40F26PLN-D_SDS.pdf

NEUTRAL LIGHT WEIGHT PRINT BLOCK
Unsaturated Polyester Resin Gel Coat
Liquid.
SAFETY DATA SHEET
GHS product identifier
Other means of
identification
Product type
Emergency telephone
number (with hours of
operation)
Section 1. Identification
:
:
:
:
Supplier’s details :INTERPLASTIC CORPORATION
1225 Willow Lake Boulevard
St. Paul, MN 55110-5145
651.481.6860
NEUTRAL LIGHT WEIGHT PRINT BLOCK
Material uses
Product code :F-26-PLN
Product use :Industrial applications.
CHEMTREC 24-Hour Emergency Telephone 800.424.9300
Section 2. Hazards identification
FLAMMABLE LIQUIDS – Category 3
ACUTE TOXICITY: INHALATION – Category 4
SKIN CORROSION/IRRITATION – Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION – Category 2A
CARCINOGENICITY – Category 1A
Classification of the
substance or mixture
:
Signal word :Danger
Hazard statements :Flammable liquid and vapor.
Harmful if inhaled.
Causes serious eye irritation.
Causes skin irritation.
May cause cancer.
Hazard pictograms :
Precautionary statements
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 70.8%
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Date of issue/Date of revision :5/31/2015.Date of previous issue :12/23/2014. Version:3 1/15

NEUTRAL LIGHT WEIGHT PRINT BLOCKF-26-PLN
Section 2. Hazards identification
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Use personal protective equipment as required. Wear
protective gloves. Wear eye or face protection. Keep away from heat, sparks, open
flames and hot surfaces. – No smoking. Use explosion-proof electrical, ventilating,
lighting and all material-handling equipment. Use only non-sparking tools. Take
precautionary measures against static discharge. Keep container tightly closed. Use
only outdoors or in a well-ventilated area. Avoid breathing vapor. Wash hands
thoroughly after handling.
Response :IF exposed or concerned: Get medical attention. IF INHALED: Remove victim to fresh
air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or
physician if you feel unwell. IF ON SKIN (or hair): Take off immediately all
contaminated clothing. Rinse skin with water or shower. IF ON SKIN: Wash with
plenty of soap and water. Take off contaminated clothing. If skin irritation occurs: Get
medical attention. IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation
persists: Get medical attention.
Storage :Store containers in a safe place. Store in a well-ventilated place. Keep cool.
Disposal :Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise
classified
:None known.
Section 3. Composition/information on ingredients
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Other means of
identification
:Unsaturated Polyester Resin Gel Coat
CAS number :Not applicable.
Substance/mixture
Product code :F-26-PLN
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation. Any concentration shown as
exact is based on formula.
CAS number%Ingredient name
Styrene 20.0 – 40.0 100-42-5
silicon dioxide < 5.0 7631-86-9 crystalline silica, respirable powder < 1.0 14808-60-7 GelCoat Date of issue/Date of revision :5/31/2015.Date of previous issue :12/23/2014. Version:3 2/15 NEUTRAL LIGHT WEIGHT PRINT BLOCKF-26-PLN Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Description of necessary first aid measures Specific treatments :No specific treatment. Most important symptoms/effects, acute and delayed Inhalation :Harmful if inhaled. Irritating to mouth, throat and stomach.:Ingestion Skin contact :Causes skin irritation. Causes serious eye irritation.:Eye contact Over-exposure signs/symptoms Skin contact Ingestion Inhalation No specific data. No specific data. Adverse symptoms may include the following: irritation redness : : : Eye contact :Adverse symptoms may include the following: pain or irritation watering redness Potential acute health effects Indication of immediate medical attention and special treatment needed, if necessary Date of issue/Date of revision :5/31/2015.Date of previous issue :12/23/2014. Version:3 3/15 NEUTRAL LIGHT WEIGHT PRINT BLOCKF-26-PLN Section 4. First aid measures Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. See toxicological information (Section 11) Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide metal oxide/oxides Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use dry chemical, CO , water spray (fog) or foam. Extinguishing media : : : Do not use water jet. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures : :No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders:If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Date of issue/Date of revision :5/31/2015.Date of previous issue :12/23/2014. Version:3 4/15 NEUTRAL LIGHT WEIGHT PRINT BLOCKF-26-PLN Section 6. Accidental release measures Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Do not store above the following temperature: 38 C (100.4 F). Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. : : Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. : Precautions for safe handling Section 8. Exposure controls/personal protection Control parameters Occupational exposure limits Date of issue/Date of revision :5/31/2015.Date of previous issue :12/23/2014. Version:3 5/15 NEUTRAL LIGHT WEIGHT PRINT BLOCKF-26-PLN Section 8. Exposure controls/personal protection Styrene ACGIH TLV (United States, 4/2014). TWA: 20 ppm 8 hours. TWA: 85 mg/m 8 hours. STEL: 40 ppm 15 minutes. STEL: 170 mg/m 15 minutes. OSHA PEL 1989 (United States, 3/1989). TWA: 50 ppm 8 hours. TWA: 215 mg/m 8 hours. STEL: 100 ppm 15 minutes. STEL: 425 mg/m 15 minutes. OSHA PEL Z2 (United States, 2/2013). TWA: 100 ppm 8 hours. CEIL: 200 ppm AMP: 600 ppm 5 minutes. NIOSH REL (United States, 10/2013). TWA: 50 ppm 10 hours. TWA: 215 mg/m 10 hours. STEL: 100 ppm 15 minutes. STEL: 425 mg/m 15 minutes. silicon dioxide NIOSH REL (United States, 10/2013). TWA: 6 mg/m 10 hours. crystalline silica, respirable powder OSHA PEL Z3 (United States, 2/2013). TWA: 250 MPPCF / (%SiO2+5) 8 hours. Form: Respirable TWA: 10 MG/M3 / (%SiO2+2) 8 hours. Form: Respirable OSHA PEL 1989 (United States, 3/1989). TWA: 0.1 mg/m , (as quartz) 8 hours. Form: Respirable dust ACGIH TLV (United States, 4/2014). TWA: 0.025 mg/m 8 hours. Form: Respirable fraction NIOSH REL (United States, 10/2013). TWA: 0.05 mg/m 10 hours. Form: respirable dust Ingredient name Exposure limits Environmental exposure controls :Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls :Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Individual protection measures Date of issue/Date of revision :5/31/2015.Date of previous issue :12/23/2014. Version:3 6/15 NEUTRAL LIGHT WEIGHT PRINT BLOCKF-26-PLN Section 8. Exposure controls/personal protection Hand protection Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Skin protection Other skin protection :Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Section 9. Physical and chemical properties Physical state Melting point Vapor pressure Relative density Vapor density Liquid. Not available. 1.27 to 1.33 3.6 [Air = 1] 0.57 kPa (4.3 mm Hg) [room temperature] Characteristic.Odor pH Tan. [Light]Color Evaporation rate >1 (ether (anhydrous) = 1)
Flash point Closed cup: 31.1 C (88 F)
Not applicable.
0.1 ppmOdor threshold
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point :145.2 C (293.4 F)
Flammability (solid, gas):Not available.
Lower and upper explosive
(flammable) limits
:Lower: 1.1%
Upper: 6.1%
Burning rate Not applicable.:
Burning time :Not applicable.
Date of issue/Date of revision :5/31/2015.Date of previous issue :12/23/2014. Version:3 7/15

NEUTRAL LIGHT WEIGHT PRINT BLOCKF-26-PLN
Section 9. Physical and chemical properties
Solubility Not available.
Auto-ignition temperature Not available.
Not available.
Viscosity Not available.
Partition coefficient: n-
octanol/water
:
:
:
:
SADT Not applicable.:
Decomposition temperature:Not available.
Solubility in water :Not applicable.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Hazardous reactions or instability may occur under certain conditions of storage or use.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Reactive or incompatible with the following materials: acids and alkalis.
Keep away from oxidizing agents. Incompatible with alkali metals. Incompatible with
some strong acids.
Section 11. Toxicological information
Acute toxicity
Styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours
LC50 Inhalation Vapor Rat 11800 mg/m 4 hours
LD50 Oral Rat 2650 mg/kg –
Product/ingredient name Result Species Dose Exposure
Irritation/Corrosion
Styrene Eyes – Mild irritant Human – 50 parts per
million

Eyes – Moderate irritantRabbit – 24 hours 100
milligrams

Eyes – Severe irritantRabbit – 100
milligrams

Skin – Mild irritant Rabbit – 500
milligrams

Product/ingredient name Result Score Exposure ObservationSpecies
Information on toxicological effects
Date of issue/Date of revision :5/31/2015.Date of previous issue :12/23/2014. Version:3 8/15

NEUTRAL LIGHT WEIGHT PRINT BLOCKF-26-PLN
Section 11. Toxicological information
Carcinogenicity
Not available.
Conclusion/Summary :
Mutagenicity
Not available.
Skin – Moderate irritantRabbit – 100 Percent-
silicon dioxide Eyes – Mild irritant Rabbit – 24 hours 25
milligrams

Sensitization
Not available.
Styrene manufacturers vary on their determination that the GHS hazard classification
criteria for carcinogenicity has been met.
Styrene is listed by IARC as a possible carcinogen to humans (Group 2B) based on
“limited evidence” in humans, “limited evidence” in animals and “other relevant data”.
The United States NTP listed styrene as reasonably anticipated to be a human
carcinogen based on “limited evidence” from studies in humans, “sufficient evidence”
from studies in experimental animals, and supporting data on mechanisms of
carcinogenesis. The significance of these results for humans has not been established
through risk assessment.
The primary route of exposure to silica for the carcinogen classification is inhalation.
Exposure to respirable particles from the product as shipped and while wet is not likely.
Exposure to respirable particles may be possible when grinding, cutting, or sanding a
cured article.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Information on the likely
routes of exposure
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Not available.
Not available.
Aspiration hazard
Not available.
:Not available.
Potential acute health effects
Classification
Styrene – 2B Reasonably anticipated to be a human carcinogen.
silicon dioxide – 3 –
crystalline silica, respirable
powder
– 1 Known to be a human carcinogen.
Product/ingredient name NTPIARCOSHA
Date of issue/Date of revision :5/31/2015.Date of previous issue :12/23/2014. Version:3 9/15

NEUTRAL LIGHT WEIGHT PRINT BLOCKF-26-PLN
Section 11. Toxicological information
Not available.
Inhalation :Harmful if inhaled.
Irritating to mouth, throat and stomach.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
No known significant effects or critical hazards.General :
May cause cancer. Risk of cancer depends on duration and level of exposure.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Oral 3018.5 mg/kg
Inhalation (gases) 3155.1 ppm
Inhalation (vapors) 13.44 mg/l
Route ATE value
Acute toxicity estimates
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
Date of issue/Date of revision :5/31/2015.Date of previous issue :12/23/2014. Version:3 10/15

NEUTRAL LIGHT WEIGHT PRINT BLOCKF-26-PLN
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Product/ingredient name
Styrene 0.35 13.49 low
Toxicity
Styrene Acute EC50 1400 g/l Fresh water Algae – Pseudokirchneriella
subcapitata
72 hours
Acute EC50 720 g/l Fresh water Algae – Pseudokirchneriella
subcapitata
96 hours
Acute EC50 4700 g/l Fresh water Daphnia – Daphnia magna 48 hours
Acute LC50 52000 g/l Marine waterCrustaceans – Artemia salina –
Nauplii
48 hours
Acute LC50 4020 g/l Fresh water Fish – Pimephales promelas 96 hours
Chronic NOEC 63 g/l Fresh water Algae – Pseudokirchneriella
subcapitata
96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Not available.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
Date of issue/Date of revision :5/31/2015.Date of previous issue :12/23/2014. Version:3 11/15

NEUTRAL LIGHT WEIGHT PRINT BLOCKF-26-PLN
Section 14. Transport information
Special precautions for user
Transport in bulk according
to Annex II of MARPOL
73/78 and the IBC Code
Transport within user s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
:Not available.
:
RESIN
SOLUTION
(contains
STYRENE
MONOMER)
3
III
RESIN
SOLUTION
(contains
STYRENE
MONOMER)
3
III
RESIN
SOLUTION
(contains
STYRENE
MONOMER)
UN1866
3
III
UN1866 UN1866
Reportable
quantity
3905.9 lbs /
1773.3 kg [360.
35 gal / 1364.1
L]
Package sizes
shipped in
quantities less
than the
product
reportable
quantity are
not subject to
the RQ
(reportable
quantity)
transportation
requirements.
– –
DOT
Classification
IMDG IATA
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
Yes. Yes. No.
Mexico
Classification
UN1866
RESIN
SOLUTION
(contains
STYRENE
MONOMER)
3
III
Yes.

