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3MrM Scotch-WeldrM Concrete Repair DP600 Grav and Concrete Repair 600 Grav. Part A 04127121
Safety Data Sheet
Copyright,2O2l, 3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (l) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document Group:
Issue Date:
I 8-0894-8
04127121
Version Number:
Supercedes Date:
12.03
12102120
SECTION 1: Identification
1.1. Product identifier
3MrM Scotch-WeldrM Concrete Repair DP600 Gray and Concrete Repair 600 Gray, Part A
Product Identification Numbers
62-2749-8535-7
7010130543
1.2. Recommended use and restrictions on use
Recommended use
Two-part urethane adhesive/sealant., Structural adhesive
This chemical/product is not and cannot be distributed in commerce (as defined in TSCA section 3(13)) for consumer paint or
coating removal
1.3. Supplier’s details
MANUFACTURER:
DIVISION:
ADDRESS:
Telephone:
1.4. Emergency telephone number
l-800-364-3577 or (651)737-6501 (24 hours)
3M
Industrial Adhesives and Tapes Division
3M Center, St. Paul, MN 55144-1000, USA
1 -888-3M HELPS ( l -888-364-3s77)
SECTION 2: Hazard identification
2.1. Hazar d classifi cation
Serious Eye Damage/Irritation: Category 24.
Skin Corrosion/Initation: Category 2.
Respiratory Sensitizer: Category 1.
Skin Sensitizer: Category l.
Specific Target Organ Toxicity (single exposure): Category 3.
Specific Target Organ Toxicity (repeated exposure): Category I
2.2.Label elements
Signal word
Danger
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3MrM Scotch-Weldrrli Concrete Repair DP600 Gray and Concrete Repair 600 Grav. Part A 04127121
Symbols
Exclamation mark I Health Hazard
I
Pictograms
Hazard Statements
Causes serious eye irritation.
Causes skin irritation.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause an allergic skin reaction.
May cause respiratory irritation.
Causes damage to organs through prolonged or repeated exposure:
respiratory system
I
Precautionary Statements
Prevention:
Do not breathe dust/fume/gas/mist/vapors/spray.
Use only outdoors or in a well-ventilated area.
In case of inadequate ventilation wear respiratory protection.
Wear protective gloves and eye/face protection.
Do not eat, drink or smoke when using this product.
Wash thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.
Response:
IF INHALED: Remove person to fresh air and keep comforlable for breathing.
If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do
Continue rinsing.
If eye irritation persists: Get medical advice/attention.
IF ON SKIN: Wash with plenty of soap and water.
If skin irritation or rash occurs: Get medical advice/attention.
Take off contaminated clothing and wash it before reuse.
Get medical advice/attention if you feel unwell.
Storage:
Keep container tightly closed.
Store locked up in a well-ventilated place.
Disposal:
Dispose of contents/container in accordancs with applicable local/regional/national/international regulations.
Supplemental Information:
Persons previously sensitized to isocyanates rnay develop a cross-sensitization reaction to other isocyanates.
;
I
SECTION 3: Composition/information on ingredients
Ingredient C.A.S. No. wr
o/
/o
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Page 2 of 12
3Ml
Nr
Scotch_WeldrNr Concrete r DP600 and Concrete 600 Part A 04/27t21
4,4′-diphenyllnethane diisocyanate I 0 I -68-8 35 – 53 Trade Secret
*
diphenylmethanediisocyanate prepolymer 68424-09-9 15 – 40 Trade Secret
*
poly(diphenylmethane-4,4′-diisocyanate) 2s686-28-6 25 – 40 Tracle Secret
*
arnorphous silica 6′,7’762-90-1 I – 5 Trade Secret
*
Methylene Chloride t5-09-2 < 0.01 Trade Secret
*
*The
specific cl.ren.rical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation:
Remove person to firesh air. If you feel unwell, get medical attention.
Skin Contact:
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get
medical attention.
Eye Contact:
Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention.
lf Srvallowed:
Rinse mouth. [f you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
lrritating to the respiratory tract (coughing, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain). Allergic respiratory
reacrion (difficulty breathing, wheezing, cough, and tightness ofchest). Allergic skin reaction (redness, swelling, blistering, and itching).
Target organ effects following prolonged or repeated exposure. See Section I I for additional details.
4,3. lndication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-tinmeasures
5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.
5.2. Special hazards arising from the substance or mixture
None inherent in this product.
llazardous Decomposition or By-Products
Substance
Carbon monoxide
Carbon dioxide
Hydrogen Cyanide
Oxides of Nitrogen
Toxic Vapor, Gas, Particulate
Condition
During Combustion
During Combustion
During Combustion
During Combustion
During Combustion
5.3. Special protective actions for fire-fighters
Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus,
bunkcr coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas ofthe head.
SECTION 6: Accidental release measures
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3MTiu Scotch_weldTNr concrete Rr DP600 and Concrete 600 G Part A 04tz't/21
6.1. Pcrsonal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation
to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Refer to other sections of this SDS for
infonnation regarding physical and health hazards, respiratory protection, ventilation, and personal protective equiprnent.
6.2. Environmental precautions
Avoid rcleasc to thc environrncnt.
bodies of water.
For larger spills, cover drains and build dikes to prevent entry into sewer systems or
6.3. Methods and material for containment and cleaning up
Contain spill. Pour isocyanate decontaminant solution (90Yowater,80/o concentrated ammoni a,2o/o detergent) on spill and
allow to leact for 10 minutes. Or pour water on spill and allow to react for more than 30 minutes. Cover with absorbent
material. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available
inorganic absorbent rrraterial. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material
does not rcmove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a
container approved for transporlation by appropriate authorities, but do not seal the container for 48 hours to avoid pressure
build-r.rp. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area
with fresh air. Read and follow safety precautions on the solvent label and SDS. Dispose of collected material as soon as
possible in accordance with applicable local/regional/national/international regulations.
SECTION 7: H and stor
7.1. Precautions for safe handling
For industrial/occupational use only. Not for consumer sale or use. Do not breathe dust/fume/gas/mist/vapors/spray.
not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after
handling. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment.
Wash contaminated clothing before reuse.
Do
7.2. Conditions for safe storage including any incompatibilities
Store in a well-ventilated place. Keep container tightly closed to prevent contamination with water or air
is suspected, do not reseal container. Store away from acids. Store away from strong bases.
If contamination
SECTION 8: osure co nal on
8.1. Control parameters
Occupational exposure limits
If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the
ACGIH : Anrerican Conference of Governmental lndustrial Hygienists
AIHA : Arnerican lndustrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Guidelines
Ingredient C.A.S. No.Agencv Limit fype Additional Comments
4,4'-diphenylmethane
diisocyanate
1 0 I -68-8ACGIH TWA:0.005 ppm
4,4'-diphenyImethane
diisocyanate
I 0 l -68-8OSHA CEIL:0.2 mg/m3(0.02 ppm)
SILICA, AMORPHOUS 67762-90-7OSHA TWA:20 millions of
particles/cu. ft.;TWA
concentration:0. 8 melm3
Methylene Chloride 75-09-2 ACGIH TWA:50 ppm ,A.3: Confirmed animal
carctn.
Methylene Chloride 7s-09-2 OSHA TWA:25 ppm;STEL: I 25 ppm29 CFR 1910.1052,
SKIN
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3Mr.Nr Scotch_WeldTNr Concrctc air l)l'600 G and Concrete r 600 Part A 04t27 t21
OSLIA : Unitetl States Departnrcnt ol'Latror - Occupational Safety and l-lealth Administration
TWA: Tirne-Weighted-Average
STEL: Short'l'erm Exposr.rre Lirnit
CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airbome exposures to below relevant Exposure
Limits and/or control dust/ftuneigas/n-rist/vapols/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equiprnent (PPE)
Eye/face protection
Select and use eye/face protcction to prevent contact based on the results ofan exposure assessment. The following eye/face
protection(s) are recommended:
Indirect Vented Goggles
Skin/hand protection
Select and use gloves and/or protcctive clothing approved to relevant local standards to prevent skin contact based on the
results ofan exposure assessment. Selection should be based on use factors such as exposure levels, concentration ofthe
snbstance or mixture, frequency and duration, physical challenges such as temperafure extremes, and other use conditions
Consult with your glove and/or protective clothing manufacfurer for selection of appropriate compatible gloves/protective
clothing.
Gloves made from the following material(s) are recommended: Neoprene
Nitrile Rubber
If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then
use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an
exposure assessment. The following protective clothing material(s) are recommended: Apron - Neoprene
Apron -
Nitrile
Respiratory protection
An exposure assessment may be needcd to decide if a respirator is required. If a respirator is needed, use respirators as part
of a full respiratory protection program. Based on the results of the exposure assessment, select from the following
respirator type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates
For questions about suitability for a specific application, consult with your respirator manufacturer
SECTION 9: Phvsical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance
Physical state
Color
Specific Physical Form:
Odor
Odor threshold
pH
Melting point
Boiling Point
Flash Point
Liquid
Milky White
Viscous
Low Odor
No Data Available
Not Applicable
No Data Available
>:400’F
>:290
oF
fTest Method:Tagliabue Closed Cupl
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3MTM Scotch-Weldlrlt Concrete Repair DP600 Gray and Concrete Repair 600 Gray, Part A 04127121
Evaporation rate
Flammability (solid, gas)
Flammable Limits(LEL)
Flammable Limits(UEL)
Vapor Pressure
Vapor Density
Density
Specific Gravity
Solubility in Water
Solubility- non-water
Partition coefficient: n-octanol/ water
Autoignition temperature
Decomposition temperature
Viscosity
Hazardous Air Pollutants
Molecular weight
VOC Less H2O & Exempt Solvents
10.6. Hazardous decomposition products
Substance
None known.
<:1
lDetails:Gels with exposure to hurnidity.]
Not Applicable
Not Applicable
Not Applicable
<:0.000004 mmHg [@ 68'F]
>:l
[Rel.trdjAlR:l]
1.l l g/ml
1.1I lRef Std:WATER:Il
Negligible
No Data Available
No Data Available
Not Applicable
No Data Available
1,250 – 2,750 centipoise
< 60
o
weight
[Test Method.'Calculated]
No Data Available
0 gll
lTest Method:calculated SCAQMD rule 443.11
lDetails:when used as intended with Part B]
0
o/o
fTest Method:calculated SCAQMD rule 443.1]
lDetails:when used as intended with Part B]
0 gll[Test Method:calculated SCAQMD rule 443.1] lDetails:as
suppliedl
Condition
VOC Less H2O & Exempt Solvents
VOC Less H2O & Exempt Solvents
SECTION L0: Stabilitv and reactivity
10.1. Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section.
I 0.2. Chemical stability
Stable.
10.3. Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4. Conditions to avoid
Heat is generated during cure. Do not cure a mass larger than 50 grams in a confined space to prevent a premature exothermic
reaction with production of intense heat and smoke.
10.5. Incompatible materials
Water
Strong acids
Strong bases
Refer to section 5.2 for hazardous decomposition products during combustion.
SECTION 1,1: Toxicolosical information
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may tre
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3MTM Scotch_Weld',rilr Concrete DP6()O nnd Concrete r 600 GraPart A 04t27t21
present below the threshold for labeling, an ingredient lnay not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1. Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.
Allergic Respiratory Reaction: Signs/symptoms may inch-rde difficulty breathing, wheezing, cough, and tightness of chest.
May cause additional health effects (see below).
Skin Contact:
Skin lrritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain.
Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.
Eye Contact:
Severe Eye Initation: Signs/symptoms may include significant reciness, swelling, pain, tearing, cloudy appearance of the
cornea, and impaired vision.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and dianhea.
Additional Health Effects:
Prolonged or repeated exposure may cause target organ c'lTects:
Respiratory Effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart
rate, bluish colored skin (cyanosis), sputum production, changes in lung finction tests, and/or respiratory failure.
