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Safety Data Sheet
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Printing date 10/08/2019 Reviewed on 10/08/2019
49.1.7
1 Identification
Product identifier
Trade name: EL336 Hardener
Article number:I501389-1
Application of the substance / the mixtureEpoxy curing agent
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
ehs-us@axson.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
* 2 Hazard(s) identification
Classification of the substance or mixture
GHS08 Health hazard
Carc. 2 H351 Suspected of causing cancer.
GHS05 Corrosion
Skin Corr. 1B H314 Causes severe skin burns and eye damage.
Eye Dam. 1 H318 Causes serious eye damage.
GHS07
Skin Sens. 1 H317 May cause an allergic skin reaction.
Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
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49.1.7
Hazard pictograms
GHS05GHS07GHS08
Signal wordDanger
Hazard-determining components of labeling:
cyclohex-1,2-ylenediamine
3,6-diazaoctanethylenediamin
m-phenylenebis(methylamine)
1-methylimidazole
1,6-Hexanediamine, 2,2,4 (or 2,4,4)-trimethyl-
(R)-p-mentha-1,8-diene
Hazard statements
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Suspected of causing cancer.
Harmful to aquatic life with long lasting effects.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Do not breathe dusts or mists.
Wear protective gloves/protective clothing/eye protection/face protection.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment (see on this label).
Wash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
3
1
0
Health = 3
Fire = 1
Reactivity = 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
*3
1
0
Health = *3
Fire = 1
Reactivity = 0
(Contd. on page 3)
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49.1.7
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
* 3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 694-83-7
EINECS: 211-776-7
cyclohex-1,2-ylenediamine 20-50%
CAS: 112-24-3
EINECS: 203-950-6
3,6-diazaoctanethylenediamin 20-<25%
CAS: 1477-55-0
EINECS: 216-032-5
m-phenylenebis(methylamine) 10-20%
CAS: 616-47-7
EINECS: 210-484-7
1-methylimidazole 5-10%
CAS: 931-36-2
EINECS: 213-234-5
2-ethyl-4-methylimidazole 1-5%
CAS: 25513-64-8
EINECS: 247-134-8
1,6-Hexanediamine, 2,2,4 (or 2,4,4)-trimethyl- 0.1-<1%
CAS: 822-36-6
EINECS: 212-497-3
4-methylimidazole 0.1-1%
CAS: 5989-27-5
EINECS: 227-813-5
(R)-p-mentha-1,8-diene 0.1-<0.25%
4 First-aid measures
Description of first aid measures
General information:Immediately remove any clothing soiled by the product.
After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing:Drink copious amounts of water and provide fresh air. Immediately call a doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
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49.1.7
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:Use fire fighting measures that suit the environment.
Special hazards arising from the substance or mixture
During heating or in case of fire poisonous gases are produced.
Advice for firefighters
Protective equipment:
Mouth respiratory protective device.
Wear self-contained respiratory protective device.
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
* 6 Accidental release measures
Personal precautions, protective equipment and emergency procedures
Mount respiratory protective device.
Wear protective equipment. Keep unprotected persons away.
Environmental precautions:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Use neutralizing agent.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
694-83-7 cyclohex-1,2-ylenediamine 2.1 mg/m
112-24-3 3,6-diazaoctanethylenediamin 3 ppm
616-47-7 1-methylimidazole 2.3 mg/m
822-36-6 4-methylimidazole 10 mg/m
5989-27-5 (R)-p-mentha-1,8-diene 15 ppm
(Contd. on page 5)
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49.1.7
PAC-2:
694-83-7 cyclohex-1,2-ylenediamine 23 mg/m
112-24-3 3,6-diazaoctanethylenediamin 14 ppm
616-47-7 1-methylimidazole 25 mg/m
822-36-6 4-methylimidazole 110 mg/m
5989-27-5 (R)-p-mentha-1,8-diene 67 ppm
PAC-3:
694-83-7 cyclohex-1,2-ylenediamine 140 mg/m
112-24-3 3,6-diazaoctanethylenediamin 83 ppm
616-47-7 1-methylimidazole 150 mg/m
822-36-6 4-methylimidazole 150 mg/m
5989-27-5 (R)-p-mentha-1,8-diene 170 ppm
* 7 Handling and storage
Handling:
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Prevent formation of aerosols.
Information about protection against explosions and fires:Keep respiratory protective device available.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:Keep receptacle tightly sealed.
Specific end use(s)No further relevant information available.
* 8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
The following constituent is the only constituent of the product which has a PEL, TLV or other recommended
exposure limit.
At this time, the other constituents have no known exposure limits.
112-24-3 3,6-diazaoctanethylenediamin
WEEL Long-term value: 6 mg/m , 1 ppm
Skin
(Contd. on page 6) US
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49.1.7
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Tightly sealed goggles
* 9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Color: Light yellow
Odor: Amine-like
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49.1.7
Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range:Undetermined.
Boiling point/Boiling range:188 C (370.4 F)
Flash point: 105 C (221 F)
Flammability (solid, gaseous):Not applicable.
Ignition temperature: 335 C (635 F)
Decomposition temperature: Not determined.
Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: Not determined.
Upper: Not determined.
Vapor pressure: Not determined.
Density at 20 C (68 F): 0.99 g/cm (8.26 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Solvent content:
Organic solvents: 0.1-0.2 %
VOC content: 0.06-0.18 %
1.7 g/l / 0.01 lb/gal
Solids content: 2 %
Other information No further relevant information available.
10 Stability and reactivity
ReactivityNo further relevant information available.
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49.1.7
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:Carbon monoxide and carbon dioxide
* 11 Toxicological information
Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
112-24-3 3,6-diazaoctanethylenediamin
Oral LD50 2,000 mg/kg (rat)
Dermal LD50 2,000 mg/kg (rabbit)
1477-55-0 m-phenylenebis(methylamine)
Oral LD50 1,040 mg/kg (rat)
Dermal LD50 2,000 mg/kg (rabbit)
Inhalative LC50/4 h 2.4 mg/l (rat)
616-47-7 1-methylimidazole
Oral LD50 1,400 mg/kg (mouse)
5989-27-5 (R)-p-mentha-1,8-diene
Oral LD50 4,400 mg/kg (rat)
Primary irritant effect:
on the skin:Caustic effect on skin and mucous membranes.
on the eye:
Strong caustic effect.
Strong irritant with the danger of severe eye injury.
Sensitization:Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Corrosive
Irritant
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus
and stomach.
Carcinogenic categories
IARC (International Agency for Research on Cancer)
822-36-6 4-methylimidazole 2B
5989-27-5 (R)-p-mentha-1,8-diene 3
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49.1.7
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
12 Ecological information
Toxicity
Aquatic toxicity:
1477-55-0 m-phenylenebis(methylamine)
72 or 96 hr ErC50 12 mg/l (Chaetogammarus marinus)
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Ecotoxical effects:
Remark:Harmful to fish
Additional ecological information:
General notes:
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Must not reach bodies of water or drainage ditch undiluted or unneutralized.
Danger to drinking water if even small quantities leak into the ground.
