40804025G_SDS.pdf

HV FAST BONDING PUTTY
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue: 08/11/2016 Revision date: 08/11/2016 Supersedes: 09/10/2014

08/11/2016 EN (English US) Page 1

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Product form : Mixture
Trade name : HV FAST BONDING PUTTY
CAS No : mixture
Product code : 804-025
Formula : na

1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : BONDING PUTTY

1.3. Details of the supplier of the safety data sheet
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316

909.877.8477
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887

1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
GHS-US classification
Flam. Liq. 3 H226
Skin Irrit. 2 H315
Eye Irrit. 2A H319
Carc. 2 H351
Repr. 2 H361
STOT SE 3 H335
STOT RE 1 H372

2.2. Label elements
GHS-US labeling
Hazard pictograms (GHS-US) :

GHS02

GHS07

GHS08

Signal word (GHS-US) : Danger
Hazard statements (GHS-US) : H226 – Flammable liquid and vapor
H315 – Causes skin irritation
H319 – Causes serious eye irritation
H335 – May cause respiratory irritation
H351 – Suspected of causing cancer
H361 – Suspected of damaging fertility or the unborn child
H372 – Causes damage to organs through prolonged or repeated exposure
Precautionary statements (GHS-US) : P201 – Obtain special instructions before use
P202 – Do not handle until all safety precautions have been read and understood
P210 – Keep away from heat, hot surfaces, open flames, sparks. – No smoking
P233 – Keep container tightly closed
P240 – Ground/bond container and receiving equipment
P241 – Use explosion-proof electrical, lighting, ventilating equipment
P242 – Use only non-sparking tools
P243 – Take precautionary measures against static discharge
P260 – Do not breathe dust/fume/gas/mist/vapors/spray

HV FAST BONDING PUTTY
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

08/11/2016 EN (English US) 2/10

P261 – Avoid breathing dust/fume/gas/mist/vapors/spray
P264 – Wash EXPOSED AREA. thoroughly after handling
P270 – Do not eat, drink or smoke when using this product
P271 – Use only outdoors or in a well-ventilated area
P280 – Wear eye protection, protective clothing, protective gloves
P302+P352 – IF ON SKIN: Wash with plenty of soap and water
P303+P361+P353 – IF ON SKIN (or hair): Remove/Take off immediately all contaminated
clothing. Rinse skin with water/shower
P304+P340 – IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable
for breathing
P305+P351+P338 – If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P308+P313 – IF exposed or concerned: Get medical advice/attention
P312 – Call a POISON CENTER or doctor/physician if you feel unwell
P314 – Get medical advice and attention if you feel unwell
P321 – Specific treatment (see SEEK MEDICAL AID. on this label)
P332+P313 – If skin irritation occurs: Get medical advice/attention
P337+P313 – If eye irritation persists: Get medical advice/attention
P362 – Take off contaminated clothing and wash it before reuse
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish
P403+P233 – Store in a well-ventilated place. Keep container tightly closed
P403+P235 – Store in a well-ventilated place. Keep cool
P405 – Store locked up
P501 – Dispose of contents/container to LOCAL, STATE, AND NATIONAL REGULATIONS.

2.3. Other hazards
No additional information available
2.4. Unknown acute toxicity (GHS-US)
No data available
SECTION 3: Composition/Information on ingredients