Carcinogenicity:
Additional Information :
Persons previously sensitized to isocyanates may develop a cross-sensitization reaction to other isocyanates.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute
Inqredient CAS No. Class Description Regulation
Methvlene Chloride 7s-09-2 Grp. 2,A: Probable human carc. International Asencv for Research on Cancer
Methylene Chloride 75-09-2 Anticinated humarr carcinoqen National Toxicolosv Prosram Carcinosens
Methylene Chloride 75-09-2 Cancer hazard OSHA Carcinosens
Name Route Snecies Value
Overall product lnhalation-
Vaoor(4 hr)
No data available; calculated ATE >50 mg/l
Overall product lngestion No data available; calculated ATE >5,000 mg/kg
4.4′-diohenvlmethane diisocvanate Dermal Rabbil LD50 > 5.000 me/ks
4,4′-diphenylmethane di isocyanate Inhalation-
Dust/Mist
(4 hours)
Rat LC50 0.368 mg/l
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3M’f
nt
Scotch-WeldlM Concrete Repair DP600 Gray and Concrete Repair 600 Gray, Part A 04127/21
4.4′-diohenvlnrethane diisocvanate Insestion Rat LD50 3 1,600 nre/ke
poly(diphenyhnethane-4,4′-di isocyanate) Dennal Rabbit LD50 > 5.000 rns/kp
poly(diphenyhnethane-4,4′-diisocyanate) lnhalation-
Dust/Mist
(4 hours)
Rat LC50 0.368 rng/l
polv(diphenvlmethane-4.4′-diisocvanate) Insestion Rat LD50 31.600 rns/ks
amorphous silica Dennal Rabbit LD50 > 5.000 ms/ks
amorphous silica Inhalation-
Dust/Mist
(4 hours)
Rat LC50 > 0.691 mg/l
amomhous silica Inseslion Rat LD50 > 5.1l0 ms/ks
Methylene Chloride Dennal Rat LD50 > 2,000 ms/ks
Methylene Chloride Inhalation-
Vapor (4
hours)
Rat LC50 63.7 mg/l
Methvlene Chloride lngestion Rat LD50 1.410 ms/ke
ATE: acute toxicity estimate
Skin Corrosionilrritation
Serious
Skin Sensitization
Sensitization
Name Species Value
4,4′-diphenylmethane diisocyanate official
classifica
tion
lrritant
poly(diphenylmethane-4,4′-diisocyanate) official
classifica
tion
Irritant
arnomhous silica Rabhit No signifi cant initation
Methylene Chloride Rabbit lnitant
Name Species Value
4,4′-diphenylmethane diisocyanate official
classifica
tion
Severe initant
poly(diphenylmethane-4,4′-diisocyanate) official
classifica
tion
Severe irritant
amorphous silica Rabbit No sisnifi cant initation
Methvlene Chloride Rabbit Severe irritant
Name Soecies Value
4,4′-diphenylmethane diisocyanate official
classifica
tion
Sensitizing
poly(diphenylmethane-4,4′-diisocyanate) official
classifica
tion
Sensitizing
amorphous silica FIuman
and
animal
Not classified
Name Species Value
4.4′-dinhenvlmethane diisocvanate Human Sensitizing
poly(diphenylmelhane-4,4′-diisocyanate) Human Sensitizine
Germ Cell
Name Route Value
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3MrM Scotch-WeldTrlr Concrete Repair DP600 Grav and Concrete Repair 600 Gray, Part A 0412’ll2l
4,4′-diphenylmethane diisocyanate ln Vitro Some positive data cxisl, but the data are not
sufJlcierrt for classi lication
poly(diphenylmethane-4,4′-diisocyanate) In Vitro Some positive data exist, bu1 the data are not
sulfi cient lor classifi cation
amomhous silica ln Vitro Not mutasenic
Methvlene Chloride ln vivo Not rrutagenic
Methylene Chloride In Vitro Sorne positive data exist, but the data are not
suffi cient lbr classiilcation
Carcino
Name Route Snecies Value
4,4′-diphenyhrethane di isocyanate InhalationRat Sorne positive data exist, but the data are not
suffi cient for classifi cation
poly(diphenyhnethane-4,4′-di isocyanate) InhalationRat Some positive data exist, but the data are not
suffi cient for classiflcation
arnorphous silica Not
Specified
Mouse Sorne positive data exist, but the data are not
sulfi cient for classifi cation
Methylene Chloride InhalationMultiple
animal
species
Carcinogenic
Reproductive Toxicity
roductive and/or Effects
Target Organ(s)
T T
Name Route Value Species
‘I’cst
Result Exposure
Duration
4,4′-diphenylmethane diisocyanate lnhalationNot classified for development Rat NOAEL O.OO4
mg/l
during
organogenesi
s
poly(diphenylmethane-4,4’-diisocyanate) InhalationNot classified for development Rat NOAEL O.OO4
mg/l
during
organogenesi
s
amorphous silica IngestionNot classified for female reproduction Rat NOAEL 509
ms/ks/dav
I generation
amorphous silica IngestionNot classified for male reproduction Rat NOAEL 497
ms/ks/dav
I generation
amorphous silica IngestionNot classified for development Rat NOAEL I,350
mg/kg/day
during
organogenesl
Methylene Chloride InhalationNot classified lor female reproduction Rat NOAEL 5.2
mr./l
2 generation
Methylene Chloride InhalationNot classified for male reproduction Rat NOAEL 5.2
ms/l
2 generation
Methylene Chloride InhalationNot classified for development Multiple
animal
species
NOAEL 4.3
mg/l
during
gestation
Name Route Target Organ(s) Value Species
‘l’est
Result Exposure
Duration
4,4′-diphenylmethane
diisocyanate
Inhalationrespiratory irritationMay cause respiratory irritationolficial
classifica
tion
NOAEL Not
available
May cause respiratory irritationpoly(diphenylm ethane-4,4′ –
diisocyanate)
Inhalationrespiratory irritation ofhcial
classifica
tion
NOAEL Not
available
Methylene Chloride Dermal blood Some positive data exist, but the
data are not sufficient lor
classification
Rat NOAEL Not
available
4 hours
Methylene Chloride Inhalationcentral nervous
svstem deoression
May cause drowsiness or
dizziness
Human NOAEL Not
available
occupational
exDosure
Methylene Chloride Inhalationblood Some positive data exist, but the
data are not sufficient for
Human NOAEL Not
available
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3NlIm Scotch-WeldTrn Concrete Repair DI’600 Gray and Concrete Repair 600 Gray, Part A 04127121
classification
Methylene Chloride lnhalationrespiratory irritationSorne positive data exist, but thc
data are not sufficient for
classification
NOAEL Not
availab le
ecific T n
Aspiration Hazard
For the component/components, either no data are currently available or the data are not sufficient for classification
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
SECTION 12: Ecolosical information
Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.
SECTION 13: Disposal considerations
13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.
Dispose of completely cured (or polymerized) material in a permitted industrial waste facility. As a disposal alternative,
Species Exposure
Duration
Name Route Target Organ(s) Value Test Result
4,4′-diphenylmethane
diisocvanate
lnhalationresplratory system Causes damage to organs through
nrolonged ol lepeated exDosure
Rat I-OAI]I,
0.004 rnsil
I 3 rveeks
poly(diphenylmethane-
4.4′-di isocvanate)
Inhalationresplratory system Causes damage to organs through
nrolonsed or reoeated exoosure
Rat LOAEL
0.004 rnq/l
l3 weeks
Inhalationrespiratory system
I
si I icos is
Not classified Human NOAEI- Not
available
occupational
exDosure
amorphous silica
Methylene Chloride Inhalationkidney and/or
bladder
Some positive data exist, but the
data are not sufficient for
classification
Rat LOAEL 6.95
rrg/l
2 years
Methylene Chloride lnhalationliver Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL O. I 7
mg/l
2 years
Methylene Chloride Inhalationresplratory system Some positive data exist, but the
data are not sufficient for
classification
Multiple
animal
species
LOAEL 35
mgll
8 weeks
Methylene Chloride Inhalationheart Not classified Human NOAEL Not
available
Methylene Chloride Inhalationlmmune system Not classified Rat NOAEL I8
ms/l
28 days
Some positive data exist, but the
data are not sufficient for
classification
Rat
1,200
LOAEL
mp/ks/dav
3 rnonthsMethylene Chloride Ingestionliver
Not classified Rat NOAEL 249
mp/ks/dav
2 yearsMethylene Chloride Ingestion blood
Methylene Chloride lngestion kidney and/or
bladder
Not classified Rat NOAEL
t,469
mp/ks/dav
3 months
Methylene Chloride lngestion eyes Not classified Rat NOAEL 249
ms/ks/dav
I 04 weeks
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3M1’M Scotch-WeldTlt Concrete Repair DP600 Gray and Concrete Renair 600 Grav. Part A 04127121
incinerate urlcured product in a permitted waste incineration faciliry. Proper destruction may require the use of additional fuel
during incineration processes. Empty drums/barrels/containers used for transporting and handling hazardous chemicals
(chernical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered,
stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the
respective regulating authorities to determine the available treatment and disposal facilities.
EPA Hazardous Waste Number (RCRA): Not regulated
SECTION 14: Transport Information
For Transport Information, please visit http://3M.com/Transportinfo or call l-800-364-3577 or 651-137-6501
SECTION 15: Regulatorv information
f5.1. US Federal Regulations
Contact 3M for more information.
EPCRA 3lll3l2 Hazard Classifications:
Physical llazards
ot applicable
flealth Hazards
Respiratory or Skin Sensitization
Serious eye damage or eye irritation
Skin Corrosion or lrritation
Specific target organ toxicity (single or repeated exposure)
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
This material contains a chemical which requires export notification under TSCA Section 12[b]:
Ingredient
4,4’-diphenylmethane diisocyanate
Insredient (Catesory if applicable)
Methylene Chloride
C.A.S. No %o bv Wt
101-68-8 Trade Secret 35 – 53
C.A.S. No
7s-09-2
Reeulation
Toxic Substances Control Act (TSCA) 6
Banned or Restricted Use Chemicals
Status
Applicable
Additional TSCA Information
15.2. State Regulations
Contact 3M lor more information
15.3. Chemical Inventories
The components of this product are in compliance with the chemical notification requirements of TSCA. All required
components of this product are listed on the active portion of the TSCA Inventory.
Comnonents CAS No Additional Information
Methylene Chloride 75-09-2 This chemical/product is not and cannot be distributed in
commerce (as defined in TSCA section 3(5)) or processed (as
defined in TSCA section 3(13)) for consumer paint or coating
removal.
pg 27 4 of 444-PPrint5825829.pdf–40591921 2–267 13378
Page l1 of 12
3MrM Scotch-WeldrM Concrete Repair DP600 Grav and Concrete Repair 600 Grav. Part A 04/27t21
Contact 3M for more information.
15.4. International Regulations
Contact 3M for more information.
This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: Other information
NFPA Hazard Classification
Health: 2 Flammability: I Instability: I Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies, Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
Document Group:
Issue Date:
I 8-0894-8
04127121
Version Number:
Supercedes Date:
12.03
t2/02120
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be corect as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user’s method of use or application. Given the variefy of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user’s knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user’s method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M.
3M USA SDSs are available at www.3M.com
pg 27 5 of 444-PPrint5825829.pdt–405919212–267 13378
Page 12 of 12
gl,l
3M’tM Scotch-Weld’Iirr Concrete llepair DP600 Gray and Concrete llepair 600 Gray, Part B 04/L9/2t
Safety Data Sheet
Copyright,202l, 3M Company.
All rights reserued. Copying and/or downloading of this informatior.r for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of eaming a profit thereon
Document Group:
Issue Date:
18-0901-1
04119/21
Version Number:
,Sipercedes Date:
10.04
12111120
SECTION 1: Identification
1.1. Product identifier
3MrM Scotch-WeldrM Concrete Repair DP600 Gray and Concrete Repair 600 Gray, Parl B
Product Identifi cation Numbers
62-2649-8535-9
70t0110293
1.2. Recommended use and restrictions on use
Recommended use
Two-pafi urethane adhesive/sealant., Structural adhesive
1.3. Supplier’s details
MANUFACTURER:
DIVISION:
ADDRESS:
Telephone:
1.4. Emergency telephone number
l-800-364-3577 or (651) 137-6501 (24 hours)
3M
Industrial Adhesives and Tapes Division
3M Center, St. Paul, MN 55144- 1000, USA
1 -888-3M HELPS (1 -888-364-3 577)
SECTION 2: Hazard identification
2.1. Hazar d classifi cation
Serious Eye Damage/Irritation: Category 2A.
Skin Sensitizer: Category 1A.
2.2.Label elements
Signal word
Warning
Symbols
Exclamation mark
I
Pictograms
pg 252 ol 444-PPrint5825829.pdt–40591921 2-267 1 3378
Page I of 12
I
t
3MrM Scotch-WeldTM Concrete ir DP600 G and Concrete 600 Part B 04n9121
Hazard Statements
Causes serious eye irritation.
May cause an allergic skin reaction
Precautionary Statements
Prevention:
Avoid breathing dust/fume/gas/mi st/vapors/spray.
Wear protective gloves and eye/face protection.
Wash thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace
Response:
IF IN EYES: Rinse cautiously with water for several minutes.
Continue rinsing.
If eye initation persists: Get medical advice/attention.
IF ON SKIN: Wash with plenry of soap and water.
If skin irritation or rash occurs: Get medical advice/attention.
Wash contaminated clothing before reuse.
Remove contact lenses, if present and easy to do.
Disposal:
Dispose of contents/container in accordance with applicable local/regional/national/international regulations.
Supplemental Information :
Persons previously sensitized to amines may develop a cross-sensitization reaction to ceftain other amines.
SECTION 3: Comosition/information on in ts
Ingredient C.A.S. No. %o bv Wt
Polyether Polyol 9082-00-2 40 – 70 Trade Secret
*
Proooxvlated Trimethylolpropane 2s123-16-4 l0 – 30 Trade Secret
*
Tetrakis(2-hvdroxypropyl) ethylened iamine 102-60-3 l0 – 30 Trade Secret
*
Amorphous Silica 6861r-44-9 I – 5 Trade Secret
*
Bis( 1.2.2,6.6-pentamethyl-4-piperidinyl) sebacate 82919-37-1 < I Trade Secret
*
Polvmeric Benzotriazole l 048 l 0-48-2 < I Trade Secret
*
Po lvmeri c B enzotriazole lI l 048 1 0-47-1 < I Trade Secret
*
Substituted Pioervdinvl Sebcate 4t556-26-l < I Trade Secret
*
m-Xvlene-.alpha.alpha'. -diamine 1477-55-0 <: 0.5 Trade Secret
*
N,N'-Ethylenebis- I 2-Hydroxystearamide 123-26-2 <:0.5 Trade Secret
*
Titanium Dioxide 13463-6'7 -',| <: 0.5 Trade Secret
*
*The
specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.
