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INDEX
80EL336
80EL336-5
80EL336-G
Page 1 of 5 Revision Date: 06/10/2013
SAFETY DATA SHEET
1.0 IDENTIFICATION
1.1 GHS product identifier: EL-336 Resin
1.2 Other means of identification: Epoxy Resin Blend
1.3 Recommended use of the chemical and restrictions on use: N/A
1.4 Supplier’s details: CASS POLYMERS OF MICHIGAN, INC.
815 WEST SHEPHERD STREET
CHARLOTTE MI 48813 USA
INFORMATION PHONE NUMBER: (248) 588-2270
1.5 Emergency phone number: (703) 527-3887(Call Collect)
2.0 HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture:
Skin Corrosion/Irritation 2, Eye Damage/Irritation 2B, Skin Sensitizer 1
2.2 GHS label elements:
Signal Word: Warning
Hazard Statement: Causes skin irritation
Prevention: Wash hands thoroughly after handling. Wear protective gloves.
Response: If on skin: wash with plenty of soap and water. If skin irritation occurs: get medical
advice/attention. Take off contaminated clothing and wash before reuse.
Signal Word: Warning
Hazard Statement: Causes eye irritation
Prevention: Flush eyes thoroughly after eye contact.
Response: If in eyes: rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: get medical advice/attention.
Signal Word: Warning
Hazard Statement: May cause an allergic skin reaction
Prevention: Avoid breathing dust/fume/gas/mist/vapors/spray. Contaminated work clothing must
not be allowed out of the workplace. Wear protective gloves.
Response: If on skin: Wash with plenty of soap and water. If skin irritation or rash occurs: Get
medical advice/attention. Continued and thorough washing in flowing water for at least 15
minutes is imperative while removing contaminated clothing. Prompt medical consultation is
essential. Wash contaminated clothing before reuse.
Disposal: Preferred method of disposal includes incineration under controlled conditions in
accordance with all local and national laws and regulations.
2.3 Other hazards which do not result in classification: N/A
2.4 Hazards Material Information System (United States):
Health 2
Flammability 1
Physical Hazard 0
Hazard Codes: 0=Chronic Hazard 0=Minimal Hazard, 1=Slight Hazard, 2=Moderate Hazard, 3=Serious Hazard,
4=Severe Hazard
3.0 COMPOSITION/INFORMATION ON INGREDIENTS
3.1 Mixtures
Chemical Identity CAS No. Concentration
Reaction Product of Bisphenol-A and Epichlorhydrin 25068-38-6 50% – 60%
Neopentyl Glycol Diglycidyl Ether 17557-23-2 5% – 10%
Reaction Product of Epichlorhydrin, Phenol-Formaldehyde Novalac 28064-14-4 20% – 30%
Glycidoxypropyl Trimethoxysilane 2530-83-8 1%
Page 2 of 5 Revision Date: 06/10/2013
4.0 FIRST-AID MEASURES
4.1 Description of necessary first-aid measures:
Never give fluids or induce vomiting if patient is unconscious or is having convulsions.
Inhalation: Move effected persons to fresh air; if effects occur, consult a physician.
Skin Contact: Continued and thorough washing in flowing water for at least 15 minutes is imperative while
removing contaminated clothing. Prompt medical consultation is essential. Wash clothing before reuse. Destroy
contaminated leather items.
Eye Contact: Wash immediately and continuously with flowing water for at least 15 minutes. Remove contact
lenses after the first 5 minutes and continue washing. Obtain prompt medical consultation, preferably from an
ophthalmologist.
Ingestion: If swallowed, call a physician immediately. Remove stomach contents by gastric suction or induce
vomiting only as directed by a physician or medical personnel. Do not give anything by mouth to an unconscious
person.
Note to Physician: No specific antidote. Treatment of exposure should be directed at the control of symptoms and
the clinical condition of the patient.
4.2 Most Important symptoms/effects, acute and delayed:
Signs and Symptoms of Exposure (Acute Effects): Contact with eyes may cause mild irritation and discomfort.
Contact with skin causes irritation, redness and discomfort which is transient. Inhalation of mists may cause irritation
in the respiratory tract. Inhalation of vapors from heated materials may cause irritation in the respiratory tract.
Coughing and chest pain may result.
Signs and Symptoms of Exposure (Possible Longer Term Effects): Repeated and/or prolonged exposure may
cause allergic reaction/sensitization. Repeated and/or prolonged exposures may result in: adverse skin effects (such
as rash, irritation or corrosion).
Medical Conditions Generally Aggravated by Exposure: Skin disorders and Allergies
Carcinogens under OSHA, ACGIH, NTP, IARC, Other: This product contains no known or suspected
carcinogens in concentrations of 0.1 percent or greater.
4.3 Indication of immediate medical attention and special treatment needed, if necessary: N/A
5.0 FIRE-FIGHTING MEASURES
5.1 Suitable extinguishing media:
Water fog or fine spray. Carbon dioxide. Alcohol resistant foam. Dry chemical fire extinguishers.
5.2 Specific hazards arising from the chemical:
Flash point is Not Determined. May generate toxic or irritating combustion products. Sudden reaction and fire may
occur if product is mixed with an oxidizing agent.
5.3 Special protective actions for fire-fighters:
Wear positive-pressure self-contained breathing apparatus and protective firefighting clothing (includes firefighting
helmet, coat, trousers, boots and gloves.)
6.0 ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures:
Wear adequate personal protective equipment; see Section 8-EXPOSURE CONTROLS/PERSONAL
PROTECTION.
6.2 Methods and materials for containment and clean up:
Large spills: Contain with dike. Pump into suitable and properly labeled containers.
Small spills: Dilute with water and recover or use non-combustible absorbent material/sand and shovel into
appropriate containers.
7.0 HANDLING AND STORAGE
7.1 Precautions for safe handling:
Avoid contact with skin or eyes. Avoid breathing of vapors. Handle in well-ventilated workspace. When handling, do
not eat, drink, or smoke.
Other Precautions: Emergency showers and eye wash stations should be readily accessible. Adhere to work practice
rules established by government regulations (e.g. OSHA).
7.2 Conditions for safe storage, including any incompatibilities:
Keep away from: oxidizers. Keep in cool, dry, ventilated storage areas and in closed containers.
Page 3 of 5 Revision Date: 06/10/2013
8.0 EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 Control parameters
Component CAS No. Percent Exposure Limits Source
Glycidoxypropyl Trimethoxysilane 2530-83-8 1% – 2%
5ppm TWA
10ppm STEL
Dow-Corning
8.2 Appropriate engineering controls:
No specific controls needed.
8.3 Individual protection measures, such as personal protective equipment:
Eye Protection: Chemical safety glasses. A full-face shield and vapor respirator is recommended for operations
involving spraying or other operations placing this material under pressurized conditions.
Hand Protection: Neoprene rubber gloves. Impermeable gloves. Nitrile rubber gloves. The breakthrough time of
the selected glove(s) must be greater than the intended use period.
Respiratory Protection: Not required under normal conditions and in a well-ventilated workplace. At elevated
temperatures, a cartridge mask National Institute for Occupational Safety and Health (NIOSH) approved for organic
vapors may be appropriate.
Protective Clothing: Long sleeved clothing.
Work and Hygienic Practices: Provide readily accessible eye wash stations and safety showers. Wash at the end of
each work shift and before eating, smoking or using the toilet.
Notice: The selection of a specific glove for a particular application and duration of use in a workplace should also
take into account all requisite workplace factors such as, but not limited to: Other chemicals which may be handled,
physical requirements (cut/puncture protection, dexterity, thermal protection), as well as the
instructions/specifications provided by the glove supplier.
9.0 PHYSICAL AND CHEMICAL PROPERTIES
9.1 Appearance (physical state, color, etc.): Liquid, Amber to Clear
9.2 Odor: Epoxy Odor
9.3 Odor threshold: N/A
9.4 pH: Not Determined
9.5 Melting point/freezing point: Not Determined
9.6 Initial boiling point and boiling range: Not Determined
9.7 Flash Point: Not Determined
9.8 Evaporation rate: N/A
9.9 Flammability (solid, gas): N/A
9.10 Upper/lower flammability or explosive limits: LFL-Not Determined; UFL-Not Determined
9.11 Vapor pressure: Not Determined
9.12 Vapor Density: N/A
9.13 Relative density(Specific Gravity): 1.10 1.15
9.14 Solubility(ies): Liquid Components are Not Readily Soluble in Water
9.15 Partition coefficient; n-octanol/water: N/A
9.16 Auto-ignition temperature: >300 C
9.17 Decomposition temperature: N/A
9.18 Viscosity: N/A
9.19 % Volatile (VOC): 0g/L
10.0 STABILITY AND REACTIVITY
10.1 Reactivity: N/A
10.2 Chemical stability: Stable
10.3 Possibility of hazardous reactions: Will not occur
10.4 Conditions to avoid: N/A
10.5 Incompatible materials: Oxidizing Agents (i.e. perchlorates, nitrates etc.). Sodium or Calcium Hypochlorite.
Reaction with peroxides may result in violent decomposition of peroxide possibly creating an explosion.
