBPNs and very few non-cancer chronic toxicity studies were
identified for other LBPNs. An LOAEC of 200 mg/m3 was noted in a chronic inhalation study that exposed mice and rats to unleaded gasoline
(containing 2% benzene). This inhalation LOAEC was based on ocular discharge and ocular irritation in rats. At the higher concentration of 6170
mg/m3, increased kidney weight was observed in male and female rats (increased kidney weight was also observed in males only at 870
mg/m3). Furthermore, decreased body weight in male and female mice was also observed at 6170 mg/m3
A LOAEL of 714 mg/kg-bw was identified for dermal exposure based on local skin effects (inflammatory and degenerative skin changes) in mice
following application of naphtha for 105 weeks. No systemic toxicity was reported.
Genotoxicity:
Although few genotoxicity studies were identified for the site-restricted LBPNs, the genotoxicity of several other LBPN substances has been
evaluated using a variety of in vivo and in vitro assays. While in vivo genotoxicity assays were negative overall, the in vitro tests exhibited mixed
results.
For in vivo genotoxicity tests, LBPNs exhibited negative results for chromosomal aberrations and micronuclei induction, but exhibited positive
results in one sister chromatid exchange assay although this result was not considered definitive for clastogenic activity as no genetic material
was unbalanced or lost. Mixtures that were tested, which included a number of light naphthas, displayed mixed results (i.e., both positive and
negative for the same assay) for chromosomal aberrations and negative results for the dominant lethal mutation assay. Unleaded gasoline
(containing 2% benzene) was tested for its ability to induce unscheduled deoxyribonucleic acid (DNA) synthesis (UDS) and replicative DNA
synthesis (RDS) in rodent hepatocytes and kidney cells. UDS and RDS were induced in mouse hepatocytes via oral exposure and RDS was
induced in rat kidney cells via oral and inhalation exposure. Unleaded gasoline (benzene content not stated) exhibited negative results for
chromosomal aberrations and the dominant lethal mutation assay and mixed results for atypical cell foci in rodent renal and hepatic cells.
For in vitro genotoxicity studies, LBPNs were negative for six out of seven Ames tests, and were also negative for UDS and for forward mutations
LBPNs exhibited mixed or equivocal results for the mouse lymphoma and sister chromatid exchange assays, as well as for cell transformation
and positive results for one bacterial DNA repair assay. Mixtures that were tested, which included a number of light naphthas, displayed negative
results for the Ames and mouse lymphoma assays Gasoline exhibited negative results for the Ames test battery, the sister chromatid exchange
assay and for one mutagenicity assay . Mixed results were observed for UDS and the mouse lymphoma assay.
While the majority of in vivo genotoxicity results for LBPN substances are negative, the potential for genotoxicity of LBPNs as a group cannot be
discounted based on the mixed in vitro genotoxicity results.
Carcinogenicity:
Although a number of epidemiological studies have reported increases in the incidence of a variety of cancers, the majority of these studies are
considered to contain incomplete or inadequate information. Limited data, however, are available for skin cancer and leukemia incidence, as well
as mortality among petroleum refinery workers. It was concluded that there is limited evidence supporting the view that working in petroleum
refineries entails a carcinogenic risk (Group 2A carcinogen). IARC (1989a) also classified gasoline as a Group 2B carcinogen; it considered the
evidence for carcinogenicity in humans from gasoline to be inadequate and noted that published epidemiological studies had several limitations,
including a lack of exposure data and the fact that it was not possible to separate the effects of combustion products from those of gasoline itself.
Similar conclusions were drawn from other reviews of epidemiological studies for gasoline (US EPA 1987a, 1987b). Thus, the evidence gathered
from these epidemiological studies is considered to be inadequate to conclude on the effect
s of human exposure to LBPN substances.
No inhalation studies assessing the carcinogenicity of the site-restricted LBPNs were identified. Only unleaded gasoline has been examined for
its carcinogenic potential, in several inhalation studies. In one study, rats and mice were exposed to 0, 200, 870 or 6170 mg/m3 of a 2% benzene
formulation of the test substance, via inhalation, for approximately 2 years. A statistically significant increase in hepatocellular adenomas and
carcinomas, as well as a non-statistical increase in renal tumours, were observed at the highest dose in female mice. A dose-dependent increase
in the incidence of primary renal neoplasms was also detected in male rats, but this was not considered to be relevant to humans, as discussed
previously.Carcinogenicity was also assessed for unleaded gasoline, via inhalation, as part of initiation/promotion studies. In these studies,
unleaded gasoline did not appear to initiate tumour formation, but did show renal cell and hepatic tumour promotion ability, when rats and mice
were exposed, via inhalation, for durations ranging from 13 weeks to approximately 1 year using an initiation/promotion protocol However, further
examination of data relevant to the composition of unleaded gasoline demonstrated that this is a highly-regulated substance; it is expected to
contain a lower percentage of benzene and has a discrete component profile when compared to other substances in the LBPN group.
Both the European Commission and the International Agency for Research on Cancer (IARC) have classified LBPN substances as carcinogenic.
All of these substances were classified by the European Commission (2008) as Category 2 (R45: may cause cancer) (benzene content = 0.1%
by weight). IARC has classified gasoline, an LBPN, as a Group 2B carcinogen (possibly carcinogenic to humans) and occupational exposures in
petroleum refining as Group 2A carcinogens (probably carcinogenic to humans).
Several studies were conducted on experimental animals to investigate the dermal carcinogenicity of LBPNs. The majority of these studies were
conducted through exposure of mice to doses ranging from 694-1351 mg/kg-bw, for durations ranging from 1 year to the animals lifetime or until
a tumour persisted for 2 weeks. Given the route of exposure, the studies specifically examined the formation of skin tumours. Results for
carcinogenicity via dermal exposure are mixed. Both malignant and benign skin tumours were induced with heavy catalytic cracked naphtha, light
catalytic cracked naphtha, light
straight-run naphtha and naphtha Significant increases in squamous cell carcinomas were also observed when mice were dermally treated with
Stoddard solvent, but the latter was administered as a mixture (90% test substance), and the details of the study were not available. In contrast,
insignificant increases in tumour formation or no tumours were observed when light alkylate naphtha, heavy catalytic reformed naphtha,
sweetened naphtha, light catalytically cracked naphtha
or unleaded gasoline was dermally applied to mice. Negative results for skin tumours were also observed in male mice dermally exposed to
sweetened naphtha using an initiation/promotion protocol.
Reproductive/ Developmental toxicity:
No reproductive or developmental toxicity was observed for the majority of LBPN substances evaluated. Most of these studies were carried out
by inhalation exposure in rodents.
NOAEC values for reproductive toxicity following inhalation exposure ranged from 1701 mg/m3 (CAS RN 8052-41-3) to 27 687 mg/m3 (CAS RN
64741-63-5) for the LBPNs group evaluated, and from 7690 mg/m3 to 27 059 mg/m3 for the site-restricted light catalytic cracked and full-range
catalytic reformed naphthas. However, a decreased number of pups per litter and higher frequency of post-implantation loss were observed
following inhalation exposure of female rats to hydrotreated heavy naphtha (CAS RN 64742-48-9) at a concentration of 4679 mg/m3, 6 hours per
day, from gestational days 7-20. For dermal exposures, NOAEL values of 714 mg/kg-bw (CAS RN 8030-30-6) and 1000 mg/kg-bw per day (CAS
RN 68513-02-0) were noted . For oral exposures, no adverse effects on reproductive parameters were reported when rats were given
site-restricted light catalytic cracked naphtha at 2000 mg/kg on gestational day 13 .
For most LBPNs, no treatment-related developmental effects were observed by the different routes of exposure However, developmental toxicity Version No: 7.8 Page 11 of 18
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was observed for a few naphthas. Decreased foetal body weight and an increased incidence of ossification variations were observed when rat
dams were exposed to light aromatized solvent naphtha, by gavage, at 1250 mg/kg-bw per day. In addition, pregnant rats exposed by inhalation
to hydrotreated heavy naphtha at 4679 mg/m3 delivered pups with higher birth weights. Cognitive and memory impairments were also observed
in the offspring.
Low Boiling Point Naphthas [Site-Restricted]
For petroleum: This product contains benzene, which can cause acute myeloid leukaemia, and n-hexane, which can be metabolized to
compounds which are toxic to the nervous system. This product contains toluene, and animal studies suggest high concentrations of toluene lead
to hearing loss. This product contains ethyl benzene and naphthalene, from which animal testing shows evidence of tumour formation.
Cancer-causing potential: Animal testing shows inhaling petroleum causes tumours of the liver and kidney; these are however not considered to
be relevant in humans.
Mutation-causing potential: Most studies involving gasoline have returned negative results regarding the potential to cause mutations, including
all recent studies in living human subjects (such as in petrol service station attendants).
Reproductive toxicity: Animal studies show that high concentrations of toluene (>0.1%) can cause developmental effects such as lower birth
weight and developmental toxicity to the nervous system of the foetus. Other studies show no adverse effects on the foetus.
Human effects: Prolonged or repeated contact may cause defatting of the skin which can lead to skin inflammation and may make the skin more
susceptible to irritation and penetration by other materials.
Animal testing shows that exposure to gasoline over a lifetime can cause kidney cancer, but the relevance in humans is questionable.
PROPANE No significant acute toxicological data identified in literature search.
1,1-DIFLUOROETHANE
1,1-difluoroethane is practically non-toxic following acute or chronic inhalation exposure. In animal testing, extremely high concentrations (5%
and over) may cause reduced contraction of heart muscle and at even higher levels, heartbeat irregularities. It seems to have a weak effect in
damaging genetic material in cells. Studies have not shown it to cause developmental or reproductive toxicity, and it has not been shown to
cause mutations.
METYFIX 3 SPRAY ADHESIVE
AEROSOL, MULTI-PURPOSE
SPRAY ADHESIVE &
Hydrocarbons, C6-C7,
n-alkanes, isoalkanes, cyclics,
<5% n-hexane Animal studies indicate that normal, branched and cyclic paraffins are absorbed from the gastrointestinal tract and that the absorption of n-paraffins is inversely proportional to the carbon chain length, with little absorption above C30. With respect to the carbon chain lengths likely to be present in mineral oil, n-paraffins may be absorbed to a greater extent than iso- or cyclo-paraffins. The major classes of hydrocarbons are well absorbed into the gastrointestinal tract in various species. In many cases, the hydrophobic hydrocarbons are ingested in association with fats in the diet. Some hydrocarbons may appear unchanged as in the lipoprotein particles in the gut lymph, but most hydrocarbons partly separate from fats and undergo metabolism in the gut cell. The gut cell may play a major role in determining the proportion of hydrocarbon that becomes available to be deposited unchanged in peripheral tissues such as in the body fat stores or the liver. METYFIX 3 SPRAY ADHESIVE AEROSOL, MULTI-PURPOSE SPRAY ADHESIVE & METHYL ACETATE For methyl acetate: Acute toxicity: Methyl acetate is a water-soluble substance with high volatility. In animal testing, the substance has narcotic properties at high concentration; this is soon reversible after exposure ends. Methyl acetate is absorbed via the lungs. After absorption, it is broken down to methanol and acetic acid. The main breakdown product is methanol, which is itself metabolized to formic acid. Methanol is highly toxic, so methyl acetate is of concern for acute toxicity. In humans, accidental inhalation of vapours of methyl acetate caused severe headache and considerable sleepiness. Methyl acetate has proven to cause only weak skin irritation in humans. Eye irritation, however, was severe, but in animal testing was reversible after 7 days. Exposure to methyl acetate vapours causes irritation to the eyes and airways. Sensitisation: Methyl acetate is not expected to sensitise the skin. Repeat dose toxicity: Adequate data does not exist for repeated or prolonged exposure in humans. Methyl acetate may cause dryness and cracking of the skin. Mutation-causing potential: In testing involving bacterial and animal cells, methyl acetate had negative results. Furthermore, the breakdown products, methanol and acetic acid, show no evidence for causing mutations. Methyl acetate should not be classified as causing mutations. Reproductive toxicity: There is no data on the reproductive toxicity of methyl acetate. Methanol, one of the breakdown products, showed some toxicity to the foetus and potential for birth defects, but at high concentrations only, which were toxic to the mother. Acute Toxicity Carcinogenicity Skin Irritation/Corrosion Reproductivity Serious Eye Damage/Irritation STOT - Single Exposure Respiratory or Skin sensitisation STOT - Repeated Exposure Mutagenicity Aspiration Hazard Legend: Data either not available or does not fill the criteria for classification Data available to make classification SECTION 12 Ecological information Toxicity METYFIX 3 SPRAY ADHESIVE AEROSOL, MULTI-PURPOSE SPRAY ADHESIVE Endpoint Test Duration (hr) Species Value Source Not Available Not Available Not Available Not Available Not Available methyl acetate Endpoint Test Duration (hr) Species Value Source NOEC(ECx) 72h Algae or other aquatic plants >=120mg/l 1
EC50 72h Algae or other aquatic plants >120mg/l 1
LC50 96h Fish 250mg/l 1
EC50 48h Crustacea 1026.7mg/l 1
Hydrocarbons, C6-C7,
n-alkanes, isoalkanes, cyclics,
<5% n-hexane Endpoint Test Duration (hr) Species Value Source NOEC(ECx) 504h Crustacea 0.17mg/l 2 LC50 96h Fish 4.26mg/l 2 EC50 96h Algae or other aquatic plants 64mg/l 2 EC50 48h Crustacea 0.64mg/l 2 Version No: 7.8 Page 12 of 18 METYFIX 3 SPRAY ADHESIVE AEROSOL, MULTI-PURPOSE SPRAY ADHESIVE Issue Date: 20/03/2023 Print Date: 20/03/2023 Continued... butane Endpoint Test Duration (hr) Species Value Source LC50 96h Fish 24.11mg/l 2 EC50(ECx) 96h Algae or other aquatic plants 7.71mg/l 2 EC50 96h Algae or other aquatic plants 7.71mg/l 2 propane Endpoint Test Duration (hr) Species Value Source Not Available Not Available Not Available Not Available Not Available iso-butane Endpoint Test Duration (hr) Species Value Source EC50(ECx) 96h Algae or other aquatic plants 7.71mg/l 2 EC50 96h Algae or other aquatic plants 7.71mg/l 2 LC50 96h Fish 24.11mg/l 2 1,1-difluoroethane Endpoint Test Duration (hr) Species Value Source EC50(ECx) 96h Algae or other aquatic plants 47.755mg/l 2 EC50 96h Algae or other aquatic plants 47.755mg/l 2 LC50 96h Fish 291.31mg/l 2 EC50 48h Crustacea 146.695mg/l 2 Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Do NOT allow product to come in contact with surface waters or to intertidal areas below the mean high water mark. Do not contaminate water when cleaning equipment or disposing of equipment wash-waters. Wastes resulting from use of the product must be disposed of on site or at approved waste sites. When released in the environment, alkanes don't undergo rapid biodegradation, because they have no functional groups (like hydroxyl or carbonyl) that are needed by most organisms in order to metabolize the compound. However, some bacteria can metabolise some alkanes (especially those linear and short), by oxidizing the terminal carbon atom. The product is an alcohol, that could be next oxidised to an aldehyde, and finally to a carboxylic acid. The resulting fatty acid could be metabolised through the fatty acid degradation pathway. For petroleum distillates: Environmental fate: When petroleum substances are released into the environment, four major fate processes will take place: dissolution in water, volatilization, biodegradation and adsorption. These processes will cause changes in the composition of these UVCB substances. In the case of spills on land or water surfaces, photodegradation-another fate process-can also be significant. As noted previously, the solubility and vapour pressure of components within a mixture will differ from those of the component alone. These interactions are complex for complex UVCBs such as petroleum hydrocarbons. Each of the fate processes affects hydrocarbon families differently. Aromatics tend to be more water-soluble than aliphatics of the same carbon number, whereas aliphatics tend to be more volatile. Thus,when a petroleum mixture is released into the environment, the principal water contaminants are likely to be aromatics, whereas aliphatics will be the principal air contaminants . The trend in volatility by component class is as follows: alkenes = alkanes > aromatics = cycloalkanes.
The most soluble and volatile components have the lowest molecular weight; thus there is a general shift to higher molecular weight components in residual materials.
Biodegradation:
Biodegradation is almost always operative when petroleum mixtures are released into the environment. It has been widely demonstrated that nearly all soils and sediments have
populations of bacteria and other organisms capable of degrading petroleum hydrocarbons Degradation occurs both in the presence and absence of oxygen. Two key factors that
determine degradation rates are oxygen supply and molecular structure. In general, degradation is more rapid under aerobic conditions. Decreasing trends in degradation rates
according to structure are as follows:
(1) n-alkanes, especially in the C10 C25 range, which are degraded readily;
(2) isoalkanes;
(3) alkenes;
(4) benzene, toluene, ethylbenzene, xylenes (BTEX) (when present in concentrations that are not toxic to microorganisms);
(5) monoaromatics;
(6) polynuclear (polycyclic) aromatic hydrocarbons (PAHs); and
(7) higher molecular weight cycloalkanes (which may degrade very slowly.
Three weathering processes-dissolution in water, volatilization and biodegradation-typically result in the depletion of the more readily soluble,volatile and degradable compounds and
the accumulation of those most resistant to these processes in residues.
When large quantities of a hydrocarbon mixture enter the soil compartment, soil organic matter and other sorption sites in soil are fully saturated and the hydrocarbons will begin to
form a separate phase (a non-aqueous phase liquid, or NAPL) in the soil. At concentrations below the retention capacity for the hydrocarbon in the soil, the NAPL will be immobile this
is referred to as residual NAPL . Above the retention capacity, the NAPL becomes mobile and will move within the soil
Bioaccumulation:
Bioaccumulation potential was characterized based on empirical and/or modelled data for a suite of petroleum hydrocarbons expected to occur in petroleum substances.
Bioaccumulation factors (BAFs) are the preferred metric for assessing the bioaccumulation potential of substances, as the bioconcentration factor (BCF) may not adequately account
for the bioaccumulation potential of substances via the diet, which predominates for substances with log Kow > ~4.5
In addition to fish BCF and BAF data, bioaccumulation data for aquatic invertebrate species were also considered. Biota-sediment/soil accumulation factors (BSAFs), trophic
magnification factors and biomagnification factors were also considered in characterizing bioaccumulation potential.
Overall, there is consistent empirical and predicted evidence to suggest that the following components have the potential for high bioaccumulation, with BAF/BCF values greater than
5000: C13 C15 isoalkanes, C12 alkenes, C12 C15 one-ring cycloalkanes, C12 and C15 two-ring cycloalkanes, C14 polycycloalkanes, C15 one-ring aromatics, C15 and C20
cycloalkane monoaromatics, C12 C13 diaromatics, C20 cycloalkane diaromatics, and C14 and C20 three-ring PAHs
These components are associated with a slow rate of metabolism and are highly lipophilic. Exposures from water and diet, when combined, suggest that the rate of uptake would
exceed that of the total elimination rate. Most of these components are not expected to biomagnify in aquatic or terrestrial foodwebs, largely because a combination of metabolism, low
dietary assimilation efficiency and growth dilution allows the elimination rate to exceed the uptake rate from the diet; however,
one study suggests that some alkyl-PAHs may biomagnify.While only BSAFs were found for some PAHs, it is possible that BSAFs will be > 1 for invertebrates, given that they do not
have the same metabolic competency as fish.
In general, fish can efficiently metabolize aromatic compounds. There is some evidence that alkylation increases bioaccumulation of naphthalene but it is not known if this can be
generalized to larger PAHs or if any potential increase in bioaccumulation due to alkylation will be sufficient to exceed a BAF/BCF of 5000.
Some lower trophic level organisms (i.e., invertebrates) appear to lack the capacity to efficiently metabolize aromatic compounds, resulting in high bioaccumulation potential for some
aromatic components as compared to fish. Version No: 7.8 Page 13 of 18
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This is the case for the C14 three-ring PAH, which was bioconcentrated to a high level (BCF > 5000) by invertebrates but not by fish. There is potential for such bioaccumulative
components to reach toxic levels in organisms if exposure is continuous and of sufficient magnitude, though this is unlikely in the water column following a spill scenario due to
relatively rapid dispersal
Bioaccumulation of aromatic compounds might be lower in natural environments than what is observed in the laboratory. PAHs may sorb to organic material suspended in the water
column (dissolved humic material), which decreases their overall bioavailability primarily due to an increase in size. This has been observed with fish
Ecotoxicity:
Diesel fuel studies in salt water are available. The values varied greatly for aquatic species such as rainbow trout and Daphnia magna, demonstrating the inherent variability of diesel
fuel compositions and its effects on toxicity. Most experimental acute toxicity values are above 1 mg/L. The lowest 48-hour LC50 for salmonids was 2.4 mg/L. Daphnia magna had a
24-hour LC50 of 1.8 mg/.The values varied greatly for aquatic species such as rainbow trout and Daphnia magna, demonstrating the inherent variability of diesel fuel compositions
and its effects on toxicity. Most experimental acute toxicity values are above 1 mg/L. The lowest 48-hour LC50 for salmonids was 2.4 mg/L. Daphnia magna had a 24-hour LC50 of 1.8
mg/L
The tropical mysid Metamysidopsis insularis was shown to be very sensitive to diesel fuel, with a 96-hour LC50 value of 0.22 mg/L this species has been shown to be as sensitive as
temperate mysids to toxicants. However,However this study used nominal concentrations,and therefore was not considered acceptable. In another study involving diesel fuel, the
effect on brown or common shrimp (Crangon crangon) a 96-hour LC50 of 22 mg/L was determined. A gas oil was also tested and a 96-hour LC50 of 12 mg/L.was determined
The steady state cell density of marine phytoplankton decreased with increasing concentrations of diesel fuel, with different sensitivities between species . The diatom Phaeodactylum
tricornutum showed a 20% decrease in cell density in 24 hours following a 3 mg/L exposure with a 24-hour no-observed effect concentration (NOEC) of 2.5 mg/L. The microalga
Isochrysis galbana was more tolerant to diesel fuel, with a 24-hour lowest-observed-effect concentration (LOEC) of 26 mg/L (14% decrease in cell density), and a NOEC of 25 mg/L.
Finally, the green algae Chlorella salina was relatively insensitive to diesel fuel contamination, with a 24-hour LOEC of 170 mg/L (27% decrease in cell density), and a NOEC of 160
mg/L . All populations of phytoplankton returned to a steady state within 5 days of exposure
In sandy soils, earthworm (Eisenia fetida) mortality only occurred at diesel fuel concentrations greater than 10 000 mg/kg, which was also the concentration at which sub-lethal weight
loss was recorded
Nephrotoxic effects of diesel fuel have been documented in several animal and human studies.Some species of birds (mallard ducks in particular) are generally resistant to the toxic
effects of petrochemical ingestion, and large amounts of petrochemicals are needed in order to cause direct mortality