3.1. Substance
Not applicable
Full text of H-phrases: see section 16

3.2. Mixture

Name Product identifier % GHS-US classification
Unsaturated Polyester Resin (CAS No) TRADE SECRET <= 38 Not classified styrene, inhibited (CAS No) 100-42-5 <= 22 Flam. Liq. 3, H226 Acute Tox. 4 (Inhalation:vapour), H332 Skin Irrit. 2, H315 Eye Irrit. 2A, H319 Carc. 2, H351 Repr. 2, H361 STOT SE 3, H335 STOT RE 1, H372 fibreglass, diameter > 3 micrometers, length > 5 micrometers (CAS No) 65997-17-3 <= 22 Not classified talc (CAS No) 14807-96-6 <= 12 Not classified cobalt(II) 2-ethylhexanoate (CAS No) 136-52-7 <= 0.5 Carc. 2, H351 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. Suspected of causing cancer. IF exposed or concerned: Get medical advice/attention. First-aid measures after inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. First-aid measures after skin contact : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. Specific treatment (see ... on this label). First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. HV FAST BONDING PUTTY Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 08/11/2016 EN (English US) 3/10 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : May cause genetic defects (avoid skin contact and inhalation.). May cause cancer (avoid skin contact and inhalation.). Suspected of damaging fertility or the unborn child. Causes damage to organs through prolonged or repeated exposure. Symptoms/injuries after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if inhaled. May cause respiratory irritation. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms/injuries after eye contact : Causes serious eye irritation. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Fire hazard : Highly flammable liquid and vapor. Flammable liquid and vapor. Explosion hazard : May form flammable/explosive vapor-air mixture. Reactivity : No reactivity hazard other than the effects described in sub-sections below. 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No smoking. 6.1.1. For non-emergency personnel Protective equipment : Gloves. Protective goggles. Protective clothing. Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up For containment : Dam up the liquid spill. Contain released substance, pump into suitable containers. Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed : Handle empty containers with care because residual vapors are flammable. Precautions for safe handling : Use only outdoors or in a well-ventilated area. Avoid breathing DUST, FUMES, MIST, OR VAPORS. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Eliminate all ignition sources if safe to do so. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. No open flames. No smoking. Take precautionary measures against static discharge. Use only non-sparking tools. Do not breathe dust/fume/gas/mist/vapors/spray. Hygiene measures : Wash ... thoroughly after handling. Do not eat, drink or smoke when using this product. HV FAST BONDING PUTTY Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 08/11/2016 EN (English US) 4/10 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Storage conditions : Keep in fireproof place. Keep only in the original container in a cool, well ventilated place away from : Keep container tightly closed. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. Heat sources. 7.3. Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection 8.1. Control parameters styrene, inhibited (100-42-5) USA ACGIH ACGIH TWA (ppm) 20 ppm USA ACGIH ACGIH STEL (ppm) 20 ppm talc (14807-96-6) USA ACGIH ACGIH TWA (mg/m ) 2 mg/m fibreglass, diameter > 3 micrometers, length > 5 micrometers (65997-17-3)
USA ACGIH ACGIH TWA (mg/m ) 5 mg/m

8.2. Exposure controls
Appropriate engineering controls : Ensure exposure is below occupational exposure limits (where available).
Personal protective equipment : Avoid all unnecessary exposure.
Hand protection : Wear protective gloves.
Eye protection : Chemical goggles or safety glasses.
Skin and body protection : Wear suitable protective clothing.
Respiratory protection : Wear appropriate mask.
Other information : Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : Liquid

Color : Colourless to yellow.

Odor : characteristic.

Odor threshold : No data available

pH : No data available

Relative evaporation rate (butyl acetate=1) : No data available

Melting point : No data available

Freezing point : No data available

Boiling point : 64 C

Flash point : 30 – 34 C

Auto-ignition temperature : No data available

Decomposition temperature : No data available

Flammability (solid, gas) : No data available

Vapor pressure : No data available

Relative vapor density at 20 C : No data available

Relative density : No data available

Specific gravity / density : 1.43
Solubility : No data available

Log Pow : No data available

Log Kow : No data available

HV FAST BONDING PUTTY
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

08/11/2016 EN (English US) 5/10

Viscosity, kinematic : No data available

Viscosity, dynamic : No data available

Explosive properties : No data available

Oxidizing properties : No data available

Explosive limits : No data available

9.2. Other information
No additional information available
SECTION 10: Stability and reactivity

10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.

