by | Sep 27, 2025
CREAM HARDENER
BLUE
Not available.
Liquid.
(888) 345-5732
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Emergency telephone
number of the company
Section 1. Identification
:
:
:
:
Manufacturer :U.S. CHEMICAL & PLASTICS
600 Nova Dr. S.E.
Massillon, OH 44646
USA
Relevant identified uses of the substance or mixture and uses advised against
Paint or paint related material.
27160
27160Product code :
Product Information
Telephone Number
:(330) 830-6000
Transportation Emergency
Telephone Number
:(800) 424-9300
Section 2. Hazards identification
ORGANIC PEROXIDES – Type E
SKIN CORROSION/IRRITATION – Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION – Category 2A
SKIN SENSITIZATION – Category 1
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) – Category 2
Classification of the
substance or mixture
:
Signal word :Warning
Hazard pictograms :
Precautionary statements
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 1%
(oral), 57% (dermal), 57% (inhalation)
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Heating may cause a fire.
Causes skin irritation.
May cause an allergic skin reaction.
Causes serious eye irritation.
May cause damage to organs through prolonged or repeated exposure. (lungs)
:Hazard statements
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Section 2. Hazards identification
Prevention :Wear protective gloves, protective clothing and eye or face protection. Keep away from
heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep
away from clothing and other combustible materials. Keep only in original packaging.
Do not breathe vapor. Wash thoroughly after handling. Contaminated work clothing
must not be allowed out of the workplace.
Response :Get medical advice or attention if you feel unwell. Take off contaminated clothing and
wash it before reuse. Wash contaminated clothing before reuse. IF ON SKIN: Wash
with plenty of water. If skin irritation or rash occurs: Get medical advice or attention. IF
IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or
attention.
Storage :Protect from sunlight. Store at temperatures not exceeding 25 C/77 F. Keep cool.
Store separately.
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise
classified
:None known.
Please refer to the SDS for additional information. Keep out of reach of children. Do not
transfer contents to other containers for storage.
Supplemental label
elements
FOR PROFESSIONAL USE ONLY. This product must be mixed with other components
before use. Before opening the packages, READ AND FOLLOW WARNING LABELS
ON ALL COMPONENTS.
:
Section 3. Composition/information on ingredients
Dibenzoyl peroxide 50 – 75 94-36-0
Zinc Stearate 10 557-05-1
Calcium Sulfate 5 7778-18-9
Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-, hydrolysis products with silica 3 68909-20-6
Iron Blue 3 14038-43-8
Ingredient name CAS number% by weight
Other means of
identification
:Not available.
Substance/mixture
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified and hence require reporting in this section.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention following exposure or if
feeling unwell. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt
or waistband. In case of inhalation of decomposition products in a fire, symptoms may
Section 4. First aid measures
Eye contact
Inhalation :
:
Description of necessary first aid measures
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Section 4. First aid measures
Wash out mouth with water. Remove dentures if any. If material has been swallowed
and the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention following
exposure or if feeling unwell. Never give anything by mouth to an unconscious person.
If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Get medical attention. In the event of any
complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean
shoes thoroughly before reuse.
be delayed. The exposed person may need to be kept under medical surveillance for
48 hours.
Skin contact
Ingestion :
:
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Notes to physician :In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
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Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
nitrogen oxides
sulfur oxides
metal oxide/oxides
Runoff to sewer may create fire or explosion hazard. This material increases the risk of
fire and may aid combustion. Heating may cause a fire. May re-ignite itself after fire is
extinguished. Hazardous decomposition may occur. In a fire or if heated, a pressure
increase will occur and the container may burst.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
:
:
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Avoid contamination with reactive
substances. Do not absorb in sawdust or other combustible material. It may lead to a
fire risk when it dries out. Wash spillages into an effluent treatment plant or proceed as
follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand,
earth, vermiculite or diatomaceous earth and place in container for disposal according
to local regulations (see Section 13). Dispose of via a licensed waste disposal
contractor. Contaminated absorbent material may pose the same hazard as the spilled
product. Note: see Section 1 for emergency contact information and Section 13 for
waste disposal.
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Avoid contamination with reactive substances. Dilute with
water and mop up if water-soluble. Do not absorb in sawdust or other combustible
material. It may lead to a fire risk when it dries out. Alternatively, or if water-insoluble,
absorb with an inert dry material and place in an appropriate waste disposal container.
Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in “For non-
emergency personnel”.
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Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
To avoid the risk of formation of shock-sensitive crystals or loss of stability, it is
important to store the product within the recommended temperature range.
Temperature control may be required. Store in accordance with local regulations. Store
in a segregated and approved area. Store in original container protected from direct
sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see
Section 10) and food and drink. Store at temperatures not exceeding 25 C/77 F.
Eliminate all ignition sources. Separate from reducing agents and combustible
materials. Keep away from rust, iron and copper. Keep container tightly closed and
sealed until ready for use. Prevent product contamination. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental
contamination. See Section 10 for incompatible materials before handling or use.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Do not get in eyes or on skin or clothing. Do not breathe vapor or
mist. Do not ingest. Use only with adequate ventilation. Do not enter storage areas
and confined spaces unless adequately ventilated. Keep in the original container or an
approved alternative made from a compatible material, kept tightly closed when not in
use. Store and use away from heat, sparks, open flame or any other ignition source.
Use explosion-proof electrical (ventilating, lighting and material handling) equipment.
Use only non-sparking tools. Keep away from clothing, incompatible materials and
combustible materials. Temperature control may be required. Empty containers retain
product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
Dibenzoyl peroxide 94-36-0 ACGIH TLV (United States, 1/2024).
TWA: 5 mg/m 8 hours.
NIOSH REL (United States, 10/2020).
TWA: 5 mg/m 10 hours.
OSHA PEL (United States, 5/2018).
TWA: 5 mg/m 8 hours.
Zinc Stearate 557-05-1 ACGIH TLV (United States, 1/2024).
[Stearates]
TWA: 10 mg/m 8 hours. Form: Inhalable
fraction
TWA: 3 mg/m 8 hours. Form: Respirable
fraction
NIOSH REL (United States, 10/2020).
TWA: 5 mg/m 10 hours. Form: Respirable
fraction
TWA: 10 mg/m 10 hours. Form: Total
OSHA PEL (United States, 5/2018).
TWA: 5 mg/m 8 hours. Form: Respirable
fraction
TWA: 15 mg/m 8 hours. Form: Total dust
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits (OSHA United States)
CAS #
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Section 8. Exposure controls/personal protection
Calcium Sulfate 7778-18-9 ACGIH TLV (United States, 1/2024).
[Calcium sulfate]
TWA: 10 mg/m 8 hours. Form: Inhalable
fraction
NIOSH REL (United States, 10/2020).
TWA: 5 mg/m 10 hours. Form: Respirable
fraction
TWA: 10 mg/m 10 hours. Form: Total
OSHA PEL (United States, 5/2018).
TWA: 5 mg/m 8 hours. Form: Respirable
fraction
TWA: 15 mg/m 8 hours. Form: Total dust
Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-,
hydrolysis products with silica
68909-20-6 None.
Iron Blue 14038-43-8 ACGIH TLV (United States, 1/2024). [Iron
salts, soluble]
TWA: 1 mg/m , (as Fe) 8 hours.
NIOSH REL (United States, 10/2020). [iron
salts]
TWA: 1 mg/m , (as Fe) 10 hours.
OSHA PEL (United States, 5/2018).
[Cyanides] Absorbed through skin.
TWA: 5 mg/m , (as CN) 8 hours.
Dibenzoyl peroxide 94-36-0 CA Alberta Provincial (Canada, 3/2023).
OEL: 5 mg/m 8 hours.
CA British Columbia Provincial (Canada,
8/2023).
TWA: 5 mg/m 8 hours.
CA Ontario Provincial (Canada, 6/2019).
TWA: 5 mg/m 8 hours.
CA Quebec Provincial (Canada, 2/2024).
TWAEV: 5 mg/m 8 hours.
CA Saskatchewan Provincial (Canada,
4/2021).
STEL: 10 mg/m 15 minutes.
TWA: 5 mg/m 8 hours.
Ingredient name Exposure limits
Occupational exposure limits (Canada)
Dibenzoyl peroxide 94-36-0 NOM-010-STPS-2014 (Mexico, 4/2016).
TWA: 5 mg/m 8 hours.
Exposure limits
Occupational exposure limits (Mexico)
CAS #
CAS #
Biological exposure indices (United States)
No exposure indices known.
Biological exposure indices (Canada)
Biological exposure indices (Mexico)
No exposure indices known.
No exposure indices known.
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Section 8. Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
:
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use process enclosures, local exhaust ventilation or other engineering controls to keep
worker exposure to airborne contaminants below any recommended or statutory limits.
The engineering controls also need to keep gas, vapor or dust concentrations below any
lower explosive limits. Use explosion-proof ventilation equipment. Use with adequate
ventilation.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Environmental exposure
controls
:
Section 9. Physical and chemical properties
Physical state
Melting point/freezing point
Liquid.
Not available.
Not available.Odor
pH
Blue.Color
Evaporation rate 0.09 (butyl acetate = 1)
Flash point Closed cup: 94 C (201.2 F) [Pensky-Martens Closed Cup]
Not applicable.
Not available.Odor threshold
:
:
:
:
:
:
:
:
Appearance
:100 C (212 F)Boiling point, initial boiling
point, and boiling range
The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.
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Section 9. Physical and chemical properties
Vapor pressure
Relative density 1.19
1 [Air = 1]
Auto-ignition temperature Not available.
Not applicable.
Viscosity Kinematic (40 C (104 F)): >20.5 mm
2
/s (>20.5 cSt)
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:Not available.
:Not available.
SADT 50 C (122 F):
Decomposition temperature:Not available.
Heat of combustion :21.85 kJ/g
Molecular weight :Not applicable.
Flammability
Lower and upper explosion
limit/flammability limit
Relative vapor density
2.3 kPa (17.5 mm Hg)
Solubility(ies) :
Media Result
cold water Partially soluble
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Avoid
increased storage temperature. Drying on clothing or other combustible materials may
cause fire.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
combustible materials
reducing materials
copper
iron
rust
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Hazardous reactions or instability may occur under certain conditions of storage or use.
Conditions may include the following:
temperature increase
high temperature
Reactions may include the following:
hazardous decomposition
risk of causing fire
Reactivity :This product, in laboratory testing, neither detonates nor deflagrates and only shows low
or no effect when heated under confinement.
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Section 11. Toxicological information
Acute toxicity
Dibenzoyl peroxide LD50 Oral Rat 6400 mg/kg –
Zinc Stearate LD50 Oral Rat >10 g/kg –
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
Dibenzoyl peroxide Eyes – Mild irritant Rabbit – 24 hours 500
mg
–
Skin – Moderate irritantWoman – 1 % –
Skin – Severe irritantHuman – 1344 hours 5
% I
–
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Not available.
Name Category
Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-, hydrolysis
products with silica
Category 2 inhalation lungs
Aspiration hazard
Not available.
Route of
exposure
Target organs
Information on toxicological effects
Classification
Dibenzoyl peroxide – 3 –
Product/ingredient name NTPIARCOSHA
Information on the likely
routes of exposure
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
:Not available.
Potential acute health effects
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Section 11. Toxicological information
Not available.
May cause damage to organs through prolonged or repeated exposure. Once
sensitized, a severe allergic reaction may occur when subsequently exposed to very low
levels.
General :
No known significant effects or critical hazards.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Not available.
Acute toxicity estimates
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
Section 12. Ecological information
Toxicity
Dibenzoyl peroxide EC10 0.001 mg/l Daphnia 21 days
EC50 0.0711 mg/l Algae 72 hours
Acute EC50 0.11 mg/l Daphnia 48 hours
Calcium Sulfate Acute LC50 >1910 mg/l Fresh water Crustaceans – Ceriodaphnia
dubia
48 hours
Acute LC50 >1970 mg/l Fresh water Daphnia – Daphnia magna 48 hours
Acute LC50 2980 ppm Fresh water Fish – Lepomis macrochirus 96 hours
Chronic NOEC 360 mg/l Fresh water Daphnia – Daphnia magna –
Neonate
3 weeks
Product/ingredient name SpeciesResult Exposure
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Section 12. Ecological information
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Not available.
Product/ingredient name Aquatic half-life Photolysis Biodegradability
Dibenzoyl peroxide – – Inherent
Chronic NOEC 233 mg/l Fresh water Fish – Coregonus albula – Egg 60 days
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Do not cut, weld or grind used containers unless they have been cleaned thoroughly
internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways,
drains and sewers.
:Disposal methods
Section 14. Transport information
ORGANIC
PEROXIDE TYPE
E, SOLID
(Dibenzoyl
peroxide)
5.2
–
ORGANIC
PEROXIDE TYPE
E, SOLID
(Dibenzoyl
peroxide). Marine
pollutant
(Dibenzoyl
peroxide, Zinc
Stearate)
5.2
–
UN3108 UN3108
DOT
Classification
IMDG
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
TDG
Classification
UN3108
ORGANIC
PEROXIDE TYPE
E, SOLID
(Dibenzoyl
peroxide)
5.2
–
Mexico
Classification
UN3108
ORGANIC
PEROXIDE TYPE
E, SOLID
(Dibenzoyl
peroxide)
5.2
–
IATA
UN3108
ORGANIC
PEROXIDE
TYPE E, SOLID
(Dibenzoyl
peroxide)
5.2
–
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Section 14. Transport information
– The marine
pollutant mark is
not required when
transported in
sizes of 5 L or 5
kg.
Emergency
schedules F-J, S-
R
Additional
information
Environmental
hazards
Special precautions for user
Transport in bulk according
to IMO instruments
No. Yes.
Not available.
:
Proper shipping name :
Not available.
:
No.
Product classified
as per the
following sections
of the
Transportation of
Dangerous Goods
Regulations:
2.23-2.25 (Class
5).
No.
–
Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability prior
to shipment, and compliance with the applicable regulations is the sole responsibility
of the person offering the product for transport. People loading and unloading
dangerous goods must be trained on all of the risks deriving from the substances
and on all actions in case of emergency situations.
Yes. The
environmentally
hazardous
substance mark
is not required.
The
environmentally
hazardous
substance mark
may appear if
required by other
transportation
regulations.
145
ERG No.
145 145
ERG No. ERG No.
Section 15. Regulatory information
All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED
and rely on information provided to us by our raw material suppliers. Our suppliers often provide an estimated value or
range less than a certain upper limit. We calculate MAXIMUM THEORETICAL VALUES using defined values, if provided,
or the upper limit reported by our supplier. Additionally, the suppliers information may include amounts present in the
product as unintentional byproducts or impurities. Variations may occur in individual batches due to adjustments made
during production. Reporting of chemicals in this section does not necessarily indicate their presence in the final
formulated product.
Not applicable.
California Prop. 65
International regulations
Montreal Protocol
Not listed.
Dibenzoyl peroxide 50 94-36-0
Zinc Compound 6
Ingredient name CAS number% by weight
SARA 313
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Section 15. Regulatory information
Australia inventory (AIIC): Not determined.
China inventory (IECSC): Not determined.
Japan inventory (CSCL): Not determined.
Japan inventory (ISHL): Not determined.
Korea inventory (KECI): Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
Taiwan Chemical Substances Inventory (TCSI): Not determined.
Thailand inventory: Not determined.
Turkey inventory: Not determined.
Vietnam inventory: Not determined.
International lists :
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Section 16. Other information
1/15/2025
History
Date of printing
Date of issue/Date of
revision
Version
Date of previous issue
:
:
:
:
Key to abbreviations :
1/15/2025
12/14/2024
14.01
Hazardous Material Information System (U.S.A.)
2
0
4
*
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS
ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS
Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual.
ORGANIC PEROXIDES – Type E Expert judgment
SKIN CORROSION/IRRITATION – Category 2 Calculation method
SERIOUS EYE DAMAGE/ EYE IRRITATION – Category 2A Calculation method
SKIN SENSITIZATION – Category 1 Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) – Category 2 Calculation method
Procedure used to derive the classification
Classification Justification
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. (“Marpol” = marine pollution)
N/A = Not available
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Section 16. Other information
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer,
or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements
are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is
responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The
conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is
responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user
should not use the product for any purpose other than the purpose shown in the applicable section of this SDS
without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of
sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs
obtained from any other source.
Indicates information that has changed from previously issued version.
Notice to reader
SGG = Segregation Group
UN = United Nations
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1 Identification
Product identifier
Trade name: XTEND CX-500
Application of the substance / the mixtureIndustrial cleaner
Details of the supplier of the safety data sheet
Manufacturer/Supplier:
Axel Plastics Research Laboratories, Inc.
50 Cambridge Drive
Monroe, CT 06468 USA
info@axelplastics.com
Information department:Product safety department
Emergency telephone number:
USA and Canada: 1-800-424-9300 (24 hours)
Outside of USA and Canada: 001-703-527-3887 (24 hours)
2 Hazard(s) identification
Classification of the substance or mixture
GHS02 Flame
Flam. Liq. 2 H225 Highly flammable liquid and vapor.
GHS08 Health hazard
Repr. 2 H361 Suspected of damaging fertility or the unborn child.
STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure.
Asp. Tox. 1 H304 May be fatal if swallowed and enters airways.
GHS07
Acute Tox. 4 H332 Harmful if inhaled.
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
STOT SE 3 H336 May cause drowsiness or dizziness.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS02GHS07GHS08
Signal wordDanger
Hazard-determining components of labeling:
xylene
toluene
butanone
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Hazard statements
Highly flammable liquid and vapor.
Harmful if inhaled.
Causes skin irritation.
Causes serious eye irritation.
Suspected of damaging fertility or the unborn child.
May cause drowsiness or dizziness.
May cause damage to organs through prolonged or repeated exposure.
May be fatal if swallowed and enters airways.
Precautionary statements
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Keep away from heat/sparks/open flames/hot surfaces. – No smoking.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting/equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Do not breathe dust/fume/gas/mist/vapors/spray.
Wash thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Wear protective gloves/protective clothing/eye protection/face protection.
If swallowed: Immediately call a poison center/doctor.
Specific treatment (see on this label).
Do NOT induce vomiting.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF exposed or concerned: Get medical advice/attention.
Call a poison center/doctor if you feel unwell.
Get medical advice/attention if you feel unwell.
Take off contaminated clothing and wash it before reuse.
If skin irritation occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
In case of fire: Use for extinction: CO2, powder or water spray.
Store in a well-ventilated place. Keep container tightly closed.
Store in a well-ventilated place. Keep cool.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
1
3
0
Health = 1
Fire = 3
Reactivity = 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
*1
3
0
Health = *1
Fire = 3
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
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vPvB:Not applicable.
3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Component Information:
78-93-3 butanone 25 50%
108-88-3 toluene 25 50%
1330-20-7 xylene 25 50%
4 First-aid measures
Description of first aid measures
General information:
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
After inhalation:
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing:If symptoms persist consult doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
For safety reasons unsuitable extinguishing agents:Water with full jet
Special hazards arising from the substance or mixture
During heating or in case of fire poisonous gases are produced.
Advice for firefighters
Protective equipment:Mouth respiratory protective device.
6 Accidental release measures
Personal precautions, protective equipment and emergency procedures
Mount respiratory protective device.
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep
unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Do not
breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate.
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Put on appropriate personal protective equipment.
Environmental precautions:
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the
relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Small spill: Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-
soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Large spill: Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent
entry into sewers, water courses, basements or confined areas. Wash spillage into an effluent treatment plant or
proceed as follow. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth,
vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section
13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same
hazard as the spilled product. Note: See Section 1 for emergency contact information and Section 13 for waste
disposal.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
7 Handling and storage
Handling:
Precautions for safe handling
Store in cool, dry place in tightly closed receptacles.
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Prevent formation of aerosols.
Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid contact with eyes, skin and
clothing. Avoid breathing vapor or mist. Avoid release to the environment. Use only with adequate ventilation.
Wear appropriate respirator when ventilation is inadequate. Keep in the original container or an approved
alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product
residue and can be hazardous. Do not reuse container.
Information about protection against explosions and fires:
Keep ignition sources away – Do not smoke.
Protect against electrostatic charges.
Keep respiratory protective device available.
Conditions for safe storage, including any incompatibilities
Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool
and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Avoid freezing.
Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to
avoid environmental contamination.