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NEUTRAL LIGHT WEIGHT PRINT BLOCKF-26-PLN
1,4-dihydroxybenzene 0.01 Yes.500 / 10000- 100 –
Section 15. Regulatory information
U.S. Federal regulations
The following components are listed: STYRENE MONOMER; AMORPHOUS SILICA;
SOAPSTONE
WARNING: This product contains a chemical known to the State of California to cause cancer.
WARNING: This product contains less than 1% of a chemical known to the State of California to cause birth defects or
other reproductive harm.
Clean Water Act (CWA) 307: Naphthenic acids, copper salts; chloromethane
Clean Water Act (CWA) 311: styrene
Massachusetts
:
:
SARA 313
Product name CAS number %
styrene 100-42-5 25.60
styrene 100-42-5 25.60
Form R – Reporting
requirements
Supplier notification
California Prop. 65
Clean Air Act Section 112
(b) Hazardous Air
Pollutants (HAPs)
:Listed
Clean Air Act Section 602
Class I Substances
:Not listed
Clean Air Act Section 602
Class II Substances
:Not listed
New York :The following components are listed: Styrene
New Jersey :The following components are listed: STYRENE MONOMER; BENZENE, ETHENYL-;
SOAPSTONE; SILICA, QUARTZ; QUARTZ (SiO2)
Pennsylvania :The following components are listed: BENZENE, ETHENYL-; SILICA; SOAPSTONE
DUST; QUARTZ (SIO2)
State regulations
TSCA 8(a) PAIR: 4-tert-butylpyrocatechol; N,N-dimethylaniline
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
United States inventory (TSCA 8b): Not determined.
SARA 302/304
SARA 304 RQ :1096491.2 lbs / 497807 kg [101159 gal / 382928.5 L]
Composition/information on ingredients
Name % EHS(lbs) (lbs)(gallons) (gallons)
SARA 302 TPQ SARA 304 RQ
SARA 311/312
Classification :Fire hazard
Immediate (acute) health hazard
Delayed (chronic) health hazard
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NEUTRAL LIGHT WEIGHT PRINT BLOCKF-26-PLN
Section 15. Regulatory information
Talc , not containing asbestiform fibresYes. No. No. No.
crystalline silica, respirable powderYes. No. No. No.
chloromethane No. Yes. No. No.
Ingredient name Cancer Reproductive No significant risk
level
Maximum
acceptable dosage
level
Canada inventory :Not determined.
Australia inventory (AICS): Not determined.
China inventory (IECSC): Not determined.
Japan inventory: Not determined.
Korea inventory: Not determined.
Malaysia Inventory (EHS Register): Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
Taiwan inventory (CSNN): Not determined.
International regulations
International lists :
Section 16. Other information
5/31/2015.
History
Date of printing :
:5/31/2015.
Hazardous Material Information System (U.S.A.)
2
3
1
1
3
2
*
National Fire Protection Association (U.S.A.)
Health
Special
Instability/Reactivity
Flammability
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS ratings are not required on SDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS ratings are to be used with a fully implemented HMIS
program. HMIS is a registered mark of the National Paint & Coatings Association (NPCA). HMIS materials
may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
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NEUTRAL LIGHT WEIGHT PRINT BLOCKF-26-PLN
Section 16. Other information
Date of issue/Date of
revision
Version
Prepared by
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Notice to reader
Date of previous issue
:
:
Indicates information that has changed from previously issued version.
References :OSHA Hazard Communication Standard, March 2012 (29 CFR 1910.1200)
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. (“Marpol” = marine pollution)
UN = United Nations
12/23/2014.
3
Health, Safety and Environmental Department
Email :For questions regarding the SDS contact:iasafety@ip-corporation.com
Date of issue/Date of revision :5/31/2015.Date of previous issue :12/23/2014. Version:3 15/15

40B853DVD_SDS.pdf

BLACK VE BARRIER COAT
Vinyl Ester Coating.
Liquid.
SAFETY DATA SHEET
Product identifier
Other means of identification
Product type
Emergency telephone
number (with hours of
operation)
SECTION 1: Identification of the substance/mixture and of the
company/undertaking
:
:
:
:
Supplier’s details :INTERPLASTIC CORPORATION
1225 Willow Lake Boulevard
St. Paul, MN 55110-5145
651.481.6860
BLACK VE BARRIER COAT
Relevant identified uses of the substance or mixture and uses advised against
Product code :B-853DV-LMM
Industrial applications.
CHEMTREC 24-Hour Emergency Telephone
US and Canada 800.424.9300
Outside US and Canada +1 703.741.5970
SECTION 2: Hazards identification
FLAMMABLE LIQUIDS – Category 3
ACUTE TOXICITY (inhalation) – Category 4
SKIN IRRITATION – Category 2
EYE IRRITATION – Category 2A
CARCINOGENICITY – Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) – Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing
organs) – Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard statements :H226 – Flammable liquid and vapor.
H332 – Harmful if inhaled.
H319 – Causes serious eye irritation.
H315 – Causes skin irritation.
H351 – Suspected of causing cancer.
H335 – May cause respiratory irritation.
H372 – Causes damage to organs through prolonged or repeated exposure.
(hearing organs)
Hazard pictograms :
Precautionary statements
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown oral toxicity: 11.7%
Percentage of the mixture consisting of ingredient(s) of unknown dermal toxicity: 45.
8%
Percentage of the mixture consisting of ingredient(s) of unknown inhalation toxicity:
11.7%
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BLACK VE BARRIER COAT Mexico B-853DV-LMM
SECTION 2: Hazards identification
Prevention :P201 – Obtain special instructions before use. P202 – Do not handle until all safety
precautions have been read and understood. P280 – Wear protective gloves. Wear
protective clothing. Wear eye or face protection. P210 – Keep away from heat, hot
surfaces, sparks, open flames and other ignition sources. No smoking. P271 – Use
only outdoors or in a well-ventilated area. P260 – Do not breathe vapor. P270 – Do
not eat, drink or smoke when using this product. P264 – Wash hands thoroughly
after handling.
Response :P314 – Get medical attention if you feel unwell. P308 + P313 – IF exposed or
concerned: Get medical attention. P304 + P340 + P312 – IF INHALED: Remove
person to fresh air and keep comfortable for breathing. Call a POISON CENTER or
physician if you feel unwell. P303 + P361 + P353 – IF ON SKIN (or hair): Take off
immediately all contaminated clothing. Rinse skin with water. P302 + P352 +
P362+P364 – IF ON SKIN: Wash with plenty of soap and water. Take off
contaminated clothing and wash it before reuse. P332 + P313 – If skin irritation
occurs: Get medical attention. P305 + P351 + P338 – IF IN EYES: Rinse cautiously
with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. P337 + P313 – If eye irritation persists: Get medical attention.
Storage :P405 – Store locked up.
Disposal :P501 – Dispose of contents and container in accordance with all local, regional,
national and international regulations. No Code(s) – Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.
Other hazards which do not
result in classification
:None known.
SECTION 3: Composition/information on ingredients
styrene 25 – 46 100-42-5
Talc , not containing asbestiform fibres 10 14807-96-6
N,N-dimethylaniline 0.3 121-69-7
Ingredient name CAS number%
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.
Other means of
identification
:Vinyl Ester Coating.
Substance/mixture :
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash
clothing before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing.
If it is suspected that fumes are still present, the rescuer should wear an appropriate
mask or self-contained breathing apparatus. If not breathing, if breathing is irregular
or if respiratory arrest occurs, provide artificial respiration or oxygen by trained
personnel. It may be dangerous to the person providing aid to give mouth-to-mouth
resuscitation. Get medical attention. If necessary, call a poison center or physician.
If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or
waistband.
SECTION 4: First aid measures
Eye contact
Skin contact
Inhalation
:
:
:
Description of necessary first aid measures
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention. Buffered baby shampoo will aid in removal of resin.
Date of issue/Date of revision :3/18/2020Date of previous issue :9/30/2018 Version:0.02 2/12

BLACK VE BARRIER COAT Mexico B-853DV-LMM
SECTION 4: First aid measures
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air
and keep at rest in a position comfortable for breathing. If material has been
swallowed and the exposed person is conscious, give small quantities of water to
drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not
induce vomiting unless directed to do so by medical personnel. If vomiting occurs,
the head should be kept low so that vomit does not enter the lungs. Get medical
attention. Never give anything by mouth to an unconscious person. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Ingestion :
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it
is suspected that fumes are still present, the rescuer should wear an appropriate
mask or self-contained breathing apparatus. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
SECTION 5: Firefighting measures
Specific hazards arising
from the chemical
Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard.
In a fire or if heated, a pressure increase will occur and the container may burst, with
the risk of a subsequent explosion. The vapor/gas is heavier than air and will
spread along the ground. Vapors may accumulate in low or confined areas or travel
a considerable distance to a source of ignition and flash back.
Use dry chemical, CO , water spray (fog) or foam.
Extinguishing media
:
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
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BLACK VE BARRIER COAT Mexico B-853DV-LMM
SECTION 5: Firefighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without
suitable training. Move containers from fire area if this can be done without risk.
Use water spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
halogenated compounds
metal oxide/oxides
Fire-fighters should wear appropriate protective equipment and self-contained
breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.
Special protective
equipment for fire-fighters
:
:
Special protective actions
for fire-fighters
:
SECTION 6: Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways,
drains and sewers. Inform the relevant authorities if the product has caused
environmental pollution (sewers, waterways, soil or air).
Large spill :
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialized clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in “For non-emergency personnel”.
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dispose of via a licensed waste disposal contractor.
Absorb with an inert material and transfer the spilled material and absorbent to an
appropriate waste disposal container. Wear appropriate respirator when ventilation
is inadequate. Wear eye/face protection.
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Contain and collect spillage
with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local
regulations (see Section 13). Dispose of via a licensed waste disposal contractor.
Contaminated absorbent material may pose the same hazard as the spilled product.
Note: see Section 1 for emergency contact information and Section 13 for waste
disposal. Wear appropriate respiratory protection. Wear protective clothing and
eye or face protection:
SECTION 7: Handling and storage
Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure –
obtain special instructions before use. Do not handle until all safety precautions
have been read and understood. Do not get in eyes or on skin or clothing. Do not
breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Wear
appropriate respirator when ventilation is inadequate. Do not enter storage areas
and confined spaces unless adequately ventilated. Keep in the original container or
an approved alternative made from a compatible material, kept tightly closed when
not in use. Store and use away from heat, sparks, open flame or any other ignition
source. Use explosion-proof electrical (ventilating, lighting and material handling)
equipment. Use only non-sparking tools. Take precautionary measures against
:
Precautions for safe handling
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BLACK VE BARRIER COAT Mexico B-853DV-LMM
SECTION 7: Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before
eating, drinking and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8 for additional
information on hygiene measures.
Do not store above the following temperature: 38 C (100.4 F). Store in accordance
with local regulations. Store in a segregated and approved area. Store in original
container protected from direct sunlight in a dry, cool and well-ventilated area, away
from incompatible materials (see Section 10) and food and drink. Eliminate all
ignition sources. Separate from oxidizing materials. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination. See Section 10
for incompatible materials before handling or use. Store containers in a safe place.
:
:
electrostatic discharges. Empty containers retain product residue and can be
hazardous. Do not reuse container.
styrene NOM-010-STPS-2014 (Mexico, 4/2016).
TWA: 20 ppm 8 hours.
STEL: 40 ppm 15 minutes.
Talc , not containing asbestiform fibres NOM-010-STPS-2014 (Mexico, 4/2016).
STEL: 2 mg/m 15 minutes. Form: Respirable fraction
TWA: 0.1 fibers/cm 8 hours.
N,N-dimethylaniline NOM-010-STPS-2014 (Mexico, 4/2016). Absorbed
through skin.
TWA: 5 ppm 8 hours.
STEL: 10 ppm 15 minutes.
SECTION 8: Exposure controls/personal protection
Ingredient name Exposure limits
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn,
unless the assessment indicates a higher degree of protection: chemical splash
goggles.
Eye/face protection :
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust
ventilation or other engineering controls to keep worker exposure to airborne
contaminants below any recommended or statutory limits. The engineering controls
also need to keep gas, vapor or dust concentrations below any lower explosive
limits. Use explosion-proof ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and
safety showers are close to the workstation location.
Hygiene measures :
Control parameters
Individual protection measures
Occupational exposure limits
Skin protection
Date of issue/Date of revision :3/18/2020Date of previous issue :9/30/2018 Version:0.02 5/12

