39COBALT-Q_SDS.pdf

Duroct Cobalt 12%
Safety data sheet
according to 29 CFR 1910.1200
SECTION 1: IDENTIFICATION
1.1GHS Product identifier:Duroct Cobalt 12%
1.2Recommended use of the chemical and restrictions on use:
Relevant uses: Catalyst for coatings. For industrial user only.
Uses advised against: All uses not specified in this section or in section 7.3
1.3Name, address, and telephone number of the chemical manufacturer, importer, or other responsible party:
DURA CHEMICALS, INC.
2200 Powell Street, Suite 450
94608 Emeryville – California – U.S.A.
Phone.: 1-510-658-1987 – Fax: 1-510-658-8025
www.durachem.com
1.4Emergency phone number: 1-800-424-9300 CHEMTREC
SECTION 2: HAZARD(S) IDENTIFICATION
2.1Classification of the substance or mixture:
NFPA:
Health Hazards: 2
Flammability Hazards: 2
Instability Hazards: 0
Special Hazards: Non-applicable
29 CFR 1910.1200:
Classification of this product has been carried out in accordance with paragraph (d) of 1910.1200.
Eye Irrit. 2: Eye irritation, Category 2, H319
Flam. Liq. 4: Flammable liquids, Category 4, H227
Repr. 1B: Reproductive toxicity, Category 1B, H360
Skin Sens. 1A: Sensitisation, skin, Category 1A, H317
2.2Label elements:
NFPA:
29 CFR 1910.1200:
Danger
Hazard statements:
Eye Irrit. 2: H319 – Causes serious eye irritation
Flam. Liq. 4: H227 – Combustible liquid
Repr. 1B: H360 – May damage fertility or the unborn child
Skin Sens. 1A: H317 – May cause an allergic skin reaction
Precautionary statements:
P201: Obtain special instructions before use
P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking
P280: Wear protective gloves/protective clothing/eye protection/face protection
P302+P352: IF ON SKIN: Wash with plenty of soap and water
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing
P308+P313: IF exposed or concerned: Get medical advice/attention
P370+P378: In case of fire: Use ABC powder extinguisher to put it out
P501: Dispose of contents and / or containers in accordance with regulations on hazardous waste or packaging and packaging
waste respectively
Substances that contribute to the classification
Page 1/10Date of compilation: 7/2/2018 Revised: 1/16/2020 Version: 5 (Replaced 4)
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Duroct Cobalt 12%
Safety data sheet
according to 29 CFR 1910.1200
SECTION 2: HAZARD(S) IDENTIFICATION (continued)
Cobalt bis(2-ethylhexanoate) (CAS: 136-52-7)
2.3Hazards not otherwise classified (HNOC):
Non-applicable
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.1Substances:
Non-applicable
3.2Mixtures:
Chemical description:Additive/s
Components:
Remaining components are non-hazardous and/or present at amounts below reportable limits. The specific chemical identity
and/or exact percentage (concentration) of composition has been withheld as a trade secret in accordance with paragraph (i) of
1910.1200.Therefore, in accordance with Appendix D to 1910.1200, the product contains:
Identification Chemical name Concentration
CAS:136-52-7 Cobalt bis(2-ethylhexanoate) 60 – <75 % CAS:64742-47-8 Distillates (petroleum), hydrotreated light (60 C < fp < 93 C) 25 - <40 % To obtain more information on the hazards of the substances consult sections 11, 12 and 16. SECTION 4: FIRST-AID MEASURES 4.1Description of necessary measures: The symptoms resulting from intoxication can appear after exposure, therefore, in case of doubt, seek medical attention for direct exposure to the chemical product or persistent discomfort, showing the SDS of this product. By inhalation: This product does not contain substances classified as hazardous for inhalation, however, in case of symptoms of intoxication remove the person affected from the exposure area and provide with fresh air. Seek medical attention if the symptoms get worse or persist. By skin contact: Remove contaminated clothing and footwear, rinse skin or shower the person affected if appropriate with plenty of cold water and neutral soap. In serious cases see a doctor. If the product causes burns or freezing, clothing should not be removed as this could worsen the injury caused if it is stuck to the skin. If blisters form on the skin, these should never be burst as this will increase the risk of infection. By eye contact: Rinse eyes thoroughly with lukewarm water for at least 15 minutes. Do not allow the person affected to rub or close their eyes. If the injured person uses contact lenses, these should be removed unless they are stuck to the eyes, as this could cause further damage. In all cases, after cleaning, a doctor should be consulted as quickly as possible with the SDS of the product. By ingestion/aspiration: Do not induce vomiting, but if it does happen keep the head down to avoid aspiration. Keep the person affected at rest. Rinse out the mouth and throat, as they may have been affected during ingestion. 4.2Most important symptoms/effects, acute and delayed: Acute and delayed effects are indicated in sections 2 and 11. 4.3Indication of immediate medical attention and special treatment needed, if necessary: Non-applicable SECTION 5: FIRE-FIGHTING MEASURES 5.1Suitable (and unsuitable) extinguishing media: Page 2/10Date of compilation: 7/2/2018 Revised: 1/16/2020 Version: 5 (Replaced 4) - CONTINUED ON NEXT PAGE - Duroct Cobalt 12% Safety data sheet according to 29 CFR 1910.1200 SECTION 5: FIRE-FIGHTING MEASURES (continued) Combustible liquid. In the case of inflammation as a result of improper manipulation, storage or use preferably use polyvalent powder extinguishers (ABC powder), in accordance with the Regulation on fire protection systems. IT IS NOT RECOMMENDED to use full jet water as an extinguishing agent. 5.2Specific hazards arising from the chemical: As a result of combustion or thermal decomposition reactive sub-products are created that can become highly toxic and, consequently, can present a serious health risk. 5.3Special protective equipment and precautions for fire-fighters: Depending on the magnitude of the fire it may be necessary to use full protective clothing and individual respiratory equipment. Minimum emergency facilities and equipment should be available (fire blankets, portable first aid kit,...) Additional provisions: As in any fire, prevent human exposure to fire, smoke, fumes or products of combustion. Only properly trained personnel should be involved in firefighting. Evacuate nonessential personnel from the fire area. Destroy any source of ignition. In case of fire, refrigerate the storage containers and tanks for products susceptible to inflammation. Avoid spillage of the products used to extinguish the fire into an aqueous medium. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1Personal precautions, protective equipment and emergency procedures: Isolate leaks provided that there is no additional risk for the people performing this task. Personal protection equipment must be used against potential contact with the spilt product (See section 8). Evacuate the area and keep out those who do not have protection. 6.2Environmental precautions: This product is not classified as hazardous to the environment. Keep product away from drains, surface and underground water. 6.3Methods and materials for containment and cleaning up: It is recommended: Absorb the spillage using sand or inert absorbent and move it to a safe place. Do not absorb in sawdust or other combustible absorbents. For any concern related to disposal consult section 13. 6.4Reference to other sections: See sections 8 and 13. SECTION 7: HANDLING AND STORAGE 7.1Precautions for safe handling: A.-Precautions for safe manipulation Comply with the current standards 29 CFR 1910 Occupational Safety and Health Standards. Keep containers hermetically sealed. Control spills and residues, destroying them with safe methods (section 6). Avoid leakages from the container. Maintain order and cleanliness where dangerous products are used. B.-Technical recommendations for the prevention of fires and explosions Product is non-flammable under normal conditions of storage, manipulation and use. It is recommended to transfer at slow speeds to avoid the generation of electrostatic charges that can affect flammable products. Consult section 10 for information on conditions and materials that should be avoided. C.-Technical recommendations to prevent ergonomic and toxicological risks PREGNANT WOMEN SHOULD NOT BE EXPOSED TO THIS PRODUCT. Transfer in fixed places that comply with the necessary security conditions (emergency showers and eyewash stations in close proximity), using personal protection equipment, especially on the hands and face (See section 8). Limit manual transfers to containers of small amounts. Do not eat or drink during the process, washing hands afterwards with suitable cleaning products. D.-Technical recommendations to prevent environmental risks It is recommended to have absorbent material available at close proximity to the product (See subsection 6.3) 7.2Conditions for safe storage, including any incompatibilities: A.-Technical measures for storage Minimum Temp.: 41 F Maximum Temp.: 86 F Maximum time: 60 Months Page 3/10Date of compilation: 7/2/2018 Revised: 1/16/2020 Version: 5 (Replaced 4) - CONTINUED ON NEXT PAGE - Duroct Cobalt 12% Safety data sheet according to 29 CFR 1910.1200 SECTION 7: HANDLING AND STORAGE (continued) B.-General conditions for storage Avoid sources of heat, radiation, static electricity and contact with food. For additional information see subsection 10.5 7.3Specific end use(s): Except for the instructions already specified it is not necessary to provide any special recommendation regarding the uses of this product. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1Control parameters: Substances whose occupational exposure limits have to be monitored in the workplace There are no occupational exposure limits for the substances contained in the product 8.2Appropriate engineering controls: A.-Individual protection measures, such as personal protective equipment As a preventative measure it is recommended to use basic Personal Protection Equipment. For more information on Personal Protection Equipment (storage, use, cleaning, maintenance, class of protection, ) consult the information leaflet provided by the manufacturer. For more information see subsection 7.1. All information contained herein is a recommendation, the information on clothing performance must be combined with professional judgment, and a clear understanding of the clothing application, to provide the best protection to the worker. All chemical protective clothing use must be based on a hazard assessment to determine the risks for exposure to chemicals and other hazards. Conduct hazard assessments in accordance with 29 CFR 1910.132. B.-Respiratory protection Pictogram PPE Remarks Mandatory respiratory tract protection Filter mask for gases and vapours Replace when there is a taste or smell of the contaminant inside the face mask. If the contaminant comes with warnings it is recommended to use isolation equipment. Use respirator in accordance with manufacturer s use limitations and OSHA standard 1910.134 (29CFR) C.-Specific protection for the hands Pictogram PPE Remarks Mandatory hand protection NON-disposable chemical protective gloves The Breakthrough Time indicated by the manufacturer must exceed the period during which the product is being used. Do not use protective creams after the product has come into contact with skin. Use gloves in accordance with manufacturer s use limitations and OSHA standard 1910.138 (29CFR) As the product is a mixture of several substances, the resistance of the glove material can not be calculated in advance with total reliability and has therefore to be checked prior to the application D.-Ocular and facial protection Pictogram PPE Remarks Mandatory face protection Face shield Clean daily and disinfect periodically according to the manufacturer s instructions. Use if there is a risk of splashing. Use this PPE in accordance with manufacturer s use limitations and OSHA standard 1910.133 (29CFR) E.-Bodily protection Pictogram PPE Remarks Mandatory complete body protection Disposable clothing for protection against chemical risks For professional use only. Clean periodically according to the manufacturer s instructions. Mandatory foot protection Safety footwear for protection against chemical risk Replace boots at any sign of deterioration. Use foot protection in accordance with manufacturer s use limitations and OSHA standard 1910.136 (29CFR) Page 4/10Date of compilation: 7/2/2018 Revised: 1/16/2020 Version: 5 (Replaced 4) - CONTINUED ON NEXT PAGE - Duroct Cobalt 12% Safety data sheet according to 29 CFR 1910.1200 SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION (continued) F.-Additional emergency measures Emergency measure Standards Emergency measure Standards Emergency shower ANSI Z358-1 ISO 3864-1:2011, ISO 3864-4:2011 Eyewash stations DIN 12 899 ISO 3864-1:2011, ISO 3864-4:2011 Environmental exposure controls: In accordance with the community legislation for the protection of the environment it is recommended to avoid environmental spillage of both the product and its container. For additional information see subsection 7.1.D National volatile organic compound emission standards (40 CFR Part 59): V.O.C. (Subpart C - Consumer):36.2 % weight V.O.C. (Coatings) at 77 F: 372.86 kg/m (372.86 g/L) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1Information on basic physical and chemical properties: For complete information see the product datasheet. Appearance: Physical state at 68 F: Liquid Appearance: Not available Color: Cobalt Odor: Not available Odour threshold: Non-applicable * Volatility: Boiling point at atmospheric pressure: 429 F Vapour pressure at 77 F: 939 Pa Vapour pressure at 122 F: 3667.58 Pa (3.67 kPa) Evaporation rate at 77 F: Non-applicable * Product description: Density at 77 F: 980 - 1080 kg/m Relative density at 77 F: 1.03 Dynamic viscosity at 77 F: 250 cP Kinematic viscosity at 77 F: 243 cSt Kinematic viscosity at 104 F: Non-applicable * Concentration: Non-applicable * pH: Non-applicable * Vapour density at 77 F: Non-applicable * Partition coefficient n-octanol/water 77 F: Non-applicable * Solubility in water at 77 F: Non-applicable * Solubility properties: Non-applicable * Decomposition temperature: Non-applicable * Melting point/freezing point: Non-applicable * Explosive properties: Non-applicable * Oxidising properties: Non-applicable * Flammability: Flash Point: 149 F *Not relevant due to the nature of the product, not providing information property of its hazards. Page 5/10Date of compilation: 7/2/2018 Revised: 1/16/2020 Version: 5 (Replaced 4) - CONTINUED ON NEXT PAGE - Duroct Cobalt 12% Safety data sheet according to 29 CFR 1910.1200 SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES (continued) Flammability (solid, gas): Non-applicable * Autoignition temperature: 437 F Lower flammability limit: Non-applicable * Upper flammability limit: Non-applicable * Explosive: Lower explosive limit: Non-applicable * Upper explosive limit: Non-applicable * 9.2Other information: Surface tension at 77 F: Non-applicable * Refraction index: Non-applicable * *Not relevant due to the nature of the product, not providing information property of its hazards. SECTION 10: STABILITY AND REACTIVITY 10.1Reactivity: No hazardous reactions are expected because the product is stable under recommended storage conditions. See section 7. 10.2Chemical stability: Chemically stable under the conditions of storage, handling and use. 10.3Possibility of hazardous reactions: Under the specified conditions, hazardous reactions that lead to excessive temperatures or pressure are not expected. 10.4Conditions to avoid: Applicable for handling and storage at room temperature: Shock and friction Contact with air Increase in temperature Sunlight Humidity Not applicable Not applicable Risk of combustion Avoid direct impact Not applicable 10.5Incompatible materials: Acids Water Oxidising materials Combustible materials Others Avoid strong acids Not applicable Not applicable Not applicable Avoid alkalis or strong bases 10.6Hazardous decomposition products: See subsection 10.3, 10.4 and 10.5 to find out the specific decomposition products. Depending on the decomposition conditions, complex mixtures of chemical substances can be released: carbon dioxide (CO2), carbon monoxide and other organic compounds. SECTION 11: TOXICOLOGICAL INFORMATION 11.1Information on toxicological effects: The experimental information related to the toxicological properties of the product itself is not available Dangerous health implications: In case of exposure that is repetitive, prolonged or at concentrations higher than recommended by the occupational exposure limits, it may result in adverse effects on health depending on the means of exposure: A-Ingestion (acute effect): - Acute toxicity : Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for consumption. For more information see section 3. - Corrosivity/Irritability: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this effect. For more information see section 3. B-Inhalation (acute effect): - Acute toxicity : Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for inhalation. For more information see section 3. - Corrosivity/Irritability: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this effect. For more information see section 3. Page 6/10Date of compilation: 7/2/2018 Revised: 1/16/2020 Version: 5 (Replaced 4) - CONTINUED ON NEXT PAGE - Duroct Cobalt 12% Safety data sheet according to 29 CFR 1910.1200 SECTION 11: TOXICOLOGICAL INFORMATION (continued) C-Contact with the skin and the eyes (acute effect): - Contact with the skin: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for skin contact. For more information see section 3. - Contact with the eyes: Produces eye damage after contact. D-CMR effects (carcinogenicity, mutagenicity and toxicity to reproduction): - Carcinogenicity: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for the effects mentioned. For more information see section 3. IARC: Non-applicable - Mutagenicity: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this effect. For more information see section 3. - Reproductive toxicity: May damage fertility or the unborn child E-Sensitizing effects: - Respiratory: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous with sensitising effects. For more information see section 3. - Cutaneous: Prolonged contact with the skin can result in episodes of allergic contact dermatitis. F-Specific target organ toxicity (STOT) - single exposure: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this effect. For more information see section 3. G-Specific target organ toxicity (STOT)-repeated exposure: - Specific target organ toxicity (STOT)-repeated exposure: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this effect. For more information see section 3. - Skin: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this effect. For more information see section 3. H-Aspiration hazard: Based on available data, the classification criteria are not met, however it does contain substances classified as dangerous for this effect. For more information see section 3. Other information: Non-applicable Specific toxicology information on the substances: Identification Acute toxicity Genus Distillates (petroleum), hydrotreated light (60 C < fp < 93 C) LD50 oral >5000 mg/kg
CAS: 64742-47-8 LD50 dermal >5000 mg/kg
LC50 inhalation >20 mg/L (4 h)
Cobalt bis(2-ethylhexanoate) LD50 oral >5000 mg/kg
CAS: 136-52-7 LD50 dermal >5000 mg/kg
LC50 inhalation >5 mg/L (4 h)
SECTION 12: ECOLOGICAL INFORMATION
The experimental information related to the eco-toxicological properties of the product itself is not available
12.1Ecotoxicity (aquatic and terrestrial, where available):
Not available
12.2Persistence and degradability:
Not available
12.3Bioaccumulative potential:
Not available
12.4Mobility in soil:
Not available
12.5Results of PBT and vPvB assessment:
Non-applicable
12.6Other adverse effects:
Page 7/10Date of compilation: 7/2/2018 Revised: 1/16/2020 Version: 5 (Replaced 4)
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Duroct Cobalt 12%
Safety data sheet
according to 29 CFR 1910.1200
SECTION 12: ECOLOGICAL INFORMATION (continued)
Not described
SECTION 13: DISPOSAL CONSIDERATIONS
13.1Disposal methods:
Waste management (disposal and evaluation):
Consult the authorized waste service manager on the assessment and disposal operations. In case the container has been in
direct contact with the product, it will be processed the same way as the actual product. Otherwise, it will be processed as non-
dangerous residue. We do not recommended disposal down the drain. See epigraph 6.2.
Regulations related to waste management:
Legislation related to waste management:
40 CFR Part 261- IDENTIFICATION AND LISTING OF HAZARDOUS WASTE
SECTION 14: TRANSPORT INFORMATION
DOT
49CFR 173.150: Combustiible liquid. It can be shipped as non hazardous material if the container is under 119 gallons.
Under 49CFR 171.4, Except when transporting aboard a vessel, the requirements of this subchapter specific to marine
pollutants do not apply to non-bulk packagings transported by motor vehicles, railcars and aircraft.
Transport of dangerous goods by land:
With regard to 49 CFR on the Transport of Dangerous Goods:
14.6
14.4
14.3
14.2
14.1
see section 9Physico-Chemical properties:
IIIPacking group, if applicable:
3Labels:
3Transport hazard class(es):
Combustible liquid, n.o.s. (Cobalt bis(2-ethylhexanoate))UN proper shipping name:
UN number: NA1993
Marine pollutant: Yes14.5
Transport in bulk (according
to Annex II of MARPOL
73/78 and the IBC Code):
Non-applicable14.7
Special precautions which a user needs to be aware of, or needs to comply with, in
connection with transport or conveyance either within or outside their premises
Transport of dangerous goods by sea:
With regard to IMDG 39-18:
14.6
14.4
14.3
14.2
14.1
see section 9Physico-Chemical properties:
IIIPacking group, if applicable:
9Labels:
9Transport hazard class(es):
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(Cobalt bis(2-ethylhexanoate))
UN proper shipping name:
UN number: UN3082
Marine pollutant: Yes14.5
Transport in bulk (according
to Annex II of MARPOL
73/78 and the IBC Code):
Non-applicable14.7
Special precautions which a user needs to be aware of, or needs to comply with, in
connection with transport or conveyance either within or outside their premises
Transport of dangerous goods by air:
With regard to IATA/ICAO 2020:
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Duroct Cobalt 12%
Safety data sheet
according to 29 CFR 1910.1200
SECTION 14: TRANSPORT INFORMATION (continued)
14.6
14.4
14.3
14.2
14.1
see section 9Physico-Chemical properties:
IIIPacking group, if applicable:
9Labels:
9Transport hazard class(es):
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(Cobalt bis(2-ethylhexanoate))
UN proper shipping name:
UN number: UN3082
Marine pollutant: Yes14.5
Transport in bulk (according
to Annex II of MARPOL
73/78 and the IBC Code):
Non-applicable14.7
Special precautions which a user needs to be aware of, or needs to comply with, in
connection with transport or conveyance either within or outside their premises
SECTION 15: REGULATORY INFORMATION
SARA Title III – Toxic Chemical Release Inventory Reporting (Section 313): Cobalt bis(2-ethylhexanoate)
California Proposition 65 (the Safe Drinking Water and Toxic Enforcement Act of 1986): Non-applicable
The Toxic Substances Control Act (TSCA) : Cobalt bis(2-ethylhexanoate) ; Distillates (petroleum), hydrotreated light (60 C < fp < 93 C) Massachusetts RTK - Substance List: Cobalt bis(2-ethylhexanoate) New Jersey Worker and Community Right-to-Know Act: Cobalt bis(2-ethylhexanoate) New York RTK - Substance list: Cobalt bis(2-ethylhexanoate) Pennsylvania Worker and Community Right-to-Know Law: Cobalt bis(2-ethylhexanoate) CANADA-Domestic Substances List (DSL): Cobalt bis(2-ethylhexanoate) ; Distillates (petroleum), hydrotreated light (60 C < fp < 93 C) CANADA-Non-Domestic Substances List (NDSL): Non-applicable NTP (National Toxicology Program): Non-applicable Minnesota - Hazardous substances ERTK: Cobalt bis(2-ethylhexanoate) Rhode Island - Hazardous substances RTK: Non-applicable OSHA Specifically Regulated Substances (29 CFR 1910.1001-1096): Non-applicable Hazardous substances release notification under CERCLA sections 102-103 (40 CFR Part 302): Non-applicable Specific provisions in terms of protecting people or the environment: It is recommended to use the information included in this safety data sheet as data used in a risk evaluation of the local circumstances in order to establish the necessary risk prevention measures for the manipulation, use, storage and disposal of this product. Other legislation: The Toxic Substances Control Act (TSCA) Occupational Safety and Health Standards (1910 Subpart Z - Toxic and Hazardous Substances) 15.1Safety, health and environmental regulations specific for the product in question: SECTION 16: OTHER INFORMATION Legislation related to safety data sheets: This safety data sheet has been designed in accordance with Appendix d to 1910.1200 - Safety data sheets Texts of the legislative phrases mentioned in section 2: H319: Causes serious eye irritation H360: May damage fertility or the unborn child H317: May cause an allergic skin reaction H227: Combustible liquid Advice related to training: Minimal training is recommended to prevent industrial risks for staff using this product, in order to facilitate their comprehension and interpretation of this safety data sheet, as well as the label on the product. Principal bibliographical sources: Occupational Safety & Health Administration (OSHA). Abbreviations and acronyms: Page 9/10Date of compilation: 7/2/2018 Revised: 1/16/2020 Version: 5 (Replaced 4) - CONTINUED ON NEXT PAGE - Duroct Cobalt 12% Safety data sheet according to 29 CFR 1910.1200 SECTION 16: OTHER INFORMATION (continued) IMDG: International maritime dangerous goods code IATA: International Air Transport Association ICAO: International Civil Aviation Organisation COD: Chemical Oxygen Demand BOD5: 5-day biochemical oxygen demand BCF: Bioconcentration factor LD50: Lethal Dose 50 CL50: Lethal Concentration 50 EC50: Effective concentration 50 Log-POW: Octanol-water partition coefficient Koc: Partition coefficient of organic carbon ManufacturerDisclaimer:Theinformationcontainedinthissafetydatesheet( SDS )isbasedonsources,technicalknowledgeandcurrentlegislation.Furthermore,isbasedondatabelievedto beaccurate;thus,thecompanydoesnotassumeanyliabilityforitsaccuracy.Theinformationprovidedhereincannotbeconsideredaguaranteeofthepropertiesofthisproductandthesameis simplyadescriptionofthesecurityrequirements.Theuse,occupationalmethodologyand/orconditionsforusersofthisproductarenotwithinourawarenessorcontrol.Itisultimatelythe responsibilityoftheuser(s)totakethenecessarymeasurestoobtainthelegalrequirementsconcerningthemanipulation,storage,useanddisposalofchemicalproducts.Theinformationofthis SDSonlyreferstothisproduct,whichshouldnotbeusedforpurposesotherthanthosespecified.Finally,themannerinwhichthisproductisusedandwhetherthereisanyinfringementof patentsisthesoleresponsibilityoftheuser(s). Page 10/10Date of compilation: 7/2/2018 Revised: 1/16/2020 Version: 5 (Replaced 4) END OF SAFETY DATA SHEET