Storage:
Requirements to be met by storerooms and receptacles:Store in a cool location.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:
Keep receptacle tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
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Specific end use(s)No further relevant information available.
8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
78-93-3 butanone
PEL Long-term value: 590 mg/m , 200 ppm
REL Short-term value: 885 mg/m , 300 ppm
Long-term value: 590 mg/m , 200 ppm
TLV Short-term value: 885 mg/m , 300 ppm
Long-term value: 590 mg/m , 200 ppm
BEI
108-88-3 toluene
PEL Long-term value: 200 ppm
Ceiling limit value: 300; 500* ppm
*10-min peak per 8-hr shift
REL Short-term value: 560 mg/m , 150 ppm
Long-term value: 375 mg/m , 100 ppm
TLV Long-term value: 75 mg/m , 20 ppm
BEI
1330-20-7 xylene
PEL Long-term value: 435 mg/m , 100 ppm
REL Short-term value: 655 mg/m , 150 ppm
Long-term value: 435 mg/m , 100 ppm
TLV Short-term value: 651 mg/m , 150 ppm
Long-term value: 434 mg/m , 100 ppm
BEI
Ingredients with biological limit values:
78-93-3 butanone
BEI 2 mg/L
Medium: urine
Time: end of shift
Parameter: MEK
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108-88-3 toluene
BEI 0.02 mg/L
Medium: blood
Time: prior to last shift of workweek
Parameter: Toluene
0.03 mg/L
Medium: urine
Time: end of shift
Parameter: Toluene
0.3 mg/g creatinine
Medium: urine
Time: end of shift
Parameter: o-Cresol with hydrolysis (background)
1330-20-7 xylene
BEI 1.5 g/g creatinine
Medium: urine
Time: end of shift
Parameter: Methylhippuric acids
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes and skin.
Breathing equipment:
If a risk assessment indicates engineering controls are not sufficient to protect worker health or comply with
relevant legislation, use an approved respirator. Respirator selection must be based on known or anticipated
exposure levels, the hazards of the product and the safe working limits of the selected respirator. Respirators to be
considered for this material include: Half-face filter respirator with Type A filter material.
For the European Union, refer to Standardization (CEN) standards EN 136, 140 and 405 for respirator masks and
EN 149 and 143 for filter recommendations. In the United States of America, refer to OSHA Respiratory
Protection Standard, 29 CFR 1910.134 and ANSI Z88.2 for respiratory selection, use and maintenance.
Protection of hands:
Use of a strong chemical resistant glove is recommended.
Hand Protection: Glove suitability depends on the conditions of use. Use gauntlet style gloves if
forearms are likely to be exposed. Contact glove manufacturer for appropriate glove selection. Skin
Protection: Chemical/oil resistant and flame retardant protective clothing is recommended.
The gloves listed below may provide protection against permeation. Gloves of other chemically resistant materials
may not provide adequate protection. Protective gloves are recommended to protect against contact with product.
Polyvinyl alcohol, Viton, Safety 4H, Teflon. When splashing is possible, full chemically resistant protective
clothing and boots are required. The following materials are acceptable for use as protective clothing: Polyvinyl
alcohol (PVA), Viton, Teflon. Facilities storing or utilizing this material should be equipped with an eyewash
facility and a safety shower. Remove contaminated clothing and wash before reuse. For non-fire emergencies,
positive pressure SCBA and structural firefighter’s protective clothing will provide only limited protection.
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
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Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Chemical safety glasses with side shields, goggles or face shield.
Body protection:Protective work clothing
* 9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Fluid
Color: Clear
Odor: Characteristic
Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 80 – 140 C
Flash Point (C.O.C.): < 23 C (< 73.4 F)
Percentage Volatile 100 %
Decomposition temperature: Not determined.
Auto igniting: Product is not selfigniting.
Danger of explosion: Product is not explosive. However, formation of explosive air/vapor
mixtures are possible.
Explosion limits:
Lower: Not determined.
Upper: Not determined.
Oxidizing properties Not determined.
Vapor pressure at 20 C (68 F):105 hPa (78.8 mm Hg)
Density: Not determined.
Relative density 0.840
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water):Not determined.
Viscosity: < 15 cps @ 25C
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Dynamic: Not determined.
Kinematic: Not determined.
VOC content: Not determined.
Other information No further relevant information available.
10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stabilityThe product is stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:No dangerous decomposition products known.
11 Toxicological information
Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
ATE (Acute Toxicity Estimate)
Oral LD50 3,984 mg/kg (rat)
Dermal LD50 4,348 mg/kg (rabbit)
Inhalative LC50/4 h 36.7 mg/l
108-88-3 toluene
Oral LD50 5,000 mg/kg (rat)
Dermal LD50 12,124 mg/kg (rabbit)
Inhalative LC50/4 h 5,320 mg/l (mouse)
1330-20-7 xylene
Oral LD50 4,300 mg/kg (rat)
Dermal LD50 2,000 mg/kg (rabbit)
Inhalative LC50/4 h 11 mg/l (ATE)
Primary irritant effect:
on the skin:Irritant to skin and mucous membranes.
on the eye:Irritating effect.
Sensitization:No sensitizing effects known.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Harmful
Irritant
Carcinogenic categories
IARC (International Agency for Research on Cancer)
108-88-3 toluene 3
1330-20-7 xylene 3
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NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
IARC Monographs
Group 1: Carcinogenic to humans
Group 2A: Probably carcinogenic to humans
Group 2B: Possibly carcinogenic to humans
Group 3: Not classifiable as to its carcinogenicity to humans
Group 4: Probably not carcinogenic to humans
12 Ecological information
Toxicity
Aquatic toxicity:No further relevant information available.
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Additional ecological information:
General notes:
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions
and any by-products should at all times comply with the requirements of environmental protection and waste
disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully
compliant with the requirements of all authorities with jurisdiction.
The classification of the product may meet the criteria for a hazardous waste.
Uncleaned packagings:
Recommendation:
The generation of waste should be avoided or minimized wherever possible. Waste packaging should be recycled.
Incineration or landfill should only be considered when recycling is not feasible.
This material and its container must be disposed of in a safe way. Care should be taken when handling emptied
containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
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14 Transport information
UN-Number
DOT, IMDG, IATA UN1993
UN proper shipping name
DOT Flammable liquids, n.o.s. (Ethyl methyl ketone, Toluene)
IMDG, IATA FLAMMABLE LIQUID, N.O.S. (ETHYL METHYL KETONE
(METHYL ETHYL KETONE), TOLUENE)
Transport hazard class(es)
DOT
Class 3 Flammable liquids
Label 3
IMDG, IATA
Class 3 Flammable liquids
Label 3
Packing group
DOT, IMDG, IATA II
Environmental hazards: Not applicable.
Special precautions for user Warning: Flammable liquids
Danger code (Kemler): 33
EMS Number: F-E,S-E
Stowage Category B
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
Transport/Additional information:
DOT
Quantity limitations On passenger aircraft/rail: 5 L
On cargo aircraft only: 60 L
IMDG
Limited quantities (LQ) 1L
Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 500 ml
UN "Model Regulation": UN 1993 FLAMMABLE LIQUIDS, N.O.S. (ETHYL METHYL
KETONE, TOLUENE), 3, II
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15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 313 (Specific toxic chemical listings):
All ingredients are listed.
TSCA (Toxic Substances Control Act) (Substances not listed):
All ingredients are listed.
Proposition 65
Chemicals known to cause cancer:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
108-88-3 toluene
US State Regulations
Connecticut - Hazardous Air Pollutants - HLVs (30 min)
None of the ingredients is listed.
Connecticut - Hazardous Air Pollutants - HLVs (8 hr)
None of the ingredients is listed.
Idaho - Non-Carcinogenic Toxic Air Pollutants - Emission Levels (ELs)
None of the ingredients is listed.
Idaho - Non-Carcinogenic Toxic Air Pollutants - Acceptable Ambient Concentrations
None of the ingredients is listed.
Occupational Exposure Limits - TWAs
None of the ingredients is listed.
Michigan - Occupational Exposure Limits - Skin Designations
None of the ingredients is listed.
Michigan - Occupational Exposure Limits - TWAs
None of the ingredients is listed.
Minnesota - Hazardous Substance List
None of the ingredients is listed.
Minnesota - Permissible Exposure Limits - Skin Designations
None of the ingredients is listed.
Minnesota - Permissible Exposure Limits - TWAs
None of the ingredients is listed.
New Hampshire - Regulated Toxic Air Pollutants - Ambient Air Levels (AALs) - 24-Hour
None of the ingredients is listed.
New Hampshire - Regulated Toxic Air Pollutants - Ambient Air Levels (AALs) - Annual
None of the ingredients is listed.
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New York - Occupational Exposure Limits - Skin Designations
None of the ingredients is listed.
New York - Occupational Exposure Limits - TWAs
None of the ingredients is listed.
North Dakota - Air Pollutants - Guideline Concentrations - 1-Hour
None of the ingredients is listed.
North Dakota - Air Pollutants - Guideline Concentrations - 8-Hour
None of the ingredients is listed.
Oregon - Permissible Exposure Limits - TWAs
None of the ingredients is listed.
Tennessee - Occupational Exposure Limits - Skin Designations
None of the ingredients is listed.
Tennessee - Occupational Exposure Limits - TWAs
None of the ingredients is listed.
Texas - Effects Screening Levels - Long Term
None of the ingredients is listed.
Texas - Effects Screening Levels - Short Term
None of the ingredients is listed.
Vermont - Permissible Exposure Limits - Skin Designations
None of the ingredients is listed.
Vermont - Permissible Exposure Limits - TWAs
None of the ingredients is listed.
Washington - Permissible Exposure Limits - Skin Designations
None of the ingredients is listed.
Washington - Permissible Exposure Limits - STELs
None of the ingredients is listed.
Washington - Permissible Exposure Limits - TWAs
None of the ingredients is listed.
Wisconsin - Hazardous Air Contaminants - All Sources - Emissions From Stack Heights 25 Feet to Less
Than 40 Feet
None of the ingredients is listed.
Wisconsin - Hazardous Air Contaminants - All Sources - Emissions From Stack Heights 40 Feet to Less
Than 75 Feet
None of the ingredients is listed.
Wisconsin - Hazardous Air Contaminants - All Sources - Emissions From Stack Heights 75 Feet or Greater
None of the ingredients is listed.
Wisconsin - Hazardous Air Contaminants - All Sources - Emissions From Stack Heights Less Than 25 Feet
None of the ingredients is listed.
Carcinogenic categories
EPA (Environmental Protection Agency)
78-93-3 butanone I
108-88-3 toluene II
1330-20-7 xylene I
(Contd. on page 13)
US
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Safety Data Sheet
acc. to OSHA HCS
Printing date 08/28/2018 Reviewed on 08/28/2018
Trade name: XTEND CX-500
(Contd. of page 12)
47.0.17
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
EPA Carcinogen Category Key
EPA 2005 Guidelines:
CaH - Carcinogenic to humans.
L - Likely to be carcinogenic to humans.
SC - Suggestive evidence of carcinogenic potential.
II - Inadequate information to assess carcinogenic potential.
NL - Not likely to be carcinogenic to humans.
EPA 1999 Guidelines:
CaH - Carcinogenic to humans.
L - Likely to be carcinogenic to humans.
S - Suggestive evidence of carcinogenicity, but not sufficient to assess human carcinogenic potential.
I - Data are inadequate for an assessment of human carcinogenic potential.
NL - Not likely to be carcinogenic to humans.
EPA 1996 Guidelines:
K/L - Known/likely human carcinogen.
CBD - Carcinogenic potential cannot be determined.
NL - Not likely to be carcinogenic to humans.
EPA 1986 Guidelines:
A - Human carcinogen
B1 - Probable human carcinogen - based on limited evidence of carcinogenicity in humans and sufficient evidence
of carcinogenicity in animals.
B2 - Probable human carcinogen - based on sufficient evidence of carcinogenicity in animals.
C - Possible human carcinogen.
D - Not classifiable as to human carcinogenicity.
E - Evidence of non-carcinogenicity for humans.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS02GHS07GHS08
Signal wordDanger
Hazard-determining components of labeling:
xylene
toluene
butanone
Hazard statements
Highly flammable liquid and vapor.
Harmful if inhaled.
Causes skin irritation.
Causes serious eye irritation.
Suspected of damaging fertility or the unborn child.
May cause drowsiness or dizziness.
May cause damage to organs through prolonged or repeated exposure.
May be fatal if swallowed and enters airways.
(Contd. on page 14)
US
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Safety Data Sheet
acc. to OSHA HCS
Printing date 08/28/2018 Reviewed on 08/28/2018
Trade name: XTEND CX-500
(Contd. of page 13)
47.0.17
Precautionary statements
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting/equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Do not breathe dust/fume/gas/mist/vapors/spray.
Wash thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Wear protective gloves/protective clothing/eye protection/face protection.
If swallowed: Immediately call a poison center/doctor.
Specific treatment (see on this label).
Do NOT induce vomiting.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF exposed or concerned: Get medical advice/attention.
Call a poison center/doctor if you feel unwell.
Get medical advice/attention if you feel unwell.
Take off contaminated clothing and wash it before reuse.
If skin irritation occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
In case of fire: Use for extinction: CO2, powder or water spray.
Store in a well-ventilated place. Keep container tightly closed.
Store in a well-ventilated place. Keep cool.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
National regulations:
The components of this product are listed on the USA (TSCA) inventory.
The components of this product are listed on the Canadian (DSL) inventory.
The components of this product are listed on the European (EINECS) inventory.
The components of this product are listed on the Australia (AICS) inventory.
The components of this product are listed on the Japan (ENCS) inventory.
The components of this product are listed on the South Korean (KECI) inventory.
The components of this product are listed on the Chinese (IECSC) inventory.
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
Disclaimer: This data is offered in good faith as typical values and not as a product specification. No warranty,
either expressed or implied, is hereby made. The recommended industrial hygiene and safe handling procedures
are believed to be generally applicable. However, each user should review recommendations in the specific context
of the intended use and determine whether they are appropriate.
Procedure used to derive the classification
Calculation method.
Test data.
Contact:info@axelplastics.com
Date of preparation / last revision08/28/2018 / 10
Abbreviations and acronyms:
ADR: Accord europ en sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage
of Dangerous Goods by Road)
(Contd. on page 15)
US
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Safety Data Sheet
acc. to OSHA HCS
Printing date 08/28/2018 Reviewed on 08/28/2018
Trade name: XTEND CX-500
(Contd. of page 14)
47.0.17
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
BEI: Biological Exposure Limit
Flam. Liq. 2: Flammable liquids Category 2
Acute Tox. 4: Acute toxicity Category 4
Skin Irrit. 2: Skin corrosion/irritation Category 2
Eye Irrit. 2A: Serious eye damage/eye irritation Category 2A
Repr. 2: Reproductive toxicity Category 2
STOT SE 3: Specific target organ toxicity (single exposure) Category 3
STOT RE 2: Specific target organ toxicity (repeated exposure) Category 2
Asp. Tox. 1: Aspiration hazard Category 1
* Data compared to the previous version altered.
US
by | Sep 27, 2025
by | Sep 27, 2025
MSDS
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Print Date: 10/14/2013
Page 1 of 5
SECTION 1 Chemical Product and Company Identification
QUEST AUTOMOTIVE PRODUCTS For Chemical Emergency:
600 Nova Drive SE CHEMTREC: 1-800-424-9300
Massillon, OH 44646
PH 330-830-6000 – FAX 330-830-6005
PRODUCT NAME: U.S. Chemical & Plastics Icing Lite
PRODUCT CODE: (26043), 26012
SYNONYM/CROSS REFERENCE: Purable/Brushable Polyester Finishing Putty
SCHEDULE B NUMBER: 3014.10.0090
SECTION 2 Hazard Identification
OVEREXPOSURE EFFECTS:
ACUTE EFFECTS:
EYES: Contact with eyes can cause irritation, redness, tearing, blurred vision, and/or swelling.
SKIN: Contact with skin can cause irritation, (minor itching, burning and/or redness), Dermatitis,
defatting may be readily absorbed through the skin.
INHALATION: Inhalation of vapors can cause nasal and respiratory irritation, dizziness, weakness,
fatigue, nausea, headache, possible unconsciousness and/or asphyxiation. Aspiration of material into lungs
may result in chemical pneumonitis which can be fatal.
INGESTION: Ingestion can cause gastrointestinal irritation, nausea, vomiting, diarrhea.
PRIMARY ROUTES OF EXPOSURE: skin, inhalation, eyes
SECTION 3 Composition, Information or Ingredients
INGREDIENTS WGT% CAS #
Styrene 20-30% 100-42-5
Non-fibrous Talc 10-20% 14807-96-6
Glass Beads 1-10% 65997-17-3
Titanium Dioxide 1-5% 13463-67-7
Calcium Carbonate 5-15% 1317-65-3, 471-34-1
SECTION 4 First Aid Measures
INHALATION: If inhaled, remove victim from exposure to a well-ventilated area. Make them comfortably
warm, but not hot. Use oxygen or artificial respiration as required. Consult a physician.
SKIN: For skin contact, wash promptly with soap and excess water.
EYES: For eye contact, flush promptly with excess water for at least fifteen minutes. Consult a physician.
INGESTION: If ingested, do not induce vomiting. Give victim a glass of water. Call a physician
immediately.
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SECTION 5 Fire-Fighting Measures
FLASH POINT: 89 F/31.7 C Seta Flash Closed cup
LOWER FLAMMABLE LIMIT %: N/E
UPPER FLAMMABLE LIMIT %: N/E
FIRE EXTINGUISHING MEDIA: Carbon Dioxide, Dry Chemical, Foam
SPECIAL FIRE FIGHTING PROCEDURES: Fight like a fuel oil fire. Cool fire exposed containers with
water spray. Firefighter should wear OSHA/NIOSH approved self-contained breathing apparatus.
UNUSUAL FIRE AND EXPLOSION HAZARD: Closed containers exposed to high temperatures, such as
fire conditions may rupture.
SECTION 6 Accidental Release Measures
SPILLS, LEAK OR RELEASE: Ventilate area. Remove all possible sources of ignition. Avoid prolonged
breathing of vapor. Contain spill with inert absorbent.
SECTION 7 Handling and Storage
STORAGE AND HANDLING: Use with adequate ventilation. Avoid contact with eyes and skin. Avoid
breathing vapors. Do not store the product above 100 F/38 C. Do not flame, cut, braze weld or melt empty
containers. Keep the product away from heat, open flame, and other sources of ignition. Avoid contact with
strong acids, alkalis, and oxidizers.
SECTION 8 Exposure Controls and Personal Protection
INGREDIENTS CAS # TLV/PEL
Styrene 100-42-5 ACGIH: TLV 20 ppm (skin), STEL 40 ppm (skin)
OSHA: PEL 100 ppm, CPEL 200 ppm
See Health Hazard Information
Non-fibrous Talc 14807-96-6 ACGIH: TWA 2 mg/m
3
, OSHA: TLV 30 mppcf
Glass Beads 65997-17-3 ACGIH: TWA 10 mg/m
3
Titanium Dioxide 13463-67-7 ACGIH: TLV 10 mg/m
3
, OSHA: TWA 15 mg/m
3
Calcium Carbonate 1317-65-3 ACGIH: TLV 10 mg/m
3
471-34-1
RESPIRATORY PROTECTION: If component TLV limits are exceeded, use NIOSH/MSHA approved
respirator to remove vapors. Use an air-supplied respirator if necessary.
VENTILATION: Use adequate ventilation in volume and pattern to keep TLV/PEL below recommended
levels. Explosion-proof ventilation may be necessary.
PROTECTIVE GLOVES: To prevent prolonged exposure use rubber gloves; solvents may be absorbed
through the skin.
EYE PROTECTION: Safety Glasses or goggles with splash guards or side shields.
OTHER PROTECTIVE EQUIPMENT: Wear protective clothing as required to prevent skin contact.
MSDS
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Print Date: 10/14/2013
Page 3 of 5
SECTION 9 Physical and Chemical Properties
APPEARANCE: Yellow smooth paste
SPECIFIC GRAVITY: 0.96
VAPOR PRESSURE (mmHG): Heavier than air
BOILING POINT: N/Av
VAPOR DENSITY: Heavier than air
EVAPORATION RATE (Ethyl Ether = 1): Slower than Ethyl Ether
VOLATILES BY WEIGHT: 281 less exempts
SOLUBILITY IN WATER: None
VOC: Grams/liter = 245 less exempts; Grams/liter = 2.2 unconsumed VOC upon curing
SECTION 10 Stability and Reactivity
STABILITY: Stable
CONDITIONS TO AVOID: Open flames, sparks, heat, electrical and static discharge.