For 1,1-Difluorethane: Log Kow: 0.75; BCF: 2.
Environmental Fate: 1,1-difluoroethane is expected to exist solely as a vapor in the ambient atmosphere with a half-life of about 472 days. Some 1,1-difluoroethane is expected to
diffuse into the stratosphere above the ozone layer where it will slowly degrade due to direct photolysis from UV-radiation.
Aquatic Fate: The estimated half-life for a model river is 2 hours and model lake is 77 hours. 1,1-Difluoroethane is not expected to adsorb to suspended solids and sediment. The
chemical is expected to volatilize rapidly from surface water.
Atmospheric Fate: Ninety-nine percent of 1,1-difluorethane released to air distributes to the atmospheric compartment.
Ecotoxicity: 1,1-difluoroethane is unlikely to represent an unacceptable risk to aquatic organisms or wildlife. Bioconcentration of this chemical tends to be low and is slightly to
relatively non-toxic to fish and Daphnia magna water fleas. The substance is moderately toxic to algae.
for methyl actetate:
Environmental fate:
Biodegradation
The substance can be classified as readily biodegradable on the basis of an available study according to OECD-guideline 301 D. This closed bottle test indicates 74%
biodegradation after 14 days, 75% after 19 days and 70% after 28 days. There is no information on possible intermediates before ultimate degradation of methyl acetate. Probably
methanol and acetic acid could be intermediates of the biodegradation. The degradation of the possible intermediates is included in the results of the biodegradation test.
Photodegradation
Direct photolysis of methyl acetate in the atmosphere is not to be expected. However, in the atmosphere gaseous methyl acetate reacts with hydroxyl radicals which have been
formed photochemically. On the basis of an atmospheric concentration of the OH-radicals amounting to 5.10exp5 OH/cm3 and the rate constant (kdeg(air)) of 0.3182.10exp-
12cm3.molecule-1.s-1, a half-life of 50.4 days is calculated for the photochemical degradation in the atmosphere. A half-life of 94 days was determined on the basis of laboratory
investigations into photochemical degradation.
Hydrolysis
The hydrolysis of methyl acetate was examined in an older investigation from 1935. In this, a hydrolysis half-life of approximately 53 days at a temperature of 23.2 to 25.4 deg C was
determined for methyl acetate (148.6 g/l). No information was provided on the pH value of the solution.
Hydrolysis half-lives of between approximately 63 days (pH = 8) and approximately 627 days (pH = 7) were calculated for the substance using QSAR calculations. Hydrolysis should
therefore not represent a significant elimination process for methyl acetate in the environment.
Distribution
On account of the vapour pressure of 217 hPa, methyl acetate is expected to evaporate quickly from surfaces.
A Henrys Constant of 6.43 Pa m3/mol at 20 deg C is calculated from the data on the vapour pressure and water solubility of methyl acetate given in Section 1. Consequently, the
substance is moderately volatile from an aqueous solution..
No bioaccumulation potential is to be expected due to the measured log Kow value for methyl acetate of 0.18. On the basis of this value the Koc is calculated as 12.99 l/kg and the
partition coefficients can be calculated according to the organic carbon content in the individual environmental compartments.
Accumulation
No investigations on bioaccumulation are available. The measured log Kow of 0.18 does not provide any indication of a relevant bioaccumulation potential.
The calculated Koc value of 12.99 l/kg also does not indicate that a significant geoaccumulation potential is to be expected for methyl acetate. The substance may be washed out
from soil to groundwater by rainwater depending on the elimination in soil by degradation and distribution.
Atmosphere
Due to the atmospheric half-life (t1/2 = 74 to 94 days), abiotic effects on the atmosphere, such as global warming and ozone depletion, are not to be expected in connection with
methyl acetate
For n-Heptane: Log Kow: 4.66; Koc: 2400-8100; Half-life (hr) Air: 52.8; Half-life (hr) Surface Water: 2.9-312; Henry’s atm m3 /mol: 2.06; BOD 5 (if unstated): 1.92; COD: 0.06; BCF:
340-2000; Log BCF: 2.53-3.31.
Atmospheric Fate: Breakdown of n-heptane by sunlight is not expected to be an important fate process. If released to the atmosphere, n-heptane is expected to exist entirely in the
vapor phase, in ambient air. Reactions hydroxyl radicals in the atmosphere have been shown to be important. Night-time reactions with nitrate radicals may contribute to the
atmospheric transformation of n-heptane, especially in urban environments. n-Heptane is not expected to be susceptible to direct breakdown by sunlight
Terrestrial Fate: n-Heptane is expected to be broken down by biological processes in the soil; however, evaporation and adsorption from soil are expected to be a more important fate
processes. n-Heptane will be slightly mobile to immobile in soil.
Aquatic Fate: Breakdown of n-heptane by water is not expected to be an important fate process.
Biological breakdown may occur in water; however, evaporation is expected to be a more important fate process. The evaporation half-life for the substance from a model river is 2.9
hours and from a model pond is 13 days. In aquatic systems, n-heptane may partition from the water column to organic matter in sediments and suspended solids.
Ecotoxicity: Concentration of the substance in aquatic life may be important in aquatic environments. The substance is moderately toxic to goldfish; however n-heptane has low toxicity
to golden orfe, western mosquitofish, Daphnia magna water fleas, and snail. The substance is toxic to opossum shrimp.
For Butane (Synonym: n-Butane): Log Kow: 2.89; Koc: 450-900; Henry s Law Constant: 0.95 atm-cu m/mole, Vapor Pressure: 1820 mm Hg; BCF: 1.9.
Atmospheric Fate: Butane is expected to exist only as a gas in the ambient atmosphere. Gas-phase n-butane is degraded in the atmosphere by reaction with hydroxyl radicals; the
half-life for this reaction in air is estimated to be 6.3 days, (@ 25 C). Butane is not expected to absorb UV light and probably will probably not be broken down directly by sunlight in the
atmosphere. Nighttime reactions with radical species and nitrogen oxides may contribute to the atmospheric transformation of butane.
Terrestrial Fate: Butane is expected to have low mobility in soil. Evaporation from dry soil surfaces is expected to be the main fate process. This substance is expected to be
biologically degraded in soil.
Aquatic Fate: Butane may adsorb to suspended solids and sediment and is expected to occur from water surfaces with an estimated half-life for a model river of 2.2 hours and 3 days,
from a model lake. Biological breakdown in water is expected to occur with complete breakdown estimated to be 34 days to 2-butanone and 2-butanol, (observed in studies).
Breakdown by water and by sunlight in water are not expected to be important fate processes.
Ecotoxicity: The substance is expected to moderately accumulate in aquatic organisms. Butane is moderately toxic to fish, and Daphnia water fleas.
For Propane: Koc 460. log
Kow 2.36.
Henry’s Law constant of 7.07×10-1 atm-cu m/mole, derived from its vapour pressure, 7150 mm Hg, and water solubility, 62.4 mg/L. Estimated BCF: 13.1.
Terrestrial Fate: Propane is expected to have moderate mobility in soil. Volatilization from moist soil surfaces is expected to be an important fate process. Volatilization from dry soil Version No: 7.8 Page 14 of 18
METYFIX 3 SPRAY ADHESIVE AEROSOL, MULTI-PURPOSE SPRAY ADHESIVE
Issue Date: 20/03/2023
Print Date: 20/03/2023 Continued…