BLACK VE BARRIER COAT Mexico B-853DV-LMM
SECTION 8: Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should
be worn at all times when handling chemical products if a risk assessment indicates
this is necessary. Considering the parameters specified by the glove manufacturer,
check during use that the gloves are still retaining their protective properties. It
should be noted that the time to breakthrough for any glove material may be
different for different glove manufacturers. In the case of mixtures, consisting of
several substances, the protection time of the gloves cannot be accurately
estimated.
Respiratory protection :
:
Body protection Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product. When there is a risk of ignition from static electricity,
wear anti-static protective clothing. For the greatest protection from static
discharges, clothing should include anti-static overalls, boots and gloves.
:
Other skin protection :Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
SECTION 9: Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
1.06 to 1.14
3.6 [Air = 1]
0.67 kPa (5 mm Hg) [room temperature]
Not available.
Sweetish.Odor
pH
Black.Color
Evaporation rate <1 (butyl acetate = 1) Auto-ignition temperature Flash point Not available. Closed cup: 31 C (87.8 F) Not available. Not applicable. Viscosity Not available. 0.1 ppmOdor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance Boiling point :145 C (293 F) Flammability (solid, gas):Not available. Lower and upper explosive (flammable) limits :Lower: 0.9% Upper: 6.8% Decomposition temperature:Not available. Solubility in water :Not applicable. Molecular weight :Not applicable. Flow time (ISO 2431) :Not available. VOC content :34.7 % (w/w) As shipped, including monomers and additives. Date of issue/Date of revision :3/18/2020Date of previous issue :9/30/2018 Version:0.02 6/12 BLACK VE BARRIER COAT Mexico B-853DV-LMM SECTION 10: Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability Reactive or incompatible with the following materials: oxidizing materials : : : Incompatible materials : Possibility of hazardous reactions :Hazardous reactions or instability may occur under certain conditions of storage or use. Reactivity :No specific test data related to reactivity available for this product or its ingredients. Reactive or incompatible with the following materials: metals, acids and alkalis. Incompatible with alkali metals. Incompatible with some alkalis. Incompatible with some strong acids. Incompatible with copper alloys, brass. Hazardous polymerization may occur under certain conditions of storage or use. Keep away from heat and direct sunlight. Keep away from heat and flame. Keep away from oxidizing agents. SECTION 11: Toxicological information Acute toxicity styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours LC50 Inhalation Vapor Rat 11800 mg/m 4 hours LD50 Oral Rat 2650 mg/kg - N,N-dimethylaniline LD50 Dermal Rabbit 1770 mg/kg - LD50 Oral Rat 951 mg/kg - Product/ingredient nameResult Species Dose Exposure Carcinogenicity Mutagenicity Not available. Irritation/Corrosion styrene Eyes - Mild irritant Human - 50 ppm - Eyes - Moderate irritantRabbit - 24 hours 100 mg - Eyes - Severe irritantRabbit - 100 mg - Skin - Mild irritant Rabbit - 500 mg - Skin - Moderate irritantRabbit - 100 % - Talc , not containing asbestiform fibres Skin - Mild irritant Human - 72 hours 300 ug I - N,N-dimethylaniline Eyes - Moderate irritantRabbit - 24 hours 20 mg - Eyes - Moderate irritantRabbit - 20 mg - Skin - Mild irritant Rabbit - 24 hours 500 mg - Skin - Mild irritant Rabbit - 500 mg - Product/ingredient nameResult Score Exposure Observation Sensitization Not available. Species Information on toxicological effects Date of issue/Date of revision :3/18/2020Date of previous issue :9/30/2018 Version:0.02 7/12 BLACK VE BARRIER COAT Mexico B-853DV-LMM SECTION 11: Toxicological information Not available. Teratogenicity Not available. Reproductive toxicity Not available. Information on the likely routes of exposure Inhalation :Harmful if inhaled. May cause respiratory irritation. No known significant effects or critical hazards.:Ingestion Skin contact :Causes skin irritation. Causes serious eye irritation.:Eye contact Symptoms related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing No specific data. Adverse symptoms may include the following: irritation redness : : : Eye contact :Adverse symptoms may include the following: pain or irritation watering redness Delayed and immediate effects and also chronic effects from short and long term exposure Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) styrene Category 3 Not applicable.Respiratory tract irritation Name Category Name Category styrene Category 1 Inhalation hearing organs N,N-dimethylaniline Category 2 Not determinedNot determined Aspiration hazard Name Result styrene ASPIRATION HAZARD - Category 1 Route of exposure Target organs Route of exposure Target organs :Not available. Potential acute health effects Potential immediate effects :Not available. Short term exposure Potential delayed effects:Not available. Potential immediate effects :Not available. Long term exposure Potential delayed effects:Not available. Date of issue/Date of revision :3/18/2020Date of previous issue :9/30/2018 Version:0.02 8/12 BLACK VE BARRIER COAT Mexico B-853DV-LMM SECTION 11: Toxicological information Not available. Causes damage to organs through prolonged or repeated exposure.General : Suspected of causing cancer. Risk of cancer depends on duration and level of exposure. Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : No known significant effects or critical hazards.Teratogenicity : Developmental effects :No known significant effects or critical hazards. Fertility effects :No known significant effects or critical hazards. Potential chronic health effects Numerical measures of toxicity Oral 6855.4 mg/kg Inhalation (gases) 7165.9 ppm Inhalation (vapors) 30.53 mg/l Route ATE value Acute toxicity estimates SECTION 12: Ecological information LogPow BCF Potential Bioaccumulative potential Product/ingredient name styrene 0.35 13.49 low N,N-dimethylaniline 1.171 16 low Product/ingredient name Aquatic half-life Photolysis Biodegradability styrene - - Readily Toxicity styrene Acute EC50 1400 g/l Fresh water Algae - Pseudokirchneriella subcapitata 72 hours Acute EC50 720 g/l Fresh water Algae - Pseudokirchneriella subcapitata 96 hours Acute EC50 4700 g/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 52 mg/l Marine water Crustaceans - Artemia salina48 hours Acute LC50 4020 g/l Fresh water Fish - Pimephales promelas 96 hours Chronic NOEC 63 g/l Fresh water Algae - Pseudokirchneriella subcapitata 96 hours N,N-dimethylaniline Acute EC50 22000 g/l Fresh waterAlgae - Chlorella pyrenoidosa72 hours Acute EC50 2.3 mg/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 52600 g/l Fresh waterFish - Pimephales promelas 96 hours Chronic NOEC 14000 g/l Fresh waterAlgae - Chlorella pyrenoidosa72 hours Product/ingredient name SpeciesResult Exposure Persistence and degradability styrene OECD 70 % - Readily - 28 days - - Product/ingredient name Test DoseResult Inoculum Soil/water partition coefficient (KOC) :Not available. Mobility in soil Date of issue/Date of revision :3/18/2020Date of previous issue :9/30/2018 Version:0.02 9/12 BLACK VE BARRIER COAT Mexico B-853DV-LMM SECTION 12: Ecological information Other adverse effects :No known significant effects or critical hazards. SECTION 13: Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non- recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. :Disposal methods SECTION 14: Transport information Special precautions for user Transport in bulk according to Annex II of MARPOL and the IBC Code Transport within user s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. :Not available. : RESIN SOLUTION 3 III RESIN SOLUTION 3 III RESIN SOLUTION UN1866 3 III UN1866 UN1866 Reportable quantity 2929.6 lbs / 1330 kg [319.41 gal / 1209.1 L]. Package sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity) transportation requirements. DOT Classification IMDG IATA UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards No. No. No. TDG Classification UN1866 RESIN SOLUTION 3 III No. Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.18-2.19 (Class 3). ADR/RID UN1866 RESIN SOLUTION 3 III No. Tunnel code (D/E) Mexico Classification UN1866 RESIN SOLUTION 3 III No. DOT Classification TDG Classification ADR/RID : : : Date of issue/Date of revision :3/18/2020Date of previous issue :9/30/2018 Version:0.0210/12 BLACK VE BARRIER COAT Mexico B-853DV-LMM SECTION 15: Regulatory information International regulations Montreal Protocol (Annexes A, B, C, E) Not listed. Stockholm Convention on Persistent Organic Pollutants Not listed. Rotterdam Convention on Prior Informed Consent (PIC) Not listed. Chemical Weapon Convention List Schedules I, II & III Chemicals Not listed. UNECE Aarhus Protocol on POPs and Heavy Metals Not listed. Inventory list Australia :Not determined. Canada :Not determined. China :Not determined. Europe :Not determined. Japan :Japan inventory (ENCS): Not determined. Japan inventory (ISHL): Not determined. Republic of Korea :Not determined. Malaysia :Not determined. New Zealand :Not determined. Philippines :Not determined. Taiwan :Not determined. United States :All components are listed or exempted. Turkey :Not determined. National Fire Protection Association (U.S.A.) 1 3 2 Health Special Instability/Reactivity Flammability Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. Thailand :Not determined. Viet Nam :Not determined. Date of issue/Date of revision :3/18/2020Date of previous issue :9/30/2018 Version:0.0211/12 BLACK VE BARRIER COAT Mexico B-853DV-LMM SECTION 16: Other information 3/18/2020 History Date of printing Date of issue/Date of revision Version Prepared by The information, which is based on the current knowledge of the chemical substance or mixture and applies to appropriate safety precautions for the product, is deemed correct but is not exhaustive and will be used only as a guide. Notice to reader Date of previous issue : : : : : Indicates information that has changed from previously issued version. References : Key to abbreviations :ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations 3/18/2020 9/30/2018 0.02 Procedure used to derive the classification Classification Justification FLAMMABLE LIQUIDS - Category 3 On basis of test data ACUTE TOXICITY (inhalation) - Category 4 Calculation method SKIN IRRITATION - Category 2 Calculation method EYE IRRITATION - Category 2A Calculation method CARCINOGENICITY - Category 2 Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 Calculation method SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) - Category 1 Calculation method Hazardous Material Information System (U.S.A.) 2 3 1 * Health Flammability Physical hazards Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. HMIS ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service mark of the American Coatings Association, Inc. The customer is responsible for determining the PPE code for this material. For more information on HMIS Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual. iasafety@ip-corporation.com NOM-018-STPS-2015 Date of issue/Date of revision :3/18/2020Date of previous issue :9/30/2018 Version:0.0212/12

40B816BD_SDS.pdf

BLACK COLORANT
Unsaturated Polyester Resin Colorant
Liquid.
SAFETY DATA SHEET
GHS product identifier
Other means of identification
Product type
Emergency telephone
number (with hours of
operation)
Section 1. Identification
:
:
:
:
Supplier’s details :INTERPLASTIC CORPORATION
1225 Willow Lake Boulevard
St. Paul, MN 55110-5145
651.481.6860
BLACK COLORANT
Relevant identified uses of the substance or mixture and uses advised against
Product code :B-816B-CZZ
Industrial applications.
CHEMTREC 24-Hour Emergency Telephone
US and Canada 800.424.9300
Outside US and Canada +1 703.741.5970
Section 2. Hazards identification
Not classified.Classification of the
substance or mixture
:
Signal word :No signal word.
Hazard statements :No known significant effects or critical hazards.
Precautionary statements
Prevention :Not applicable.
Response :Not applicable.
Storage :Not applicable.
Disposal :Not applicable.
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown oral toxicity: 57%
Percentage of the mixture consisting of ingredient(s) of unknown dermal toxicity: 57%
Percentage of the mixture consisting of ingredient(s) of unknown inhalation toxicity: 58.
3%
Hazards not otherwise
classified
:None known.
OSHA/HCS status :While this material is not considered hazardous by the OSHA Hazard Communication
Standard (29 CFR 1910.1200), this SDS contains valuable information critical to the
safe handling and proper use of the product. This SDS should be retained and available
for employees and other users of this product.
Date of issue/Date of revision :12/28/2020 Date of previous issue :9/14/2018 Version:2 1/11

BLACK COLORANT B-816B-CZZ
Section 3. Composition/information on ingredients
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Other means of
identification
:Unsaturated Polyester Resin Colorant
Substance/mixture :
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Any concentration shown as exact is based on formula.
VOC content is listed in Section 9.
Environmental composition is shown in Section 15.
Proprietary Proprietary –
COLORANT
Ingredient name % CAS number
Wash out mouth with water. Remove victim to fresh air and keep at rest in a position
comfortable for breathing. If material has been swallowed and the exposed person is
conscious, give small quantities of water to drink. Do not induce vomiting unless
directed to do so by medical personnel. Get medical attention if symptoms occur.
Remove contaminated clothing and shoes. Flush contaminated skin with plenty of
water. Get medical attention if symptoms occur.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get
medical attention if symptoms occur.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Description of necessary first aid measures
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact :No specific data.
Potential acute health effects
Indication of immediate medical attention and special treatment needed, if necessary
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. If irritation persists, get medical attention.
Date of issue/Date of revision :12/28/2020 Date of previous issue :9/14/2018 Version:2 2/11

BLACK COLORANT B-816B-CZZ
Section 4. First aid measures
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training.
See toxicological information (Section 11)
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
In a fire or if heated, a pressure increase will occur and the container may burst.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
:
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Put on appropriate personal
protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in “For non-
emergency personnel”.
Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas.
Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth,
vermiculite or diatomaceous earth and place in container for disposal according to local
regulations (see Section 13). Dispose of via a licensed waste disposal contractor.
Contaminated absorbent material may pose the same hazard as the spilled product.
Note: see Section 1 for emergency contact information and Section 13 for waste
disposal. Wear appropriate respiratory protection. Wear protective clothing and eye or
face protection:
Stop leak if without risk. Move containers from spill area. Dispose of via a licensed
waste disposal contractor. Absorb with an inert material and transfer the spilled
material and absorbent to an appropriate waste disposal container. Wear appropriate
respirator when ventilation is inadequate. Wear eye/face protection.
Date of issue/Date of revision :12/28/2020 Date of previous issue :9/14/2018 Version:2 3/11

BLACK COLORANT B-816B-CZZ
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Do not store above the following temperature: 38 C (100.4 F). Store in accordance with
local regulations. Store in original container protected from direct sunlight in a dry, cool
and well-ventilated area, away from incompatible materials (see Section 10) and food
and drink. Keep container tightly closed and sealed until ready for use. Containers that
have been opened must be carefully resealed and kept upright to prevent leakage. Do
not store in unlabeled containers. Use appropriate containment to avoid environmental
contamination. See Section 10 for incompatible materials before handling or use.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8).:
Precautions for safe handling
Proprietary Solvent. None.
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: safety glasses with side-
shields.
Eye/face protection
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Good general ventilation should be sufficient to control worker exposure to airborne
contaminants.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Control parameters
Individual protection measures
Occupational exposure limits
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Date of issue/Date of revision :12/28/2020 Date of previous issue :9/14/2018 Version:2 4/11

BLACK COLORANT B-816B-CZZ
Section 8. Exposure controls/personal protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Respiratory protection :
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
1.88 to 2
Not available.
Not available.
Not available.
Characteristic.Odor
pH
Black.Color
Evaporation rate Not applicable.
Auto-ignition temperature
Flash point
Not available.
Closed cup: >93.3 C (>199.9 F)
Not available.
Not applicable.
Viscosity Not available.
Not available.Odor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point :>184 C (>363.2 F)
Lower and upper explosive
(flammable) limits
:Not available.
Solubility in water :Not applicable.
VOC content :1.8 % (w/w) As shipped, including monomers and additives.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid No specific data.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
No specific data.
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Not available.
Slightly reactive or incompatible with the following materials: oxidizing materials, acids
and alkalis.
Date of issue/Date of revision :12/28/2020 Date of previous issue :9/14/2018 Version:2 5/11

BLACK COLORANT B-816B-CZZ
Section 11. Toxicological information
Acute toxicity
Proprietary Solvent. LD50 Dermal Rabbit 1970 mg/kg –
LD50 Oral Rat 3730 mg/kg –
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
Proprietary Solvent. Eyes – Moderate irritantRabbit – 24 hours 20
mg

Eyes – Moderate irritantRabbit – 20 ug –
Eyes – Severe irritantRabbit – 20 mg –
Skin – Mild irritant Rabbit – 415 mg –
Skin – Moderate irritantRabbit – 24 hours 500
mg

Skin – Severe irritantRabbit – 0.5 Ml –
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Information on the likely
routes of exposure
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Proprietary Solvent. Category 3 Not applicable.Respiratory tract
irritation
Name Category
Not available.
Aspiration hazard
Not available.
Route of
exposure
Target organs
Information on toxicological effects
:Not available.
Potential acute health effects
Date of issue/Date of revision :12/28/2020 Date of previous issue :9/14/2018 Version:2 6/11

BLACK COLORANT B-816B-CZZ
Section 11. Toxicological information
Not available.
No known significant effects or critical hazards.General :
No known significant effects or critical hazards.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact :No specific data.
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Oral 127445.4 mg/kg
Dermal 67310.3 mg/kg
Route ATE value
Acute toxicity estimates
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Product/ingredient name
Proprietary Solvent. 2.9 25.33 low
Toxicity
Proprietary Solvent. Acute LC50 28200 g/l Fresh water Fish – Pimephales promelas 96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Not available.
Date of issue/Date of revision :12/28/2020 Date of previous issue :9/14/2018 Version:2 7/11

BLACK COLORANT B-816B-CZZ
Section 12. Ecological information
Other adverse effects :No known significant effects or critical hazards.
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Empty containers or liners may retain some product residues. Avoid
dispersal of spilled material and runoff and contact with soil, waterways, drains and
sewers.
:Disposal methods
Section 14. Transport information







Not regulated.


Not regulated. Not regulated.
Reportable quantity 29949.1 lbs / 13596.9 kg [1851.5 gal / 7008.7 L]. Package sizes
shipped in quantities less than the product reportable quantity are not subject to the RQ
(reportable quantity) transportation requirements.
Special provisions COLORANT, NOT REGULATED
DOT
Classification
IMDGIATA
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional information
Environmental
hazards
Special precautions for user
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
No. No.No.
Transport within user s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
:Not available.
:
Mexico
Classification
Not regulated.



No.
DOT Classification :
TDG
Classification
Not regulated.