39COBALT-P_SDS.pdf

Duroct Cobalt 12%
Safety data sheet
according to 29 CFR 1910.1200
SECTION 1: IDENTIFICATION
1.1GHS Product identifier:Duroct Cobalt 12%
1.2Recommended use of the chemical and restrictions on use:
Relevant uses: Catalyst for coatings. For industrial user only.
Uses advised against: All uses not specified in this section or in section 7.3
1.3Name, address, and telephone number of the chemical manufacturer, importer, or other responsible party:
DURA CHEMICALS, INC.
2200 Powell Street, Suite 450
94608 Emeryville – California – U.S.A.
Phone.: 1-510-658-1987 – Fax: 1-510-658-8025
www.durachem.com
1.4Emergency phone number: 1-800-424-9300 CHEMTREC
SECTION 2: HAZARD(S) IDENTIFICATION
2.1Classification of the substance or mixture:
NFPA:
Health Hazards: 2
Flammability Hazards: 2
Instability Hazards: 0
Special Hazards: Non-applicable
29 CFR 1910.1200:
Classification of this product has been carried out in accordance with paragraph (d) of 1910.1200.
Eye Irrit. 2: Eye irritation, Category 2, H319
Flam. Liq. 4: Flammable liquids, Category 4, H227
Repr. 1B: Reproductive toxicity, Category 1B, H360
Skin Sens. 1A: Sensitisation, skin, Category 1A, H317
2.2Label elements:
NFPA:
29 CFR 1910.1200:
Danger
Hazard statements:
Eye Irrit. 2: H319 – Causes serious eye irritation
Flam. Liq. 4: H227 – Combustible liquid
Repr. 1B: H360 – May damage fertility or the unborn child
Skin Sens. 1A: H317 – May cause an allergic skin reaction
Precautionary statements:
P201: Obtain special instructions before use
P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking
P280: Wear protective gloves/protective clothing/eye protection/face protection
P302+P352: IF ON SKIN: Wash with plenty of soap and water
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing
P308+P313: IF exposed or concerned: Get medical advice/attention
P370+P378: In case of fire: Use ABC powder extinguisher to put it out
P501: Dispose of contents and / or containers in accordance with regulations on hazardous waste or packaging and packaging
waste respectively
Substances that contribute to the classification
Page 1/10Date of compilation: 7/2/2018 Revised: 1/16/2020 Version: 5 (Replaced 4)
– CONTINUED ON NEXT PAGE –