Ingredient Persistence: Water/Soil Persistence: Air
Ingredient Bioaccumulation
Ingredient Mobility
surfaces is based vapor pressure. Biodegradation may be an important fate process in soil and sediment.
Aquatic Fate: Propane is expected to adsorb to suspended solids and sediment. Volatilization from water surfaces is expected and half-lives for a model river and model lake are
estimated to be 41 minutes and 2.6 days, respectively. Biodegradation may not be an important fate process in water.
Ecotoxicity: The potential for bioconcentration in aquatic organisms is low.
Atmospheric Fate: Propane is expected to exist solely as a gas in the ambient atmosphere. Gas-phase propane is degraded in the atmosphere by reaction with photochemically-
produced hydroxyl radicals; the half-life for this reaction in air is estimated to be 14 days and is not expected to be susceptible to direct photolysis by sunlight.
DO NOT discharge into sewer or waterways.
Persistence and degradability
methyl acetate LOW LOW
butane LOW LOW
propane LOW LOW
iso-butane HIGH HIGH
1,1-difluoroethane LOW LOW
Bioaccumulative potential
methyl acetate LOW (LogKOW = 0.18)
butane LOW (LogKOW = 2.89)
propane LOW (LogKOW = 2.36)
iso-butane LOW (BCF = 1.97)
1,1-difluoroethane LOW (LogKOW = 0.75)
Mobility in soil
methyl acetate MEDIUM (KOC = 3.324)
butane LOW (KOC = 43.79)
propane LOW (KOC = 23.74)
iso-butane LOW (KOC = 35.04)
1,1-difluoroethane LOW (KOC = 35.04)
SECTION 13 Disposal considerations
Waste treatment methods
Product / Packaging disposal
DO NOT allow wash water from cleaning or process equipment to enter drains.
It may be necessary to collect all wash water for treatment before disposal.
In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first.
Where in doubt contact the responsible authority.
Consult State Land Waste Management Authority for disposal.
Discharge contents of damaged aerosol cans at an approved site.
Allow small quantities to evaporate.
DO NOT incinerate or puncture aerosol cans.
Bury residues and emptied aerosol cans at an approved site.
SECTION 14 Transport information
Labels Required
Marine PollutantNO
Land transport (DOT)
UN number or ID number 1950
UN proper shipping name Aerosols, flammable, (each not exceeding 1 L capacity)
Transport hazard class(es)
Class 2.1
Subsidiary riskNot Applicable
Packing group Not Applicable
Environmental hazard Not Applicable
Special precautions for user
Hazard Label 2.1
Special provisionsN82 Version No: 7.8 Page 15 of 18
METYFIX 3 SPRAY ADHESIVE AEROSOL, MULTI-PURPOSE SPRAY ADHESIVE
Issue Date: 20/03/2023
Print Date: 20/03/2023 Continued…