No.
Date of issue/Date of revision :12/28/2020 Date of previous issue :9/14/2018 Version:2 8/11

BLACK COLORANT B-816B-CZZ
Section 15. Regulatory information
U.S. Federal regulations
The following components are listed: Proprietary Solvent.
Clean Water Act (CWA) 307: ethylbenzene
Clean Water Act (CWA) 311: xylene; ethylbenzene; maleic anhydride
Massachusetts
:
:
SARA 313
Product name CAS number %
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
Ethylbenzene
Form R – Reporting
requirements
Supplier notification
California Prop. 65
Clean Air Act Section 112(b)
Hazardous Air Pollutants
(HAPs)
:
Clean Air Act Section 602
Class I Substances
:Not listed
Clean Air Act Section 602
Class II Substances
:Not listed
New York :The following components are listed: Ethylbenzene
New Jersey :The following components are listed: ETHYL BENZENE; BENZENE, ETHYL-
Pennsylvania :The following components are listed: Proprietary Solvent.; BENZENE, ETHYL-
State regulations
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
SARA 302/304
SARA 304 RQ :Not applicable.
No products were found.
Composition/information on ingredients
Inventory list
Australia :Not determined.
Canada :All components are listed or exempted.
China :All components are listed or exempted.
Europe :Not determined.
Japan :Japan inventory (ENCS): All components are listed or exempted.
Japan inventory (ISHL): Not determined.
Republic of Korea :All components are listed or exempted.
Malaysia :Not determined.
New Zealand :All components are listed or exempted.
Philippines :All components are listed or exempted.
SARA 311/312
Classification :Not applicable.
:The following components are listed. For more information go to www.P65Warnings.ca.gov.
ethylbenzene 100-41-4 <= 1.0 ethylbenzene 100-41-4 0.14 Any concentration shown as exact is based on formula. Listed If components are "Listed", and additional information is required, contact Supplier using email in Section 16. Date of issue/Date of revision :12/28/2020 Date of previous issue :9/14/2018 Version:2 9/11 BLACK COLORANT B-816B-CZZ Section 15. Regulatory information Taiwan :All components are listed or exempted. Turkey :Not determined. United States :All components are listed or exempted. Thailand :Not determined. Viet Nam :Not determined. Section 16. Other information 12/28/2020 History Date of printing Date of issue/Date of revision Version Prepared by Date of previous issue : : : : : 12/28/2020 9/14/2018 2 Hazardous Material Information System (U.S.A.) 1 1 0 0 1 1 * National Fire Protection Association (U.S.A.) Health Special Instability/Reactivity Flammability Health Flammability Physical hazards Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service mark of the American Coatings Association, Inc. The customer is responsible for determining the PPE code for this material. For more information on HMIS Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual. Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. Procedure used to derive the classification Classification Justification Not classified. Health, Safety and Environmental Department For questions about the SDS, contact :iasafety@ip-corporation.com New form 08-2018 Date of issue/Date of revision :12/28/2020 Date of previous issue :9/14/2018 Version:2 10/11 BLACK COLORANT B-816B-CZZ Section 16. Other information To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Notice to reader Indicates information that has changed from previously issued version. References : Key to abbreviations :ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations 29 CFR 1910.1200 Hazard Communication Standard, March 2012 CCR Title 27 Division 4 Office of Environmental Health Hazard Assessment (California Prop. 65) American Composites Manufacturers Association Styrene Information and Research Center Date of issue/Date of revision :12/28/2020 Date of previous issue :9/14/2018 Version:2 11/11

40B555OLUUUD_SDS.pdf

GRAY ODD LOT GEL COAT
Unsaturated Polyester Resin Gel Coat
Liquid.
SAFETY DATA SHEET
GHS product identifier
Other means of
identification
Product type
Emergency telephone
number (with hours of
operation)
Section 1. Identification
:
:
:
:
Supplier’s details :INTERPLASTIC CORPORATION
1225 Willow Lake Boulevard
St. Paul, MN 55110-5145
651.481.6860
GRAY ODD LOT GEL COAT
Material uses
Product code :B-555OL-UUU
Product use :Industrial applications.
CHEMTREC 24-Hour Emergency Telephone 800.424.9300
Section 2. Hazards identification
FLAMMABLE LIQUIDS – Category 3
ACUTE TOXICITY: INHALATION – Category 4
SKIN CORROSION/IRRITATION – Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION – Category 2A
CARCINOGENICITY – Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) [Respiratory tract
irritation] – Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): INHALATION
[ears] – Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard statements :Flammable liquid and vapor.
Harmful if inhaled.
Causes serious eye irritation.
Causes skin irritation.
Suspected of causing cancer.
May cause respiratory irritation.
Causes damage to organs through prolonged or repeated exposure if inhaled. (ears)
Hazard pictograms :
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 22.5%
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Date of issue/Date of revision :8/30/2016.Date of previous issue :3/30/2016. Version:4.01 1/15

GRAY ODD LOT GEL COATB-555OL-UUU
Section 2. Hazards identification
Precautionary statements
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Use personal protective equipment as required. Wear
protective gloves. Wear eye or face protection. Keep away from heat, sparks, open
flames and hot surfaces. – No smoking. Use explosion-proof electrical, ventilating,
lighting and all material-handling equipment. Use only non-sparking tools. Take
precautionary measures against static discharge. Keep container tightly closed. Use
only outdoors or in a well-ventilated area. Do not breathe vapor. Do not eat, drink or
smoke when using this product. Wash hands thoroughly after handling.
Response :Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention. IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF
ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water or shower. IF ON SKIN: Wash with plenty of soap and water. Take off
contaminated clothing. If skin irritation occurs: Get medical attention. IF IN EYES:
Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. If eye irritation persists: Get medical attention.
Storage :Store containers in a safe place. Store in a well-ventilated place. Keep cool.
Disposal :Dispose of contents and container in accordance with all local, regional, national and
international regulations. Do not pressurize, cut, weld, braze, solder, drill, grind or
expose containers to heat or sources of ignition.
Hazards not otherwise
classified
:None known.
Section 3. Composition/information on ingredients
styrene <= 36.0 100-42-5 cobalt carboxylate <= 1.0 136-52-7 Ingredient name CAS number% There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Other means of identification :Unsaturated Polyester Resin Gel Coat CAS number :Not applicable. Substance/mixture Product code :B-555OL-UUU CAS number/other identifiers : Occupational exposure limits, if available, are listed in Section 8. Mixture Any concentration shown as a range is to protect confidentiality or is due to batch variation. Any concentration shown as exact is based on formula. See Section 9 for VOC content. See Section 15 for HAP information. Date of issue/Date of revision :8/30/2016.Date of previous issue :3/30/2016. Version:4.01 2/15 GRAY ODD LOT GEL COATB-555OL-UUU Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Description of necessary first aid measures Specific treatments :No specific treatment. Most important symptoms/effects, acute and delayed Inhalation :Harmful if inhaled. May cause respiratory irritation. Irritating to mouth, throat and stomach.:Ingestion Skin contact :Causes skin irritation. Causes serious eye irritation.:Eye contact Over-exposure signs/symptoms Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing No specific data. Adverse symptoms may include the following: irritation redness : : : Eye contact :Adverse symptoms may include the following: pain or irritation watering redness Potential acute health effects Indication of immediate medical attention and special treatment needed, if necessary Date of issue/Date of revision :8/30/2016.Date of previous issue :3/30/2016. Version:4.01 3/15 GRAY ODD LOT GEL COATB-555OL-UUU Section 4. First aid measures Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. See toxicological information (Section 11) Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide metal oxide/oxides Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use dry chemical, CO , water spray (fog) or foam. Extinguishing media : : : Do not use water jet. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures : :No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders:If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Date of issue/Date of revision :8/30/2016.Date of previous issue :3/30/2016. Version:4.01 4/15 GRAY ODD LOT GEL COATB-555OL-UUU Section 6. Accidental release measures Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Do not store above the following temperature: 38 C (100.4 F). Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. : : Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. : Precautions for safe handling Section 8. Exposure controls/personal protection Control parameters Occupational exposure limits Date of issue/Date of revision :8/30/2016.Date of previous issue :3/30/2016. Version:4.01 5/15 GRAY ODD LOT GEL COATB-555OL-UUU Section 8. Exposure controls/personal protection styrene ACGIH TLV (United States, 3/2015). TWA: 20 ppm 8 hours. TWA: 85 mg/m 8 hours. STEL: 40 ppm 15 minutes. STEL: 170 mg/m 15 minutes. OSHA PEL 1989 (United States, 3/1989). TWA: 50 ppm 8 hours. TWA: 215 mg/m 8 hours. STEL: 100 ppm 15 minutes. STEL: 425 mg/m 15 minutes. OSHA PEL Z2 (United States, 2/2013). TWA: 100 ppm 8 hours. CEIL: 200 ppm AMP: 600 ppm 5 minutes. NIOSH REL (United States, 10/2013). TWA: 50 ppm 10 hours. TWA: 215 mg/m 10 hours. STEL: 100 ppm 15 minutes. STEL: 425 mg/m 15 minutes. cobalt bis(2-ethylhexanoate) ACGIH TLV (United States, 3/2015). TWA: 0.02 mg/m , (as Co) 8 hours. Ingredient name Exposure limits Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection : : Environmental exposure controls :Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls :Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Date of issue/Date of revision :8/30/2016.Date of previous issue :3/30/2016. Version:4.01 6/15 GRAY ODD LOT GEL COATB-555OL-UUU Section 8. Exposure controls/personal protection Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Respiratory protection : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Other skin protection :Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Section 9. Physical and chemical properties Physical state Melting point Vapor pressure Relative density Vapor density Liquid. Not available. 1.1 to 1.3 3.6 [Air = 1] 0.57 kPa (4.3 mm Hg) [room temperature] Characteristic. Aromatic. Sweetish.Odor pH Gray.Color Evaporation rate <1 (butyl acetate = 1) Auto-ignition temperature Flash point Not available. Closed cup: 31.1 C (88 F) Not available. Not applicable. Viscosity Not available. 0.1 ppmOdor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : Appearance Boiling point :145.2 C (293.4 F) Lower and upper explosive (flammable) limits :Lower: 1.1% Upper: 6.1% Decomposition temperature:Not available. Solubility in water :Not applicable. VOC content (industrial use)36.4 % (w/w) As shipped. Including monomer. Section 10. Stability and reactivity The product is stable.Chemical stability : Possibility of hazardous reactions :Hazardous reactions or instability may occur under certain conditions of storage or use. Reactivity :No specific test data related to reactivity available for this product or its ingredients. Date of issue/Date of revision :8/30/2016.Date of previous issue :3/30/2016. Version:4.01 7/15 GRAY ODD LOT GEL COATB-555OL-UUU Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas. Under normal conditions of storage and use, hazardous decomposition products should not be produced. Reactive or incompatible with the following materials: oxidizing materials : : Incompatible materials : Reactive or incompatible with the following materials: acids and alkalis. Incompatible with alkali metals. Incompatible with some alkalis. Incompatible with some strong acids. Hazardous polymerization may occur under certain conditions of storage or use. Keep away from heat and direct sunlight. Keep away from heat and flame. Keep away from oxidizing agents. Section 11. Toxicological information Acute toxicity styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours LC50 Inhalation Vapor Rat 11800 mg/m 4 hours LD50 Oral Rat 2650 mg/kg - cobalt bis(2-ethylhexanoate)LD50 Dermal Rabbit >5 g/kg –
LD50 Oral Rat 1.22 g/kg –
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Not available.
Conclusion/Summary :
Mutagenicity
Not available.
Irritation/Corrosion
styrene Eyes – Mild irritant Human – 50 parts per
million

Eyes – Moderate irritantRabbit – 24 hours 100
milligrams

Eyes – Severe irritantRabbit – 100
milligrams

Skin – Mild irritant Rabbit – 500
milligrams

Skin – Moderate irritantRabbit – 100 Percent-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Information on toxicological effects
Date of issue/Date of revision :8/30/2016.Date of previous issue :3/30/2016. Version:4.01 8/15

GRAY ODD LOT GEL COATB-555OL-UUU
Section 11. Toxicological information
Styrene manufacturers have determined that the weight of evidence for the
carcinogenicity of this substance does not meet the criteria for classification.
Styrene is listed by IARC as a possible carcinogen to humans (Group 2B) based on
“limited evidence” in humans, “limited evidence” in animals and “other relevant data”.
The United States NTP listed styrene as reasonably anticipated to be a human
carcinogen based on “limited evidence” from studies in humans, “sufficient evidence”
from studies in experimental animals, and supporting data on mechanisms of
carcinogenesis. The significance of these results for humans has not been established
through risk assessment.
Titanium dioxide manufacturers have determined that the weight of evidence for the
carcinogenicity of this substance does not meet the criteria for classification.
Exposure to respirable particles of this substance from the product as shipped is not
likely. Exposure to respirable dust is possible when cutting, grinding, or sanding a cured
item.
Titanium Dioxide is listed as IARC Group 2B possible carcinogen to humans is based
on “sufficient evidence” in experimental animals and “inadequate evidence” in humans
and respiratory tract exposure to very high concentrations of dust containing titanium
dioxide.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Information on the likely
routes of exposure
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
styrene Category 3 Not applicable.Respiratory tract
irritation
Name Category
Name Category
styrene Category 1 Inhalation ears
Aspiration hazard
Name Result
styrene ASPIRATION HAZARD – Category 1
Route of
exposure
Target organs
Route of
exposure
Target organs
:Not available.
Potential acute health effects
Classification
styrene – 2B Reasonably anticipated to be a human carcinogen.
cobalt bis(2-ethylhexanoate)- 2B –
Product/ingredient name NTPIARCOSHA
Date of issue/Date of revision :8/30/2016.Date of previous issue :3/30/2016. Version:4.01 9/15

GRAY ODD LOT GEL COATB-555OL-UUU
Section 11. Toxicological information
Not available.
Inhalation :Harmful if inhaled. May cause respiratory irritation.
Irritating to mouth, throat and stomach.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
Causes damage to organs through prolonged or repeated exposure if inhaled.General :
Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Oral 5742.1 mg/kg
Inhalation (gases) 6002.1 ppm
Inhalation (vapors) 25.57 mg/l
Route ATE value
Acute toxicity estimates
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
Date of issue/Date of revision :8/30/2016.Date of previous issue :3/30/2016. Version:4.01 10/15

GRAY ODD LOT GEL COATB-555OL-UUU
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Product/ingredient name
styrene 0.35 13.49 low
cobalt bis(2-ethylhexanoate)- 15600 high
Toxicity
styrene Acute EC50 1400 g/l Fresh water Algae – Pseudokirchneriella
subcapitata
72 hours
Acute EC50 720 g/l Fresh water Algae – Pseudokirchneriella
subcapitata
96 hours
Acute EC50 4700 g/l Fresh water Daphnia – Daphnia magna 48 hours
Acute LC50 52000 g/l Marine waterCrustaceans – Artemia salina –
Nauplii
48 hours
Acute LC50 4020 g/l Fresh water Fish – Pimephales promelas 96 hours
Chronic NOEC 63 g/l Fresh water Algae – Pseudokirchneriella
subcapitata
96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Not available.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
Date of issue/Date of revision :8/30/2016.Date of previous issue :3/30/2016. Version:4.01 11/15

GRAY ODD LOT GEL COATB-555OL-UUU
Section 14. Transport information
Special precautions for user
Transport in bulk according
to Annex II of MARPOL
73/78 and the IBC Code
Transport within user s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
:Not available.
:
RESIN
SOLUTION
3
III
RESIN
SOLUTION
3
III
RESIN
SOLUTION
UN1866
3
III
UN1866 UN1866
Reportable
quantity
2795.3 lbs /
1269.1 kg [279.
38 gal / 1057.6
L]
Package sizes
shipped in
quantities less
than the
product
reportable
quantity are
not subject to
the RQ
(reportable
quantity)
transportation
requirements.
– –
DOT
Classification
IMDG IATA
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
No. No. No.
Mexico
Classification
UN1866
RESIN
SOLUTION
3
III
No.