INCOMPATIBILITY MATERIALS TO AVOID: Strong acids, alkalis, oxidizers.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Dioxide, Carbon Monoxide, and Carbon.
HAZARDOUS POLYMERIZATION: Will not occur.
SECTION 11 Toxicological Information
CHRONIC EFFECTS:
Overexposure to this material has apparently been known to cause the following effects in lab animals: Eye,
skin, lung, and central nervous system damage.
CARCINOGEN: YES __ NO X
TERATOGEN: YES __ NO X
MUTAGEN: YES __ NO X
STYRENE CARCINOGENICITY
Styrene is listed by IARC to be a possible carcinogen. Styrene studies have shown that Styrene causes cancer
in certain laboratory animals. However, there is insufficient evidence to conclude that Styrene is a human
carcinogen.
SECTION 12 Ecological Information
N/E
SECTION 13 Disposal Considerations
WASTE DISPOSAL: Dispose of in accordance with local, state, and federal regulations.
MSDS
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Page 4 of 5
SECTION 14 Transport Information
For Ground Transport: In USA
Consumer Commodity ORM-D or Limited Quantity with inner containers less than 1 gallon
For containers larger than 1 gallon:
UN1866, Resin Solution, 3, PGIII and Cream Hardener shipped separately
Consumer Commodity ORM-D or Limited Quantity
For Air Transport:
Must be re-boxed to UN specified packaging in quantities of no more than 5 kg per fiberboard box
UN3269, Polyester Resin Kit, 3, PGIII
Packing Instruction 370
For Ocean Transport:
UN3269, Polyester Resin Kit, 3, PGIII, F/P 31.7 C
EMS # F-E, S-D, In limited quantity
SECTION 15 Regulatory Information
CALIFORNIA PROPOSITION 65:
Trace amounts of some chemicals known to the State of California to cause cancer, birth defects, or other
reproductive harm may be present in this product.
SECTION 313 SUPPLIER NOTIFICATION:
This product contains the following toxic chemicals subject to the reporting requirements of the Emergency
Planning and Community Right-To-Know Act of 1986 and 40 CFR 372:
CHEMICAL NAME CAS % BY WGT
Styrene 100-42-5 20-30%
This information must be included in all MSDS that are copied and distributed for this chemical.
SECTION 16 Other Information
HMIS RATING: Health 2 4 = Extreme
Fire 3 3 = High
Reactivity 1 2 = Moderate
1 = Slight
0 = Insignificant
Personal Protection – See Section VIII
MSDS
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Page 5 of 5
ABBREVIATIONS
IARC = International Agency for Research on Cancer
ACGIH = American Conference of Governmental Industrial Hygienists
NIOSH = National Institute of Occupational Safety and Health
TLV = Threshold Limit Value
PEL = Permissible Emission Level
DOT = Department of Transportation
NTP = National Toxicology Program
N/AV = Not Available
N/AP = Not Applicable
N/E = Not Established
N/D = Not Determined
PREPARED BY: QUEST AUTOMOTIVE PRODUCTS
600 NOVA DRIVE SE
MASSILLON, OH 44646
TELEPHONE NBR: 330-830-6000
FAX NBR: 330-830-6005
DATE REVIEWED: October 14, 2013
DATE REVISED: NEW
REVISION: N/a
The information in the Material Safety Data Sheet has been compiled from our experience and from data
presented in various technical publications. It is the user s responsibility to determine the suitability of
this information for the adoption of the safety precautions as may be necessary. We reserve the right to
revise Material Safety Data Sheets from time to time as new technical information becomes available.
The user has the responsibility to contact the Company to make sure that the MSDS is the latest one
issued.
by | Sep 27, 2025
SPECIAL LITE FILLER
Not available.
Liquid.
(888) 345-5732
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Emergency telephone
number of the company
Section 1. Identification
:
:
:
:
Manufacturer :U.S. CHEMICAL & PLASTICS
600 Nova Dr. S.E.
Massillon, OH 44646
USA
Relevant identified uses of the substance or mixture and uses advised against
Paint or paint related material.
15310
15310Product code :
Product Information
Telephone Number
:(330) 830-6000
Transportation Emergency
Telephone Number
:(800) 424-9300
Section 2. Hazards identification
FLAMMABLE LIQUIDS – Category 3
ACUTE TOXICITY (inhalation) – Category 4
SKIN CORROSION/IRRITATION – Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION – Category 2A
SKIN SENSITIZATION – Category 1
CARCINOGENICITY – Category 1B
TOXIC TO REPRODUCTION – Category 2
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) – Category 1
ASPIRATION HAZARD – Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard pictograms :
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 32%
(oral), 49.6% (dermal), 32% (inhalation)
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Date of issue/Date of revision :1/13/2025Date of previous issue :12/14/2024 Version:11 1/17
15310 SPECIAL LITE FILLER SHW-85-NA-GHS-US
Section 2. Hazards identification
Precautionary statements
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves, protective clothing and eye or face
protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking. Use explosion-proof electrical, ventilating or lighting equipment.
Use non-sparking tools. Take action to prevent static discharges. Keep container
tightly closed. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Do
not eat, drink or smoke when using this product. Wash thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.
Response :IF exposed or concerned: Get medical advice or attention. IF INHALED: Remove
person to fresh air and keep comfortable for breathing. Call a POISON CENTER or
doctor if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or
doctor. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all
contaminated clothing. Rinse skin with water. Wash contaminated clothing before
reuse. IF ON SKIN: Wash with plenty of water. If skin irritation or rash occurs: Get
medical advice or attention. IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye
irritation persists: Get medical advice or attention.
Storage :Store locked up. Store in a well-ventilated place. Keep cool.
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise
classified
:None known.
Flammable liquid and vapor.
May be fatal if swallowed and enters airways.
Causes skin irritation.
May cause an allergic skin reaction.
Causes serious eye irritation.
Harmful if inhaled.
May cause cancer.
Suspected of damaging fertility or the unborn child.
Causes damage to organs through prolonged or repeated exposure. (hearing organs,
lungs)
:Hazard statements
Please refer to the SDS for additional information. Keep out of reach of children. Do not
transfer contents to other containers for storage.
Supplemental label
elements
DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which
can cause permanent brain and nervous system damage. Intentional misuse by
deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING:
This product contains chemicals known to the State of California to cause cancer and
birth defects or other reproductive harm. FOR PROFESSIONAL USE ONLY. This
product must be mixed with other components before use. Before opening the
packages, READ AND FOLLOW WARNING LABELS ON ALL COMPONENTS.
:
Section 3. Composition/information on ingredients
Other means of
identification
:Not available.
Substance/mixture
CAS number/other identifiers
:Mixture
Date of issue/Date of revision :1/13/2025Date of previous issue :12/14/2024 Version:11 2/17
15310 SPECIAL LITE FILLER SHW-85-NA-GHS-US
Section 3. Composition/information on ingredients
Unsaturated Polyester 25 – 50 –
Talc 10 – 25 14807-96-6
Styrene 10 – <20 100-42-5
Magnesium Carbonate 10 - 25 546-93-0
Calcium Carbonate 10 471-34-1
Silica gel, pptd., cryst.-free 3 112926-00-8
Titanium Dioxide 1 13463-67-7
Ingredient name CAS number% by weight
Occupational exposure limits, if available, are listed in Section 8.
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified and hence require reporting in this section.
Get medical attention immediately. Call a poison center or physician. Wash out mouth
with water. Remove dentures if any. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Stop if the exposed person
feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter
lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Never give anything by mouth to an
unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Get medical attention. In the event of any
complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean
shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Inhalation :Harmful if inhaled.
May be fatal if swallowed and enters airways.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
Date of issue/Date of revision :1/13/2025Date of previous issue :12/14/2024 Version:11 3/17
15310 SPECIAL LITE FILLER SHW-85-NA-GHS-US
Section 4. First aid measures
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
nausea or vomiting
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
:
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides
Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a
fire or if heated, a pressure increase will occur and the container may burst, with the risk
of a subsequent explosion. The vapor/gas is heavier than air and will spread along the
ground. Vapors may accumulate in low or confined areas or travel a considerable
distance to a source of ignition and flash back.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use dry chemical, CO , water spray (fog) or foam.
Extinguishing media
:
:
:
Flammable liquid.Remark :
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Date of issue/Date of revision :1/13/2025Date of previous issue :12/14/2024 Version:11 4/17
15310 SPECIAL LITE FILLER SHW-85-NA-GHS-US
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
Section 7. Handling and storage
Advice on general
occupational hygiene
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Avoid exposure - obtain special instructions before use. Avoid
exposure during pregnancy. Do not handle until all safety precautions have been read
and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist.
Do not swallow. Use only with adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Do not enter storage areas and confined spaces unless
adequately ventilated. Keep in the original container or an approved alternative made
from a compatible material, kept tightly closed when not in use. Store and use away
from heat, sparks, open flame or any other ignition source. Use explosion-proof
electrical (ventilating, lighting and material handling) equipment. Use only non-sparking
tools. Take precautionary measures against electrostatic discharges. Empty containers
retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
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15310 SPECIAL LITE FILLER SHW-85-NA-GHS-US
Section 7. Handling and storage
Conditions for safe storage,
including any
incompatibilities
Store in accordance with local regulations. Store in a segregated and approved area.
Store in original container protected from direct sunlight in a dry, cool and well-ventilated
area, away from incompatible materials (see Section 10) and food and drink. Store
locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental
contamination. See Section 10 for incompatible materials before handling or use.
:
Unsaturated Polyester None.
Talc 14807-96-6 NIOSH REL (United States, 10/2020).
TWA: 2 mg/m 10 hours. Form: Respirable
fraction
ACGIH TLV (United States, 1/2024).
TWA: 2 mg/m 8 hours. Form: Respirable
fraction
Styrene 100-42-5 ACGIH TLV (United States, 1/2024).
Ototoxicant.
TWA: 10 ppm 8 hours.
STEL: 20 ppm 15 minutes.
OSHA PEL Z2 (United States, 2/2013).
TWA: 100 ppm 8 hours.
CEIL: 200 ppm
AMP: 600 ppm 5 minutes.
NIOSH REL (United States, 10/2020).
TWA: 50 ppm 10 hours.
TWA: 215 mg/m 10 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
Magnesium Carbonate 546-93-0 NIOSH REL (United States, 10/2020).
TWA: 5 mg/m 10 hours. Form: Respirable
fraction
TWA: 10 mg/m 10 hours. Form: Total
OSHA PEL (United States, 5/2018).
TWA: 5 mg/m 8 hours. Form: Respirable
fraction
TWA: 15 mg/m 8 hours. Form: Total dust
Calcium Carbonate 471-34-1 NIOSH REL (United States, 10/2020).
[calcium carbonate]
TWA: 5 mg/m 10 hours. Form: Respirable
fraction
TWA: 10 mg/m 10 hours. Form: Total
Silica gel, pptd., cryst.-free 112926-00-8 NIOSH REL (United States, 10/2020).
[SILICA, AMORPHOUS]
TWA: 6 mg/m 10 hours.
Titanium Dioxide 13463-67-7 OSHA PEL (United States, 5/2018).
TWA: 15 mg/m 8 hours. Form: Total dust
ACGIH TLV (United States, 1/2024).
TWA: 2.5 mg/m 8 hours. Form: respirable
fraction, finescale particles
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits (OSHA United States)
Occupational exposure limits (Canada)
CAS #
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15310 SPECIAL LITE FILLER SHW-85-NA-GHS-US
Section 8. Exposure controls/personal protection
talc (none asbestiform) 14807-96-6 CA British Columbia Provincial (Canada,
8/2023). Notes: the value is for particulate
matter containing no asbestos and less
than 1% crystalline silica.
TWA: 2 mg/m 8 hours. Form: Respirable
CA Alberta Provincial (Canada, 3/2023).
OEL: 2 mg/m 8 hours. Form: Respirable
particulate
CA Ontario Provincial (Canada, 6/2019).
TWA: 2 mg/m 8 hours. Form: Respirable
particulate matter.
TWA: 2 f/cc 8 hours.
CA Quebec Provincial (Canada, 2/2024).
TWAEV: 2 mg/m 8 hours. Form: respirable
aerosol fraction
CA Saskatchewan Provincial (Canada,
4/2021).
TWA: 2 mg/m 8 hours. Form: respirable
fraction
Vinyl benzene 100-42-5 CA Alberta Provincial (Canada, 3/2023).
OEL: 40 ppm 15 minutes.
OEL: 170 mg/m 15 minutes.
OEL: 85 mg/m 8 hours.
OEL: 20 ppm 8 hours.
CA British Columbia Provincial (Canada,
8/2023).
TWA: 20 ppm 8 hours.
STEL: 40 ppm 15 minutes.
CA Ontario Provincial (Canada, 6/2019).
TWA: 35 ppm 8 hours.
STEL: 100 ppm 15 minutes.
CA Quebec Provincial (Canada, 2/2024).
TWAEV: 50 ppm 8 hours.
STEV: 75 ppm 15 minutes.
CA Saskatchewan Provincial (Canada,
4/2021).
STEL: 40 ppm 15 minutes.
TWA: 20 ppm 8 hours.
Ingredient name Exposure limits
Styrene 100-42-5 NOM-010-STPS-2014 (Mexico, 4/2016).
TWA: 20 ppm 8 hours.
STEL: 40 ppm 15 minutes.
N,N-dimethylaniline 121-69-7 NOM-010-STPS-2014 (Mexico, 4/2016).
Absorbed through skin.
TWA: 5 ppm 8 hours.
STEL: 10 ppm 15 minutes.
Exposure limits
Occupational exposure limits (Mexico)
CAS #
CAS #
Biological exposure indices (United States)
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15310 SPECIAL LITE FILLER SHW-85-NA-GHS-US
Section 8. Exposure controls/personal protection
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection :
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Environmental exposure
controls
:
Styrene ACGIH BEI (United States, 1/2024)
BEI: 150 mg/g creatinine, mandelic acid plus
phenylglyoxylic acid [in urine]. Sampling time:
end of shift.
BEI: 20 g/l, styrene [in urine]. Sampling time:
end of shift.
Ingredient name Exposure indices
Biological exposure indices (Canada)
Biological exposure indices (Mexico)
No exposure indices known.
Styrene Official Mexican STANDARD NOM-
047-SSA1-2011, Environmental Health-
Biological exposure indices for personnel
occupationally exposed to chemical
substances. (Mexico, 6/2012)
BEI: 0.2 mg/L [semi-quantitative.The
biological determinant is an indicator of
chemical exposure, but the quantitative
interpretation of the measure is ambiguous.
These biological determinants should be used
as a screening test if a quantitative test is not
possible.], styrene [in venous blood]. Sampling
time: at the end of the work shift.
BEI: 400 mg/g creatinine [non-specific.The
determinant is nonspecific, since it can be
found after exposure to other chemicals.],
mandelic Acid plus Phenylglyoxylic Acid [in
urine]. Sampling time: at the end of the work
shift.
Ingredient name Exposure indices
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15310 SPECIAL LITE FILLER SHW-85-NA-GHS-US
Section 8. Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Respiratory protection :
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point/freezing point
Vapor pressure
Relative density
Liquid.
Not available.
1.1
3.6 [Air = 1]
Not available.Odor
pH
Gray.Color
Evaporation rate 0.49 (butyl acetate = 1)
Auto-ignition temperature
Flash point
Not available.
Closed cup: 40 C (104 F) [Pensky-Martens Closed Cup]
Not applicable.
Not applicable.
Viscosity Kinematic (40 C (104 F)): <20.5 mm
2
/s (<20.5 cSt)
Not available.Odor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
:145 C (293 F)
:Flammable liquid.
:Lower: 1.1%
Upper: 6.1%
Decomposition temperature:Not available.
Molecular weight :Not applicable.
Boiling point, initial boiling
point, and boiling range
Flammability
Lower and upper explosion
limit/flammability limit
Relative vapor density
The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.
0.57 kPa (4.3 mm Hg)
Solubility(ies) :
Media Result
cold water Not soluble
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15310 SPECIAL LITE FILLER SHW-85-NA-GHS-US
Section 9. Physical and chemical properties
Heat of combustion :7.737 kJ/g
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
Styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours
LC50 Inhalation Vapor Rat 11800 mg/m 4 hours
LD50 Oral Rat 2650 mg/kg -
Magnesium Carbonate LD50 Oral Rat 8000 mg/kg -
Calcium Carbonate LD50 Oral Rat 6450 mg/kg -
Product/ingredient name Result Species Dose Exposure
Mutagenicity
Not available.
Irritation/Corrosion
Talc Skin - Mild irritant Human - 72 hours 300
ug I
-
Styrene Eyes - Mild irritant Human - 50 ppm -
Eyes - Moderate irritantRabbit - 24 hours 100
mg
-
Eyes - Severe irritantRabbit - 100 mg -
Skin - Mild irritant Rabbit - 500 mg -
Skin - Moderate irritantRabbit - 100 % -
Calcium Carbonate Eyes - Severe irritantRabbit - 24 hours 750
ug
-
Skin - Moderate irritantRabbit - 24 hours 500
mg
-
Titanium Dioxide Skin - Mild irritant Human - 72 hours 300
ug I
-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Information on toxicological effects
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15310 SPECIAL LITE FILLER SHW-85-NA-GHS-US
Section 11. Toxicological information
Carcinogenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Styrene Category 3 - Respiratory tract
irritation
Name Category
Name Category
Talc Category 1 inhalation lungs
Styrene Category 1 - hearing organs
Aspiration hazard
Name Result
Styrene ASPIRATION HAZARD - Category 1
Route of
exposure
Target organs
Route of
exposure
Target organs
Classification
Talc - 3 -
Styrene - 2A Reasonably anticipated to be a human carcinogen.
Silica gel, pptd., cryst.-free- 3 -
Titanium Dioxide - 2B -
Product/ingredient name NTPIARCOSHA
Information on the likely
routes of exposure
Inhalation :Harmful if inhaled.
May be fatal if swallowed and enters airways.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Inhalation Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
:Not available.
Potential acute health effects
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15310 SPECIAL LITE FILLER SHW-85-NA-GHS-US
Section 11. Toxicological information
Not available.
Causes damage to organs through prolonged or repeated exposure. Once sensitized, a
severe allergic reaction may occur when subsequently exposed to very low levels.
General :
May cause cancer. Risk of cancer depends on duration and level of exposure.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
Suspected of damaging the unborn child.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Skin contact
Ingestion Adverse symptoms may include the following:
nausea or vomiting
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Oral 10247.15 mg/kg
Inhalation (gases) 10711.17 ppm
Inhalation (vapors) 45.63 mg/l
Route ATE value
Acute toxicity estimates
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
Section 12. Ecological information
Toxicity
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15310 SPECIAL LITE FILLER SHW-85-NA-GHS-US
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Product/ingredient name
Styrene - 13.49 Low
Styrene Acute EC50 1400 g/l Fresh water Algae - Raphidocelis subcapitata72 hours
Acute EC50 720 g/l Fresh water Algae - Raphidocelis subcapitata96 hours
Acute EC50 4700 g/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 52 mg/l Marine water Crustaceans - Artemia salina 48 hours
Acute LC50 4020 g/l Fresh water Fish - Pimephales promelas 96 hours
Chronic NOEC 63 g/l Fresh water Algae - Raphidocelis subcapitata96 hours
Calcium Carbonate Acute LC50 >56000 ppm Fresh water Fish – Gambusia affinis – Adult96 hours
Chronic NOEC 16.5 mg/l Fresh waterFish – Rhamdia quelen 30 days
Titanium Dioxide Acute LC50 >1000000 g/l Marine waterFish – Fundulus heteroclitus 96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Not available.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
Section 14. Transport information
RESIN SOLUTION RESIN SOLUTION
UN1866 UN1866
DOT
Classification
IMDG
UN number
UN proper
shipping name
TDG
Classification
UN1866
RESIN SOLUTION
Mexico
Classification
UN1866
RESIN SOLUTION
IATA
UN1866
RESIN
SOLUTION
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Section 14. Transport information
3
III
3
III
This product may
be re-classified as
“Combustible
Liquid,” unless
transported by
vessel or aircraft.