Product name Group
Product name Ship Type
Air transport (ICAO-IATA / DGR)
UN number 1950
UN proper shipping name Aerosols, flammable
Transport hazard class(es)
ICAO/IATA Class 2.1
ICAO / IATA SubriskNot Applicable
ERG Code 10L
Packing group Not Applicable
Environmental hazard Not Applicable
Special precautions for user
Special provisions A145 A167 A802
Cargo Only Packing Instructions 203
Cargo Only Maximum Qty / Pack 150 kg
Passenger and Cargo Packing Instructions 203
Passenger and Cargo Maximum Qty / Pack 75 kg
Passenger and Cargo Limited Quantity Packing InstructionsY203
Passenger and Cargo Limited Maximum Qty / Pack 30 kg G
Sea transport (IMDG-Code / GGVSee)
UN number 1950
UN proper shipping name AEROSOLS
Transport hazard class(es)
IMDG Class 2.1
IMDG Subrisk Not Applicable
Packing group Not Applicable
Environmental hazard Not Applicable
Special precautions for user
EMS Number F-D, S-U
Special provisions63 190 277 327 344 381 959
Limited Quantities1000 ml
Transport in bulk according to Annex II of MARPOL and the IBC code
Not Applicable
Transport in bulk in accordance with MARPOL Annex V and the IMSBC Code
methyl acetate Not Available
Hydrocarbons, C6-C7,
n-alkanes, isoalkanes, cyclics,
<5% n-hexane Not Available butane Not Available propane Not Available iso-butane Not Available 1,1-difluoroethane Not Available Transport in bulk in accordance with the IGC Code methyl acetate Not Available Hydrocarbons, C6-C7, n-alkanes, isoalkanes, cyclics, <5% n-hexane Not Available butane Not Available propane Not Available iso-butane Not Available 1,1-difluoroethane Not Available SECTION 15 Regulatory information Safety, health and environmental regulations / legislation specific for the substance or mixture methyl acetate is found on the following regulatory lists Version No: 7.8 Page 16 of 18 METYFIX 3 SPRAY ADHESIVE AEROSOL, MULTI-PURPOSE SPRAY ADHESIVE Issue Date: 20/03/2023 Print Date: 20/03/2023 Continued... US - Massachusetts - Right To Know Listed Chemicals US DOE Temporary Emergency Exposure Limits (TEELs) US NIOSH Recommended Exposure Limits (RELs) US OSHA Permissible Exposure Limits (PELs) Table Z-1 US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory US TSCA Chemical Substance Inventory - Interim List of Active Substances US TSCA Section 4/12 (b) - Sunset Dates/Status Hydrocarbons, C6-C7, n-alkanes, isoalkanes, cyclics, <5% n-hexane is found on the following regulatory lists Chemical Footprint Project - Chemicals of High Concern List International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs - Not Classified as Carcinogenic US DOE Temporary Emergency Exposure Limits (TEELs) US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory US TSCA Chemical Substance Inventory - Interim List of Active Substances butane is found on the following regulatory lists Chemical Footprint Project - Chemicals of High Concern List US - Massachusetts - Right To Know Listed Chemicals US Department of Homeland Security (DHS) - Chemical Facility Anti-Terrorism Standards (CFATS) - Chemicals of Interest US DOE Temporary Emergency Exposure Limits (TEELs) US NIOSH Recommended Exposure Limits (RELs) US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory US TSCA Chemical Substance Inventory - Interim List of Active Substances propane is found on the following regulatory lists US - Massachusetts - Right To Know Listed Chemicals US Department of Homeland Security (DHS) - Chemical Facility Anti-Terrorism Standards (CFATS) - Chemicals of Interest US DOE Temporary Emergency Exposure Limits (TEELs) US NIOSH Recommended Exposure Limits (RELs) US OSHA Permissible Exposure Limits (PELs) Table Z-1 US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory US TSCA Chemical Substance Inventory - Interim List of Active Substances iso-butane is found on the following regulatory lists Chemical Footprint Project - Chemicals of High Concern List US - Massachusetts - Right To Know Listed Chemicals US Department of Homeland Security (DHS) - Chemical Facility Anti-Terrorism Standards (CFATS) - Chemicals of Interest US DOE Temporary Emergency Exposure Limits (TEELs) US NIOSH Recommended Exposure Limits (RELs) US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory US TSCA Chemical Substance Inventory - Interim List of Active Substances 1,1-difluoroethane is found on the following regulatory lists US - Massachusetts - Right To Know Listed Chemicals US AIHA Workplace Environmental Exposure Levels (WEELs) US Department of Homeland Security (DHS) - Chemical Facility Anti-Terrorism Standards (CFATS) - Chemicals of Interest US DOE Temporary Emergency Exposure Limits (TEELs) US EPA Integrated Risk Information System (IRIS) US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory US Toxicology Excellence for Risk Assessment (TERA) Workplace Environmental Exposure Levels (WEEL) US TSCA Chemical Substance Inventory - Interim List of Active Substances Federal Regulations Superfund Amendments and Reauthorization Act of 1986 (SARA) Section 311/312 hazard categories Flammable (Gases, Aerosols, Liquids, or Solids) Yes Gas under pressure No Explosive No Self-heating No Pyrophoric (Liquid or Solid) No Pyrophoric Gas No Corrosive to metal No Oxidizer (Liquid, Solid or Gas) No Organic Peroxide No Self-reactive No In contact with water emits flammable gas No Combustible Dust No Carcinogenicity No Acute toxicity (any route of exposure) No Reproductive toxicity No Skin Corrosion or Irritation Yes Respiratory or Skin Sensitization No Serious eye damage or eye irritation Yes Specific target organ toxicity (single or repeated exposure) Yes Aspiration Hazard No Germ cell mutagenicity No Simple Asphyxiant No Hazards Not Otherwise Classified No US. EPA CERCLA Hazardous Substances and Reportable Quantities (40 CFR 302.4) None Reported State Regulations Version No: 7.8 Page 17 of 18 METYFIX 3 SPRAY ADHESIVE AEROSOL, MULTI-PURPOSE SPRAY ADHESIVE Issue Date: 20/03/2023 Print Date: 20/03/2023 Continued... National Inventory Status Version Date of Update Sections Updated US. California Proposition 65 None listed National Inventory Status Australia - AIIC / Australia Non-Industrial Use Yes Canada - DSL Yes Canada - NDSL No (methyl acetate; Hydrocarbons, C6-C7, n-alkanes, isoalkanes, cyclics, <5% n-hexane; butane; propane; iso-butane; 1,1-difluoroethane) China - IECSC Yes Europe - EINEC / ELINCS / NLP Yes Japan - ENCS No (Hydrocarbons, C6-C7, n-alkanes, isoalkanes, cyclics, <5% n-hexane) Korea - KECI Yes New Zealand - NZIoC Yes Philippines - PICCS Yes USA - TSCA Yes Taiwan - TCSI Yes Mexico - INSQ Yes Vietnam - NCI Yes Russia - FBEPH Yes Legend: Yes = All CAS declared ingredients are on the inventory No = One or more of the CAS listed ingredients are not on the inventory. These ingredients may be exempt or will require registration. SECTION 16 Other information Revision Date 20/03/2023 Initial Date07/04/2022 SDS Version Summary 6.8 20/03/2023 Firefighting measures - Fire Fighter (fire/explosion hazard), Composition / information on ingredients - Ingredients, Identification of the substance / mixture and of the company / undertaking - Supplier Information Other information Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references. The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered. Definitions and abbreviations PC TWA: Permissible Concentration-Time Weighted Average PC STEL: Permissible Concentration-Short Term Exposure Limit IARC: International Agency for Research on Cancer ACGIH: American Conference of Governmental Industrial Hygienists STEL: Short Term Exposure Limit TEEL: Temporary Emergency Exposure Limit IDLH: Immediately Dangerous to Life or Health Concentrations ES: Exposure Standard OSF: Odour Safety Factor NOAEL :No Observed Adverse Effect Level LOAEL: Lowest Observed Adverse Effect Level TLV: Threshold Limit Value LOD: Limit Of Detection OTV: Odour Threshold Value BCF: BioConcentration Factors BEI: Biological Exposure Index AIIC: Australian Inventory of Industrial Chemicals DSL: Domestic Substances List NDSL: Non-Domestic Substances List IECSC: Inventory of Existing Chemical Substance in China EINECS: European INventory of Existing Commercial chemical Substances ELINCS: European List of Notified Chemical Substances NLP: No-Longer Polymers ENCS: Existing and New Chemical Substances Inventory KECI: Korea Existing Chemicals Inventory NZIoC: New Zealand Inventory of Chemicals PICCS: Philippine Inventory of Chemicals and Chemical Substances TSCA: Toxic Substances Control Act TCSI: Taiwan Chemical Substance Inventory INSQ: Inventario Nacional de Sustancias Qu micas NCI: National Chemical Inventory FBEPH: Russian Register of Potentially Hazardous Chemical and Biological Substances Powered by AuthorITe, from Chemwatch. Version No: 7.8 Page 18 of 18 METYFIX 3 SPRAY ADHESIVE AEROSOL, MULTI-PURPOSE SPRAY ADHESIVE Issue Date: 20/03/2023 Print Date: 20/03/2023 end of SDS

23M55420FSA_SDS.pdf

by | Sep 27, 2025

SDS
SAFETY DATA SHEET

SDS Number:
Page 1 of 7
BD320FX/BD420FX/BD422FX/BD425FX
Structural Acrylic Bonding Adhesive – Cartridges
Revision No.: 2
Date:07/09/2018
3
Section 1 IDENTIFICATION
Product Name: BD320FX/BD420FX/BD422FX/BD425FX Structural Acrylic Bonding Adhesive – Cartridges

Manufacturer: Big Dog Adhesives, LLC
615 S 4
th
Street
Elkhart, INDIANA, USA 46516-2717
Phone: 1-833-244-3644 (1-833-BIG-DOGG) Fax: 1-833-244-3649 (1-833-BIG-DOGZ)
Email: sales@bigdogadhesives.com Website: www.bigdogadhesives.com
Trade Name: BD320FX/BD420FX/BD422FX/BD425FX Structural Acrylic Bonding Adhesives

Materials Uses: High strength acrylic adhesive for bonding fiberglass, steel, aluminum, and various
substrates together. 10:1 product has high flexural strength and tensile strengths.
In Case of Emergency Contact CHEMTREC : 800-424-9300 (USA)
703-527-3887 (INTERNATIONAL)

Section 2 HAZARD IDENTIFICATION
GHS Classification:
CATEGORY
SIGNAL
WORD
HAZARD STATEMENT(S)
Physical
Flammable Liquids, Category 2

DANGER

H225 Highly flammable liquid and vapor

Health
Acute Oral Toxicity, Category 4
Skin Irritation, Category 2
Eye Irritation, Category 2B
Skin Sensitization, Category 1
STOT SE, Category 3

WARNING
WARNING
WARNING
WARNING
WARNING

H302 Harmful if swallowed
H315 Causes skin irritation
H320 Causes eye irritation
H317 May cause an allergic skin reaction
H335 – May cause a respiratory irritation
Environmental
Acute, Category 3
Chronic, Category 4

H402 Harmful to aquatic life
H413 May cause long lasting harmful effects to aquatic life

GHS Precaution Statements:
Prevention:
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P261 Avoid breathing dust/fume/mist/vapors/spray.
P264 Wash hands (or other affected skin surfaces) thoroughly after handling.
P270 Do not eat, drink, or smoke when using this product.

SDS
SAFETY DATA SHEET

SDS Number:
Page 2 of 7
BD320FX/BD420FX/BD422FX/BD425FX
Structural Acrylic Bonding Adhesive – Cartridges
Revision No.: 2
Date:07/09/2018
3
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P370/P378 In case of fire: Use dry chemical or CO2 to extinguish
P305/P351/P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P301/P312 IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell.
P302/P352 IF ON SKIN: Wash with plenty of soap and water.
P333/P313 If skin irritation or rash occurs get medical advice/attention.
Storage:
P403 Store in a well-ventilated place .
P410 Protect from sunlight.
P411 Store at temperatures not exceeding 25
O
C (75
O
F).
Disposal:
P501 Dispose of contents/containers in accordance with local/regional/national/international regulations.
Route of Entry: Eye contact, skin contact, inhalation, and ingestion.
Target Organs: Skin, eyes, respiratory tract, digestive tract, liver, kidney, olfactory and Central Nervous System
(CNS).
Skin Contact: May cause irritation of the skin. Prolonged exposure may cause sensitization. Preexisting skin
conditions may be aggravated by exposure to this material.
Eye Contact: May cause irritation and/or sensitization.
Respiratory Contact: Respiratory tract irritant. Prolonged exposure may result in dizziness, nausea, headache,
and anesthetic effects. May cause sensitization. Preexisting respiratory conditions may be aggravated by
exposure to this product. May cause CNS depression.
Ingestion: Not an expected route of entry. If ingested it may cause irritation to the gastrointestinal tract.

ADHESIVE:
HMIS (United States) NFPA (United States) WHMIS (Canada): B2, D2B
Health 2

Flammability 3

3

Reactivity 2

PPE B

2

2

ACTIVATOR:
HMIS (United States) NFPA (United States) WHMIS (Canada): C, D2B
Health 2

Flammability 3

3

Reactivity 2

PPE B

2

2

SDS
SAFETY DATA SHEET

SDS Number:
Page 3 of 7
BD320FX/BD420FX/BD422FX/BD425FX
Structural Acrylic Bonding Adhesive – Cartridges
Revision No.: 2
Date:07/09/2018
3
Section 3 COMPOSITION / INFORMATION ON INGREDIENTS
Name CAS # % by Weight
Adhesive: Methyl Methacrylate Monomer 80-62-6 40 80
Methacrylic Acid 79-41-4 1 10
Activator: Benzoyl Peroxide 94-36-0 5 30

Section 4 FIRST-AID MEASURES
Skin: Remove contaminated clothing. Flush skin with water, then wash affected areas with soap and water. If
irritation develops, seek medical attention. Wash or dispose of clothing before reuse.
Eye: Flush eyes with water for 15 minutes. Remove contact lenses prior to water flush if possible. Seek
immediate medical attention.
Respiratory: Remove patient to fresh air. If patient is having difficulty breathing, seek immediate medical
attention. If not breathing, clear airway and start mouth-to-mouth artificial respiration (or use bag-mask
respirator). Seek immediate medical attention.
Ingestion: Give patient water to dilute material in stomach. DO NOT induce vomiting. Seek immediate medical
attention. If vomiting occurs naturally, have person lean forward to reduce risk of aspiration. DO NOT give
anything by mouth to an unconscious person.