10.6 Hazardous decomposition products: Carbon Monoxide in a fire. Carbon Dioxide in a fire. Irritating and toxic
fumes at elevated temperatures.
11.0 TOXICOLOGICAL INFORMATION
Page 4 of 5 Revision Date: 06/10/2013
11.1 Likely routes of exposure: Eye Contact, Skin Contact, Ingestion.
11.2 Symptoms related to the physical, chemical and toxicological characteristics:
Ingestion: This material has a low potential for toxic effects due to ingestion.
Skin Contact: Prolonged or widespread skin contact is not likely to cause toxic effects.
Irritation:
Skin: Skin contact has caused allergic skin reactions in certain sensitized individuals.
Eyes: May cause slight temporary eye irritation with local redness. Mechanical irritation possible due to solid filler
materials.
Inhalation: May cause allergic respiratory response upon exposure to heated vapors.
11.3 Delayed and immediate effects and also chronic effects from short and long term exposure:
Carcinogen: This material contains no known or suspected carcinogens in levels above 0.1%.
Mutagen: This material contains no known or suspected mutagens in levels above 0.1%.
Reproductive Hazard: This material contains no materials known or suspected to cause reproductive hazards in
levels above 0.1%.
11.4 Numerical measures of toxicity:
This finished product has not been tested to determine individual toxicological/ecological limits. Individual
components of this mixture have been independently tested by the raw material manufacturers and any known results
have been presented below. The results for the individual components may not be representative of the toxicity of
this finished product.
Ingredient Name CAS No. % Test Result Route Species
Polymer of Epichlorohydrin,Phenol-
Formaldehyde Novolac
28064-14-4 20% – 30% LD50 >4,000 mg/kg Oral Rat
Neopentyl Glycol Diglycidyl Ether 17557-23-2 5% – 10% LD50 4,500 mg/kg Oral Rat
12.0 ECOLOGICAL INFORMATION
12.1 Ecotoxicity:
Diglycidyl Ether of Bisphenol-A (DGEBA) resins (44% formula mass) are toxic to aquatic organisms
(LC50/EC50/IC50 between 1 and 10 mg/L in most sensitive species). However, DGEBA is insoluble in water under
most conditions.
Individual components of this mixture have been independently tested by the raw material suppliers and any known
information has been presented above. The results for the individual components may not be representative of the
ecological toxicity of this finished product. Caution should be taken to prevent release to the environment. See
Section 13 for further information.
12.2 Persistence and degradability:
This material contains components that show little or no evidence of biodegradability. Caution should be taken to
prevent release to the environment. See Section 13 for further information.
Degradation: Based on the stringent OECD test guidelines, this material cannot be considered as readily
biodegradable; however, these results do not necessarily mean that the material is not biodegradable under
environmental conditions.
12.3 Bioaccumulative potential: N/A
12.4 Mobility in soil: N/A
12.5 Other adverse effects: N/A
13.0 DISPOSAL CONSIDERATIONS
13.1 Disposal methods:
Preferred method of disposal includes incineration under controlled conditions in accordance with all local and
national laws and regulations. The generation of waste should be avoided or minimized wherever possible.
Untreated material is not suitable for disposal. Waste, even small quantities, should never be poured down drains,
sewers or watercourses. Waste must be disposed of in accordance with federal, state and local environmental control
regulations. This material, when properly mixed and cured with its resin component at the proper mix ratio, may be
safely landfilled.
Contaminated packaging: Empty containers can only be disposed of when the remaining product adhering to the
container walls has been removed. Hazard warning labels should be removed from the container only after it has
been properly emptied.
14.0 TRANSPORT INFORMATION
14.1 UN number: Not Regulated
Page 5 of 5 Revision Date: 06/10/2013
14.2 UN proper shipping name: Liquid Plastic, NOI
14.3 Transport hazard class(es): Not Regulated
14.4 Packing group, if applicable: Not Regulated
14.5 Environmental hazards: N/A
14.6 Transport in bulk: N/A
14.7 Special precautions for user: N/A
15.0 REGULATORY INFORMATION
15.1 Safety, health and environmental regulations:
Toxic Substances Control Act (TSCA): All components are included in the EPA Toxic Substances Control Act
(TSCA) Chemical Substance Inventory.
Toxic Substance Control Act (TSCA) 12(b) Component(s): None
OSHA Hazard Communication Standard (29CFR1910.1200) hazard class(es): Irritant. Sensitizer.
EPA SARA Title III Section 312 (40CFR370) hazard class: Immediate Health Hazard. Delayed Health Hazard.
EPA SARA Title III Section 313 (40CFR372) toxic chemicals above “de minimis” level are: None
CALIFORNIA PROPOSITION 65: Warning This product contains the following chemical(s) listed by the State
of California under The Safe Drinking Water and Toxic Enforcement Act of 1986, as being know t cause cancer,
birth defects or other reproductive harm. None Known
CANADA REGULATIONS
DSL: Components of this product have been reported to Environment Canada in accordance with subsection 25
of the Canadian Environmental Protection Act and are included on the Domestic Substances List.
WHMIS Hazard Classification: Class D Division 2B
Hazardous Products Act Information: This product contains the following ingredients which are Controlled
Products and/or on the Ingredient Disclosure List (Canadian HPA section 13 and 14):
POLYMER OF EPICHLOROHYDRIN PHENOL -FORMALDEHYDE NOVOLAC, CAS #28064 -14-4 , 23% (w/w)
WHMIS Trade Secret Registry Number(s): This product has been classified in accordance with the hazard criteria
of the CPR and the MSDS contains all the information required by the CPR. None
WHMIS SYMBOLS
16.0 OTHER INFORMATION
16.1 Date of Preparation: 06/10/2013
To the best of our knowledge, the information contained herein is accurate. Final determination of the suitability of any material
is the sole responsibility of the users. All materials may present unknown hazards and should be used with caution. Although
certain hazards are described herein, we cannot guarantee that these are the only hazards which exist.
Page 1 of 6 Revision Date: 04/22/2013
SAFETY DATA SHEET
1.0 IDENTIFICATION
1.1 GHS product identifier: EL-336 Hardener
1.2 Other means of identification: Amine Adduct
1.3 Recommended use of the chemical and restrictions on use: N/A
1.4 Supplier’s details: CASS POLYMERS OF MICHIGAN, INC.
815 WEST SHEPHERD STREET
CHARLOTTE MI 48813 USA
INFORMATION PHONE NUMBER: (248) 588-2270
1.5 Emergency phone number: (703) 527-3887(Call Collect)
2.0 HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture:
Acute Toxicity Inhalation 4, Acute Toxicity Dermal 4, Skin Corrosion/Irritant 1B, Carcinogenicity 2, Eye
Damage/Irritation 1
2.2 GHS label elements:
Signal Word: Warning
Hazard Statement: Harmful if inhaled
Prevention: Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-
ventilated area.
Response: If inhaled: remove victim to fresh air and keep at rest in a position comfortable for
breathing. Call a poison center or doctor/physician if you feel unwell.
Signal Word: Warning
Hazard Statement: Harmful in contact with skin
Prevention: Wear protective gloves/protective clothing.
Response: If on skin: wash with plenty of soap and water. Call a poison center or
doctor/physician if you feel unwell. Immediate, continued and thorough washing in flowing water
for at least 30 minutes is imperative while removing contaminated clothing. Prompt medical
consultation is essential. Wash contaminated clothing before reuse.
Disposal: Dispose of contents/container by incineration under controlled conditions in accordance
with all local and national laws and regulations.
Signal Word: Danger
Hazard Statement: Causes severe skin burns and eye damage
Prevention: Do not breathe dusts or mists. Wash hands thoroughly after handling. Wear
protective gloves/protective clothing/eye protection/face protection.
Response: If swallowed: Rinse mouth. Do NOT induce vomiting. If on skin (or hair):
Remove/take off immediately all contaminated clothing. Rinse skin with water/shower.
Immediate, continued and thorough washing in flowing water for at least 30 minutes is imperative
while removing contaminated clothing. Prompt medical consultation is essential. Wash
contaminated clothing before reuse. If inhaled: Remove victim to fresh air and keep at rest in a
position comfortable for breathing. Immediately call a poison center or doctor/physician. If in
eye: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
Storage: Store locked up.