Non-bulk
packages (less
than or equal to
119 gal) of
combustible
liquids are not
regulated as
hazardous
materials in
package sizes
less than the
product reportable
quantity.
Emergency
schedules F-E, S-
E
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
Special precautions for user
Transport in bulk according
to IMO instruments
No. No.
Not available.
:
Proper shipping name :
Not available.
:
3
III
No.
Product classified
as per the
following sections
of the
Transportation of
Dangerous Goods
Regulations:
2.18-2.19 (Class
3).
3
III
No.
–
Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability prior
to shipment, and compliance with the applicable regulations is the sole responsibility
of the person offering the product for transport. People loading and unloading
dangerous goods must be trained on all of the risks deriving from the substances
and on all actions in case of emergency situations.
3
III
No.
–
127
ERG No.
127 127
ERG No. ERG No.
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15310 SPECIAL LITE FILLER SHW-85-NA-GHS-US
Section 15. Regulatory information
All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED
and rely on information provided to us by our raw material suppliers. Our suppliers often provide an estimated value or
range less than a certain upper limit. We calculate MAXIMUM THEORETICAL VALUES using defined values, if provided,
or the upper limit reported by our supplier. Additionally, the suppliers information may include amounts present in the
product as unintentional byproducts or impurities. Variations may occur in individual batches due to adjustments made
during production. Reporting of chemicals in this section does not necessarily indicate their presence in the final
formulated product.
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.
California Prop. 65
Australia inventory (AIIC): Not determined.
China inventory (IECSC): Not determined.
Japan inventory (CSCL): Not determined.
Japan inventory (ISHL): Not determined.
Korea inventory (KECI): Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
Taiwan Chemical Substances Inventory (TCSI): Not determined.
Thailand inventory: Not determined.
Turkey inventory: Not determined.
Vietnam inventory: Not determined.
International regulations
International lists :
Montreal Protocol
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Styrene 18 100-42-5
Ingredient name CAS number% by weight
SARA 313
Section 16. Other information
Hazardous Material Information System (U.S.A.)
3
3
0
*
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS
ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS
Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual.
Procedure used to derive the classification
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15310 SPECIAL LITE FILLER SHW-85-NA-GHS-US
Section 16. Other information
1/13/2025
History
Date of printing
Date of issue/Date of
revision
Version
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer,
or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements
are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is
responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The
conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is
responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user
should not use the product for any purpose other than the purpose shown in the applicable section of this SDS
without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of
sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs
obtained from any other source.
Date of previous issue
:
:
:
:
Indicates information that has changed from previously issued version.
Key to abbreviations :
1/13/2025
12/14/2024
11
FLAMMABLE LIQUIDS – Category 3 On basis of test data
ACUTE TOXICITY (inhalation) – Category 4 Calculation method
SKIN CORROSION/IRRITATION – Category 2 Calculation method
SERIOUS EYE DAMAGE/ EYE IRRITATION – Category 2A Calculation method
SKIN SENSITIZATION – Category 1 Calculation method
CARCINOGENICITY – Category 1B Calculation method
TOXIC TO REPRODUCTION – Category 2 Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) – Category 1 Calculation method
ASPIRATION HAZARD – Category 1 Calculation method
Classification Justification
Notice to reader
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. (“Marpol” = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
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15310 SPECIAL LITE FILLER SHW-85-NA-GHS-US
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15310 SPECIAL LITE FILLER SHW-85-NA-GHS-US
by | Sep 27, 2025
by | Sep 27, 2025
3MGeneral Offices
3M Center
St. Paul, MN 55144-1000
1-800-364-3577 or (651) 737-6501 (24 hours)
10/2/2012 7:32:59 AM
Material Safety Data Sheet
Purchase Order #: –
Customer Number: SMG1993
STE B
REVCHEM COMPOSITES INC
2720 S WILLOW AVE
BLOOMINGTON, CA 92316-3259
United States of America
Dear STE B
Enclosed is the Material Safety Data Sheet (MSDS) for the product that your company recently purchased from 3M.
The MSDS being sent to you is required by the Supplier Notification Requirement of 40 CFR 372.45 (c 4), a part of
Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. The Supplier
Notification Requirement requires the supplier to provide new notification to the recipient when the supplier
changes an MSDS in any of the following ways related to EPCRA Section 313 chemical(s):
Additional EPCRA Section 313 chemical(s) were added to the MSDS,
The percent weight of any EPCRA Section 313 chemical(s) changed, or
EPCRA 313 chemical(s)were deleted from the MSDS.
Please forward the attached MSDS to the individual in your organization responsible for implementing Title III of
the Superfund Amendments and Reorganization Act of 1986 and 40 CFR Part 372 regulations.
This letter and accompanying MSDS were created using a 3M computerized system. This system automatically
prints and sends an MSDS when a product is first ordered by a customer, when the MSDS has been changed at the
time of a subsequent order by the customer, or if renotification is warranted by Title III of the Superfund
Amendments and Reauthorization Act of 1986 and 40 CFR Part 372 regulations.
3M MSDSs are available over the Internet at www.3m.com/MSDSSearch. You may also order a CD-ROM of 3M
MSDSs by calling 1-800-364-3577.
3M is committed to meeting our customer requirements, and we ask that you contact your 3M customer service or
sales representative if you have any questions. If you do not know whom to contact, please call the 3M Product
Information Center at 1-800-364-3577.
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MATERIAL SAFETY DATA SHEET 3M Dyanatron White CreamHardener 308, 30759 10/01/12
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Page 1of 8
Material Safety Data Sheet
Copyright, 2012, 3M Company All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M Dyanatron White Cream Hardener 308, 30759
MANUFACTURER: 3M
DIVISION: Automotive Aftermarket
ADDRESS: 3M Center, St. Paul, MN 55144-1000
EMERGENCY PHONE: 1 -800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 10/01/12
Supercedes Date: 07/21/11
Document Group:24-8015-0
Product Use:
Intended Use: Automotive
Specific Use: Hardener for body fillers
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt
BENZOYL PEROXIDE 94-36-0 30 -60
WATER 7732-18-5 10 -30
BENZOIC ACID, C9-11-BRANCHED ALKYL ESTERS 131298-44-7 10 -20
ZINC STEARATE 557-05-1 3 -7
OXIRANE, POLYMER WITH METHYLOXIRANE, MONOBUTYL ETHER 9038-95-3 3 -4
CALCIUM SULFATE 7778-18-9 3 -4
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Specific Physical Form: Viscous
Odor, Color, Grade: White paste with slight ester odor
General Physical Form: Solid
Immediate health, physical, and environmental hazards: Closed containers exposed to heat from fire may build pressure and
explode. Dust clouds of this material in combination with an ignition source may be explosive. May cause severe eye irritation.
Maycause allergic skin reaction.
MATERIAL SAFETY DATA SHEET 3M Dyanatron White CreamHardener 308, 30759 10/01/12
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3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:
Severe EyeIrritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and
impaired vision.
Skin Contact:
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching.
Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.
Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and
throat pain.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
Maybe absorbed following ingestion and cause target organ effects.
Target Organ Effects:
Prolonged or repeatedexposure may cause:
Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and
jaundice.
Kidney/Bladder Effects: Signs/symptoms may include changes in urine production, abdominal or lower back p ain, increased
protein in urine, increased blood urea nitrogen (BUN), blood in urine, and painful urination.
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention.
Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical
attention. Wash contaminated clothing and clean shoes before reuse.
Inhalation: Remove person to fresh air. Ifsigns/symptoms develop, get medical attention.
If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never
give anything by mouth to an unconscious person. Get medical attention.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
Autoignition temperature No Data Available
Flash Point 111 C [Test Method: Estimated]
Flammable Limits(LEL) Not Applicable
Flammable Limits(UEL) Not Applicable
MATERIAL SAFETY DATA SHEET 3M Dyanatron White CreamHardener 308, 30759 10/01/12
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5.2 EXTINGUISHING MEDIA
Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus
(SCBA).
Unusual Fire and Explosion Hazards: Closed containers exposed to heat from fire may build pressure and explode. Dust clouds
of this material in combination with an ignition source may be explosive.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the
area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in
accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or
vapors in the spill area to burn or explode. Remember, adding an absorbent material does not remove a toxic, corrosivity or
flammability hazard.
6.2. Environmental precautions
For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Place in a metal container
approved for use in transportation by appropriate authorities.The container must be lined with polyethylene plastic or contain a
plastic drum liner made of polyethylene. Dispose of collected material as soon as possible.
Clean-up methods
Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and
personal protective equipment. Contain spill. Cover spill area with a fire -extinguishing foam. An aqueous film forming foam
(AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially
available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as
possible using non-sparking tools. Clean up residue with an appropriate solvent selected by a qualified and authorized person.
Ventilate the area with fresh air. Read and followsafety precautions on the solvent label and MSDS. Seal the container.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLING
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away fromheat,
sparks, open flame, pilot lights and other sources of ignition. Avoid static discharge. Avoid eye contact with vapors, mists, or spray.
Keep out of the reach of children. Avoid breathing of dust created by cutting, sanding, grinding or machining. Avoid eye contact
with dust or airborne particles.
7.2 STORAGE
Store awayfrom heat. Store out of direct sunlight. Keep containertightly closed. Do not heat under confinement to avoid risk of
explosion
MATERIAL SAFETY DATA SHEET 3M Dyanatron White CreamHardener 308, 30759 10/01/12
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SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLS
Provide appropriate local exhaust for cutting, grinding, sanding or machining. Do not use in a confined area or areas with little or no
air movement. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational
Exposure Limits and/or control dust, fume, or airborne particles. If ventilation is not adequate, use respiratory protection equipment.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact with vapors, mists, or spray.
The following eye protection(s) are recommended: Safety Glasses with side shields
Indirect Vented Goggles
.
8.2.2 Skin Protection
Avoid skin contact.
Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with
your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.
Gloves made from the following material(s) are recommended: Polymer laminate
. Use an additional glove (e.g. supported PVC or Nitrile) over the PE/EVAL glove, and change the over-glove frequently.
8.2.3 Respiratory Protection
Avoid breathing of vapors, mists or spray. Avoid breathing of dust created by cutting, sanding, grinding or machining.
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full
respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce
inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
8.2.4 Prevention of Swallowing
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.
8.3 EXPOSURE GUIDELINES
IngredientAuthorityType Limit Additional Information
BENZOYL PEROXIDE ACGIH TWA 5 mg/m3
BENZOYL PEROXIDE OSHA TWA 5 mg/m3
CALCIUM SULFATE ACGIH TWA, inhalable
fraction
10 mg/m3
CALCIUM SULFATE OSHA TWA, respirable
fraction
5 mg/m3
CALCIUM SULFATE OSHA TWA, as total dust15 mg/m3
STEARATES ACGIH TWA 10 mg/m3
ZINC STEARATE OSHA TWA, respirable
fraction
5 mg/m3
ZINC STEARATE OSHA TWA, as total dust15 mg/m3
SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration
MATERIAL SAFETY DATA SHEET 3M Dyanatron White CreamHardener 308, 30759 10/01/12
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AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Specific Physical Form: Viscous
Odor, Color, Grade: White paste with slight ester odor
General Physical Form: Solid
Autoignition temperature No Data Available
Flash Point 111 C [Test Method: Estimated]
Flammable Limits(LEL) Not Applicable
Flammable Limits(UEL) Not Applicable
Boiling Point [Details: Decomposes]
Vapor Density Not Applicable
Vapor Pressure Not Applicable
Specific Gravity 1.2 [@ 25 C] [Ref Std: WATER=1]
pH No Data Available
Melting point No Data Available
Solubility in Water Negligible
Evaporation rate Not Applicable
Hazardous Air Pollutants 0 % weight [Test Method: Calculated]
Volatile Organic Compounds 0 g/l [Test Method: calculated SCAQMD rule 443.1]
Volatile Organic Compounds 0 % weight [Test Method: calculated per CARB title 2]
Kow -Oct/Water partition coef No Data Available
Percent volatile 20 % [Details: Water is the volatile component]
VOC Less H2O & Exempt Solvents 0 g/l [Test Method: calculated SCAQMD rule 443.1]
Viscosity No Data Available
SECTION 10: STABILITY AND REACTIVITY
Stability:Stable. Stable unless exposed to heat, flames and drying conditions.
Materials and Conditions to Avoid:
10.1 Conditions to avoid
Not determined
10.2 Materials to avoid
Accelerators
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide Not Specified
Carbon dioxide Not Specified
Toxic Vapor, Gas, Particulate Not Specified
MATERIAL SAFETY DATA SHEET 3M Dyanatron White CreamHardener 308, 30759 10/01/12
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SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product in
a permitted hazardous waste facility.
This product has been classified on the basis that it is stable as sold. Material may become unstable if allowed to dry out. Classify
appropriately before disposal.
EPA Hazardous Waste Number (RCRA):D001 (Ignitable)
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number(s):
70-0080-0378-5, 70-0080-0379-3
For Transport Information, please visit http://3M.com/Transportinfo or call 1 -800-364-3577 or 651-737-6501.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard -No Pressure Hazard -No Reactivity Hazard -Yes Immediate Hazard -Yes Delayed Hazard -Yes
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
Ingredient C.A.S. No% by Wt
ZINC STEARATE (ZINC COMPOUNDS) 557-05-1 3 -7
BENZOYL PEROXIDE 94-36-0 30 -60
STATE REGULATIONS
Contact 3M for more information.
MATERIAL SAFETY DATA SHEET 3M Dyanatron White CreamHardener 308, 30759 10/01/12
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CHEMICAL INVENTORIES
The components of this product are in compliance with the chemical notification requirements of TSCA.
Contact 3M for more information.
INTERNATIONAL REGULATIONS
Contact 3M for more information.
WHMIS: Hazardous
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 2 Flammability: 2 Reactivity: 1 Special Hazards: Oxidizer
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill,or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.
Revision Changes:
Section 1: Product name was modified.
Section 1: Product use information was modified.
Section 10: Hazardous decomposition or by-products table was modified.
Section 13: Waste disposal method information was modified.
Section 13: EPA hazardous waste number (RCRA) information was modified.
Section 8: Respiratory protection -recommended respirators information was modified.
Section 8: Respiratory protection -recommended respirators was modified.
Page Heading: Product name was modified.
Section 9: Vapor density value was modified.
Section 9: Vapor pressure value was modified.
Section 9: Boiling point information was modified.
Section 5: Flammable limits (UE) information was modified.
Section 5: Flammable limits (LEL) information was modified.
Section 5: Autoignition temperature information was modified.
Section 5: Flash point information was modified.
Section 9: Property description for optional properties was modified.
Section 9: Specific gravity information was modified.
Section 9: pH information was modified.
Section 9: Melting point information was modified.
Section 9: Solubility in water text was modified.
Section 8: Respiratory protection -recommended respirators guide was modifi ed.
Section 9: Flash point information was modified.
Section 9: Flammable limits (LEL) information was modified.
Section 9: Flammable limits (UEL) information was modified.
Section 9: Autoignition temperature information was modified.
Section 2: Ingredienttable was modified.
Section 15: EPCRA 313 information was modified.
Section 8: Exposure guidelines ingredient information was modified.
MATERIAL SAFETY DATA SHEET 3M Dyanatron White CreamHardener 308, 30759 10/01/12
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Section 6: Personal precautions information was modified.
Section 6: Environmental procedures information was modified.
Section 6: Methods for cleaning up information was modified.
Copyright was modified.
Section 8: Respiratory protection -recommended respirators punctuation was deleted.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed tobe correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user’s method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user’s knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user’s method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M
3MUSA MSDSs are available at www.3M.com
by | Sep 27, 2025
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Revision Date: 24 Jun 2010
Page 1 of 10
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MATERIAL SAFETY DATA SHEET
SECTION 1 PRODUCT AND COMPANY IDENTIFICATION
PRODUCT
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Product Description: LLDPE without polymer processing aid, see Section 16 for applicable grades.
Product Code: 19889
Intended Use: Coatings, Extrusion and moulding, Film blowing
COMPANY IDENTIFICATION
Supplier: CIOL – EXXONMOBIL CHEMICAL CANADA
Division of Canada Imperial Oil Limited, an Affiliate of Exxon Mobil Corporation
240 4TH AVENUE S.W.
CALGARY, ALBERTA. T2P 3M9 Canada
24 Hour Health Emergency 519-339-2145
Transportation Emergency Phone 519-339-2145
Product Technical Information 800-668-0177
SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS
No Reportable Hazardous Substance(s) or Complex Substance(s).
NOTE: The product may contain varying levels of additives such as slip and antiblocking agents, antioxidants and
stabilizers.
SECTION 3 HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15).
POTENTIAL PHYSICAL / CHEMICAL EFFECTS
High dust levels may create potential for explosion. Spilled pellets present a slipping hazard on hard
surfaces. Contact with hot material can cause thermal burns which may result in permanent damage.
Material can accumulate static charges which may cause an ignition.
POTENTIAL HEALTH EFFECTS
Material is essentially non-toxic. However, if dust is generated, it could scratch the eyes and cause minor
irritation to the respiratory tract. When heated, the vapors/fumes given off may cause respiratory tract irritation.
NFPA Hazard ID: Health: 1 Flammability: 1 Reactivity: 0
HMIS Hazard ID: Health: 1 Flammability: 1 Reactivity: 0
SECTION 4 FIRST AID MEASURES
INHALATION
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Revision Date: 24 Jun 2010
Page 2 of 10
______________________________________________________________________________________________________________________
In case of adverse exposure to vapors and / or aerosols formed at elevated temperatures, immediately remove
the affected victim from exposure. Administer artificial respiration if breathing is stopped. Keep at rest.
SKIN CONTACT
For hot product: Immediately immerse in or flush affected area with large amounts of cold water to dissipate
heat. Cover with clean cotton sheeting or gauze and get prompt medical attention.
EYE CONTACT
Flush thoroughly with water. If irritation occurs, get medical assistance.
INGESTION
No adverse effects due to ingestion are expected.
SECTION 5 FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish
flames.
Inappropriate Extinguishing Media: Straight Streams of Water
FIRE FIGHTING
Fire Fighting Instructions: Assure an extended cooling down period to prevent re-ignition. Evacuate area.
Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. Firefighters
should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA).
Use water spray to cool fire exposed surfaces and to protect personnel.
Unusual Fire Hazards: High dust levels may create potential for explosion.
Hazardous Combustion Products: Smoke, Fume, Incomplete combustion products, Oxides of carbon,
Flammable hydrocarbons
FLAMMABILITY PROPERTIES
Flash Point [Method]: N/A
Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D
Autoignition Temperature: N/A
SECTION 6 ACCIDENTAL RELEASE MEASURES
NOTIFICATION PROCEDURES
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable
regulations. US regulations require reporting releases of this material to the environment which exceed the
applicable reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The
National Response Center can be reached at (800)424-8802.
SPILL MANAGEMENT
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Revision Date: 24 Jun 2010
Page 3 of 10
______________________________________________________________________________________________________________________
Land Spill: Spilled pellets present a slipping hazard on hard surfaces. Small Dry Spills: With clean shovel
place material into clean, dry container and cover loosely; move containers from spill area.
Water Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Warn other
shipping. Skim from surface.
Water spill and land spill recommendations are based on the most likely spill scenario for this material;
however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction
and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be
consulted. Note: Local regulations may prescribe or limit action to be taken.
ENVIRONMENTAL PRECAUTIONS
Prevent entry into waterways, sewers, basements or confined areas. For Large Spills: Cover spill with plastic
sheet or tarpaulin to minimize spreading.
SECTION 7 HANDLING AND STORAGE
HANDLING
Avoid elevated temperatures for prolonged periods of time. Prevent small spills and leakage to avoid slip
hazard. Avoid conditions which create dust. DO NOT handle, store or open near an open flame, sources of
heat or sources of ignition. Protect material from direct sunlight. Material can accumulate static charges which
may cause an electrical spark (ignition source). Care should be taken when storing and handling this product.
Apart from the specific nature of the polymer product, conditions such as humidity, sunlight, and temperature
have an influence on the way the product behaves during storage and handling. Special attention should be
paid to avoid inappropriate stacking of palletized bags or other package units. Indeed, polymer products may be
dimensionally unstable under certain conditions. Avoid conditions generating heat during transfer operations.