Duroct Cobalt 12%
Safety data sheet
according to 29 CFR 1910.1200
SECTION 2: HAZARD(S) IDENTIFICATION (continued)
Cobalt bis(2-ethylhexanoate) (CAS: 136-52-7)
2.3Hazards not otherwise classified (HNOC):
Non-applicable
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.1Substances:
Non-applicable
3.2Mixtures:
Chemical description:Additive/s
Components:
Remaining components are non-hazardous and/or present at amounts below reportable limits. The specific chemical identity
and/or exact percentage (concentration) of composition has been withheld as a trade secret in accordance with paragraph (i) of
1910.1200.Therefore, in accordance with Appendix D to 1910.1200, the product contains:
Identification Chemical name Concentration
CAS:136-52-7 Cobalt bis(2-ethylhexanoate) 60 – <75 % CAS:64742-47-8 Distillates (petroleum), hydrotreated light (60 C < fp < 93 C) 25 - <40 % To obtain more information on the hazards of the substances consult sections 11, 12 and 16. SECTION 4: FIRST-AID MEASURES 4.1Description of necessary measures: The symptoms resulting from intoxication can appear after exposure, therefore, in case of doubt, seek medical attention for direct exposure to the chemical product or persistent discomfort, showing the SDS of this product. By inhalation: This product does not contain substances classified as hazardous for inhalation, however, in case of symptoms of intoxication remove the person affected from the exposure area and provide with fresh air. Seek medical attention if the symptoms get worse or persist. By skin contact: Remove contaminated clothing and footwear, rinse skin or shower the person affected if appropriate with plenty of cold water and neutral soap. In serious cases see a doctor. If the product causes burns or freezing, clothing should not be removed as this could worsen the injury caused if it is stuck to the skin. If blisters form on the skin, these should never be burst as this will increase the risk of infection. By eye contact: Rinse eyes thoroughly with lukewarm water for at least 15 minutes. Do not allow the person affected to rub or close their eyes. If the injured person uses contact lenses, these should be removed unless they are stuck to the eyes, as this could cause further damage. In all cases, after cleaning, a doctor should be consulted as quickly as possible with the SDS of the product. By ingestion/aspiration: Do not induce vomiting, but if it does happen keep the head down to avoid aspiration. Keep the person affected at rest. Rinse out the mouth and throat, as they may have been affected during ingestion. 4.2Most important symptoms/effects, acute and delayed: Acute and delayed effects are indicated in sections 2 and 11. 4.3Indication of immediate medical attention and special treatment needed, if necessary: Non-applicable SECTION 5: FIRE-FIGHTING MEASURES 5.1Suitable (and unsuitable) extinguishing media: Page 2/10Date of compilation: 7/2/2018 Revised: 1/16/2020 Version: 5 (Replaced 4) - CONTINUED ON NEXT PAGE - Duroct Cobalt 12% Safety data sheet according to 29 CFR 1910.1200 SECTION 5: FIRE-FIGHTING MEASURES (continued) Combustible liquid. In the case of inflammation as a result of improper manipulation, storage or use preferably use polyvalent powder extinguishers (ABC powder), in accordance with the Regulation on fire protection systems. IT IS NOT RECOMMENDED to use full jet water as an extinguishing agent. 5.2Specific hazards arising from the chemical: As a result of combustion or thermal decomposition reactive sub-products are created that can become highly toxic and, consequently, can present a serious health risk. 5.3Special protective equipment and precautions for fire-fighters: Depending on the magnitude of the fire it may be necessary to use full protective clothing and individual respiratory equipment. Minimum emergency facilities and equipment should be available (fire blankets, portable first aid kit,...) Additional provisions: As in any fire, prevent human exposure to fire, smoke, fumes or products of combustion. Only properly trained personnel should be involved in firefighting. Evacuate nonessential personnel from the fire area. Destroy any source of ignition. In case of fire, refrigerate the storage containers and tanks for products susceptible to inflammation. Avoid spillage of the products used to extinguish the fire into an aqueous medium. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1Personal precautions, protective equipment and emergency procedures: Isolate leaks provided that there is no additional risk for the people performing this task. Personal protection equipment must be used against potential contact with the spilt product (See section 8). Evacuate the area and keep out those who do not have protection. 6.2Environmental precautions: This product is not classified as hazardous to the environment. Keep product away from drains, surface and underground water. 6.3Methods and materials for containment and cleaning up: It is recommended: Absorb the spillage using sand or inert absorbent and move it to a safe place. Do not absorb in sawdust or other combustible absorbents. For any concern related to disposal consult section 13. 6.4Reference to other sections: See sections 8 and 13. SECTION 7: HANDLING AND STORAGE 7.1Precautions for safe handling: A.-Precautions for safe manipulation Comply with the current standards 29 CFR 1910 Occupational Safety and Health Standards. Keep containers hermetically sealed. Control spills and residues, destroying them with safe methods (section 6). Avoid leakages from the container. Maintain order and cleanliness where dangerous products are used. B.-Technical recommendations for the prevention of fires and explosions Product is non-flammable under normal conditions of storage, manipulation and use. It is recommended to transfer at slow speeds to avoid the generation of electrostatic charges that can affect flammable products. Consult section 10 for information on conditions and materials that should be avoided. C.-Technical recommendations to prevent ergonomic and toxicological risks PREGNANT WOMEN SHOULD NOT BE EXPOSED TO THIS PRODUCT. Transfer in fixed places that comply with the necessary security conditions (emergency showers and eyewash stations in close proximity), using personal protection equipment, especially on the hands and face (See section 8). Limit manual transfers to containers of small amounts. Do not eat or drink during the process, washing hands afterwards with suitable cleaning products. D.-Technical recommendations to prevent environmental risks It is recommended to have absorbent material available at close proximity to the product (See subsection 6.3) 7.2Conditions for safe storage, including any incompatibilities: A.-Technical measures for storage Minimum Temp.: 41 F Maximum Temp.: 86 F Maximum time: 60 Months Page 3/10Date of compilation: 7/2/2018 Revised: 1/16/2020 Version: 5 (Replaced 4) - CONTINUED ON NEXT PAGE - Duroct Cobalt 12% Safety data sheet according to 29 CFR 1910.1200 SECTION 7: HANDLING AND STORAGE (continued) B.-General conditions for storage Avoid sources of heat, radiation, static electricity and contact with food. For additional information see subsection 10.5 7.3Specific end use(s): Except for the instructions already specified it is not necessary to provide any special recommendation regarding the uses of this product. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1Control parameters: Substances whose occupational exposure limits have to be monitored in the workplace There are no occupational exposure limits for the substances contained in the product 8.2Appropriate engineering controls: A.-Individual protection measures, such as personal protective equipment As a preventative measure it is recommended to use basic Personal Protection Equipment. For more information on Personal Protection Equipment (storage, use, cleaning, maintenance, class of protection, ) consult the information leaflet provided by the manufacturer. For more information see subsection 7.1. All information contained herein is a recommendation, the information on clothing performance must be combined with professional judgment, and a clear understanding of the clothing application, to provide the best protection to the worker. All chemical protective clothing use must be based on a hazard assessment to determine the risks for exposure to chemicals and other hazards. Conduct hazard assessments in accordance with 29 CFR 1910.132. B.-Respiratory protection Pictogram PPE Remarks Mandatory respiratory tract protection Filter mask for gases and vapours Replace when there is a taste or smell of the contaminant inside the face mask. If the contaminant comes with warnings it is recommended to use isolation equipment. Use respirator in accordance with manufacturer s use limitations and OSHA standard 1910.134 (29CFR) C.-Specific protection for the hands Pictogram PPE Remarks Mandatory hand protection NON-disposable chemical protective gloves The Breakthrough Time indicated by the manufacturer must exceed the period during which the product is being used. Do not use protective creams after the product has come into contact with skin. Use gloves in accordance with manufacturer s use limitations and OSHA standard 1910.138 (29CFR) As the product is a mixture of several substances, the resistance of the glove material can not be calculated in advance with total reliability and has therefore to be checked prior to the application D.-Ocular and facial protection Pictogram PPE Remarks Mandatory face protection Face shield Clean daily and disinfect periodically according to the manufacturer s instructions. Use if there is a risk of splashing. Use this PPE in accordance with manufacturer s use limitations and OSHA standard 1910.133 (29CFR) E.-Bodily protection Pictogram PPE Remarks Mandatory complete body protection Disposable clothing for protection against chemical risks For professional use only. Clean periodically according to the manufacturer s instructions. Mandatory foot protection Safety footwear for protection against chemical risk Replace boots at any sign of deterioration. Use foot protection in accordance with manufacturer s use limitations and OSHA standard 1910.136 (29CFR) Page 4/10Date of compilation: 7/2/2018 Revised: 1/16/2020 Version: 5 (Replaced 4) - CONTINUED ON NEXT PAGE - Duroct Cobalt 12% Safety data sheet according to 29 CFR 1910.1200 SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION (continued) F.-Additional emergency measures Emergency measure Standards Emergency measure Standards Emergency shower ANSI Z358-1 ISO 3864-1:2011, ISO 3864-4:2011 Eyewash stations DIN 12 899 ISO 3864-1:2011, ISO 3864-4:2011 Environmental exposure controls: In accordance with the community legislation for the protection of the environment it is recommended to avoid environmental spillage of both the product and its container. For additional information see subsection 7.1.D National volatile organic compound emission standards (40 CFR Part 59): V.O.C. (Subpart C - Consumer):36.2 % weight V.O.C. (Coatings) at 77 F: 372.86 kg/m (372.86 g/L) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1Information on basic physical and chemical properties: For complete information see the product datasheet. Appearance: Physical state at 68 F: Liquid Appearance: Not available Color: Cobalt Odor: Not available Odour threshold: Non-applicable * Volatility: Boiling point at atmospheric pressure: 429 F Vapour pressure at 77 F: 939 Pa Vapour pressure at 122 F: 3667.58 Pa (3.67 kPa) Evaporation rate at 77 F: Non-applicable * Product description: Density at 77 F: 980 - 1080 kg/m Relative density at 77 F: 1.03 Dynamic viscosity at 77 F: 250 cP Kinematic viscosity at 77 F: 243 cSt Kinematic viscosity at 104 F: Non-applicable * Concentration: Non-applicable * pH: Non-applicable * Vapour density at 77 F: Non-applicable * Partition coefficient n-octanol/water 77 F: Non-applicable * Solubility in water at 77 F: Non-applicable * Solubility properties: Non-applicable * Decomposition temperature: Non-applicable * Melting point/freezing point: Non-applicable * Explosive properties: Non-applicable * Oxidising properties: Non-applicable * Flammability: Flash Point: 149 F *Not relevant due to the nature of the product, not providing information property of its hazards. Page 5/10Date of compilation: 7/2/2018 Revised: 1/16/2020 Version: 5 (Replaced 4) - CONTINUED ON NEXT PAGE - Duroct Cobalt 12% Safety data sheet according to 29 CFR 1910.1200 SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES (continued) Flammability (solid, gas): Non-applicable * Autoignition temperature: 437 F Lower flammability limit: Non-applicable * Upper flammability limit: Non-applicable * Explosive: Lower explosive limit: Non-applicable * Upper explosive limit: Non-applicable * 9.2Other information: Surface tension at 77 F: Non-applicable * Refraction index: Non-applicable * *Not relevant due to the nature of the product, not providing information property of its hazards. SECTION 10: STABILITY AND REACTIVITY 10.1Reactivity: No hazardous reactions are expected because the product is stable under recommended storage conditions. See section 7. 10.2Chemical stability: Chemically stable under the conditions of storage, handling and use. 10.3Possibility of hazardous reactions: Under the specified conditions, hazardous reactions that lead to excessive temperatures or pressure are not expected. 10.4Conditions to avoid: Applicable for handling and storage at room temperature: Shock and friction Contact with air Increase in temperature Sunlight Humidity Not applicable Not applicable Risk of combustion Avoid direct impact Not applicable 10.5Incompatible materials: Acids Water Oxidising materials Combustible materials Others Avoid strong acids Not applicable Not applicable Not applicable Avoid alkalis or strong bases 10.6Hazardous decomposition products: See subsection 10.3, 10.4 and 10.5 to find out the specific decomposition products. Depending on the decomposition conditions, complex mixtures of chemical substances can be released: carbon dioxide (CO2), carbon monoxide and other organic compounds. SECTION 11: TOXICOLOGICAL INFORMATION 11.1Information on toxicological effects: The experimental information related to the toxicological properties of the product itself is not available Dangerous health implications: In case of exposure that is repetitive, prolonged or at concentrations higher than recommended by the occupational exposure limits, it may result in adverse effects on health depending on the means of exposure: A-Ingestion (acute effect): - Acute toxicity : Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for consumption. For more information see section 3. - Corrosivity/Irritability: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this effect. For more information see section 3. B-Inhalation (acute effect): - Acute toxicity : Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for inhalation. For more information see section 3. - Corrosivity/Irritability: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this effect. For more information see section 3. Page 6/10Date of compilation: 7/2/2018 Revised: 1/16/2020 Version: 5 (Replaced 4) - CONTINUED ON NEXT PAGE - Duroct Cobalt 12% Safety data sheet according to 29 CFR 1910.1200 SECTION 11: TOXICOLOGICAL INFORMATION (continued) C-Contact with the skin and the eyes (acute effect): - Contact with the skin: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for skin contact. For more information see section 3. - Contact with the eyes: Produces eye damage after contact. D-CMR effects (carcinogenicity, mutagenicity and toxicity to reproduction): - Carcinogenicity: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for the effects mentioned. For more information see section 3. IARC: Non-applicable - Mutagenicity: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this effect. For more information see section 3. - Reproductive toxicity: May damage fertility or the unborn child E-Sensitizing effects: - Respiratory: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous with sensitising effects. For more information see section 3. - Cutaneous: Prolonged contact with the skin can result in episodes of allergic contact dermatitis. F-Specific target organ toxicity (STOT) - single exposure: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this effect. For more information see section 3. G-Specific target organ toxicity (STOT)-repeated exposure: - Specific target organ toxicity (STOT)-repeated exposure: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this effect. For more information see section 3. - Skin: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this effect. For more information see section 3. H-Aspiration hazard: Based on available data, the classification criteria are not met, however it does contain substances classified as dangerous for this effect. For more information see section 3. Other information: Non-applicable Specific toxicology information on the substances: Identification Acute toxicity Genus Distillates (petroleum), hydrotreated light (60 C < fp < 93 C) LD50 oral >5000 mg/kg
CAS: 64742-47-8 LD50 dermal >5000 mg/kg
LC50 inhalation >20 mg/L (4 h)
Cobalt bis(2-ethylhexanoate) LD50 oral >5000 mg/kg
CAS: 136-52-7 LD50 dermal >5000 mg/kg
LC50 inhalation >5 mg/L (4 h)
SECTION 12: ECOLOGICAL INFORMATION
The experimental information related to the eco-toxicological properties of the product itself is not available
12.1Ecotoxicity (aquatic and terrestrial, where available):
Not available
12.2Persistence and degradability:
Not available
12.3Bioaccumulative potential:
Not available
12.4Mobility in soil:
Not available
12.5Results of PBT and vPvB assessment:
Non-applicable
12.6Other adverse effects:
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Duroct Cobalt 12%
Safety data sheet
according to 29 CFR 1910.1200
SECTION 12: ECOLOGICAL INFORMATION (continued)
Not described
SECTION 13: DISPOSAL CONSIDERATIONS
13.1Disposal methods:
Waste management (disposal and evaluation):
Consult the authorized waste service manager on the assessment and disposal operations. In case the container has been in
direct contact with the product, it will be processed the same way as the actual product. Otherwise, it will be processed as non-
dangerous residue. We do not recommended disposal down the drain. See epigraph 6.2.
Regulations related to waste management:
Legislation related to waste management:
40 CFR Part 261- IDENTIFICATION AND LISTING OF HAZARDOUS WASTE
SECTION 14: TRANSPORT INFORMATION
DOT
49CFR 173.150: Combustiible liquid. It can be shipped as non hazardous material if the container is under 119 gallons.
Under 49CFR 171.4, Except when transporting aboard a vessel, the requirements of this subchapter specific to marine
pollutants do not apply to non-bulk packagings transported by motor vehicles, railcars and aircraft.
Transport of dangerous goods by land:
With regard to 49 CFR on the Transport of Dangerous Goods:
14.6
14.4
14.3
14.2
14.1
see section 9Physico-Chemical properties:
IIIPacking group, if applicable:
3Labels:
3Transport hazard class(es):
Combustible liquid, n.o.s. (Cobalt bis(2-ethylhexanoate))UN proper shipping name:
UN number: NA1993
Marine pollutant: Yes14.5
Transport in bulk (according
to Annex II of MARPOL
73/78 and the IBC Code):
Non-applicable14.7
Special precautions which a user needs to be aware of, or needs to comply with, in
connection with transport or conveyance either within or outside their premises
Transport of dangerous goods by sea:
With regard to IMDG 39-18:
14.6
14.4
14.3
14.2
14.1
see section 9Physico-Chemical properties:
IIIPacking group, if applicable:
9Labels:
9Transport hazard class(es):
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(Cobalt bis(2-ethylhexanoate))
UN proper shipping name:
UN number: UN3082
Marine pollutant: Yes14.5
Transport in bulk (according
to Annex II of MARPOL
73/78 and the IBC Code):
Non-applicable14.7
Special precautions which a user needs to be aware of, or needs to comply with, in
connection with transport or conveyance either within or outside their premises
Transport of dangerous goods by air:
With regard to IATA/ICAO 2020:
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Duroct Cobalt 12%
Safety data sheet
according to 29 CFR 1910.1200
SECTION 14: TRANSPORT INFORMATION (continued)
14.6
14.4
14.3
14.2
14.1
see section 9Physico-Chemical properties:
IIIPacking group, if applicable:
9Labels:
9Transport hazard class(es):
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(Cobalt bis(2-ethylhexanoate))
UN proper shipping name:
UN number: UN3082
Marine pollutant: Yes14.5
Transport in bulk (according
to Annex II of MARPOL
73/78 and the IBC Code):
Non-applicable14.7
Special precautions which a user needs to be aware of, or needs to comply with, in
connection with transport or conveyance either within or outside their premises
SECTION 15: REGULATORY INFORMATION
SARA Title III – Toxic Chemical Release Inventory Reporting (Section 313): Cobalt bis(2-ethylhexanoate)
California Proposition 65 (the Safe Drinking Water and Toxic Enforcement Act of 1986): Non-applicable
The Toxic Substances Control Act (TSCA) : Cobalt bis(2-ethylhexanoate) ; Distillates (petroleum), hydrotreated light (60 C < fp < 93 C) Massachusetts RTK - Substance List: Cobalt bis(2-ethylhexanoate) New Jersey Worker and Community Right-to-Know Act: Cobalt bis(2-ethylhexanoate) New York RTK - Substance list: Cobalt bis(2-ethylhexanoate) Pennsylvania Worker and Community Right-to-Know Law: Cobalt bis(2-ethylhexanoate) CANADA-Domestic Substances List (DSL): Cobalt bis(2-ethylhexanoate) ; Distillates (petroleum), hydrotreated light (60 C < fp < 93 C) CANADA-Non-Domestic Substances List (NDSL): Non-applicable NTP (National Toxicology Program): Non-applicable Minnesota - Hazardous substances ERTK: Cobalt bis(2-ethylhexanoate) Rhode Island - Hazardous substances RTK: Non-applicable OSHA Specifically Regulated Substances (29 CFR 1910.1001-1096): Non-applicable Hazardous substances release notification under CERCLA sections 102-103 (40 CFR Part 302): Non-applicable Specific provisions in terms of protecting people or the environment: It is recommended to use the information included in this safety data sheet as data used in a risk evaluation of the local circumstances in order to establish the necessary risk prevention measures for the manipulation, use, storage and disposal of this product. Other legislation: The Toxic Substances Control Act (TSCA) Occupational Safety and Health Standards (1910 Subpart Z - Toxic and Hazardous Substances) 15.1Safety, health and environmental regulations specific for the product in question: SECTION 16: OTHER INFORMATION Legislation related to safety data sheets: This safety data sheet has been designed in accordance with Appendix d to 1910.1200 - Safety data sheets Texts of the legislative phrases mentioned in section 2: H319: Causes serious eye irritation H360: May damage fertility or the unborn child H317: May cause an allergic skin reaction H227: Combustible liquid Advice related to training: Minimal training is recommended to prevent industrial risks for staff using this product, in order to facilitate their comprehension and interpretation of this safety data sheet, as well as the label on the product. Principal bibliographical sources: Occupational Safety & Health Administration (OSHA). Abbreviations and acronyms: Page 9/10Date of compilation: 7/2/2018 Revised: 1/16/2020 Version: 5 (Replaced 4) - CONTINUED ON NEXT PAGE - Duroct Cobalt 12% Safety data sheet according to 29 CFR 1910.1200 SECTION 16: OTHER INFORMATION (continued) IMDG: International maritime dangerous goods code IATA: International Air Transport Association ICAO: International Civil Aviation Organisation COD: Chemical Oxygen Demand BOD5: 5-day biochemical oxygen demand BCF: Bioconcentration factor LD50: Lethal Dose 50 CL50: Lethal Concentration 50 EC50: Effective concentration 50 Log-POW: Octanol-water partition coefficient Koc: Partition coefficient of organic carbon ManufacturerDisclaimer:Theinformationcontainedinthissafetydatesheet( SDS )isbasedonsources,technicalknowledgeandcurrentlegislation.Furthermore,isbasedondatabelievedto beaccurate;thus,thecompanydoesnotassumeanyliabilityforitsaccuracy.Theinformationprovidedhereincannotbeconsideredaguaranteeofthepropertiesofthisproductandthesameis simplyadescriptionofthesecurityrequirements.Theuse,occupationalmethodologyand/orconditionsforusersofthisproductarenotwithinourawarenessorcontrol.Itisultimatelythe responsibilityoftheuser(s)totakethenecessarymeasurestoobtainthelegalrequirementsconcerningthemanipulation,storage,useanddisposalofchemicalproducts.Theinformationofthis SDSonlyreferstothisproduct,whichshouldnotbeusedforpurposesotherthanthosespecified.Finally,themannerinwhichthisproductisusedandwhetherthereisanyinfringementof patentsisthesoleresponsibilityoftheuser(s). Page 10/10Date of compilation: 7/2/2018 Revised: 1/16/2020 Version: 5 (Replaced 4) END OF SAFETY DATA SHEET