SECTION 4: First aid measures
4.1. Description of first aid measures
pg 253 of 444-P Print5825829.pdf--4O5919212--267 13378
Page 2 of 12
3Nfln scotch-Weldlrlr Concrete Repair DP600 Grav and Concrete Renair 600 Grav. Part B o4/l9tzl
I nhalation:
Rcmovc person to flesh air. If you feel unwell, get medical attention
Skin Contact:
Immediately wash'"vith soap and water. Remove contaminated clothing and wash before reuse. lf signs/symptoms develop, get
medical attention.
Eye Contact:
lmrnediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get nredical attention
lf Swallowed:
Rinse rnouth. If you leel unwell, get medical attention.
4,2. Most important symptoms and effects, both acute and delayed
Allergic skin rcaction (redness, swelling, blistering, and itching).
4.3. lndication of any immediate medical attention and special treatment required
Not applicable
SBCTION 5: Fire-fighting measures
5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.
5.2. Special hazards arising from the substance or mixture
None inherent in this product.
Hazardous Decomposition or By-Products
Substance
Aldehydes
Carbon monoxide
Carbon dioxide
Hydrogen Chloride
Oxides ofNitrogen
Condition
During Combustion
During Combustion
During Combustion
During Combustion
During Combustion
5.3. Special protective actions for fire-fighters
Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus,
bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas ofthe head.
StrCTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation
to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Refer to other sections of this SDS for
information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions
Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or
bodies of water.
6.3. Methods and material for containment and cleaning up
Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially
available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent
rnaterial does not remove a physical, health, or environmentalhazard. Collect as much of the spilled material as possible.
Place in a closed container approved for transportation by appropriate authorities. Clean up residue with an appropriate
solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions
pg 254 ol 444-P Print5B25B29.pdf--405919212--267 13378
Page 3 of 12
3MTi Scotch_WeldTNr concrete r DP600 G and Concrete 600 G Part I] 04n9t27
on the solvent label and SDS. Seal the contaiuer. Dispose of collected material as soon as possible in accordance with
applicable local/rcgional/national/international regulations.
SECTION 7: Handlinand stora
7.1. Precautions for safe handling
For industrial/occupational use only. Not for consumer sale or use. Avoid breathing dust/fume/gas/mist/vapors/spray.
Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after
handling. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment.
Wash contaminated clothing before reuse. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.)
7.2. Conditions for safe storage including any incompatibilities
Store away from acids. Store away from oxidizing agents.
SECTION 8: osure controlsonal
8.1. Control parameters
Occupational exposure limits
If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the
ACGIH : American Conference of Governmental IndustrialHygienists
AIHA : American lndustrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Cuidelines
OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limiis and/or control dust/ftime/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results ofan exposure assessment. The following eye/face
protection(s) are rccommended:
Indirect Vented Goggles
Skin/hand protection
Select and tise gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results ofan exposure asscssment. Selection should be based on use factors such as exposure levels, concentration ofthe
substance o, -i*tnr",
frequency and duration, physical challenges such as temperature extremes, and other use conditions
Ingredient C.A.S. NoAsencv Limit tvpe Additional Comments
Titanium Dioxide 13463-61-7ACGIH TWA:10 mglm3 A.4: Not class. as human
carcln
Titanium Dioxide 13463-67-1OSHA TWA(as total dust):15 ms/m3
m-Xylene-.alpha.alpha'.-diamine| 411-55-0ACGIH CEIL:O.018 ppm Danger of cutaneous
absorption
SILICA, AMORPHOUS 68611-44-9OSHA TWA:20 millions of
particles/cu. ft.;TWA
concentration:0.8 mg/m3
pg 255 oI 444-PPrint5B25829.pdf--40591 921 2--267 1 337 B
Page 4 of 12
3Mr'Nr Scotch-WeldTNr Concrcte ll.epair DP600 Gray nnd Concrcte llepair 600 Gray. Part B 04/79121
Consult with your glove andior protectivc clothing manufacturer for selection of appropriate compatible gloves/protecttve
clothing. Note: Nitrile gloves rnay be wom over polymer laminate gloves to improve dexterity.
Gloves made frorn thc follor,ving n-raterial(s) al'e recolr'lmended: Polymer laminate
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part
of a full respiratory protection program. Based on the results of the exposure assessment, select fi'om the following
respirator type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates
For questions about sr"ritability for a specific application, consult with your respirator manufacturer.
SECTION 9: Phvsical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance
Physical state
Color
Specific Physical Form:
Odor
Odor threshold
pH
Melting point
Boiling Point
Flash Point
Evaporation rate
Flammability (solid, gas)
Flammable Limits(LEL)
Flammable Limits(UEL)
Vapor Pressure
Vapor Density
Density
Specific Gravity
Solubility in Water
Solubility- non-water
Partition coefficient: n-octanol/ water
Autoignition temperature
Decomposition temperature
Viscosity
Hazardous Air Pollutants
Molecular weight
VOC Less IJZO & Exempt Solvents
Liquid
Gray
Viscous
Slight Ammoniacal
No Data Available
Not Applicable
No Data Available
>:400
oF
>:290
oF
lTest Method:Tagliabue Closed Cupl
<:l
[Ref Std:WATER:l]
Not Applicable
Not Applicable
Not Applicable
Not Applicable
>:l
[RelSrd.AIR:I]
1.04 g/ml
1.04 lRef Std:WATER:ll
Negligible
No Data Available
No Data Available
Not Applicable
No Data Available
3,200 – 5,600 centipoise
0 % weight fTest Method:Calculatedl
No Data Available
0 gllfTest Method:calculated SCAQMD rule 443.1]
fDetails:when
used as intended with Part A]
0 gllfTest Method:calculated SCAQMD rule 443.1] lDetails:as
suppliedl
0
o/o
fTest Method:calculated SCAQMD rule 443.1]
lDetails:when used as intended with Part A]
VOC Less H2O & Exempt Solvents
VOC Less H2O & Exempt Solvents
SECTION l0: Stabilitv and reactivitv
10.1. Reactivity
This material may be reactive with certain agents under certain conditions – see the remaining headings in this section.
pg 256 ol 444
-PPrint5825829.pdl–40591
921 2 –267 1 337 B
Page 5 of 12
3MTrv Scotch_Weld
I M
Concrete DP6OO G and Concrete 600 GraPart B 04t19121
10.2. Chemical stability
Stable.
10.3. Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4. Conditions to avoid
None known.
10.5. Incompatible materials
Strong acids
Strong oxidizing agents
10.6. Hazardous decomposition products
Substance
None known.
Condition
Refer to section 5.2 for hazardous decomposition products during combustion.
SECTION 11: T information
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1. Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation:
Respiratory Tract Irritation:
and throat pain.
Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
Skin Contact:
Contact with the skin during product use is not expected to result in significant irritation. Allergic Skin Reaction (non-photo
induced): Signs/symptoms may include redness, swelling, blistering, and itching.
Eye Contact:
Severe Eye lrritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the
cornea, and impaired vision.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
Carcinogenicity:
Additional Information :
Persons previously sensitized to amines may develop a cross-sensitization reaction to certain other amines.
Insredient CAS No. Class l)escrintion Resulation
Titanium Dioxide 13463-67-7 Gm. 28: Possible human carc. lnternational Asencv lor Research on Cancer
pg 257 of 444-PPrints825829.pdf–405919212–267 13378
Page 6 of 12
3MTM Scotch-Weld’rM Concrete Repair DP600 Gray and Concrete Repair 600 Gray, Part B 04lt9t2t
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, eithel no data are available for that endpoint or
the data are not snfficient for classification.
Acute
ATE: acute toxicity estimate
Skin Corrosion/Irritation
Namc Route Species Value
Overall product Derrnal No data available; calculated ATE >5,000 mg/kg
Overall product Ingestion No data available; calculated ATE >5,000 mg/kg
Polyether Polyol Dernral Rabbit LD50 > 5,000 rne/ks
Polyether Polyol lngestion Rat LD50 > 10.000 ms/ks
Propoxvlated Trimethvlolpropane Demral Rat LD50 > 2,000 rne/ks
Proooxvlated Trimethvlolnrooane Ingestion Rat LD50 > 2.500 rns/ks
Tetrakis(2-hydroxypropyl)ethvlenediamine Dennal Rat LD50 > 2,000 me/ks
Tetrakis(2-hvdroxvoronvl)ethvlenediamine lngestion Rat LD50 2.890 rns/ks
Amorphous Silica Dennal Rabbit LD50 > 5,000 me/ks
Amorphous Silica lnhalation-
Dust/Mist
(4 hours)
Rat LC50 > 0.691 mg/l
Amomhous Silica Insestion Rat LD50 > 5.1l0 ms/ks
rn-Xylene-.alpha.alpha’.-diamrne Dermal Rabbit LD50 > 2.000 ms/ks
m-Xylene-.alpha.alpha’.-diamine lnhalation-
Dust/Mist
(4 hours)
Rat LC50 1.2 mgll
m-Xvlene-.alpha.alpha’.-diamrne lneestion Rat LD50 980 me/ke
Substituted Piperydinyl Sebcate Dennal LD50 estimated ro be 2,000 – 5,000 mg/kg
Substituted Pipervdinvl Sebcate Insestion Ral LD50 3.125 ms/ks
Titanium Dioxide Dermal Rabbit LD50 > 10.000 ms/ks
Titanium Dioxide Inhalation-
Dust/Mist
(4 hours)
Rat LC50 > 6.82 mg/l
Titanium Dioxide lngestion Rat LD50 > 10.000 rns/ks
Polymeric Benzotriazole Derrnal Rat LD50 > 2,000 ms/ks
Polymeric Benzotriazole lnhalation-
Dust/Mist
(4 hours)
Rat LC50 > 5.8 mg/l
Polymeric Benzotriazole Insestion Rat LD50 > 5.000 me/ks
Polvmeric Benzotriazole II Demal Rat LD50 > 2.000 mp/ks
Polymeric Benzotriazole II Inhalation-
Dust/Mist
(4 hours)
Rat LC50 > 5.8 mg/l
Polvmeric Benzotriazole ll lngeslion Rat LD50 > 5.000 ms/ks
Bis( 1,2,2,6,6-pentamethyl-4-piperidinyl) sebacate Demal LD50 estimated to be 2,000 – 5,000 mg/kg
Bis( 1,2,2,6,6-pentamethvl-4-piperidinyl) sebacate lnqestion Rat LD50 3,125 me/day
N,N’-Ethylenebis- I 2-Hydroxystearamide Inhalation-
DusVMist
(4 hours)
Rat LC50 > 5.05 mg/l
N,N’-Ethylenebis- I 2-Hvdroxvstearamide lngestion Rat LD50 > 2,000 me/ka
N,N’-Ethylenebis- I 2-Hydroxystearamide Demal similar
health
hazards
LD50 Not available
Name Species Value
Propoxylated Trimethylolpropane Rabbit No sisnifi cant irritation
Tetrakis(2-hydroxypropyl)ethvlenediamine Rabbit No signifi cant irritation
Amorphous Silica Rabbit No sisnifi cant irritation
m-Xylene-.alpha.alpha’.-diamrne Rat Corrosive
Substituted Pioervdinvl Sebcate Rabbit No signifi cant irritation
Titanium Dioxide Rabbit No sisnifi cant irritation
Polymeric Benzotriazole Rabbit No signifi cant irritation
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Page 7 of 12
3MrIlr Scotch-WeldrM Concrete ir DP600 and Concrete 600 Part B 04119121
Polyrneric Benzotriazole Il Rabbit No significant initation
Bis( 1,2,2,6,6-oentarnethyl-4-piperidinvl) sebacate Rabbit No sisnifi cant in’itation
Serious
Skin Sensitization
Respiratory Sensitization
For the component/components, either no data are currently available or the data are not sufficient for classification.