Loading/Unloading Temperature: [Ambient]
Transport Temperature: [Ambient]
Transport Pressure: [Ambient]
Static Accumulator: This material is a static accumulator.
STORAGE
The container choice, for example storage vessel, may effect static accumulation and dissipation. Store in a
cool, dry place with adequate ventilation. Keep away from incompatible materials, open flames, and high
temperatures. Do not store in open or unlabelled containers.
Storage Temperature: [Ambient]
Storage Pressure: [Ambient]
Suitable Containers/Packing: Bulk Containers; Hopper Cars; Bags; Boxes; Drums; Octatainer; Silos
Suitable Materials and Coatings (Chemical Compatibility): Aluminum; Polyethylene Bags
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure limits/standards for materials that can be formed when handling this product: For dusty conditions,
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Revision Date: 24 Jun 2010
Page 4 of 10
______________________________________________________________________________________________________________________
OSHA recommends for particulates not otherwise regulated an 8-hour TWA of 15 mg/m3 (total dust), 5 mg/m3
(respirable fraction); ACGIH recommends for insoluble and poorly soluble particles not otherwise specified an 8-hour
TWA of 10 mg/m3 (inhalable particles), 3 mg/m3 (respirable particles). Product may also contain varying levels of
additives, such as slip and antiblocking agents (talc or silica), antioxidants, stabilizers, and corrosion inhibitors. Certain
grades may contain cristobalite, a form of crystalline silica, as an additive that is encapsulated in the polymer. Inhaled
crystalline silica in an occupational environment is recognized as a known human carcinogen. However, the potential for
release of silica to the air when this polymer is handled has been assessed and the encapsulated silica within the
polymer is not expected to pose a health hazard when processed under normal conditions of use.
NOTE: Limits/standards shown for guidance only. Follow applicable regulations.
ENGINEERING CONTROLS
The level of protection and types of controls necessary will vary depending upon potential exposure conditions.
Control measures to consider:
Adequate ventilation should be provided so that exposure limits are not exceeded. SPECIAL
PRECAUTIONS: Should significant vapors/fumes be generated during thermal processing of this
product, it is recommended that work stations be monitored for the presence of thermal degradation
by-products which may evolve at elevated temperatures (for example, oxygenated components).
Processors of this product should assure that adequate ventilation or other controls are used to control
exposure. It is recommended that the current ACGIH-TLVs for thermal degradation by-products be
observed. Contact your local sales representative for further information.
PERSONAL PROTECTION
Personal protective equipment selections vary based on potential exposure conditions such as applications,
handling practices, concentration and ventilation. Information on the selection of protective equipment for use
with this material, as provided below, is based upon intended, normal usage.
Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a
level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator
selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of
respirators to be considered for this material include:
Half-face filter respirator
For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode.
Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate,
gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded.
Hand Protection: Any specific glove information provided is based on published literature and glove
manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions.
Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use
conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material
include:
If product is hot, thermally protective, chemical resistant gloves are recommended. If contact with
forearms is likely, wear gauntlet style gloves.
Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or
manufacturer data. The types of clothing to be considered for this material include:
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Revision Date: 24 Jun 2010
Page 5 of 10
______________________________________________________________________________________________________________________
If product is hot, thermally protective, chemical resistant apron and long sleeves are recommended.
Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after
handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned.
Practice good housekeeping.
ENVIRONMENTAL CONTROLS
See Sections 6, 7, 12, 13.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Typical physical and chemical properties are given below. Consult the Supplier in Section 1 for additional
data.
GENERAL INFORMATION
Physical State: Solid
Form: Pellet, Granule, Powder
Color: Clear to Opaque, White to Off-White
Odor: None to Mild
Odor Threshold: N/A
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION
Relative Density (at 15 C): 0.9 – 0.95
Bulk Density: 0.4 g/cc at 20 C – 1 g/cc at 20 C
Flash Point [Method]: N/A
Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D
Autoignition Temperature: N/A
Boiling Point / Range: N/A
Vapor Density (Air = 1): N/A
Vapor Pressure: N/A
Evaporation Rate (n-butyl acetate = 1): N/A
pH: N/A
Log Pow (n-Octanol/Water Partition Coefficient): N/A
Solubility in Water: Negligible
Viscosity: N/A
Oxidizing Properties: See Hazards Identification Section.
OTHER INFORMATION
Freezing Point: N/D
Melting Point: 115 C (239 F) – 130 C (266 F)
Molecular Weight: > 25000
Hygroscopic: No
SECTION 10 STABILITY AND REACTIVITY
STABILITY: Material is stable under normal conditions.
CONDITIONS TO AVOID: Avoid elevated temperatures for prolonged periods of time.
MATERIALS TO AVOID: Strong oxidizers
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Revision Date: 24 Jun 2010
Page 6 of 10
______________________________________________________________________________________________________________________
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures.
HAZARDOUS POLYMERIZATION: Will not occur.
SECTION 11 TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
Route of Exposure
Conclusion / Remarks
Inhalation
Toxicity: Data available. Minimally Toxic. Based on test data for structurally similar
materials.
Irritation: Data available. Negligible haz ard at ambient/normal handling temperatures.
Based on test data for structurally similar materials.
Ingestion
Toxicity: Data available. Minimally Toxic. Based on test data for structurally similar
materials.
Skin
Toxicity: Data available. Minimally Toxic. Based on test data for structurally similar
materials.
Irritation: Data available. Negl igible irritation to skin at ambient temperatures. Based on test
data for structurally similar materials.
Eye
Irritation: Data available. May cause mild, s hort-lasting discomfort to eyes. Based on test
data for structurally similar materials.
CHRONIC/OTHER EFFECTS
For the product itself:
Dust may be irritating to the eyes and respiratory tract.
Elevated temperatures or mechanical action may form vapors, mists or fumes which may be irritating to the
eyes and respiratory tract.
Contains additives that are encapsulated in the polymer. Under normal conditions of processing and use the
encapsulated additives are not expected to pose a health hazard, however, grinding of the polymer is not
recommended.
Additional information is available by request.
The following ingredients are cited on the lists below: None.
–REGULATORY LISTS SEARCHED–
1 = NTP CARC 3 = IARC 1 5 = IARC 2B
2 = NTP SUS 4 = IARC 2A 6 = OSHA CARC
SECTION 12 ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials.
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Revision Date: 24 Jun 2010
Page 7 of 10
______________________________________________________________________________________________________________________
ECOTOXICITY
Material — Not expected to be harmful to aquatic organisms.
Material — Not expected to be harmful to terrestrial organisms.
MOBILITY
Material — Low solubility and floats and is expected to migrate from water to the land. Expected to
partition to sediment and wastewater solids.
PERSISTENCE AND DEGRADABILITY
Biodegradation:
Material — Expected to be persistent.
Hydrolysis:
Material — Transformation due to hydrolysis not expected to be significant.
Photolysis:
Material — Transformation due to photolysis not expected to be significant.
Atmospheric Oxidation:
Material — Transformation due to atmospheric oxidation not expected to be significant.
BIOACCUMULATION POTENTIAL
Material — Potential to bioaccumulate is low.
SECTION 13 DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable
laws and regulations, and material characteristics at time of disposal.
DISPOSAL RECOMMENDATIONS
Suitable routes of disposal are supervised incineration, preferentially with energy recovery, or appropriate
recycling methods in accordance with applicable regulations and material characteristics at the time of disposal.
REGULATORY DISPOSAL INFORMATION
RCRA Information: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous
waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed as hazardous wastes. It
does not exhibit the hazardous characteristics of ignitability, corrositivity or reactivity and is not formulated with
contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used
product may be regulated.
SECTION 14 TRANSPORT INFORMATION
LAND (DOT): Not Regulated for Land Transport
LAND (TDG): Not Regulated for Land Transport
SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Revision Date: 24 Jun 2010
Page 8 of 10
______________________________________________________________________________________________________________________
AIR (IATA): Not Regulated for Air Transport
SECTION 15 REGULATORY INFORMATION
OSHA HAZARD COMMUNICATION STANDARD: When used for its intended purposes, this material is not
classified as hazardous in accordance with OSHA 29 CFR 1910.1200.
NATIONAL CHEMICAL INVENTORY LISTING: EINECS, TSCA
EPCRA: This material contains no extremely hazardous substances.
CWA / OPA: Plastic pellets are defined by the US EPA under the Clean Water Act (40CFR122.26) as a “significant
material” which requires any industrial plant that may expose pellets to storm water to secure a storm water permit.
Violations of the rule carry the same penalties as other Clean Water Act violations. Pellets found in storm water runoff
are subject to EPA regulations with the potential for substantial fines and penalties.
SARA (311/312) REPORTABLE HAZARD CATEGORIES: None.
SARA (313) TOXIC RELEASE INVENTORY: This material contains no chemicals subject to the supplier notification
requirements of the SARA 313 Toxic Release Program.
The following ingredients are cited on the lists below:* None.
–REGULATORY LISTS SEARCHED–
1 = ACGIH ALL 6 = TSCA 5a2 11 = CA P65 REPRO 16 = MN RTK
2 = ACGIH A1 7 = TSCA 5e 12 = CA RTK 17 = NJ RTK
3 = ACGIH A2 8 = TSCA 6 13 = IL RTK 18 = PA RTK
4 = OSHA Z 9 = TSCA 12b 14 = LA RTK 19 = RI RTK
5 = TSCA 4 10 = CA P65 CARC 15 = MI 293
Code key: CARC=Carcinogen; REPRO=Reproductive
* EPA recently added new chemical substances to its TSCA Section 4 test rules. Please contact the supplier to
confirm whether the ingredients in this product currently appear on a TSCA 4 or TSCA 12b list.
Contact Sales / Marketing group for complete chemical inventory listing applicable to product.
SECTION 16 OTHER INFORMATION
N/D = Not determined, N/A = Not applicable
THIS SAFETY DATA SHEET CONTAI NS THE FOLLOWING REVISIONS:
Revision Changes:
Section 10 Stability and Reactivity – Header was modified.
Section 13: Disposal Recommendations – Note was modified.
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Revision Date: 24 Jun 2010
Page 9 of 10
______________________________________________________________________________________________________________________
Section 08: Personal Protection was modified.
Section 07: Handling and Storage – Storage Phrases was modified.
Hazard Identification: Physical/Chemical Hazard was modified.
Section 07: Loading/Unloading Temperature C(F) was modified.
Section 07: Transport Temperature C(F) was modified.
Section 07: Transport Pressure kPa was modified.
Section 07: Storage Temperature C(F) was modified.
Section 07: Storage Pressure kPa was modified.
Section 07: Suitable Materials and Coatings – Header was modified.
Section 11: Dermal Lethality Test Comment was modified.
Section 05: Hazardous Combustion Products was modified.
Section 06: Accidental Release – Spill Management – Water was modified.
Section 09: Relative Density – Header was modified.
Section 08: Hand Protection was modified.
Section 14: Sea (IMDG) – Header was modified.
Section 14: Air (IATA) – Header was modified.
Section 14: LAND (TDG) – Header was modified.
Section 14: LAND (DOT) – Header was modified.
Section 15: List Citation Table – Header was modified.
Section 14: LAND (DOT) – Default was modified.
Section 14: LAND (TDG) Default was modified.
Section 14: Sea (IMDG) – Default was modified.
Section 14: Air (IATA) – Default was modified.
Section 15: National Chemical Inventory Listing was modified.
Section 08: Exposure limits/standards was modified.
Section 15: OSHA Hazard Communication Standard was modified.
Hazard Identification: OSHA – May be Hazardous Statement was modified.
Section 06: Notification Procedures was modified.
Composition: Footnotes was modified.
Section 11: Chronic Tox – Product was modified.
Section 09: Oxidizing Properties was modified.
THIS MSDS COVERS THE FOLLOWING MATERIALS: Linear Low Density PE grades for which the grade name
consists of a base polymer designated by a LL or LLP prefix followed by a suffix referring to an additive package.
Applicable designations follow. | Base polymers : | LL 1000S | LL 1001 | LL 1002 | LL 1004 | LL 1015
| LL 1030 | LL 1201 | LL 1433 | LL 3000S | LL 3001 | LL 3002 | LL 3003 | LL 3113 | LL 3201 |
LL 3402 | LL 3403 | LL 3404 | LL 3405 | LL 4004 | LL 5002 | LL 5100 | LL 5202 | LL 5252 | LL
60 | LL 6021 | LL 6100 | LL 6101 | LL 6201 | LL 6202 | LL 6235 | LL 6301 | LL 6407 | LL 8360 |
LL 8446 | LL 8450 | LL 8455 | LL 8460 | LL 8470 | LL 8501 | LL 8555 | LLP 8360 | LLP 8450 |
LLP 8455 | LLP 8460 | LLP 8470 | LLP 8555 | Possible additive packages : | 09 | 17 | 17BG | 19 |
19BG | 21 | 22 | 24 | 25 | 28 | 29 | 31 | 32 | 38 | 39 | 42 | 43 | 45 | 46 | 47 | 48
| 55 | 67 | 74 | 77 | 79 | 80 | 82 | BG | EL | KI | KW | RQ | X29 | X59 | X72 |
X74 | X75 | X76 | XR | XV | XW1 | XW2 | XZ1 | XZ2 | YB | YM | YMEX | ZA | ZB |
ZZ
—————————————————————————————————————————————————–
—————————————————————————————————————————————————–
The information and recommendations contained herein are, to the best of ExxonMobil’s knowledge and belief, accurate
and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current
available from ExxonMobil. The information and recommendations are offered for the user’s consideration and
examination. It is the user’s responsibility to satisfy itself that the product is suitable for the intended use. If buyer
repackages this product, it is the user’s responsibility to insure proper health, safety and other necessary information is
included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to
handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law,
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Revision Date: 24 Jun 2010
Page 10 of 10
______________________________________________________________________________________________________________________
re-publication or retransmission of this document, in whole or in part, is not permitted. The term, “ExxonMobil” is used
for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any
affiliates in which they directly or indirectly hold any interest.
—————————————————————————————————————————————————–
Internal Use Only
MHC: 0, 0, 0, 0, 0, 0
DGN: 4406375KCA (1010937)
—————————————————————————————————————————————————–
Copyright 2002 Exxon Mobil Corporation, All rights reserved
by | Sep 27, 2025
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Revision Date: 24 Jun 2010
Page 1 of 10
______________________________________________________________________________________________________________________
MATERIAL SAFETY DATA SHEET
SECTION 1 PRODUCT AND COMPANY IDENTIFICATION
PRODUCT
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Product Description: LLDPE without polymer processing aid, see Section 16 for applicable grades.
Product Code: 19889
Intended Use: Coatings, Extrusion and moulding, Film blowing
COMPANY IDENTIFICATION
Supplier: CIOL – EXXONMOBIL CHEMICAL CANADA
Division of Canada Imperial Oil Limited, an Affiliate of Exxon Mobil Corporation
240 4TH AVENUE S.W.
CALGARY, ALBERTA. T2P 3M9 Canada
24 Hour Health Emergency 519-339-2145
Transportation Emergency Phone 519-339-2145
Product Technical Information 800-668-0177
SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS
No Reportable Hazardous Substance(s) or Complex Substance(s).
NOTE: The product may contain varying levels of additives such as slip and antiblocking agents, antioxidants and
stabilizers.
SECTION 3 HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15).
POTENTIAL PHYSICAL / CHEMICAL EFFECTS
High dust levels may create potential for explosion. Spilled pellets present a slipping hazard on hard
surfaces. Contact with hot material can cause thermal burns which may result in permanent damage.
Material can accumulate static charges which may cause an ignition.
POTENTIAL HEALTH EFFECTS
Material is essentially non-toxic. However, if dust is generated, it could scratch the eyes and cause minor
irritation to the respiratory tract. When heated, the vapors/fumes given off may cause respiratory tract irritation.
NFPA Hazard ID: Health: 1 Flammability: 1 Reactivity: 0
HMIS Hazard ID: Health: 1 Flammability: 1 Reactivity: 0
SECTION 4 FIRST AID MEASURES
INHALATION
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Revision Date: 24 Jun 2010
Page 2 of 10
______________________________________________________________________________________________________________________
In case of adverse exposure to vapors and / or aerosols formed at elevated temperatures, immediately remove
the affected victim from exposure. Administer artificial respiration if breathing is stopped. Keep at rest.
SKIN CONTACT
For hot product: Immediately immerse in or flush affected area with large amounts of cold water to dissipate
heat. Cover with clean cotton sheeting or gauze and get prompt medical attention.
EYE CONTACT
Flush thoroughly with water. If irritation occurs, get medical assistance.
INGESTION
No adverse effects due to ingestion are expected.
SECTION 5 FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish
flames.
Inappropriate Extinguishing Media: Straight Streams of Water
FIRE FIGHTING
Fire Fighting Instructions: Assure an extended cooling down period to prevent re-ignition. Evacuate area.
Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. Firefighters
should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA).
Use water spray to cool fire exposed surfaces and to protect personnel.
Unusual Fire Hazards: High dust levels may create potential for explosion.
Hazardous Combustion Products: Smoke, Fume, Incomplete combustion products, Oxides of carbon,
Flammable hydrocarbons
FLAMMABILITY PROPERTIES
Flash Point [Method]: N/A
Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D
Autoignition Temperature: N/A
SECTION 6 ACCIDENTAL RELEASE MEASURES
NOTIFICATION PROCEDURES
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable
regulations. US regulations require reporting releases of this material to the environment which exceed the
applicable reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The
National Response Center can be reached at (800)424-8802.
SPILL MANAGEMENT
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Revision Date: 24 Jun 2010
Page 3 of 10
______________________________________________________________________________________________________________________
Land Spill: Spilled pellets present a slipping hazard on hard surfaces. Small Dry Spills: With clean shovel
place material into clean, dry container and cover loosely; move containers from spill area.
Water Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Warn other
shipping. Skim from surface.
Water spill and land spill recommendations are based on the most likely spill scenario for this material;
however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction
and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be
consulted. Note: Local regulations may prescribe or limit action to be taken.
ENVIRONMENTAL PRECAUTIONS
Prevent entry into waterways, sewers, basements or confined areas. For Large Spills: Cover spill with plastic
sheet or tarpaulin to minimize spreading.
SECTION 7 HANDLING AND STORAGE
HANDLING
Avoid elevated temperatures for prolonged periods of time. Prevent small spills and leakage to avoid slip
hazard. Avoid conditions which create dust. DO NOT handle, store or open near an open flame, sources of
heat or sources of ignition. Protect material from direct sunlight. Material can accumulate static charges which
may cause an electrical spark (ignition source). Care should be taken when storing and handling this product.
Apart from the specific nature of the polymer product, conditions such as humidity, sunlight, and temperature
have an influence on the way the product behaves during storage and handling. Special attention should be
paid to avoid inappropriate stacking of palletized bags or other package units. Indeed, polymer products may be
dimensionally unstable under certain conditions. Avoid conditions generating heat during transfer operations.
Loading/Unloading Temperature: [Ambient]
Transport Temperature: [Ambient]
Transport Pressure: [Ambient]
Static Accumulator: This material is a static accumulator.
STORAGE
The container choice, for example storage vessel, may effect static accumulation and dissipation. Store in a
cool, dry place with adequate ventilation. Keep away from incompatible materials, open flames, and high
temperatures. Do not store in open or unlabelled containers.
Storage Temperature: [Ambient]
Storage Pressure: [Ambient]
Suitable Containers/Packing: Bulk Containers; Hopper Cars; Bags; Boxes; Drums; Octatainer; Silos
Suitable Materials and Coatings (Chemical Compatibility): Aluminum; Polyethylene Bags
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure limits/standards for materials that can be formed when handling this product: For dusty conditions,
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Revision Date: 24 Jun 2010
Page 4 of 10
______________________________________________________________________________________________________________________
OSHA recommends for particulates not otherwise regulated an 8-hour TWA of 15 mg/m3 (total dust), 5 mg/m3
(respirable fraction); ACGIH recommends for insoluble and poorly soluble particles not otherwise specified an 8-hour
TWA of 10 mg/m3 (inhalable particles), 3 mg/m3 (respirable particles). Product may also contain varying levels of
additives, such as slip and antiblocking agents (talc or silica), antioxidants, stabilizers, and corrosion inhibitors. Certain
grades may contain cristobalite, a form of crystalline silica, as an additive that is encapsulated in the polymer. Inhaled
crystalline silica in an occupational environment is recognized as a known human carcinogen. However, the potential for
release of silica to the air when this polymer is handled has been assessed and the encapsulated silica within the
polymer is not expected to pose a health hazard when processed under normal conditions of use.