10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Highly flammable liquid and vapor. Not established. Flammable liquid and
vapor. May form flammable/explosive vapor-air mixture.

10.3. Possibility of hazardous reactions
Not established.

10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Heat. Sparks.

10.5. Incompatible materials
Strong acids. Strong bases.

10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity : Not classified

HV FAST BONDING PUTTY ( f )mixture
ATE CLP (vapors) 11.000 mg/l/4h

styrene, inhibited (100-42-5)
LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
LD50 dermal rat 2820 mg/kg (Rat; Literature study; OECD 402: Acute Dermal Toxicity; >2000 mg/kg
bodyweight; Rat; Experimental value)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 inhalation rat (mg/l) 12 mg/l/4h (Rat; Literature study)
LC50 inhalation rat (ppm) 2770 ppm/4h (Rat; Literature study)
ATE CLP (oral) 5000.000 mg/kg body weight
ATE CLP (dermal) 2820.000 mg/kg body weight
ATE CLP (gases) 2770.000 ppmV/4h
ATE CLP (vapors) 12.000 mg/l/4h
ATE CLP (dust, mist) 12.000 mg/l/4h

cobalt(II) 2-ethylhexanoate (136-52-7)
LD50 oral rat 3129 mg/kg body weight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat > 2000 mg/kg body weight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)
ATE CLP (oral) 3129.000 mg/kg body weight

Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitization : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Suspected of causing cancer.

styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans

HV FAST BONDING PUTTY
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

08/11/2016 EN (English US) 6/10

cobalt(II) 2-ethylhexanoate (136-52-7)
IARC group 2B – Possibly carcinogenic to humans

talc (14807-96-6)
IARC group 3 – Not classifiable

Reproductive toxicity : Suspected of damaging fertility or the unborn child.
Based on available data, the classification criteria are not met
Specific target organ toxicity (single exposure) : May cause respiratory irritation.

Specific target organ toxicity (repeated
exposure)
: Causes damage to organs through prolonged or repeated exposure.
Based on available data, the classification criteria are not met
Causes damage to organs through prolonged or repeated exposure

Aspiration hazard : Not classified
Based on available data, the classification criteria are not met
Potential Adverse human health effects and
symptoms
: Harmful if inhaled. Based on available data, the classification criteria are not met.
Symptoms/injuries after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled. May cause respiratory irritation.
Symptoms/injuries after skin contact : Causes skin irritation.
Symptoms/injuries after eye contact : Causes serious eye irritation.
SECTION 12: Ecological information

12.1. Toxicity

styrene, inhibited (100-42-5)
LC50 fish 1 25 mg/l (96 h; Lepomis macrochirus; GLP)
LC50 other aquatic organisms 1 10 – 100 mg/l (96 h)
EC50 Daphnia 1 23 mg/l (48 h; Daphnia magna; Locomotor effect)
LC50 fish 2 32 mg/l (96 h; Pimephales promelas)
EC50 Daphnia 2 27 mg/l (24 h; Daphnia magna; GLP)
TLM fish 1 25.1 mg/l (96 h; Lepomis macrochirus; Soft water)
TLM fish 2 46.4 mg/l (96 h; Pimephales promelas; Soft water)
TLM other aquatic organisms 1 10 – 100,96 h
Threshold limit other aquatic organisms 1 10 – 100,96 h; Pseudomonas putida
Threshold limit other aquatic organisms 2 72 mg/l
Threshold limit algae 1 > 200 mg/l (192 h; Scenedesmus quadricauda; Inhibitory)
Threshold limit algae 2 67 mg/l (Microcystis aeruginosa; Inhibitory)

cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 1 54.1 mg/l (96 h; Pimephales promelas)
EC50 Daphnia 1 2618 g/l (48 h)
Threshold limit algae 1 24.1 g/l (7 days)
Threshold limit algae 2 90.1 g/l (7 days; Lemna minor; Growth rate)

talc (14807-96-6)
LC50 fish 1 > 100 g/l (24 h; Brachydanio rerio; Intermittent flow)