Section 15. Regulatory information
U.S. Federal regulations
Clean Water Act (CWA) 307: Naphthenic acids, copper salts; chloromethane;
chromium; Nickel; ethylbenzene; polychloro copper phthalocyanine
Clean Water Act (CWA) 311: styrene; ethylbenzene; xylene
:TSCA 8(a) PAIR: 4-tert-butylpyrocatechol
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
United States inventory (TSCA 8b): All components are listed or exempted.
Date of issue/Date of revision :8/30/2016.Date of previous issue :3/30/2016. Version:4.01 12/15

GRAY ODD LOT GEL COATB-555OL-UUU
Section 15. Regulatory information
1,4-dihydroxybenzene 0.01 Yes.500 / 10000- 100 –
The following components are listed: STYRENE MONOMER; SOAPSTONE;
PRECIPITATED SILICA
WARNING: This product contains a chemical known to the State of California to cause cancer.
WARNING: This product contains less than 1% of a chemical known to the State of California to cause birth defects or
other reproductive harm.
Massachusetts :
SARA 313
Product name CAS number %
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
styrene 100-42-5 <= 36.0 cobalt bis(2-ethylhexanoate) 136-52-7 <= 1.0 styrene 100-42-5 35.77 cobalt bis(2-ethylhexanoate) 136-52-7 0.23 Form R - Reporting requirements Supplier notification California Prop. 65 Clean Air Act Section 112 (b) Hazardous Air Pollutants (HAPs) : Clean Air Act Section 602 Class I Substances :Not listed Clean Air Act Section 602 Class II Substances :Not listed New York :The following components are listed: Styrene New Jersey :The following components are listed: STYRENE MONOMER; BENZENE, ETHENYL-; SOAPSTONE; COBALT compounds; SILICA, AMORPHOUS, PRECIPITATE & GEL; TITANIUM DIOXIDE; TITANIUM OXIDE (TiO2) Pennsylvania :The following components are listed: BENZENE, ETHENYL-; SOAPSTONE DUST; COBALT COMPOUNDS; PRECIPITATED SILICA; TITANIUM OXIDE (TIO2) State regulations SARA 302/304 SARA 304 RQ :1174553.2 lbs / 533247.2 kg [117390.8 gal / 444372.6 L] Composition/information on ingredients Name % EHS(lbs) (lbs)(gallons) (gallons) SARA 302 TPQ SARA 304 RQ SARA 311/312 Classification :Fire hazard Immediate (acute) health hazard Delayed (chronic) health hazard styrene Date of issue/Date of revision :8/30/2016.Date of previous issue :3/30/2016. Version:4.01 13/15 GRAY ODD LOT GEL COATB-555OL-UUU Section 15. Regulatory information styrene Yes. No. No. No. Talc , not containing asbestiform fibresYes. No. No. No. titanium dioxide Yes. No. No. No. ethanediol No. Yes. No. No. ethylbenzene Yes. No. 41 g/day (ingestion) 54 g/day (inhalation) No. cumene Yes. No. No. No. Nickel Yes. No. No. No. Proprietary Yes. No. No. No. chloromethane No. Yes. No. No. Ingredient name Cancer Reproductive No significant risk level Maximum acceptable dosage level Canada inventory :All components are listed or exempted. Australia inventory (AICS): Not determined. China inventory (IECSC): All components are listed or exempted. Japan inventory: Not determined. Korea inventory: All components are listed or exempted. Malaysia Inventory (EHS Register): Not determined. New Zealand Inventory of Chemicals (NZIoC): Not determined. Philippines inventory (PICCS): Not determined. Taiwan inventory (CSNN): Not determined. International regulations International lists : Section 16. Other information Hazardous Material Information System (U.S.A.) 2 3 1 1 3 2 * National Fire Protection Association (U.S.A.) Health Special Instability/Reactivity Flammability Health Flammability Physical hazards Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS ratings are to be used with a fully implemented HMIS program. HMIS is a registered mark of the National Paint & Coatings Association (NPCA). HMIS materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Date of issue/Date of revision :8/30/2016.Date of previous issue :3/30/2016. Version:4.01 14/15 GRAY ODD LOT GEL COATB-555OL-UUU Section 16. Other information 8/30/2016. History Date of printing Date of issue/Date of revision Version Prepared by To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Notice to reader Date of previous issue : : : : Indicates information that has changed from previously issued version. References :OSHA Hazard Communication Standard, March 2012 (29 CFR 1910.1200) Key to abbreviations :ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations 8/30/2016. 3/30/2016. 4.01 Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. Health, Safety and Environmental Department Email :For questions regarding the SDS contact:iasafety@ip-corporation.com Date of issue/Date of revision :8/30/2016.Date of previous issue :3/30/2016. Version:4.01 15/15

4091401D_SDS.pdf

Gel Coat
Product name
Product type
Section 1. Identification
Chemical family Aromatic.
Relevant identified uses of the substance or mixture and uses advised against
SDS No. NA-1802:4717 (Version: 2.0)
Uses advised against
Identified uses Used in the manufacture of thermoset plastic parts.
No additional information.
G245MC81708
SAFETY DATA SHEET
Date of issue: 08/15/2018
Date of previous issue: 02/08/2018
Emergency telephone number
Supplier’s details
CHEMTREC Within USA and Canada
CHEMTREC Outside USA and Canada
CANUTEC Within Canada
+1 (800) 424-9300
+1 (703) 527-3887
+1 (613) 996-6666
CCN1023
AOC, LLC
955 Highway 57 East
Collierville, TN 38017
Phone Number: (901) 854-2800
Hours: 8AM-5pm (Central Time) Mon-Fri
AOC, LLC
38 Royal Road
Guelpha, Ontario Canada N1H 1G3
Phone Number: (519) 821-5180
Hours: 8am-5pm (Eastern) Mon-Fri
E-Mail: aoc.sds@aoc-resins.com
Website: www.aoc-resins.com
United States: Canada:
Section 2. Hazards identification
OSHA/HCS status
FLAMMABLE LIQUIDS Category 3 H226
SKIN CORROSION/IRRITATION Category 2 H315
SERIOUS EYE DAMAGE/ EYE IRRITATION Category 2 H319
ACUTE TOXICITY (INHALATION) Category 4 H332
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) Category 3 H335
REPRODUCTIVE TOXICITY Category 2 H361d
CARCINOGENICITY Category 2 H351
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) Category 1 H372
ASPIRATION HAZARD Category 1 H304
Classification of the substance or mixture
Signal word
Danger
Hazard statements
H226: Flammable liquid and vapor.
H332: Harmful if inhaled.
H361d: Suspected of damaging the unborn child.
H351: Suspected of causing cancer.
H319: Causes serious eye irritation.
H315: Causes skin irritation.
H335: May cause respiratory irritation.
H372: Causes damage to organs through prolonged or repeated exposure if inhaled.
H304: May be fatal if swallowed and enters airways.
Hazard pictograms
Precautionary statements
GHS label elements
General
This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Page: 1 of 10Date of issue: 08/15/2018 Date of previous issue: 02/08/2018 NA-1802:4717 (Version: 2.0)