NOTE: Limits/standards shown for guidance only. Follow applicable regulations.
ENGINEERING CONTROLS
The level of protection and types of controls necessary will vary depending upon potential exposure conditions.
Control measures to consider:
Adequate ventilation should be provided so that exposure limits are not exceeded. SPECIAL
PRECAUTIONS: Should significant vapors/fumes be generated during thermal processing of this
product, it is recommended that work stations be monitored for the presence of thermal degradation
by-products which may evolve at elevated temperatures (for example, oxygenated components).
Processors of this product should assure that adequate ventilation or other controls are used to control
exposure. It is recommended that the current ACGIH-TLVs for thermal degradation by-products be
observed. Contact your local sales representative for further information.
PERSONAL PROTECTION
Personal protective equipment selections vary based on potential exposure conditions such as applications,
handling practices, concentration and ventilation. Information on the selection of protective equipment for use
with this material, as provided below, is based upon intended, normal usage.
Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a
level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator
selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of
respirators to be considered for this material include:
Half-face filter respirator
For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode.
Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate,
gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded.
Hand Protection: Any specific glove information provided is based on published literature and glove
manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions.
Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use
conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material
include:
If product is hot, thermally protective, chemical resistant gloves are recommended. If contact with
forearms is likely, wear gauntlet style gloves.
Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or
manufacturer data. The types of clothing to be considered for this material include:
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Revision Date: 24 Jun 2010
Page 5 of 10
______________________________________________________________________________________________________________________
If product is hot, thermally protective, chemical resistant apron and long sleeves are recommended.
Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after
handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned.
Practice good housekeeping.
ENVIRONMENTAL CONTROLS
See Sections 6, 7, 12, 13.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Typical physical and chemical properties are given below. Consult the Supplier in Section 1 for additional
data.
GENERAL INFORMATION
Physical State: Solid
Form: Pellet, Granule, Powder
Color: Clear to Opaque, White to Off-White
Odor: None to Mild
Odor Threshold: N/A
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION
Relative Density (at 15 C): 0.9 – 0.95
Bulk Density: 0.4 g/cc at 20 C – 1 g/cc at 20 C
Flash Point [Method]: N/A
Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D
Autoignition Temperature: N/A
Boiling Point / Range: N/A
Vapor Density (Air = 1): N/A
Vapor Pressure: N/A
Evaporation Rate (n-butyl acetate = 1): N/A
pH: N/A
Log Pow (n-Octanol/Water Partition Coefficient): N/A
Solubility in Water: Negligible
Viscosity: N/A
Oxidizing Properties: See Hazards Identification Section.
OTHER INFORMATION
Freezing Point: N/D
Melting Point: 115 C (239 F) – 130 C (266 F)
Molecular Weight: > 25000
Hygroscopic: No
SECTION 10 STABILITY AND REACTIVITY
STABILITY: Material is stable under normal conditions.
CONDITIONS TO AVOID: Avoid elevated temperatures for prolonged periods of time.
MATERIALS TO AVOID: Strong oxidizers
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Revision Date: 24 Jun 2010
Page 6 of 10
______________________________________________________________________________________________________________________
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures.
HAZARDOUS POLYMERIZATION: Will not occur.
SECTION 11 TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
Route of Exposure
Conclusion / Remarks
Inhalation
Toxicity: Data available. Minimally Toxic. Based on test data for structurally similar
materials.
Irritation: Data available. Negligible haz ard at ambient/normal handling temperatures.
Based on test data for structurally similar materials.
Ingestion
Toxicity: Data available. Minimally Toxic. Based on test data for structurally similar
materials.
Skin
Toxicity: Data available. Minimally Toxic. Based on test data for structurally similar
materials.
Irritation: Data available. Negl igible irritation to skin at ambient temperatures. Based on test
data for structurally similar materials.
Eye
Irritation: Data available. May cause mild, s hort-lasting discomfort to eyes. Based on test
data for structurally similar materials.
CHRONIC/OTHER EFFECTS
For the product itself:
Dust may be irritating to the eyes and respiratory tract.
Elevated temperatures or mechanical action may form vapors, mists or fumes which may be irritating to the
eyes and respiratory tract.
Contains additives that are encapsulated in the polymer. Under normal conditions of processing and use the
encapsulated additives are not expected to pose a health hazard, however, grinding of the polymer is not
recommended.
Additional information is available by request.
The following ingredients are cited on the lists below: None.
–REGULATORY LISTS SEARCHED–
1 = NTP CARC 3 = IARC 1 5 = IARC 2B
2 = NTP SUS 4 = IARC 2A 6 = OSHA CARC
SECTION 12 ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials.
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Revision Date: 24 Jun 2010
Page 7 of 10
______________________________________________________________________________________________________________________
ECOTOXICITY
Material — Not expected to be harmful to aquatic organisms.
Material — Not expected to be harmful to terrestrial organisms.
MOBILITY
Material — Low solubility and floats and is expected to migrate from water to the land. Expected to
partition to sediment and wastewater solids.
PERSISTENCE AND DEGRADABILITY
Biodegradation:
Material — Expected to be persistent.
Hydrolysis:
Material — Transformation due to hydrolysis not expected to be significant.
Photolysis:
Material — Transformation due to photolysis not expected to be significant.
Atmospheric Oxidation:
Material — Transformation due to atmospheric oxidation not expected to be significant.
BIOACCUMULATION POTENTIAL
Material — Potential to bioaccumulate is low.
SECTION 13 DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable
laws and regulations, and material characteristics at time of disposal.
DISPOSAL RECOMMENDATIONS
Suitable routes of disposal are supervised incineration, preferentially with energy recovery, or appropriate
recycling methods in accordance with applicable regulations and material characteristics at the time of disposal.
REGULATORY DISPOSAL INFORMATION
RCRA Information: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous
waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed as hazardous wastes. It
does not exhibit the hazardous characteristics of ignitability, corrositivity or reactivity and is not formulated with
contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used
product may be regulated.
SECTION 14 TRANSPORT INFORMATION
LAND (DOT): Not Regulated for Land Transport
LAND (TDG): Not Regulated for Land Transport
SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Revision Date: 24 Jun 2010
Page 8 of 10
______________________________________________________________________________________________________________________
AIR (IATA): Not Regulated for Air Transport
SECTION 15 REGULATORY INFORMATION
OSHA HAZARD COMMUNICATION STANDARD: When used for its intended purposes, this material is not
classified as hazardous in accordance with OSHA 29 CFR 1910.1200.
NATIONAL CHEMICAL INVENTORY LISTING: EINECS, TSCA
EPCRA: This material contains no extremely hazardous substances.
CWA / OPA: Plastic pellets are defined by the US EPA under the Clean Water Act (40CFR122.26) as a “significant
material” which requires any industrial plant that may expose pellets to storm water to secure a storm water permit.
Violations of the rule carry the same penalties as other Clean Water Act violations. Pellets found in storm water runoff
are subject to EPA regulations with the potential for substantial fines and penalties.
SARA (311/312) REPORTABLE HAZARD CATEGORIES: None.
SARA (313) TOXIC RELEASE INVENTORY: This material contains no chemicals subject to the supplier notification
requirements of the SARA 313 Toxic Release Program.
The following ingredients are cited on the lists below:* None.
–REGULATORY LISTS SEARCHED–
1 = ACGIH ALL 6 = TSCA 5a2 11 = CA P65 REPRO 16 = MN RTK
2 = ACGIH A1 7 = TSCA 5e 12 = CA RTK 17 = NJ RTK
3 = ACGIH A2 8 = TSCA 6 13 = IL RTK 18 = PA RTK
4 = OSHA Z 9 = TSCA 12b 14 = LA RTK 19 = RI RTK
5 = TSCA 4 10 = CA P65 CARC 15 = MI 293
Code key: CARC=Carcinogen; REPRO=Reproductive
* EPA recently added new chemical substances to its TSCA Section 4 test rules. Please contact the supplier to
confirm whether the ingredients in this product currently appear on a TSCA 4 or TSCA 12b list.
Contact Sales / Marketing group for complete chemical inventory listing applicable to product.
SECTION 16 OTHER INFORMATION
N/D = Not determined, N/A = Not applicable
THIS SAFETY DATA SHEET CONTAI NS THE FOLLOWING REVISIONS:
Revision Changes:
Section 10 Stability and Reactivity – Header was modified.
Section 13: Disposal Recommendations – Note was modified.
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Revision Date: 24 Jun 2010
Page 9 of 10
______________________________________________________________________________________________________________________
Section 08: Personal Protection was modified.
Section 07: Handling and Storage – Storage Phrases was modified.
Hazard Identification: Physical/Chemical Hazard was modified.
Section 07: Loading/Unloading Temperature C(F) was modified.
Section 07: Transport Temperature C(F) was modified.
Section 07: Transport Pressure kPa was modified.
Section 07: Storage Temperature C(F) was modified.
Section 07: Storage Pressure kPa was modified.
Section 07: Suitable Materials and Coatings – Header was modified.
Section 11: Dermal Lethality Test Comment was modified.
Section 05: Hazardous Combustion Products was modified.
Section 06: Accidental Release – Spill Management – Water was modified.
Section 09: Relative Density – Header was modified.
Section 08: Hand Protection was modified.
Section 14: Sea (IMDG) – Header was modified.
Section 14: Air (IATA) – Header was modified.
Section 14: LAND (TDG) – Header was modified.
Section 14: LAND (DOT) – Header was modified.
Section 15: List Citation Table – Header was modified.
Section 14: LAND (DOT) – Default was modified.
Section 14: LAND (TDG) Default was modified.
Section 14: Sea (IMDG) – Default was modified.
Section 14: Air (IATA) – Default was modified.
Section 15: National Chemical Inventory Listing was modified.
Section 08: Exposure limits/standards was modified.
Section 15: OSHA Hazard Communication Standard was modified.
Hazard Identification: OSHA – May be Hazardous Statement was modified.
Section 06: Notification Procedures was modified.
Composition: Footnotes was modified.
Section 11: Chronic Tox – Product was modified.
Section 09: Oxidizing Properties was modified.
THIS MSDS COVERS THE FOLLOWING MATERIALS: Linear Low Density PE grades for which the grade name
consists of a base polymer designated by a LL or LLP prefix followed by a suffix referring to an additive package.
Applicable designations follow. | Base polymers : | LL 1000S | LL 1001 | LL 1002 | LL 1004 | LL 1015
| LL 1030 | LL 1201 | LL 1433 | LL 3000S | LL 3001 | LL 3002 | LL 3003 | LL 3113 | LL 3201 |
LL 3402 | LL 3403 | LL 3404 | LL 3405 | LL 4004 | LL 5002 | LL 5100 | LL 5202 | LL 5252 | LL
60 | LL 6021 | LL 6100 | LL 6101 | LL 6201 | LL 6202 | LL 6235 | LL 6301 | LL 6407 | LL 8360 |
LL 8446 | LL 8450 | LL 8455 | LL 8460 | LL 8470 | LL 8501 | LL 8555 | LLP 8360 | LLP 8450 |
LLP 8455 | LLP 8460 | LLP 8470 | LLP 8555 | Possible additive packages : | 09 | 17 | 17BG | 19 |
19BG | 21 | 22 | 24 | 25 | 28 | 29 | 31 | 32 | 38 | 39 | 42 | 43 | 45 | 46 | 47 | 48
| 55 | 67 | 74 | 77 | 79 | 80 | 82 | BG | EL | KI | KW | RQ | X29 | X59 | X72 |
X74 | X75 | X76 | XR | XV | XW1 | XW2 | XZ1 | XZ2 | YB | YM | YMEX | ZA | ZB |
ZZ
—————————————————————————————————————————————————–
—————————————————————————————————————————————————–
The information and recommendations contained herein are, to the best of ExxonMobil’s knowledge and belief, accurate
and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current
available from ExxonMobil. The information and recommendations are offered for the user’s consideration and
examination. It is the user’s responsibility to satisfy itself that the product is suitable for the intended use. If buyer
repackages this product, it is the user’s responsibility to insure proper health, safety and other necessary information is
included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to
handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law,
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Revision Date: 24 Jun 2010
Page 10 of 10
______________________________________________________________________________________________________________________
re-publication or retransmission of this document, in whole or in part, is not permitted. The term, “ExxonMobil” is used
for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any
affiliates in which they directly or indirectly hold any interest.
—————————————————————————————————————————————————–
Internal Use Only
MHC: 0, 0, 0, 0, 0, 0
DGN: 4406375KCA (1010937)
—————————————————————————————————————————————————–
Copyright 2002 Exxon Mobil Corporation, All rights reserved
by | Sep 27, 2025
3M Platinum Plus , PN 0032, 01130, 01131, 01132, 01135B, 31181, 31139, 31632 08/03/23
________________________________________________________________________________________________________
Page 1 of 2
Safety Data Sheet
Copyright,2023, 3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed
provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither
the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document Group:24-8735-3Version Number:6.03Issue Date:08/03/23Supercedes Date:03/10/23
Product identifier
3M Platinum Plus , PN 0032, 01130, 01131, 01132, 01135B, 31181, 31139, 31632
ID Number(s):
41-0003-6598-5, 41-0003-6676-9, 41-0003-6712-2, 41-0003-6733-8, 41-0003-6789-0, 60-4550-4436-6, 60-4550-4793-0, 60-4550-
5371-4, 60-4550-5544-6, 60-4550-5548-7, 60-4550-6546-0, 60-4550-8115-2, 60-4550-8621-9, 70-0080-0095-5, 70-0080-0096-3
7000001498, 7010314197, 7000119981, 7000120072, 7100142876
Recommended use
Automotive, Auto Body Repair
Supplier’s details
MANUFACTURER:3MDIVISION:Automotive AftermarketADDRESS:3M Center, St. Paul, MN 55144-1000, USATelephone:1-888-3M HELPS (1-888-364-3577)
Emergency telephone number
1-800-364-3577 or (651) 737-6501 (24 hours)
This product is a kit or a multipart product which consists of multiple, independently packaged components. A Safety Data
Sheet (SDS), Article Information Sheet (AIS), or Article Information Letter (AIL) for each of these components is included.
Please do not separate the component documents from this cover page. The document numbers for components of this
product are:
29-5993-0, 24-8206-5
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO
WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user’s method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user’s knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user’s method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
3M Platinum Plus , PN 0032, 01130, 01131, 01132, 01135B, 31181, 31139, 31632 08/03/23
________________________________________________________________________________________________________
Page 2 of 2
In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M.
3M USA SDSs are available at www.3M.com
3M Cream Hardener (Red, White & Blue) 02/24/22
__________________________________________________________________________________________
Page 1 of 12
Safety Data Sheet
Copyright,2022, 3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document Group:29-5993-0Version Number:6.00Issue Date:02/24/22Supercedes Date:12/07/21
SECTION 1: Identification
1.1. Product identifier
3M Cream Hardener (Red, White & Blue)
Product Identification Numbers
LB-K100-0965-7, LB-K100-0965-8, LB-K100-0965-9, LB-K100-0966-0, LB-K100-0966-1, LB-K100-0966-2, LB-K100-
0966-3, LB-K100-1035-6, LB-K100-1045-4, LB-K100-1286-7, 41-0003-6674-4, 41-0003-6682-7, 41-0003-6685-0, 41-0003-
6686-8, 41-0003-6687-6, 41-0003-7901-0, 41-0003-7903-6, 41-0003-7904-4, 41-0003-7922-6, 41-0003-7928-3, 41-0003-
7930-9, 41-0003-7931-7, 41-0003-7932-5, 41-0003-7933-3, 41-0003-7935-8, 41-0003-7987-9, 41-0003-8059-6, 41-0003-
8072-9, 41-0003-8073-7, 41-0003-8074-5, 41-0003-8146-1, 60-4550-6617-9, 60-4550-6830-8, 60-4550-6981-9, 60-4550-
6982-7, 60-4550-8123-6, 60-4551-0388-1
7000120090, 7010327931, 7000120133, 7100191003
1.2. Recommended use and restrictions on use
Recommended use
Automotive, hardener for body fillers & glazes
1.3. Supplier s details
MANUFACTURER:3MDIVISION:Automotive AftermarketADDRESS:3M Center, St. Paul, MN 55144-1000, USATelephone:1-888-3M HELPS (1-888-364-3577)
1.4. Emergency telephone number
1-800-364-3577 or (651) 737-6501 (24 hours)
SECTION 2: Hazard identification
The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200.
This information may be different from the actual product label information for labels regulated by other agencies.
2.1. Hazard classification
Organic Peroxide: Type E.
Serious Eye Damage/Irritation: Category 2A.
Skin Sensitizer: Category 1B.
Specific Target Organ Toxicity (single exposure): Category 1.
2.2. Label elements
3M Cream Hardener (Red, White & Blue) 02/24/22
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Signal word
Danger
Symbols
Flame | Exclamation mark | Health Hazard |
Pictograms
Hazard Statements
Heating may cause a fire. Causes serious eye irritation. May cause an allergic skin reaction. Causes damage to organs: cardiovascular system | nervous system | kidney/urinary tract | respiratory system |
Precautionary Statements
General:
Keep out of reach of children.
Prevention:
Keep away from heat/sparks/open flames/hot surfaces. – No smoking. Keep away from clothing and other combustible materials. Keep only in original container. Do not breathe dust/fume/gas/mist/vapors/spray. Wear protective gloves and eye/face protection. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace.
Response:
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. IF exposed: Call a POISON CENTER or doctor/physician. Specific treatment (see Notes to Physician on this label).
Storage:
Protect from sunlight. Store at temperatures not exceeding 32C/90F. Keep cool. Store locked up. Store away from other materials.
3M Cream Hardener (Red, White & Blue) 02/24/22
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Disposal:
Dispose of contents/container in accordance with applicable local/regional/national/international regulations.
Notes to Physician:
This product contains ethylene glycol. If there is reasonable suspicion of ethylene glycol poisoning, intravenous (IV)
administration with either fomepizole (preferred) or ethanol (if fomepizole is unavailable) should be considered as part of the
medical management.
SECTION 3: Composition/information on ingredients
IngredientC.A.S. No.% by WtBenzoyl Peroxide94-36-0 30 – 60 Trade Secret *Benzoic Acid, C9-11-Branched Alkyl Esters131298-44-7 10 – 30 Trade Secret *Water7732-18-5 10 – 30 Trade Secret *Calcium Sulfate7778-18-9 1 – 10 Trade Secret *Zinc Stearate557-05-1 1 – 10 Trade Secret *Ethylene Glycol107-21-1<= 7.5 Trade Secret *Iron Oxide (FE2O3)1309-37-1<= 5 Trade Secret *Oxirane, Polymer with Methyloxirane, Monobutyl Ether9038-95-3<= 5 Trade Secret *Ferric Ammonium Ferrocyanide25869-00-5<= 1 Trade Secret *Ferric Ferrocyanide14038-43-8<= 1 Trade Secret *
*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.
Skin Contact:
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get
medical attention.
Eye Contact:
Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention.
If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
Allergic skin reaction (redness, swelling, blistering, and itching). Target organ effects. See Section 11 for additional details.
4.3. Indication of any immediate medical attention and special treatment required
This product contains ethylene glycol. If there is reasonable suspicion of ethylene glycol poisoning, intravenous (IV) administration with
either fomepizole (preferred) or ethanol (if fomepizole is unavailable) should be considered as part of the medical management.
SECTION 5: Fire-fighting measures
5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.
5.2. Special hazards arising from the substance or mixture
3M Cream Hardener (Red, White & Blue) 02/24/22
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Page 4 of 12
Closed containers exposed to heat from fire may build pressure and explode. Part of the oxygen for combustion is supplied
by the peroxide itself.
5.3. Special protective actions for fire-fighters
Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus,
bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Eliminate all ignition sources if safe to do so. Keep away from heat/sparks/open flames/hot surfaces. - No
smoking. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces,
provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning!
A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to
other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and
personal protective equipment.
6.2. Environmental precautions
Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or
bodies of water.