Harmful to aquatic organisms
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
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49.1.7
14 Transport information
UN-Number
DOT, IMDG, IATA UN3267
UN proper shipping name
DOT Corrosive liquid, basic, organic, n.o.s. (Triethylenetetramine, m-
phenylenebis(methylamine))
IMDG, IATA C O R R O S I V E L I Q U I D , B A S I C , O R G A N I C , N . O . S .
(TRIETHYLENETETRAMINE, m-phenylenebis(methylamine))
Transport hazard class(es)
DOT
Class 8 Corrosive substances
Label 8
IMDG, IATA
Class 8 Corrosive substances
Label 8
Packing group
DOT, IMDG, IATA II
Environmental hazards:
Marine pollutant: No
Special precautions for user Warning: Corrosive substances
Danger code (Kemler): 80
EMS Number: F-A,S-B
Segregation groups Alkalis
Stowage Category B
Stowage Code SW2 Clear of living quarters.
Segregation Code SG35 Stow "separated from" SGG1-acids
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
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49.1.7
Transport/Additional information:
DOT
Quantity limitations On passenger aircraft/rail: 1 L
On cargo aircraft only: 30 L
IMDG
Limited quantities (LQ) 1L
Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 500 ml
UN "Model Regulation": UN 3267 CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S.
( T R I E T H Y L E N E T E T R A M I N E , M -
PHENYLENEBIS(METHYLAMINE)), 8, II
* 15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
Hazardous Air Pollutants
None of the ingredients is listed.
Proposition 65
Chemicals known to cause cancer:
822-36-6 4-methylimidazole
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
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49.1.7
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Carcinogenic categories
EPA (Environmental Protection Agency)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS05GHS07GHS08
Signal wordDanger
Hazard-determining components of labeling:
cyclohex-1,2-ylenediamine
3,6-diazaoctanethylenediamin
m-phenylenebis(methylamine)
1-methylimidazole
1,6-Hexanediamine, 2,2,4 (or 2,4,4)-trimethyl-
(R)-p-mentha-1,8-diene
Hazard statements
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Suspected of causing cancer.
Harmful to aquatic life with long lasting effects.
Precautionary statements
Do not breathe dusts or mists.
Wear protective gloves/protective clothing/eye protection/face protection.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment (see on this label).
Wash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
(Contd. on page 13)
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49.1.7
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision10/08/2019 / 6
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Skin Corr. 1B: Skin corrosion/irritation Category 1B
Eye Dam. 1: Serious eye damage/eye irritation Category 1
Skin Sens. 1: Skin sensitisation Category 1
Carc. 2: Carcinogenicity Category 2
Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard Category 3
* Data compared to the previous version altered.
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INDEX
80EL336B
80EL336B-5
80EL336B-D
80EL336H-G
Page 1 of 6 Revision Date: 04/22/2013
SAFETY DATA SHEET
1.0 IDENTIFICATION
1.1 GHS product identifier: EL-336 Hardener
1.2 Other means of identification: Amine Adduct
1.3 Recommended use of the chemical and restrictions on use: N/A
1.4 Supplier’s details: CASS POLYMERS OF MICHIGAN, INC.
815 WEST SHEPHERD STREET
CHARLOTTE MI 48813 USA
INFORMATION PHONE NUMBER: (248) 588-2270
1.5 Emergency phone number: (703) 527-3887(Call Collect)
2.0 HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture:
Acute Toxicity Inhalation 4, Acute Toxicity Dermal 4, Skin Corrosion/Irritant 1B, Carcinogenicity 2, Eye
Damage/Irritation 1
2.2 GHS label elements:
Signal Word: Warning
Hazard Statement: Harmful if inhaled
Prevention: Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-
ventilated area.
Response: If inhaled: remove victim to fresh air and keep at rest in a position comfortable for
breathing. Call a poison center or doctor/physician if you feel unwell.
Signal Word: Warning
Hazard Statement: Harmful in contact with skin
Prevention: Wear protective gloves/protective clothing.
Response: If on skin: wash with plenty of soap and water. Call a poison center or
doctor/physician if you feel unwell. Immediate, continued and thorough washing in flowing water
for at least 30 minutes is imperative while removing contaminated clothing. Prompt medical
consultation is essential. Wash contaminated clothing before reuse.
Disposal: Dispose of contents/container by incineration under controlled conditions in accordance
with all local and national laws and regulations.
Signal Word: Danger
Hazard Statement: Causes severe skin burns and eye damage
Prevention: Do not breathe dusts or mists. Wash hands thoroughly after handling. Wear
protective gloves/protective clothing/eye protection/face protection.
Response: If swallowed: Rinse mouth. Do NOT induce vomiting. If on skin (or hair):
Remove/take off immediately all contaminated clothing. Rinse skin with water/shower.
Immediate, continued and thorough washing in flowing water for at least 30 minutes is imperative
while removing contaminated clothing. Prompt medical consultation is essential. Wash
contaminated clothing before reuse. If inhaled: Remove victim to fresh air and keep at rest in a
position comfortable for breathing. Immediately call a poison center or doctor/physician. If in
eye: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
Storage: Store locked up.
Disposal: Dispose of contents/container by incineration under controlled conditions in accordance
with all local and national laws and regulations.
Signal Word: Warning
Hazard Statement: Suspected of causing cancer.
Prevention: Obtain special instructions before use. Do not handle until all safety precautions
have been read and understood. Use personal protective equipment as required.
Response: If exposed or concerned: Get medical advice/attention.
Storage: Store locked up.
Disposal: Dispose of contents/container by incineration under controlled conditions in accordance
with all local and national laws and regulations.
Page 2 of 6 Revision Date: 04/22/2013
Signal Word: Danger
Hazard Statement: Causes serious eye damage
Prevention: Wear eye protection/face protection.
Response: If in eyes: rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Immediately call a poison center or doctor/physician.
2.3 Other hazards which do not result in classification: Flammable Liquid
2.4 Hazards Material Information System (United States):
Health 3
Flammability 1
Physical Hazard 0
Hazard Codes: 0=Chronic Hazard 0=Minimal Hazard, 1=Slight Hazard, 2=Moderate Hazard, 3=Serious Hazard,
4=Severe Hazard
3.0 COMPOSITION/INFORMATION ON INGREDIENTS
3.1 Mixtures
Chemical Identity CAS No. Concentration
Reaction Product of Bisphenol-A and Epichlorhydrin 25068-38-6 5% – 10%
1,3-Benzenedimethaneamine 1477-55-0 10% – 15%
Trimethylhexanediamine 25620-58-0 1%
1-Methylimidazole 616-47-7 5% – 10%
Triethylenetetramine 112-24-3 20% – 25%
Reaction Product of Epichlorhydrin, Phenol-Formaldehyde Novalac 28064-14-4 10% – 15%
1,2-Cyclohexanediamine 694-83-7 30% – 35%
2-Ethyl-4-Methyl-1H-Imidazole 931-36-2 1% – 2%
4.0 FIRST-AID MEASURES
4.1 Description of necessary first-aid measures:
***Never give fluids or induce vomiting if patient is unconscious or is having convulsions.***
Inhalation: Move effected persons to fresh air; if effects occur, consult a physician.