Section 5 FIRE-FIGHTING MEASURES
Suitable Extinguishing Media: In case of fire, use dry chemical or CO2. Water spray may cause frothing.
Specific Hazards Arising from the Chemical: Sealed containers of adhesive may rupture violently at elevated
temperatures due to polymerization. Organic peroxides can decompose violently if heated while confined.
Special Protective Equipment and Precautions for Firefighters: Use self-contained breathing apparatus
(SCBA) and protective clothing.
Flash Point and Method: 50
o
F (10
o
C). Fine mists may be explosive below the flash point. Tag Closed Cup.
Flammability Classification: Class 1B.
Risk of Explosion due to Mechanical Impact: Not Applicable.
Risk of Explosion due to Static Discharge: Not Applicable.
Hazardous Products of Combustion: Carbon Oxides (CO and CO2), Methyl Methacrylate, and various
Hydrocarbons.
Autoignition Temp.: 790
o
F (421
o
C).
LEL: 1.7%.
UEL: 12.5%.

Section 6 ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment, and Emergency Procedures: For large spill or leak wear self-
contained breathing apparatus (SCBA) and appropriate PPE.
Environmental Precautions: Keep out of sewers and drains.
Clean-Up Methods and Materials: Absorb with an inert material and place in an appropriate container for
disposal.

Section 7 HANDLING AND STORAGE
Handling Precautions: Avoid breathing vapors. Use in a well-ventilated area. Wear rubber gloves (nitrile or
butyl) and chemical resistant apron. Wear chemical splash goggles. Do not reuse empty containers.

SDS
SAFETY DATA SHEET

SDS Number:
Page 4 of 7
BD320FX/BD420FX/BD422FX/BD425FX
Structural Acrylic Bonding Adhesive – Cartridges
Revision No.: 2
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Storage Precautions: Store in a cool, dry, well-ventilated area at temperatures less than 75
o
F (25
o
C). Storage
above 212
o
F (100
o
C) may cause explosive decomposition. Avoid storage in direct sunlight. Keep containers
closed when not in use. Keep away from heat sources, sparks, and open flames.

Section 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control Parameters and Exposures:
Material Name: Exposure Limits:
Benzoyl Peroxide (CAS 94-36-0): OSHA PEL: TWA 5 mg/m
3

ACGIH TLV: TWA 5 mg/m
3

Methacrylic Acid (CAS 79-41-4): ACGIH TLV: TWA 20 ppm
Methyl Methacrylate (CAS 80-62-6): OSHA PEL: TWA 100 ppm
ACGIH TLV: TWA 50 ppm
STEL 100 ppm
Engineering Controls: Provide adequate explosion proof ventilation (general or local exhaust). Ensure that a
working eyewash and safety shower are in the work area.
Individual Protection Measures and PPE:
Eye / Face Protection: Wear safety glasses with side shields or splash goggles.
Skin Protection: Chemical resistant gloves (nitrile or butyl) and chemical resistant apron are recommended.
Respiratory Protection In case of insufficient ventilation, wear an approved (NIOSH) respirator with organic
vapor cartridge and dust/mist pre-filter.
Thermal Hazards: None.

Section 9 PHYSICAL AND CHEMICAL PROPERTIES
Adhesive Activator
Appearance: Colored (various) Paste Colored (various) paste
Odor: Mild Sweet Mild Sweet
Odor Threshold: Not Available Not Available
pH: 4.0 6.0 4.0 6.0
Melting Point / Freezing Point: -54
o
F (-48
o
C) Not Available
Initial Boiling Point: 212
o
F (100
o
C) > 550
o
F (288
o
C)
Flash Point and Method: 50
o
F (10
o
C) Tag Closed Cup Not Available
Evaporation Rate: 3 <1 (butyl acetate = 1) Flammability: Class 1B Class 1B. Lower Explosion Limit: 1.7% Not Available Upper Explosion Limit: 12.5% Not Available Vapor Pressure: 28 mm Hg @ 68 o F (20 o C) < 0.5 mm Hg @ 68 o F (20 o C) Vapor Density: 3.5 Not Available Relative Density: 7.7 8.8 lbs./gallon Not Available Solubility(ies): Not Available Not Available Partition Coefficient (n-Octanol in Water): Not Applicable Not Applicable Auto-Ignition Temperature: 790 o F (421 o C) Not Available Decomposition Temperature: Not Available Not Available Viscosity (Dynamic CPS/mPa-s): 50k 250k 25k to 125k Percent Volatile: Not Available Not Available Specific Gravity: 0.93 1.05 1.0 to 1.15 VOC: < 50 g/L of mixed product Not Available SDS SAFETY DATA SHEET SDS Number: Page 5 of 7 BD320FX/BD420FX/BD422FX/BD425FX Structural Acrylic Bonding Adhesive - Cartridges Revision No.: 2 Date:07/09/2018 3 Section 10 STABILITY AND REACTIVITY Reactivity: Product is stable as supplied and when used as intended. Product can become unstable under certain conditions or in contact with incompatible materials. Chemical Stability: Not Available. Possibility of Hazardous Reactions: Polymerization may occur under certain conditions. Conditions to Avoid: Avoid extreme temperatures, open flames, sparks, and direct sunlight. Materials to Avoid (Incompatibility): Oxidizing agents and conditions, strong acids and alkalies, oxygen-free atmospheres, inert gas blanketing, and free radical initiators. Hazardous Decomposition Products: Carbon Oxides (CO, CO2), Methyl Methacrylate, and various Hydrocarbons. Section 11 TOXICOLOGICAL INFORMATION Acute Toxicity to Animals: Adhesive: Methyl Methacrylate (CAS 80-62-6): LC50 = 7093 ppm (4 hour inhalation, rat) LD50 = 7940 mg/kg (oral, rat) LD50 > 7550 mg/kg (dermal, rabbit)
Methacrylic Acid (CAS 79-41-4): LC50 = 7100 mg/m
3
(4 hour inhalation, rat)
LD50 > 7550 mg/kg (oral, rat)
LD50 = 1600 mg/kg (oral, mouse)
LD50 > 500 mg/kg (dermal, rabbit
Activator: Benzoyl Peroxide (CAS 94-36-0): LC50 = 2 mg/L (96 hour inhalation, guppy)
LD50 = 6400 mg/kg (oral, rat)
LD50 > 2000 mg/kg (oral, mouse)

Acute Toxicity to Humans: This product has not been tested for human effects. No additional information.
Chronic Toxicity to Animals: This product has not been tested for animal effects. No additional information.
Chronic Toxicity to Humans: This product has not been tested for human effects. No additional information.
Skin Corrosion / Irritation: Not Available.
Eye Damage / Irritation: Not Available.
Respiratory Sensitization: Not Available.
Skin Sensitization: Not Available.
Mutagenicity: Classifiable as none for human.
Carcinogenicity: Not classifiable for human or animal.
Reproductive Toxicity: Not Available.
Teratogenic Effects: Classifiable as none for human.
STOST- Single Exposure: Not Available.
STOST Repeated Exposure: Not Available.
Aspiration Hazard: Not Available.

Section 12 ECOLOGICAL INFORMATION
Ecotoxicity: This product contains components that may be harmful to aquatic organisms and may cause long
term adverse effects in an aquatic environment.
Persistence and Degradability: Not Available.

SDS
SAFETY DATA SHEET

SDS Number:
Page 6 of 7
BD320FX/BD420FX/BD422FX/BD425FX
Structural Acrylic Bonding Adhesive – Cartridges
Revision No.: 2
Date:07/09/2018
3
Bioaccumulative Potential: This product contains components with the potential to bio-accumulate.
Mobility in Soil: Not Available.
Other Adverse Effects: Not Available.

Section 13 DISPOSAL CONSIDERATIONS
Disposal Methods:
Adhesive: Adhesive is considered Hazardous Waste Product per RCRA 40 CFR 261 and is classed as D001.
Spilled, contaminated, or waste material should be put into a suitable container and handled according to
Federal, State, and local regulations. Contact a qualified waste management company for assistance.
Activator: Not a hazardous waste product (RCRA 50 CFR 261). May be disposed of by landfill or incineration.
Dispose of in accordance with Federal, State, and local regulations.
DANGER! Rags, steel wool, and waste soaked with this product may spontaneously catch fire if improperly
discarded or stored. Waste should be immediately placed in a sealed water filled container.

Section 14 TRANSPORT INFORMATION
UN Number: UN1133.
UN Proper Shipping Name: Adhesives (DOT), Flammable Liquid.
Transport Hazard Class: 3.
Packing Group: II
DOT Classification: UN1133, Adhesives, Flammable Liquid, Hazard Class 3, Packing Group II, Limited
Quantity.
Special Provision for Transport: 1 Liter (0.3 gallon) or less may use Limited Quantity exceptions (49 CFR
172.102 & 49 CFR 173.150 (a) (2)).
ADR / RID Classification: Class 3 Flammable Liquid.
ICAO/IATA Classification: Class 3 Flammable Liquid.
IMO/IMDG Classification: Class 3 Flammable Liquid.
Marine Pollutant: No additional information.

Section 15 REGULATORY INFORMATION
U.S. Federal Regulations
Chemical (& CAS Number)
SARA 302
(EHS)TPQ
SARA 304
(EHS)Rq
SARA 313
de minimis
CERCLA
Rq
CAA
112(r) TQ
RCRA
Code
Benzoyl Peroxide (CAS 94-36-0) 1.0
Methyl Methacrylate (CAS 80-62-6) 1.0 1000 U162
Methacrylic Acid (CAS 79-41-4)
All quantities in pounds.

State Regulations
Chemical (& CAS Number)
CA
Prop 65
MA
RTK
MN
RTK
NJ
RTK
PA
RTK
RI
RTK
Benzoyl Peroxide (CAS 94-36-0) X X X X
Methyl Methacrylate (CAS 80-62-6) X X X X X
Methacrylic Acid (CAS 79-41-4) X X

TSCA (Toxic Substances Control Act): All components of this product are on the TSCA Inventory or are
exempt from TSCA Inventory Requirements.

SDS
SAFETY DATA SHEET

SDS Number:
Page 7 of 7
BD320FX/BD420FX/BD422FX/BD425FX
Structural Acrylic Bonding Adhesive – Cartridges
Revision No.: 2
Date:07/09/2018
3
International Regulations:
DSL (Canada Domestic Substance List): All components of this product are on the DSL (Canada Domestic
Substance List) or are exempt from DSL.
EINECS: Not Available.
WHMIS: B2, C, D2B.

Section 16 OTHER INFORMATION
Changes to This Revision: July 9, 2018
Prepared By: Louis J. Giovannini
Telephone: USA 520-271-7313
Internet: lou@bigdogadhesives.com
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above
named manufacturer nor any of its subsidiaries assumes any liability whatsoever for accuracy or
completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may
present unknown hazards and should be used with caution. Although certain hazards are described
herein, we cannot guarantee that these are the only hazards that exist.
END OF SDS DOCUMENT

23M55330_SDS.pdf

by | Sep 27, 2025

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SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : ASI MP-55330-A
Product code : 100000008550
Manufacturer or supplier’s details
Company : H.B. Fuller Engineering Adhesives

Address : 9001 W Fey Drive
Frankfort, IL, 60423
Telephone : 1-815-464-5606

Medical Emergency Phone Number (24 Hours): 1-888-853-1758

Transport Emergency Phone Number (CHEMTREC): 1-800-424-9300

Recommended use of the chemical and restrictions on use
Recommended use : Adhesive

Restrictions on use : For industrial use only.