6.3. Methods and material for containment and cleaning up
Collect as much of the spilled material as possible using non-sparking tools. Place in a closed container approved for
transportation by appropriate authorities. Clean up residue. Seal the container. Dispose of collected material as soon as
possible in accordance with applicable local/regional/national/international regulations.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Do not use in a confined area with minimal air exchange. Keep out of reach of children. Keep away from heat/sparks/open
flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on
clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work
clothing should not be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing
before reuse.
7.2. Conditions for safe storage including any incompatibilities
Keep container tightly closed. Protect from sunlight. Store away from heat. Store at temperatures not exceeding
32C/90F. Keep cool. Keep only in original container. Store away from other materials. Keep/store away from clothing
and other combustible materials.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Occupational exposure limits
If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
IngredientC.A.S. No.AgencyLimit typeAdditional CommentsEthylene Glycol107-21-1ACGIHTWA(Vapor fraction):25
ppm;STEL(Vapor fraction):50
ppm;STEL(Inhalable
aerosol):10 mg/m3
A4: Not class. as human
carcin
Iron Oxide (FE2O3)1309-37-1ACGIHTWA(respirable fraction):5
mg/m3
A4: Not class. as human
carcin
3M Cream Hardener (Red, White & Blue) 02/24/22
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Iron Oxide (FE2O3)1309-37-1OSHATWA(as fume):10 mg/m3CYANIDES14038-43-8OSHATWA(as CN):5 mg/m3SKINZinc Stearate557-05-1OSHATWA(as total dust):15
mg/m3;TWA(respirable
fraction):5 mg/m3
Calcium Sulfate7778-18-9ACGIHTWA(inhalable fraction):10
mg/m3
Calcium Sulfate7778-18-9OSHATWA(as total dust):15
mg/m3;TWA(respirable
fraction):5 mg/m3
Benzoyl Peroxide94-36-0ACGIHTWA:5 mg/m3A4: Not class. as human
carcin
Benzoyl Peroxide94-36-0OSHATWA:5 mg/m3
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Guidelines
OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Provide ventilation adequate to maintain dust concentration below minimum explosive concentrations. Use general dilution
ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control
dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Indirect Vented Goggles
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity.
Gloves made from the following material(s) are recommended: Polymer laminate
If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then
use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an
exposure assessment. The following protective clothing material(s) are recommended: Apron - polymer laminate
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part
of a full respiratory protection program. Based on the results of the exposure assessment, select from the following
respirator type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
3M Cream Hardener (Red, White & Blue) 02/24/22
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SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance
Physical state
Color
Solid
Red
Specific Physical Form: PasteOdorSlight EsterOdor thresholdNo Data AvailablepHNo Data AvailableMelting pointNo Data AvailableBoiling PointNo Data AvailableFlash Point111 C [ Test Method:Estimated]Evaporation rateNo Data AvailableFlammability (solid, gas)Organic Peroxide: Type E.Flammable Limits(LEL)Not ApplicableFlammable Limits(UEL)Not ApplicableVapor PressureNot ApplicableVapor DensityNot ApplicableDensity1.2 g/cm3Specific Gravity1.2 [@ 25 C] [Ref Std:WATER=1]Solubility in WaterNegligibleSolubility- non-waterNo Data AvailablePartition coefficient: n-octanol/ waterNo Data AvailableAutoignition temperatureNo Data AvailableDecomposition temperatureNo Data AvailableViscosityNo Data AvailableHazardous Air Pollutants0 - 0.1209 lb HAPS/lb solids [Test Method:Calculated]Molecular weightNot ApplicableVolatile Organic Compounds0 - 90 g/l [ Test Method:calculated SCAQMD rule 443.1]Volatile Organic Compounds0 % weight [Test Method: calculated per CARB title 2]Percent volatile21 - 28.5 %VOC Less H2O & Exempt Solvents0 - 121 g/l [ Test Method:calculated SCAQMD rule 443.1]
SECTION 10: Stability and reactivity
10.1. Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section.
10.2. Chemical stability
Stable. Stable unless exposed to heat, flames and drying conditions.
10.3. Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4. Conditions to avoid
Heat
10.5. Incompatible materials
Accelerators
10.6. Hazardous decomposition products
SubstanceCondition Carbon monoxide Not Specified
3M Cream Hardener (Red, White & Blue) 02/24/22
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Carbon dioxide Not Specified Toxic Vapor, Gas, Particulate Not Specified
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1. Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.
Skin Contact:
May be harmful in contact with skin.
Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.
Eye Contact:
Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the
cornea, and impaired vision.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
May cause additional health effects (see below).
Additional Health Effects:
Single exposure may cause target organ effects:
Cardiac Effects: Signs/symptoms may include irregular heartbeat (arrhythmia), changes in heart rate, damage to heart
muscle, heart attack, and may be fatal.
Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or
numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate.
Respiratory Effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart
rate, bluish colored skin (cyanosis), sputum production, changes in lung function tests, and/or respiratory failure.
Kidney/Bladder Effects: Signs/symptoms may include changes in urine production, abdominal or lower back pain,
increased protein in urine, increased blood urea nitrogen (BUN), blood in urine, and painful urination.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
NameRouteSpeciesValue
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Overall productDermalNo data available; calculated ATE >2,000 – 5,000
mg/kg
Overall productInhalation-
Dust/Mist(4
hr)
No data available; calculated ATE >12.5 mg/lOverall productIngestionNo data available; calculated ATE >5,000 mg/kgBenzoyl PeroxideDermalLD50 estimated to be 2,000 – 5,000 mg/kgBenzoyl PeroxideInhalation-
Dust/Mist
(4 hours)
RatLC50 > 24.3 mg/lBenzoyl PeroxideIngestionRatLD50 > 5,000 mg/kgBenzoic Acid, C9-11-Branched Alkyl EstersDermalRabbitLD50 > 2,000 mg/kgBenzoic Acid, C9-11-Branched Alkyl EstersInhalation-
Dust/Mist
(4 hours)
RatLC50 > 5 mg/lBenzoic Acid, C9-11-Branched Alkyl EstersIngestionRatLD50 > 5,000 mg/kgCalcium SulfateDermalProfessio
nal
judgeme
nt
LD50 estimated to be > 5,000 mg/kgCalcium SulfateIngestionRatLD50 > 5,000 mg/kgZinc StearateDermalRabbitLD50 > 2,000 mg/kgZinc StearateInhalation-
Dust/Mist
(4 hours)
RatLC50 > 50 mg/lZinc StearateIngestionRatLD50 > 5,000 mg/kgEthylene GlycolIngestionHumanLD50 1,600 mg/kgEthylene GlycolInhalation-
Dust/Mist
(4 hours)
OtherLC50 estimated to be 5 – 12.5 mg/lEthylene GlycolDermalRabbit 9,530 mg/kgIron Oxide (FE2O3)DermalNot
available
LD50 3,100 mg/kgIron Oxide (FE2O3)IngestionNot
available
LD50 3,700 mg/kgOxirane, Polymer with Methyloxirane, Monobutyl EtherDermalRabbitLD50 > 16,960 mg/kgOxirane, Polymer with Methyloxirane, Monobutyl EtherInhalation-
Dust/Mist
(4 hours)
RatLC50 > 5 mg/lOxirane, Polymer with Methyloxirane, Monobutyl EtherIngestionRatLD50 4,240 mg/kgFerric Ammonium FerrocyanideDermalLD50 estimated to be > 5,000 mg/kgFerric FerrocyanideDermalLD50 estimated to be > 5,000 mg/kgFerric Ammonium FerrocyanideIngestionRatLD50 > 5,110 mg/kgFerric FerrocyanideIngestionRatLD50 > 8,000 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
NameSpeciesValueBenzoyl PeroxideRabbitMinimal irritationZinc StearateRabbitNo significant irritationEthylene GlycolRabbitMinimal irritationIron Oxide (FE2O3)RabbitNo significant irritationOxirane, Polymer with Methyloxirane, Monobutyl EtherRabbitMinimal irritation
Serious Eye Damage/Irritation
NameSpeciesValueBenzoyl PeroxideRabbitSevere irritantZinc StearateRabbitNo significant irritationEthylene GlycolRabbitMild irritantIron Oxide (FE2O3)RabbitNo significant irritationOxirane, Polymer with Methyloxirane, Monobutyl EtherRabbitNo significant irritation
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Skin Sensitization
NameSpeciesValueBenzoyl PeroxideGuinea
pig
SensitizingEthylene GlycolHumanNot classifiedIron Oxide (FE2O3)HumanNot classified
Respiratory Sensitization
For the component/components, either no data are currently available or the data are not sufficient for classification.
Germ Cell Mutagenicity
NameRouteValueBenzoyl PeroxideIn VitroNot mutagenicBenzoyl PeroxideIn vivoNot mutagenicEthylene GlycolIn VitroNot mutagenicEthylene GlycolIn vivoNot mutagenicIron Oxide (FE2O3)In VitroNot mutagenic
Carcinogenicity
NameRouteSpeciesValueBenzoyl PeroxideIngestionMultiple
animal
species
Not carcinogenicBenzoyl PeroxideDermalMouseSome positive data exist, but the data are not
sufficient for classification
Ethylene GlycolIngestionMultiple
animal
species
Not carcinogenicIron Oxide (FE2O3)InhalationHumanSome positive data exist, but the data are not
sufficient for classification
Oxirane, Polymer with Methyloxirane, Monobutyl EtherIngestionRatNot carcinogenic
Reproductive Toxicity
Reproductive and/or Developmental Effects
NameRouteValueSpeciesTest Result Exposure
Duration
Benzoyl PeroxideIngestionNot classified for female reproductionRatNOAEL 1,000
mg/kg/day
premating &
during
gestation
Benzoyl PeroxideIngestionNot classified for male reproductionRatNOAEL 500
mg/kg/day
premating &
during
gestation
Benzoyl PeroxideIngestionNot classified for developmentRatNOAEL 500
mg/kg/day
premating &
during
gestation
Ethylene GlycolDermalNot classified for developmentMouseNOAEL 3,549
mg/kg/day
during
organogenesi
s
Ethylene GlycolIngestionNot classified for developmentMouseLOAEL 750
mg/kg/day
during
organogenesi
s
Ethylene GlycolInhalationNot classified for developmentMouseNOAEL 1,000
mg/kg/day
during
organogenesi
s
Oxirane, Polymer with Methyloxirane,
Monobutyl Ether
InhalationNot classified for male reproductionRatNOAEL 1
mg/l
2 weeks
Target Organ(s)
Specific Target Organ Toxicity – single exposure
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NameRouteTarget Organ(s)ValueSpeciesTest Result Exposure
Duration
Ethylene GlycolIngestionheart | nervous
system | kidney
and/or bladder |
respiratory system
Causes damage to organsHumanNOAEL Not
available
poisoning
and/or abuse
Ethylene GlycolIngestioncentral nervous
system depression
May cause drowsiness or
dizziness
HumanNOAEL Not
available
poisoning
and/or abuse
Ethylene GlycolIngestionliverNot classifiedHumanNOAEL Not
available
poisoning
and/or abuse
Oxirane, Polymer with
Methyloxirane, Monobutyl
Ether
Ingestionnervous systemNot classifiedRatNOAEL Not
available
Specific Target Organ Toxicity – repeated exposure
NameRouteTarget Organ(s)ValueSpeciesTest Result Exposure
Duration
Ethylene GlycolIngestionkidney and/or
bladder
Some positive data exist, but the
data are not sufficient for
classification
RatNOAEL 200
mg/kg/day
2 yearsEthylene GlycolIngestionvascular systemNot classifiedRatNOAEL 200
mg/kg/day
2 yearsEthylene GlycolIngestionheart |
hematopoietic
system | liver |
immune system |
muscles
Not classifiedRatNOAEL
1,000
mg/kg/day
2 yearsEthylene GlycolIngestionrespiratory systemNot classifiedMouseNOAEL
12,000
mg/kg/day
2 yearsEthylene GlycolIngestionskin | endocrine
system | bone, teeth,
nails, and/or hair |
nervous system |
eyes
Not classifiedMultiple
animal
species
NOAEL
1,000
mg/kg/day
2 yearsIron Oxide (FE2O3)Inhalationpulmonary fibrosis |
pneumoconiosis
Not classifiedHumanNOAEL Not
available
occupational
exposure
Oxirane, Polymer with
Methyloxirane, Monobutyl
Ether
Inhalationendocrine system |
hematopoietic
system | liver |
nervous system
Not classifiedRatNOAEL 1
mg/l
2 weeksOxirane, Polymer with
Methyloxirane, Monobutyl
Ether
Inhalationkidney and/or
bladder
Not classifiedRatNOAEL
0.005 mg/l
2 weeksOxirane, Polymer with
Methyloxirane, Monobutyl
Ether
Inhalationrespiratory systemNot classifiedRatLOAEL
0.001 mg/l
2 weeksOxirane, Polymer with
Methyloxirane, Monobutyl
Ether
InhalationheartNot classifiedRatNOAEL 0.5
mg/l
2 weeksOxirane, Polymer with
Methyloxirane, Monobutyl
Ether
Ingestionliver | kidney and/or
bladder
Some positive data exist, but the
data are not sufficient for
classification
RatNOAEL 145
mg/kg/day
90 daysOxirane, Polymer with
Methyloxirane, Monobutyl
Ether
Ingestionhematopoietic
system
Not classifiedRatNOAEL 500
mg/kg/day
2 yearsOxirane, Polymer with
Methyloxirane, Monobutyl
Ether
Ingestionheart | endocrine
system | respiratory
system
Not classifiedRatNOAEL
3,770
mg/kg/day
90 days
Aspiration Hazard
For the component/components, either no data are currently available or the data are not sufficient for classification.
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
3M Cream Hardener (Red, White & Blue) 02/24/22
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SECTION 12: Ecological information
Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.
SECTION 13: Disposal considerations
13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.
Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste
incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Empty
drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations
classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes
unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the
available treatment and disposal facilities.
SECTION 14: Transport Information
For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.
SECTION 15: Regulatory information
15.1. US Federal Regulations
Contact 3M for more information.
EPCRA 311/312 Hazard Classifications:
Physical HazardsOrganic peroxideHealth HazardsRespiratory or Skin SensitizationSerious eye damage or eye irritationSpecific target organ toxicity (single or repeated exposure)
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
IngredientC.A.S. No% by WtEthylene Glycol 107-21-1 Trade Secret <= 7.5Zinc Stearate (ZINC COMPOUNDS) 557-05-1 Trade Secret 1 - 10Benzoyl Peroxide 94-36-0 Trade Secret 30 - 60Ferric Ferrocyanide (CYANIDES) 14038-43-8 Trade Secret <= 1
15.2. State Regulations
Contact 3M for more information.
3M Cream Hardener (Red, White & Blue) 02/24/22
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15.3. Chemical Inventories
The components of this product are in compliance with the chemical notification requirements of TSCA. All required
components of this product are listed on the active portion of the TSCA Inventory.
Contact 3M for more information.
15.4. International Regulations
Contact 3M for more information.
This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: Other information
NFPA Hazard Classification
Health: 2 Flammability: 1 Instability: 0 Special Hazards: Oxidizer
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
HMIS Hazard Classification
Health: 4 Flammability: 1 Physical Hazard: 0 Personal Protection: X - See PPE section.
Hazardous Material Identification System (HMIS IV) hazard ratings are designed to inform employees of chemical hazards
in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use
and are not intended for use in emergency situations. HMIS IV ratings are to be used with a fully implemented HMIS IV
program. HMIS is a registered mark of the American Coatings Association (ACA).
Document Group:29-5993-0Version Number:6.00Issue Date:02/24/22Supercedes Date:12/07/21
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M.
3M USA SDSs are available at www.3M.com
3M Platinum Plus Filler, PN 0032, 01130, 01131, 01132, 01135, 01135B, 31135, 31181, 31139, 31361 02/15/23
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Page 1 of 15
Safety Data Sheet
Copyright,2023, 3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document Group:24-8206-5Version Number:11.00Issue Date:02/15/23Supercedes Date:11/09/22
SECTION 1: Identification
1.1. Product identifier
3M Platinum Plus Filler, PN 0032, 01130, 01131, 01132, 01135, 01135B, 31135, 31181, 31139, 31361
Product Identification Numbers
LB-K100-0535-1, LB-K100-0535-2, LB-K100-0535-3, LB-K100-0601-5, LB-K100-1029-4, LB-K100-1959-7, LB-K100-
0913-2, 41-0003-6573-8, 41-0003-6595-1, 41-0003-7943-2, 41-3588-1070-7, 60-4550-5270-8, 60-4550-7279-7, 70-0080-
0094-8, 70-0080-0097-1
7000125034, 4010033246
1.2. Recommended use and restrictions on use
Recommended use
Automotive, Body Repair
1.3. Supplier s details
MANUFACTURER:3MDIVISION:Automotive AftermarketADDRESS:3M Center, St. Paul, MN 55144-1000, USATelephone:1-888-3M HELPS (1-888-364-3577)
1.4. Emergency telephone number
1-800-364-3577 or (651) 737-6501 (24 hours)
SECTION 2: Hazard identification
The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200.
This information may be different from the actual product label information for labels regulated by other agencies.
2.1. Hazard classification
Flammable Liquid: Category 3.
Serious Eye Damage/Irritation: Category 2A.
Skin Corrosion/Irritation: Category 2.
Carcinogenicity: Category 1A.
Specific Target Organ Toxicity (single exposure): Category 1.
Specific Target Organ Toxicity (single exposure): Category 3.
Specific Target Organ Toxicity (repeated exposure): Category 1.
2.2. Label elements
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Signal word
Danger
Symbols
Flame | Exclamation mark | Health Hazard |
Pictograms
Hazard Statements
Flammable liquid and vapor. Causes serious eye irritation. Causes skin irritation. May cause respiratory irritation. May cause drowsiness or dizziness. May cause cancer. Causes damage to organs: liver | sensory organs | Causes damage to organs through prolonged or repeated exposure: respiratory system | sensory organs | May cause damage to organs through prolonged or repeated exposure: liver |
Precautionary Statements
General:
Keep out of reach of children.
Prevention:
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use explosion-proof electrical/ventilating/lighting equipment. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves and eye/face protection. Do not eat, drink or smoke when using this product. Wash thoroughly after handling.
Response:
IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
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Wash contaminated clothing before reuse. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention. If skin irritation occurs: Get medical advice/attention. IF exposed or concerned: Get medical advice/attention. In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to
extinguish.
Storage:
Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up.
Disposal:
Dispose of contents/container in accordance with applicable local/regional/national/international regulations.
24% of the mixture consists of ingredients of unknown acute oral toxicity.
24% of the mixture consists of ingredients of unknown acute dermal toxicity.
26% of the mixture consists of ingredients of unknown acute inhalation toxicity.
SECTION 3: Composition/information on ingredients
IngredientC.A.S. No.% by WtStyrene Monomer100-42-5 10 - 30 Trade Secret *Talc14807-96-6 7 - 30 Trade Secret *Polyester PolymerTrade Secret* 10 - 30 Trade Secret *Proprietary Polyester ResinTrade Secret* 10 - 30 Trade Secret *Inert FillerTrade Secret* 5 - 10 Trade Secret *Limestone1317-65-3 1 - 5 Trade Secret *Magnesium Carbonate546-93-0 1 - 5 Trade Secret *Titanium Dioxide13463-67-7 1 - 5 Trade Secret *Organophilic PhyllosilicateTrade Secret* 1 - 5 Trade Secret *Chlorite (Mineral)1318-59-8< 3 Trade Secret *Zinc Phosphate7779-90-0 0.5 - 2.5 Trade Secret *PolyamideTrade Secret*< 2 Trade Secret *Paraffin Wax8002-74-2 0.1 - 1 Trade Secret *Poly(oxypropylene)diamine9046-10-0 0.1 - 1 Trade Secret *Quartz Silica14808-60-7< 0.3 Trade Secret *
*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.
Skin Contact:
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get
medical attention.
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Eye Contact:
Immediately flush with large amounts of water for at least 15 minutes. Remove contact lenses if easy to do. Continue rinsing.
Immediately get medical attention.
If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
Irritating to the respiratory tract (coughing, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain). Central nervous
system depression (headache, dizziness, drowsiness, incoordination, nausea, slurred speech, giddiness, and unconsciousness). Target organ
effects. See Section 11 for additional details. Target organ effects following prolonged or repeated exposure. See Section 11 for
additional details.