Skin Contact: Immediate, continued and thorough washing in flowing water for at least 30 minutes is imperative
while removing contaminated clothing. Prompt medical consultation is essential. Wash clothing before reuse.
Destroy contaminated leather items.
Eye Contact: Wash immediately and continuously with flowing water for at least 30 minutes. Remove contact
lenses after the first 5 minutes and continue washing. Obtain prompt medical consultation, preferably from an
ophthalmologist.
Ingestion: Do not induce vomiting. Give one glass (ca. 2.5 dL) of water or milk if available and transport to
medical facility. Do not give anything by mouth to an unconscious person.
Note to Physician: Due to irritant properties, swallowing may result in burns/ulceration of mouth, stomach and
lower gastrointestinal tract with subsequent stricture. Aspiration of vomitus may cause lung injury. Suggest
endotracheal/esophageal control if lavage is done. If burn is present, treat as any thermal burn, after
decontamination. No specific antidote. Treatment of exposure should be directed at the control of symptoms and the
clinical condition of the patient.
4.2 Most Important symptoms/effects, acute and delayed:
Potential Acute Health Effects:
Eyes: Very hazardous in case of eye contact (irritant, corrosive). Inflammation of the eye is characterized by
redness, watering and itching. Exposure of the eyes to amine vapors may produce a temporary and reversible hazing
or blurring of vision. Symptoms disappear soon after exposure is terminated.
Respiratory: Vapors produced though handling of this material in its uncured state may cause irritation of the eyes,
nose, throat or other mucous membranes. Maintain adequate local exhaust or wear adequate personal protective
equipment. Processing of cured materials may produce harmful and/or irritating dusts. Use of local exhaust and or
dust/vapor respirators is recommended.
Skin: Hazardous in case of skin contact (corrosive). Skin contact may produce burns.
Potential Chronic Health Effects:
Respiratory: Repeated inhalation of vapors may cause lung damage. Provide appropriate ventilation to maintain
exposures below occupational limits. Use of a filtering respirator rated for use with amines/ammonia is
recommended where local ventilation is not adequate. See section 8-EXPOSURE CONTROLS/PERSONAL
PROTECTION for exposure limits and recommended protective equipment. See section 11-TOXICOLOGICAL
INFORMATION for further information.
Page 3 of 6 Revision Date: 04/22/2013
Skin: Repeated skin contact may cause a persistent irritation or dermatitis. Repeated or prolonged exposure may
aggravate existing dermatitis (skin contact). Overexposure to vapor, dust, or mist may aggravate existing respiratory
conditions such as asthma, bronchitis, and inflammatory or fibrotic respiratory disease.
4.3 Indication of immediate medical attention and special treatment needed, if necessary: N/A
5.0 FIRE-FIGHTING MEASURES
5.1 Suitable extinguishing media:
Water fog or fine spray. Carbon dioxide. Alcohol resistant foam. Dry chemical fire extinguishers.
5.2 Specific hazards arising from the chemical:
Flash point is 105 C (225 F). Combustion products may include and are not limited to: Nitrogen oxides, carbon
dioxide, carbon monoxide.
5.3 Special protective actions for fire-fighters:
Wear positive-pressure self-contained breathing apparatus and protective firefighting clothing (includes firefighting
helmet, coat, trousers, boots and gloves.)
6.0 ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures:
Wear adequate personal protective equipment; see Section 8, EXPOSURE CONTROLS/PERSONAL
PROTECTION.
6.2 Methods and materials for containment and clean up:
Large spills: Contain with dike. Pump into suitable and properly labeled containers.
Small spills: Dilute with water and recover or use non-combustible absorbent material/sand and shovel into
appropriate containers. Neutralize residues with a dilute solution of acetic acid.
7.0 HANDLING AND STORAGE
7.1 Precautions for safe handling:
Keep container dry. Do not ingest. Do not breathe gas/fumes/dust/spray/dust. If ingested, seek medical advice
immediately and show the container, label or this document. Avoid contact with skin and eyes.
7.2 Conditions for safe storage, including any incompatibilities:
Store under nitrogen blanket for maximum shelf life. Product should not come in contact with copper or copper-
bearing alloys. Storage Temperature and Shelf Life: Store between 10 C and 27 C for maximum shelf life.
8.0 EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 Control parameters
No data available.
8.2 Appropriate engineering controls:
Good general ventilation should be sufficient for most conditions. Local exhaust ventilation may be necessary for
operations involving machining of dry or cured material.
8.3 Individual protection measures, such as personal protective equipment:
Respiratory Protection: For use of this material in its uncured state, no respiratory protection should be needed
with use of adequate local exhaust, however, if handling at elevated temperatures or without sufficient ventilation,
use of an approved air-purifying or supplied air respirator is recommended. Use a CE approved air-purifying
respirator with cartridge/filter for Amines or Ammonia
Skin Protection: Use protective clothing chemically resistant to this material. Selection of specific items such as
face shield, gloves, boots, apron, or full body suit will depend on operation. Safety shower should be located in
immediate work area. Remove contaminated clothing immediately, wash skin area with soap and water, and launder
clothing before reuse or dispose of properly. Items which cannot be decontaminated, such as shoes, belts and
watchbands, should be removed and disposed of properly.
Hand protection: Use chemical resistant gloves classified under standard EN 374: Protective gloves against
chemicals and microorganisms.
Notice: The selection of a specific glove for a particular application and duration of use in a workplace should also
take into account all requisite workplace factors such as, but not limited to: Other chemicals which may be handled,
physical requirements (cut/puncture protection, dexterity, thermal protection), as well as the
instructions/specifications provided by the glove supplier.
Eye/Face Protection: Eye wash fountain should be located in immediate work area. Use chemical goggles. A full-
face shield and vapor respirator is recommended for operations involving spraying or other operations placing this
material under pressurized conditions.
9.0 PHYSICAL AND CHEMICAL PROPERTIES
9.1 Appearance (physical state, color, etc.): Mobile Liquid, Amber
9.2 Odor: Amine Odor
Page 4 of 6 Revision Date: 04/22/2013
9.3 Odor threshold: N/A
9.4 pH: Basic
9.5 Melting point/freezing point: Not Determined
9.6 Initial boiling point and boiling range: Not Determined
9.7 Flash Point: 105 C (225 F)
9.8 Evaporation rate: N/A
9.9 Flammability (solid, gas): N/A
9.10 Upper/lower flammability or explosive limits: N/A
9.11 Vapor pressure: Not Determined
9.12 Vapor Density: N/A
9.13 Relative density(Specific Gravity): 1.0 1.1
9.14 Solubility(ies): Slightly Soluble in Water
9.15 Partition coefficient; n-octanol/water: N/A
9.16 Auto-ignition temperature: >300 C
9.17 Decomposition temperature: N/A
9.18 Viscosity: N/A
9.19 % Volatile (VOC): 0g/L
10.0 STABILITY AND REACTIVITY
10.1 Reactivity: N/A
10.2 Chemical stability: Stable under normal handling and storage conditions, see Section 7,Handling and Storage.
10.3 Possibility of hazardous reactions: N/A
10.4 Conditions to avoid: N/A
10.5 Incompatible materials: Acrylates. Aldehydes. Ketones. Halogenated organic compounds. Oxidizing agents. Acids.
Copper and its alloys (Brass, Bronze, etc.) Mixture with these materials will result in a temperature and/or pressure
increase.