Disposal: Dispose of contents/container by incineration under controlled conditions in accordance
with all local and national laws and regulations.
Signal Word: Warning
Hazard Statement: Suspected of causing cancer.
Prevention: Obtain special instructions before use. Do not handle until all safety precautions
have been read and understood. Use personal protective equipment as required.
Response: If exposed or concerned: Get medical advice/attention.
Storage: Store locked up.
Disposal: Dispose of contents/container by incineration under controlled conditions in accordance
with all local and national laws and regulations.
Page 2 of 6 Revision Date: 04/22/2013
Signal Word: Danger
Hazard Statement: Causes serious eye damage
Prevention: Wear eye protection/face protection.
Response: If in eyes: rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Immediately call a poison center or doctor/physician.
2.3 Other hazards which do not result in classification: Flammable Liquid
2.4 Hazards Material Information System (United States):
Health 3
Flammability 1
Physical Hazard 0
Hazard Codes: 0=Chronic Hazard 0=Minimal Hazard, 1=Slight Hazard, 2=Moderate Hazard, 3=Serious Hazard,
4=Severe Hazard
3.0 COMPOSITION/INFORMATION ON INGREDIENTS
3.1 Mixtures
Chemical Identity CAS No. Concentration
Reaction Product of Bisphenol-A and Epichlorhydrin 25068-38-6 5% – 10%
1,3-Benzenedimethaneamine 1477-55-0 10% – 15%
Trimethylhexanediamine 25620-58-0 1%
1-Methylimidazole 616-47-7 5% – 10%
Triethylenetetramine 112-24-3 20% – 25%
Reaction Product of Epichlorhydrin, Phenol-Formaldehyde Novalac 28064-14-4 10% – 15%
1,2-Cyclohexanediamine 694-83-7 30% – 35%
2-Ethyl-4-Methyl-1H-Imidazole 931-36-2 1% – 2%
4.0 FIRST-AID MEASURES
4.1 Description of necessary first-aid measures:
***Never give fluids or induce vomiting if patient is unconscious or is having convulsions.***
Inhalation: Move effected persons to fresh air; if effects occur, consult a physician.
Skin Contact: Immediate, continued and thorough washing in flowing water for at least 30 minutes is imperative
while removing contaminated clothing. Prompt medical consultation is essential. Wash clothing before reuse.
Destroy contaminated leather items.
Eye Contact: Wash immediately and continuously with flowing water for at least 30 minutes. Remove contact
lenses after the first 5 minutes and continue washing. Obtain prompt medical consultation, preferably from an
ophthalmologist.
Ingestion: Do not induce vomiting. Give one glass (ca. 2.5 dL) of water or milk if available and transport to
medical facility. Do not give anything by mouth to an unconscious person.
Note to Physician: Due to irritant properties, swallowing may result in burns/ulceration of mouth, stomach and
lower gastrointestinal tract with subsequent stricture. Aspiration of vomitus may cause lung injury. Suggest
endotracheal/esophageal control if lavage is done. If burn is present, treat as any thermal burn, after
decontamination. No specific antidote. Treatment of exposure should be directed at the control of symptoms and the
clinical condition of the patient.
4.2 Most Important symptoms/effects, acute and delayed:
Potential Acute Health Effects:
Eyes: Very hazardous in case of eye contact (irritant, corrosive). Inflammation of the eye is characterized by
redness, watering and itching. Exposure of the eyes to amine vapors may produce a temporary and reversible hazing
or blurring of vision. Symptoms disappear soon after exposure is terminated.
Respiratory: Vapors produced though handling of this material in its uncured state may cause irritation of the eyes,
nose, throat or other mucous membranes. Maintain adequate local exhaust or wear adequate personal protective
equipment. Processing of cured materials may produce harmful and/or irritating dusts. Use of local exhaust and or
dust/vapor respirators is recommended.
Skin: Hazardous in case of skin contact (corrosive). Skin contact may produce burns.
Potential Chronic Health Effects:
Respiratory: Repeated inhalation of vapors may cause lung damage. Provide appropriate ventilation to maintain
exposures below occupational limits. Use of a filtering respirator rated for use with amines/ammonia is
recommended where local ventilation is not adequate. See section 8-EXPOSURE CONTROLS/PERSONAL
PROTECTION for exposure limits and recommended protective equipment. See section 11-TOXICOLOGICAL
INFORMATION for further information.
Page 3 of 6 Revision Date: 04/22/2013
Skin: Repeated skin contact may cause a persistent irritation or dermatitis. Repeated or prolonged exposure may
aggravate existing dermatitis (skin contact). Overexposure to vapor, dust, or mist may aggravate existing respiratory
conditions such as asthma, bronchitis, and inflammatory or fibrotic respiratory disease.
4.3 Indication of immediate medical attention and special treatment needed, if necessary: N/A
5.0 FIRE-FIGHTING MEASURES
5.1 Suitable extinguishing media:
Water fog or fine spray. Carbon dioxide. Alcohol resistant foam. Dry chemical fire extinguishers.
5.2 Specific hazards arising from the chemical:
Flash point is 105 C (225 F). Combustion products may include and are not limited to: Nitrogen oxides, carbon
dioxide, carbon monoxide.
5.3 Special protective actions for fire-fighters:
Wear positive-pressure self-contained breathing apparatus and protective firefighting clothing (includes firefighting
helmet, coat, trousers, boots and gloves.)
6.0 ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures:
Wear adequate personal protective equipment; see Section 8, EXPOSURE CONTROLS/PERSONAL
PROTECTION.
6.2 Methods and materials for containment and clean up:
Large spills: Contain with dike. Pump into suitable and properly labeled containers.
Small spills: Dilute with water and recover or use non-combustible absorbent material/sand and shovel into
appropriate containers. Neutralize residues with a dilute solution of acetic acid.
7.0 HANDLING AND STORAGE
7.1 Precautions for safe handling:
Keep container dry. Do not ingest. Do not breathe gas/fumes/dust/spray/dust. If ingested, seek medical advice
immediately and show the container, label or this document. Avoid contact with skin and eyes.
7.2 Conditions for safe storage, including any incompatibilities:
Store under nitrogen blanket for maximum shelf life. Product should not come in contact with copper or copper-
bearing alloys. Storage Temperature and Shelf Life: Store between 10 C and 27 C for maximum shelf life.
8.0 EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 Control parameters
No data available.
8.2 Appropriate engineering controls:
Good general ventilation should be sufficient for most conditions. Local exhaust ventilation may be necessary for
operations involving machining of dry or cured material.
8.3 Individual protection measures, such as personal protective equipment:
Respiratory Protection: For use of this material in its uncured state, no respiratory protection should be needed
with use of adequate local exhaust, however, if handling at elevated temperatures or without sufficient ventilation,
use of an approved air-purifying or supplied air respirator is recommended. Use a CE approved air-purifying
respirator with cartridge/filter for Amines or Ammonia
Skin Protection: Use protective clothing chemically resistant to this material. Selection of specific items such as
face shield, gloves, boots, apron, or full body suit will depend on operation. Safety shower should be located in
immediate work area. Remove contaminated clothing immediately, wash skin area with soap and water, and launder
clothing before reuse or dispose of properly. Items which cannot be decontaminated, such as shoes, belts and
watchbands, should be removed and disposed of properly.
Hand protection: Use chemical resistant gloves classified under standard EN 374: Protective gloves against
chemicals and microorganisms.
Notice: The selection of a specific glove for a particular application and duration of use in a workplace should also
take into account all requisite workplace factors such as, but not limited to: Other chemicals which may be handled,
physical requirements (cut/puncture protection, dexterity, thermal protection), as well as the
instructions/specifications provided by the glove supplier.
Eye/Face Protection: Eye wash fountain should be located in immediate work area. Use chemical goggles. A full-
face shield and vapor respirator is recommended for operations involving spraying or other operations placing this
material under pressurized conditions.
9.0 PHYSICAL AND CHEMICAL PROPERTIES
9.1 Appearance (physical state, color, etc.): Mobile Liquid, Amber
9.2 Odor: Amine Odor
Page 4 of 6 Revision Date: 04/22/2013
9.3 Odor threshold: N/A
9.4 pH: Basic
9.5 Melting point/freezing point: Not Determined
9.6 Initial boiling point and boiling range: Not Determined
9.7 Flash Point: 105 C (225 F)
9.8 Evaporation rate: N/A
9.9 Flammability (solid, gas): N/A
9.10 Upper/lower flammability or explosive limits: N/A
9.11 Vapor pressure: Not Determined
9.12 Vapor Density: N/A
9.13 Relative density(Specific Gravity): 1.0 1.1
9.14 Solubility(ies): Slightly Soluble in Water
9.15 Partition coefficient; n-octanol/water: N/A
9.16 Auto-ignition temperature: >300 C
9.17 Decomposition temperature: N/A
9.18 Viscosity: N/A
9.19 % Volatile (VOC): 0g/L
10.0 STABILITY AND REACTIVITY
10.1 Reactivity: N/A
10.2 Chemical stability: Stable under normal handling and storage conditions, see Section 7,Handling and Storage.
10.3 Possibility of hazardous reactions: N/A
10.4 Conditions to avoid: N/A
10.5 Incompatible materials: Acrylates. Aldehydes. Ketones. Halogenated organic compounds. Oxidizing agents. Acids.
Copper and its alloys (Brass, Bronze, etc.) Mixture with these materials will result in a temperature and/or pressure
increase.