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish.
5.2. Special hazards arising from the substance or mixture
Closed containers exposed to heat from fire may build pressure and explode.
Hazardous Decomposition or By-Products
Substance ConditionHydrocarbonsDuring CombustionCarbon monoxideDuring CombustionCarbon dioxideDuring Combustion
5.3. Special protective actions for fire-fighters
Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and
prevent explosive rupture. Wear full protective clothing, including helmet, self-contained, positive pressure or pressure
demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering
for exposed areas of the head.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools.
Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or
exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and
could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for
information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions
Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or
bodies of water.
6.3. Methods and material for containment and cleaning up
Contain spill. Cover spill area with a fire-extinguishing foam. Working from around the edges of the spill inward, cover
with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it
appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard.
Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for
transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and
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authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal
the container. Dispose of collected material as soon as possible in accordance with applicable
local/regional/national/international regulations.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Keep away from
heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Take precautionary measures against
static discharge. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat,
drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. Avoid
contact with oxidizing agents (eg. chlorine, chromic acid etc.) Wear low static or properly grounded shoes. Use personal
protective equipment (gloves, respirators, etc.) as required. To minimize the risk of ignition, determine applicable electrical
classifications for the process using this product and select specific local exhaust ventilation equipment to avoid flammable
vapor accumulation. Ground/bond container and receiving equipment if there is potential for static electricity accumulation
during transfer.
7.2. Conditions for safe storage including any incompatibilities
Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store away from heat. Store away from
acids. Store away from strong bases. Store away from oxidizing agents.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Occupational exposure limits
If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
IngredientC.A.S. No.AgencyLimit typeAdditional CommentsStyrene Monomer100-42-5ACGIHTWA:10 ppm;STEL:20 ppmA3: Confirmed animal
carcin., Ototoxicant
Styrene Monomer100-42-5OSHATWA:100 ppm;CEIL:200 ppmLimestone1317-65-3OSHATWA(as total dust):15
mg/m3;TWA(respirable
fraction):5 mg/m3
Titanium Dioxide13463-67-7ACGIHTWA(Respirable nanoscale
particles):0.2
mg/m3;TWA(Respirable
finescale particles):2.5 mg/m3
A3: Confirmed animal
carcin.
Titanium Dioxide13463-67-7OSHATWA(as total dust):15 mg/m3Talc14807-96-6ACGIHTWA(respirable fraction):2
mg/m3
A4: Not class. as human
carcin
Talc14807-96-6OSHATWA
concentration(respirable):0.1
mg/m3(2.4 millions of
particles/cu. ft.);TWA:20
millions of particles/cu. ft.
Quartz Silica14808-60-7ACGIHTWA(respirable
fraction):0.025 mg/m3
A2: Suspected human
carcin.
Quartz Silica14808-60-7OSHATWA Table Z-
1(respirable):0.05
mg/m3;TWA Table Z-
3(respirable):0.1 mg/m3;TWA
concentration(respirable):0.1
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mg/m3(2.4 millions of
particles/cu. ft.)
Magnesium Carbonate546-93-0OSHATWA(as total dust):15
mg/m3;TWA(respirable
fraction):5 mg/m3
Paraffin Wax8002-74-2ACGIHTWA(as fume):2 mg/m3Inert FillerTrade
Secret
Manufacturer
determined
TWA(as non-fibrous,
respirable)(8 hours):3
mg/m3;TWA(as non-fibrous,
inhalable fraction)(8 hours):10
mg/m3
Inert FillerTrade
Secret
ACGIHTWA(as fiber):0.2 fiber/ccA2: Suspected human
carcin.
Inert FillerTrade
Secret
ACGIHTWA(as fiber):1 fiber/ccA3: Confirmed animal
carcin.
Inert FillerTrade
Secret
ACGIHTWA(as fiber):1 fiber/ccA4: Not class. as human
carcin
Inert FillerTrade
Secret
ACGIHTWA(inhalable fraction):5
mg/m3
A4: Not class. as human
carcin
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Guidelines
OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.
Use explosion-proof ventilation equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Safety Glasses with side shields
Indirect Vented Goggles
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity.
Gloves made from the following material(s) are recommended: Polymer laminate
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part
of a full respiratory protection program. Based on the results of the exposure assessment, select from the following
respirator type(s) to reduce inhalation exposure:
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Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance
Physical state
Color
Liquid
Gold
Specific Physical Form: PasteOdorPungent StyreneOdor thresholdNo Data AvailablepHNo Data AvailableMelting pointNo Data AvailableBoiling Point293 FFlash Point88 F [Test Method:Closed Cup]Evaporation rate0.1 - 0.5 [Ref Std:BUOAC=1]Flammability (solid, gas)Not ApplicableFlammable Limits(LEL)0.9 % [Details:based on styrene]Flammable Limits(UEL)6.8 % [Details:based on styrene]Vapor Pressure4.5 mmHgVapor Density3.6 [Ref Std:AIR=1]Density0.984 g/mlSpecific Gravity0.984 [Ref Std:WATER=1]Solubility in WaterNegligibleSolubility- non-waterNo Data AvailablePartition coefficient: n-octanol/ waterNo Data AvailableAutoignition temperatureNo Data AvailableDecomposition temperatureNo Data AvailableViscosity144,000 centipoise - 168,000 centipoiseHazardous Air Pollutants0.617 lb HAPS/lb solids [Test Method:Calculated]Volatile Organic Compounds23.7 % weight [Test Method: calculated per CARB title 2]Volatile Organic Compounds233 g/l [Test Method:calculated SCAQMD rule 443.1]Percent volatile24.1 % weightPercent volatile26.2 % volumeVOC Less H2O & Exempt Solvents234 g/l [Test Method:calculated SCAQMD rule 443.1]Solids Content38.2 % weight
SECTION 10: Stability and reactivity
10.1. Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section.
10.2. Chemical stability
Stable. Stable under normal conditions. May become unstable at elevated temperatures and/or pressure.
10.3. Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4. Conditions to avoid
Sparks and/or flames
Heat
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10.5. Incompatible materials
Strong acids
Strong oxidizing agents
Alkali and alkaline earth metals
Strong bases
10.6. Hazardous decomposition products
SubstanceCondition None known.
Refer to section 5.2 for hazardous decomposition products during combustion.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1. Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation:
May be harmful if inhaled.
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and
nose and throat pain.
May cause additional health effects (see below).
Skin Contact:
Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain.
Eye Contact:
Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the
cornea, and impaired vision.
Ingestion:
May be harmful if swallowed.
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
May cause additional health effects (see below).
Additional Health Effects:
Single exposure may cause target organ effects:
Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears.
Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and
jaundice.
Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination,
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nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness.
Prolonged or repeated exposure may cause target organ effects:
Pneumoconiosis: Sign/symptoms may include persistent cough, breathlessness, chest pain, increased amounts of sputum,
and changes in lung function tests.
Ocular Effects: Signs/symptoms may include blurred or significantly impaired vision.
Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears.
Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and
jaundice.
Carcinogenicity:
Contains a chemical or chemicals which can cause cancer.
IngredientCAS No.Class DescriptionRegulationSilica, Crystalline (Respirable Size)14808-60-7Known To Be Human Carcinogen.National Toxicology Program CarcinogensInert FillerTrade SecretGrp. 2B: Possible human carc.International Agency for Research on CancerInert FillerTrade SecretAnticipated human carcinogenNational Toxicology Program CarcinogensSilica dust, crystalline, in the form of quartz
or cristobalite
14808-60-7Grp. 1: Carcinogenic to humansInternational Agency for Research on CancerStyrene100-42-5Grp. 2A: Probable human carc.International Agency for Research on CancerStyrene100-42-5Anticipated human carcinogenNational Toxicology Program CarcinogensTitanium dioxide13463-67-7Grp. 2B: Possible human carc.International Agency for Research on Cancer
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
NameRouteSpeciesValueOverall productDermalNo data available; calculated ATE >5,000 mg/kgOverall productInhalation-
Vapor(4 hr)
No data available; calculated ATE >20 – =50 mg/lOverall productIngestionNo data available; calculated ATE >2,000 – =5,000
mg/kg
Styrene MonomerDermalRatLD50 > 2,000 mg/kgStyrene MonomerInhalation-
Vapor (4
hours)
RatLC50 11.8 mg/lStyrene MonomerIngestionRatLD50 5,000 mg/kgTalcDermalLD50 estimated to be > 5,000 mg/kgTalcIngestionLD50 estimated to be > 5,000 mg/kgPolyester PolymerDermalLD50 estimated to be > 5,000 mg/kgPolyester PolymerIngestionLD50 estimated to be 2,000 – 5,000 mg/kgInert FillerDermalLD50 estimated to be > 5,000 mg/kgInert FillerIngestionLD50 estimated to be 2,000 – 5,000 mg/kgLimestoneDermalRatLD50 > 2,000 mg/kgLimestoneInhalation-
Dust/Mist
(4 hours)
RatLC50 3 mg/lLimestoneIngestionRatLD50 6,450 mg/kgMagnesium CarbonateDermalProfessio
nal
judgeme
nt
LD50 estimated to be 2,000 – 5,000 mg/kgMagnesium CarbonateIngestionRatLD50 > 2,000 mg/kgChlorite (Mineral)DermalLD50 estimated to be > 5,000 mg/kg
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Chlorite (Mineral)IngestionLD50 estimated to be > 5,000 mg/kgTitanium DioxideDermalRabbitLD50 > 10,000 mg/kgTitanium DioxideInhalation-
Dust/Mist
(4 hours)
RatLC50 > 6.82 mg/lTitanium DioxideIngestionRatLD50 > 10,000 mg/kgZinc PhosphateDermalLD50 estimated to be > 5,000 mg/kgZinc PhosphateIngestionRatLD50 > 5,000 mg/kgPolyamideDermalLD50 estimated to be > 5,000 mg/kgPolyamideIngestionLD50 estimated to be 2,000 – 5,000 mg/kgPoly(oxypropylene)diamineDermalRabbitLD50 2,090 mg/kgParaffin WaxDermalRatLD50 > 5,000 mg/kgParaffin WaxIngestionRatLD50 > 5,000 mg/kgPoly(oxypropylene)diamineIngestionRatLD50 475 mg/kgQuartz SilicaDermalLD50 estimated to be > 5,000 mg/kgQuartz SilicaIngestionLD50 estimated to be > 5,000 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
NameSpeciesValueStyrene MonomerProfessio
nal
judgeme
nt
Mild irritantTalcRabbitNo significant irritationInert FillerProfessio
nal
judgeme
nt
No significant irritationLimestoneRabbitNo significant irritationMagnesium CarbonateIn vitro
data
No significant irritationChlorite (Mineral)Professio
nal
judgeme
nt
No significant irritationTitanium DioxideRabbitNo significant irritationParaffin WaxRabbitNo significant irritationPoly(oxypropylene)diamineRabbitCorrosiveQuartz SilicaProfessio
nal
judgeme
nt
No significant irritation
Serious Eye Damage/Irritation
NameSpeciesValueStyrene MonomerProfessio
nal
judgeme
nt
Moderate irritantTalcRabbitNo significant irritationInert FillerProfessio
nal
judgeme
nt
No significant irritationLimestoneRabbitNo significant irritationMagnesium CarbonateRabbitMild irritantChlorite (Mineral)Professio
nal
judgeme
nt
No significant irritation
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Titanium DioxideRabbitNo significant irritationParaffin WaxRabbitNo significant irritationPoly(oxypropylene)diamineRabbitCorrosive
Skin Sensitization
NameSpeciesValueStyrene MonomerGuinea
pig
Not classifiedTitanium DioxideHuman
and
animal
Not classifiedParaffin WaxGuinea
pig
Not classified
Respiratory Sensitization
NameSpeciesValueTalcHumanNot classified
Germ Cell Mutagenicity
NameRouteValueStyrene MonomerIn VitroSome positive data exist, but the data are not
sufficient for classification
Styrene MonomerIn vivoSome positive data exist, but the data are not
sufficient for classification
TalcIn VitroNot mutagenicTalcIn vivoNot mutagenicInert FillerIn VitroSome positive data exist, but the data are not
sufficient for classification
Titanium DioxideIn VitroNot mutagenicTitanium DioxideIn vivoNot mutagenicParaffin WaxIn VitroNot mutagenicPoly(oxypropylene)diamineIn VitroNot mutagenicPoly(oxypropylene)diamineIn vivoNot mutagenicQuartz SilicaIn VitroSome positive data exist, but the data are not
sufficient for classification
Quartz SilicaIn vivoSome positive data exist, but the data are not
sufficient for classification
Carcinogenicity
NameRouteSpeciesValueStyrene MonomerIngestionMouseCarcinogenicStyrene MonomerInhalationHuman
and
animal
CarcinogenicTalcInhalationRatSome positive data exist, but the data are not
sufficient for classification
Inert FillerInhalationMultiple
animal
species
Some positive data exist, but the data are not
sufficient for classification
Titanium DioxideIngestionMultiple
animal
species
Not carcinogenicTitanium DioxideInhalationRatCarcinogenicParaffin WaxIngestionRatNot carcinogenicQuartz SilicaInhalationHuman
and
animal
Carcinogenic
Reproductive Toxicity
Reproductive and/or Developmental Effects
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NameRouteValueSpeciesTest Result Exposure
Duration
Styrene MonomerIngestionNot classified for female reproductionRatNOAEL 21
mg/kg/day
3 generationStyrene MonomerInhalationNot classified for female reproductionRatNOAEL 2.1
mg/l
2 generationStyrene MonomerInhalationNot classified for male reproductionRatNOAEL 2.1
mg/l
2 generationStyrene MonomerIngestionNot classified for male reproductionRatNOAEL 400
mg/kg/day
60 daysStyrene MonomerIngestionNot classified for developmentRatNOAEL 400
mg/kg/day
during
gestation
Styrene MonomerInhalationNot classified for developmentMultiple
animal
species
NOAEL 2.1
mg/l
during
gestation
TalcIngestionNot classified for developmentRatNOAEL 1,600
mg/kg
during
organogenesi
s
LimestoneIngestionNot classified for developmentRatNOAEL 625
mg/kg/day
premating &
during
gestation
Target Organ(s)
Specific Target Organ Toxicity – single exposure
NameRouteTarget Organ(s)ValueSpeciesTest Result Exposure
Duration
Styrene MonomerInhalationauditory systemCauses damage to organsMultiple
animal
species
LOAEL 4.3
mg/l
not availableStyrene MonomerInhalationliverCauses damage to organsMouseLOAEL 2.1
mg/l
not availableStyrene MonomerInhalationcentral nervous
system depression
May cause drowsiness or
dizziness
HumanNOAEL Not
available
occupational
exposure
Styrene MonomerInhalationrespiratory irritationMay cause respiratory irritationHuman
and
animal
NOAEL Not
available
Styrene MonomerInhalationendocrine systemNot classifiedRatNOAEL Not
available
not availableStyrene MonomerInhalationkidney and/or
bladder
Not classifiedMultiple
animal
species
NOAEL 2.1
mg/l
not availableLimestoneInhalationrespiratory systemNot classifiedRatNOAEL
0.812 mg/l
90 minutesPoly(oxypropylene)diamin
e
Inhalationrespiratory irritationSome positive data exist, but the
data are not sufficient for
classification
similar
health
hazards
NOAEL Not
available
Specific Target Organ Toxicity – repeated exposure
NameRouteTarget Organ(s)ValueSpeciesTest Result Exposure
Duration
Styrene MonomerInhalationauditory systemCauses damage to organs through
prolonged or repeated exposure
HumanNOAEL not
available
occupational
exposure
Styrene MonomerInhalationeyesCauses damage to organs through
prolonged or repeated exposure
HumanNOAEL Not
available
occupational
exposure
Styrene MonomerInhalationliverMay cause damage to organs
though prolonged or repeated
exposure
MouseLOAEL 0.85
mg/l
13 weeksStyrene MonomerInhalationnervous systemSome positive data exist, but the
data are not sufficient for
classification
Multiple
animal
species
LOAEL 1.1
mg/l
not availableStyrene MonomerInhalationhematopoietic
system
Not classifiedRatNOAEL 0.85
mg/l
7 daysStyrene MonomerInhalationendocrine systemNot classifiedRatNOAEL 0.6
mg/l
10 days
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Styrene MonomerInhalationrespiratory systemNot classifiedMultiple
animal
species
LOAEL 0.09
mg/l
not availableStyrene MonomerInhalationheart |
gastrointestinal tract
| bone, teeth, nails,
and/or hair |
muscles | kidney
and/or bladder
Not classifiedMultiple
animal
species
NOAEL 4.3
mg/l
2 yearsStyrene MonomerIngestionnervous systemSome positive data exist, but the
data are not sufficient for
classification
RatLOAEL 500
mg/kg/day
8 weeksStyrene MonomerIngestionimmune systemSome positive data exist, but the
data are not sufficient for
classification
Multiple
animal
species
NOAEL Not
available
not availableStyrene MonomerIngestionliver | kidney and/or
bladder
Not classifiedRatNOAEL 677
mg/kg/day
6 monthsStyrene MonomerIngestionhematopoietic
system
Not classifiedDogNOAEL 600
mg/kg/day
470 daysStyrene MonomerIngestionheart | respiratory
system
Not classifiedRatNOAEL 35
mg/kg/day
105 weeksTalcInhalationpneumoconiosisCauses damage to organs through
prolonged or repeated exposure
HumanNOAEL Not
available
occupational
exposure
TalcInhalationpulmonary fibrosis |
respiratory system
Not classifiedRatNOAEL 18
mg/m3
113 weeksInert FillerInhalationrespiratory systemNot classifiedHumanNOAEL not
available
occupational
exposure
LimestoneInhalationrespiratory systemNot classifiedHumanNOAEL Not
available
occupational
exposure
Titanium DioxideInhalationrespiratory systemSome positive data exist, but the
data are not sufficient for
classification
RatLOAEL 0.01
mg/l
2 yearsTitanium DioxideInhalationpulmonary fibrosisNot classifiedHumanNOAEL Not
available
occupational
exposure
Paraffin WaxIngestionheartSome positive data exist, but the
data are not sufficient for
classification
RatNOAEL 15
mg/kg/day
90 daysParaffin WaxIngestionhematopoietic
system | liver |
immune system |
skin | endocrine
system | bone, teeth,
nails, and/or hair |
muscles | nervous
system | eyes |
kidney and/or
bladder | respiratory
system | vascular
system
Not classifiedRatNOAEL
1,500
mg/kg/day
90 daysQuartz SilicaInhalationsilicosisCauses damage to organs through
prolonged or repeated exposure
HumanNOAEL Not
available
occupational
exposure
Aspiration Hazard
NameValueStyrene MonomerAspiration hazardPoly(oxypropylene)diamineSome positive data exist, but the data are not sufficient for
classification
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
SECTION 12: Ecological information
Ecotoxicological information
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Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.
SECTION 13: Disposal considerations
13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.
Incinerate uncured product in a permitted waste incineration facility. As a disposal alternative, utilize an acceptable permitted
waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical
substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated
& disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective
regulating authorities to determine the available treatment and disposal facilities.
SECTION 14: Transport Information
For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.
SECTION 15: Regulatory information
15.1. US Federal Regulations
Contact manufacturer for more information
EPCRA 311/312 Hazard Classifications:
Physical HazardsFlammable (gases, aerosols, liquids, or solids)Health HazardsCarcinogenicitySerious eye damage or eye irritationSkin Corrosion or IrritationSpecific target organ toxicity (single or repeated exposure)
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
IngredientC.A.S. No% by WtStyrene Monomer 100-42-5 Trade Secret 10 – 30Zinc Phosphate (ZINC COMPOUNDS) 7779-90-0 Trade Secret 0.5 – 2.5
15.2. State Regulations
Contact manufacturer for more information
15.3. Chemical Inventories
The components of this product are in compliance with the chemical notification requirements of TSCA. All required
components of this product are listed on the active portion of the TSCA Inventory.
Contact manufacturer for more information
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15.4. International Regulations
Contact manufacturer for more information
This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: Other information
NFPA Hazard Classification
Health: 2 Flammability: 3 Instability: 1 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
Document Group:24-8206-5Version Number:11.00Issue Date:02/15/23Supercedes Date:11/09/22
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user’s method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user’s knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user’s method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M.
3M USA SDSs are available at www.3M.com