12.2. Persistence and degradability
HV FAST BONDING PUTTY (mixture)
Persistence and degradability Not established.

styrene, inhibited (100-42-5)
Persistence and degradability Readily biodegradable in water. Not readily biodegradable in water. Forming sediments in
water. Non degradable in the soil. Adsorbs into the soil. Photodegradation in the air. Not
established.
Chemical oxygen demand (COD) 2.80 g O /g substance
ThOD 3.07 g O /g substance
BOD (% of ThOD) 0.42 % ThOD

HV FAST BONDING PUTTY
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

08/11/2016 EN (English US) 7/10

cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability Biodegradability in water: no data available.

talc (14807-96-6)
Persistence and degradability Biodegradability: not applicable.
Biochemical oxygen demand (BOD) Not applicable
Chemical oxygen demand (COD) Not applicable
ThOD Not applicable
BOD (% of ThOD) Not applicable

fibreglass, diameter > 3 micrometers, length > 5 micrometers (65997-17-3)
Persistence and degradability Biodegradability: not applicable. Not established.
Biochemical oxygen demand (BOD) Not applicable
Chemical oxygen demand (COD) Not applicable
ThOD Not applicable
BOD (% of ThOD) Not applicable

Unsaturated Polyester Resin (TRADE SECRET)
Persistence and degradability Not established.

12.3. Bioaccumulative potential
HV FAST BONDING PUTTY (mixture)
Bioaccumulative potential Not established.

styrene, inhibited (100-42-5)
BCF fish 1 35.5 (Carassius auratus)
BCF other aquatic organisms 1 74
Log Pow 2.96 (Experimental value; OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method; 25 C)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Not established. cobalt(II) 2-ethylhexanoate (136-52-7) Bioaccumulative potential No bioaccumulation data available. fibreglass, diameter > 3 micrometers, length > 5 micrometers (65997-17-3)
Bioaccumulative potential No bioaccumulation data available. Not established.

Unsaturated Polyester Resin (TRADE SECRET)
Bioaccumulative potential Not established.

12.4. Mobility in soil

styrene, inhibited (100-42-5)
Surface tension 0.032 N/m (19 C)

cobalt(II) 2-ethylhexanoate (136-52-7)
Surface tension 0.064 N/m (20 C; 1 g/l)

12.5. Other adverse effects
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations

13.1. Waste treatment methods
Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to …
Additional information : Handle empty containers with care because residual vapors are flammable.
Ecology – waste materials : Avoid release to the environment.
SECTION 14: Transport information

In accordance with DOT
UN-No.(DOT) : UN1866
Proper Shipping Name (DOT) : RESIN SOLUTION

HV FAST BONDING PUTTY
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

08/11/2016 EN (English US) 8/10

Transport hazard class(es) (DOT) : 3 – Class 3 – Flammable and combustible liquid 49 CFR 173.120
Hazard labels (DOT) : 3 – Flammable liquid

Packing group (DOT) : III – Minor Danger

Additional information
Other information : No supplementary information available.

ADR
Transport document description : UN 1866, 3, III, (D/E)
Packing group (ADR) : III
Class (ADR) : 3 – Flammable liquid
Hazard identification number (Kemler No.) : 33
Classification code (ADR) : F1
Hazard labels (ADR) : 3 – Flammable liquids

Orange plates :

Tunnel restriction code : D/E
LQ : 5l
Excepted quantities (ADR) : E2
Transport by sea
UN-No. (IMDG) : 1866
Proper Shipping Name (IMDG) : RESIN SOLUTION
Class (IMDG) : 3 – Flammable liquids
Packing group (IMDG) : III – substances presenting low danger
Air transport
UN-No. (IATA) : 1866
Proper Shipping Name (IATA) : RESIN SOLUTION
Class (IATA) : 3 – Flammable Liquids
Packing group (IATA) : III – Minor Danger
SECTION 15: Regulatory information