10.6 Hazardous decomposition products: N/A
11.0 TOXICOLOGICAL INFORMATION
11.1 Likely routes of exposure: N/A
11.2 Symptoms related to the physical, chemical and toxicological characteristics:
Ingestion: Ingestion may cause gastrointestinal irritation or ulceration. Ingestion may cause burns of mouth and
throat. Aspiration into the lungs may occur during ingestion or vomiting, causing tissue damage or lung injury.
Skin Contact: Prolonged or widespread skin contact may result in absorption of harmful amounts.
Irritation:
Skin: Brief contact may cause severe skin burns. Symptoms may include pain, severe local redness and tissue
damage. Skin contact has caused allergic skin reactions in certain sensitized individuals.
Eyes: May cause pain disproportionate to the level of irritation to eye tissues. May cause severe irritation with
corneal injury which may result in permanent impairment of vision, even blindness. Chemical burns may occur.
Inhalation: May cause allergic respiratory response. Excessive exposure may cause irritation to upper respiratory
tract (nose and throat).
11.3 Delayed and immediate effects and also chronic effects from short and long term exposure:
Carcinogen: This product contains no materials that are reported as known or suspect carcinogens in levels above
0.1%.
Mutagen: This product contains no materials that are reported as known or suspect mutagens in levels above 0.1%.
Reproductive Hazard: This product contains no materials that are known or suspected of causing a reproductive
hazard in levels above 0.1%.
11.4 Numerical measures of toxicity:
This finished product has not been tested to determine individual toxicological/ecological limits. Individual
components of this mixture have been independently tested by the raw material manufacturers and any known results
have been presented below. The results for the individual components may not be representative of the toxicity of
this finished product.
Ingredient Name CAS No. % Test Result Route Species
Trimethylhexanediamine 25620-58-0 1% LD50 910 mg/kg Oral Rat
Triethylenetetramine 112-24-3 20% – 25% LD50 805 mg/kg Dermal Rabbit
1,2-Diaminocyclohexane 694-83-7 30% – 35% LD50 4,556 mg/kg Oral Rat
Page 5 of 6 Revision Date: 04/22/2013
12.0 ECOLOGICAL INFORMATION
12.1 Ecotoxicity:
Component CAS No. % Test Result Species
Methylimidazole, 1- 616-47-7 5% – 10% LC50, 96 hour 100 220 mg/L Golden Orfe
Individual components of this mixture have been independently tested by the raw material suppliers and any known
results have been presented above. The results for the individual components may not be representative of the
ecological toxicity of this finished product. This finished product has not been tested to determine individual
toxicological/ecological limits Great Caution should be taken to prevent release to the environment. See Section 13
for further information.
12.2 Persistence and degradability:
N/A
12.3 Bioaccumulative potential: N/A
12.4 Mobility in soil: N/A
12.5 Other adverse effects: N/A
13.0 DISPOSAL CONSIDERATIONS
13.1 Disposal methods:
Preferred method of disposal includes incineration under controlled conditions in accordance with all local and
national laws and regulations. The generation of waste should be avoided or minimized wherever possible.
Untreated material is not suitable for disposal. Waste, even small quantities, should never be poured down drains,
sewers or watercourses. Waste must be disposed of in accordance with federal, state and local environmental control
regulations. This material, when properly mixed and cured with its resin component at the proper mix ratio, may be
safely landfilled.
Contaminated packaging: Empty containers can only be disposed of when the remaining product adhering to the
container walls has been removed. Hazard warning labels should be removed from the container only after it has
been properly emptied.
14.0 TRANSPORT INFORMATION
14.1 UN number: UN-2735
14.2 UN proper shipping name: Amines, Liquid, Corrosive, NOS (Meta-xylenediamine, Cycloaliphatic Amine)
14.3 Transport hazard class(es): 8
14.4 Packing group, if applicable: II
14.5 Environmental hazards: N/A
14.6 Transport in bulk: N/A
14.7 Special precautions for user: N/A
15.0 REGULATORY INFORMATION
15.1 Safety, health and environmental regulations:
TSCA: This product is manufactured in compliance with all provisions of the Toxic Substances Control
Act, 15 U.S.C. 2601 et. seq. This product contains a chemical substance that is subject to export notification under
Section 12(b) of the Toxic Substances Control Act, 15 U.S.C. 2601 et. seq.
Toxic Substances Control Act (TSCA) 12(b) Components: None Known
OSHA Hazard Communication Standard (29CFR1910.1200) hazard class(es): Corrosive, Toxic by Skin
Absorption, Dangerous for the Environment.
EPA SARA Title III section 302 (40CFR370) Hazard Class: Immediate Health Hazard, Delayed Health Hazard
EPA SARA Title III section 313 (40 CFR 372) Toxic Chemicals above de minimus levels: None
California Proposition 65: Warning- This product contains the following chemical(s) listed by the State of
California under The Safe Drinking Water and Toxic Enforcement Act 1986, as being known to cause cancer, birth
defects or other reproductive harm. None Known
CANADA REGULATIONS
WHMIS Classification: D2A – respiratory tract sensitizer, D2B – skin sensitizer, E – corrosive to metal or skin
WHMIS Symbol(s):
Page 6 of 6 Revision Date: 04/22/2013
DSL: Components of this product have been reported to Environment Canada in accordance with subsection 25 of
the Canadian Environmental Protection Act and are included on the Domestic Substances List.
Hazardous Products Act Information: This product contains the following ingredients which are Controlled
Products and/or on the Ingredient Disclosure List (Canadian HPA section 13 and 14)
16.0 OTHER INFORMATION
16.1 Date of Preparation: 04/22/2013
To the best of our knowledge, the information contained herein is accurate. Final determination of the suitability of any material
is the sole responsibility of the users. All materials may present unknown hazards and should be used with caution. Although
certain hazards are described herein, we cannot guarantee that these are the only hazards which exist.
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49.1.7
1 Identification
Product identifier
Trade name: EL336 Hardener
Article number:I501389-1
Application of the substance / the mixtureEpoxy curing agent
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
ehs-us@axson.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
* 2 Hazard(s) identification
Classification of the substance or mixture
GHS08 Health hazard
Carc. 2 H351 Suspected of causing cancer.
GHS05 Corrosion
Skin Corr. 1B H314 Causes severe skin burns and eye damage.
Eye Dam. 1 H318 Causes serious eye damage.
GHS07
Skin Sens. 1 H317 May cause an allergic skin reaction.
Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
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49.1.7
Hazard pictograms
GHS05GHS07GHS08
Signal wordDanger
Hazard-determining components of labeling:
cyclohex-1,2-ylenediamine
3,6-diazaoctanethylenediamin
m-phenylenebis(methylamine)
1-methylimidazole
1,6-Hexanediamine, 2,2,4 (or 2,4,4)-trimethyl-
(R)-p-mentha-1,8-diene
Hazard statements
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Suspected of causing cancer.
Harmful to aquatic life with long lasting effects.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Do not breathe dusts or mists.
Wear protective gloves/protective clothing/eye protection/face protection.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment (see on this label).