10.6 Hazardous decomposition products: N/A
11.0 TOXICOLOGICAL INFORMATION
11.1 Likely routes of exposure: N/A
11.2 Symptoms related to the physical, chemical and toxicological characteristics:
Ingestion: Ingestion may cause gastrointestinal irritation or ulceration. Ingestion may cause burns of mouth and
throat. Aspiration into the lungs may occur during ingestion or vomiting, causing tissue damage or lung injury.
Skin Contact: Prolonged or widespread skin contact may result in absorption of harmful amounts.
Irritation:
Skin: Brief contact may cause severe skin burns. Symptoms may include pain, severe local redness and tissue
damage. Skin contact has caused allergic skin reactions in certain sensitized individuals.
Eyes: May cause pain disproportionate to the level of irritation to eye tissues. May cause severe irritation with
corneal injury which may result in permanent impairment of vision, even blindness. Chemical burns may occur.
Inhalation: May cause allergic respiratory response. Excessive exposure may cause irritation to upper respiratory
tract (nose and throat).
11.3 Delayed and immediate effects and also chronic effects from short and long term exposure:
Carcinogen: This product contains no materials that are reported as known or suspect carcinogens in levels above
0.1%.
Mutagen: This product contains no materials that are reported as known or suspect mutagens in levels above 0.1%.
Reproductive Hazard: This product contains no materials that are known or suspected of causing a reproductive
hazard in levels above 0.1%.
11.4 Numerical measures of toxicity:
This finished product has not been tested to determine individual toxicological/ecological limits. Individual
components of this mixture have been independently tested by the raw material manufacturers and any known results
have been presented below. The results for the individual components may not be representative of the toxicity of
this finished product.
Ingredient Name CAS No. % Test Result Route Species
Trimethylhexanediamine 25620-58-0 1% LD50 910 mg/kg Oral Rat
Triethylenetetramine 112-24-3 20% – 25% LD50 805 mg/kg Dermal Rabbit
1,2-Diaminocyclohexane 694-83-7 30% – 35% LD50 4,556 mg/kg Oral Rat
Page 5 of 6 Revision Date: 04/22/2013
12.0 ECOLOGICAL INFORMATION
12.1 Ecotoxicity:
Component CAS No. % Test Result Species
Methylimidazole, 1- 616-47-7 5% – 10% LC50, 96 hour 100 220 mg/L Golden Orfe
Individual components of this mixture have been independently tested by the raw material suppliers and any known
results have been presented above. The results for the individual components may not be representative of the
ecological toxicity of this finished product. This finished product has not been tested to determine individual
toxicological/ecological limits Great Caution should be taken to prevent release to the environment. See Section 13
for further information.
12.2 Persistence and degradability:
N/A
12.3 Bioaccumulative potential: N/A
12.4 Mobility in soil: N/A
12.5 Other adverse effects: N/A
13.0 DISPOSAL CONSIDERATIONS
13.1 Disposal methods:
Preferred method of disposal includes incineration under controlled conditions in accordance with all local and
national laws and regulations. The generation of waste should be avoided or minimized wherever possible.
Untreated material is not suitable for disposal. Waste, even small quantities, should never be poured down drains,
sewers or watercourses. Waste must be disposed of in accordance with federal, state and local environmental control
regulations. This material, when properly mixed and cured with its resin component at the proper mix ratio, may be
safely landfilled.
Contaminated packaging: Empty containers can only be disposed of when the remaining product adhering to the
container walls has been removed. Hazard warning labels should be removed from the container only after it has
been properly emptied.
14.0 TRANSPORT INFORMATION
14.1 UN number: UN-2735
14.2 UN proper shipping name: Amines, Liquid, Corrosive, NOS (Meta-xylenediamine, Cycloaliphatic Amine)
14.3 Transport hazard class(es): 8
14.4 Packing group, if applicable: II
14.5 Environmental hazards: N/A
14.6 Transport in bulk: N/A
14.7 Special precautions for user: N/A
15.0 REGULATORY INFORMATION
15.1 Safety, health and environmental regulations:
TSCA: This product is manufactured in compliance with all provisions of the Toxic Substances Control
Act, 15 U.S.C. 2601 et. seq. This product contains a chemical substance that is subject to export notification under
Section 12(b) of the Toxic Substances Control Act, 15 U.S.C. 2601 et. seq.
Toxic Substances Control Act (TSCA) 12(b) Components: None Known
OSHA Hazard Communication Standard (29CFR1910.1200) hazard class(es): Corrosive, Toxic by Skin
Absorption, Dangerous for the Environment.
EPA SARA Title III section 302 (40CFR370) Hazard Class: Immediate Health Hazard, Delayed Health Hazard
EPA SARA Title III section 313 (40 CFR 372) Toxic Chemicals above de minimus levels: None
California Proposition 65: Warning- This product contains the following chemical(s) listed by the State of
California under The Safe Drinking Water and Toxic Enforcement Act 1986, as being known to cause cancer, birth
defects or other reproductive harm. None Known
CANADA REGULATIONS
WHMIS Classification: D2A – respiratory tract sensitizer, D2B – skin sensitizer, E – corrosive to metal or skin
WHMIS Symbol(s):
Page 6 of 6 Revision Date: 04/22/2013
DSL: Components of this product have been reported to Environment Canada in accordance with subsection 25 of
the Canadian Environmental Protection Act and are included on the Domestic Substances List.
Hazardous Products Act Information: This product contains the following ingredients which are Controlled
Products and/or on the Ingredient Disclosure List (Canadian HPA section 13 and 14)
16.0 OTHER INFORMATION
16.1 Date of Preparation: 04/22/2013
To the best of our knowledge, the information contained herein is accurate. Final determination of the suitability of any material
is the sole responsibility of the users. All materials may present unknown hazards and should be used with caution. Although
certain hazards are described herein, we cannot guarantee that these are the only hazards which exist.
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49.1.7
1 Identification
Product identifier
Trade name: EL336 Hardener
Article number:I501389-1
Application of the substance / the mixtureEpoxy curing agent
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
ehs-us@axson.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
* 2 Hazard(s) identification
Classification of the substance or mixture
GHS08 Health hazard
Carc. 2 H351 Suspected of causing cancer.
GHS05 Corrosion
Skin Corr. 1B H314 Causes severe skin burns and eye damage.
Eye Dam. 1 H318 Causes serious eye damage.
GHS07
Skin Sens. 1 H317 May cause an allergic skin reaction.
Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
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49.1.7
Hazard pictograms
GHS05GHS07GHS08
Signal wordDanger
Hazard-determining components of labeling:
cyclohex-1,2-ylenediamine
3,6-diazaoctanethylenediamin
m-phenylenebis(methylamine)
1-methylimidazole
1,6-Hexanediamine, 2,2,4 (or 2,4,4)-trimethyl-
(R)-p-mentha-1,8-diene
Hazard statements
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Suspected of causing cancer.
Harmful to aquatic life with long lasting effects.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Do not breathe dusts or mists.
Wear protective gloves/protective clothing/eye protection/face protection.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment (see on this label).
Wash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
3
1
0
Health = 3
Fire = 1
Reactivity = 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
*3
1
0
Health = *3
Fire = 1
Reactivity = 0
(Contd. on page 3)
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49.1.7
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
* 3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 694-83-7
EINECS: 211-776-7
cyclohex-1,2-ylenediamine 20-50%
CAS: 112-24-3
EINECS: 203-950-6
3,6-diazaoctanethylenediamin 20-<25%
CAS: 1477-55-0
EINECS: 216-032-5
m-phenylenebis(methylamine) 10-20%
CAS: 616-47-7
EINECS: 210-484-7
1-methylimidazole 5-10%
CAS: 931-36-2
EINECS: 213-234-5
2-ethyl-4-methylimidazole 1-5%
CAS: 25513-64-8
EINECS: 247-134-8
1,6-Hexanediamine, 2,2,4 (or 2,4,4)-trimethyl- 0.1-<1%
CAS: 822-36-6
EINECS: 212-497-3
4-methylimidazole 0.1-1%
CAS: 5989-27-5
EINECS: 227-813-5
(R)-p-mentha-1,8-diene 0.1-<0.25%
4 First-aid measures
Description of first aid measures
General information:Immediately remove any clothing soiled by the product.