SECTION 2. HAZARDS IDENTIFICATION

Emergency Overview
Appearance paste
Color off-white
Odor characteristic

GHS Classification
Flammable liquids : Category 2
Acute toxicity (Inhalation) : Category 2
Skin irritation : Category 2
Serious eye damage : Category 1
Skin sensitization : Category 1
Carcinogenicity : Category 2
Specific target organ toxicity –
single exposure
: Category 3 (Respiratory system)
GHS label elements
Hazard pictograms :

Signal Word : Danger

Hazard Statements:
H225 Highly flammable liquid and vapor. H315 Causes skin irritation. H317 May cause an allergic
skin reaction. H318 Causes serious eye damage. H330 Fatal if inhaled. H335 May cause

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respiratory irritation. H351 Suspected of causing cancer.
Precautionary Statements:
Prevention: P201 Obtain special instructions before use. P202 Do not handle until all safety
precautions have been read and understood. P210 Keep away from heat/sparks/open flames/hot
surfaces. No smoking. P233 Keep container tightly closed. P240 Ground/bond container and
receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use
only non-sparking tools. P243 Take precautionary measures against static discharge. P260 Do not
breathe dust/ fume/ gas/ mist/ vapors/ spray. P264 Wash skin thoroughly after handling. P271 Use
only outdoors or in a well-ventilated area. P272 Contaminated work clothing must not be allowed
out of the workplace. P280 Wear protective gloves/ protective clothing/ eye protection/ face
protection. P284 Wear respiratory protection.
Response: P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water/shower. P304 + P340 + P310 IF INHALED: Remove person to fresh
air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351
+ P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
P308 + P313 IF exposed or concerned: Get medical advice/ attention. P333 + P313 If skin irritation
or rash occurs: Get medical advice/ attention. P362 Take off contaminated clothing and wash before
reuse. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to
extinguish.
Storage: P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235
Store in a well-ventilated place. Keep cool. P405 Store locked up.
Disposal: P501 Dispose of contents/ container to an approved waste disposal plant.
Potential Health Effects

Carcinogenicity:
IARC Group 2B: Possibly carcinogenic to humans
tetrahydrofuran

109-99-9
cumene

98-82-8
OSHA No component of this product present at levels greater than or
equal to 0.1% is on OSHA s list of regulated carcinogens.
NTP Reasonably anticipated to be a human carcinogen
cumene

98-82-8

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

Hazardous ingredients
Chemical name CAS-No. Concentration [%]
ethyl 2-cyanoacrylate 7085-85-0 50 – 70
methyl methacrylate 80-62-6 5 – 10
1,4-Naphthalenedione 130-15-4 3 – 5
2,6-di-tert-butyl-p-cresol 128-37-0 1 – 5
tetrahydrofuran 109-99-9 1 – 5
2-Propenoic acid, 2-methyl-, 2-hydroxyethyl ester,
phosphate
52628-03-2 0.1 – 1
, -dimethylbenzyl hydroperoxide 80-15-9 0.1 – 1

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cumene 98-82-8 0.1 – 1

SECTION 4. FIRST AID MEASURES

General advice : Show this material safety data sheet to the doctor in
attendance.

If inhaled : Move to fresh air.
Keep patient warm and at rest.
Consult a physician after significant exposure.

In case of skin contact : Wash off immediately with soap and plenty of water.
Call a physician if irritation develops or persists.

In case of eye contact : Rinse immediately with plenty of water, also under the eyelids.
Seek medical advice.

If swallowed : If swallowed, call a poison control center or doctor
immediately.
Do not induce vomiting without medical advice.
Drink plenty of water.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Carbon dioxide (CO2)
Sand
Foam

Unsuitable extinguishing
media
: Water

Hazardous combustion
products
: No hazardous combustion products are known
Specific extinguishing
methods
:
Further information : Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.

Special protective equipment
for fire-fighters
: Wear an approved positive pressure self-contained breathing
apparatus in addition to standard fire fighting gear.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions,
protective equipment and
emergency procedures
: Refer to protective measures listed in sections 7 and 8.
Ensure adequate ventilation.

Environmental precautions : Prevent product from entering drains.
Do not flush into surface water or sanitary sewer system.

Methods and materials for
containment and cleaning up
: Ventilate the area.
Soak up with inert absorbent material.

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Use neutralizing agents.
Shovel or sweep up.

SECTION 7. HANDLING AND STORAGE

Local/Total ventilation : Use only with adequate ventilation.

Advice on safe handling : Wear personal protective equipment.
Do not get on skin or clothing.
Keep away from heat and flame.

Conditions for safe storage : Keep containers tightly closed in a dry, cool and well-
ventilated place.
Store in original container.

Materials to avoid : Do not store together with oxidizing and self-igniting products.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters
Components CAS-No. Value type
(Form of
exposure)
Control
parameters /
Permissible
concentration
Basis
ethyl 2-cyanoacrylate 7085-85-0 PEL 0.2 ppm
1.02 mg/m3
CAL PEL
TWA 0.2 ppm ACGIH
STEL 1 ppm ACGIH
methyl methacrylate 80-62-6 TWA 50 ppm ACGIH
STEL 100 ppm ACGIH
TWA 100 ppm
410 mg/m3
OSHA Z-1
TWA 100 ppm
410 mg/m3
OSHA P0
PEL 50 ppm
205 mg/m3
CAL PEL
STEL 100 ppm
410 mg/m3
CAL PEL
2,6-di-tert-butyl-p-cresol 128-37-0 TWA
(Inhalable
fraction and
vapor)
2 mg/m3 ACGIH
TWA 10 mg/m3 OSHA P0
PEL 10 mg/m3 CAL PEL
tetrahydrofuran 109-99-9 TWA 50 ppm ACGIH
STEL 100 ppm ACGIH
TWA 200 ppm
590 mg/m3
OSHA Z-1
STEL 250 ppm OSHA P0

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735 mg/m3
TWA 200 ppm
590 mg/m3
OSHA P0
PEL 200 ppm
590 mg/m3
CAL PEL
STEL 250 ppm
735 mg/m3
CAL PEL
cumene 98-82-8 TWA 50 ppm ACGIH
TWA 50 ppm
245 mg/m3
NIOSH REL
TWA 50 ppm
245 mg/m3
OSHA Z-1
TWA 50 ppm
245 mg/m3
OSHA P0
PEL 50 ppm
245 mg/m3
CAL PEL

Personal protective equipment
Respiratory protection : Use respiratory protection unless adequate local exhaust
ventilation is provided or exposure assessment demonstrates
that exposures are within recommended exposure guidelines.

Filter type : Combined particulates and organic vapor type

Hand protection
Material : Impervious gloves

Eye protection : Tightly fitting safety goggles
Ensure that eyewash stations and safety showers are close to
the workstation location.

Skin and body protection : Long sleeved clothing
Preventive skin protection

Protective measures : Avoid contact with skin.

Hygiene measures : Avoid contact with skin, eyes and clothing.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : paste
Color : off-white
Odor : characteristic
Odor Threshold : No data available
Melting point/freezing point : not determined
Boiling point/boiling range : not determined
Flash point : 10 C
Evaporation rate : not determined
Flammability (solid, gas) : Not classified as a flammability hazard

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Upper explosion limit : Upper flammability limit
not determined
Lower explosion limit : Lower flammability limit
not determined
Density : 0.99 g/cm3
Solubility(ies)
Water solubility : not determined
Partition coefficient: n-
octanol/water
: No data available
Autoignition temperature : not determined
Viscosity
Viscosity, kinematic : not determined

SECTION 10. STABILITY AND REACTIVITY

Chemical stability : The product is chemically stable.

Hazardous decomposition
products
: Nitrogen oxides (NOx)
Sulfur oxides

SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity
Product:
Acute oral toxicity : Acute toxicity estimate : 2,347 mg/kg
Method: Calculation method

Acute inhalation toxicity : Acute toxicity estimate : 1.25 mg/l
Exposure time: 4 h
Test atmosphere: vapor
Method: Calculation method

Components:
methyl methacrylate:
Acute inhalation toxicity : LC50 Rat: 4632 ppm
Exposure time: 4 h
Test atmosphere: vapor

2,6-di-tert-butyl-p-cresol:
Acute oral toxicity : LD50 Oral Rat: 6,000 mg/kg

, -dimethylbenzyl hydroperoxide:

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Acute oral toxicity : LD50 Oral Rat: 382 mg/kg

Acute inhalation toxicity : LC50 Rat: 220 ppm
Exposure time: 4 h
Test atmosphere: vapor

Acute dermal toxicity : LD50 Dermal Rat: 500 mg/kg

cumene:
Acute oral toxicity : LD50 Oral Rat: 1,400 mg/kg

Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitization
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
No data available
Reproductive toxicity
No data available
STOT-single exposure
No data available
STOT-repeated exposure
No data available
Aspiration toxicity
No data available

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

Components:
methyl methacrylate :
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): > 79 mg/l
Exposure time: 96 h
Test Method: flow-through test

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 69 mg/l

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aquatic invertebrates Exposure time: 48 h
Test Method: static test

2,6-di-tert-butyl-p-cresol :
Toxicity to fish : LC50 (Oryzias latipes (Japanese medaka)): 5 mg/l
Exposure time: 48 h
Test Method: static test

Toxicity to algae : EC50 (Desmodesmus subspicatus (green algae)): > 0.42 mg/l
Exposure time: 72 h
Test Type: flow-through test

, -dimethylbenzyl hydroperoxide :
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 3.9 mg/l
Exposure time: 96 h
Test Method: static test

Toxicity to daphnia and other
aquatic invertebrates
: EC50 (Daphnia magna (Water flea)): 7 mg/l
Exposure time: 24 h
Test Method: static test

cumene :
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 2.7 mg/l
Exposure time: 96 h
Test Method: semi-static test

Toxicity to daphnia and other
aquatic invertebrates
: EC50 (Daphnia magna (Water flea)): 0.6 mg/l
Exposure time: 48 h
Test Method: static test

Toxicity to algae : EC50 (Pseudokirchneriella subcapitata (microalgae)): 2.6 mg/l
Exposure time: 72 h
Test Type: flow-through test

Persistence and degradability
No data available
Bioaccumulative potential
Mobility in soil
No data available
Other adverse effects
No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : Do not dispose of together with household waste.
Do not dispose of waste into sewer.
To the best of our knowledge, this product does not meet the
definition of hazardous waste under the U.S. EPA Hazardous

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Waste Regulations 40 CFR 261. Disposal via incineration at
an approved facility is recommended, as industry best
practice. Consult state, local or provincial authorities for more
restrictive requirements.

SECTION 14. TRANSPORT INFORMATION

Special precautions for user
Not applicable
Domestic regulation
49 CFR
UN/ID/NA number : 1133
Proper shipping name : Adhesives
Class : 3
Packing group : II
Labels : 3
ERG Code : 128
Marine pollutant : no

International Regulations
IATA-DGR

UN/ID No. : 1133
Proper shipping name : Adhesives
Class : 3
Packing group : II
Labels : 3
Packing instruction (cargo
aircraft)
: 364
Packing instruction
(passenger aircraft)
: 353
IMDG-Code

UN number : 1133
Proper shipping name : ADHESIVES
Class : 3
Packing group : II
Labels : 3
EmS Code : F-E, S-D
Marine pollutant : no
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.

SECTION 15. REGULATORY INFORMATION

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SARA 311/312 Hazards : Flammable (gases, aerosols, liquids, or solids)
Acute toxicity (any route of exposure)
Skin corrosion or irritation
Serious eye damage or eye irritation
Respiratory or skin sensitization
Carcinogenicity
Specific target organ toxicity (single or repeated exposure)

SARA 302 : This material does not contain any components with a section 302
EHS TPQ.