Germ Cell
C
Name Species Value
Propoxylated Trimethylolpropane Rabbit Mild irritant
Tetrakis(2-hydroxypropyl)ethylenediamine Rabbit Severe irritant
Amorphous Silica Rabbit No signifi cant initation
m-Xylene-.alpha.alpha’.-diamine Rabbit Corrosive
Substituted Piperydinyl Sebcale Rabbit No sisnificant initation
Titanium Dioxide Rabbit No siqnificant initation
Polymeric Benzotriazole Rabbit No significant initation
Polymeric Benzotriazole Il Rabbit No signifi cant irritation
Bis( 1,2,2,6,6-pentamethvl-4-piperidinvl) sebacate Rabbit No significant initation
Name Species Value
Tetrakis(2-hydroxypropyl)erhylenediam ine Guinea
Dla
Not classified
Amorphous Silica Human
and
animal
Not classified
m-Xylene-.alpha.alpha’.-diamine Guinea
ois
Sensitizing
Substituted Piperydinyl Sebcate Guinea
Dls
Sensitizing
Titanium Dioxide Human
and
animal
Not classified
Polymeric Benzotriazole Guinea
Dlg
Sensitizing
Polymeric Benzotriazole II Guinea
Drg
Sensitizing
Bis(,2,2,6,6-pentamethyl-4-piperidinyl) sebacate Guinea
Drg
Sensitizing
N,N’-Ethylenebis- I 2-Flydroxystearamide Guinea
plg
Sensitizing
Name Route Value
Tetrakis(2-hydroxypropyl)ethylenediamine ln Vitro Not mutagenic
Amorphous Silica In Vitro Not mutagenic
m-Xylene-.alpha.alpha’.-diamine In Vitro Not mutaAenic
m-Xylene-.alpha.alpha’.-diamine ln vivo Not mutagenic
Substituted Piperydinyl Sebcate In Vitro Not mutagenic
Titanium Dioxide In Vitro Not mutagenic
Titanium Dioxide In vivo Not mutagenic
Polymeric Benzotriazole In Vitro Not mutagenic
Polymeric Benzotriazole In vivo Not mutagenic
Polymeric Benzotriazole II In Vitro Not mutagenic
Polymeric Benzotriazole ll In vivo Not mutagenic
Bis( 1,2,2,6,6-pentamethyl-4-piperidinyl) sebacate In Vitro Not mutagenic
Name Route Species Value
Amorphous Silica Not
Snecified
Mouse Some positive data exist, but the data are not
suffi cient for classifi cation
Titanium Dioxide IngestionMultipleNot carcinogenic
pg 259 ol 444-PPrintSB25829.pdi–4OSS1 921 2–267 1 337 I
Page 8 of 12
3Mrer Scotch-Weld
rM
Concrete air DP600 G and Concrete 600 G Part B 04Jt9t2l
anirnal
sDecies
Titanium Dioxidc lnhalationRat Carcinogenic
Reproductive Toxicity
roductive and/or Effects
Target Organ(s)
T ure
Name Route Value Species Tcst Result Exposure
Duration
Tetrakis(2-hydroxypropyl)ethylenediaminelngestionNot classified for female reproduction Rat NOAEL I,OOO
me/ke/dav
prematlng
into lactation
Tetrakis(2-hydroxypropyl)ethylenediaminelngestionNot classified for male reproduction Rat NOAEL 1,OOO
rns/kp/dav
30 days
Tetrakis(2-hydroxypropyl)ethylenediamineIngestionNot classified for development Rat NOAEL I,OOO
ms/ks/dav
prematrng
into lactation
Amorphous Silica IngestionNot classified for female reproduction Rat NOAEL 509
ms/ks/dav
I generation
Amorphous Silica IngestionNot classified for male reproduction Rat NOAEL 497
rne/ks/day
I generation
Amorphous Silica lngestionNot classified for development Rat NOAEL I,350
nrg/kg/day
during
organogenesi
S
m-Xylene-.alpha.alpha’.-diarnine lngestionNot classified for female reproduction Rat NOAEL 450
ms/kg/day
I generation
m-Xylene-.alpha.alpha’.-diamine IngestionNot classified for male reproduction Rat NOAEL 450
ms/ks
I generation
rn-Xylene-.alpha.alpha’.-diamine IngestionNot classified for development Rat NOAEL 450
n1e/ks./day
I generation
Polymeric Benzotriazole IngestionNot classified for female reproduction Rat NOAEL IOO
me/ke/day
premating
into lactation
Polymeric Benzotriazole IngestionNot classified for male reproduction Rat NOAEL IOO
me/ks/day
I l5 days
Polymeric Benzotriazole IngestionNot classified for development Rat NOAEL 2
me/ks/dav
prgmatlng
into Iactation
Polymeric Benzotriazole ll IngestionNot classified for female reproduction Rat NOAEL IOO
rns/ks/dav
prematlng
into Iactation
Polyrneric Benzotriazole II lngestionNot classified for male reproduction Rat NOAEL IOO
me/ks/day
I 15 days
Polymeric Benzotriazole ll IngestionNot classified for development Rat NOAEL 2
rns/keldav
prematrng
into lactation
Name Route Target Organ(s) Value Specics Test Result Exposure
Duration
Tetrakis(2-
hydroxypropyl)ethylenedia
mine
lnhalationrespiratory irritationSome positive data exist, but the
data are not sufficient for
classification
similar
health
hazards
NOAEL
Positive
m-Xylene-.alpha.alpha’.-
diamine
Inhalationrespiratory initationSome positive data exist, but the
data are not sufficient for
classification
Not
available
NOAEL Not
avaliable
Name Route Target Organ(s) Value Species Test Result Exposure
Duration
Tetrakis(2-
hydroxypropyl)ethylenedia
mine
Ingestionnervous system Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL 3OO
ng/kg/day
30 days
Tetrakis(2-
hydroxypropyl)ethylenedia
mine
lngestionheart
I skin
I
endocrine system
I
gastrointestinal tract
I bone, teeth, nails,
and/or hair
I
hematoooietic
Not classified Rat NOAEL
1,000
ng/kg/day
30 davs
pg 260 ot 444-P Print5B25B29.pdf–405919212–267 13378
Page 9 of 12
3M
t’M
Scotch_Weld’fM concrete ir DP600 and Concrete r600G Part B 04n9/2t
system
I liver
I
immune system
I
muscles
I
eyes
I
kidney and/or
bladder
I respiratory
system I vascular
system
Amorphous Silica Inhalationrespiratory system
I
si licosis
Not classifled Iluman NOAEL Not
available
occupational
exposr.lre
rn-Xylene-.alpha.alpha’
diamine
Ingestionendocrine systern
I
blood
I bone
marrow
Not classified Rat NOAEL 600
mg/kg/day
2tl days
Titanir”un Dioxide Inhalationrespiratory system Some positive data exist, but the
data are not sufficient for
classification
Rat LOAEL O.OI
mg/l
2 years
Titanium Dioxide Inhalationpulmonary fibrosisNot classified Human NOAEL Not
available
occupational
exDosure
Polymeric Benzotriazole Ingestionkidney and/or
bladder
Not classified Rat NOAEL not
available
28 days
Polymeric Benzotriazole Ingestionhematopoietic
svstem
Not classified Rat NOAEL 50
me/ks/dav
90 days
Polymeric Benzotriazole Ingestionliver Not classified Rat NOAEL IO
ms/ks/dav
28 days
Polymeric Benzotriazole Ingestion eyes Not classified Rat NOAEL 5O
ms/ks/dav
90 days
Polymeric Benzotriazole IIlngestionkidney and/or
bladder
Not classified Rat NOAEL not
available
28 days
Polymeric Benzotriazole Illngestionhematopoietic
svstem
Not classified Rat NOAEL 50
ms/ke/dav
90 days
Polymeric Benzotriazole llIngestionliver Not classified Rat NOAEL IO
ms/kp/dav
28 days
Polymeric Benzotriazole IlIngestion eyes Not classified Rat NOAEL 50
ms/ksldav
90 days
Aspiration Hazard
For the component/components, either no data are currently available or the data are not sufficient for classification
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
SECTION 12: Ecoloal information
Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on tlris material
and/or its components.
SECTION 13: considerations
13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations
Dispose of completely cured (or polymerized) material in a permitted industrial waste facility. As a disposal alternative,
incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional fuel
during incineration processes. Combustion products will include halogen acid (HC1/HF/HBr). Facility must be capable of
handling halogenated materials. Empty drums/barrels/containers used for transporting and handling hazardous chemicals
(chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be consider d,
pg 261 ol 444-PPrint5825B29.pdI–4059 1921 2–267 1337 I
Page l0 of l2
3MTnr Scotch_Weld’rM Concrete r DP600 and Concrete 600 G Part B 04119127
stored, treated & disposed of as hazardolls wastes Llnless otherwise defined by applicable waste regulations. Consult with the
respective regr”rlating authorities to determine the available treatment and disposal facilities.
SECTION 14: ort Information
For Informati vlsrt M or call 1-800-364-3577 or 651-737-6501
SECTION 15: latoinformation
15.1. US Federal Regulations
Contact 3M for more inforrnation.
EPCRA 31ll3l2 Hazard Classifications:
Physical Hazards
Not applicable
llealth Hazards
Respiratory or Skin Sensitization
Serious eye damage or eye irritation
15.2. State Regulations
Contact 3M for more information.
15.3. Chemical Inventories
The components of this product are in compliance with the chemical notification requirements of TSCA. A11 required
components of this product are listed on the active portion of the TSCA Inventory.
Contact 3M for more information
15.4. International Regulations
Contact 3M for more information.
This SDS has been to meet the U.S. OSHA Hazard Communication 29 CFR 1910.r200.
SECTION 16: Other information
NFPA Hazard Classification
Health: 2 Flammability: I Instability: I Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by shorl-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
Document Group:
Issue Date:
l8-0901-1
04/19/2t
Version Number:
Supercedes Date:
10.04
12/11/20
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be corect as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PEMORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user’s method of use or application. Given the variety of factors that can affect the use and application of a 3M prodr”rct,
pg 262 ol 444-PPrint5B25B29.pdl–405919212–267 1337 B
Page l1 of 12
3MrM Scotch-weldrM DP6OO G and Concrete r 600 Part B 04tr9t2l
some of which are uniquely within the user’s knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user’s rnethod of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in enors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M.
3M USA SDSs are available at www.3M.com
pg 263 of 444-PPrint5825829.pdl–40591 921 2–267 1337 8
Page 12 of 12
by | Sep 27, 2025
3M(TM) Marine Adhesive Sealant Fast Cure 5200, White; PN 06520 , 05220, 06534, 06535 10/29/14
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Page 1 of 12
Safety Data Sheet
Copyright,2014,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2)neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document Group:16-5850-9 Version Number: 12.00
Issue Date: 10/29/14 Supercedes Date: 08/22/12
SECTION 1: Identification
1.1. Product identifier
3M(TM) Marine Adhesive Sealant Fast Cure 5200, White; PN 06520 , 05220, 06534, 06535
Product Identification Numbers
60-9800-4557-3, 60-9800-4558-1, 60-9800-4562-3, 62-5239-0330-0, 62-5239-5236-4
1.2. Recommended use and restrictions on use
Recommended use
Adhesive Sealant, Sealant
1.3. Supplier s details
MANUFACTURER: 3M
DIVISION: Industrial Adhesives and Tapes Division
ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA
Telephone: 1-888-3M HELPS (1-888-364-3577)
1.4. Emergency telephone number
1-800-364-3577 or (651) 737-6501 (24 hours)
SECTION 2: Hazard identification
2.1. Hazard classification
Respiratory Sensitizer: Category 1.
Skin Sensitizer: Category 1.
Specific Target Organ Toxicity (repeated exposure): Category 1.
2.2. Label elements
Signal word
Danger
Symbols
Health Hazard |
Pictograms
3M(TM) Marine Adhesive Sealant Fast Cure 5200, White; PN 06520 , 05220, 06534, 06535 10/29/14
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Hazard Statements
Maycause allergy or asthma symptoms or breathing difficulties if inhaled.
Maycause an allergic skin reaction.
Causes damage to organs through prolonged or repeated exposure:
respiratory system |
Precautionary Statements
General:
Keep out of reach of children.
Prevention:
Do not breathe dust/fume/gas/mist/vapors/spray.
In case of inadequate ventilation wear respiratory protection.
Wear protective gloves.
Do not eat, drink or smoke when using this product.
Wash thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.
Response:
IF INHALED: If breathing is difficult, remove person to fresh air and keep comfortable for breathing.
If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
IF ON SKIN: Wash with plenty of soap and water.
If skin irritation or rash occurs: Get medical advice/attention.
Wash contaminated clothing before reuse.
Get medical advice/attention if you feel unwell.
Disposal:
Dispose of contents/container in accordance with applicable local/regional/national/international regulations.
2.3. Hazards not otherwise classified
None.
1% of the mixture consists of ingredients of unknown acute oral toxicity.
1% of the mixture consists of ingredients of unknown acute dermal toxicity.
3% of the mixture consists of ingredients of unknown acute inhalation toxicity.
SECTION 3: Composition/information on ingredients
Ingredient C.A.S. No. % by Wt
Urethane Polymer 51447-37-1 40 – 70 Trade Secret *
Titanium Dioxide 13463-67-7 10 – 30 Trade Secret *
Fumed Silica 112945-52-5 1 – 5 Trade Secret *
p,p’-Methylenebis(Phenyl Isocyanate) 101-68-8 < 2.4 Trade Secret *
Zinc Oxide 1314-13-2 < 2.3 Trade Secret *
Alkyl Isocyanate Silane 85702-90-5 < 2 Trade Secret *
Carbitol Acetate 112-15-2 < 2.0 Trade Secret *
Fumed Silica 7631-86-9 0.5 - 1.5 Trade Secret *
Heptane 142-82-5 < 0.3 Trade Secret*
3M(TM) Marine Adhesive Sealant Fast Cure 5200, White; PN 06520 , 05220, 06534, 06535 10/29/14
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*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.
Skin Contact:
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop,
get medical attention.
Eye Contact:
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get
medical attention.
If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both a cute and delayed
See Section 11.1. Information on toxicological effects.
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.
5.2. Special hazards arising fromthe substance or mixture
None inherent in this product.