After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing:Drink copious amounts of water and provide fresh air. Immediately call a doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
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49.1.7
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:Use fire fighting measures that suit the environment.
Special hazards arising from the substance or mixture
During heating or in case of fire poisonous gases are produced.
Advice for firefighters
Protective equipment:
Mouth respiratory protective device.
Wear self-contained respiratory protective device.
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
* 6 Accidental release measures
Personal precautions, protective equipment and emergency procedures
Mount respiratory protective device.
Wear protective equipment. Keep unprotected persons away.
Environmental precautions:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Use neutralizing agent.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
694-83-7 cyclohex-1,2-ylenediamine 2.1 mg/m
112-24-3 3,6-diazaoctanethylenediamin 3 ppm
616-47-7 1-methylimidazole 2.3 mg/m
822-36-6 4-methylimidazole 10 mg/m
5989-27-5 (R)-p-mentha-1,8-diene 15 ppm
(Contd. on page 5)
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49.1.7
PAC-2:
694-83-7 cyclohex-1,2-ylenediamine 23 mg/m
112-24-3 3,6-diazaoctanethylenediamin 14 ppm
616-47-7 1-methylimidazole 25 mg/m
822-36-6 4-methylimidazole 110 mg/m
5989-27-5 (R)-p-mentha-1,8-diene 67 ppm
PAC-3:
694-83-7 cyclohex-1,2-ylenediamine 140 mg/m
112-24-3 3,6-diazaoctanethylenediamin 83 ppm
616-47-7 1-methylimidazole 150 mg/m
822-36-6 4-methylimidazole 150 mg/m
5989-27-5 (R)-p-mentha-1,8-diene 170 ppm
* 7 Handling and storage
Handling:
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Prevent formation of aerosols.
Information about protection against explosions and fires:Keep respiratory protective device available.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:Keep receptacle tightly sealed.
Specific end use(s)No further relevant information available.
* 8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
The following constituent is the only constituent of the product which has a PEL, TLV or other recommended
exposure limit.
At this time, the other constituents have no known exposure limits.
112-24-3 3,6-diazaoctanethylenediamin
WEEL Long-term value: 6 mg/m , 1 ppm
Skin
(Contd. on page 6) US
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49.1.7
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Tightly sealed goggles
* 9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Color: Light yellow
Odor: Amine-like
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49.1.7
Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range:Undetermined.
Boiling point/Boiling range:188 C (370.4 F)
Flash point: 105 C (221 F)
Flammability (solid, gaseous):Not applicable.
Ignition temperature: 335 C (635 F)
Decomposition temperature: Not determined.
Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: Not determined.
Upper: Not determined.
Vapor pressure: Not determined.
Density at 20 C (68 F): 0.99 g/cm (8.26 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Solvent content:
Organic solvents: 0.1-0.2 %
VOC content: 0.06-0.18 %
1.7 g/l / 0.01 lb/gal
Solids content: 2 %
Other information No further relevant information available.
10 Stability and reactivity
ReactivityNo further relevant information available.
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49.1.7
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:Carbon monoxide and carbon dioxide
* 11 Toxicological information
Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
112-24-3 3,6-diazaoctanethylenediamin
Oral LD50 2,000 mg/kg (rat)
Dermal LD50 2,000 mg/kg (rabbit)
1477-55-0 m-phenylenebis(methylamine)
Oral LD50 1,040 mg/kg (rat)
Dermal LD50 2,000 mg/kg (rabbit)
Inhalative LC50/4 h 2.4 mg/l (rat)
616-47-7 1-methylimidazole
Oral LD50 1,400 mg/kg (mouse)
5989-27-5 (R)-p-mentha-1,8-diene
Oral LD50 4,400 mg/kg (rat)
Primary irritant effect:
on the skin:Caustic effect on skin and mucous membranes.
on the eye:
Strong caustic effect.
Strong irritant with the danger of severe eye injury.
Sensitization:Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Corrosive
Irritant
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus
and stomach.
Carcinogenic categories
IARC (International Agency for Research on Cancer)
822-36-6 4-methylimidazole 2B
5989-27-5 (R)-p-mentha-1,8-diene 3
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49.1.7
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
12 Ecological information
Toxicity
Aquatic toxicity:
1477-55-0 m-phenylenebis(methylamine)
72 or 96 hr ErC50 12 mg/l (Chaetogammarus marinus)
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Ecotoxical effects:
Remark:Harmful to fish
Additional ecological information:
General notes:
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Must not reach bodies of water or drainage ditch undiluted or unneutralized.
Danger to drinking water if even small quantities leak into the ground.
Harmful to aquatic organisms
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
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49.1.7
14 Transport information
UN-Number
DOT, IMDG, IATA UN3267
UN proper shipping name
DOT Corrosive liquid, basic, organic, n.o.s. (Triethylenetetramine, m-
phenylenebis(methylamine))
IMDG, IATA C O R R O S I V E L I Q U I D , B A S I C , O R G A N I C , N . O . S .
(TRIETHYLENETETRAMINE, m-phenylenebis(methylamine))
Transport hazard class(es)
DOT
Class 8 Corrosive substances
Label 8
IMDG, IATA
Class 8 Corrosive substances
Label 8
Packing group
DOT, IMDG, IATA II
Environmental hazards:
Marine pollutant: No
Special precautions for user Warning: Corrosive substances
Danger code (Kemler): 80
EMS Number: F-A,S-B
Segregation groups Alkalis
Stowage Category B
Stowage Code SW2 Clear of living quarters.
Segregation Code SG35 Stow "separated from" SGG1-acids
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
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Transport/Additional information:
DOT
Quantity limitations On passenger aircraft/rail: 1 L
On cargo aircraft only: 30 L
IMDG
Limited quantities (LQ) 1L
Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 500 ml
UN "Model Regulation": UN 3267 CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S.
( T R I E T H Y L E N E T E T R A M I N E , M -
PHENYLENEBIS(METHYLAMINE)), 8, II
* 15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
Hazardous Air Pollutants
None of the ingredients is listed.
Proposition 65
Chemicals known to cause cancer:
822-36-6 4-methylimidazole
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
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49.1.7
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Carcinogenic categories
EPA (Environmental Protection Agency)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS05GHS07GHS08
Signal wordDanger
Hazard-determining components of labeling:
cyclohex-1,2-ylenediamine
3,6-diazaoctanethylenediamin
m-phenylenebis(methylamine)
1-methylimidazole
1,6-Hexanediamine, 2,2,4 (or 2,4,4)-trimethyl-
(R)-p-mentha-1,8-diene
Hazard statements
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Suspected of causing cancer.
Harmful to aquatic life with long lasting effects.
Precautionary statements
Do not breathe dusts or mists.
Wear protective gloves/protective clothing/eye protection/face protection.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment (see on this label).
Wash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
(Contd. on page 13)
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Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision10/08/2019 / 6
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Skin Corr. 1B: Skin corrosion/irritation Category 1B
Eye Dam. 1: Serious eye damage/eye irritation Category 1
Skin Sens. 1: Skin sensitisation Category 1
Carc. 2: Carcinogenicity Category 2
Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard Category 3
* Data compared to the previous version altered.
US
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INDEX
80EL336B
80EL336B-5
80EL336B-D
80EL336H-G
Page 1 of 6 Revision Date: 04/22/2013
SAFETY DATA SHEET
1.0 IDENTIFICATION
1.1 GHS product identifier: EL-336 Hardener
1.2 Other means of identification: Amine Adduct
1.3 Recommended use of the chemical and restrictions on use: N/A
1.4 Supplier’s details: CASS POLYMERS OF MICHIGAN, INC.
815 WEST SHEPHERD STREET
CHARLOTTE MI 48813 USA
INFORMATION PHONE NUMBER: (248) 588-2270
1.5 Emergency phone number: (703) 527-3887(Call Collect)
2.0 HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture:
Acute Toxicity Inhalation 4, Acute Toxicity Dermal 4, Skin Corrosion/Irritant 1B, Carcinogenicity 2, Eye
Damage/Irritation 1
2.2 GHS label elements:
Signal Word: Warning
Hazard Statement: Harmful if inhaled
Prevention: Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-
ventilated area.
Response: If inhaled: remove victim to fresh air and keep at rest in a position comfortable for
breathing. Call a poison center or doctor/physician if you feel unwell.
Signal Word: Warning
Hazard Statement: Harmful in contact with skin
Prevention: Wear protective gloves/protective clothing.