SARA 313 : The following components are subject to reporting levels established
by SARA Title III, Section 313:
methyl methacrylate 80-62-6
cumene 98-82-8

Clean Air Act

The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR
61):
methyl methacrylate 80-62-6
cumene 98-82-8

US State Regulations
California Prop 65 Please contact Supplier for more information.

The ingredients of this product are reported in the following inventories:
TSCA On TSCA Inventory
DSL All components of this product are on the Canadian DSL
AICS On the inventory, or in compliance with the inventory
KECI On the inventory, or in compliance with the inventory
Inventories LegendTSCA (USA), DSL (Canada), REACH(Europe), AICS (Australia), NZIoC
(New Zealand), ENCS (Japan), KECI (Korea), PICCS (Philippines), IECSC (China), TWINV
(Taiwan)

SECTION 16. OTHER INFORMATION

Prepared by: Global Regulatory Department – phone: 1-651-236-5842 – email:
msds.request@hbfuller.com

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Further information

NFPA: HMIS III:

The information and recommendations set forth herein are believed to be accurate. Because some of
the information is derived from information provided to the H.B. Fuller Company from its suppliers, and
because the H.B. Fuller Company has no control over the conditions of handling and use, the H.B.
Fuller Company makes no warranty, expressed or implied, regarding the accuracy of the data or the
results to be obtained from the use thereof. The information is supplied solely for your information and
consideration, and the H.B. Fuller Company assumes no responsibility for use or reliance thereon. It is
the responsibility of the user of H.B. Fuller Company products to comply with all applicable federal,
state and local laws and regulations.

Flammability

Health

Instability

3
3

0

Special hazard
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
3

0

3*

0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic

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SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : ASI MP-55330-B
Product code : 100000008551
Manufacturer or supplier’s details
Company : H.B. Fuller Engineering Adhesives

Address : 9001 W Fey Drive
Frankfort, IL, 60423
Telephone : 1-815-464-5606

Medical Emergency Phone Number (24 Hours): 1-888-853-1758

Transport Emergency Phone Number (CHEMTREC): 1-800-424-9300

Recommended use of the chemical and restrictions on use
Recommended use : Activator

Restrictions on use : For industrial use only.

SECTION 2. HAZARDS IDENTIFICATION

Emergency Overview
Appearance liquid
Color light cream
Odor characteristic

GHS Classification
Flammable liquids : Category 2
Skin irritation : Category 2
Skin sensitization : Category 1
Carcinogenicity : Category 2
Specific target organ toxicity –
single exposure
: Category 3 (Respiratory system)
GHS label elements
Hazard pictograms :

Signal Word : Danger

Hazard Statements:
H225 Highly flammable liquid and vapor. H315 Causes skin irritation. H317 May cause an allergic
skin reaction. H335 May cause respiratory irritation. H351 Suspected of causing cancer.

Precautionary Statements:
Prevention: P201 Obtain special instructions before use. P202 Do not handle until all safety

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precautions have been read and understood. P210 Keep away from heat/sparks/open flames/hot
surfaces. No smoking. P233 Keep container tightly closed. P240 Ground/bond container and
receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use
only non-sparking tools. P243 Take precautionary measures against static discharge. P261 Avoid
breathing dust/ fume/ gas/ mist/ vapors/ spray. P264 Wash skin thoroughly after handling. P271 Use
only outdoors or in a well-ventilated area. P272 Contaminated work clothing must not be allowed
out of the workplace. P280 Wear protective gloves/ protective clothing/ eye protection/ face
protection.
Response: P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water/shower. P304 + P340 + P312 IF INHALED: Remove person to fresh
air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. P308 +
P313 IF exposed or concerned: Get medical advice/ attention. P333 + P313 If skin irritation or rash
occurs: Get medical advice/ attention. P362 Take off contaminated clothing and wash before reuse.
P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
Storage: P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235
Store in a well-ventilated place. Keep cool. P405 Store locked up.
Disposal: P501 Dispose of contents/ container to an approved waste disposal plant.
Potential Health Effects

Carcinogenicity:
IARC Group 2B: Possibly carcinogenic to humans
tetrahydrofuran

109-99-9
OSHA No component of this product present at levels greater than or
equal to 0.1% is on OSHA s list of regulated carcinogens.
NTP No ingredient of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

Hazardous ingredients
Chemical name CAS-No. Concentration [%]
methyl methacrylate 80-62-6 70 – 90
3,5-diethyl-1,2-dihydro-1-phenyl-2-propylpyridine 34562-31-7 1 – 5
2,6-di-tert-butyl-p-cresol 128-37-0 1 – 5
tetrahydrofuran 109-99-9 0.1 – 1

SECTION 4. FIRST AID MEASURES

General advice : Show this material safety data sheet to the doctor in
attendance.

If inhaled : Move to fresh air.
Keep patient warm and at rest.
Consult a physician after significant exposure.

In case of skin contact : Wash off immediately with soap and plenty of water.

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Call a physician if irritation develops or persists.

In case of eye contact : Rinse immediately with plenty of water, also under the eyelids.
Seek medical advice.

If swallowed : If swallowed, call a poison control center or doctor
immediately.
Do not induce vomiting without medical advice.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Carbon dioxide (CO2)
Sand
Foam

Unsuitable extinguishing
media
: Water

Hazardous combustion
products
: No hazardous combustion products are known
Specific extinguishing
methods
:
Further information : Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.

Special protective equipment
for fire-fighters
: Wear an approved positive pressure self-contained breathing
apparatus in addition to standard fire fighting gear.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions,
protective equipment and
emergency procedures
: Refer to protective measures listed in sections 7 and 8.
Ensure adequate ventilation.

Environmental precautions : Prevent product from entering drains.
Do not flush into surface water or sanitary sewer system.

Methods and materials for
containment and cleaning up
: Ventilate the area.
Soak up with inert absorbent material.
Do not flush with water.
Shovel or sweep up.

SECTION 7. HANDLING AND STORAGE

Local/Total ventilation : Use only with adequate ventilation.

Advice on safe handling : Wear personal protective equipment.
Do not get on skin or clothing.
Keep away from heat and flame.

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Conditions for safe storage : Keep containers tightly closed in a dry, cool and well-
ventilated place.
Store in original container.

Materials to avoid : Do not store together with oxidizing and self-igniting products.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters
Components CAS-No. Value type
(Form of
exposure)
Control
parameters /
Permissible
concentration
Basis
methyl methacrylate 80-62-6 TWA 50 ppm ACGIH
STEL 100 ppm ACGIH
TWA 100 ppm
410 mg/m3
OSHA Z-1
TWA 100 ppm
410 mg/m3
OSHA P0
PEL 50 ppm
205 mg/m3
CAL PEL
STEL 100 ppm
410 mg/m3
CAL PEL
2,6-di-tert-butyl-p-cresol 128-37-0 TWA
(Inhalable
fraction and
vapor)
2 mg/m3 ACGIH
TWA 10 mg/m3 OSHA P0
PEL 10 mg/m3 CAL PEL
tetrahydrofuran 109-99-9 TWA 50 ppm ACGIH
STEL 100 ppm ACGIH
TWA 200 ppm
590 mg/m3
OSHA Z-1
STEL 250 ppm
735 mg/m3
OSHA P0
TWA 200 ppm
590 mg/m3
OSHA P0
PEL 200 ppm
590 mg/m3
CAL PEL
STEL 250 ppm
735 mg/m3
CAL PEL

Personal protective equipment
Respiratory protection : Use respiratory protection unless adequate local exhaust
ventilation is provided or exposure assessment demonstrates
that exposures are within recommended exposure guidelines.

Filter type : Combined particulates and organic vapor type

Hand protection

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Material : Impervious gloves

Eye protection : Tightly fitting safety goggles
Ensure that eyewash stations and safety showers are close to
the workstation location.

Skin and body protection : Long sleeved clothing
Preventive skin protection

Protective measures : Avoid contact with skin.

Hygiene measures : Avoid contact with skin, eyes and clothing.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid
Color : light cream
Odor : characteristic
Odor Threshold : No data available
Melting point/freezing point : not determined
Boiling point/boiling range : not determined
Evaporation rate : not determined
Flammability (solid, gas) : Not classified as a flammability hazard

Upper explosion limit : Upper flammability limit
not determined
Lower explosion limit : Lower flammability limit
not determined
Density : 0.94 g/cm3
Solubility(ies)
Water solubility : not determined
Partition coefficient: n-
octanol/water
: No data available
Autoignition temperature : not determined
Viscosity
Viscosity, kinematic : not determined

SECTION 10. STABILITY AND REACTIVITY

Chemical stability : The product is chemically stable.

Hazardous decomposition
products
: Nitrogen oxides (NOx)
Sulfur oxides

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SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity
Product:
Acute oral toxicity : Acute toxicity estimate : > 5,000 mg/kg
Method: Calculation method

Components:
methyl methacrylate:
Acute inhalation toxicity : LC50 Rat: 4632 ppm
Exposure time: 4 h
Test atmosphere: vapor

2,6-di-tert-butyl-p-cresol:
Acute oral toxicity : LD50 Oral Rat: 6,000 mg/kg

Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitization
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
No data available
Reproductive toxicity
No data available
STOT-single exposure
No data available
STOT-repeated exposure
No data available
Aspiration toxicity
No data available

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

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Components:
methyl methacrylate :
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): > 79 mg/l
Exposure time: 96 h
Test Method: flow-through test

Toxicity to daphnia and other
aquatic invertebrates
: EC50 (Daphnia magna (Water flea)): 69 mg/l
Exposure time: 48 h
Test Method: static test

2,6-di-tert-butyl-p-cresol :
Toxicity to fish : LC50 (Oryzias latipes (Japanese medaka)): 5 mg/l
Exposure time: 48 h
Test Method: static test

Toxicity to algae : EC50 (Desmodesmus subspicatus (green algae)): > 0.42 mg/l
Exposure time: 72 h
Test Type: flow-through test

Persistence and degradability
No data available
Bioaccumulative potential
Mobility in soil
No data available
Other adverse effects
No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : Do not dispose of together with household waste.
Do not dispose of waste into sewer.
To the best of our knowledge, this product does not meet the
definition of hazardous waste under the U.S. EPA Hazardous
Waste Regulations 40 CFR 261. Disposal via incineration at
an approved facility is recommended, as industry best
practice. Consult state, local or provincial authorities for more
restrictive requirements.

SECTION 14. TRANSPORT INFORMATION

Special precautions for user
Not applicable
Domestic regulation

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49 CFR
UN/ID/NA number : 1247
Proper shipping name : Methyl methacrylate monomer, stabilized solution
Class : 3
Packing group : II
Labels : 3
ERG Code : 129P
Marine pollutant : no

International Regulations
IATA-DGR

UN/ID No. : 1247
Proper shipping name : Methyl methacrylate monomer, stabilized
Class : 3
Packing group : II
Labels : 3
Packing instruction (cargo
aircraft)
: 364
Packing instruction
(passenger aircraft)
: 353
IMDG-Code

UN number : 1247
Proper shipping name : METHYL METHACRYLATE, MONOMER, STABILIZED
Class : 3
Packing group : II
Labels : 3
EmS Code : F-E, S-D
Marine pollutant : no
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.

SECTION 15. REGULATORY INFORMATION

SARA 311/312 Hazards : Flammable (gases, aerosols, liquids, or solids)
Skin corrosion or irritation
Respiratory or skin sensitization
Specific target organ toxicity (single or repeated exposure)
Carcinogenicity

SARA 302 : This material does not contain any components with a section 302
EHS TPQ.

SARA 313 : The following components are subject to reporting levels established
by SARA Title III, Section 313:

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methyl methacrylate 80-62-6

Clean Air Act

The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR
61):
methyl methacrylate 80-62-6

US State Regulations
California Prop 65 : Please contact Supplier for more information.