Wash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
3
1
0
Health = 3
Fire = 1
Reactivity = 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
*3
1
0
Health = *3
Fire = 1
Reactivity = 0
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49.1.7
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
* 3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 694-83-7
EINECS: 211-776-7
cyclohex-1,2-ylenediamine 20-50%
CAS: 112-24-3
EINECS: 203-950-6
3,6-diazaoctanethylenediamin 20-<25%
CAS: 1477-55-0
EINECS: 216-032-5
m-phenylenebis(methylamine) 10-20%
CAS: 616-47-7
EINECS: 210-484-7
1-methylimidazole 5-10%
CAS: 931-36-2
EINECS: 213-234-5
2-ethyl-4-methylimidazole 1-5%
CAS: 25513-64-8
EINECS: 247-134-8
1,6-Hexanediamine, 2,2,4 (or 2,4,4)-trimethyl- 0.1-<1%
CAS: 822-36-6
EINECS: 212-497-3
4-methylimidazole 0.1-1%
CAS: 5989-27-5
EINECS: 227-813-5
(R)-p-mentha-1,8-diene 0.1-<0.25%
4 First-aid measures
Description of first aid measures
General information:Immediately remove any clothing soiled by the product.
After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing:Drink copious amounts of water and provide fresh air. Immediately call a doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
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49.1.7
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:Use fire fighting measures that suit the environment.
Special hazards arising from the substance or mixture
During heating or in case of fire poisonous gases are produced.
Advice for firefighters
Protective equipment:
Mouth respiratory protective device.
Wear self-contained respiratory protective device.
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
* 6 Accidental release measures
Personal precautions, protective equipment and emergency procedures
Mount respiratory protective device.
Wear protective equipment. Keep unprotected persons away.
Environmental precautions:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Use neutralizing agent.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
694-83-7 cyclohex-1,2-ylenediamine 2.1 mg/m
112-24-3 3,6-diazaoctanethylenediamin 3 ppm
616-47-7 1-methylimidazole 2.3 mg/m
822-36-6 4-methylimidazole 10 mg/m
5989-27-5 (R)-p-mentha-1,8-diene 15 ppm
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49.1.7
PAC-2:
694-83-7 cyclohex-1,2-ylenediamine 23 mg/m
112-24-3 3,6-diazaoctanethylenediamin 14 ppm
616-47-7 1-methylimidazole 25 mg/m
822-36-6 4-methylimidazole 110 mg/m
5989-27-5 (R)-p-mentha-1,8-diene 67 ppm
PAC-3:
694-83-7 cyclohex-1,2-ylenediamine 140 mg/m
112-24-3 3,6-diazaoctanethylenediamin 83 ppm
616-47-7 1-methylimidazole 150 mg/m
822-36-6 4-methylimidazole 150 mg/m
5989-27-5 (R)-p-mentha-1,8-diene 170 ppm
* 7 Handling and storage
Handling:
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Prevent formation of aerosols.
Information about protection against explosions and fires:Keep respiratory protective device available.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:Keep receptacle tightly sealed.
Specific end use(s)No further relevant information available.
* 8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
The following constituent is the only constituent of the product which has a PEL, TLV or other recommended
exposure limit.
At this time, the other constituents have no known exposure limits.
112-24-3 3,6-diazaoctanethylenediamin
WEEL Long-term value: 6 mg/m , 1 ppm
Skin
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49.1.7
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Tightly sealed goggles
* 9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Color: Light yellow
Odor: Amine-like
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Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range:Undetermined.
Boiling point/Boiling range:188 C (370.4 F)
Flash point: 105 C (221 F)
Flammability (solid, gaseous):Not applicable.
Ignition temperature: 335 C (635 F)
Decomposition temperature: Not determined.
Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: Not determined.
Upper: Not determined.
Vapor pressure: Not determined.
Density at 20 C (68 F): 0.99 g/cm (8.26 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Solvent content:
Organic solvents: 0.1-0.2 %
VOC content: 0.06-0.18 %
1.7 g/l / 0.01 lb/gal
Solids content: 2 %
Other information No further relevant information available.
10 Stability and reactivity
ReactivityNo further relevant information available.
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Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:Carbon monoxide and carbon dioxide
* 11 Toxicological information
Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
112-24-3 3,6-diazaoctanethylenediamin
Oral LD50 2,000 mg/kg (rat)
Dermal LD50 2,000 mg/kg (rabbit)
1477-55-0 m-phenylenebis(methylamine)
Oral LD50 1,040 mg/kg (rat)
Dermal LD50 2,000 mg/kg (rabbit)
Inhalative LC50/4 h 2.4 mg/l (rat)
616-47-7 1-methylimidazole
Oral LD50 1,400 mg/kg (mouse)
5989-27-5 (R)-p-mentha-1,8-diene
Oral LD50 4,400 mg/kg (rat)
Primary irritant effect:
on the skin:Caustic effect on skin and mucous membranes.
on the eye:
Strong caustic effect.
Strong irritant with the danger of severe eye injury.
Sensitization:Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Corrosive
Irritant
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus
and stomach.
Carcinogenic categories
IARC (International Agency for Research on Cancer)
822-36-6 4-methylimidazole 2B
5989-27-5 (R)-p-mentha-1,8-diene 3
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NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
12 Ecological information
Toxicity
Aquatic toxicity:
1477-55-0 m-phenylenebis(methylamine)
72 or 96 hr ErC50 12 mg/l (Chaetogammarus marinus)
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Ecotoxical effects:
Remark:Harmful to fish
Additional ecological information:
General notes:
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Must not reach bodies of water or drainage ditch undiluted or unneutralized.
Danger to drinking water if even small quantities leak into the ground.
Harmful to aquatic organisms
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
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14 Transport information
UN-Number
DOT, IMDG, IATA UN3267
UN proper shipping name
DOT Corrosive liquid, basic, organic, n.o.s. (Triethylenetetramine, m-
phenylenebis(methylamine))
IMDG, IATA C O R R O S I V E L I Q U I D , B A S I C , O R G A N I C , N . O . S .
(TRIETHYLENETETRAMINE, m-phenylenebis(methylamine))
Transport hazard class(es)
DOT
Class 8 Corrosive substances
Label 8
IMDG, IATA
Class 8 Corrosive substances
Label 8
Packing group
DOT, IMDG, IATA II
Environmental hazards:
Marine pollutant: No
Special precautions for user Warning: Corrosive substances
Danger code (Kemler): 80
EMS Number: F-A,S-B
Segregation groups Alkalis
Stowage Category B
Stowage Code SW2 Clear of living quarters.
Segregation Code SG35 Stow "separated from" SGG1-acids
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
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Transport/Additional information:
DOT
Quantity limitations On passenger aircraft/rail: 1 L
On cargo aircraft only: 30 L
IMDG
Limited quantities (LQ) 1L
Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 500 ml
UN "Model Regulation": UN 3267 CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S.
( T R I E T H Y L E N E T E T R A M I N E , M -
PHENYLENEBIS(METHYLAMINE)), 8, II
* 15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
Hazardous Air Pollutants
None of the ingredients is listed.