Response: If on skin: wash with plenty of soap and water. Call a poison center or
doctor/physician if you feel unwell. Immediate, continued and thorough washing in flowing water
for at least 30 minutes is imperative while removing contaminated clothing. Prompt medical
consultation is essential. Wash contaminated clothing before reuse.
Disposal: Dispose of contents/container by incineration under controlled conditions in accordance
with all local and national laws and regulations.
Signal Word: Danger
Hazard Statement: Causes severe skin burns and eye damage
Prevention: Do not breathe dusts or mists. Wash hands thoroughly after handling. Wear
protective gloves/protective clothing/eye protection/face protection.
Response: If swallowed: Rinse mouth. Do NOT induce vomiting. If on skin (or hair):
Remove/take off immediately all contaminated clothing. Rinse skin with water/shower.
Immediate, continued and thorough washing in flowing water for at least 30 minutes is imperative
while removing contaminated clothing. Prompt medical consultation is essential. Wash
contaminated clothing before reuse. If inhaled: Remove victim to fresh air and keep at rest in a
position comfortable for breathing. Immediately call a poison center or doctor/physician. If in
eye: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
Storage: Store locked up.
Disposal: Dispose of contents/container by incineration under controlled conditions in accordance
with all local and national laws and regulations.
Signal Word: Warning
Hazard Statement: Suspected of causing cancer.
Prevention: Obtain special instructions before use. Do not handle until all safety precautions
have been read and understood. Use personal protective equipment as required.
Response: If exposed or concerned: Get medical advice/attention.
Storage: Store locked up.
Disposal: Dispose of contents/container by incineration under controlled conditions in accordance
with all local and national laws and regulations.
Page 2 of 6 Revision Date: 04/22/2013
Signal Word: Danger
Hazard Statement: Causes serious eye damage
Prevention: Wear eye protection/face protection.
Response: If in eyes: rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Immediately call a poison center or doctor/physician.
2.3 Other hazards which do not result in classification: Flammable Liquid
2.4 Hazards Material Information System (United States):
Health 3
Flammability 1
Physical Hazard 0
Hazard Codes: 0=Chronic Hazard 0=Minimal Hazard, 1=Slight Hazard, 2=Moderate Hazard, 3=Serious Hazard,
4=Severe Hazard
3.0 COMPOSITION/INFORMATION ON INGREDIENTS
3.1 Mixtures
Chemical Identity CAS No. Concentration
Reaction Product of Bisphenol-A and Epichlorhydrin 25068-38-6 5% – 10%
1,3-Benzenedimethaneamine 1477-55-0 10% – 15%
Trimethylhexanediamine 25620-58-0 1%
1-Methylimidazole 616-47-7 5% – 10%
Triethylenetetramine 112-24-3 20% – 25%
Reaction Product of Epichlorhydrin, Phenol-Formaldehyde Novalac 28064-14-4 10% – 15%
1,2-Cyclohexanediamine 694-83-7 30% – 35%
2-Ethyl-4-Methyl-1H-Imidazole 931-36-2 1% – 2%
4.0 FIRST-AID MEASURES
4.1 Description of necessary first-aid measures:
***Never give fluids or induce vomiting if patient is unconscious or is having convulsions.***
Inhalation: Move effected persons to fresh air; if effects occur, consult a physician.
Skin Contact: Immediate, continued and thorough washing in flowing water for at least 30 minutes is imperative
while removing contaminated clothing. Prompt medical consultation is essential. Wash clothing before reuse.
Destroy contaminated leather items.
Eye Contact: Wash immediately and continuously with flowing water for at least 30 minutes. Remove contact
lenses after the first 5 minutes and continue washing. Obtain prompt medical consultation, preferably from an
ophthalmologist.
Ingestion: Do not induce vomiting. Give one glass (ca. 2.5 dL) of water or milk if available and transport to
medical facility. Do not give anything by mouth to an unconscious person.
Note to Physician: Due to irritant properties, swallowing may result in burns/ulceration of mouth, stomach and
lower gastrointestinal tract with subsequent stricture. Aspiration of vomitus may cause lung injury. Suggest
endotracheal/esophageal control if lavage is done. If burn is present, treat as any thermal burn, after
decontamination. No specific antidote. Treatment of exposure should be directed at the control of symptoms and the
clinical condition of the patient.
4.2 Most Important symptoms/effects, acute and delayed:
Potential Acute Health Effects:
Eyes: Very hazardous in case of eye contact (irritant, corrosive). Inflammation of the eye is characterized by
redness, watering and itching. Exposure of the eyes to amine vapors may produce a temporary and reversible hazing
or blurring of vision. Symptoms disappear soon after exposure is terminated.
Respiratory: Vapors produced though handling of this material in its uncured state may cause irritation of the eyes,
nose, throat or other mucous membranes. Maintain adequate local exhaust or wear adequate personal protective
equipment. Processing of cured materials may produce harmful and/or irritating dusts. Use of local exhaust and or
dust/vapor respirators is recommended.
Skin: Hazardous in case of skin contact (corrosive). Skin contact may produce burns.
Potential Chronic Health Effects:
Respiratory: Repeated inhalation of vapors may cause lung damage. Provide appropriate ventilation to maintain
exposures below occupational limits. Use of a filtering respirator rated for use with amines/ammonia is
recommended where local ventilation is not adequate. See section 8-EXPOSURE CONTROLS/PERSONAL
PROTECTION for exposure limits and recommended protective equipment. See section 11-TOXICOLOGICAL
INFORMATION for further information.
Page 3 of 6 Revision Date: 04/22/2013
Skin: Repeated skin contact may cause a persistent irritation or dermatitis. Repeated or prolonged exposure may
aggravate existing dermatitis (skin contact). Overexposure to vapor, dust, or mist may aggravate existing respiratory
conditions such as asthma, bronchitis, and inflammatory or fibrotic respiratory disease.
4.3 Indication of immediate medical attention and special treatment needed, if necessary: N/A
5.0 FIRE-FIGHTING MEASURES
5.1 Suitable extinguishing media:
Water fog or fine spray. Carbon dioxide. Alcohol resistant foam. Dry chemical fire extinguishers.
5.2 Specific hazards arising from the chemical:
Flash point is 105 C (225 F). Combustion products may include and are not limited to: Nitrogen oxides, carbon
dioxide, carbon monoxide.
5.3 Special protective actions for fire-fighters:
Wear positive-pressure self-contained breathing apparatus and protective firefighting clothing (includes firefighting
helmet, coat, trousers, boots and gloves.)
6.0 ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures:
Wear adequate personal protective equipment; see Section 8, EXPOSURE CONTROLS/PERSONAL
PROTECTION.
6.2 Methods and materials for containment and clean up:
Large spills: Contain with dike. Pump into suitable and properly labeled containers.
Small spills: Dilute with water and recover or use non-combustible absorbent material/sand and shovel into
appropriate containers. Neutralize residues with a dilute solution of acetic acid.
7.0 HANDLING AND STORAGE
7.1 Precautions for safe handling:
Keep container dry. Do not ingest. Do not breathe gas/fumes/dust/spray/dust. If ingested, seek medical advice
immediately and show the container, label or this document. Avoid contact with skin and eyes.
7.2 Conditions for safe storage, including any incompatibilities:
Store under nitrogen blanket for maximum shelf life. Product should not come in contact with copper or copper-
bearing alloys. Storage Temperature and Shelf Life: Store between 10 C and 27 C for maximum shelf life.
8.0 EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 Control parameters
No data available.
8.2 Appropriate engineering controls:
Good general ventilation should be sufficient for most conditions. Local exhaust ventilation may be necessary for
operations involving machining of dry or cured material.
8.3 Individual protection measures, such as personal protective equipment:
Respiratory Protection: For use of this material in its uncured state, no respiratory protection should be needed
with use of adequate local exhaust, however, if handling at elevated temperatures or without sufficient ventilation,
use of an approved air-purifying or supplied air respirator is recommended. Use a CE approved air-purifying
respirator with cartridge/filter for Amines or Ammonia
Skin Protection: Use protective clothing chemically resistant to this material. Selection of specific items such as
face shield, gloves, boots, apron, or full body suit will depend on operation. Safety shower should be located in
immediate work area. Remove contaminated clothing immediately, wash skin area with soap and water, and launder
clothing before reuse or dispose of properly. Items which cannot be decontaminated, such as shoes, belts and
watchbands, should be removed and disposed of properly.
Hand protection: Use chemical resistant gloves classified under standard EN 374: Protective gloves against
chemicals and microorganisms.
Notice: The selection of a specific glove for a particular application and duration of use in a workplace should also
take into account all requisite workplace factors such as, but not limited to: Other chemicals which may be handled,
physical requirements (cut/puncture protection, dexterity, thermal protection), as well as the
instructions/specifications provided by the glove supplier.