39COBALT-F_SDS.pdf

Duroct Cobalt 12%
Safety data sheet
according to 29 CFR 1910.1200
SECTION 1: IDENTIFICATION
1.1GHS Product identifier:Duroct Cobalt 12%
1.2Recommended use of the chemical and restrictions on use:
Relevant uses: Catalyst for coatings. For industrial user only.
Uses advised against: All uses not specified in this section or in section 7.3
1.3Name, address, and telephone number of the chemical manufacturer, importer, or other responsible party:
DURA CHEMICALS, INC.
2200 Powell Street, Suite 450
94608 Emeryville – California – U.S.A.
Phone.: 1-510-658-1987 – Fax: 1-510-658-8025
www.durachem.com
1.4Emergency phone number: 1-800-424-9300 CHEMTREC
SECTION 2: HAZARD(S) IDENTIFICATION
2.1Classification of the substance or mixture:
NFPA:
Health Hazards: 2
Flammability Hazards: 2
Instability Hazards: 0
Special Hazards: Non-applicable
29 CFR 1910.1200:
Classification of this product has been carried out in accordance with paragraph (d) of 1910.1200.
Eye Irrit. 2: Eye irritation, Category 2, H319
Flam. Liq. 4: Flammable liquids, Category 4, H227
Repr. 1B: Reproductive toxicity, Category 1B, H360
Skin Sens. 1A: Sensitisation, skin, Category 1A, H317
2.2Label elements:
NFPA:
29 CFR 1910.1200:
Danger
Hazard statements:
Eye Irrit. 2: H319 – Causes serious eye irritation
Flam. Liq. 4: H227 – Combustible liquid
Repr. 1B: H360 – May damage fertility or the unborn child
Skin Sens. 1A: H317 – May cause an allergic skin reaction
Precautionary statements:
P201: Obtain special instructions before use
P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking
P280: Wear protective gloves/protective clothing/eye protection/face protection
P302+P352: IF ON SKIN: Wash with plenty of soap and water
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing
P308+P313: IF exposed or concerned: Get medical advice/attention
P370+P378: In case of fire: Use ABC powder extinguisher to put it out
P501: Dispose of contents and / or containers in accordance with regulations on hazardous waste or packaging and packaging
waste respectively
Substances that contribute to the classification
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Duroct Cobalt 12%
Safety data sheet
according to 29 CFR 1910.1200
SECTION 2: HAZARD(S) IDENTIFICATION (continued)
Cobalt bis(2-ethylhexanoate) (CAS: 136-52-7)
2.3Hazards not otherwise classified (HNOC):
Non-applicable
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.1Substances:
Non-applicable
3.2Mixtures:
Chemical description:Additive/s
Components:
Remaining components are non-hazardous and/or present at amounts below reportable limits. The specific chemical identity
and/or exact percentage (concentration) of composition has been withheld as a trade secret in accordance with paragraph (i) of
1910.1200.Therefore, in accordance with Appendix D to 1910.1200, the product contains:
Identification Chemical name Concentration
CAS:136-52-7 Cobalt bis(2-ethylhexanoate) 60 – <75 % CAS:64742-47-8 Distillates (petroleum), hydrotreated light (60 C < fp < 93 C) 25 - <40 % To obtain more information on the hazards of the substances consult sections 11, 12 and 16. SECTION 4: FIRST-AID MEASURES 4.1Description of necessary measures: The symptoms resulting from intoxication can appear after exposure, therefore, in case of doubt, seek medical attention for direct exposure to the chemical product or persistent discomfort, showing the SDS of this product. By inhalation: This product does not contain substances classified as hazardous for inhalation, however, in case of symptoms of intoxication remove the person affected from the exposure area and provide with fresh air. Seek medical attention if the symptoms get worse or persist. By skin contact: Remove contaminated clothing and footwear, rinse skin or shower the person affected if appropriate with plenty of cold water and neutral soap. In serious cases see a doctor. If the product causes burns or freezing, clothing should not be removed as this could worsen the injury caused if it is stuck to the skin. If blisters form on the skin, these should never be burst as this will increase the risk of infection. By eye contact: Rinse eyes thoroughly with lukewarm water for at least 15 minutes. Do not allow the person affected to rub or close their eyes. If the injured person uses contact lenses, these should be removed unless they are stuck to the eyes, as this could cause further damage. In all cases, after cleaning, a doctor should be consulted as quickly as possible with the SDS of the product. By ingestion/aspiration: Do not induce vomiting, but if it does happen keep the head down to avoid aspiration. Keep the person affected at rest. Rinse out the mouth and throat, as they may have been affected during ingestion. 4.2Most important symptoms/effects, acute and delayed: Acute and delayed effects are indicated in sections 2 and 11. 4.3Indication of immediate medical attention and special treatment needed, if necessary: Non-applicable SECTION 5: FIRE-FIGHTING MEASURES 5.1Suitable (and unsuitable) extinguishing media: Page 2/10Date of compilation: 7/2/2018 Revised: 1/16/2020 Version: 5 (Replaced 4) - CONTINUED ON NEXT PAGE - Duroct Cobalt 12% Safety data sheet according to 29 CFR 1910.1200 SECTION 5: FIRE-FIGHTING MEASURES (continued) Combustible liquid. In the case of inflammation as a result of improper manipulation, storage or use preferably use polyvalent powder extinguishers (ABC powder), in accordance with the Regulation on fire protection systems. IT IS NOT RECOMMENDED to use full jet water as an extinguishing agent. 5.2Specific hazards arising from the chemical: As a result of combustion or thermal decomposition reactive sub-products are created that can become highly toxic and, consequently, can present a serious health risk. 5.3Special protective equipment and precautions for fire-fighters: Depending on the magnitude of the fire it may be necessary to use full protective clothing and individual respiratory equipment. Minimum emergency facilities and equipment should be available (fire blankets, portable first aid kit,...) Additional provisions: As in any fire, prevent human exposure to fire, smoke, fumes or products of combustion. Only properly trained personnel should be involved in firefighting. Evacuate nonessential personnel from the fire area. Destroy any source of ignition. In case of fire, refrigerate the storage containers and tanks for products susceptible to inflammation. Avoid spillage of the products used to extinguish the fire into an aqueous medium. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1Personal precautions, protective equipment and emergency procedures: Isolate leaks provided that there is no additional risk for the people performing this task. Personal protection equipment must be used against potential contact with the spilt product (See section 8). Evacuate the area and keep out those who do not have protection. 6.2Environmental precautions: This product is not classified as hazardous to the environment. Keep product away from drains, surface and underground water. 6.3Methods and materials for containment and cleaning up: It is recommended: Absorb the spillage using sand or inert absorbent and move it to a safe place. Do not absorb in sawdust or other combustible absorbents. For any concern related to disposal consult section 13. 6.4Reference to other sections: See sections 8 and 13. SECTION 7: HANDLING AND STORAGE 7.1Precautions for safe handling: A.-Precautions for safe manipulation Comply with the current standards 29 CFR 1910 Occupational Safety and Health Standards. Keep containers hermetically sealed. Control spills and residues, destroying them with safe methods (section 6). Avoid leakages from the container. Maintain order and cleanliness where dangerous products are used. B.-Technical recommendations for the prevention of fires and explosions Product is non-flammable under normal conditions of storage, manipulation and use. It is recommended to transfer at slow speeds to avoid the generation of electrostatic charges that can affect flammable products. Consult section 10 for information on conditions and materials that should be avoided. C.-Technical recommendations to prevent ergonomic and toxicological risks PREGNANT WOMEN SHOULD NOT BE EXPOSED TO THIS PRODUCT. Transfer in fixed places that comply with the necessary security conditions (emergency showers and eyewash stations in close proximity), using personal protection equipment, especially on the hands and face (See section 8). Limit manual transfers to containers of small amounts. Do not eat or drink during the process, washing hands afterwards with suitable cleaning products. D.-Technical recommendations to prevent environmental risks It is recommended to have absorbent material available at close proximity to the product (See subsection 6.3) 7.2Conditions for safe storage, including any incompatibilities: A.-Technical measures for storage Minimum Temp.: 41 F Maximum Temp.: 86 F Maximum time: 60 Months Page 3/10Date of compilation: 7/2/2018 Revised: 1/16/2020 Version: 5 (Replaced 4) - CONTINUED ON NEXT PAGE - Duroct Cobalt 12% Safety data sheet according to 29 CFR 1910.1200 SECTION 7: HANDLING AND STORAGE (continued) B.-General conditions for storage Avoid sources of heat, radiation, static electricity and contact with food. For additional information see subsection 10.5 7.3Specific end use(s): Except for the instructions already specified it is not necessary to provide any special recommendation regarding the uses of this product. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1Control parameters: Substances whose occupational exposure limits have to be monitored in the workplace There are no occupational exposure limits for the substances contained in the product 8.2Appropriate engineering controls: A.-Individual protection measures, such as personal protective equipment As a preventative measure it is recommended to use basic Personal Protection Equipment. For more information on Personal Protection Equipment (storage, use, cleaning, maintenance, class of protection, ) consult the information leaflet provided by the manufacturer. For more information see subsection 7.1. All information contained herein is a recommendation, the information on clothing performance must be combined with professional judgment, and a clear understanding of the clothing application, to provide the best protection to the worker. All chemical protective clothing use must be based on a hazard assessment to determine the risks for exposure to chemicals and other hazards. Conduct hazard assessments in accordance with 29 CFR 1910.132. B.-Respiratory protection Pictogram PPE Remarks Mandatory respiratory tract protection Filter mask for gases and vapours Replace when there is a taste or smell of the contaminant inside the face mask. If the contaminant comes with warnings it is recommended to use isolation equipment. Use respirator in accordance with manufacturer s use limitations and OSHA standard 1910.134 (29CFR) C.-Specific protection for the hands Pictogram PPE Remarks Mandatory hand protection NON-disposable chemical protective gloves The Breakthrough Time indicated by the manufacturer must exceed the period during which the product is being used. Do not use protective creams after the product has come into contact with skin. Use gloves in accordance with manufacturer s use limitations and OSHA standard 1910.138 (29CFR) As the product is a mixture of several substances, the resistance of the glove material can not be calculated in advance with total reliability and has therefore to be checked prior to the application D.-Ocular and facial protection Pictogram PPE Remarks Mandatory face protection Face shield Clean daily and disinfect periodically according to the manufacturer s instructions. Use if there is a risk of splashing. Use this PPE in accordance with manufacturer s use limitations and OSHA standard 1910.133 (29CFR) E.-Bodily protection Pictogram PPE Remarks Mandatory complete body protection Disposable clothing for protection against chemical risks For professional use only. Clean periodically according to the manufacturer s instructions. Mandatory foot protection Safety footwear for protection against chemical risk Replace boots at any sign of deterioration. Use foot protection in accordance with manufacturer s use limitations and OSHA standard 1910.136 (29CFR) Page 4/10Date of compilation: 7/2/2018 Revised: 1/16/2020 Version: 5 (Replaced 4) - CONTINUED ON NEXT PAGE - Duroct Cobalt 12% Safety data sheet according to 29 CFR 1910.1200 SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION (continued) F.-Additional emergency measures Emergency measure Standards Emergency measure Standards Emergency shower ANSI Z358-1 ISO 3864-1:2011, ISO 3864-4:2011 Eyewash stations DIN 12 899 ISO 3864-1:2011, ISO 3864-4:2011 Environmental exposure controls: In accordance with the community legislation for the protection of the environment it is recommended to avoid environmental spillage of both the product and its container. For additional information see subsection 7.1.D National volatile organic compound emission standards (40 CFR Part 59): V.O.C. (Subpart C - Consumer):36.2 % weight V.O.C. (Coatings) at 77 F: 372.86 kg/m (372.86 g/L) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1Information on basic physical and chemical properties: For complete information see the product datasheet. Appearance: Physical state at 68 F: Liquid Appearance: Not available Color: Cobalt Odor: Not available Odour threshold: Non-applicable * Volatility: Boiling point at atmospheric pressure: 429 F Vapour pressure at 77 F: 939 Pa Vapour pressure at 122 F: 3667.58 Pa (3.67 kPa) Evaporation rate at 77 F: Non-applicable * Product description: Density at 77 F: 980 - 1080 kg/m Relative density at 77 F: 1.03 Dynamic viscosity at 77 F: 250 cP Kinematic viscosity at 77 F: 243 cSt Kinematic viscosity at 104 F: Non-applicable * Concentration: Non-applicable * pH: Non-applicable * Vapour density at 77 F: Non-applicable * Partition coefficient n-octanol/water 77 F: Non-applicable * Solubility in water at 77 F: Non-applicable * Solubility properties: Non-applicable * Decomposition temperature: Non-applicable * Melting point/freezing point: Non-applicable * Explosive properties: Non-applicable * Oxidising properties: Non-applicable * Flammability: Flash Point: 149 F *Not relevant due to the nature of the product, not providing information property of its hazards. Page 5/10Date of compilation: 7/2/2018 Revised: 1/16/2020 Version: 5 (Replaced 4) - CONTINUED ON NEXT PAGE - Duroct Cobalt 12% Safety data sheet according to 29 CFR 1910.1200 SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES (continued) Flammability (solid, gas): Non-applicable * Autoignition temperature: 437 F Lower flammability limit: Non-applicable * Upper flammability limit: Non-applicable * Explosive: Lower explosive limit: Non-applicable * Upper explosive limit: Non-applicable * 9.2Other information: Surface tension at 77 F: Non-applicable * Refraction index: Non-applicable * *Not relevant due to the nature of the product, not providing information property of its hazards. SECTION 10: STABILITY AND REACTIVITY 10.1Reactivity: No hazardous reactions are expected because the product is stable under recommended storage conditions. See section 7. 10.2Chemical stability: Chemically stable under the conditions of storage, handling and use. 10.3Possibility of hazardous reactions: Under the specified conditions, hazardous reactions that lead to excessive temperatures or pressure are not expected. 10.4Conditions to avoid: Applicable for handling and storage at room temperature: Shock and friction Contact with air Increase in temperature Sunlight Humidity Not applicable Not applicable Risk of combustion Avoid direct impact Not applicable 10.5Incompatible materials: Acids Water Oxidising materials Combustible materials Others Avoid strong acids Not applicable Not applicable Not applicable Avoid alkalis or strong bases 10.6Hazardous decomposition products: See subsection 10.3, 10.4 and 10.5 to find out the specific decomposition products. Depending on the decomposition conditions, complex mixtures of chemical substances can be released: carbon dioxide (CO2), carbon monoxide and other organic compounds. SECTION 11: TOXICOLOGICAL INFORMATION 11.1Information on toxicological effects: The experimental information related to the toxicological properties of the product itself is not available Dangerous health implications: In case of exposure that is repetitive, prolonged or at concentrations higher than recommended by the occupational exposure limits, it may result in adverse effects on health depending on the means of exposure: A-Ingestion (acute effect): - Acute toxicity : Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for consumption. For more information see section 3. - Corrosivity/Irritability: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this effect. For more information see section 3. B-Inhalation (acute effect): - Acute toxicity : Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for inhalation. For more information see section 3. - Corrosivity/Irritability: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this effect. For more information see section 3. Page 6/10Date of compilation: 7/2/2018 Revised: 1/16/2020 Version: 5 (Replaced 4) - CONTINUED ON NEXT PAGE - Duroct Cobalt 12% Safety data sheet according to 29 CFR 1910.1200 SECTION 11: TOXICOLOGICAL INFORMATION (continued) C-Contact with the skin and the eyes (acute effect): - Contact with the skin: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for skin contact. For more information see section 3. - Contact with the eyes: Produces eye damage after contact. D-CMR effects (carcinogenicity, mutagenicity and toxicity to reproduction): - Carcinogenicity: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for the effects mentioned. For more information see section 3. IARC: Non-applicable - Mutagenicity: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this effect. For more information see section 3. - Reproductive toxicity: May damage fertility or the unborn child E-Sensitizing effects: - Respiratory: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous with sensitising effects. For more information see section 3. - Cutaneous: Prolonged contact with the skin can result in episodes of allergic contact dermatitis. F-Specific target organ toxicity (STOT) - single exposure: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this effect. For more information see section 3. G-Specific target organ toxicity (STOT)-repeated exposure: - Specific target organ toxicity (STOT)-repeated exposure: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this effect. For more information see section 3. - Skin: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this effect. For more information see section 3. H-Aspiration hazard: Based on available data, the classification criteria are not met, however it does contain substances classified as dangerous for this effect. For more information see section 3. Other information: Non-applicable Specific toxicology information on the substances: Identification Acute toxicity Genus Distillates (petroleum), hydrotreated light (60 C < fp < 93 C) LD50 oral >5000 mg/kg
CAS: 64742-47-8 LD50 dermal >5000 mg/kg
LC50 inhalation >20 mg/L (4 h)
Cobalt bis(2-ethylhexanoate) LD50 oral >5000 mg/kg
CAS: 136-52-7 LD50 dermal >5000 mg/kg
LC50 inhalation >5 mg/L (4 h)
SECTION 12: ECOLOGICAL INFORMATION
The experimental information related to the eco-toxicological properties of the product itself is not available
12.1Ecotoxicity (aquatic and terrestrial, where available):
Not available
12.2Persistence and degradability:
Not available
12.3Bioaccumulative potential:
Not available
12.4Mobility in soil:
Not available
12.5Results of PBT and vPvB assessment:
Non-applicable
12.6Other adverse effects:
Page 7/10Date of compilation: 7/2/2018 Revised: 1/16/2020 Version: 5 (Replaced 4)
– CONTINUED ON NEXT PAGE –

Duroct Cobalt 12%
Safety data sheet
according to 29 CFR 1910.1200
SECTION 12: ECOLOGICAL INFORMATION (continued)
Not described
SECTION 13: DISPOSAL CONSIDERATIONS
13.1Disposal methods:
Waste management (disposal and evaluation):
Consult the authorized waste service manager on the assessment and disposal operations. In case the container has been in
direct contact with the product, it will be processed the same way as the actual product. Otherwise, it will be processed as non-
dangerous residue. We do not recommended disposal down the drain. See epigraph 6.2.
Regulations related to waste management:
Legislation related to waste management:
40 CFR Part 261- IDENTIFICATION AND LISTING OF HAZARDOUS WASTE
SECTION 14: TRANSPORT INFORMATION
DOT
49CFR 173.150: Combustiible liquid. It can be shipped as non hazardous material if the container is under 119 gallons.
Under 49CFR 171.4, Except when transporting aboard a vessel, the requirements of this subchapter specific to marine
pollutants do not apply to non-bulk packagings transported by motor vehicles, railcars and aircraft.
Transport of dangerous goods by land:
With regard to 49 CFR on the Transport of Dangerous Goods:
14.6
14.4
14.3
14.2
14.1
see section 9Physico-Chemical properties:
IIIPacking group, if applicable:
3Labels:
3Transport hazard class(es):
Combustible liquid, n.o.s. (Cobalt bis(2-ethylhexanoate))UN proper shipping name:
UN number: NA1993
Marine pollutant: Yes14.5
Transport in bulk (according
to Annex II of MARPOL
73/78 and the IBC Code):
Non-applicable14.7
Special precautions which a user needs to be aware of, or needs to comply with, in
connection with transport or conveyance either within or outside their premises
Transport of dangerous goods by sea:
With regard to IMDG 39-18:
14.6
14.4
14.3
14.2
14.1
see section 9Physico-Chemical properties:
IIIPacking group, if applicable:
9Labels:
9Transport hazard class(es):
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(Cobalt bis(2-ethylhexanoate))
UN proper shipping name:
UN number: UN3082
Marine pollutant: Yes14.5
Transport in bulk (according
to Annex II of MARPOL
73/78 and the IBC Code):
Non-applicable14.7
Special precautions which a user needs to be aware of, or needs to comply with, in
connection with transport or conveyance either within or outside their premises
Transport of dangerous goods by air:
With regard to IATA/ICAO 2020:
Page 8/10Date of compilation: 7/2/2018 Revised: 1/16/2020 Version: 5 (Replaced 4)
– CONTINUED ON NEXT PAGE –

Duroct Cobalt 12%
Safety data sheet
according to 29 CFR 1910.1200
SECTION 14: TRANSPORT INFORMATION (continued)
14.6
14.4
14.3
14.2
14.1
see section 9Physico-Chemical properties:
IIIPacking group, if applicable:
9Labels:
9Transport hazard class(es):
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(Cobalt bis(2-ethylhexanoate))
UN proper shipping name:
UN number: UN3082
Marine pollutant: Yes14.5
Transport in bulk (according
to Annex II of MARPOL
73/78 and the IBC Code):
Non-applicable14.7
Special precautions which a user needs to be aware of, or needs to comply with, in
connection with transport or conveyance either within or outside their premises
SECTION 15: REGULATORY INFORMATION
SARA Title III – Toxic Chemical Release Inventory Reporting (Section 313): Cobalt bis(2-ethylhexanoate)
California Proposition 65 (the Safe Drinking Water and Toxic Enforcement Act of 1986): Non-applicable
The Toxic Substances Control Act (TSCA) : Cobalt bis(2-ethylhexanoate) ; Distillates (petroleum), hydrotreated light (60 C < fp < 93 C) Massachusetts RTK - Substance List: Cobalt bis(2-ethylhexanoate) New Jersey Worker and Community Right-to-Know Act: Cobalt bis(2-ethylhexanoate) New York RTK - Substance list: Cobalt bis(2-ethylhexanoate) Pennsylvania Worker and Community Right-to-Know Law: Cobalt bis(2-ethylhexanoate) CANADA-Domestic Substances List (DSL): Cobalt bis(2-ethylhexanoate) ; Distillates (petroleum), hydrotreated light (60 C < fp < 93 C) CANADA-Non-Domestic Substances List (NDSL): Non-applicable NTP (National Toxicology Program): Non-applicable Minnesota - Hazardous substances ERTK: Cobalt bis(2-ethylhexanoate) Rhode Island - Hazardous substances RTK: Non-applicable OSHA Specifically Regulated Substances (29 CFR 1910.1001-1096): Non-applicable Hazardous substances release notification under CERCLA sections 102-103 (40 CFR Part 302): Non-applicable Specific provisions in terms of protecting people or the environment: It is recommended to use the information included in this safety data sheet as data used in a risk evaluation of the local circumstances in order to establish the necessary risk prevention measures for the manipulation, use, storage and disposal of this product. Other legislation: The Toxic Substances Control Act (TSCA) Occupational Safety and Health Standards (1910 Subpart Z - Toxic and Hazardous Substances) 15.1Safety, health and environmental regulations specific for the product in question: SECTION 16: OTHER INFORMATION Legislation related to safety data sheets: This safety data sheet has been designed in accordance with Appendix d to 1910.1200 - Safety data sheets Texts of the legislative phrases mentioned in section 2: H319: Causes serious eye irritation H360: May damage fertility or the unborn child H317: May cause an allergic skin reaction H227: Combustible liquid Advice related to training: Minimal training is recommended to prevent industrial risks for staff using this product, in order to facilitate their comprehension and interpretation of this safety data sheet, as well as the label on the product. Principal bibliographical sources: Occupational Safety & Health Administration (OSHA). Abbreviations and acronyms: Page 9/10Date of compilation: 7/2/2018 Revised: 1/16/2020 Version: 5 (Replaced 4) - CONTINUED ON NEXT PAGE - Duroct Cobalt 12% Safety data sheet according to 29 CFR 1910.1200 SECTION 16: OTHER INFORMATION (continued) IMDG: International maritime dangerous goods code IATA: International Air Transport Association ICAO: International Civil Aviation Organisation COD: Chemical Oxygen Demand BOD5: 5-day biochemical oxygen demand BCF: Bioconcentration factor LD50: Lethal Dose 50 CL50: Lethal Concentration 50 EC50: Effective concentration 50 Log-POW: Octanol-water partition coefficient Koc: Partition coefficient of organic carbon ManufacturerDisclaimer:Theinformationcontainedinthissafetydatesheet( SDS )isbasedonsources,technicalknowledgeandcurrentlegislation.Furthermore,isbasedondatabelievedto beaccurate;thus,thecompanydoesnotassumeanyliabilityforitsaccuracy.Theinformationprovidedhereincannotbeconsideredaguaranteeofthepropertiesofthisproductandthesameis simplyadescriptionofthesecurityrequirements.Theuse,occupationalmethodologyand/orconditionsforusersofthisproductarenotwithinourawarenessorcontrol.Itisultimatelythe responsibilityoftheuser(s)totakethenecessarymeasurestoobtainthelegalrequirementsconcerningthemanipulation,storage,useanddisposalofchemicalproducts.Theinformationofthis SDSonlyreferstothisproduct,whichshouldnotbeusedforpurposesotherthanthosespecified.Finally,themannerinwhichthisproductisusedandwhetherthereisanyinfringementof patentsisthesoleresponsibilityoftheuser(s). Page 10/10Date of compilation: 7/2/2018 Revised: 1/16/2020 Version: 5 (Replaced 4) END OF SAFETY DATA SHEET