15.1. US Federal regulations

styrene, inhibited (100-42-5)
RQ (Reportable quantity, section 304 of EPA’s
List of Lists)
1000 lb
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Reactive hazard
Fire hazard
Delayed (chronic) health hazard

15.2. International regulations
CANADA
No additional information available

HV FAST BONDING PUTTY
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

08/11/2016 EN (English US) 9/10

EU-Regulations
No additional information available

Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flam. Liq. 3 H226
Acute Tox. 4 (Inhalation:vapour) H332
Skin Irrit. 2 H315
Eye Irrit. 2 H319
Muta. 1B H340
Carc. 1B H350

Full text of H-phrases: see section 16

Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]
Carc.Cat.2; R45
Muta.Cat.2; R46
F; R11
Xn; R20
Xi; R36/38
Full text of R-phrases: see section 16
15.2.2. National regulations

styrene, inhibited (100-42-5)
Listed on EPA’s Hazardous Air Pollutants (HAPS)

15.3. US State regulations

styrene, inhibited (100-42-5)
U.S. – California –
Proposition 65 –
Carcinogens List
U.S. – California –
Proposition 65 –
Developmental Toxicity
U.S. – California –
Proposition 65 –
Reproductive Toxicity –
Female
U.S. – California –
Proposition 65 –
Reproductive Toxicity – Male
Non-significant risk level
(NSRL)

styrene, inhibited (100-42-5)
U.S. – Massachusetts – Right To Know List
U.S. – New Jersey – Right to Know Hazardous Substance List
U.S. – Pennsylvania – RTK (Right to Know) – Environmental Hazard List

SECTION 16: Other information

Other information : None.

Full text of H-phrases: see section 16:
—— Acute Tox. 4 (Inhalation:vapour) Acute toxicity (inhalation:vapour) Category 4
—— Carc. 2 Carcinogenicity Category 2
—— Eye Irrit. 2A Serious eye damage/eye irritation Category 2A
—— Flam. Liq. 3 Flammable liquids Category 3
—— Repr. 2 Reproductive toxicity Category 2
—— Skin Irrit. 2 Skin corrosion/irritation Category 2
—— STOT RE 1 Specific target organ toxicity (repeated exposure) Category 1
—— STOT SE 3 Specific target organ toxicity (single exposure) Category 3
—— H226 Flammable liquid and vapor
—— H315 Causes skin irritation
—— H319 Causes serious eye irritation
—— H332 Harmful if inhaled

HV FAST BONDING PUTTY
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

08/11/2016 EN (English US) 10/10

—— H335 May cause respiratory irritation
—— H351 Suspected of causing cancer
—— H361 Suspected of damaging fertility or the unborn child
—— H372 Causes damage to organs through prolonged or repeated exposure

NFPA health hazard : 2 – Intense or continued exposure could cause temporary
incapacitation or possible residual injury unless prompt
medical attention is given.

NFPA fire hazard : 3 – Liquids and solids that can be ignited under almost all
ambient conditions.
NFPA reactivity : 2 – Normally unstable and readily undergo violent
decomposition but do not detonate. Also: may react
violently with water or may form potentially explosive
mixtures with water.

HMIS III Rating

Health : 2 Moderate Hazard – Temporary or minor injury may occur
Flammability : 3 Serious Hazard
Physical : 1 Slight Hazard
Personal Protection : H

SDS US (GHS HazCom 2012)

To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied
warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.