Eye/Face Protection: Eye wash fountain should be located in immediate work area. Use chemical goggles. A full-
face shield and vapor respirator is recommended for operations involving spraying or other operations placing this
material under pressurized conditions.
9.0 PHYSICAL AND CHEMICAL PROPERTIES
9.1 Appearance (physical state, color, etc.): Mobile Liquid, Amber
9.2 Odor: Amine Odor
Page 4 of 6 Revision Date: 04/22/2013
9.3 Odor threshold: N/A
9.4 pH: Basic
9.5 Melting point/freezing point: Not Determined
9.6 Initial boiling point and boiling range: Not Determined
9.7 Flash Point: 105 C (225 F)
9.8 Evaporation rate: N/A
9.9 Flammability (solid, gas): N/A
9.10 Upper/lower flammability or explosive limits: N/A
9.11 Vapor pressure: Not Determined
9.12 Vapor Density: N/A
9.13 Relative density(Specific Gravity): 1.0 1.1
9.14 Solubility(ies): Slightly Soluble in Water
9.15 Partition coefficient; n-octanol/water: N/A
9.16 Auto-ignition temperature: >300 C
9.17 Decomposition temperature: N/A
9.18 Viscosity: N/A
9.19 % Volatile (VOC): 0g/L
10.0 STABILITY AND REACTIVITY
10.1 Reactivity: N/A
10.2 Chemical stability: Stable under normal handling and storage conditions, see Section 7,Handling and Storage.
10.3 Possibility of hazardous reactions: N/A
10.4 Conditions to avoid: N/A
10.5 Incompatible materials: Acrylates. Aldehydes. Ketones. Halogenated organic compounds. Oxidizing agents. Acids.
Copper and its alloys (Brass, Bronze, etc.) Mixture with these materials will result in a temperature and/or pressure
increase.
10.6 Hazardous decomposition products: N/A
11.0 TOXICOLOGICAL INFORMATION
11.1 Likely routes of exposure: N/A
11.2 Symptoms related to the physical, chemical and toxicological characteristics:
Ingestion: Ingestion may cause gastrointestinal irritation or ulceration. Ingestion may cause burns of mouth and
throat. Aspiration into the lungs may occur during ingestion or vomiting, causing tissue damage or lung injury.
Skin Contact: Prolonged or widespread skin contact may result in absorption of harmful amounts.
Irritation:
Skin: Brief contact may cause severe skin burns. Symptoms may include pain, severe local redness and tissue
damage. Skin contact has caused allergic skin reactions in certain sensitized individuals.
Eyes: May cause pain disproportionate to the level of irritation to eye tissues. May cause severe irritation with
corneal injury which may result in permanent impairment of vision, even blindness. Chemical burns may occur.
Inhalation: May cause allergic respiratory response. Excessive exposure may cause irritation to upper respiratory
tract (nose and throat).
11.3 Delayed and immediate effects and also chronic effects from short and long term exposure:
Carcinogen: This product contains no materials that are reported as known or suspect carcinogens in levels above
0.1%.
Mutagen: This product contains no materials that are reported as known or suspect mutagens in levels above 0.1%.
Reproductive Hazard: This product contains no materials that are known or suspected of causing a reproductive
hazard in levels above 0.1%.
11.4 Numerical measures of toxicity:
This finished product has not been tested to determine individual toxicological/ecological limits. Individual
components of this mixture have been independently tested by the raw material manufacturers and any known results
have been presented below. The results for the individual components may not be representative of the toxicity of
this finished product.
Ingredient Name CAS No. % Test Result Route Species
Trimethylhexanediamine 25620-58-0 1% LD50 910 mg/kg Oral Rat
Triethylenetetramine 112-24-3 20% – 25% LD50 805 mg/kg Dermal Rabbit
1,2-Diaminocyclohexane 694-83-7 30% – 35% LD50 4,556 mg/kg Oral Rat
Page 5 of 6 Revision Date: 04/22/2013
12.0 ECOLOGICAL INFORMATION
12.1 Ecotoxicity:
Component CAS No. % Test Result Species
Methylimidazole, 1- 616-47-7 5% – 10% LC50, 96 hour 100 220 mg/L Golden Orfe
Individual components of this mixture have been independently tested by the raw material suppliers and any known
results have been presented above. The results for the individual components may not be representative of the
ecological toxicity of this finished product. This finished product has not been tested to determine individual
toxicological/ecological limits Great Caution should be taken to prevent release to the environment. See Section 13
for further information.
12.2 Persistence and degradability:
N/A
12.3 Bioaccumulative potential: N/A
12.4 Mobility in soil: N/A
12.5 Other adverse effects: N/A
13.0 DISPOSAL CONSIDERATIONS
13.1 Disposal methods:
Preferred method of disposal includes incineration under controlled conditions in accordance with all local and
national laws and regulations. The generation of waste should be avoided or minimized wherever possible.
Untreated material is not suitable for disposal. Waste, even small quantities, should never be poured down drains,
sewers or watercourses. Waste must be disposed of in accordance with federal, state and local environmental control
regulations. This material, when properly mixed and cured with its resin component at the proper mix ratio, may be
safely landfilled.
Contaminated packaging: Empty containers can only be disposed of when the remaining product adhering to the
container walls has been removed. Hazard warning labels should be removed from the container only after it has
been properly emptied.
14.0 TRANSPORT INFORMATION
14.1 UN number: UN-2735
14.2 UN proper shipping name: Amines, Liquid, Corrosive, NOS (Meta-xylenediamine, Cycloaliphatic Amine)
14.3 Transport hazard class(es): 8
14.4 Packing group, if applicable: II
14.5 Environmental hazards: N/A
14.6 Transport in bulk: N/A
14.7 Special precautions for user: N/A
15.0 REGULATORY INFORMATION
15.1 Safety, health and environmental regulations:
TSCA: This product is manufactured in compliance with all provisions of the Toxic Substances Control
Act, 15 U.S.C. 2601 et. seq. This product contains a chemical substance that is subject to export notification under
Section 12(b) of the Toxic Substances Control Act, 15 U.S.C. 2601 et. seq.
Toxic Substances Control Act (TSCA) 12(b) Components: None Known
OSHA Hazard Communication Standard (29CFR1910.1200) hazard class(es): Corrosive, Toxic by Skin
Absorption, Dangerous for the Environment.
EPA SARA Title III section 302 (40CFR370) Hazard Class: Immediate Health Hazard, Delayed Health Hazard
EPA SARA Title III section 313 (40 CFR 372) Toxic Chemicals above de minimus levels: None
California Proposition 65: Warning- This product contains the following chemical(s) listed by the State of
California under The Safe Drinking Water and Toxic Enforcement Act 1986, as being known to cause cancer, birth
defects or other reproductive harm. None Known
CANADA REGULATIONS
WHMIS Classification: D2A – respiratory tract sensitizer, D2B – skin sensitizer, E – corrosive to metal or skin
WHMIS Symbol(s):
Page 6 of 6 Revision Date: 04/22/2013
DSL: Components of this product have been reported to Environment Canada in accordance with subsection 25 of
the Canadian Environmental Protection Act and are included on the Domestic Substances List.
Hazardous Products Act Information: This product contains the following ingredients which are Controlled
Products and/or on the Ingredient Disclosure List (Canadian HPA section 13 and 14)
16.0 OTHER INFORMATION
16.1 Date of Preparation: 04/22/2013
To the best of our knowledge, the information contained herein is accurate. Final determination of the suitability of any material
is the sole responsibility of the users. All materials may present unknown hazards and should be used with caution. Although
certain hazards are described herein, we cannot guarantee that these are the only hazards which exist.
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49.1.7
1 Identification
Product identifier
Trade name: EL336 Hardener
Article number:I501389-1
Application of the substance / the mixtureEpoxy curing agent
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
ehs-us@axson.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
* 2 Hazard(s) identification
Classification of the substance or mixture
GHS08 Health hazard
Carc. 2 H351 Suspected of causing cancer.
GHS05 Corrosion
Skin Corr. 1B H314 Causes severe skin burns and eye damage.
Eye Dam. 1 H318 Causes serious eye damage.
GHS07
Skin Sens. 1 H317 May cause an allergic skin reaction.
Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
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49.1.7
Hazard pictograms
GHS05GHS07GHS08
Signal wordDanger
Hazard-determining components of labeling:
cyclohex-1,2-ylenediamine
3,6-diazaoctanethylenediamin
m-phenylenebis(methylamine)
1-methylimidazole
1,6-Hexanediamine, 2,2,4 (or 2,4,4)-trimethyl-
(R)-p-mentha-1,8-diene
Hazard statements
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Suspected of causing cancer.