392165CRF_SDS.pdf

SAFETY DATA SHEET
STAN-MASK 21651 CITRUS SWEET GRAS
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product identifier
Product Name STAN-MASK 21651 CITRUS SWEET GRAS
Other means of identification
CAS No Mixture
Synonyms None
Recommended use of the chemical and restrictions on use
Recommended Use Fragrances
Uses advised against No information available
Details of the supplier of the safety data sheet
Manufactured for and Supplied by Harwick Standard Distribution Corporation
P.O. Box 9360
60 S. Seiberling Street
Akron, OH 44305 USA
(330) 798-9300
www.harwickstandard.com
2. HAZARDS IDENTIFICATION
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Skin corrosion/irritation – Category 2
Skin sensitization – Category 1B
Aspiration toxicity – Category 1
Label elements Physical hazards – Flammable liquids – Category 3
Signal word – Danger
Hazard statements
Causes skin irritation
May cause an allergic skin reaction
May be fatal if swallowed and enters airways
_____________________________________________________________________________________________
Page 1 / 9
Product Name: STAN-MASK 21651 CITRUS SWEET GRAS
Flammable liquid and vapor

_____________________________________________________________________________________________
Precautionary Statements
Wash face, hands and any exposed skin thoroughly after handling
Avoid breathing dust/fume/gas/mist/vapors/spray
Contaminated work clothing must not be allowed out of the workplace
Keep away from heat/sparks/open flames/hot surfaces. – No smoking
Keep container tightly closed
Ground/bond container and receiving equipment
Use explosion-proof electrical/ ventilating / lighting/ .? / equipment
Use only non-sparking tools
Take precautionary measures against static discharge
Wear protective gloves/eye protection/face protection
Specific treatment (see .? on this label)
If skin irritation or rash occurs: Get medical advice/attention
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower
Wash contaminated clothing before reuse
IF SWALLOWED: Immediately call a POISON CENTER or doctor
Do NOT induce vomiting
In case of fire: Use CO2, dry chemical, or foam to extinguish
Precautionary Statements – Storage
Store locked up
Store in a well-ventilated place. Keep cool
Precautionary Statements – Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Not applicable Other Information
May be harmful if swallowed May be harmful in contact with skin Toxic to aquatic life with long lasting effects Toxic to aquatic life Unknown acute toxicity 1.9 % of the mixture consists of ingredient(s) of unknown toxicity
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance
Chemical name CAS No Weight-% Trade secret
ORANGE TERPENES 68647-72-3 80 – 90 *
BENZALDEHYDE 100-52-7 1 – 10 *
ANETHOLE 4180-23-8 1 – 10 *
CINNAMIC ALCOHOL 104-54-1 1 – 10 *
ALDEHYDE C-12 LAURIC 112-54-9 <1 * Appearanceclear liquid Physical State @20 C liquid Odor Characteristic _____________________________________________________________________________________________ Page 2 / 9 Product Name: STAN-MASK 21651 CITRUS SWEET GRAS _____________________________________________________________________________________________ *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures Inhalation Remove to fresh air. Eye contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician. Skin contact Wash skin with soap and water. Ingestion Clean mouth with water and drink afterwards plenty of water. Most important symptoms and effects, both acute and delayed Symptoms No information available. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use ex tinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media CAUTION: Use of water spray when fighting fire may be inefficient. Specific hazards arising from the chemical No information available. Explosion data Sensitivity to Mechanical ImpactNone. Sensitivity to Static DischargeNone. Special protective equipment for fire-fighters Firefighters should wear self-contained breathing apparatus and full firefighting turnout gear. Use personal protection equipment. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation. Environmental precautions Environmental precautions See Section 12 for additional Ecological Information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Pick up and transfer to properly labeled containers. _____________________________________________________________________________________________ Page 3 / 9 Product Name: STAN-MASK 21651 CITRUS SWEET GRAS _____________________________________________________________________________________________ Prevention of secondary hazardsClean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Limits The following ingredients are the only ingredients of the product above the cut-off level (or level that contributes to the hazard classification of the mixture) which have an exposure limit applicable in the region for which this safety data sheet is intended or other recommended limit. At this time, the other relevant constituents have no known exposure limits from the sources listed here. Appropriate engineering controls Engineering controls Showers Eyewash stations Ventilation systems. Individual protection measures, such as personal protective equipment Eye/face protection No special protective equipment required. Skin and body protection No special protective equipment required. Respiratory protection No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required. General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State @20 C liquid Appearance clear liquid Odor Characteristic Color Colorless - Pale Yellow Odor threshold No information available _____________________________________________________________________________________________ Page 4 / 9 Product Name: STAN-MASK 21651 CITRUS SWEET GRAS _____________________________________________________________________________________________ Specific gravity 0.8590-0.8790 Refractive Index 1.4740-1.4940 Explosive properties No information available Oxidizing properties No information available Softening point No information available Molecular weight No information available VOC Content (%) No information available Density VALUE No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity No information av ailable. Chemical stability Stable under normal conditions. Possibility of hazardous reactionsNone under normal processing. Conditions to avoid None known based on information supplied. Incompatible materials None known based on information supplied. Hazardous decomposition productsNone known based on information supplied. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Inhalation Specific test data for the substance or mixture is not available. Eye contact Specific test data for the substance or mixture is not available. Skin contact Specific test data for the substance or mixture is not available. Property Values pH No data available Melting point / freezing point No data available Boiling point / boiling range > 35 C / 95 F
Flash point 51 C / 124 F
Evaporation rate No data available
Flammability (solid, gas) No data available
Flammability Limit in Air
Upper flammability limit: No data available
Lower flammability limit: No data available
Vapor pressure No data available
Vapor density No data available
Relative density No data available
Water solubility No data available
Solubility in other solvents No data available
Partition coefficient No data available
Autoignition temperature No data available
Decomposition temperature No data available
Kinematic viscosity No data available
Dynamic viscosity
_____________________________________________________________________________________________
Page 5 / 9
Product Name: STAN-MASK 21651 CITRUS SWEET GRAS
No data available

_____________________________________________________________________________________________
Ingestion Specific test data for the substance or mixture is not available.
Information on toxicological effects
Symptoms No information available.
Numerical measures of toxicity
Acute toxicity
The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral) 4,266.00 mg/kg
ATEmix (dermal) 4,280.00 mg/kg mg/l
ATEmix (inhalation-dust/mist)33.30 mg/l
ATEmix (inhalation-vapor) 244.00 mg/l
Unknown acute toxicity 1.9 % of the mixture consists of ingredient(s) of unknown toxicity
Component Information
Chemical name Oral LD50 LD50/dermal/rat – NO UNITS
(Wizards mg/kg)
Inhalation LC50
BENZALDEHYDE
100-52-7
= 1292 mg/kg ( Rat ) > 1250 mg/kg ( Rabbit ) –
ANETHOLE
4180-23-8
= 2090 mg/kg ( Rat ) – –
CINNAMIC ALCOHOL
104-54-1
= 2 g/kg ( Rat ) > 5 g/kg ( Rabbit ) –
ALDEHYDE C-12 LAURIC
112-54-9
= 23 g/kg ( Rat ) – –
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Skin corrosion/irritation No information available.
Serious eye damage/eye irritationNo information available.
Respiratory or skin sensitizationNo information available.
Germ cell mutagenicity No information available.
Carcinogenicity No information available.
Reproductive toxicity No information available.
STOT – single exposure No information available.
STOT – repeated exposure No information available.
Aspiration hazard No information available.
12. ECOLOGICAL INFORMATION
Ecotoxicity The env
ironmental impact of this product has not been fully investigated.Chemical name Algae/aquatic plants Fish Toxicity to
microorganisms
Crustacea
BENZALDEHYDE
100-52-7
– 0.8 – 1.44: 96 h Lepomis
macrochirus mg/L LC50
flow-through 10.6 – 11.8:
– 50: 24 h Daphnia magna
mg/L EC50
_____________________________________________________________________________________________
Page 6 / 9
Product Name: STAN-MASK 21651 CITRUS SWEET GRAS

_____________________________________________________________________________________________
96 h Oncorhynchus
mykiss mg/L LC50
flow-through 6.8 – 8.53:
96 h Pimephales
promelas mg/L LC50
flow-through 12.69: 96 h
Oncorhynchus mykiss
mg/L LC50 static 7.5: 96
h Lepomis macrochirus
mg/L LC50 static
Persistence and degradability No information available.
Bioaccumulation There is no data for this product.
Component Information
Chemical name Partition coefficient
BENZALDEHYDE
100-52-7
1.48
CINNAMIC ALCOHOL
104-54-1
1.9
Other adverse effects No information available.
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Waste from residues/unused
products
Dispose of in accordance with local regulations. Dispose of waste in accordance with
environmental legislation.
Contaminated packaging Do not reuse empty containers.
14. TRANSPORT INFORMATION
DOT Not regulated
IATA
UN/ID no UN1169
Proper Shipping Name EXTRACTS, AROMATIC, LIQUID
Hazard Class 3
Packing group III
ERG Code 3L
Description UN1169, EXTRACTS, AROMATIC, LIQUID, 3, III
IMDG
UN/ID no UN1169
Proper Shipping Name EXTRACTS, AROMATIC, LIQUID
Hazard Class 3
Packing group III
_____________________________________________________________________________________________
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Product Name: STAN-MASK 21651 CITRUS SWEET GRAS

_____________________________________________________________________________________________
EmS No. F-E, S-D
Special Provisions 223, 955
Marine pollutant This product contains a chemical which is listed as a marine pollutant according to
IMDG/IMO
Description UN1169, EXTRACTS, AROMATIC, LIQUID, 3, III, (51 C C.C.)
ADR
UN/ID no UN1169
Proper Shipping Name EXTRACTS, AROMATIC, LIQUID
Hazard Class 3
Packing group III
Classification code F1
Tunnel restriction code D/E
Special Provisions 601, 640E
Description UN1169, EXTRACTS, AROMATIC, LIQUID, 3, III
ADR/RID-Labels 3
15. REGULATORY INFORMATION
International Inventories
TSCA Complies
DSL/NDSL Complies
EINECS/ELINCS Complies
ENCS Complies
IECSC Complies
KECL Complies
PICCS Complies
NZIoC Complies
AICS Complies
Legend: TSCA – United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL – Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS – European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS – Japan Existing and New Chemical Substances
IECSC – China Inventory of Existing Chemical Substances
KECL – Korean Existing and Evaluated Chemical Substances
PICCS – Philippines Inventory of Chemicals and Chemical Substances
NZIoC – New Zealand Inventory of Chemicals
AICS – Australian Inventory of Chemical Substances
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.
SARA 311/312 Hazard Categories
Acute health hazard Yes
Chronic Health Hazard Yes
Fire hazard Yes
Sudden release of pressure hazard No
Reactive Hazard No
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42).
_____________________________________________________________________________________________
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Product Name: STAN-MASK 21651 CITRUS SWEET GRAS

_____________________________________________________________________________________________
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material.
US State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations
US State Regulations This product does not contain any substances regulated by state right-to-know regulations
Chemical name New Jersey Massachusetts Pennsylvania
BENZALDEHYDE
100-52-7
X X X
ETHYL BENZOATE
93-89-0
– – X
U.S. EPA Label Information
EPA Pesticide Registration NumberNot applicable
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION
Issue Date:
Revision Date:
Version #:
07-22-2015
08-03-2017
02
Disclaimer: The information and recommendations contained herein are based upon data that are believed to be accurate
and reliable. Application and performance information are provided only as a guide, since the conditions of use are
beyond the control of Harwick Standard Distribution Corporation. Consequently, Harwick Standard makes no warranties,
express or implied, with respect to the goods or use of the goods or the performance of the goods and makes no
warranties of fitness for a particular purpose or merchantability. Buyer acknowledges that Harwick Standard will not be
liable for consequential, incidental, direct or special damages arising, directly or indirectly, in respect to such goods or
the use or failure thereof, whether based on breach of warranty, negligence, strict liability in tort or otherwise.
End of Safety Data Sheet
NFPA Health hazards 2 Flammability 2 Instability 0 Physical and chemical
properties –
HMIS Health hazards 2 Flammability 2 Physical hazards 0 Personal protection X
_____________________________________________________________________________________________
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Product Name: STAN-MASK 21651 CITRUS SWEET GRAS

39ACETATE_SDS.pdf

SAFETY DATA SHEET
SDS Distribution: The information in this document
should be made available to all who may handle the
product.
A.G. Layne, Inc. urges each customer or recipient of this SDS to study it carefully and consult appropriate expertise, as necessary or appropriate, to
become aware of and understand the data contained in this SDS and any hazards associated with the product. It is the Buyer’s/User’s responsibility to
ensure that his activities comply with all Federal, State, Provincial or Local laws. The information presented here pertains only to the product as shipped.
The information contained herein is based on our current knowledge of the underlying data and is intended to describe the product for the purpose of
health, safety and environmental requirements only. NO warranty or guarantee is expressed or implied regarding the accuracy of this data or the results
to be obtained from the use of the product.
Product ID Methyl Acetate
Methyl Acetate
Page 1 of 8 www.aglayne.com

SECTION 2) HAZARDS IDENTIFICATION
Classification:
Specific Target Organ Toxicity -Single Exposure (Narcotic Effects) – Category 3
Skin Irritation – Category 2
Eye Irritation – Category 2A
Flammable Liquids Category 2
Acute toxicity, Dermal – Category 5
Acute toxicity, Oral – Category 5
Pictograms:
Signal Word:
Danger
Hazardous Statements – Physical:
Highly flammable liquid and vapor
Hazardous Statements – Health:
May be harmful in contact with skin
May be harmful if swallowed
Causes serious eye irritation
Causes skin irritation
May cause drowsiness or dizziness
Precautionary Statements – General:
If medical advice is needed, have product container or label at hand.
Keep out of reach of children.
Read label before use.
Precautionary Statements – Prevention:
Wash with soap and water thoroughly after handling.
SAFETY DATA SHEET
May 19, 2015
A. G. Layne, Inc.
Product ID:
4578 Brazil Street Los Angeles, CA, US, 90039
Product Name:
Manufacturer’s Name:
Revision Date:
Address:
SECTION 1) CHEMICAL PRODUCT AND SUPPLIER’S IDENTIFICATION
Methyl Acetate
Version: 1.1
Date Printed: Sep 23, 2015
Supersedes Date: May 19, 2015
Methyl Acetate
Emergency Phone:
Information Phone:
CHEMTREC US : 1-800-424-9300, INTERNATIONAL CALLS : 1-703-527-3887
323-245-2345
Fax:
Product/Recommended Uses: Paint and coatings, industrial cleaning applications and other formulary applications
Methyl Acetate
Page 2 of 8 www.aglayne.com

Wear protective gloves/protective clothing/eye protection/face protection.
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
Keep container tightly closed.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting equipment.
Use only non-sparking tools.
Take action to prevent static discharges.
Avoid breathing dust/fume/gas/mist/vapors/spray.
Use only outdoors or in a well-ventilated area.
Precautionary Statements – Response:
Call a POISON CENTER/doctor if you feel unwell.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
If eye irritation persists: Get medical advice/attention.
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse with water or shower.
In case of fire: Use DRY chemical, alcohol- resistant foam, water spray/fog or carbon-dioxide to extinguish.
IF ON SKIN: Wash with plenty of water.
Specific treatment (see First-aid on this label).
If skin irritation occurs: Get medical advice/attention.
Take off contaminated clothing. And wash it before reuse.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Precautionary Statements – Storage:
Store in a well-ventilated place. Keep cool.
Store in a well-ventilated place. Store locked up.
Precautionary Statements – Disposal:
Dispose of contents/container to disposal recycling center.
Waste management should be in full compliance with federal, state and local laws.
SECTION 4) FIRST-AID MEASURES
Inhalation:
Remove source of exposure or move person to fresh air and keep comfortable for breathing. If victim is not breathing, call 911 and
administer CPR as directed.
Eliminate all ignition sources if safe to do so.
Skin Contact:
Rinse/wash with lukewarm, gently flowing water (and mild soap) for 15-20 minutes or until product is removed. If skin irritation occurs or
you feel unwell: Get medical advice/attention.
Eye Contact:
Remove source of exposure or move person to fresh air. Rinse eyes cautiously with lukewarm, gently flowing water for 15-20 minutes,
while holding the eyelids open. Remove contact lenses, if present and easy to do. Continue rinsing. Take care not to rinse contaminated
water into the unaffected eye or onto the face. Get immidiate medical attention.
Ingestion:
Do NOT induce vomiting. If vomiting occurs naturally, lie on your side, in the recovery position. Immediately call 911 POISON
CENTER/doctor/. Immediately transport to the nearest medical facility for treatment.
SECTION 5) FIRE-FIGHTING MEASURES
Suitable Extinguishing Media:
SECTION 3) COMPOSITION / INFORMATION ON INGREDIENTS
CAS Chemical Name % By Weight
0000079-20-9 METHYL ACETATE 80% – 100%
Methyl Acetate
Page 3 of 8 www.aglayne.com

Dry chemical, foam, carbon dioxide or fog is recommended. Water spray is recommended to cool or protect exposed materials or
structures. Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces. Simultaneous use of
foam and water on the same surface is to be avoided as water destroys the foam. Sand or earth may be used for small fires only.
Unsuitable Extinguishing Media:
No data available.
Specific Hazards in Case of Fire:
No data available.
Fire-fighting Procedures:
Isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done safely. Move undamaged
containers from immediate hazard area if it can be done safely. Water spray may be useful in minimizing or dispersing vapors and to
protect personnel.
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
Special Protective Actions:
Wear protective pressure self-contained breathing apparatus (SCBA) and full turnout gear.
SECTION 6) ACCIDENTAL RELEASE MEASURES
Emergency Procedure:
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
RELEASE CAN CAUSE FIRE/EXPLOSION. LIQUIDS/VAPORS MAY IGNITE.
Do not touch or walk through spilled material.
Isolate hazard area and keep unnecessary people away. Remove all possible sources of ignition in the surrounding area. Notify authorities
if any exposure to the general public or the environment occurs or is likely to occur.
If spilled material is cleaned up using a regulated solvent, the resulting waste mixture may be regulated.
Recommended Equipment:
Positive pressure, full-facepiece self-contained breathing apparatus (SCBA), or positive pressure supplied air respirator with escape SCBA
(NIOSH approved).
Personal Precautions:
Avoid breathing vapor. Avoid contact with skin, eye or clothing. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in
immediate area). Use explosive proof equipment. Avoid inhalation of dust and contact with skin and eyes. Do not touch damaged
containers or spilled materials unless wearing appropriate protective clothing.
Environmental Precautions:
Stop spill/release if it can be done safely. Prevent spilled material from entering sewers, storm drains, other unauthorized drainage systems
and natural waterways by using sand, earth, or other appropriate barriers.
Methods and Materials for Containment and Cleaning up:
Sand, clay and absorbent socks can be used to contain a spill.
SECTION 7) HANDLING AND STORAGE
General:
Wash hands after use.
Do not get in eyes, on skin or on clothing.
Do not breathe vapors or mists.
Use good personal hygiene practices.
Eating, drinking and smoking in work areas is prohibited.
Remove contaminated clothing and protective equipment before entering eating areas.
Eyewash stations and showers should be available in areas where this material is used and stored.
Ventilation Requirements:
Use only with adequate ventilation to control air contaminants to their exposure limits. The use of local ventilation is recommended to
control emissions near the source.
Storage Room Requirements:
Keep container(s) tightly closed and properly labeled. Store in cool, dry, well-ventilated areas away from heat, direct sunlight, strong
oxidizers and any incompatibilities. Store in approved containers and protect against physical damage. Keep containers securely sealed
when not in use. Indoor storage should meet OSHA standards and appropriate fire codes. Containers that have been opened must be
carefully resealed to prevent leakage. Empty container retain residue and may be dangerous.
Use non-sparking ventilation systems, approved explosion-proof equipment and intrinsically safe electrical systems in areas where this
product is used and stored.
Ground and bond containers and receiving equipment. Avoid static electricity by grounding.
Methyl Acetate
Page 4 of 8 www.aglayne.com