G245MC81708
Section 2. Hazards identification
Prevention
P210: Keep away from heat, sparks, open flames and hot surfaces. – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical/ventilating/lighting/material-handling equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P260: Do not breathe vapor or mist.
Response
P370+P378: In case of fire: Use dry chemical, CO , water spray (fog) or foam.
P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P331: Do NOT induce vomiting.
P308+P313: IF exposed or concerned: Get medical advice/attention.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P312: Call a POISON CENTER or physician if you feel unwell.
P303+P361+P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
P332+P313: If skin irritation occurs, get medical advice/attention.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P337+P313: If eye irritation persists, get medical advice/attention.
P308+P311: IF exposed or concerned: Call a POISON CENTER or doctor/physician.
P391: Collect spillage.
Storage
P403 + P235: Store in a well-ventilated place. Keep cool.
P233: Keep container tightly closed.
P405: Store locked up.
Disposal
P501: Dispose of contents and container in accordance with all local, regional, national and international regulations.
P101: If medical advice is needed, have product container or label at hand.
P102: Keep out of reach of children.
Hazards not otherwise classified
None known.
Section 3. Composition/information on ingredients
Ingredient name CAS number %
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are
classified as hazardous to health or the environment and hence require reporting in this section.
Substance/mixture
Occupational exposure limits, if available, are listed in Section 8.
Mixture.
styrene 100-42-5 29.7
Solvent naphtha (petroleum), light arom. 64742-95-6 0.3
Section 4. First aid measures
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Use of buffered baby
shampoo will aid in removal. If irritation persists, get medical attention.
Move the victim to a safe area as soon as possible. Allow the victim to rest in a well-ventilated area. If breathing is difficult, give oxygen.
If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention.
Eye contact
Skin contact
Inhalation
Description of necessary first aid measures
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G245MC81708
Section 4. First aid measures
Wash out mouth with water. Remove dentures if any. Stop if the exposed person feels sick as vomiting may be dangerous. Do not
induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not
enter the lungs. Seek immediate medical attention.
In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. If irritation persists, seek
medical attention. Wash contaminated clothing before reuse. Clean shoes thoroughly before reuse.
Ingestion
Notes to physician
Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.
Most important symptoms/effects, acute and delayed
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Irritating to mouth, throat and stomach.
Causes serious eye irritation.
Causes skin irritation.
Harmful if inhaled. May cause respiratory irritation.
Eye contact
Skin contact
Inhalation
Ingestion
Over-exposure signs/symptoms
Eye contact
Inhalation
Skin contact
Ingestion
Adverse symptoms may include the following: pain or irritation, watering, redness.
Adverse symptoms may include the following: respiratory tract irritation, coughing.
Adverse symptoms may include the following: irritation, redness.
Adverse symptoms may include the following: Irritating to mouth, throat and stomach..
Section 5. Fire-fighting measures
Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.
Hazardous thermal decomposition products
Specific hazards arising from the chemical
Decomposition products may include the following materials: carbon dioxide, carbon monoxide, sulfur oxides halogenated compounds,
metal oxide/oxides
Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a
subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined
areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard. This
material is harmful to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented
from being discharged to any waterway, sewer or drain.
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated
in positive pressure mode.
Special protective equipment for fire-fighters
Use dry chemical, CO , water spray (fog) or foam.
Extinguishing media
Do not use water jet.
Suitable extinguishing media
Unsuitable extinguishing media
Special protective actions for fire-fighters
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G245MC81708
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses,
basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local
regulations (see Section 13). Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor.
Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment
if released in large quantities.
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble,
absorb with an inert dry material and place in an appropriate waste disposal container. Use spark-proof tools and explosion-proof
equipment. Dispose of via a licensed waste disposal contractor.
Methods and materials for containment and cleaning up
For non-emergency personnel
For emergency responders
No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Do not touch or walk
through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist.
Provide adequate ventilation.
If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials.
Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. See also the information in
“For non-emergency personnel”.
Small spill
Large spill
Section 7. Handling and storage
Advice on general occupational hygiene
Conditions for safe storage, including any incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash
hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating
areas. See also Section 8 for additional information on hygiene measures.
Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct
sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all
ignition sources. Segregate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have
been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate
containment to avoid environmental contamination. Refer to the product label and/or technical data sheet for further information.
Protective measures
Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this
material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove
contaminated clothing and protective equipment before entering eating areas. Do not breathe vapor or mist. Do not ingest. Avoid contact
with eyes, skin and clothing. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or
an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks,
open flame or any other ignition source. Use only non-sparking tools. Take precautionary measures against electrostatic discharges.
Empty containers retain product residue and can be hazardous. Do not reuse container.
Precautions for safe handling
Section 8. Exposure controls/personal protection
Control parameters
Occupational exposure limits
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G245MC81708
Section 8. Exposure controls/personal protection
styrene ACGIH TLV (United States, 3/2017). Absorbed through skin.
TWA: 20 ppm 8 hours.
TWA: 85 mg/m 8 hours.
STEL: 40 ppm 15 minutes.
STEL: 170 mg/m 15 minutes.
OSHA PEL Z2 (United States, 2/2013).
TWA: 100 ppm 8 hours.
CEIL: 200 ppm
AMP: 600 ppm 5 minutes.
NIOSH REL (United States, 10/2016).
TWA: 50 ppm 10 hours.
TWA: 215 mg/m 10 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
Ingredient name Exposure limits
Hand protection
Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is
necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working
limits of the selected respirator.
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products
if a risk assessment indicates this is necessary.
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid
exposure to liquid splashes, mists or dusts.
Eye/face protection
Respiratory protection
Body protection
Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Appropriate engineering controls
Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker
exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or
dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end
of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Ensure that eyewash stations
and safety showers are close to the workstation location.
Hygiene measures
Individual protection measures
Other skin protection
Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks
involved and should be approved by a specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Vapor density
Liquid.
23.8 F / 30.6 C (Styrene)
3.6 (Air = 1) (Styrene )
5.0 mm Hg@ 68 F / 20 C (Styrene)
Aromatic.Odor
pH
White.Color
Evaporation rate < 1 (Butyl acetate = 1) Flash point 88 F / 31 C (Styrene) Not applicable. 0.01 - 0.1 ppm (Styrene)Odor threshold Appearance Boiling point 293 F / 145 C (Styrene) Flammability (solid, gas) Not applicable. Lower and upper explosive (flammable) limits Lower: 1.1% Upper: 6.1% (Styrene) Page: 5 of 10Date of issue: 08/15/2018 Date of previous issue: 02/08/2018 NA-1802:4717 (Version: 2.0) G245MC81708 Section 9. Physical and chemical properties Relative density Solubility 1.1 to 1.4 (Water = 1) Slight. Auto-ignition temperature 914 F / 490 C (Styrene) Not available. Viscosity Not available. Partition coefficient: n-octanol/water Molecular weight Not available. Decomposition temperature Not available. Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable. Stable under recommended storage and handling conditions (see Section 7). Chemical stability Reactive or incompatible with the following materials: oxidizing materials Incompatible materials Possibility of hazardous reactions Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity No specific test data related to reactivity available for this product or its ingredients. Section 11. Toxicological information Acute toxicity styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours LC50 Inhalation Vapor Rat 11800 mg/m 4 hours LC50 Inhalation Vapor Rat 5634.2 ppm 4 hours LD50 Oral Rat 2650 mg/kg - Solvent naphtha (petroleum), light arom. LD50 Oral Rat 8400 mg/kg - Ingredient name Result Species Dose Exposure Carcinogenicity Irritation/Corrosion styrene Eyes - Mild irritant Human - 50 parts per million - Eyes - Moderate irritant Rabbit - 24 hours 100 milligrams - Eyes - Severe irritant Rabbit - 100 milligrams- Skin - Mild irritant Rabbit - 500 milligrams- Skin - Moderate irritant Rabbit - 100 Percent - Solvent naphtha (petroleum), light arom. Eyes - Mild irritant Rabbit - 24 hours 100 microliters - Ingredient name Result Score Exposure Observation Sensitization Species Information on toxicological effects Classification styrene - 2A Reasonably anticipated to be a human carcinogen. Ingredient name NTPIARCACGIH May cause sensitization by skin contact. Page: 6 of 10Date of issue: 08/15/2018 Date of previous issue: 02/08/2018 NA-1802:4717 (Version: 2.0) G245MC81708 Section 11. Toxicological information Mutagenicity Teratogenicity Reproductive toxicity Inhalation Harmful if inhaled. May cause respiratory irritation. Irritating to mouth, throat and stomach. Ingestion Skin contact Causes skin irritation. Causes serious eye irritation. Eye contact Symptoms related to the physical, chemical and toxicological characteristics Skin contact Ingestion Adverse symptoms may include the following: respiratory tract irritation, coughing. Adverse symptoms may include the following: Irritating to mouth, throat and stomach.. Adverse symptoms may include the following: irritation, redness. Eye contact Adverse symptoms may include the following: pain or irritation, watering, redness. Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Potential acute health effects No mutagenic effect. 1) Negative Study A published study concluded that the mechanism for producing cancer in mice exposed to styrene is not applicable in human metabolism. (June 2013 Pharmacology & Toxicology 66 (2013)) 2) Negative Study A recent update to an extensive study of reinforced plastic workers from 1948-1977 concluded that there was no coherent evidence that styrene exposure increased risk of cancer (March 2013 Epidemiology Vol. 24 Issue 2) 3) Positive Study Styrene induced pulmonary toxicity and carcinogenicity in mice was shown to be caused by a metabolite of styrene, probably styrene oxide. (Dec.2001 Toxicology Vol.169 Issue 2) Not considered to be toxic to the reproductive system. No known effect according to our database. No known effect according to our database. A study of long term effects of workers exposed to styrene levels in the range of 25-35 ppm, 8 hour TWA, indicated a possible mild hearing loss. No known effect according to our database. Inhalation Section 12. Ecological information Bioaccumulative potential Toxicity styrene Acute EC50 1400 g/l Fresh water Algae - Pseudokirchneriella subcapitata 72 hours Acute EC50 720 g/l Fresh water Algae - Pseudokirchneriella subcapitata 96 hours Acute EC50 4700 g/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 52 mg/l Marine water Crustaceans - Artemia salina 48 hours Acute LC50 4020 g/l Fresh water Fish - Pimephales promelas 96 hours Chronic NOEC 63 g/l Fresh water Algae - Pseudokirchneriella subcapitata 96 hours Ingredient name SpeciesResult Exposure Persistence and degradability Not available. Page: 7 of 10Date of issue: 08/15/2018 Date of previous issue: 02/08/2018 NA-1802:4717 (Version: 2.0) G245MC81708 Section 12. Ecological information LogPow BCF Potential Other adverse effects No known effect according to our database. styrene 0.35 13.49 low Solvent naphtha (petroleum), light arom. - 10 to 2500 high Soil/water partition coefficient (KOC) Not available. Mobility in soil Ingredient name Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some product residues. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by- products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Avoid disposal. Attempt to use product completely in accordance with intended use. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. Disposal methods The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for any available use-specific information provided in the Exposure Scenario(s). Special precautions This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Section 14. Transport information Resin Solution 3 III UN1866UN number Proper shipping name Transport hazard class(es) Packing group DOT / TDG/ IMDG/IMO / ICAO/IATA and National regulations. Additional information US regulations require the reporting of spills when the amount exceeds the Reportable Quantity (RQ) for specific components of this material. See CERCLA in Section 15, Regulatory Information, for the Reportable Quantities. Environmental hazards Marine pollutant: No. Special precautions for user Transport within user s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. IMDGEmergency schedules (EmS): F-E, S-E Remarks: FP-31 C IATANo additional information. Section 15. Regulatory information International regulations lists All components are listed or exempted.United States inventory (TSCA 8b) Australia (AICS) All components are listed or exempted. Canada (DSL) At least one component is not listed in DSL but all such components are listed in NDSL. China (IECSC) All components are listed or exempted. Europe (EINECS) Not determined. New Zealand (NZIoC) All components are listed or exempted. Philippines (PICCS) All components are listed or exempted. Page: 8 of 10Date of issue: 08/15/2018 Date of previous issue: 02/08/2018 NA-1802:4717 (Version: 2.0) G245MC81708 Section 15. Regulatory information SARA 313 Ingredient name styrene 100-42-5 Form R - Reporting requirements SARA 311/312 Japan Japan inventory (ENCS): Not determined. Japan inventory (ISHL): Not determined. Republic of Korea (KECI) All components are listed or exempted. Malaysia (EHS Register) Not determined. Taiwan (CSNN) All components are listed or exempted. CAS number California Prop. 65 State regulations styrene - 1000 lbs. (453.6 kg)CERCLA RQ - WARNING: This product can expose you to chemicals including Styrene, Titanium dioxide, which are known to the State of California to cause cancer, and Methanol, which is known to the State of California to cause birth defects or other reproductive harm. For more information go to www.P65Warnings.ca.gov. Per the June 13, 2016 Federal Register notice, EPA harmonized the EPCRA 311/312 hazard categories with the 2012 OSHA hazard communication standard for classifying and labeling of chemicals (i.e. GHS). Please refer to Section 2 of the SDS to identify the appropriate hazard categories for reporting purposes. U.S. Federal regulations Section 16. Other information History Version Prepared by Notice to reader Date of previous issue Indicates information that has changed from previously issued version. Key to abbreviations ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations 08/15/2018 02/08/2018 2.0 National Fire Protection Association (U.S.A.) Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. AOC Corporate Regulatory Affairs 1 3 2 Health Special Instability Flammability Date of issue Page: 9 of 10Date of issue: 08/15/2018 Date of previous issue: 02/08/2018 NA-1802:4717 (Version: 2.0) G245MC81708 Section 16. Other information The information contained in this data sheet is furnished in good faith and without warranty, representation, or inducement or license of any kind, except that it is accurate to the best of AOC, LLC's knowledge, or was obtained from sources believed by AOC, LLC to be reliable. The accuracy, adequacy or completeness of health and safety precautions set forth herein cannot be guaranteed, and the buyer is solely responsible for ensuring that the product is used, handled, stored, and disposed of safely and in compliance with applicable federal, state or provincial, and local laws. AOC, LLC disclaims liability for any loss, damage or personal injury that arises from, or is in any way related to, use of the information contained in this data sheet. This Safety Data Sheet (SDS) and its content are the confidential and proprietary information of AOC and it may not be modified, altered, deconstructed, or presented in any other manner, without the explicit authorization of AOC and/or its legal counsel. Page: 10 of 10Date of issue: 08/15/2018 Date of previous issue: 02/08/2018 NA-1802:4717 (Version: 2.0)

4091400D_SDS.pdf

Gel Coat
Product name
Product type
Emergency telephone number
Section 1. Identification
Chemical family Aromatic.
Supplier’s details AOC, LLC
955 Highway 57 East
Collierville, TN 38017
E-Mail: aoc.sds@aoc-resins.com
Website: www.aoc-resins.com
Phone Number: (901) 854-2800
Hours: 8AM-5pm (Central Time) Monday-Friday
Relevant identified uses of the substance or mixture and uses advised against
SDS No. NA1504:1232 (Version: 2.0)
Uses advised against
Identified uses Used in the manufacture of thermoset plastic parts.
No additional information.
G130LN81525
CHEMTREC Within USA and Canada
CHEMTREC Outside USA and Canada
CANUTEC Within Canada
+1 (800) 424-9300
+1 (703) 527-3887
+1 (613) 996-6666
CCN1023
SAFETY DATA SHEET
Date of issue: 02/01/2017
Date of previous issue: 05/26/2015
Section 2. Hazards identification
OSHA/HCS status
FLAMMABLE LIQUIDS Category 3 H226
SKIN CORROSION/IRRITATION Category 2 H315
SERIOUS EYE DAMAGE/ EYE IRRITATION Category 2 H319
ACUTE TOXICITY (INHALATION) Category 4 H332
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) Category 3 H335
REPRODUCTIVE TOXICITY Category 2 H361d
CARCINOGENICITY Category 2 H351
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) Category 1 H372
ASPIRATION HAZARD Category 1 H304
Classification of the substance or mixture
Signal word
Danger
Hazard statements
H226: Flammable liquid and vapor.
H332: Harmful if inhaled.
H361d: Suspected of damaging the unborn child.
H351: Suspected of causing cancer.
H319: Causes serious eye irritation.
H315: Causes skin irritation.
H335: May cause respiratory irritation.
H372: Causes damage to organs through prolonged or repeated exposure if inhaled.
H304: May be fatal if swallowed and enters airways.
Hazard pictograms
GHS label elements
This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Page: 1 of 10G130LN81525

Section 2. Hazards identification
Precautionary statements
Prevention
P210: Keep away from heat, sparks, open flames and hot surfaces. – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical/ventilating/lighting/material-handling equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P260: Do not breathe vapor or mist.
Response
P370+P378: In case of fire: Use dry chemical, CO , water spray (fog) or foam.
P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P331: Do NOT induce vomiting.
P308+P313: IF exposed or concerned: Get medical advice/attention.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P312: Call a POISON CENTER or physician if you feel unwell.
P303+P361+P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
P332+P313: If skin irritation occurs, get medical advice/attention.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing.
P337+P313: If eye irritation persists, get medical advice/attention.
P308+P311: IF exposed or concerned: Call a POISON CENTER or doctor/physician.
P391: Collect spillage.
Storage
P403 + P235: Store in a well-ventilated place. Keep cool.
P233: Keep container tightly closed.
P405: Store locked up.
Disposal
P501: Dispose of contents and container in accordance with all local, regional, national and international regulations.
General
P101: If medical advice is needed, have product container or label at hand.
P102: Keep out of reach of children.
Hazards not otherwise classified
None known.
Section 3. Composition/information on ingredients
Ingredient name CAS number %
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are
classified as hazardous to health or the environment and hence require reporting in this section.
Substance/mixture :
Occupational exposure limits, if available, are listed in Section 8.
Mixture.
Styrene 100-42-5 29.4
Petroleum Naphtha 64742-95-6 0.3
Cobalt 2-Ethylhexanoate 136-52-7 0.3
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Use of
buffered baby shampoo will aid in removal. If irritation persists, get medical attention.
Move the victim to a safe area as soon as possible. Allow the victim to rest in a well-ventilated area. If breathing is difficult, give
oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention.
Section 4. First aid measures
Eye contact
Inhalation
Description of necessary first aid measures
Page: 2 of 10G130LN81525

Section 4. First aid measures
Wash out mouth with water. Remove dentures if any. Stop if the exposed person feels sick as vomiting may be dangerous. Do
not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit
does not enter the lungs. Seek immediate medical attention.
In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. If irritation persists,
seek medical attention. Wash contaminated clothing before reuse. Clean shoes thoroughly before reuse.
Skin contact
Ingestion
Notes to physician
Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.
Most important symptoms/effects, acute and delayed
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Irritating to mouth, throat and stomach.
Causes serious eye irritation.
Causes skin irritation.
Harmful if inhaled. May cause respiratory irritation.
Eye contact
Skin contact
Inhalation
Ingestion
Over-exposure signs/symptoms
Eye contact
Inhalation
Skin contact
Ingestion
Adverse symptoms may include the following: pain or irritation, watering, redness.
Adverse symptoms may include the following: respiratory tract irritation, coughing.
Adverse symptoms may include the following: irritation, redness.
Adverse symptoms may include the following: Irritating to mouth, throat and stomach..
Section 5. Fire-fighting measures
Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or
drain.
Hazardous thermal decomposition products
Specific hazards arising from the chemical
Decomposition products may include the following materials: carbon dioxide, carbon monoxide, sulfur oxides halogenated
compounds, metal oxide/oxides
Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a
subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or
confined areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or
explosion hazard. This material is harmful to aquatic life with long lasting effects. Fire water contaminated with this material must
be contained and prevented from being discharged to any waterway, sewer or drain.
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece
operated in positive pressure mode.
Special protective equipment for fire-fighters
Use dry chemical, CO , water spray (fog) or foam.
Extinguishing media
Do not use water jet.
Suitable extinguishing media
Unsuitable extinguishing media
Special protective actions for fire-fighters
Page: 3 of 10G130LN81525

Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water
courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and
collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Use spark-proof tools and explosion-proof equipment.
Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled
product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities
if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to
the environment if released in large quantities.
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-
insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Use spark-proof tools and
explosion-proof equipment. Dispose of via a licensed waste disposal contractor.
Methods and materials for containment and cleaning up
For non-emergency personnel
For emergency responders
No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Do not touch or
walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or
mist. Provide adequate ventilation.
If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable
materials. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. See
also the information in “For non-emergency personnel”.
Small spill
Large spill
Section 7. Handling and storage
Advice on general occupational hygiene
Conditions for safe storage, including any incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers
should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment
before entering eating areas. See also Section 8 for additional information on hygiene measures.
Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from
direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink.
Eliminate all ignition sources. Segregate from oxidizing materials. Keep container tightly closed and sealed until ready for use.
Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled
containers. Use appropriate containment to avoid environmental contamination. Refer to the product label and/or technical data
sheet for further information.
Protective measures
Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas
where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking.
Remove contaminated clothing and protective equipment before entering eating areas. Do not breathe vapor or mist. Do not
ingest. Avoid contact with eyes, skin and clothing. Avoid release to the environment. Use only with adequate ventilation. Wear
appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately
ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when
not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical
(ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against
electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container.
Precautions for safe handling
Section 8. Exposure controls/personal protection
Control parameters
Occupational exposure limits
Page: 4 of 10G130LN81525