Hazardous Decomposition or By -Products
SubstanceCondition
Isocyanates During Combustion
Carbon monoxide During Combustion
Carbon dioxide During Combustion
Hydrogen Cyanide During Combustion
Oxides of Nitrogen During Combustion
Toxic Vapor, Gas, Particulate During Combustion
5.3. Special protective actions for fire-fighters
No special protective actions for fire-fighters are anticipated.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and
health hazards, respiratory protection, ventilation, and personal protective equipment.
3M(TM) Marine Adhesive Sealant Fast Cure 5200, White; PN 06520 , 05220, 06534, 06535 10/29/14
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6.2. Environmental precautions
Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or
bodies of water.
6.3. Methods and material for containment and cleaning up
Pour isocyanate decontaminant solution (90% water, 8% concentrated ammonia, 2% detergent) on spill and allowto react for
10 minutes. Or pour water on spill and allow to react for more than 30 minutes. Cover with absorbent material. Working
from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent
material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a
physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a container approved
for transportation by appropriate authorities, but do not seal the container for 48 hours to avoid pressure build-up. Clean up
residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and
followsafety precautions on the solvent label and SDS. Dispose of collected material as soon as possible.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Keep out of reach of children. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing.
Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should
not be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse.
7.2. Conditions for safe storage including any incompatibilities
Keep container tightly closed to prevent contamination with water or air. If contamination is suspected, do not reseal
container. Store away from amines.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Occupational exposure limits
If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
Ingredient C.A.S. No.Agency Limit type Additional Comments
p,p'-Methylenebis(Phenyl
Isocyanate)
101-68-8ACGIH TWA:0.005 ppm
FREE ISOCYANATES 101-68-8Manufacturer
determined
TWA:0.005 ppm;STEL:0.02
ppm
p,p'-Methylenebis(Phenyl
Isocyanate)
101-68-8OSHA CEIL:0.2 mg/m3(0.02 ppm)
SILICA, AMORPHOUS 112945-52-
5
OSHA TWA concentration:0.8
mg/m3;TWA:20 millions of
particles/cu. ft.
Zinc Oxide 1314-13-2OSHA TWA(as fume):5
mg/m3;TWA(as total dust):15
mg/m3;TWA(respirable
fraction):5 mg/m3
Zinc Oxide 1314-13-2ACGIH TWA(respirable fraction):2
mg/m3;STEL(respirable
fraction):10 mg/m3
Titanium Dioxide 13463-67-7OSHA TWA(as total dust):15 mg/m3
Titanium Dioxide 13463-67-7ACGIH TWA:10 mg/m3 A4: Not class. as human
carcin
Titanium Dioxide 13463-67-7CMRG TWA(as respirable dust):5
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mg/m3
Heptane 142-82-5ACGIH TWA:400 ppm;STEL:500 ppm
Heptane 142-82-5OSHA TWA:2000 mg/m3(500 ppm)
SILICA, AMORPHOUS 7631-86-9OSHA TWA concentration:0.8
mg/m3;TWA:20 millions of
particles/cu. ft.
Fumed Silica 7631-86-9CMRG TWA(as respirable dust):3
mg/m3
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Guidelines
OSHA : United States Department of Labor -Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to belowrelevant Exposure
Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequencyand duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing.
Gloves made from the following material(s) are recommended: Polymer laminate
If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.),then
use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an
exposure assessment. The following protective clothing material(s) are recommended: Apron -polymer laminate
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator
type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
General Physical Form: Liquid
Specific Physical Form: Paste
Odor, Color, Grade: White thixotropic paste, slight odor
Odor threshold No Data Available
3M(TM) Marine Adhesive Sealant Fast Cure 5200, White; PN 06520 , 05220, 06534, 06535 10/29/14
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pHNot Applicable
Melting point Not Applicable
Boiling Point Not Applicable
Flash Point No flash point
Evaporation rate No Data Available
Flammability (solid, gas) Not Applicable
Flammable Limits(LEL) Not Applicable
Flammable Limits(UEL) Not Applicable
Vapor Pressure No Data Available
Vapor Density No Data Available
Density 1.3 g/ml
Specific Gravity 1.3 [Ref Std: WATER=1]
Solubility in Water Nil
Solubility-non-water No Data Available
Partition coefficient: n-octanol/ water No Data Available
Autoignition temperature No Data Available
Decomposition temperature No Data Available
Viscosity 100,000 -500,000 centipoise
Hazardous Air Pollutants 2.6 % weight [ Test Method: Calculated]
Volatile Organic Compounds 38 g/l [Test Method: tested per EPA method 24] [Details: EU
VOC content]
Percent volatile 2.83 % weight
VOC Less H2O & Exempt Solvents 38 g/l [Test Method: tested per EPA method 24]
SECTION 10: Stability and reactivity
10.1. Reactivity
This material may be reactive with certain agents under certain conditions -see the remaining headings in this section.
10.2. Chemical stability
Stable.
10.3. Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4. Conditions to avoid
None known.
10.5. Incompatible materials
Amines
Alcohols
Water
10.6. Hazardous decomposition products
Substance Condition
None known.
Refer to section 5.2 for hazardous decomposition products during combustion.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
3M(TM) Marine Adhesive Sealant Fast Cure 5200, White; PN 06520 , 05220, 06534, 06535 10/29/14
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reflected in the material clas sification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1. Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.
Allergic Respiratory Reaction: Signs/symptoms may include difficulty breathing, wheezing, cough, and tightness of chest.
Maycause target organ effects after inhalation.
Skin Contact:
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin Reaction
(non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.
Eye Contact:
Contact with the eyes during product use is not expected to result in significant irritation.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
Target Organ Effects:
Prolongedor repeated exposure may cause:
Respiratory Effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart rate,
bluish colored skin (cyanosis), sputum production, changes in lung function tests, and/or respiratory failure.
Carcinogenicity:
IngredientC.A.S. No. Class Description Regulation
Titanium Dioxide 13463-67-7 Grp. 2B: Possible human carc.International Agency for Research on Cancer
Additional Information:
Persons previously sensitized to isocyanates may develop a cross-sensitization reaction to other isocyanates.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
Name Route SpeciesValue
Overall product Dermal No data available; calculated ATE > 5,000 mg/kg
Overall product Inhalation-
Vapor(4 hr)
No data available; calculated ATE > 50 mg/l
Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg
Urethane Polymer IngestionRat LD50 > 5,000 mg/kg
Titanium Dioxide Dermal Rabbit LD50 > 10,000 mg/kg
Titanium Dioxide Inhalation-
Dust/Mist
(4 hours)
Rat LC50 > 6.82 mg/l
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Titanium Dioxide IngestionRat LD50 > 10,000 mg/kg
Fumed Silica Dermal Rabbit LD50 > 5,000 mg/kg
Fumed Silica Inhalation-
Dust/Mist
(4 hours)
Rat LC50 > 0.691 mg/l
Fumed Silica IngestionRat LD50 > 5,110 mg/kg
p,p’-Methylenebis(Phenyl Isocyanate) Inhalation-
Vapor
LC50 estimated to be 10 -20 mg/l
p,p’-Methylenebis(Phenyl Isocyanate) Dermal Rabbit LD50 > 5,000 mg/kg
p,p’-Methylenebis(Phenyl Isocyanate) Inhalation-
Dust/Mist
(4 hours)
Rat LC50 0.369 mg/l
p,p’-Methylenebis(Phenyl Isocyanate) IngestionRat LD50 31,600 mg/kg
Zinc Oxide Dermal LD50 estimated to be > 5,000 mg/kg
Zinc Oxide Inhalation-
Dust/Mist
(4 hours)
Rat LC50 > 5.7 mg/l
Zinc Oxide IngestionRat LD50 > 5,000 mg/kg
Carbitol Acetate Dermal Rabbit LD50 15,000 mg/kg
Carbitol Acetate IngestionRat LD50 11,000 mg/kg
Fumed Silica Dermal Rabbit LD50 > 5,000 mg/kg
Fumed Silica Inhalation-
Dust/Mist
(4 hours)
Rat LC50 > 0.691 mg/l
Fumed Silica IngestionRat LD50 > 5,110 mg/kg
Heptane Dermal Rabbit LD50 3,000 mg/kg
Heptane Inhalation-
Vapor (4
hours)
Rat LC50 103 mg/l
Heptane IngestionRat LD50 > 15,000 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name SpeciesValue
Titanium Dioxide Rabbit No significant irritation
Fumed Silica Rabbit No significant irritation
p,p’-Methylenebis(Phenyl Isocyanate) official
classifica
tion
Irritant
Zinc Oxide Human
and
animal
No significant irritation
Carbitol Acetate Human
and
animal
Minimal irritation
Fumed Silica Rabbit No significant irritation
Heptane Human Mild irritant
Serious Eye Damage/Irritation
Name SpeciesValue
Titanium Dioxide Rabbit No significant irritation
Fumed Silica Rabbit No significant irritation
p,p’-Methylenebis(Phenyl Isocyanate) official
classifica
tion
Severe irritant
Zinc Oxide Rabbit Mild irritant
Carbitol Acetate Rabbit Mild irritant
Fumed Silica Rabbit No significant irritation
Heptane Moderate irritant
Skin Sensitization
Name SpeciesValue
Titanium Dioxide Human
and
animal
Not sensitizing
Fumed Silica Human Not sensitizing
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and
animal
p,p’-Methylenebis(Phenyl Isocyanate) official
classifica
tion
Sensitizing
Zinc Oxide Guinea
pig
Some positive data exist, but the data are not
sufficient for classification
Carbitol Acetate Human
and
animal
Not sensitizing
Fumed Silica Human
and
animal
Not sensitizing
Respiratory Sensitization
Name SpeciesValue
p,p’-Methylenebis(Phenyl Isocyanate) Human Sensitizing
Germ Cell Mutagenicity
Name Route Value
Titanium Dioxide In VitroNot mutagenic
Titanium Dioxide In vivo Not mutagenic
Fumed Silica In VitroNot mutagenic
p,p’-Methylenebis(Phenyl Isocyanate) In VitroSome positive data exist, but the data are not
sufficient for classification
Zinc Oxide In VitroSome positive data exist, but the data are not
sufficient for classification
Zinc Oxide In vivo Some positive data exist, but the data are not
sufficient for classification
Carbitol Acetate In VitroNot mutagenic
Fumed Silica In VitroNot mutagenic
Heptane In VitroNot mutagenic
Carcinogenicity
Name Route SpeciesValue
Titanium Dioxide IngestionMultiple
animal
species
Not carcinogenic
Titanium Dioxide InhalationRat Carcinogenic
Fumed Silica Not
Specified
Mouse Some positive data exist, but the data are not
sufficient for classification
p,p’-Methylenebis(Phenyl Isocyanate) InhalationRat Some positive data exist, but the data are not
sufficient for classification
Fumed Silica Not
Specified
Mouse Some positive data exist, but the data are not
sufficient for classification
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value SpeciesTest Result Exposure
Duration
Fumed Silica IngestionNot toxic to female reproductionRat NOAEL 509
mg/kg/day
1 generation
Fumed Silica IngestionNot toxic to male reproduction Rat NOAEL 497
mg/kg/day
1 generation
Fumed Silica IngestionNot toxic to development Rat NOAEL
1,350
mg/kg/day
during
organogenesi
s
p,p’-Methylenebis(Phenyl Isocyanate)InhalationSome positive developmental data exist,
but the data are not sufficient for
classification
Rat NOAEL
0.004 mg/l
during
organogenesi
s
Zinc Oxide IngestionSome positive
reproductive/developmental data exist,
but the data are not sufficient for
classification
Multiple
animal
species
NOAEL 125
mg/kg/day
premating &
during
gestation
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Fumed Silica IngestionNot toxic to female reproductionRat NOAEL 509
mg/kg/day
1 generation
Fumed Silica IngestionNot toxic to male reproduction Rat NOAEL 497
mg/kg/day
1 generation
Fumed Silica IngestionNot toxic to development Rat NOAEL
1,350
mg/kg/day
during
organogenesi
s
Target Organ(s)
Specific Target Organ Toxicity -single exposure
Name Route Target Organ(s)Value SpeciesTest Result Exposure
Duration
p,p’-Methylenebis(Phenyl
Isocyanate)
Inhalationrespiratory irritationMay cause respiratory irritationofficial
classifica
tion
NOAEL Not
available
Carbitol Acetate Inhalationcentral nervous
system depression
May cause drowsiness or
dizziness
Human
and
animal
NOAEL Not
available
not applicable
Carbitol Acetate Ingestioncentral nervous
system depression
May cause drowsiness or
dizziness
Multiple
animal
species
NOAEL Not
available
not applicable
Heptane Inhalationcentral nervous
system depression
May cause drowsiness or
dizziness
Human NOAEL Not
available
Heptane Inhalationrespiratory irritationSome positive data exist, but the
data are not sufficient for
classification
Human NOAEL Not
available
Heptane Ingestioncentral nervous
system depression
May cause drowsiness or
dizziness
Human NOAEL Not
available
Specific Target Organ Toxicity -repeated exposure
Name Route Target Organ(s) Value SpeciesTest Result Exposure
Duration
Titanium Dioxide Inhalationrespiratory systemSome positive data exist, but the
data are not sufficient for
classification
Rat LOAEL
0.010 mg/l
2 years
Titanium Dioxide Inhalationpulmonary fibrosisAll data are negative Human NOAEL Not
available
occupational
exposure
Fumed Silica Inhalationrespiratory system |
silicosis
All data are negative Human NOAEL Not
available
occupational
exposure
p,p’-Methylenebis(Phenyl
Isocyanate)
Inhalationrespiratory systemCauses damage to organs
through prolonged or repeated
exposure
Rat LOAEL
0.004 mg/l
13 weeks
Zinc Oxide Ingestionnervous system Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL 600
mg/kg/day
10 days
Zinc Oxide Ingestionendocrine system |
hematopoietic
system | kidney
and/or bladder
Some positive data exist, but the
data are not sufficient for
classification
Other NOAEL 500
mg/kg/day
6 months
Carbitol Acetate Inhalationrespiratory systemSome positive data exist, but the
data are not sufficient for
classification
Rat NOAEL 0.48
mg/l
2 weeks
Carbitol Acetate Inhalationliver | immune
system | kidney
and/or bladder
All data are negative Rat NOAEL 0.48
mg/l
2 weeks
Fumed Silica Inhalationrespiratory system |
silicosis
All data are negative Human NOAEL Not
available
occupational
exposure
Heptane Inhalationliver | nervous
system | kidney
and/or bladder
All data are negative Rat NOAEL 12
mg/l
26 weeks
Aspiration Hazard
Name Value
Heptane Aspiration hazard
3M(TM) Marine Adhesive Sealant Fast Cure 5200, White; PN 06520 , 05220, 06534, 06535 10/29/14
__________________________________________________________________________________________
Page 11 of 12
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
SECTION 12: Ecological information
Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information onthis material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.