Electrostatic charges may be generated during pumping. Keep away from aerosols, flammables, oxidizing agents, corrosives and from
other flammable products.
SECTION 8) EXPOSURE CONTROLS, PERSONAL PROTECTION
Chemical Name OSHA
TWA
(ppm)
OSHA
TWA
(mg/m3)
OSHA
STEL
(ppm)
OSHA
STEL
(mg/m3)
OSHA
Tables (Z1,
Z2, Z3)

OSHA
Carcinogen
OSHA
Skin
designation
NIOSH
TWA
(ppm)
NIOSH
TWA
(mg/m3)
NIOSH
STEL
(ppm)
NIOSH
STEL
(mg/m3)

NIOSH
Carcinogen
METHYL ACETATE 200 610 1 200 610 250 760
Chemical Name ACGIH
TWA
(ppm)
ACGIH
TWA
(mg/m3)
ACGIH
STEL
(ppm)
ACGIH
STEL
(mg/m3)

ACGIH
Carcinogen

ACGIH
Notations

ACGIH
TLV Basis
METHYL ACETATE 200 606 250 757 Headache;
dizziness;
nausea;
eye dam
(degenerati
on of
ganglion
cells in the
retina)
Respiratory Protection:
If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker, a respiratory protection
program that meets or is equivalent to OSHA 29 CFR 1910.134 and ANSI Z88.2 should be followed. Check with respiratory protective
equipment suppliers.
Skin Protection:
Use of gloves approved to relevant standards made from the following materials may provide suitable chemical protection: PVC, neoprene
or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical
resistance of glove material, glove thickness, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced.
Use of an apron and over- boots of chemically impervious materials such as neoprene or nitrile rubber is recommended to avoid skin
sensitization. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at
the specific workplace. Launder soiled clothes or properly disposed of contaminated material, which cannot be decontaminated.
Eye Protection:
Wear eye protection with side shields or goggles. Wear indirect-vent, impact and splash resistant goggles when working with liquids. If
additional protection is needed for entire face, use in combination with a face shield.
Appropriate Engineering Controls:
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold
limit value.
SECTION 9) PHYSICAL AND CHEMICAL PROPERTIES
Appearance Clear liquid
Odor Threshold N/A
Odor Description Pleasant
pH N/A
Water Solubility N/A
Flammability Flashpoint below 73 F
Flash Point Symbol C
Flash Point -10 C
Physical and Chemical Properties
Specific Gravity 0.93
Density 7.80 lb/gal
% VOC 0.00%
VOC Actual 0.00 lb/gal
Density VOC 0.00 lb/gal
% Solids By Weight 0.00%
Methyl Acetate
Page 5 of 8 www.aglayne.com

Viscosity N/A
Lower Explosion Level N/A
Upper Explosion Level N/A
Vapor Pressure N/A
Vapor Density N/A
Freezing Point N/A
Melting Point N/A
Low Boiling Point N/A
High Boiling Point N/A
Auto Ignition Temp N/A
Decomposition Pt N/A
Evaporation Rate N/A
Coefficient Water/Oil N/A
VOC Composite Partial Pressure 0 mmHg (Calculated @ 20 C/68 F)
SECTION 10) STABILITY AND REACTIVITY
Stability:
Stable under normal conditions of use.
Conditions to Avoid:
Avoid heat, sparks, open flames and other ignition sources.
Hazardous Reactions/Polymerization:
No data available.
Incompatible Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Thermal decomposition may yield carbon dioxide and/or carbon monoxide.
SECTION 11) TOXICOLOGICAL INFORMATION
Acute toxicity:
Ingestion: May be harmful or fatal if swallowed.
Skin Corrosion/Irritation:
Causes skin irritation
Serious eye damage/irritation:
Causes serious eye irritation
Germ cell mutagenicity:
No data available
Respiratory/Skin Sensitization:
Slightly irritating to respiratory system.
Carcinogenicity:
No data available
Reproductive toxicity:
No data available
Specific Target Organ Toxicity – Repeated Exposure:
No data available
Aspiration hazard:
No data available
Specific Target Organ Toxicity – Single Exposure:
May cause drowsiness or dizziness
Methyl Acetate
Page 6 of 8 www.aglayne.com

0000079-20-9 METHYL ACETATE
SECTION 12) ECOLOGICAL INFORMATION
Bio-accumulative Potential:
No data available.
Persistence and Degradability:
No data available.
Mobility in Soil:
No data available.
Toxicity:
No data available
Other adverse effects:
No data available.
SECTION 13) DISPOSAL CONSIDERATIONS
Waste Disposal Method:
Under RCRA it is the responsibility of the user of the product to determine at the time of disposal whether the product meets RCRA criteria
for hazardous waste. Waste management should be in full compliance with federal, state and local laws.
Empty Containers retain product residue which may exhibit hazards of material, therefore do not pressurize, cut, glaze, weld or use for any
other purposes. Return drums to reclamation centers for proper cleaning and reuse.
SECTION 14) TRANSPORT INFORMATION
U.S. DOT Information:
UN1231, Methyl Acetate, 3, PG II
Emergency Response Guide (ERG):
Emergency Response Guide 129
SECTION 15) REGULATORY INFORMATION
CAS Chemical Name % By Weight Regulation List
0000079-20-9 METHYL ACETATE 80% – 100% SARA312,VOC_exempt,TSCA,OSHA
SECTION 16) OTHER INFORMATION
General:
A.G. Layne, Inc. urges each customer or recipient of this SDS to study it carefully and consult appropriate expertise, as necessary or
appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. It is the
Buyer’s/User’s responsibility to ensure that his activities comply with all Federal, State, Provincial or Local laws. The information presented
here pertains only to the product as shipped. The information contained herein is based on our current knowledge of the underlying data
and is intended to describe the product for the purpose of health, safety and environmental requirements only. NO warranty or guarantee
is expressed or implied regarding the accuracy of this data or the results to be obtained from the use of the product.
Methyl Acetate
Page 7 of 8 www.aglayne.com

2
3
H
0
HMIS
Chronic :
Version 1.1:
Change in Section 8-Respirator
DISCLAIMER
To the best of our knowledge, the information contained herein is accurate. However, neither A. G. Layne, Inc. nor any of its subsidiaries assumes
any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the
sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are
described herein, we cannot guarantee that these are the only hazards that exist. The above information pertains to this product as currently
formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.
Methyl Acetate
Page 8 of 8 www.aglayne.com

3921651CRF_SDS.pdf

SAFETY DATA SHEET
STAN-MASK 21651 CITRUS SWEET GRAS
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product identifier
Product Name STAN-MASK 21651 CITRUS SWEET GRAS
Other means of identification
CAS No Mixture
Synonyms None
Recommended use of the chemical and restrictions on use
Recommended Use Fragrances
Uses advised against No information available
Details of the supplier of the safety data sheet
Manufactured for and Supplied by Harwick Standard Distribution Corporation
P.O. Box 9360
60 S. Seiberling Street
Akron, OH 44305 USA
(330) 798-9300
www.harwickstandard.com
2. HAZARDS IDENTIFICATION
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Skin corrosion/irritation – Category 2
Skin sensitization – Category 1B
Aspiration toxicity – Category 1
Label elements Physical hazards – Flammable liquids – Category 3
Signal word – Danger
Hazard statements
Causes skin irritation
May cause an allergic skin reaction
May be fatal if swallowed and enters airways
_____________________________________________________________________________________________
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Product Name: STAN-MASK 21651 CITRUS SWEET GRAS
Flammable liquid and vapor

_____________________________________________________________________________________________
Precautionary Statements
Wash face, hands and any exposed skin thoroughly after handling
Avoid breathing dust/fume/gas/mist/vapors/spray
Contaminated work clothing must not be allowed out of the workplace
Keep away from heat/sparks/open flames/hot surfaces. – No smoking
Keep container tightly closed
Ground/bond container and receiving equipment
Use explosion-proof electrical/ ventilating / lighting/ .? / equipment
Use only non-sparking tools
Take precautionary measures against static discharge
Wear protective gloves/eye protection/face protection
Specific treatment (see .? on this label)
If skin irritation or rash occurs: Get medical advice/attention
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower
Wash contaminated clothing before reuse
IF SWALLOWED: Immediately call a POISON CENTER or doctor
Do NOT induce vomiting
In case of fire: Use CO2, dry chemical, or foam to extinguish
Precautionary Statements – Storage
Store locked up
Store in a well-ventilated place. Keep cool
Precautionary Statements – Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Not applicable Other Information
May be harmful if swallowed May be harmful in contact with skin Toxic to aquatic life with long lasting effects Toxic to aquatic life Unknown acute toxicity 1.9 % of the mixture consists of ingredient(s) of unknown toxicity
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance
Chemical name CAS No Weight-% Trade secret
ORANGE TERPENES 68647-72-3 80 – 90 *
BENZALDEHYDE 100-52-7 1 – 10 *
ANETHOLE 4180-23-8 1 – 10 *
CINNAMIC ALCOHOL 104-54-1 1 – 10 *
ALDEHYDE C-12 LAURIC 112-54-9 <1 * Appearanceclear liquid Physical State @20 C liquid Odor Characteristic _____________________________________________________________________________________________ Page 2 / 9 Product Name: STAN-MASK 21651 CITRUS SWEET GRAS _____________________________________________________________________________________________ *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures Inhalation Remove to fresh air. Eye contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician. Skin contact Wash skin with soap and water. Ingestion Clean mouth with water and drink afterwards plenty of water. Most important symptoms and effects, both acute and delayed Symptoms No information available. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use ex tinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media CAUTION: Use of water spray when fighting fire may be inefficient. Specific hazards arising from the chemical No information available. Explosion data Sensitivity to Mechanical ImpactNone. Sensitivity to Static DischargeNone. Special protective equipment for fire-fighters Firefighters should wear self-contained breathing apparatus and full firefighting turnout gear. Use personal protection equipment. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation. Environmental precautions Environmental precautions See Section 12 for additional Ecological Information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Pick up and transfer to properly labeled containers. _____________________________________________________________________________________________ Page 3 / 9 Product Name: STAN-MASK 21651 CITRUS SWEET GRAS _____________________________________________________________________________________________ Prevention of secondary hazardsClean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Limits The following ingredients are the only ingredients of the product above the cut-off level (or level that contributes to the hazard classification of the mixture) which have an exposure limit applicable in the region for which this safety data sheet is intended or other recommended limit. At this time, the other relevant constituents have no known exposure limits from the sources listed here. Appropriate engineering controls Engineering controls Showers Eyewash stations Ventilation systems. Individual protection measures, such as personal protective equipment Eye/face protection No special protective equipment required. Skin and body protection No special protective equipment required. Respiratory protection No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required. General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State @20 C liquid Appearance clear liquid Odor Characteristic Color Colorless - Pale Yellow Odor threshold No information available _____________________________________________________________________________________________ Page 4 / 9 Product Name: STAN-MASK 21651 CITRUS SWEET GRAS _____________________________________________________________________________________________ Specific gravity 0.8590-0.8790 Refractive Index 1.4740-1.4940 Explosive properties No information available Oxidizing properties No information available Softening point No information available Molecular weight No information available VOC Content (%) No information available Density VALUE No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity No information av ailable. Chemical stability Stable under normal conditions. Possibility of hazardous reactionsNone under normal processing. Conditions to avoid None known based on information supplied. Incompatible materials None known based on information supplied. Hazardous decomposition productsNone known based on information supplied. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Inhalation Specific test data for the substance or mixture is not available. Eye contact Specific test data for the substance or mixture is not available. Skin contact Specific test data for the substance or mixture is not available. Property Values pH No data available Melting point / freezing point No data available Boiling point / boiling range > 35 C / 95 F
Flash point 51 C / 124 F
Evaporation rate No data available
Flammability (solid, gas) No data available
Flammability Limit in Air
Upper flammability limit: No data available
Lower flammability limit: No data available
Vapor pressure No data available
Vapor density No data available
Relative density No data available
Water solubility No data available
Solubility in other solvents No data available
Partition coefficient No data available
Autoignition temperature No data available
Decomposition temperature No data available
Kinematic viscosity No data available
Dynamic viscosity
_____________________________________________________________________________________________
Page 5 / 9
Product Name: STAN-MASK 21651 CITRUS SWEET GRAS
No data available

_____________________________________________________________________________________________
Ingestion Specific test data for the substance or mixture is not available.
Information on toxicological effects
Symptoms No information available.
Numerical measures of toxicity
Acute toxicity
The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral) 4,266.00 mg/kg
ATEmix (dermal) 4,280.00 mg/kg mg/l
ATEmix (inhalation-dust/mist)33.30 mg/l
ATEmix (inhalation-vapor) 244.00 mg/l
Unknown acute toxicity 1.9 % of the mixture consists of ingredient(s) of unknown toxicity
Component Information
Chemical name Oral LD50 LD50/dermal/rat – NO UNITS
(Wizards mg/kg)
Inhalation LC50
BENZALDEHYDE
100-52-7
= 1292 mg/kg ( Rat ) > 1250 mg/kg ( Rabbit ) –
ANETHOLE
4180-23-8
= 2090 mg/kg ( Rat ) – –
CINNAMIC ALCOHOL
104-54-1
= 2 g/kg ( Rat ) > 5 g/kg ( Rabbit ) –
ALDEHYDE C-12 LAURIC
112-54-9
= 23 g/kg ( Rat ) – –
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Skin corrosion/irritation No information available.
Serious eye damage/eye irritationNo information available.
Respiratory or skin sensitizationNo information available.
Germ cell mutagenicity No information available.
Carcinogenicity No information available.
Reproductive toxicity No information available.
STOT – single exposure No information available.
STOT – repeated exposure No information available.
Aspiration hazard No information available.
12. ECOLOGICAL INFORMATION
Ecotoxicity The env
ironmental impact of this product has not been fully investigated.Chemical name Algae/aquatic plants Fish Toxicity to
microorganisms
Crustacea
BENZALDEHYDE
100-52-7
– 0.8 – 1.44: 96 h Lepomis
macrochirus mg/L LC50
flow-through 10.6 – 11.8:
– 50: 24 h Daphnia magna
mg/L EC50
_____________________________________________________________________________________________
Page 6 / 9
Product Name: STAN-MASK 21651 CITRUS SWEET GRAS

_____________________________________________________________________________________________
96 h Oncorhynchus
mykiss mg/L LC50
flow-through 6.8 – 8.53:
96 h Pimephales
promelas mg/L LC50
flow-through 12.69: 96 h
Oncorhynchus mykiss
mg/L LC50 static 7.5: 96
h Lepomis macrochirus
mg/L LC50 static
Persistence and degradability No information available.
Bioaccumulation There is no data for this product.
Component Information
Chemical name Partition coefficient
BENZALDEHYDE
100-52-7
1.48
CINNAMIC ALCOHOL
104-54-1
1.9
Other adverse effects No information available.
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Waste from residues/unused
products
Dispose of in accordance with local regulations. Dispose of waste in accordance with
environmental legislation.
Contaminated packaging Do not reuse empty containers.
14. TRANSPORT INFORMATION
DOT Not regulated
IATA
UN/ID no UN1169
Proper Shipping Name EXTRACTS, AROMATIC, LIQUID
Hazard Class 3
Packing group III
ERG Code 3L
Description UN1169, EXTRACTS, AROMATIC, LIQUID, 3, III
IMDG
UN/ID no UN1169
Proper Shipping Name EXTRACTS, AROMATIC, LIQUID
Hazard Class 3
Packing group III
_____________________________________________________________________________________________
Page 7 / 9
Product Name: STAN-MASK 21651 CITRUS SWEET GRAS

_____________________________________________________________________________________________
EmS No. F-E, S-D
Special Provisions 223, 955
Marine pollutant This product contains a chemical which is listed as a marine pollutant according to
IMDG/IMO
Description UN1169, EXTRACTS, AROMATIC, LIQUID, 3, III, (51 C C.C.)
ADR
UN/ID no UN1169
Proper Shipping Name EXTRACTS, AROMATIC, LIQUID
Hazard Class 3
Packing group III
Classification code F1
Tunnel restriction code D/E
Special Provisions 601, 640E
Description UN1169, EXTRACTS, AROMATIC, LIQUID, 3, III
ADR/RID-Labels 3
15. REGULATORY INFORMATION
International Inventories
TSCA Complies
DSL/NDSL Complies
EINECS/ELINCS Complies
ENCS Complies
IECSC Complies
KECL Complies
PICCS Complies
NZIoC Complies
AICS Complies
Legend: TSCA – United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL – Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS – European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS – Japan Existing and New Chemical Substances
IECSC – China Inventory of Existing Chemical Substances
KECL – Korean Existing and Evaluated Chemical Substances
PICCS – Philippines Inventory of Chemicals and Chemical Substances
NZIoC – New Zealand Inventory of Chemicals
AICS – Australian Inventory of Chemical Substances
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.
SARA 311/312 Hazard Categories
Acute health hazard Yes
Chronic Health Hazard Yes
Fire hazard Yes
Sudden release of pressure hazard No
Reactive Hazard No
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42).
_____________________________________________________________________________________________
Page 8 / 9
Product Name: STAN-MASK 21651 CITRUS SWEET GRAS