Section 8. Exposure controls/personal protection
Styrene ACGIH TLV (United States, 3/2015).
TWA: 20 ppm 8 hours.
TWA: 85 mg/m 8 hours.
STEL: 40 ppm 15 minutes.
STEL: 170 mg/m 15 minutes.
OSHA PEL Z2 (United States, 2/2013).
TWA: 100 ppm 8 hours.
CEIL: 200 ppm
AMP: 600 ppm 5 minutes.
NIOSH REL (United States, 10/2013).
TWA: 50 ppm 10 hours.
TWA: 215 mg/m 10 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
Cobalt 2-Ethylhexanoate OSHA PEL (United States).
TWA: 0.1 mg/m
ACGIH TLV (United States, 3/2015).
TWA: 0.02 mg/m , (as Co) 8 hours.
Ingredient name Exposure limits
Hand protection
Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is
necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical
products if a risk assessment indicates this is necessary.
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid
exposure to liquid splashes, mists or dusts.
Eye/face protection
Respiratory protection
Body protection
Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should
be approved by a specialist before handling this product.
Appropriate engineering controls
Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep
worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need
to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at
the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Ensure that
eyewash stations and safety showers are close to the workstation location.
Hygiene measures
Individual protection measures
Other skin protection
Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the
risks involved and should be approved by a specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Liquid.
-23.8 F / -30.6 C (Styrene)
5.0 mm Hg@ 68 F / 20 C (Styrene)
Aromatic.Odor
pH
White.Color
Evaporation rate < 1 (Butyl acetate = 1) Flash point 88 F / 31 C (Styrene) Not applicable. 0.01 - 0.1 ppm (Styrene)Odor threshold Appearance Boiling point 293 F / 145 C (Styrene) Flammability (solid, gas) Not applicable. Lower and upper explosive (flammable) limits Lower: 1.1% Upper: 6.1% (Styrene) Page: 5 of 10G130LN81525 Section 9. Physical and chemical properties Relative density Vapor density Solubility 1.1 to 1.4 (Water = 1) 3.6 (Air = 1) (Styrene ) Slight. Auto-ignition temperature 914 F / 490 C (Styrene) Not available. Viscosity Not available. Partition coefficient: n-octanol/water Molecular weight Not available. Decomposition temperature Not available. Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable. Stable under recommended storage and handling conditions (see Section 7). Chemical stability Reactive or incompatible with the following materials: oxidizing materials Incompatible materials Possibility of hazardous reactions Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity No specific test data related to reactivity available for this product or its ingredients. Section 11. Toxicological information Acute toxicity Styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours LC50 Inhalation Vapor Rat 11800 mg/m 4 hours LD50 Oral Rat 2650 mg/kg - Petroleum Naphtha LD50 Oral Rat 8400 mg/kg - Cobalt 2-Ethylhexanoate LD50 Dermal Rabbit >5 g/kg –
LD50 Oral Rat 1.22 g/kg –
LD50 Oral Rat 6171 mg/kg –
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Irritation/Corrosion
Styrene Eyes – Mild irritant Human – 50 parts per
million

Eyes – Moderate irritant Rabbit – 24 hours 100
milligrams

Eyes – Severe irritant Rabbit – 100 milligrams-
Skin – Mild irritant Rabbit – 500 milligrams-
Skin – Moderate irritant Rabbit – 100 Percent –
Product/ingredient name Result Score Exposure Observation
Sensitization
Species
Information on toxicological effects
Classification
Styrene – 2B Reasonably anticipated to be a human carcinogen.
Cobalt 2-Ethylhexanoate – 2B –
Product/ingredient name NTPIARCACGIH
May cause sensitization by skin contact.
Page: 6 of 10G130LN81525

Section 11. Toxicological information
Mutagenicity
Teratogenicity
Reproductive toxicity
Inhalation
Harmful if inhaled. May cause respiratory irritation.
Irritating to mouth, throat and stomach.
Ingestion
Skin contact
Causes skin irritation.
Causes serious eye irritation.
Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Adverse symptoms may include the following: respiratory tract irritation, coughing.
Adverse symptoms may include the following: Irritating to mouth, throat and stomach..
Adverse symptoms may include the following: irritation, redness.
Eye contact
Adverse symptoms may include the following: pain or irritation, watering, redness.
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Aspiration hazard
Potential acute health effects
No mutagenic effect.
1) Negative Study A published study concluded that the mechanism for producing cancer in mice exposed to styrene
is not applicable in human metabolism. (June 2013 Pharmacology & Toxicology 66 (2013))
2) Negative Study A recent update to an extensive study of reinforced plastic workers from 1948-1977 concluded that
there was no coherent evidence that styrene exposure increased risk of cancer (March 2013 Epidemiology Vol. 24
Issue 2)
3) Positive Study Styrene induced pulmonary toxicity and carcinogenicity in mice was shown to be caused by a
metabolite of styrene, probably styrene oxide. (Dec.2001 Toxicology Vol.169 Issue 2)
Not considered to be toxic to the reproductive system.
No known effect according to our database..
No known effect according to our database.
A study of long term effects of workers exposed to styrene levels in the range of 25-35 ppm, 8 hour TWA, indicated a
possible mild hearing loss.
No known effect according to our database.
Inhalation
Section 12. Ecological information
Bioaccumulative potential
Product/ingredient name Aquatic half-life Photolysis Biodegradability
Styrene – – Readily
Toxicity
Styrene Acute EC50 4.7 mg/l Fresh water Daphnia – Daphnia magna 48 hours
Acute LC50 4.02 mg/l Fresh water Fish – Pimephales promelas 96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Styrene EU 100 % – Readily – 1 days – –
Product/ingredient name Test DoseResult Inoculum
Page: 7 of 10G130LN81525

Section 12. Ecological information
LogPow BCF Potential
Other adverse effects
No known effect according to our database.
Product/ingredient name
Styrene 2.95 13.49 low
Soil/water partition coefficient (KOC)
Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of
this product, solutions and any by-products should at all times comply with the requirements of environmental protection
and waste disposal legislation and any regional local authority requirements. Avoid disposal. Attempt to use product
completely in accordance with intended use. Waste packaging should be recycled. Incineration or landfill should only be
considered when recycling is not feasible.
Disposal methods
The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for any available use-specific information
provided in the Exposure Scenario(s).
Special precautions
This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers
that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Do not cut, weld
or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff
and contact with soil, waterways, drains and sewers.
Section 14. Transport information
Resin Solution
3
III
UN1866UN number
Proper shipping name
Transport hazard class(es)
Packing group
DOT / TDG/ IMDG/IMO / ICAO/IATA and National regulations.
Additional information US regulations require the reporting of spills when the amount exceeds the Reportable
Quantity (RQ) for specific components of this material. See CERCLA in Section 15,
Regulatory Information, for the Reportable Quantities.
Environmental hazards Marine pollutant: No.
Special precautions for user Transport within user s premises: always transport in closed containers that are upright
and secure. Ensure that persons transporting the product know what to do in the event of
an accident or spillage.
IMDGEmergency schedules (EmS): F-E, S-E
Remarks: FP-31 C
IATANo additional information.
Section 15. Regulatory information
Inventories (National and International)
:All components are listed or exempted.United States inventory (TSCA 8b)
Australia (AICS) :Not determined.
Canada (DSL) :At least one component is not listed in DSL but all such components are listed in NDSL.
China (IECSC) :All components are listed or exempted.
Europe (EINECS) :Not determined.
New Zealand (NZIoC) :Not determined.
Philippines (PICCS) :Not determined.
Page: 8 of 10G130LN81525

Section 15. Regulatory information
SARA 313
Product name
Styrene 100-42-5
Cobalt 2-Ethylhexanoate 136-52-7
Form R – Reporting
requirements
SARA 311/312
Styrene Yes. No. No. No. Yes.
Petroleum Naphtha Yes. No. No. Yes. Yes.
Cobalt 2-Ethylhexanoate No. No. No. Yes. Yes.
Name Fire
hazard
Sudden
release of
pressure
Reactive Immediate
(acute)
health hazard
Delayed
(chronic)
health hazard
Composition/information on ingredients
Japan (ENCS) :Japan inventory (ENCS): Not determined.
Japan inventory (ISHL): Not determined.
Republic of Korea (KECI) :Not determined.
Malaysia (EHS Register) :Not determined.
Taiwan (CSNN) :Not determined.
CAS number
WARNING: This product contains a chemical known to the State of California to cause cancer.
WARNING: This product contains less than 1% of a chemical known to the State of California to cause birth defects or other reproductive
harm.
California Prop. 65
State regulations
Styrene – 1000 lbs. (453.6 kg)CERCLA RQ –
Section 16. Other information
History
Date of issue
Version
Notice to reader
Date of previous issue
:
:
:
Indicates information that has changed from previously issued version.
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by
the Protocol of 1978. (“Marpol” = marine pollution)
UN = United Nations
02/01/2017
05/26/2015
2.0
1
3
2
National Fire Protection Association (U.S.A.)
Health
Special
Instability/Reactivity
Flammability
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This
reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety.
Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and
reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only.
Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk.
AOC Corporate Regulatory Affairs
Page: 9 of 10G130LN81525

Section 16. Other information
The information contained in this data sheet is furnished in good faith and without warranty, representation, or inducement or license of any kind,
except that it is accurate to the best of AOC, LLC’s knowledge, or was obtained from sources believed by AOC, LLC to be reliable. The
accuracy, adequacy or completeness of health and safety precautions set forth herein cannot be guaranteed, and the buyer is solely
responsible for ensuring that the product is used, handled, stored, and disposed of safely and in compliance with applicable federal, state or
provincial, and local laws. AOC, LLC disclaims liability for any loss, damage or personal injury that arises from, or is in any way related to, use
of the information contained in this data sheet.
This Safety Data Sheet (SDS) and its content are the confidential and proprietary information of AOC and it may not be modified, altered,
deconstructed, or presented in any other manner, without the explicit authorization of AOC and/or its legal counsel.
Page: 10 of 10G130LN81525