The ingredients of this product are reported in the following inventories:
TSCA On TSCA Inventory
DSL All components of this product are on the Canadian DSL
AICS On the inventory, or in compliance with the inventory
KECI On the inventory, or in compliance with the inventory
PICCS On the inventory, or in compliance with the inventory
IECSC On the inventory, or in compliance with the inventory
Inventories LegendTSCA (USA), DSL (Canada), REACH(Europe), AICS (Australia), NZIoC
(New Zealand), ENCS (Japan), KECI (Korea), PICCS (Philippines), IECSC (China), TWINV
(Taiwan)

SECTION 16. OTHER INFORMATION

Prepared by: Global Regulatory Department – phone: 1-651-236-5842 – email:
msds.request@hbfuller.com

Further information

NFPA: HMIS III:

The information and recommendations set forth herein are believed to be accurate. Because some of
the information is derived from information provided to the H.B. Fuller Company from its suppliers, and
because the H.B. Fuller Company has no control over the conditions of handling and use, the H.B.
Fuller Company makes no warranty, expressed or implied, regarding the accuracy of the data or the
results to be obtained from the use thereof. The information is supplied solely for your information and
Flammability

Health

Instability

2
3

0

Special hazard
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
3

0

2*

0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic

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consideration, and the H.B. Fuller Company assumes no responsibility for use or reliance thereon. It is
the responsibility of the user of H.B. Fuller Company products to comply with all applicable federal,
state and local laws and regulations.

23M552049SC_SDS.pdf

by | Sep 27, 2025

Page 1/8
Safety Data Sheet
acc. to OSHA HCS
Printing Date 01/10/2017 Revision Date 01/10/2017Revision Number 2
44.0
* 1 Identification
Product identifier
Trade name: MP55220, MP55320, MP55420 Part B (Activator)
Relevant identified uses of the substance or mixture.Activator
Application of the substance / the mixtureActivator
Details of the supplier of the safety data sheet
Manufacturer/Supplier:
Adhesive Systems, Inc.
A Division of Royal Adhesives & Sealants, LLC
9411 Corsair Road
Frankfort, Illinois 60423
Phone Number: 800-552-0299
Information department:Environment protection department.
Emergency telephone number:
ChemTrec: Day or Night within USA and Canada: 1-800-424-9300.
Outside USA and Canada: +1 703-527-3887 (collect calls accepted)
* 2 Hazard(s) identification
Classification of the substance or mixture
Flam. Liq. 4 H227 Combustible liquid.
Eye Irrit. 2B H320 Causes eye irritation.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictogramsVoid
Signal wordWarning
Hazard statements
Combustible liquid.
Causes eye irritation.
Precautionary statements
Keep away from flames and hot surfaces. No smoking.
Wear protective gloves / eye protection / face protection.
Wash thoroughly after handling.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention.
In case of fire: Use for extinction: CO2, powder or water spray.
Store in a well-ventilated place. Keep cool.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
1
1
1
Health = 1
Fire = 1
Reactivity = 1
(Contd. on page 2)
USA

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Safety Data Sheet
acc. to OSHA HCS
Printing Date 01/10/2017 Revision Date 01/10/2017Revision Number 2
Trade name: MP55220, MP55320, MP55420 Part B (Activator)
(Contd. of page 1)
44.0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
PHYSICAL HAZARD
1
1
1
Health = 1
Fire = 1
Physical Hazard = 1
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
* 3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture
Hazardous components:
94-36-0 dibenzoyl peroxide 5-20%
* 4 First-aid measures
Description of first aid measures
After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:
Rinse opened eye for 20 minutes under running water. If eye becomes irritated, obtain medical treatment.
After swallowing:
Rinse mouth with water.
Do not induce vomiting; immediately call for medical help.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
* 5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fire with alcohol resistant foam.
Use fire fighting measures that suit the environment.
Special hazards arising from the substance or mixtureNo further relevant information available.
Advice for firefighters
Firefighters use standard protective equipment including flame retardant coat, helmet with face shield, gloves,
rubber boots, and in enclosed spaces, SCBA.
Protective equipment:Protective clothing and respiratory protective device.
USA
(Contd. on page 3)

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Safety Data Sheet
acc. to OSHA HCS
Printing Date 01/10/2017 Revision Date 01/10/2017Revision Number 2
Trade name: MP55220, MP55320, MP55420 Part B (Activator)
(Contd. of page 2)
44.0
* 6 Accidental release measures
Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Environmental precautions:Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of contaminated material as waste in accordance with federal state and local regulations.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
* 7 Handling and storage
Handling:
Precautions for safe handling
Open and handle receptacle with care.
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
Information about protection against explosions and fires:
Keep container closed when not in use.
Keep ignition sources away – Do not smoke.
Prevent impact and friction.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:Store in a cool location away from direct heat.
Information about storage in one common storage facility:Store away from oxidizing agents.
Further information about storage conditions:
Store in cool, dry conditions in well sealed receptacles.
Protect product from freezing.
Protect from heat and direct sunlight.
Specific end use(s)No further relevant information available.
* 8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at
the workplace.
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment (see listings below)
General protective and hygienic measures:
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
(Contd. on page 4)
USA

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Safety Data Sheet
acc. to OSHA HCS
Printing Date 01/10/2017 Revision Date 01/10/2017Revision Number 2
Trade name: MP55220, MP55320, MP55420 Part B (Activator)
(Contd. of page 3)
44.0
Breathing equipment:
Use approved respiratory protection equipment when airborne exposure is excessive. Consult the respirator
manufacturer to determine the appropriate type of equipment for a given application. Observe respirator use
limitations specified by the manufacturer.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Material of gloves
Nitrile rubber, NBR
Neoprene gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Safety glasses with side shields.
Tightly sealed goggles
Body protection:Protective work clothing
* 9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Color: Gray
Odor: Mild
Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point: Undetermined.
Boiling point:
Flash point: 84 C (183 F)
Flammability (solid, gaseous):Not applicable.
Ignition temperature: Not determined
Decomposition temperature: Not determined.
Auto igniting: Product is not selfigniting.
Danger of explosion: Extreme risk of explosion by shock, friction, fire or other sources of
ignition.
Flammable limits:
Lower: Not determined
(Contd. on page 5)
USA

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Safety Data Sheet
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Printing Date 01/10/2017 Revision Date 01/10/2017Revision Number 2
Trade name: MP55220, MP55320, MP55420 Part B (Activator)
(Contd. of page 4)
44.0
Upper: Not determined
Vapor pressure at 20 C (68 F):1 hPa (1 mm Hg)
Specific gravity at 20 C (68 F):1.21 g/cm (10.097 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate <1 Solubility in / Miscibility with Water: Insoluble Partition coefficient (n-octanol/water):Not determined. Viscosity: Dynamic: Not determined. Kinematic: Not determined. Solvent content: Organic solvents: 0.0 % Solids content: Not available Other information No further relevant information available. * 10 Stability and reactivity ReactivityNo further relevant information available. Chemical stability Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications. Possibility of hazardous reactionsNo dangerous reactions known. Conditions to avoid Avoid high temperatures. Avoid freezing. Heat, flames, sparks. Direct sunlight Incompatible materials:Reacts with oxidizing agents. Hazardous decomposition products: Carbon monoxide Carbon dioxide Nitrogen oxides * 11 Toxicological information Information on toxicological effects Acute toxicity: Primary irritant effect: on the skin:May irritate the skin. on the eye:Irritating effect. Sensitization:No sensitizing effects known. Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Irritant (Contd. on page 6) USA Page 6/8 Safety Data Sheet acc. to OSHA HCS Printing Date 01/10/2017 Revision Date 01/10/2017Revision Number 2 Trade name: MP55220, MP55320, MP55420 Part B (Activator) (Contd. of page 5) 44.0 Carcinogenic categories IARC (International Agency for Research on Cancer) 94-36-0 dibenzoyl peroxide 3 NTP (National Toxicology Program) None of the ingredients is listed. OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. * 12 Ecological information Toxicity Aquatic toxicity:No further relevant information available. Persistence and degradabilityNo further relevant information available. Behavior in environmental systems: Bioaccumulative potentialNo further relevant information available. Mobility in soilNo further relevant information available. Additional ecological information: General notes:At present there are no ecotoxicological assessments. Results of PBT and vPvB assessment PBT:Not applicable. vPvB:Not applicable. Other adverse effectsNo further relevant information available. * 13 Disposal considerations Waste treatment methods Recommendation:Must be specially treated adhering to official regulations. Uncleaned packagings: Recommendation:Disposal must be made according to official regulations. * 14 Transport information UN-Number DOT, ADN, IMDG, IATA not regulated UN proper shipping name DOT, ADN, IMDG, IATA not regulated Transport hazard class(es) DOT, ADN, IMDG, IATA Class not regulated Packing group DOT, IMDG, IATA not regulated Environmental hazards: Not applicable. Special precautions for user Not applicable. (Contd. on page 7) USA Page 7/8 Safety Data Sheet acc. to OSHA HCS Printing Date 01/10/2017 Revision Date 01/10/2017Revision Number 2 Trade name: MP55220, MP55320, MP55420 Part B (Activator) (Contd. of page 6) 44.0 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. Transport/Additional information:Limited Quantities are allowed. Refer to 49 CFR for conditions that apply. UN "Model Regulation": not regulated * 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Sara Section 355 (extremely hazardous substances): None of the ingredients is listed. Section 313 (Specific toxic chemical listings): All ingredients are listed. TSCA (Toxic Substances Control Act): All components of this product are on the TSCA Inventory or are exempt from TSCA Inventory requirements. Proposition 65 Chemicals known to cause cancer: None of the ingredients is listed. Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. Chemicals known to cause developmental toxicity: None of the ingredients is listed. (DSL) Canada Dosmestic Substance List All components of this product are on the DSL(Canada Domestic Substance list) or are exempt from DSL requirements. New Jersey Right-to-Know List: All ingredients are listed. New Jersey Special Hazardous Substance List: 94-36-0 dibenzoyl peroxide F4, R4 Pennsylvania Right-to-Know List: All ingredients are listed. Pennsylvania Special Hazardous Substance List: 94-36-0 dibenzoyl peroxide E Cancerogenity categories EPA (Environmental Protection Agency) None of the ingredients is listed. TLV (Threshold Limit Value established by ACGIH) 94-36-0 dibenzoyl peroxide A4 (Contd. on page 8) USA Page 8/8 Safety Data Sheet acc. to OSHA HCS Printing Date 01/10/2017 Revision Date 01/10/2017Revision Number 2 Trade name: MP55220, MP55320, MP55420 Part B (Activator) (Contd. of page 7) 44.0 MAK (German Maximum Workplace Concentration) None of the ingredients is listed. NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. National regulations: Water hazard class:Water hazard class 1 (Self-assessment): slightly hazardous for water. Chemical safety assessment:A Chemical Safety Assessment has not been carried out. * 16 Other information Although the information and recommendations set forth in this SDS are presented in good faith and are believed to be correct as of the date of this SDS, Royal Adhesives & Sealants makes no representations as to the completeness or accuracy thereof. Information is supplied on the condition that the persons receiving and using it will make their own determination as to the suitability for their purpose prior to use. In no event will Royal Adhesives & Sealants or any affiliate thereof be responsible for damages of any nature whatsoever resulting from the use or reliance on the information set forth in the SDS. Department issuing SDS:Environment protection department. Creation Date:01/10/2017 Date of preparation / last revision01/10/2017 / 1 Abbreviations and acronyms: IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative NIOSH: National Institute for Occupational Safety OSHA: Occupational Safety & Health TLV: Threshold Limit Value PEL: Permissible Exposure Limit REL: Recommended Exposure Limit Flam. Liq. 4: Flammable liquids Category 4 Eye Irrit. 2B: Serious eye damage/eye irritation Category 2B USA