_____________________________________________________________________________________________
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material.
US State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations
US State Regulations This product does not contain any substances regulated by state right-to-know regulations
Chemical name New Jersey Massachusetts Pennsylvania
BENZALDEHYDE
100-52-7
X X X
ETHYL BENZOATE
93-89-0
– – X
U.S. EPA Label Information
EPA Pesticide Registration NumberNot applicable
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION
Issue Date:
Revision Date:
Version #:
07-22-2015
08-03-2017
02
Disclaimer: The information and recommendations contained herein are based upon data that are believed to be accurate
and reliable. Application and performance information are provided only as a guide, since the conditions of use are
beyond the control of Harwick Standard Distribution Corporation. Consequently, Harwick Standard makes no warranties,
express or implied, with respect to the goods or use of the goods or the performance of the goods and makes no
warranties of fitness for a particular purpose or merchantability. Buyer acknowledges that Harwick Standard will not be
liable for consequential, incidental, direct or special damages arising, directly or indirectly, in respect to such goods or
the use or failure thereof, whether based on breach of warranty, negligence, strict liability in tort or otherwise.
End of Safety Data Sheet
NFPA Health hazards 2 Flammability 2 Instability 0 Physical and chemical
properties –
HMIS Health hazards 2 Flammability 2 Physical hazards 0 Personal protection X
_____________________________________________________________________________________________
Page 9 / 9
Product Name: STAN-MASK 21651 CITRUS SWEET GRAS

3921651C-Q_SDS.pdf

SAFETY DATA SHEET
STAN-MASK 21651 CITRUS SWEET GRAS
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product identifier
Product Name STAN-MASK 21651 CITRUS SWEET GRAS
Other means of identification
CAS No Mixture
Synonyms None
Recommended use of the chemical and restrictions on use
Recommended Use Fragrances
Uses advised against No information available
Details of the supplier of the safety data sheet
Manufactured for and Supplied by Harwick Standard Distribution Corporation
P.O. Box 9360
60 S. Seiberling Street
Akron, OH 44305 USA
(330) 798-9300
www.harwickstandard.com
2. HAZARDS IDENTIFICATION
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Skin corrosion/irritation – Category 2
Skin sensitization – Category 1B
Aspiration toxicity – Category 1
Label elements Physical hazards – Flammable liquids – Category 3
Signal word – Danger
Hazard statements
Causes skin irritation
May cause an allergic skin reaction
May be fatal if swallowed and enters airways
_____________________________________________________________________________________________
Page 1 / 9
Product Name: STAN-MASK 21651 CITRUS SWEET GRAS
Flammable liquid and vapor

_____________________________________________________________________________________________
Precautionary Statements
Wash face, hands and any exposed skin thoroughly after handling
Avoid breathing dust/fume/gas/mist/vapors/spray
Contaminated work clothing must not be allowed out of the workplace
Keep away from heat/sparks/open flames/hot surfaces. – No smoking
Keep container tightly closed
Ground/bond container and receiving equipment
Use explosion-proof electrical/ ventilating / lighting/ .? / equipment
Use only non-sparking tools
Take precautionary measures against static discharge
Wear protective gloves/eye protection/face protection
Specific treatment (see .? on this label)
If skin irritation or rash occurs: Get medical advice/attention
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower
Wash contaminated clothing before reuse
IF SWALLOWED: Immediately call a POISON CENTER or doctor
Do NOT induce vomiting
In case of fire: Use CO2, dry chemical, or foam to extinguish
Precautionary Statements – Storage
Store locked up
Store in a well-ventilated place. Keep cool
Precautionary Statements – Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Not applicable Other Information
May be harmful if swallowed May be harmful in contact with skin Toxic to aquatic life with long lasting effects Toxic to aquatic life Unknown acute toxicity 1.9 % of the mixture consists of ingredient(s) of unknown toxicity
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance
Chemical name CAS No Weight-% Trade secret
ORANGE TERPENES 68647-72-3 80 – 90 *
BENZALDEHYDE 100-52-7 1 – 10 *
ANETHOLE 4180-23-8 1 – 10 *
CINNAMIC ALCOHOL 104-54-1 1 – 10 *
ALDEHYDE C-12 LAURIC 112-54-9 <1 * Appearanceclear liquid Physical State @20 C liquid Odor Characteristic _____________________________________________________________________________________________ Page 2 / 9 Product Name: STAN-MASK 21651 CITRUS SWEET GRAS _____________________________________________________________________________________________ *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures Inhalation Remove to fresh air. Eye contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician. Skin contact Wash skin with soap and water. Ingestion Clean mouth with water and drink afterwards plenty of water. Most important symptoms and effects, both acute and delayed Symptoms No information available. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use ex tinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media CAUTION: Use of water spray when fighting fire may be inefficient. Specific hazards arising from the chemical No information available. Explosion data Sensitivity to Mechanical ImpactNone. Sensitivity to Static DischargeNone. Special protective equipment for fire-fighters Firefighters should wear self-contained breathing apparatus and full firefighting turnout gear. Use personal protection equipment. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation. Environmental precautions Environmental precautions See Section 12 for additional Ecological Information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Pick up and transfer to properly labeled containers. _____________________________________________________________________________________________ Page 3 / 9 Product Name: STAN-MASK 21651 CITRUS SWEET GRAS _____________________________________________________________________________________________ Prevention of secondary hazardsClean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Limits The following ingredients are the only ingredients of the product above the cut-off level (or level that contributes to the hazard classification of the mixture) which have an exposure limit applicable in the region for which this safety data sheet is intended or other recommended limit. At this time, the other relevant constituents have no known exposure limits from the sources listed here. Appropriate engineering controls Engineering controls Showers Eyewash stations Ventilation systems. Individual protection measures, such as personal protective equipment Eye/face protection No special protective equipment required. Skin and body protection No special protective equipment required. Respiratory protection No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required. General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State @20 C liquid Appearance clear liquid Odor Characteristic Color Colorless - Pale Yellow Odor threshold No information available _____________________________________________________________________________________________ Page 4 / 9 Product Name: STAN-MASK 21651 CITRUS SWEET GRAS _____________________________________________________________________________________________ Specific gravity 0.8590-0.8790 Refractive Index 1.4740-1.4940 Explosive properties No information available Oxidizing properties No information available Softening point No information available Molecular weight No information available VOC Content (%) No information available Density VALUE No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity No information av ailable. Chemical stability Stable under normal conditions. Possibility of hazardous reactionsNone under normal processing. Conditions to avoid None known based on information supplied. Incompatible materials None known based on information supplied. Hazardous decomposition productsNone known based on information supplied. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Inhalation Specific test data for the substance or mixture is not available. Eye contact Specific test data for the substance or mixture is not available. Skin contact Specific test data for the substance or mixture is not available. Property Values pH No data available Melting point / freezing point No data available Boiling point / boiling range > 35 C / 95 F
Flash point 51 C / 124 F
Evaporation rate No data available
Flammability (solid, gas) No data available
Flammability Limit in Air
Upper flammability limit: No data available
Lower flammability limit: No data available
Vapor pressure No data available
Vapor density No data available
Relative density No data available
Water solubility No data available
Solubility in other solvents No data available
Partition coefficient No data available
Autoignition temperature No data available
Decomposition temperature No data available
Kinematic viscosity No data available
Dynamic viscosity
_____________________________________________________________________________________________
Page 5 / 9
Product Name: STAN-MASK 21651 CITRUS SWEET GRAS
No data available

_____________________________________________________________________________________________
Ingestion Specific test data for the substance or mixture is not available.
Information on toxicological effects
Symptoms No information available.
Numerical measures of toxicity
Acute toxicity
The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral) 4,266.00 mg/kg
ATEmix (dermal) 4,280.00 mg/kg mg/l
ATEmix (inhalation-dust/mist)33.30 mg/l
ATEmix (inhalation-vapor) 244.00 mg/l
Unknown acute toxicity 1.9 % of the mixture consists of ingredient(s) of unknown toxicity
Component Information
Chemical name Oral LD50 LD50/dermal/rat – NO UNITS
(Wizards mg/kg)
Inhalation LC50
BENZALDEHYDE
100-52-7
= 1292 mg/kg ( Rat ) > 1250 mg/kg ( Rabbit ) –
ANETHOLE
4180-23-8
= 2090 mg/kg ( Rat ) – –
CINNAMIC ALCOHOL
104-54-1
= 2 g/kg ( Rat ) > 5 g/kg ( Rabbit ) –
ALDEHYDE C-12 LAURIC
112-54-9
= 23 g/kg ( Rat ) – –
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Skin corrosion/irritation No information available.
Serious eye damage/eye irritationNo information available.
Respiratory or skin sensitizationNo information available.
Germ cell mutagenicity No information available.
Carcinogenicity No information available.
Reproductive toxicity No information available.
STOT – single exposure No information available.
STOT – repeated exposure No information available.
Aspiration hazard No information available.
12. ECOLOGICAL INFORMATION
Ecotoxicity The env
ironmental impact of this product has not been fully investigated.Chemical name Algae/aquatic plants Fish Toxicity to
microorganisms
Crustacea
BENZALDEHYDE
100-52-7
– 0.8 – 1.44: 96 h Lepomis
macrochirus mg/L LC50
flow-through 10.6 – 11.8:
– 50: 24 h Daphnia magna
mg/L EC50
_____________________________________________________________________________________________
Page 6 / 9
Product Name: STAN-MASK 21651 CITRUS SWEET GRAS

_____________________________________________________________________________________________
96 h Oncorhynchus
mykiss mg/L LC50
flow-through 6.8 – 8.53:
96 h Pimephales
promelas mg/L LC50
flow-through 12.69: 96 h
Oncorhynchus mykiss
mg/L LC50 static 7.5: 96
h Lepomis macrochirus
mg/L LC50 static
Persistence and degradability No information available.
Bioaccumulation There is no data for this product.
Component Information
Chemical name Partition coefficient
BENZALDEHYDE
100-52-7
1.48
CINNAMIC ALCOHOL
104-54-1
1.9
Other adverse effects No information available.
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Waste from residues/unused
products
Dispose of in accordance with local regulations. Dispose of waste in accordance with
environmental legislation.
Contaminated packaging Do not reuse empty containers.
14. TRANSPORT INFORMATION
DOT Not regulated
IATA
UN/ID no UN1169
Proper Shipping Name EXTRACTS, AROMATIC, LIQUID
Hazard Class 3
Packing group III
ERG Code 3L
Description UN1169, EXTRACTS, AROMATIC, LIQUID, 3, III
IMDG
UN/ID no UN1169
Proper Shipping Name EXTRACTS, AROMATIC, LIQUID
Hazard Class 3
Packing group III
_____________________________________________________________________________________________
Page 7 / 9
Product Name: STAN-MASK 21651 CITRUS SWEET GRAS

_____________________________________________________________________________________________
EmS No. F-E, S-D
Special Provisions 223, 955
Marine pollutant This product contains a chemical which is listed as a marine pollutant according to
IMDG/IMO
Description UN1169, EXTRACTS, AROMATIC, LIQUID, 3, III, (51 C C.C.)
ADR
UN/ID no UN1169
Proper Shipping Name EXTRACTS, AROMATIC, LIQUID
Hazard Class 3
Packing group III
Classification code F1
Tunnel restriction code D/E
Special Provisions 601, 640E
Description UN1169, EXTRACTS, AROMATIC, LIQUID, 3, III
ADR/RID-Labels 3
15. REGULATORY INFORMATION
International Inventories
TSCA Complies
DSL/NDSL Complies
EINECS/ELINCS Complies
ENCS Complies
IECSC Complies
KECL Complies
PICCS Complies
NZIoC Complies
AICS Complies
Legend: TSCA – United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL – Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS – European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS – Japan Existing and New Chemical Substances
IECSC – China Inventory of Existing Chemical Substances
KECL – Korean Existing and Evaluated Chemical Substances
PICCS – Philippines Inventory of Chemicals and Chemical Substances
NZIoC – New Zealand Inventory of Chemicals
AICS – Australian Inventory of Chemical Substances
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.
SARA 311/312 Hazard Categories
Acute health hazard Yes
Chronic Health Hazard Yes
Fire hazard Yes
Sudden release of pressure hazard No
Reactive Hazard No
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42).
_____________________________________________________________________________________________
Page 8 / 9
Product Name: STAN-MASK 21651 CITRUS SWEET GRAS

_____________________________________________________________________________________________
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material.
US State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations
US State Regulations This product does not contain any substances regulated by state right-to-know regulations
Chemical name New Jersey Massachusetts Pennsylvania
BENZALDEHYDE
100-52-7
X X X
ETHYL BENZOATE
93-89-0
– – X
U.S. EPA Label Information
EPA Pesticide Registration NumberNot applicable
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION
Issue Date:
Revision Date:
Version #:
07-22-2015
08-03-2017
02
Disclaimer: The information and recommendations contained herein are based upon data that are believed to be accurate
and reliable. Application and performance information are provided only as a guide, since the conditions of use are
beyond the control of Harwick Standard Distribution Corporation. Consequently, Harwick Standard makes no warranties,
express or implied, with respect to the goods or use of the goods or the performance of the goods and makes no
warranties of fitness for a particular purpose or merchantability. Buyer acknowledges that Harwick Standard will not be
liable for consequential, incidental, direct or special damages arising, directly or indirectly, in respect to such goods or
the use or failure thereof, whether based on breach of warranty, negligence, strict liability in tort or otherwise.
End of Safety Data Sheet
NFPA Health hazards 2 Flammability 2 Instability 0 Physical and chemical
properties –
HMIS Health hazards 2 Flammability 2 Physical hazards 0 Personal protection X
_____________________________________________________________________________________________
Page 9 / 9
Product Name: STAN-MASK 21651 CITRUS SWEET GRAS

3921651C-P_SDS.pdf

SAFETY DATA SHEET
STAN-MASK 21651 CITRUS SWEET GRAS
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product identifier
Product Name STAN-MASK 21651 CITRUS SWEET GRAS
Other means of identification
CAS No Mixture
Synonyms None
Recommended use of the chemical and restrictions on use
Recommended Use Fragrances
Uses advised against No information available
Details of the supplier of the safety data sheet
Manufactured for and Supplied by Harwick Standard Distribution Corporation
P.O. Box 9360
60 S. Seiberling Street
Akron, OH 44305 USA
(330) 798-9300
www.harwickstandard.com
2. HAZARDS IDENTIFICATION
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Skin corrosion/irritation – Category 2
Skin sensitization – Category 1B
Aspiration toxicity – Category 1
Label elements Physical hazards – Flammable liquids – Category 3
Signal word – Danger
Hazard statements
Causes skin irritation
May cause an allergic skin reaction
May be fatal if swallowed and enters airways
_____________________________________________________________________________________________
Page 1 / 9
Product Name: STAN-MASK 21651 CITRUS SWEET GRAS
Flammable liquid and vapor

_____________________________________________________________________________________________
Precautionary Statements
Wash face, hands and any exposed skin thoroughly after handling
Avoid breathing dust/fume/gas/mist/vapors/spray
Contaminated work clothing must not be allowed out of the workplace
Keep away from heat/sparks/open flames/hot surfaces. – No smoking
Keep container tightly closed
Ground/bond container and receiving equipment
Use explosion-proof electrical/ ventilating / lighting/ .? / equipment
Use only non-sparking tools
Take precautionary measures against static discharge
Wear protective gloves/eye protection/face protection
Specific treatment (see .? on this label)
If skin irritation or rash occurs: Get medical advice/attention
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower
Wash contaminated clothing before reuse
IF SWALLOWED: Immediately call a POISON CENTER or doctor
Do NOT induce vomiting
In case of fire: Use CO2, dry chemical, or foam to extinguish
Precautionary Statements – Storage
Store locked up
Store in a well-ventilated place. Keep cool
Precautionary Statements – Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Not applicable Other Information
May be harmful if swallowed May be harmful in contact with skin Toxic to aquatic life with long lasting effects Toxic to aquatic life Unknown acute toxicity 1.9 % of the mixture consists of ingredient(s) of unknown toxicity
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance
Chemical name CAS No Weight-% Trade secret
ORANGE TERPENES 68647-72-3 80 – 90 *
BENZALDEHYDE 100-52-7 1 – 10 *
ANETHOLE 4180-23-8 1 – 10 *
CINNAMIC ALCOHOL 104-54-1 1 – 10 *
ALDEHYDE C-12 LAURIC 112-54-9 <1 * Appearanceclear liquid Physical State @20 C liquid Odor Characteristic _____________________________________________________________________________________________ Page 2 / 9 Product Name: STAN-MASK 21651 CITRUS SWEET GRAS _____________________________________________________________________________________________ *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures Inhalation Remove to fresh air. Eye contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician. Skin contact Wash skin with soap and water. Ingestion Clean mouth with water and drink afterwards plenty of water. Most important symptoms and effects, both acute and delayed Symptoms No information available. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use ex tinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media CAUTION: Use of water spray when fighting fire may be inefficient. Specific hazards arising from the chemical No information available. Explosion data Sensitivity to Mechanical ImpactNone. Sensitivity to Static DischargeNone. Special protective equipment for fire-fighters Firefighters should wear self-contained breathing apparatus and full firefighting turnout gear. Use personal protection equipment. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation. Environmental precautions Environmental precautions See Section 12 for additional Ecological Information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Pick up and transfer to properly labeled containers. _____________________________________________________________________________________________ Page 3 / 9 Product Name: STAN-MASK 21651 CITRUS SWEET GRAS _____________________________________________________________________________________________ Prevention of secondary hazardsClean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Limits The following ingredients are the only ingredients of the product above the cut-off level (or level that contributes to the hazard classification of the mixture) which have an exposure limit applicable in the region for which this safety data sheet is intended or other recommended limit. At this time, the other relevant constituents have no known exposure limits from the sources listed here. Appropriate engineering controls Engineering controls Showers Eyewash stations Ventilation systems. Individual protection measures, such as personal protective equipment Eye/face protection No special protective equipment required. Skin and body protection No special protective equipment required. Respiratory protection No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required. General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State @20 C liquid Appearance clear liquid Odor Characteristic Color Colorless - Pale Yellow Odor threshold No information available _____________________________________________________________________________________________ Page 4 / 9 Product Name: STAN-MASK 21651 CITRUS SWEET GRAS _____________________________________________________________________________________________ Specific gravity 0.8590-0.8790 Refractive Index 1.4740-1.4940 Explosive properties No information available Oxidizing properties No information available Softening point No information available Molecular weight No information available VOC Content (%) No information available Density VALUE No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity No information av ailable. Chemical stability Stable under normal conditions. Possibility of hazardous reactionsNone under normal processing. Conditions to avoid None known based on information supplied. Incompatible materials None known based on information supplied. Hazardous decomposition productsNone known based on information supplied. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Inhalation Specific test data for the substance or mixture is not available. Eye contact Specific test data for the substance or mixture is not available. Skin contact Specific test data for the substance or mixture is not available. Property Values pH No data available Melting point / freezing point No data available Boiling point / boiling range > 35 C / 95 F
Flash point 51 C / 124 F
Evaporation rate No data available
Flammability (solid, gas) No data available
Flammability Limit in Air
Upper flammability limit: No data available
Lower flammability limit: No data available
Vapor pressure No data available
Vapor density No data available
Relative density No data available
Water solubility No data available
Solubility in other solvents No data available
Partition coefficient No data available
Autoignition temperature No data available
Decomposition temperature No data available
Kinematic viscosity No data available
Dynamic viscosity
_____________________________________________________________________________________________
Page 5 / 9
Product Name: STAN-MASK 21651 CITRUS SWEET GRAS
No data available