Proposition 65
Chemicals known to cause cancer:
822-36-6 4-methylimidazole
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
(Contd. on page 12)
US
Page 12/13
Safety Data Sheet
acc. to OSHA HCS
Printing date 10/08/2019 Reviewed on 10/08/2019
Trade name: EL336 Hardener
(Contd. of page 11)
49.1.7
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Carcinogenic categories
EPA (Environmental Protection Agency)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS05GHS07GHS08
Signal wordDanger
Hazard-determining components of labeling:
cyclohex-1,2-ylenediamine
3,6-diazaoctanethylenediamin
m-phenylenebis(methylamine)
1-methylimidazole
1,6-Hexanediamine, 2,2,4 (or 2,4,4)-trimethyl-
(R)-p-mentha-1,8-diene
Hazard statements
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Suspected of causing cancer.
Harmful to aquatic life with long lasting effects.
Precautionary statements
Do not breathe dusts or mists.
Wear protective gloves/protective clothing/eye protection/face protection.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment (see on this label).
Wash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
(Contd. on page 13)
US
Page 13/13
Safety Data Sheet
acc. to OSHA HCS
Printing date 10/08/2019 Reviewed on 10/08/2019
Trade name: EL336 Hardener
(Contd. of page 12)
49.1.7
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision10/08/2019 / 6
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Skin Corr. 1B: Skin corrosion/irritation Category 1B
Eye Dam. 1: Serious eye damage/eye irritation Category 1
Skin Sens. 1: Skin sensitisation Category 1
Carc. 2: Carcinogenicity Category 2
Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard Category 3
* Data compared to the previous version altered.
US
by | Sep 27, 2025
by | Sep 27, 2025
by | Sep 27, 2025
by | Sep 27, 2025
by | Sep 27, 2025
by | Sep 27, 2025
by | Sep 27, 2025
Safety Data Sheet
according to OSHA 1910.1200 Hazard Communication Standard
SikaBiresin L325 HT (formerly EL-325HTTC) Part B
Revision Date 08/17/2023
Print Date 08/17/2023
1 / 12
SECTION 1. IDENTIFICATION
Product name : SikaBiresin L325 HT (formerly EL-325HTTC) Part B
Company name : Sika Corporation
201 Polito Avenue
Lyndhurst, NJ 07071
USA
www.sikausa.com
Telephone : (201) 933-8800
Telefax : (201) 804-1076
E-mail address : ehs@sika-corp.com
Emergency telephone : CHEMTREC: 800-424-9300
INTERNATIONAL: +1-703-527-3887
Recommended use of the
chemical and restrictions on
use
: For further information, refer to product data sheet.
SECTION 2. HAZARDS IDENTIFICATION
GHS classification in accordance with the OSHA Hazard Communication Standard (29 CFR
1910.1200)
Skin corrosion
: Category 1B
Serious eye damage
: Category 1
Skin sensitization
: Category 1
Reproductive toxicity
: Category 2
GHS label elements
Hazard pictograms
:
Signal Word
: Danger
Hazard Statements
: H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H361 Suspected of damaging fertility or the unborn child.
Safety Data Sheet
according to OSHA 1910.1200 Hazard Communication Standard
SikaBiresin L325 HT (formerly EL-325HTTC) Part B
Revision Date 08/17/2023
Print Date 08/17/2023
2 / 12
Precautionary Statements
:
Prevention:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read
and understood.
P261 Avoid breathing mist or vapors.
P264 Wash skin thoroughly after handling.
P272 Contaminated work clothing must not be allowed out of
the workplace.
P280 Wear protective gloves/ protective clothing/ eye protection/
face protection.
Response:
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT
induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately
all contaminated clothing. Rinse skin with water/ shower.
P304 + P340 + P310 IF INHALED: Remove person to fresh air
and keep comfortable for breathing. Immediately call a POISON
CENTER/ doctor.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON
CENTER/ doctor.
P308 + P313 IF exposed or concerned: Get medical advice/
attention.
P333 + P313 If skin irritation or rash occurs: Get medical advice/
attention.
P362 + P364 Take off contaminated clothing and wash it before
reuse.
Storage:
P405 Store locked up.
Disposal:
P501 Dispose of contents/ container to an approved waste dis-
posal plant.
Additional Labeling
There are no ingredients with unknown acute toxicity used in a mixture at a concentration >= 1%.
Other hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Mixtures
Components
Chemical name CAS-No. Classification Concentra-
tion (% w/w)
Safety Data Sheet
according to OSHA 1910.1200 Hazard Communication Standard
SikaBiresin L325 HT (formerly EL-325HTTC) Part B
Revision Date 08/17/2023
Print Date 08/17/2023
3 / 12
Adduct XA-P (epoxy amine adduct,
polymer)
110839-13-9 Acute Tox. 4; H302
Skin Sens. 1; H317
>= 10 – < 20
Isophoronediamine 2855-13-2 Acute Tox. 4; H302
Skin Corr. 1B; H314
Eye Dam. 1; H318
Skin Sens. 1A; H317
>= 5 – < 10
m-phenylenebis(methylamine) 1477-55-0 Acute Tox. 4; H302
Acute Tox. 4; H332
Skin Corr. 1B; H314
Skin Sens. 1B; H317
>= 1 – < 5
1-methylimidazole 616-47-7 Flam. Liq. 4; H227
Acute Tox. 4; H302
Acute Tox. 3; H311
Skin Corr. 1B; H314
Eye Dam. 1; H318
Repr. 2; H361
>= 1 – < 5
2,2,4(or 2,4,4)-trimethylhexane-1,6-
diamine
25513-64-8 Acute Tox. 4; H302
Skin Corr. 1A; H314
Eye Dam. 1; H318
Skin Sens. 1A; H317
>= 0.1 – < 1
Actual concentration is withheld as a trade secret
SECTION 4. FIRST AID MEASURES
General advice : Move out of dangerous area.
Consult a physician.
Show this material safety data sheet to the doctor in attend-
ance.
If inhaled : Move to fresh air.
Consult a physician after significant exposure.
In case of skin contact : Take off contaminated clothing and shoes immediately.
Wash off with soap and plenty of water.
Immediate medical treatment is necessary as untreated
wounds from corrosion of the skin heal slowly and with difficul-
ty.
In case of eye contact : Small amounts splashed into eyes can cause irreversible tis-
sue damage and blindness.
In the case of contact with eyes, rinse immediately with plenty
of water and seek medical advice.
Continue rinsing eyes during transport to hospital.
Remove contact lenses.
Keep eye wide open while rinsing.
If swallowed : Clean mouth with water and drink afterwards plenty of water.
Do not induce vomiting without medical advice.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
Take victim immediately to hospital.
Safety Data Sheet
according to OSHA 1910.1200 Hazard Communication Standard
SikaBiresin L325 HT (formerly EL-325HTTC) Part B
Revision Date 08/17/2023
Print Date 08/17/2023
4 / 12
Most important symptoms
and effects, both acute and
delayed
: Health injuries may be delayed.
corrosive effects
sensitizing effects
Allergic reactions
Dermatitis
May cause an allergic skin reaction.
Causes serious eye damage.
Suspected of damaging fertility or the unborn child.
Causes severe burns.