4090705F_SDS.pdf

Gel Coat
Product name
Product type
Section 1. Identification
Chemical family Aromatic.
Relevant identified uses of the substance or mixture and uses advised against
SDS No. NA-1809:5336 (Version: 3.0)
Uses advised against
Identified uses Used in the manufacture of thermoset plastic parts.
No additional information.
G725AA70812
SAFETY DATA SHEET
Date of issue: 04/15/2022
Date of previous issue: 03/01/2020
Emergency telephone number
Supplier’s details
CHEMTREC Within USA and Canada
CHEMTREC Outside USA and Canada
CANUTEC Within Canada
+1 (800) 424-9300
+1 (703) 527-3887
+1 (613) 996-6666
CCN1023
AOC
955 Highway 57 East
Collierville, TN 38017
Phone Number: (901) 854-2800
Hours: 8AM-5pm (Central Time) Mon-Fri
AOC
38 Royal Road
Guelph, Ontario Canada N1H 1G3
Phone Number: (519) 821-5180
Hours: 8am-5pm (Eastern) Mon-Fri
E-Mail: aoc.sds@aocresins.com
Website: www.aocresins.com
United States: Canada:
Section 2. Hazards identification
OSHA/HCS status
FLAMMABLE LIQUIDS Category 3 H226
ACUTE TOXICITY (Inhalation) Category 4 H332
SKIN IRRITATION Category 2 H315
EYE IRRITATION Category 2A H319
CARCINOGENICITY Category 2 H351
REPRODUCTIVE TOXICITY Category 2 H361d
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) Category 3 H335
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) Category 1 H372
ASPIRATION HAZARD Category 1 H304
Classification of the substance or mixture
Signal word
Danger
Hazard statements
H226: Flammable liquid and vapor.
H332: Harmful if inhaled.
H319: Causes serious eye irritation.
H315: Causes skin irritation.
H361d: Suspected of damaging the unborn child.
H351: Suspected of causing cancer.
H304: May be fatal if swallowed and enters airways.
H335: May cause respiratory irritation.
H372: Causes damage to organs through prolonged or repeated exposure. (hearing organs, kidneys)
Hazard pictograms
Precautionary statements
GHS label elements
General
This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
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Section 2. Hazards identification
Prevention
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P210: Keep away from heat, sparks and hot surfaces. – No smoking.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical/ventilating/lighting/material-handling equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P233: Keep container tightly closed.
P271: Use only outdoors or in a well-ventilated area.
P260: Do not breathe vapor or mist.
P270: Do not eat, drink or smoke when using this product.
P264: Wash hands thoroughly after handling.
Response
P314: Get medical attention if you feel unwell.
P308+P313: IF exposed or concerned: Get medical attention.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P312: Call a POISON CENTER or physician if you feel unwell.
P370+P378: In case of fire: Use dry chemical, CO , water spray (fog) or foam.
P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P331: Do NOT induce vomiting.
P308+P313: IF exposed or concerned: Get medical advice/attention.
P303+P361+P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
P362+P364: Take off contaminated clothing and wash it before reuse.
P332+P313: If skin irritation occurs: Get medical attention.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
P337+P313: If eye irritation persists: Get medical attention.
P391: Collect spillage.
Storage
P405: Store locked up.
P403+P235: Store in a well-ventilated place. Keep cool.
P233: Keep container tightly closed.
Disposal
P501: Dispose of contents and container in accordance with all local, regional, national and international regulations.
P101: If medical advice is needed, have product container or label at hand.
P102: Keep out of reach of children.
Hazards not otherwise classified
None known.
Section 3. Composition/information on ingredients
Ingredient name CAS number %
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are
classified as hazardous to health or the environment and hence require reporting in this section.
Substance/mixture
Occupational exposure limits, if available, are listed in Section 8.
Mixture.
styrene 100-42-5 20.9
methyl methacrylate 80-62-6 17.7
cobalt bis(2-ethylhexanoate) 136-52-7 0.3
Solvent naphtha (petroleum), light arom. 64742-95-6 0.3
Section 4. First aid measures
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Use of buffered baby
shampoo will aid in removal. If irritation persists, get medical attention.
Move the victim to a safe area as soon as possible. Allow the victim to rest in a well-ventilated area. If breathing is difficult, give oxygen.
If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention.
Eye contact
Skin contact
Inhalation
Description of necessary first aid measures
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Section 4. First aid measures
Wash out mouth with water. Remove dentures if any. Stop if the exposed person feels sick as vomiting may be dangerous. Do not
induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not
enter the lungs. Seek immediate medical attention.
In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. If irritation persists, seek
medical attention. Wash contaminated clothing before reuse. Clean shoes thoroughly before reuse.
Ingestion
Notes to physician
Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.
Most important symptoms/effects, acute and delayed
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Irritating to mouth, throat and stomach.
Causes serious eye irritation.
Causes skin irritation.
Harmful if inhaled. May cause respiratory irritation. May cause drowsiness or dizziness.
Eye contact
Skin contact
Inhalation
Ingestion
Over-exposure signs/symptoms
Eye contact
Inhalation
Skin contact
Ingestion
Adverse symptoms may include the following: pain or irritation, watering, redness.
Adverse symptoms may include the following: respiratory tract irritation, coughing.
Adverse symptoms may include the following: irritation, redness.
Adverse symptoms may include the following: Irritating to mouth, throat and stomach.
Section 5. Fire-fighting measures
Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.
Hazardous thermal decomposition products
Specific hazards arising from the chemical
Decomposition products may include the following materials: carbon dioxide
Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a
subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined
areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard. This
material is harmful to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented
from being discharged to any waterway, sewer or drain.
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated
in positive pressure mode.
Special protective equipment for fire-fighters
Use dry chemical, CO , water spray (fog) or foam.
Extinguishing media
Do not use water jet.
Suitable extinguishing media
Unsuitable extinguishing media
Special protective actions for fire-fighters
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Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses,
basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local
regulations (see Section 13). Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor.
Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment
if released in large quantities.
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble,
absorb with an inert dry material and place in an appropriate waste disposal container. Use spark-proof tools and explosion-proof
equipment. Dispose of via a licensed waste disposal contractor.
Methods and materials for containment and cleaning up
For non-emergency personnel
For emergency responders
No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Do not touch or walk
through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist.
Provide adequate ventilation.
If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials.
Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. See also the information in
“For non-emergency personnel”.
Small spill
Large spill
Section 7. Handling and storage
Advice on general occupational hygiene
Conditions for safe storage, including any incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash
hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating
areas. See also Section 8 for additional information on hygiene measures.
Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct
sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all
ignition sources. Segregate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have
been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate
containment to avoid environmental contamination. Refer to the product label and/or technical data sheet for further information.
Protective measures
Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this
material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove
contaminated clothing and protective equipment before entering eating areas. Do not breathe vapor or mist. Do not ingest. Avoid contact
with eyes, skin and clothing. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or
an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks,
open flame or any other ignition source. Use only non-sparking tools. Take precautionary measures against electrostatic discharges.
Empty containers retain product residue and can be hazardous. Do not reuse container.
Precautions for safe handling
styrene ACGIH TLV (United States, 1/2021). Ototoxicant.
TWA: 10 ppm 8 hours.
STEL: 20 ppm 15 minutes.
OSHA PEL Z2 (United States, 2/2013).
TWA: 100 ppm 8 hours.
CEIL: 200 ppm
AMP: 600 ppm 5 minutes.
NIOSH REL (United States, 10/2020).
TWA: 50 ppm 10 hours.
TWA: 215 mg/m 10 hours.
STEL: 100 ppm 15 minutes.
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
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Section 8. Exposure controls/personal protection
STEL: 425 mg/m 15 minutes.
methyl methacrylate ACGIH TLV (United States, 1/2021). Skin sensitizer.
TWA: 50 ppm 8 hours.
STEL: 100 ppm 15 minutes.
NIOSH REL (United States, 10/2020).
TWA: 100 ppm 10 hours.
TWA: 410 mg/m 10 hours.
OSHA PEL (United States, 5/2018).
TWA: 100 ppm 8 hours.
TWA: 410 mg/m 8 hours.
ACGIH TLV (United States, 3/2012). Skin sensitizer.
STEL: 410 mg/m 8 hours.
TWA: 205 mg/m 8 hours.
cobalt bis(2-ethylhexanoate) OSHA PEL (United States).
TWA: 0.1 mg/m
ACGIH TLV (United States, 1/2021). Skin sensitizer. Inhalation
sensitizer.
TWA: 0.02 mg/m , (as Co) 8 hours.
Hand protection
Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is
necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working
limits of the selected respirator.
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products
if a risk assessment indicates this is necessary.
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid
exposure to liquid splashes, mists or dusts.
Eye/face protection
Respiratory protection
Body protection
Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Appropriate engineering controls
Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker
exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or
dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end
of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Ensure that eyewash stations
and safety showers are close to the workstation location.
Hygiene measures
Individual protection measures
Other skin protection
Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks
involved and should be approved by a specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Liquid.
23.8 F / 30.6 C (Styrene)
1.1 to 1.4 (Water = 1)
3.6 (Air = 1) (Styrene )
5.0 mm Hg@ 68 F / 20 C (Styrene)
Aromatic.Odor
pH
Grey.Color
Evaporation rate < 1 (Butyl acetate = 1) Flash point 88 F / 31 C (Styrene) Not applicable. 0.01 - 0.1 ppm (Styrene)Odor threshold Appearance Boiling point 293 F / 145 C (Styrene) Flammability (solid, gas) Not applicable. Lower and upper explosive (flammable) limits Lower: 1.1% Upper: 6.1% (Styrene) Page: 5 of 10Date of issue: 04/15/2022 Date of previous issue: 03/01/2020NA-1809:5336 (Version: 3.0) G725AA70812 Section 9. Physical and chemical properties Solubility Slight. Auto-ignition temperature 914 F / 490 C (Styrene) Not available. Viscosity Not available. Partition coefficient: n-octanol/water Molecular weight 1,000 to 15,000 Decomposition temperature Not available. Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable. Stable under recommended storage and handling conditions (see Section 7). Chemical stability Reactive or incompatible with the following materials: oxidizing materials Incompatible materials Possibility of hazardous reactions Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity No specific test data related to reactivity available for this product or its ingredients. Section 11. Toxicological information Acute toxicity styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours LC50 Inhalation Vapor Rat 11800 mg/m 4 hours LC50 Inhalation Vapor Rat 5634.2 ppm 4 hours LD50 Oral Rat 2650 mg/kg - methyl methacrylate LC50 Inhalation Gas. Rat 7094 ppm 4 hours LC50 Inhalation Vapor Rat 78000 mg/m 4 hours LD50 Dermal Rabbit >5 g/kg –
LD50 Oral Rat 7872 mg/kg –
LD50 Oral Rat 7872 mg/kg –
cobalt bis(2-ethylhexanoate) LD50 Dermal Rabbit >5 g/kg –
LD50 Oral Rat 1.22 g/kg –
Solvent naphtha (petroleum), light
arom.
LD50 Oral Rat 8400 mg/kg –
Ingredient name Result Species Dose Exposure
Carcinogenicity
Irritation/Corrosion
styrene Eyes – Mild irritant Human – 50 ppm –
Eyes – Moderate irritant Rabbit – 24 hours 100 mg-
Eyes – Severe irritant Rabbit – 100 mg –
Skin – Mild irritant Rabbit – 500 mg –
Skin – Moderate irritant Rabbit – 100 % –
Solvent naphtha (petroleum), light
arom.
Eyes – Mild irritant Rabbit – 24 hours 100 uL-
Ingredient name Result Score Exposure Observation
Sensitization
Species
Information on toxicological effects
Classification
styrene – 2A Reasonably anticipated to be a human carcinogen.
methyl methacrylate – 3 –
cobalt bis(2-ethylhexanoate) – 2B Reasonably anticipated to be a human carcinogen.
Ingredient name NTPIARCACGIH
No data on skin sensitization due to this product.
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Section 11. Toxicological information
Mutagenicity
Teratogenicity
Reproductive toxicity
Inhalation
Harmful if inhaled. May cause respiratory irritation. May cause drowsiness or dizziness.
Irritating to mouth, throat and stomach.
Ingestion
Skin contact
Causes skin irritation.
Causes serious eye irritation.
Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Adverse symptoms may include the following: respiratory tract irritation, coughing.
Adverse symptoms may include the following: Irritating to mouth, throat and stomach.
Adverse symptoms may include the following: irritation, redness.
Eye contact
Adverse symptoms may include the following: pain or irritation, watering, redness.
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Aspiration hazard
Potential acute health effects
No known significant effects or critical hazards.
1) Negative Study A published study concluded that the mechanism for producing cancer in mice exposed to styrene
is not applicable in human metabolism. (June 2013 Pharmacology & Toxicology 66 (2013))
2) Negative Study A recent update to an extensive study of reinforced plastic workers from 1948-1977 concluded that
there was no coherent evidence that styrene exposure increased risk of cancer (March 2013 Epidemiology Vol. 24
Issue 2)
3) Positive Study Styrene induced pulmonary toxicity and carcinogenicity in mice was shown to be caused by a
metabolite of styrene, probably styrene oxide. (Dec.2001 Toxicology Vol.169 Issue 2)
Suspected of damaging the unborn child.
No known significant effects or critical hazards.
May cause respiratory irritation.
A study of long term effects of workers exposed to styrene levels in the range of 25-35 ppm, 8 hour TWA, indicated a possible mild
hearing loss.
May be fatal if swallowed and enters airways.
Inhalation
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
styrene 0.35 13.49 low
methyl methacrylate 1.38 – low
cobalt bis(2-ethylhexanoate) – 15600 high
Solvent naphtha (petroleum), light
arom.
– 10 to 2500 high
Toxicity
styrene Acute EC50 78000 g/l Marine water Algae – Skeletonema costatum 96 hours
Acute EC50 4700 g/l Fresh water Daphnia – Daphnia magna 48 hours
Acute LC50 52 mg/l Marine water Crustaceans – Artemia salina 48 hours
Acute LC50 4020 g/l Fresh water Fish – Pimephales promelas 96 hours
methyl methacrylate Acute LC50 130000 g/l Fresh water Fish – Pimephales promelas – Adult96 hours
Ingredient name SpeciesResult Exposure
Persistence and degradability
Mobility in soil
Not available.
Ingredient name
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Section 12. Ecological information
Other adverse effects
No known effect according to our database.
Soil/water partition coefficient (KOC)
Not available.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some product residues.
Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-
products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local
authority requirements. Avoid disposal. Attempt to use product completely in accordance with intended use. Waste packaging should be
recycled. Incineration or landfill should only be considered when recycling is not feasible.
Disposal methods
The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for any
available use-specific information provided in the Exposure Scenario(s).
Special precautions
This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues. Do not cut, weld or grind used containers unless they
have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
Section 14. Transport information
Resin Solution
3
III
UN1866UN number
Proper shipping name
Transport hazard class(es)
Packing group
DOT /TDG / IMDG/IMO / ICAO/IATA and National regulations.
Additional information US regulations require the reporting of spills when the amount exceeds the Reportable
Quantity (RQ) for specific components of this material. See CERCLA in Section 15,
Regulatory Information, for the Reportable Quantities.
Environmental hazards Marine pollutant: No.
Special precautions for user Transport within user s premises: always transport in closed containers that are upright and
secure. Ensure that persons transporting the product know what to do in the event of an
accident or spillage.
IMDGEmergency schedules (EmS): F-E, S-E
Remarks: FP- 31 C
IATANo additional information.
Section 15. Regulatory information
International regulations lists
All components are active or exempted.
SARA 311/312
United States inventory (TSCA 8b)
Australia (AICS) All components are listed or exempted.
Canada (DSL) All components are listed or exempted.
China (IECSC) All components are listed or exempted.
Europe (EINECS) Not determined.
Japan (ENCS) Not determined.
Republic of Korea (KECI) All components are listed or exempted.
New Zealand (NZIoC) All components are listed or exempted.
Philippines (PICCS) At least one component is not listed.
Taiwan (CSNN) All components are listed or exempted.
U.S. Federal regulations
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Section 15. Regulatory information
SARA 313
Ingredient name
styrene 100-42-5
methyl methacrylate 80-62-6
cobalt bis(2-ethylhexanoate) 136-52-7
Form R – Reporting
requirements
CAS number
California Prop. 65
State regulations
styrene – 1000 lbs. (453.6 kg)
methyl methacrylate – 1000 lbs. (453.6 kg)
CERCLA RQ –
WARNING: This product can expose you to chemicals including Styrene and Titanium dioxide, which are known to the State of
California to cause cancer, and Ethylene Glycol, which is known to the State of California to cause birth defects or other reproductive
harm. For more information go to www.P65Warnings.ca.gov.
Per the June 13, 2016 Federal Register notice, EPA harmonized the EPCRA 311/312 hazard categories with the 2012 OSHA hazard
communication standard for classifying and labeling of chemicals (i.e. GHS). Please refer to Section 2 of the SDS to identify the appropriate
hazard categories for reporting purposes.
Section 16. Other information
History
Version
Prepared by
AOC is a registered trademark of the AOC group of companies.
The information contained in this data sheet is based on laboratory data and field experience. We believe this information to be reliable, but do not
guarantee its applicability to the user s process or assume any liability for occurrences arising out of its use. The user, by accepting the products
as described herein, agrees to be responsible for thoroughly testing each such product before committing it to production.
Altek , Atryl , Atryl TCA , Chroma-Tek , EcoTek , FirePel , Hydropel , Moldtru , PulTru , Vibrin , Vicast , Vipel , the AOC name, the
AOC logo, and the Trusted Solutions logo are registered trademarks of the AOC group of companies.
Our recommendations should not be construed as inducements to infringe any patent or violate any law, safety code or insurance regulation.
The information and recommendations contained herein are to the best of our knowledge accurate and reliable, but no rights whatsoever may be
derived by any party other than those expressly agreed to with a selling entity of the AOC group of companies in a legally binding agreement. AOC
hereby makes no warranty of any kind, express or implied, including those of merchantability and fitness for purpose. Unless explicitly agreed to in
writing by AOC otherwise, all offers, quotations, sales and deliveries of AOC products are subject to the general conditions of sale of AOC.
Notice to reader
Date of previous issue
Indicates information that has changed from previously issued version.
Key to abbreviations ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by
the Protocol of 1978. (“Marpol” = marine pollution)
UN = United Nations
04/15/2022
03/01/2020
3.0
National Fire Protection Association (U.S.A.)
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This
reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety.
Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and
reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether
the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk.
AOC Corporate Regulatory Affairs
1
3
2
Health
Special
Instability
Flammability
Date of issue
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Section 16. Other information
This Safety Data Sheet (SDS) and its content are the confidential and proprietary information of AOC and it may not be modified, altered,
deconstructed, or presented in any other manner, without the explicit authorization of AOC and/or its legal counsel.
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