_____________________________________________________________________________________________
Ingestion Specific test data for the substance or mixture is not available.
Information on toxicological effects
Symptoms No information available.
Numerical measures of toxicity
Acute toxicity
The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral) 4,266.00 mg/kg
ATEmix (dermal) 4,280.00 mg/kg mg/l
ATEmix (inhalation-dust/mist)33.30 mg/l
ATEmix (inhalation-vapor) 244.00 mg/l
Unknown acute toxicity 1.9 % of the mixture consists of ingredient(s) of unknown toxicity
Component Information
Chemical name Oral LD50 LD50/dermal/rat – NO UNITS
(Wizards mg/kg)
Inhalation LC50
BENZALDEHYDE
100-52-7
= 1292 mg/kg ( Rat ) > 1250 mg/kg ( Rabbit ) –
ANETHOLE
4180-23-8
= 2090 mg/kg ( Rat ) – –
CINNAMIC ALCOHOL
104-54-1
= 2 g/kg ( Rat ) > 5 g/kg ( Rabbit ) –
ALDEHYDE C-12 LAURIC
112-54-9
= 23 g/kg ( Rat ) – –
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Skin corrosion/irritation No information available.
Serious eye damage/eye irritationNo information available.
Respiratory or skin sensitizationNo information available.
Germ cell mutagenicity No information available.
Carcinogenicity No information available.
Reproductive toxicity No information available.
STOT – single exposure No information available.
STOT – repeated exposure No information available.
Aspiration hazard No information available.
12. ECOLOGICAL INFORMATION
Ecotoxicity The env
ironmental impact of this product has not been fully investigated.Chemical name Algae/aquatic plants Fish Toxicity to
microorganisms
Crustacea
BENZALDEHYDE
100-52-7
– 0.8 – 1.44: 96 h Lepomis
macrochirus mg/L LC50
flow-through 10.6 – 11.8:
– 50: 24 h Daphnia magna
mg/L EC50
_____________________________________________________________________________________________
Page 6 / 9
Product Name: STAN-MASK 21651 CITRUS SWEET GRAS

_____________________________________________________________________________________________
96 h Oncorhynchus
mykiss mg/L LC50
flow-through 6.8 – 8.53:
96 h Pimephales
promelas mg/L LC50
flow-through 12.69: 96 h
Oncorhynchus mykiss
mg/L LC50 static 7.5: 96
h Lepomis macrochirus
mg/L LC50 static
Persistence and degradability No information available.
Bioaccumulation There is no data for this product.
Component Information
Chemical name Partition coefficient
BENZALDEHYDE
100-52-7
1.48
CINNAMIC ALCOHOL
104-54-1
1.9
Other adverse effects No information available.
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Waste from residues/unused
products
Dispose of in accordance with local regulations. Dispose of waste in accordance with
environmental legislation.
Contaminated packaging Do not reuse empty containers.
14. TRANSPORT INFORMATION
DOT Not regulated
IATA
UN/ID no UN1169
Proper Shipping Name EXTRACTS, AROMATIC, LIQUID
Hazard Class 3
Packing group III
ERG Code 3L
Description UN1169, EXTRACTS, AROMATIC, LIQUID, 3, III
IMDG
UN/ID no UN1169
Proper Shipping Name EXTRACTS, AROMATIC, LIQUID
Hazard Class 3
Packing group III
_____________________________________________________________________________________________
Page 7 / 9
Product Name: STAN-MASK 21651 CITRUS SWEET GRAS

_____________________________________________________________________________________________
EmS No. F-E, S-D
Special Provisions 223, 955
Marine pollutant This product contains a chemical which is listed as a marine pollutant according to
IMDG/IMO
Description UN1169, EXTRACTS, AROMATIC, LIQUID, 3, III, (51 C C.C.)
ADR
UN/ID no UN1169
Proper Shipping Name EXTRACTS, AROMATIC, LIQUID
Hazard Class 3
Packing group III
Classification code F1
Tunnel restriction code D/E
Special Provisions 601, 640E
Description UN1169, EXTRACTS, AROMATIC, LIQUID, 3, III
ADR/RID-Labels 3
15. REGULATORY INFORMATION
International Inventories
TSCA Complies
DSL/NDSL Complies
EINECS/ELINCS Complies
ENCS Complies
IECSC Complies
KECL Complies
PICCS Complies
NZIoC Complies
AICS Complies
Legend: TSCA – United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL – Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS – European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS – Japan Existing and New Chemical Substances
IECSC – China Inventory of Existing Chemical Substances
KECL – Korean Existing and Evaluated Chemical Substances
PICCS – Philippines Inventory of Chemicals and Chemical Substances
NZIoC – New Zealand Inventory of Chemicals
AICS – Australian Inventory of Chemical Substances
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.
SARA 311/312 Hazard Categories
Acute health hazard Yes
Chronic Health Hazard Yes
Fire hazard Yes
Sudden release of pressure hazard No
Reactive Hazard No
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42).
_____________________________________________________________________________________________
Page 8 / 9
Product Name: STAN-MASK 21651 CITRUS SWEET GRAS

_____________________________________________________________________________________________
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material.
US State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations
US State Regulations This product does not contain any substances regulated by state right-to-know regulations
Chemical name New Jersey Massachusetts Pennsylvania
BENZALDEHYDE
100-52-7
X X X
ETHYL BENZOATE
93-89-0
– – X
U.S. EPA Label Information
EPA Pesticide Registration NumberNot applicable
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION
Issue Date:
Revision Date:
Version #:
07-22-2015
08-03-2017
02
Disclaimer: The information and recommendations contained herein are based upon data that are believed to be accurate
and reliable. Application and performance information are provided only as a guide, since the conditions of use are
beyond the control of Harwick Standard Distribution Corporation. Consequently, Harwick Standard makes no warranties,
express or implied, with respect to the goods or use of the goods or the performance of the goods and makes no
warranties of fitness for a particular purpose or merchantability. Buyer acknowledges that Harwick Standard will not be
liable for consequential, incidental, direct or special damages arising, directly or indirectly, in respect to such goods or
the use or failure thereof, whether based on breach of warranty, negligence, strict liability in tort or otherwise.
End of Safety Data Sheet
NFPA Health hazards 2 Flammability 2 Instability 0 Physical and chemical
properties –
HMIS Health hazards 2 Flammability 2 Physical hazards 0 Personal protection X
_____________________________________________________________________________________________
Page 9 / 9
Product Name: STAN-MASK 21651 CITRUS SWEET GRAS

3921651C-G_SDS.pdf

SAFETY DATA SHEET
STAN-MASK 21651 CITRUS SWEET GRAS
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product identifier
Product Name STAN-MASK 21651 CITRUS SWEET GRAS
Other means of identification
CAS No Mixture
Synonyms None
Recommended use of the chemical and restrictions on use
Recommended Use Fragrances
Uses advised against No information available
Details of the supplier of the safety data sheet
Manufactured for and Supplied by Harwick Standard Distribution Corporation
P.O. Box 9360
60 S. Seiberling Street
Akron, OH 44305 USA
(330) 798-9300
www.harwickstandard.com
2. HAZARDS IDENTIFICATION
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Skin corrosion/irritation – Category 2
Skin sensitization – Category 1B
Aspiration toxicity – Category 1
Label elements Physical hazards – Flammable liquids – Category 3
Signal word – Danger
Hazard statements
Causes skin irritation
May cause an allergic skin reaction
May be fatal if swallowed and enters airways
_____________________________________________________________________________________________
Page 1 / 9
Product Name: STAN-MASK 21651 CITRUS SWEET GRAS
Flammable liquid and vapor

_____________________________________________________________________________________________
Precautionary Statements
Wash face, hands and any exposed skin thoroughly after handling
Avoid breathing dust/fume/gas/mist/vapors/spray
Contaminated work clothing must not be allowed out of the workplace
Keep away from heat/sparks/open flames/hot surfaces. – No smoking
Keep container tightly closed
Ground/bond container and receiving equipment
Use explosion-proof electrical/ ventilating / lighting/ .? / equipment
Use only non-sparking tools
Take precautionary measures against static discharge
Wear protective gloves/eye protection/face protection
Specific treatment (see .? on this label)
If skin irritation or rash occurs: Get medical advice/attention
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower
Wash contaminated clothing before reuse
IF SWALLOWED: Immediately call a POISON CENTER or doctor
Do NOT induce vomiting
In case of fire: Use CO2, dry chemical, or foam to extinguish
Precautionary Statements – Storage
Store locked up
Store in a well-ventilated place. Keep cool
Precautionary Statements – Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Not applicable Other Information
May be harmful if swallowed May be harmful in contact with skin Toxic to aquatic life with long lasting effects Toxic to aquatic life Unknown acute toxicity 1.9 % of the mixture consists of ingredient(s) of unknown toxicity
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance
Chemical name CAS No Weight-% Trade secret
ORANGE TERPENES 68647-72-3 80 – 90 *
BENZALDEHYDE 100-52-7 1 – 10 *
ANETHOLE 4180-23-8 1 – 10 *
CINNAMIC ALCOHOL 104-54-1 1 – 10 *
ALDEHYDE C-12 LAURIC 112-54-9 <1 * Appearanceclear liquid Physical State @20 C liquid Odor Characteristic _____________________________________________________________________________________________ Page 2 / 9 Product Name: STAN-MASK 21651 CITRUS SWEET GRAS _____________________________________________________________________________________________ *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures Inhalation Remove to fresh air. Eye contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician. Skin contact Wash skin with soap and water. Ingestion Clean mouth with water and drink afterwards plenty of water. Most important symptoms and effects, both acute and delayed Symptoms No information available. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use ex tinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media CAUTION: Use of water spray when fighting fire may be inefficient. Specific hazards arising from the chemical No information available. Explosion data Sensitivity to Mechanical ImpactNone. Sensitivity to Static DischargeNone. Special protective equipment for fire-fighters Firefighters should wear self-contained breathing apparatus and full firefighting turnout gear. Use personal protection equipment. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation. Environmental precautions Environmental precautions See Section 12 for additional Ecological Information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Pick up and transfer to properly labeled containers. _____________________________________________________________________________________________ Page 3 / 9 Product Name: STAN-MASK 21651 CITRUS SWEET GRAS _____________________________________________________________________________________________ Prevention of secondary hazardsClean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Limits The following ingredients are the only ingredients of the product above the cut-off level (or level that contributes to the hazard classification of the mixture) which have an exposure limit applicable in the region for which this safety data sheet is intended or other recommended limit. At this time, the other relevant constituents have no known exposure limits from the sources listed here. Appropriate engineering controls Engineering controls Showers Eyewash stations Ventilation systems. Individual protection measures, such as personal protective equipment Eye/face protection No special protective equipment required. Skin and body protection No special protective equipment required. Respiratory protection No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required. General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State @20 C liquid Appearance clear liquid Odor Characteristic Color Colorless - Pale Yellow Odor threshold No information available _____________________________________________________________________________________________ Page 4 / 9 Product Name: STAN-MASK 21651 CITRUS SWEET GRAS _____________________________________________________________________________________________ Specific gravity 0.8590-0.8790 Refractive Index 1.4740-1.4940 Explosive properties No information available Oxidizing properties No information available Softening point No information available Molecular weight No information available VOC Content (%) No information available Density VALUE No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity No information av ailable. Chemical stability Stable under normal conditions. Possibility of hazardous reactionsNone under normal processing. Conditions to avoid None known based on information supplied. Incompatible materials None known based on information supplied. Hazardous decomposition productsNone known based on information supplied. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Inhalation Specific test data for the substance or mixture is not available. Eye contact Specific test data for the substance or mixture is not available. Skin contact Specific test data for the substance or mixture is not available. Property Values pH No data available Melting point / freezing point No data available Boiling point / boiling range > 35 C / 95 F
Flash point 51 C / 124 F
Evaporation rate No data available
Flammability (solid, gas) No data available
Flammability Limit in Air
Upper flammability limit: No data available
Lower flammability limit: No data available
Vapor pressure No data available
Vapor density No data available
Relative density No data available
Water solubility No data available
Solubility in other solvents No data available
Partition coefficient No data available
Autoignition temperature No data available
Decomposition temperature No data available
Kinematic viscosity No data available
Dynamic viscosity
_____________________________________________________________________________________________
Page 5 / 9
Product Name: STAN-MASK 21651 CITRUS SWEET GRAS
No data available

_____________________________________________________________________________________________
Ingestion Specific test data for the substance or mixture is not available.
Information on toxicological effects
Symptoms No information available.
Numerical measures of toxicity
Acute toxicity
The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral) 4,266.00 mg/kg
ATEmix (dermal) 4,280.00 mg/kg mg/l
ATEmix (inhalation-dust/mist)33.30 mg/l
ATEmix (inhalation-vapor) 244.00 mg/l
Unknown acute toxicity 1.9 % of the mixture consists of ingredient(s) of unknown toxicity
Component Information
Chemical name Oral LD50 LD50/dermal/rat – NO UNITS
(Wizards mg/kg)
Inhalation LC50
BENZALDEHYDE
100-52-7
= 1292 mg/kg ( Rat ) > 1250 mg/kg ( Rabbit ) –
ANETHOLE
4180-23-8
= 2090 mg/kg ( Rat ) – –
CINNAMIC ALCOHOL
104-54-1
= 2 g/kg ( Rat ) > 5 g/kg ( Rabbit ) –
ALDEHYDE C-12 LAURIC
112-54-9
= 23 g/kg ( Rat ) – –
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Skin corrosion/irritation No information available.
Serious eye damage/eye irritationNo information available.
Respiratory or skin sensitizationNo information available.
Germ cell mutagenicity No information available.
Carcinogenicity No information available.
Reproductive toxicity No information available.
STOT – single exposure No information available.
STOT – repeated exposure No information available.
Aspiration hazard No information available.
12. ECOLOGICAL INFORMATION
Ecotoxicity The env
ironmental impact of this product has not been fully investigated.Chemical name Algae/aquatic plants Fish Toxicity to
microorganisms
Crustacea
BENZALDEHYDE
100-52-7
– 0.8 – 1.44: 96 h Lepomis
macrochirus mg/L LC50
flow-through 10.6 – 11.8:
– 50: 24 h Daphnia magna
mg/L EC50
_____________________________________________________________________________________________
Page 6 / 9
Product Name: STAN-MASK 21651 CITRUS SWEET GRAS

_____________________________________________________________________________________________
96 h Oncorhynchus
mykiss mg/L LC50
flow-through 6.8 – 8.53:
96 h Pimephales
promelas mg/L LC50
flow-through 12.69: 96 h
Oncorhynchus mykiss
mg/L LC50 static 7.5: 96
h Lepomis macrochirus
mg/L LC50 static
Persistence and degradability No information available.
Bioaccumulation There is no data for this product.
Component Information
Chemical name Partition coefficient
BENZALDEHYDE
100-52-7
1.48
CINNAMIC ALCOHOL
104-54-1
1.9
Other adverse effects No information available.
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Waste from residues/unused
products
Dispose of in accordance with local regulations. Dispose of waste in accordance with
environmental legislation.
Contaminated packaging Do not reuse empty containers.
14. TRANSPORT INFORMATION
DOT Not regulated
IATA
UN/ID no UN1169
Proper Shipping Name EXTRACTS, AROMATIC, LIQUID
Hazard Class 3
Packing group III
ERG Code 3L
Description UN1169, EXTRACTS, AROMATIC, LIQUID, 3, III
IMDG
UN/ID no UN1169
Proper Shipping Name EXTRACTS, AROMATIC, LIQUID
Hazard Class 3
Packing group III
_____________________________________________________________________________________________
Page 7 / 9
Product Name: STAN-MASK 21651 CITRUS SWEET GRAS

_____________________________________________________________________________________________
EmS No. F-E, S-D
Special Provisions 223, 955
Marine pollutant This product contains a chemical which is listed as a marine pollutant according to
IMDG/IMO
Description UN1169, EXTRACTS, AROMATIC, LIQUID, 3, III, (51 C C.C.)
ADR
UN/ID no UN1169
Proper Shipping Name EXTRACTS, AROMATIC, LIQUID
Hazard Class 3
Packing group III
Classification code F1
Tunnel restriction code D/E
Special Provisions 601, 640E
Description UN1169, EXTRACTS, AROMATIC, LIQUID, 3, III
ADR/RID-Labels 3
15. REGULATORY INFORMATION
International Inventories
TSCA Complies
DSL/NDSL Complies
EINECS/ELINCS Complies
ENCS Complies
IECSC Complies
KECL Complies
PICCS Complies
NZIoC Complies
AICS Complies
Legend: TSCA – United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL – Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS – European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS – Japan Existing and New Chemical Substances
IECSC – China Inventory of Existing Chemical Substances
KECL – Korean Existing and Evaluated Chemical Substances
PICCS – Philippines Inventory of Chemicals and Chemical Substances
NZIoC – New Zealand Inventory of Chemicals
AICS – Australian Inventory of Chemical Substances
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.
SARA 311/312 Hazard Categories
Acute health hazard Yes
Chronic Health Hazard Yes
Fire hazard Yes
Sudden release of pressure hazard No
Reactive Hazard No
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42).
_____________________________________________________________________________________________
Page 8 / 9
Product Name: STAN-MASK 21651 CITRUS SWEET GRAS

_____________________________________________________________________________________________
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material.
US State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations
US State Regulations This product does not contain any substances regulated by state right-to-know regulations
Chemical name New Jersey Massachusetts Pennsylvania
BENZALDEHYDE
100-52-7
X X X
ETHYL BENZOATE
93-89-0
– – X
U.S. EPA Label Information
EPA Pesticide Registration NumberNot applicable
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION
Issue Date:
Revision Date:
Version #:
07-22-2015
08-03-2017
02
Disclaimer: The information and recommendations contained herein are based upon data that are believed to be accurate
and reliable. Application and performance information are provided only as a guide, since the conditions of use are
beyond the control of Harwick Standard Distribution Corporation. Consequently, Harwick Standard makes no warranties,
express or implied, with respect to the goods or use of the goods or the performance of the goods and makes no
warranties of fitness for a particular purpose or merchantability. Buyer acknowledges that Harwick Standard will not be
liable for consequential, incidental, direct or special damages arising, directly or indirectly, in respect to such goods or
the use or failure thereof, whether based on breach of warranty, negligence, strict liability in tort or otherwise.
End of Safety Data Sheet
NFPA Health hazards 2 Flammability 2 Instability 0 Physical and chemical
properties –
HMIS Health hazards 2 Flammability 2 Physical hazards 0 Personal protection X
_____________________________________________________________________________________________
Page 9 / 9
Product Name: STAN-MASK 21651 CITRUS SWEET GRAS