Notes to physician : Treat symptomatically.
SECTION 5. FIRE-FIGHTING MEASURES
Suitable extinguishing media : Use extinguishing measures that are appropriate to local cir-
cumstances and the surrounding environment.
Further information : Collect contaminated fire extinguishing water separately. This
must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
Special protective equipment
for fire-fighters
: In the event of fire, wear self-contained breathing apparatus.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protec-
tive equipment and emer-
gency procedures
: Use personal protective equipment.
Deny access to unprotected persons.
Environmental precautions
: Do not flush into surface water or sanitary sewer system.
If the product contaminates rivers and lakes or drains inform
respective authorities.
Local authorities should be advised if significant spillages
cannot be contained.
Methods and materials for
containment and cleaning up
: Soak up with inert absorbent material (e.g. sand, silica gel,
acid binder, universal binder, sawdust).
Keep in suitable, closed containers for disposal.
SECTION 7. HANDLING AND STORAGE
Advice on protection against
fire and explosion
: Normal measures for preventive fire protection.
Advice on safe handling : Avoid exceeding the given occupational exposure limits (see
section 8).
Safety Data Sheet
according to OSHA 1910.1200 Hazard Communication Standard
SikaBiresin L325 HT (formerly EL-325HTTC) Part B
Revision Date 08/17/2023
Print Date 08/17/2023
5 / 12
Do not get in eyes, on skin, or on clothing.
For personal protection see section 8.
Persons with a history of skin sensitization problems or asth-
ma, allergies, chronic or recurrent respiratory disease should
not be employed in any process in which this mixture is being
used.
Smoking, eating and drinking should be prohibited in the ap-
plication area.
Follow standard hygiene measures when handling chemical
products.
Conditions for safe storage : Store in original container.
Keep container tightly closed in a dry and well-ventilated
place.
Observe label precautions.
Store in accordance with local regulations.
Materials to avoid : Explosives
Oxidizing agents
Poisonous gases
Dangerous when wet
Flammable solids
Organic peroxides
Poisonous liquids
Spontaneously Combustible Substances
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Ingredients with workplace control parameters
Components CAS-No. Value type
(Form of
exposure)
Control parame-
ters / Permissible
concentration
Basis
m-phenylenebis(methylamine) 1477-55-0 C 0.018 ppm ACGIH
C 0.1 mg/m3 OSHA P0
The above constituents are the only constituents of the product which have a PEL, TLV or other rec-
ommended exposure limit. At this time, the other constituents have no known exposure limits.
Engineering measures : Use of adequate ventilation should be sufficient to control
worker exposure to airborne contaminants. If the use of this
product generates dust, fumes, gas, vapor or mist, use pro-
cess enclosures, local exhaust ventilation or other engineer-
ing controls to keep worker exposure below any recommend-
ed or statutory limits.
Personal protective equipment
Respiratory protection : Use a properly fitted NIOSH approved air-purifying or air-fed
respirator complying with an approved standard if a risk as-
sessment indicates this is necessary.
Safety Data Sheet
according to OSHA 1910.1200 Hazard Communication Standard
SikaBiresin L325 HT (formerly EL-325HTTC) Part B
Revision Date 08/17/2023
Print Date 08/17/2023
6 / 12
The filter class for the respirator must be suitable for the max-
imum expected contaminant concentration
(gas/vapor/aerosol/particulates) that may arise when han-
dling the product. If this concentration is exceeded, self-
contained breathing apparatus must be used.
Hand protection : Chemical-resistant, impervious gloves complying with an
approved standard should be worn at all times when handling
chemical products if a risk assessment indicates this is nec-
essary.
Eye protection : Safety eyewear complying with an approved standard should
be used when a risk assessment indicates this is necessary.
Skin and body protection : Choose body protection in relation to its type, to the concen-
tration and amount of dangerous substances, and to the spe-
cific work-place.
Hygiene measures : Avoid contact with skin, eyes and clothing.
Wash hands before breaks and immediately after handling the product.
Remove contaminated clothing and protective equipment before entering eating areas.
Wash thoroughly after handling.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : paste
Color : dark gray
Odor : amine-like
Odor Threshold : No data available
pH : Not applicable
Melting point/range / Freezing
point
: No data available
Boiling point/boiling range : No data available
Flash point : 338 F / 170 C
(Method: closed cup)
Evaporation rate : No data available
Flammability (solid, gas)
: No data available
Upper explosion limit / Upper
flammability limit
: No data available
Safety Data Sheet
according to OSHA 1910.1200 Hazard Communication Standard
SikaBiresin L325 HT (formerly EL-325HTTC) Part B
Revision Date 08/17/2023
Print Date 08/17/2023
7 / 12
Lower explosion limit / Lower
flammability limit
: No data available
Vapor pressure : 0.02 hpa
Relative vapor density : No data available
Density : 1.19 g/cm3 (68 F / 20 C)
Solubility(ies)
Water solubility : soluble
Solubility in other solvents : No data available
Partition coefficient: n-
octanol/water
: No data available
Autoignition temperature : No data available
Decomposition temperature : No data available
Viscosity
Viscosity, dynamic : No data available
Viscosity, kinematic : > 20.5 mm2/s (104 F / 40 C)
Explosive properties : No data available
Oxidizing properties : No data available
Volatile organic compounds
(VOC) content
: Not applicable
SECTION 10. STABILITY AND REACTIVITY
Reactivity : No dangerous reaction known under conditions of normal use.
Chemical stability : The product is chemically stable.
Possibility of hazardous reac-
tions
: Stable under recommended storage conditions.
Conditions to avoid : No data available
Incompatible materials : No data available
Hazardous decomposition
products
: No decomposition if stored and applied as directed.
Safety Data Sheet
according to OSHA 1910.1200 Hazard Communication Standard
SikaBiresin L325 HT (formerly EL-325HTTC) Part B
Revision Date 08/17/2023
Print Date 08/17/2023
8 / 12
SECTION 11. TOXICOLOGICAL INFORMATION
Acute toxicity
Not classified due to lack of data.
Components:
Adduct XA-P (epoxy amine adduct, polymer):
Acute oral toxicity : LD50 Oral (Rat): 300 – 2,000 mg/kg
Method: OECD Test Guideline 423
Isophoronediamine:
Acute oral toxicity : LD50 Oral (Rat): 1,030 mg/kg
Acute inhalation toxicity : LC50 (Rat): > 10 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Acute dermal toxicity : LD50 (Rabbit): > 2,000 – 5,000 mg/kg
m-phenylenebis(methylamine):
Acute oral toxicity : LD50 Oral (Rat): 930 mg/kg
Acute inhalation toxicity : LC50 (Rat): 1.34 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Assessment: Corrosive to the respiratory tract.
Acute dermal toxicity : LD50 Dermal (Rat): > 3,100 mg/kg
1-methylimidazole:
Acute oral toxicity : LD50 Oral (Rat): 1,144 mg/kg
Acute dermal toxicity : LD50 Dermal (Rat): 400 mg/kg
2,2,4(or 2,4,4)-trimethylhexane- 1,6-diamine:
Acute oral toxicity : LD50 Oral (Rat): 910 mg/kg
Skin corrosion/irritation
Causes severe burns.