SECTION 13: Disposal considerations
13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.
Dispose of waste product in a permitted industrial waste facility. Empty drums/barrels/containers used for transporting and
handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable
regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable
waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal
facilities.
EPA Hazardous Waste Number (RCRA): Not regulated
SECTION 14: Transport Information
For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.
SECTION 15: Regulatory information
15.1. US Federal Regulations
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard -No Pressure Hazard -No Reactivity Hazard -No Immediate Hazard -Yes Delayed Hazard -Yes
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
Ingredient C.A.S. No % by Wt
p,p’-Methylenebis(Phenyl Isocyanate) 101-68-8 < 2.4
p,p'-Methylenebis(Phenyl Isocyanate) (Benzene,
1,1'-methylenebis[4-isocyanato-)
101-68-8 < 2.4
p,p'-Methylenebis(Phenyl Isocyanate)
(DIISOCYANATES (CERTAIN CHEMICALS
ONLY))
101-68-8 < 2.4
Zinc Oxide (ZINC COMPOUNDS) 1314-13-2 < 2.3
Carbitol Acetate (GLYCOL ETHERS) 112-15-2 < 2.0
3M(TM) Marine Adhesive Sealant Fast Cure 5200, White; PN 06520 , 05220, 06534, 06535 10/29/14
__________________________________________________________________________________________
Page 12 of 12
15.2. State Regulations
Contact 3M for more information.
15.3. Chemical Inventories
The components of this product are in compliance with the chemical notification requirements of TSCA.
Contact 3M for more information.
15.4. International Regulations
Contact 3M for more information.
This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: Other information
NFPA Hazard Classification
Health: 2 Flammability: 1 Instability: 1 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion ordecomposition products that are known to be generated in significant quantities.
Document Group:16-5850-9 Version Number: 12.00
Issue Date: 10/29/14 Supercedes Date: 08/22/12
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PU RPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M
3MUSA SDSs are available at www.3M.com
by | Sep 27, 2025
CHT UK BRIDGWATER LTD
AS1701
Revision nr.3
Dated 4/2/2024
Printed on 4/2/2024
Page n. 1 / 10
Replaced revision:2 (Dated 10/19/2021)
EN
EPY 11.6.1 – SDS 1004.14
Safety Data Sheet
According to U.S.A. Federal Hazcom 2012
1. Identification
1.1. Product identifier
Product name AS1701
1.2. Relevant identified uses of the substance or mixture and uses advised against
Intended use Adhesive sealant.
1.3. Details of the supplier of the safety data sheet
Name CHT UK BRIDGWATER LTD
Full address Amber House Showground Road
District and Country TA6 6AJ Bridgwater (Somerset)
England
Tel. +44(0)1278411400
Fax +44(0)1278411444
e-mail address of the competent person
responsible for the Safety Data Sheet info.uk@cht.com
Supplier: CHT USA, Inc.
805 Wolfe Avenue
Cassopolis, MI 49031
1.4. Emergency telephone number
For urgent inquiries refer to Transport: +1-703-527-3887 CHEMTREC (North America, 24 hours) (CCN 1014369)
Toll Free: 1-800-424-9300 CHEMTREC (North America, 24 hours)
+52 55 8526 4930 CHEMTREC (Central America, 24 hours)
+55 11 4349 1359 CHEMTREC (South America, 24 hours)
2. Hazards identification
2.1. Classification of the substance or mixture
The product is not classified as hazardous pursuant to the provisions set forth in OSHA Hazard Communication Standard (HCS) (29 CFR
1910.1200). However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it
requires a safety data sheet with appropriate information.
Hazard pictograms: —
Signal words: —
Hazard statements: —
Precautionary statements:
Prevention:
—
Response:
—
Storage:
—
Disposal:
—
2.2. Other hazards
Information not available
3. Composition/information on ingredients
3.1. Substances
Information not relevant
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EN
EPY 11.6.1 – SDS 1004.14
3. Composition/information on ingredients… / >>
3.2. Mixtures
Contains:
Identification x = Conc. % Classification:
VINYLTRIMETHOXYSILANE
2,5 x < 3 Flammable liquid, category 3 H226, Acute toxicity, category 4 H332
EC 220-449-8
CAS 2768-02-7
REACH Reg. 01-2119513215-52
TETRA-ISOPROPYLTITANATE
2 x < 2,5 Flammable liquid, category 3 H226, Eye irritation, category 2 H319, Specific
target organ toxicity - single exposure, category 3 H336
EC 208-909-6
CAS 546-68-9
REACH Reg. 01-2119967389-17
* There is a batch to batch variation.
The full wording of hazard (H) phrases is given in section 16 of the sheet.
4. First-aid measures
4.1. Description of first aid measures
EYES: Remove contact lenses, if present. Wash immediately with plenty of water for at least 15 minutes, opening the eyelids fully. If problem
persists, seek medical advice.
SKIN: Remove contaminated clothing. Wash immediately with plenty of water. If irritation persists, get medical advice/attention. Wash
contaminated clothing before using it again.
INHALATION: Remove to open air. In the event of breathing difficulties, get medical advice/attention immediately.
INGESTION: Get medical advice/attention. Induce vomiting only if indicated by the doctor. Never give anything by mouth to an unconscious
person, unless authorised by a doctor.
4.2. Most important symptoms and effects, both acute and delayed
Specific information on symptoms and effects caused by the product are unknown.
4.3. Indication of any immediate medical attention and special treatment needed
Information not available
5. Fire-fighting measures
5.1. Extinguishing media
SUITABLE EXTINGUISHING EQUIPMENT
Extinguishing substances are: carbon dioxide, foam, chemical powder. For product loss or leakage that has not caught fire, water spray can
be used to disperse flammable vapours and protect those trying to stem the leak.
UNSUITABLE EXTINGUISHING EQUIPMENT
Do not use jets of water. Water is not effective for putting out fires but can be used to cool containers exposed to flames to prevent
explosions.
5.2. Special hazards arising from the substance or mixture
HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE
Excess pressure may form in containers exposed to fire at a risk of explosion. Do not breathe combustion products.
5.3. Advice for firefighters
GENERAL INFORMATION
Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for
health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of
contaminated water used for extinction and the remains of the fire according to applicable regulations.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS
Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with
self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137).
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EN
EPY 11.6.1 - SDS 1004.14
6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Block the leakage if there is no hazard.
Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent
any contamination of skin, eyes and personal clothing. These indications apply for both processing staff and those involved in emergency
procedures.
6.2. Environmental precautions
The product must not penetrate into the sewer system or come into contact with surface water or ground water.
6.3. Methods and material for containment and cleaning up
Collect the leaked product into a suitable container. Evaluate the compatibility of the container to be used, by checking section 10. Absorb
the remainder with inert absorbent material.
Make sure the leakage site is well aired. Contaminated material should be disposed of in compliance with the provisions set forth in point
13.
6.4. Reference to other sections
Any information on personal protection and disposal is given in sections 8 and 13.
7. Handling and storage
7.1. Precautions for safe handling
Keep away from heat, sparks and naked flames; do not smoke or use matches or lighters. Without adequate ventilation, vapours may
accumulate at ground level and, if ignited, catch fire even at a distance, with the danger of backfire. Avoid bunching of electrostatic charges.
When performing transfer operations involving large containers, connect to an earthing system and wear antistatic footwear. Vigorous
stirring and flow through the tubes and equipment may cause the formation and accumulation of electrostatic charges. In order to avoid the
risk of fires and explosions, never use compressed air when handling. Open containers with caution as they may be pressurised. Do not eat,
drink or smoke during use. Avoid leakage of the product into the environment.
7.2. Conditions for safe storage, including any incompatibilities
Store only in the original container. Store the containers sealed, in a well ventilated place, away from direct sunlight. Store in a cool and well
ventilated place, keep far away from sources of heat, naked flames and sparks and other sources of ignition. Keep containers away from
any incompatible materials, see section 10 for details.
7.3. Specific end use(s)
Information not available
8. Exposure controls/personal protection
8.1. Control parameters
Information not available
8.2. Exposure controls
As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is
well aired through effective local aspiration.
HAND PROTECTION
Protect hands with category III work gloves.
The following should be considered when choosing work glove material (OSHA 29 CFR 1910.138): compatibility, degradation, failure time
and permeability.
The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends
on the duration and type of use.
SKIN PROTECTION
Wear category I professional long-sleeved overalls and safety footwear. Wash body with soap and water after removing protective clothing.
EYE PROTECTION
Wear airtight protective goggles (OSHA 29 CFR 1910.133).
RESPIRATORY PROTECTION
If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, wear a mask with a
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EN
EPY 11.6.1 - SDS 1004.14
8. Exposure controls/personal protection... / >>
NIOSH certified filter, whose class must be chosen according to the limit of use concentration (NIOSH 42 CFR 84, OSHA 29 CFR
1910.134). In the presence of gases or vapours of various kinds and/or gases or vapours containing particulate (aerosol sprays, fumes,
mists, etc.) combined filters are required.
Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker’s exposure to the
threshold values considered. The protection provided by masks is in any case limited.
If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an
emergency, wear open-circuit compressed air breathing apparatus or external air-intake breathing apparatus. For a correct choice of
respiratory protection device, see standard NIOSH 42 CFR 84, OSHA 29 CFR 1910.134.
ENVIRONMENTAL EXPOSURE CONTROLS
The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure
compliance with environmental standards.
9. Physical and chemical properties
9.1. Information on basic physical and chemical properties
Properties Value Information
Appearance paste
Colour black
Odour characteristic
Odour threshold not available
pH not available
Melting point / freezing point not available
Initial boiling point not available
Boiling range not available
Flash point 150 C (302 F)>
Evaporation rate not available
Flammability not available
Lower inflammability limit not available
Upper inflammability limit not available
Lower explosive limit not available
Upper explosive limit not available
Vapour pressure not available
Vapour density not available
Relative density 1.28
Solubility immiscible with water
Partition coefficient: n-octanol/water not available
Auto-ignition temperature 400 C>
Decomposition temperature not available
Viscosity Paste
Explosive properties not available
Oxidising properties not available
9.2. Other information
Information not available
10. Stability and reactivity
10.1. Reactivity
There are no particular risks of reaction with other substances in normal conditions of use.
10.2. Chemical stability
The product is stable in normal conditions of use and storage.
10.3. Possibility of hazardous reactions
The vapours may also form explosive mixtures with the air.
10.4. Conditions to avoid
Avoid overheating. Avoid bunching of electrostatic charges. Avoid all sources of ignition.
10.5. Incompatible materials
CHT UK BRIDGWATER LTD
AS1701
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Replaced revision:2 (Dated 10/19/2021)
EN
EPY 11.6.1 – SDS 1004.14
10. Stability and reactivity… / >>
Information not available
10.6. Hazardous decomposition products
In the event of thermal decomposition or fire, gases and vapours that are potentially dangerous to health may be released.
11. Toxicological information
In the absence of experimental data for the product itself, health hazards are evaluated according to the properties of the substances it
contains, using the criteria specified in the applicable regulation for classification.
It is therefore necessary to take into account the concentration of the individual hazardous substances indicated in section 3, to evaluate the
toxicological effects of exposure to the product.