Harmful to aquatic life with long lasting effects.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Do not breathe dusts or mists.
Wear protective gloves/protective clothing/eye protection/face protection.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment (see on this label).
Wash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
3
1
0
Health = 3
Fire = 1
Reactivity = 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
*3
1
0
Health = *3
Fire = 1
Reactivity = 0
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49.1.7
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
* 3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 694-83-7
EINECS: 211-776-7
cyclohex-1,2-ylenediamine 20-50%
CAS: 112-24-3
EINECS: 203-950-6
3,6-diazaoctanethylenediamin 20-<25%
CAS: 1477-55-0
EINECS: 216-032-5
m-phenylenebis(methylamine) 10-20%
CAS: 616-47-7
EINECS: 210-484-7
1-methylimidazole 5-10%
CAS: 931-36-2
EINECS: 213-234-5
2-ethyl-4-methylimidazole 1-5%
CAS: 25513-64-8
EINECS: 247-134-8
1,6-Hexanediamine, 2,2,4 (or 2,4,4)-trimethyl- 0.1-<1%
CAS: 822-36-6
EINECS: 212-497-3
4-methylimidazole 0.1-1%
CAS: 5989-27-5
EINECS: 227-813-5
(R)-p-mentha-1,8-diene 0.1-<0.25%
4 First-aid measures
Description of first aid measures
General information:Immediately remove any clothing soiled by the product.
After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing:Drink copious amounts of water and provide fresh air. Immediately call a doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
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49.1.7
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:Use fire fighting measures that suit the environment.
Special hazards arising from the substance or mixture
During heating or in case of fire poisonous gases are produced.
Advice for firefighters
Protective equipment:
Mouth respiratory protective device.
Wear self-contained respiratory protective device.
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
* 6 Accidental release measures
Personal precautions, protective equipment and emergency procedures
Mount respiratory protective device.
Wear protective equipment. Keep unprotected persons away.
Environmental precautions:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Use neutralizing agent.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
694-83-7 cyclohex-1,2-ylenediamine 2.1 mg/m
112-24-3 3,6-diazaoctanethylenediamin 3 ppm
616-47-7 1-methylimidazole 2.3 mg/m
822-36-6 4-methylimidazole 10 mg/m
5989-27-5 (R)-p-mentha-1,8-diene 15 ppm
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49.1.7
PAC-2:
694-83-7 cyclohex-1,2-ylenediamine 23 mg/m
112-24-3 3,6-diazaoctanethylenediamin 14 ppm
616-47-7 1-methylimidazole 25 mg/m
822-36-6 4-methylimidazole 110 mg/m
5989-27-5 (R)-p-mentha-1,8-diene 67 ppm
PAC-3:
694-83-7 cyclohex-1,2-ylenediamine 140 mg/m
112-24-3 3,6-diazaoctanethylenediamin 83 ppm
616-47-7 1-methylimidazole 150 mg/m
822-36-6 4-methylimidazole 150 mg/m
5989-27-5 (R)-p-mentha-1,8-diene 170 ppm
* 7 Handling and storage
Handling:
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Prevent formation of aerosols.
Information about protection against explosions and fires:Keep respiratory protective device available.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:Keep receptacle tightly sealed.
Specific end use(s)No further relevant information available.
* 8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
The following constituent is the only constituent of the product which has a PEL, TLV or other recommended
exposure limit.
At this time, the other constituents have no known exposure limits.
112-24-3 3,6-diazaoctanethylenediamin
WEEL Long-term value: 6 mg/m , 1 ppm
Skin
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49.1.7
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Tightly sealed goggles
* 9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Color: Light yellow
Odor: Amine-like
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Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range:Undetermined.
Boiling point/Boiling range:188 C (370.4 F)
Flash point: 105 C (221 F)
Flammability (solid, gaseous):Not applicable.
Ignition temperature: 335 C (635 F)
Decomposition temperature: Not determined.
Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: Not determined.
Upper: Not determined.
Vapor pressure: Not determined.
Density at 20 C (68 F): 0.99 g/cm (8.26 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Solvent content:
Organic solvents: 0.1-0.2 %
VOC content: 0.06-0.18 %
1.7 g/l / 0.01 lb/gal
Solids content: 2 %
Other information No further relevant information available.
10 Stability and reactivity
ReactivityNo further relevant information available.
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Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:Carbon monoxide and carbon dioxide
* 11 Toxicological information
Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
112-24-3 3,6-diazaoctanethylenediamin
Oral LD50 2,000 mg/kg (rat)
Dermal LD50 2,000 mg/kg (rabbit)
1477-55-0 m-phenylenebis(methylamine)
Oral LD50 1,040 mg/kg (rat)
Dermal LD50 2,000 mg/kg (rabbit)
Inhalative LC50/4 h 2.4 mg/l (rat)
616-47-7 1-methylimidazole
Oral LD50 1,400 mg/kg (mouse)
5989-27-5 (R)-p-mentha-1,8-diene
Oral LD50 4,400 mg/kg (rat)
Primary irritant effect:
on the skin:Caustic effect on skin and mucous membranes.
on the eye:
Strong caustic effect.
Strong irritant with the danger of severe eye injury.
Sensitization:Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Corrosive
Irritant
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus
and stomach.
Carcinogenic categories
IARC (International Agency for Research on Cancer)
822-36-6 4-methylimidazole 2B
5989-27-5 (R)-p-mentha-1,8-diene 3
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49.1.7
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
12 Ecological information
Toxicity
Aquatic toxicity:
1477-55-0 m-phenylenebis(methylamine)
72 or 96 hr ErC50 12 mg/l (Chaetogammarus marinus)
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Ecotoxical effects:
Remark:Harmful to fish
Additional ecological information:
General notes:
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Must not reach bodies of water or drainage ditch undiluted or unneutralized.
Danger to drinking water if even small quantities leak into the ground.
Harmful to aquatic organisms
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
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(Contd. on page 10)
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Trade name: EL336 Hardener
(Contd. of page 9)
49.1.7
14 Transport information
UN-Number
DOT, IMDG, IATA UN3267
UN proper shipping name
DOT Corrosive liquid, basic, organic, n.o.s. (Triethylenetetramine, m-
phenylenebis(methylamine))
IMDG, IATA C O R R O S I V E L I Q U I D , B A S I C , O R G A N I C , N . O . S .
(TRIETHYLENETETRAMINE, m-phenylenebis(methylamine))
Transport hazard class(es)
DOT
Class 8 Corrosive substances
Label 8
IMDG, IATA
Class 8 Corrosive substances
Label 8
Packing group
DOT, IMDG, IATA II
Environmental hazards:
Marine pollutant: No
Special precautions for user Warning: Corrosive substances
Danger code (Kemler): 80
EMS Number: F-A,S-B
Segregation groups Alkalis
Stowage Category B
Stowage Code SW2 Clear of living quarters.
Segregation Code SG35 Stow "separated from" SGG1-acids
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
(Contd. on page 11)
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(Contd. of page 10)
49.1.7
Transport/Additional information:
DOT
Quantity limitations On passenger aircraft/rail: 1 L
On cargo aircraft only: 30 L
IMDG
Limited quantities (LQ) 1L
Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 500 ml
UN "Model Regulation": UN 3267 CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S.
( T R I E T H Y L E N E T E T R A M I N E , M -
PHENYLENEBIS(METHYLAMINE)), 8, II
* 15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
Hazardous Air Pollutants
None of the ingredients is listed.
Proposition 65
Chemicals known to cause cancer:
822-36-6 4-methylimidazole
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
(Contd. on page 12)
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Trade name: EL336 Hardener
(Contd. of page 11)
49.1.7
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Carcinogenic categories
EPA (Environmental Protection Agency)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS05GHS07GHS08
Signal wordDanger
Hazard-determining components of labeling:
cyclohex-1,2-ylenediamine
3,6-diazaoctanethylenediamin
m-phenylenebis(methylamine)
1-methylimidazole
1,6-Hexanediamine, 2,2,4 (or 2,4,4)-trimethyl-
(R)-p-mentha-1,8-diene
Hazard statements
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Suspected of causing cancer.
Harmful to aquatic life with long lasting effects.
Precautionary statements
Do not breathe dusts or mists.
Wear protective gloves/protective clothing/eye protection/face protection.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment (see on this label).
Wash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
(Contd. on page 13)
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Trade name: EL336 Hardener
(Contd. of page 12)
49.1.7
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision10/08/2019 / 6
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Skin Corr. 1B: Skin corrosion/irritation Category 1B
Eye Dam. 1: Serious eye damage/eye irritation Category 1
Skin Sens. 1: Skin sensitisation Category 1
Carc. 2: Carcinogenicity Category 2
Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard Category 3
* Data compared to the previous version altered.
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