Serious eye damage/eye irritation
Causes serious eye damage.
Respiratory or skin sensitization
Skin sensitization
May cause an allergic skin reaction.
Safety Data Sheet
according to OSHA 1910.1200 Hazard Communication Standard
SikaBiresin L325 HT (formerly EL-325HTTC) Part B
Revision Date 08/17/2023
Print Date 08/17/2023
9 / 12
Respiratory sensitization
Not classified due to lack of data.
Germ cell mutagenicity
Not classified due to lack of data.
Carcinogenicity
Not classified due to lack of data.
IARC Not applicable
OSHA Not applicable
NTP Not applicable
Reproductive toxicity
Suspected of damaging fertility or the unborn child.
STOT-single exposure
Not classified due to lack of data.
STOT-repeated exposure
Not classified due to lack of data.
Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels.
Aspiration toxicity
Not classified due to lack of data.
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Components:
Isophoronediamine:
Toxicity to algae/aquatic
plants
: ErC50 (Desmodesmus subspicatus (green algae)): > 10 – 100
mg/l
NOEC (Desmodesmus subspicatus (green algae)): 1.5 mg/l
m-phenylenebis(methylamine):
Toxicity to fish : LC50 (Oryzias latipes (Japanese medaka)): > 10 – 100 mg/l
Exposure time: 96 h
Toxicity to daphnia and other
aquatic invertebrates
: EC50 (Daphnia magna (Water flea)): > 10 – 100 mg/l
Exposure time: 48 h
2,2,4(or 2,4,4)-trimethylhexane- 1,6-diamine:
Toxicity to algae/aquatic
plants
: EC50 (Scenedesmus capricornutum (fresh water algae)): 29.5
mg/l
Safety Data Sheet
according to OSHA 1910.1200 Hazard Communication Standard
SikaBiresin L325 HT (formerly EL-325HTTC) Part B
Revision Date 08/17/2023
Print Date 08/17/2023
10 / 12
Toxicity to fish (Chronic tox-
icity)
: LC50 (Leuciscus idus (Golden orfe)): 174 mg/l
Exposure time: 48 h
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Other adverse effects
Product:
Additional ecological infor-
mation
: Do not empty into drains; dispose of this material and its con-
tainer in a safe way.
Avoid dispersal of spilled material and runoff and contact with
soil, waterways, drains and sewers.
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Waste from residues : Disposal of this product, solutions and any by-products should
at all times comply with the requirements of environmental
protection and waste disposal legislation and any regional
local authority requirements.
Contaminated packaging : Empty containers should be taken to an approved waste han-
dling site for recycling or disposal.
SECTION 14. TRANSPORT INFORMATION
International Regulations
IATA-DGR
UN/ID No. : UN 2735
Proper shipping name : Amines, liquid, corrosive, n.o.s.
(3-aminomethyl-3,5,5-trimethylcyclohexylamine)
Class : 8
Packing group : II
Labels : Corrosive
Packing instruction (cargo
aircraft)
: 855
Packing instruction (passen-
ger aircraft)
: 851
IMDG-Code
UN number : UN 2735
Safety Data Sheet
according to OSHA 1910.1200 Hazard Communication Standard
SikaBiresin L325 HT (formerly EL-325HTTC) Part B
Revision Date 08/17/2023
Print Date 08/17/2023
11 / 12
Proper shipping name : AMINES, LIQUID, CORROSIVE, N.O.S.
(3-aminomethyl-3,5,5-trimethylcyclohexylamine)
Class : 8
Packing group : II
Labels : 8
EmS Code : F-A, S-B
Marine pollutant : no
Domestic regulation
49 CFR
UN/ID/NA number : UN 2735
Proper shipping name : Amines, liquid, corrosive, n.o.s.
(3-aminomethyl-3,5,5-trimethylcyclohexylamine)
Class : 8
Packing group : II
Labels : CORROSIVE
ERG Code : 153
Marine pollutant : no
DOT: For Limited Quantity exceptions reference 49 CFR 173.154 (b)
IMDG: For Limited Quantity special provisions reference IMDG Code Chapter 3.4
Special precautions for user
The transport classification(s) provided herein are for informational purposes only, and solely based
upon the properties of the unpackaged material as it is described within this Safety Data Sheet.
Transportation classifications may vary by mode of transportation, package sizes, and variations in
regional or country regulations.
SECTION 15. REGULATORY INFORMATION
TSCA list : All chemical substances in this product are either listed as ac-
tive on the TSCA Inventory or are in compliance with a TSCA Inventory exemption.
No substances are subject to a Significant New Use Rule.
No substances are subject to TSCA 12(b) export notification requirements.
CERCLA Reportable Quantity
This material does not contain any components with a CERCLA RQ.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
SARA 302 Extremely Hazardous Substances Threshold Planning Quantity
This material does not contain any components with a section 302 EHS TPQ.
SARA 311/312 Hazards
: Respiratory or skin sensitization
Reproductive toxicity
Skin corrosion or irritation
Serious eye damage or eye irritation
Safety Data Sheet
according to OSHA 1910.1200 Hazard Communication Standard
SikaBiresin L325 HT (formerly EL-325HTTC) Part B
Revision Date 08/17/2023
Print Date 08/17/2023
12 / 12
SARA 313
: This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.
Clean Air Act
This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 112 (40 CFR 61).
California Prop. 65
WARNING: This product can expose you to chemicals including glass, oxide, chemicals, which is
known to the State of California to cause cancer. For more information go to
www.P65Warnings.ca.gov.
SECTION 16. OTHER INFORMATION
Full text of other abbreviations
ACGIH : USA. ACGIH Threshold Limit Values (TLV)
OSHA P0 : USA. Table Z-1-A Limits for Air Contaminants (1989 vacated
values)
ACGIH / C : Ceiling limit
OSHA P0 / C : Ceiling limit
Notes to Reader
The information contained in this Safety Data Sheet applies only to the actual Sika Corporation
(“Sika”) product identified and described herein. This information is not intended to address, nor
does it address the use or application of the identified Sika product in combination with any other
material, product or process. All of the information set forth herein is based on technical data re-
garding the identified product that Sika believes to be reliable as of the date hereof. Prior to each
use of any Sika product, the user must always read and follow the warnings and instructions on
the product’s current Product Data Sheet, product label and Safety Data Sheet for each Sika
product, which are available at web site and/or telephone number listed in Section 1 of this SDS.
SIKA MAKES NO WARRA NTIES EXPRESS OR IMPLIED AND ASSUMES NO LIABILITY
ARISING FROM THIS INFORMATION OR ITS USE. SIKA SHALL NOT BE LIABLE UNDER
ANY LEGAL THEORY FOR SPECIAL OR CONSEQUENTIAL DAMAGES AND SHALL NOT BE
RESPONSIBLE FOR THE USE OF THIS PRODUCT IN A MANNER TO INFRING E ON ANY
PATENT OR ANY OTHER INTELLECTUAL PROPERTY RIGHTS HELD BY OTHERS.
All sales of Sika products are subject to its current terms and conditions of sale available at
www.sikausa.com or 201- 933-8800.
Revision Date 08/17/2023
100000035332
US / Z8