11.1. Information on toxicological effects
Metabolism, toxicokinetics, mechanism of action and other information
Information not available
Information on likely routes of exposure
Information not available
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Information not available
Interactive effects
Information not available
ACUTE TOXICITY
VINYLTRIMETHOXYSILANE
7430 mg/kg (Rat)LD50 (Oral):
3460 mg/kg (Rabbit)LD50 (Dermal):
16,79 mg/l/4h (Rat)LC50 (Inhalation vapours):
SKIN CORROSION / IRRITATION
Does not meet the classification criteria for this hazard class
SERIOUS EYE DAMAGE / IRRITATION
Does not meet the classification criteria for this hazard class
RESPIRATORY OR SKIN SENSITISATION
Does not meet the classification criteria for this hazard class
GERM CELL MUTAGENICITY
Does not meet the classification criteria for this hazard class
CARCINOGENICITY
Does not meet the classification criteria for this hazard class
Carcinogenicity Assessment:
7631-86-9 AMORPHOUS SILICATE HYDRATE
IARC:3
67-63-0 PROPAN-2-OL
IARC:3
REPRODUCTIVE TOXICITY
Does not meet the classification criteria for this hazard class
STOT – SINGLE EXPOSURE
CHT UK BRIDGWATER LTD
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EN
EPY 11.6.1 – SDS 1004.14
11. Toxicological information… / >>
Does not meet the classification criteria for this hazard class
STOT – REPEATED EXPOSURE
Does not meet the classification criteria for this hazard class
ASPIRATION HAZARD
Does not meet the classification criteria for this hazard class Viscosity: Paste
12. Ecological information
Use this product according to good working practices. Avoid littering. Inform the competent authorities, should the product reach waterways
or contaminate soil or vegetation.
12.1. Toxicity
VINYLTRIMETHOXYSILANE
LC50 – for Fish 100 mg/l/96h
12.2. Persistence and degradability
Information not available
12.3. Bioaccumulative potential
Information not available
12.4. Mobility in soil
Information not available
12.5. Results of PBT and vPvB assessment
On the basis of available data, the product does not contain any PBT or vPvB in percentage than 0,1%.
12.6. Other adverse effects
Information not available
13. Disposal considerations
13.1. Waste treatment methods
Reuse, when possible. Neat product residues should be considered special non-hazardous waste.
Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations.
CONTAMINATED PACKAGING
Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations.
14. Transport information
The product is not dangerous under current provisions of the Code of International Carriage of Dangerous Goods by Road (ADR) and by
Rail (RID), of the International Maritime Dangerous Goods Code (IMDG), and of the International Air Transport Association (IATA)
regulations.
14.1. UN number
not applicable
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EN
EPY 11.6.1 – SDS 1004.14
14. Transport information… / >>
14.2. UN proper shipping name
not applicable
14.3. Transport hazard class(es)
not applicable
14.4. Packing group
not applicable
14.5. Environmental hazards
not applicable
14.6. Special precautions for user
not applicable
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
Information not relevant
15. Regulatory information
Austrailia AICS: On or in compliance with the inventory.
Canada DSL Inventory List: On or in compliance with the inventory.
EINECS, ELINCS or NLP: On or in compliance with the inventory.
China Inv. Existing Chemical Substances: On or in compliance with the inventory.
Korea Existing Chemicals Inv. (KECI): On or in compliance with the inventory.
Philippines PICCS: On or in compliance with the inventory.
US TSCA Inventory: On or in compliaince with the inventory.
New Zealand Inventory of Chemicals: On or in compliance with the inventory.
Taiwan Chemical Substance Inventory: On or in compliance with the inventory.
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
U.S. Federal Regulations
TSCA:
All components of this product are listed on US Toxic Substances Control Act (TSCA) Inventory or are exempt from the listing / notification
requirements.
Clean Air Act Section 112(b):
No component(s) listed.
Clean Air Act Section 602 Class I Substances:
No component(s) listed.
Clean Air Act Section 602 Class II Substances:
No component(s) listed.
Clean Water Act Priority Pollutants:
No component(s) listed.
Clean Water Act Toxic Pollutants:
No component(s) listed.
DEA List I Chemicals (Precursor Chemicals):
No component(s) listed.
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EN
EPY 11.6.1 – SDS 1004.14
15. Regulatory information… / >>
DEA List II Chemicals (Essential Chemicals):
No component(s) listed.
EPA List of Lists:
313 Category Code:
No component(s) listed.
EPCRA 302 EHS TPQ:
No component(s) listed.
EPCRA 304 EHS RQ:
No component(s) listed.
CERCLA RQ:
No component(s) listed.
EPCRA 313 TRI:
No component(s) listed.
RCRA Code:
No component(s) listed.
CAA 112 (r) RMP TQ:
No component(s) listed.
State Regulations
Massachussetts:
14808-60-7 QUARTZ IN LIQUID SUSPENSION
7631-86-9 AMORPHOUS SILICATE HYDRATE
1333-86-4 CARBON BLACK
Minnesota:
14808-60-7 QUARTZ IN LIQUID SUSPENSION
7631-86-9 AMORPHOUS SILICATE HYDRATE
1333-86-4 CARBON BLACK
New Jersey:
14808-60-7 QUARTZ IN LIQUID SUSPENSION
1333-86-4 CARBON BLACK
New York:
No component(s) listed.
Pennsylvania:
14808-60-7 QUARTZ IN LIQUID SUSPENSION
7631-86-9 AMORPHOUS SILICATE HYDRATE
1333-86-4 CARBON BLACK
California:
7631-86-9 AMORPHOUS SILICATE HYDRATE
1333-86-4 CARBON BLACK
Proposition 65:
WARNING! This product contains chemicals known to the State of California to cause cancer and birth defects or reproductive harm.
1333-86-4 CARBON BLACK
NSRL / MADL ( g/day)
Hazard type NoteOral Dermal Inhalation Intravenous
Carcinogenicity –
International Regulations
Substances subject to exportation reporting pursuant to Regulation (EU) 649/2012:
None
Substances subject to the Rotterdam Convention:
None
Substances subject to the Stockholm Convention:
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EN
EPY 11.6.1 – SDS 1004.14
None
16. Other information
Text of hazard (H) indications mentioned in section 2-3 of the sheet:
H226 Flammable liquid and vapour.
H332 Harmful if inhaled.
H226 Flammable liquid and vapour.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
LEGEND:
– 313 CATEGORY CODE: Emergency Planning and Community Right-to Know Act Section 313 Category Code
– ADR: European Agreement concerning the carriage of Dangerous goods by Road
– ATE: Acute Toxicity Estimate
– CAA 112 RMP TQ: Risk Management Plan Threshold Quantity (Clean Air Act Section 112 )
– CAS: Chemical Abstract Service Number
– CE50: Effective concentration (required to induce a 50% effect)
– CERCLA RQ: Reportable Quantity (Comprehensive Environment Response, Compensation, and Liability Act)
– CLP: Regulation (EC) 1272/2008
– DEA: Drug Enforcement Administration
– EmS: Emergency Schedule
– EPA: US Environmental Protection Agency
– EPCRA: Emergency Planning and Community Right-to Know Act
– EPCRA 302 EHS TPQ: Extremely Hazardous Substance Threshold Planning Quantity (Section 302 Category Code)
– EPCRA 304 EHS RQ: Extremely Hazardous Substance Reportable Quantity (Section 304 Category Code)
– EPCRA 313 TRI: Toxics Release Inventory (Section 313 Category Code)
– GHS: Globally Harmonized System of classification and labeling of chemicals
– IATA DGR: International Air Transport Association Dangerous Goods Regulation
– IC50: Immobilization Concentration 50%
– IMDG: International Maritime Code for dangerous goods
– IMO: International Maritime Organization
– LC50: Lethal Concentration 50%
– LD50: Lethal dose 50%
– OEL: Occupational Exposure Level
– PEL: Predicted exposure level
– RCRA Code: Resource Conservation and Recovery Act Code
– REACH: Regulation (EC) 1907/2006
– REL: Recommended exposure limit
– RID: Regulation concerning the international transport of dangerous goods by train
– TLV: Threshold Limit Value
– TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure.
– TSCA: Toxic Substances Control Act
– TWA: Time-weighted average exposure limit
– TWA STEL: Short-term exposure limit
– VOC: Volatile organic Compounds
– WHMIS: Workplace Hazardous Materials Information System.
GENERAL BIBLIOGRAPHY:
– GHS rev. 3
– The Merck Index. 10th Edition
– Handling Chemical Safety
– Niosh – Registry of Toxic Effects of Chemical Substances
– INRS – Fiche Toxicologique (toxicological sheet)
– Patty – Industrial Hygiene and Toxicology
– N.I. Sax – Dangerous properties of Industrial Materials-7, 1989 Edition
– ECHA website
– Database of SDS models for chemicals – Ministry of Health and ISS (Istituto Superiore di Sanit ) – Italy
– 6 NYCRR part 597
– Cal/OSHA website
– California Safe Drinking Water and Toxic Enforcement Act
– EPA website
– Hazard Comunication Standard (HCS 2012)
– IARC website
– List Of Lists EPA: Consolidated List of Chemicals Subject to EPCRA, CERCLA and Section 112 of the Clean Air Act
– Massachussetts 105 CMR Department of public health 670.000: “Right to Know”
– Minensota Chapter 5206 Departemnt Of Labor and Industry Hazardous Substances, Employee “Right to Know”.
CHT UK BRIDGWATER LTD
AS1701
Revision nr.3
Dated 4/2/2024
Printed on 4/2/2024
Page n. 10 / 10
Replaced revision:2 (Dated 10/19/2021)
EN
EPY 11.6.1 – SDS 1004.14
16. Other information… / >>
– New Jersey Worker and Community Right to know Act N.J.S.A.
– NTP. 2011. Report on Carcinogens, 12th Edition.
– OSHA website
– Pennsylvania, Hazardous Substance List, Chapter 323
Note for users:
The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the
suitability and thoroughness of provided information according to each specific use of the product.
This document must not be regarded as a guarantee on any specific product property.
The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current
health and safety laws and regulations. The producer is relieved from any liability arising from improper uses.
Provide appointed staff with adequate training on how to use chemical products.
CALCULATION METHODS FOR CLASSIFICATION
Product classification derives from criteria established by the OSHA Hazard Communication Standard (HCS) (29 CFR 1910.1200), unless
determined otherwise in Section 11 and 12. The data for evaluation of chemical-physical properties are reported in section 9.
Changes to previous review:
The following sections were modified:
03 / 08 / 12.
by | Sep 27, 2025
Crestomer 1152 PA Drum
Liquid.
SAFETY DATA SHEET
GHS product identifier
Product type
Section 1. Identification
:
:
Supplier’s details :
Crestomer 1152 PA Drum
Relevant identified uses of the substance or mixture and uses advised against
Resins.
Identified uses
Scott Bader ATC,
2400 Canadian Street
Drummondville, Que
Canada, J2C 7W3
Tel: +1 819 477 1752
SB –
Canada
Emergency telephone
number (with hours of
operation)
:
SDS@scottbader.com:e-mail address of person
responsible for this SDS
+1 215 207 0061 (NCEC, Geographic) 24h
+1 866 928 0789 (NCEC, Toll free) 24h
Section 2. Hazards identification
FLAMMABLE LIQUIDS – Category 3
ACUTE TOXICITY (inhalation) – Category 4
SKIN IRRITATION – Category 2
EYE IRRITATION – Category 2A
SKIN SENSITIZATION – Category 1
TOXIC TO REPRODUCTION (Fertility) – Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) – Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) –
Category 1
AQUATIC HAZARD (ACUTE) – Category 3
AQUATIC HAZARD (LONG-TERM) – Category 3
Classification of the
substance or mixture
:
Signal word :Danger
Hazard statements :H226 – Flammable liquid and vapor.
H332 – Harmful if inhaled.
H319 – Causes serious eye irritation.
H315 – Causes skin irritation.
H317 – May cause an allergic skin reaction.
H361 – Suspected of damaging fertility.
H335 – May cause respiratory irritation.
H372 – Causes damage to organs through prolonged or repeated exposure. (hearing
organs)
Hazard pictograms :
GHS label elements
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
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Crestomer 1152 PA Drum
Section 2. Hazards identification
H412 – Harmful to aquatic life with long lasting effects.
Precautionary statements
Prevention :P201 – Obtain special instructions before use.
P202 – Do not handle until all safety precautions have been read and understood.
P280 – Wear protective gloves. Wear eye or face protection. Wear protective clothing.
P210 – Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
P241 – Use explosion-proof electrical, ventilating, lighting and all material-handling
equipment.
P242 – Use only non-sparking tools.
P243 – Take precautionary measures against static discharge.
P233 – Keep container tightly closed.
P271 – Use only outdoors or in a well-ventilated area.
P273 – Avoid release to the environment.
P260 – Do not breathe vapor.
P270 – Do not eat, drink or smoke when using this product.
P264 – Wash hands thoroughly after handling.
P272 (OSHA) – Contaminated work clothing must not be allowed out of the workplace.
Response :P314 – Get medical attention if you feel unwell.
P308 + P313 – IF exposed or concerned: Get medical attention.
P304 + P340 + P312 – IF INHALED: Remove person to fresh air and keep comfortable
for breathing. Call a POISON CENTER or physician if you feel unwell.
P303 + P361 + P353 – IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water or shower.
P302 + P352 + P363 – IF ON SKIN: Wash with plenty of soap and water. Wash
contaminated clothing before reuse.
P333 + P313 – If skin irritation or rash occurs: Get medical attention.
P305 + P351 + P338 – IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 – If eye irritation persists: Get medical attention.
Storage :P405 – Store locked up.
P403 – Store in a well-ventilated place.
P235 – Keep cool.
Disposal :P501 – Dispose of contents and container in accordance with all local, regional, national
and international regulations.
Hazards not otherwise
classified
:None known.
Section 3. Composition/information on ingredients
styrene 45.156 100-42-5
2-hydroxyethyl acrylate >2.6344 818-61-1
cobalt bis(2-ethylhexanoate) 0.10986 136-52-7
Ingredient name CAS number%
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Other means of
identification
:Not available.
CAS number :Not applicable.
Substance/mixture
Product code :OL100127
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
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Crestomer 1152 PA Drum
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway. Loosen tight clothing
such as a collar, tie, belt or waistband.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Get medical attention. In the event of any
complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean
shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
Indication of immediate medical attention and special treatment needed, if necessary
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Crestomer 1152 PA Drum
Section 4. First aid measures
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.
Specific treatments :No specific treatment.
See toxicological information (Section 11)
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides
Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a
fire or if heated, a pressure increase will occur and the container may burst, with the risk
of a subsequent explosion. This material is harmful to aquatic life with long lasting
effects. Fire water contaminated with this material must be contained and prevented
from being discharged to any waterway, sewer or drain.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use dry chemical, CO , water spray (fog) or foam.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to
the environment if released in large quantities.
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in “For non-
emergency personnel”.
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Crestomer 1152 PA Drum
Section 6. Accidental release measures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
Large spill :
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Store in accordance with local regulations. Store in a segregated and approved area.
Store in original container protected from direct sunlight in a dry, cool and well-ventilated
area, away from incompatible materials (see Section 10) and food and drink. Store
locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental
contamination.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Avoid exposure – obtain special instructions before use. Avoid
exposure during pregnancy. Do not handle until all safety precautions have been read
and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist.
Do not ingest. Avoid release to the environment. Use only with adequate ventilation.
Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas
and confined spaces unless adequately ventilated. Keep in the original container or an
approved alternative made from a compatible material, kept tightly closed when not in
use. Store and use away from heat, sparks, open flame or any other ignition source.
Use explosion-proof electrical (ventilating, lighting and material handling) equipment.
Use only non-sparking tools. Take precautionary measures against electrostatic
discharges. Empty containers retain product residue and can be hazardous. Do not
reuse container.
:
Precautions for safe handling
styrene ACGIH TLV (United States, 3/2016).
TWA: 20 ppm 8 hours.
TWA: 85 mg/m 8 hours.
STEL: 40 ppm 15 minutes.
STEL: 170 mg/m 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
TWA: 50 ppm 8 hours.
TWA: 215 mg/m 8 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
OSHA PEL Z2 (United States, 2/2013).
TWA: 100 ppm 8 hours.
CEIL: 200 ppm
AMP: 600 ppm 5 minutes.
NIOSH REL (United States, 10/2016).
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
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Crestomer 1152 PA Drum
Section 8. Exposure controls/personal protection
TWA: 50 ppm 10 hours.
TWA: 215 mg/m 10 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
cobalt bis(2-ethylhexanoate) ACGIH TLV (United States, 3/2016).
TWA: 0.02 mg/m , (as Co) 8 hours.
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Section 9. Physical and chemical properties
Physical state Liquid.
SolventOdor
pH
Translucent.Color
Not available.
Not available.Odor threshold
:
:
:
:
:
Appearance
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Crestomer 1152 PA Drum
Section 9. Physical and chemical properties
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Not available.
1 to 1.1
Not available.
Not available.
Not available.
Evaporation rate Not available.
Auto-ignition temperature
Flash point
Not available.
Closed cup: 32 C (89.6 F)
Not available.
Viscosity Kinematic (40 C (104 F)): >0.4 cm
2
/s (>40 cSt)
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
Boiling point :Not available.
Flammability (solid, gas):Not available.
Lower and upper explosive
(flammable) limits
:Not available.
Burning rate Not applicable.:
Burning time :Not applicable.
SADT Not available.:
Decomposition temperature:Not available.
Aerosol product
Solubility in water :Not available.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours
LC50 Inhalation Vapor Rat 11800 mg/m 4 hours
LD50 Dermal Rat >2000 mg/kg –
LD50 Oral Rat 2650 mg/kg –
2-hydroxyethyl acrylate LD50 Dermal Rabbit 298 mg/kg –
LD50 Oral Rat 548 mg/kg –
cobalt bis(2-ethylhexanoate)LD50 Dermal Rabbit >5 g/kg –
LD50 Oral Rat >2000 mg/kg –
Product/ingredient name Result Species Dose Exposure
Irritation/Corrosion
Information on toxicological effects
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Crestomer 1152 PA Drum
Section 11. Toxicological information
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
styrene Eyes – Mild irritant Human – 50 parts per
million
–
Eyes – Moderate irritantRabbit – 24 hours 100
milligrams
–
Eyes – Severe irritantRabbit – 100
milligrams
–
Skin – Mild irritant Rabbit – 500
milligrams
–
Skin – Moderate irritantRabbit – 100 Percent-
2-hydroxyethyl acrylate Skin – Mild irritant Rabbit – 24 hours 10
milligrams
–
Skin – Moderate irritantRabbit – 500
milligrams
–
Eyes – Moderate irritantRabbit – 24 hours 20
milligrams
–
Eyes – Severe irritantRabbit – 1 milligrams-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Information on the likely
routes of exposure
Inhalation :Harmful if inhaled. May cause respiratory irritation.
Causes serious eye irritation.:Eye contact
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
styrene Category 3 Not applicable.Respiratory tract
irritation
Name Category
Name Category
styrene Category 1 Inhalation hearing organs
Aspiration hazard
Name Result
styrene ASPIRATION HAZARD – Category 1
Route of
exposure
Target organs
Route of
exposure
Target organs
:Not available.
Potential acute health effects
Classification
styrene – 2B Reasonably anticipated to be a human carcinogen.
cobalt bis(2-ethylhexanoate)- 2B Reasonably anticipated to be a human carcinogen.
Product/ingredient name NTPIARCOSHA
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Crestomer 1152 PA Drum
Section 11. Toxicological information
styrene Chronic NOAEL Dermal Rat 615 mg/kg –
Chronic NOAEL Inhalation
Gas.
Rat 20 ppm 8 hours
Product/ingredient name Result Species Dose Exposure
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes damage to organs through prolonged or repeated exposure. Once sensitized, a
severe allergic reaction may occur when subsequently exposed to very low levels.
General :
No known significant effects or critical hazards.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :Suspected of damaging fertility.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Oral 4567.2 mg/kg
Dermal 11200.1 mg/kg
Inhalation (gases) 6134.2 ppm
Inhalation (vapors) 26.13 mg/l
Route ATE value
Acute toxicity estimates
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
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Crestomer 1152 PA Drum
Section 11. Toxicological information
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Product/ingredient name
styrene 0.35 13.49 low
2-hydroxyethyl acrylate -0.17 – low
cobalt bis(2-ethylhexanoate)- 15600 high
Product/ingredient name Aquatic half-life Photolysis Biodegradability
styrene – – Readily
cobalt bis(2-ethylhexanoate)- – Not readily
Toxicity
styrene Acute EC50 1400 g/l Fresh water Algae – Pseudokirchneriella
subcapitata
72 hours
Acute EC50 33 mg/l Fresh water Algae – Pseudokirchneriella
subcapitata
96 hours
Acute EC50 4700 g/l Fresh water Daphnia – Daphnia magna 48 hours
Acute LC50 52 mg/l Marine water Crustaceans – Artemia salina48 hours
Acute LC50 4020 g/l Fresh water Fish – Pimephales promelas 96 hours
Chronic NOEC 1.01 mg/l Daphnia 21 days
2-hydroxyethyl acrylate Acute LC50 4800 g/l Fresh water Fish – Pimephales promelas –
Juvenile (Fledgling, Hatchling,
Weanling)
96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
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Crestomer 1152 PA Drum
Section 14. Transport information
Resin solution
3
III
RESIN
SOLUTION
3
III
Resin solution
UN1866
3
III
UN1866 UN1866
Reportable
quantity 2214.
5 lbs / 1005.4
kg [252.95 gal /
957.52 L].
Package sizes
shipped in
quantities less
than the
product
reportable
quantity are
not subject to
the RQ
(reportable
quantity)
transportation
requirements.
Limited
quantity Yes.
Packaging
instruction
Exceptions:
150. Non-bulk:
173. Bulk: 242.
Quantity
limitation
Passenger
aircraft/rail: 60
L. Cargo
aircraft: 220 L.
Special
provisions B1,
B52, IB3, T2,
TP1
Emergency
schedules F-E,
_S-E_
Special
provisions
223, 955
Quantity
limitation
Passenger and
Cargo Aircraft:
60 L.
Packaging
instructions:
355. Cargo
Aircraft Only:
220 L.
Packaging
instructions:
366. Limited
Quantities –
Passenger
Aircraft: 10 L.
Packaging
instructions:
Y344.
Special
provisions A3
DOT
Classification
IMDG IATA
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
Special precautions for user
No. No. No.
Transport within user s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
:
TDG
Classification
UN1866
RESIN
SOLUTION
3
III
No.
Product
classified as
per the
following
sections of the
Transportation
of Dangerous
Goods
Regulations: 2.
18-2.19 (Class
3).
Explosive
Limit and
Limited
Quantity Index
5
Passenger
Carrying
Road or Rail
Index 60
ADR/RID
UN1866
RESIN
SOLUTION
3
III
No.
Hazard
identification
number 30
Limited
quantity 5 L
Special
provisions
640E
Tunnel code
(D/E)
Mexico
Classification
UN1866
RESINA,
SOLUCIONES
DE
3
III
No.
Special
provisions 223
Date of issue/Date of revision :1/8/2019 Date of previous issue :3/13/2016 Version:1.02 11/14
Crestomer 1152 PA Drum
Section 14. Transport information
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
:Not available.
Section 15. Regulatory information
U.S. Federal regulations
The following components are listed: STYRENE; PHENYLETHYLENE; ETHYLENE
GLYCOL MONOACRYLATE; 2-HYDROXYETHYL ACRYLATE
Massachusetts
:
:
SARA 313
Product name CAS number %
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
styrene 100-42-5 45.156
cobalt bis(2-ethylhexanoate) 136-52-7 0.10986
styrene 100-42-5 45.156
cobalt bis(2-ethylhexanoate) 136-52-7 0.10986
Form R – Reporting
requirements
Supplier notification
Clean Air Act Section 112
(b) Hazardous Air
Pollutants (HAPs)
:Listed
Clean Air Act Section 602
Class I Substances
:Not listed
Clean Air Act Section 602
Class II Substances
:Not listed
DEA List I Chemicals
(Precursor Chemicals)
:Not listed
DEA List II Chemicals
(Essential Chemicals)
:Not listed
New York :The following components are listed: Styrene
State regulations
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
SARA 302/304
SARA 304 RQ :174791900.2 lbs / 79355522.7 kg [19965248.8 gal / 75576688.3 L]
sulphuric acid <0.
00063568
Yes.1000 66.3 1000 66.3
Composition/information on ingredients
Name % EHS(lbs) (lbs)(gallons) (gallons)
SARA 302 TPQ SARA 304 RQ
SARA 311/312
Classification :Fire hazard
Immediate (acute) health hazard
Delayed (chronic) health hazard
styrene 45.156 Yes. No. No. Yes. Yes.
2-hydroxyethyl acrylate >2.6344 No. No. No. Yes. No.
cobalt bis(2-ethylhexanoate) 0.10986 No. No. No. Yes. Yes.
Name % Fire
hazard
Sudden
release of
pressure
Reactive Immediate
(acute)
health
hazard
Delayed
(chronic)
health
hazard
Composition/information on ingredients
Date of issue/Date of revision :1/8/2019 Date of previous issue :3/13/2016 Version:1.02 12/14
Crestomer 1152 PA Drum
Section 15. Regulatory information
WARNING: This product contains a chemical known to the State of California to cause cancer.
styrene Yes. No. – –
sulphuric acid Yes. No. – –
1,4-naphthoquinone Yes. No. – –
Ingredient name Cancer Reproductive No significant risk
level
Maximum
acceptable dosage
level
California Prop. 65
New Jersey :The following components are listed: STYRENE MONOMER; BENZENE, ETHENYL-;
2-HYDROXYETHYL ACRYLATE; 2-PROPENOIC ACID, 2-HYDROXYETHYL ESTER;
COBALT compounds
Pennsylvania :The following components are listed: BENZENE, ETHENYL-; 2-PROPENOIC ACID,
2-HYDROXYETHYL ESTER; COBALT COMPOUNDS
International regulations
Montreal Protocol (Annexes A, B, C, E)
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
International lists
National inventoryNot determined
Section 16. Other information
Hazardous Material Information System (U.S.A.)
3
3
0
0
3
2
*
National Fire Protection Association (U.S.A.)
Health
Special
Instability/Reactivity
Flammability
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS
ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS
Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual.
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Date of issue/Date of revision :1/8/2019 Date of previous issue :3/13/2016 Version:1.02 13/14
Crestomer 1152 PA Drum
Section 16. Other information
1/8/2019
History
Date of printing
Date of issue/Date of
revision
Version
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Notice to reader
Date of previous issue
:
:
:
:
Indicates information that has changed from previously issued version.
References :Not available.
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. (“Marpol” = marine pollution)
UN = United Nations
1/8/2019
3/13/2016
1.02
Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Date of issue/Date of revision :1/8/2019 Date of previous issue :3/13/2016 Version:1.02 14/14