40804025F_SDS.pdf

HV FAST BONDING PUTTY
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue: 08/11/2016 Revision date: 08/11/2016 Supersedes: 09/10/2014

08/11/2016 EN (English US) Page 1

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Product form : Mixture
Trade name : HV FAST BONDING PUTTY
CAS No : mixture
Product code : 804-025
Formula : na

1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : BONDING PUTTY

1.3. Details of the supplier of the safety data sheet
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316

909.877.8477
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887

1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
GHS-US classification
Flam. Liq. 3 H226
Skin Irrit. 2 H315
Eye Irrit. 2A H319
Carc. 2 H351
Repr. 2 H361
STOT SE 3 H335
STOT RE 1 H372

2.2. Label elements
GHS-US labeling
Hazard pictograms (GHS-US) :

GHS02

GHS07

GHS08

Signal word (GHS-US) : Danger
Hazard statements (GHS-US) : H226 – Flammable liquid and vapor
H315 – Causes skin irritation
H319 – Causes serious eye irritation
H335 – May cause respiratory irritation
H351 – Suspected of causing cancer
H361 – Suspected of damaging fertility or the unborn child
H372 – Causes damage to organs through prolonged or repeated exposure
Precautionary statements (GHS-US) : P201 – Obtain special instructions before use
P202 – Do not handle until all safety precautions have been read and understood
P210 – Keep away from heat, hot surfaces, open flames, sparks. – No smoking
P233 – Keep container tightly closed
P240 – Ground/bond container and receiving equipment
P241 – Use explosion-proof electrical, lighting, ventilating equipment
P242 – Use only non-sparking tools
P243 – Take precautionary measures against static discharge
P260 – Do not breathe dust/fume/gas/mist/vapors/spray

HV FAST BONDING PUTTY
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

08/11/2016 EN (English US) 2/10

P261 – Avoid breathing dust/fume/gas/mist/vapors/spray
P264 – Wash EXPOSED AREA. thoroughly after handling
P270 – Do not eat, drink or smoke when using this product
P271 – Use only outdoors or in a well-ventilated area
P280 – Wear eye protection, protective clothing, protective gloves
P302+P352 – IF ON SKIN: Wash with plenty of soap and water
P303+P361+P353 – IF ON SKIN (or hair): Remove/Take off immediately all contaminated
clothing. Rinse skin with water/shower
P304+P340 – IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable
for breathing
P305+P351+P338 – If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P308+P313 – IF exposed or concerned: Get medical advice/attention
P312 – Call a POISON CENTER or doctor/physician if you feel unwell
P314 – Get medical advice and attention if you feel unwell
P321 – Specific treatment (see SEEK MEDICAL AID. on this label)
P332+P313 – If skin irritation occurs: Get medical advice/attention
P337+P313 – If eye irritation persists: Get medical advice/attention
P362 – Take off contaminated clothing and wash it before reuse
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish
P403+P233 – Store in a well-ventilated place. Keep container tightly closed
P403+P235 – Store in a well-ventilated place. Keep cool
P405 – Store locked up
P501 – Dispose of contents/container to LOCAL, STATE, AND NATIONAL REGULATIONS.

2.3. Other hazards
No additional information available
2.4. Unknown acute toxicity (GHS-US)
No data available
SECTION 3: Composition/Information on ingredients

3.1. Substance
Not applicable
Full text of H-phrases: see section 16

3.2. Mixture

Name Product identifier % GHS-US classification
Unsaturated Polyester Resin (CAS No) TRADE SECRET <= 38 Not classified styrene, inhibited (CAS No) 100-42-5 <= 22 Flam. Liq. 3, H226 Acute Tox. 4 (Inhalation:vapour), H332 Skin Irrit. 2, H315 Eye Irrit. 2A, H319 Carc. 2, H351 Repr. 2, H361 STOT SE 3, H335 STOT RE 1, H372 fibreglass, diameter > 3 micrometers, length > 5 micrometers (CAS No) 65997-17-3 <= 22 Not classified talc (CAS No) 14807-96-6 <= 12 Not classified cobalt(II) 2-ethylhexanoate (CAS No) 136-52-7 <= 0.5 Carc. 2, H351 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. Suspected of causing cancer. IF exposed or concerned: Get medical advice/attention. First-aid measures after inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. First-aid measures after skin contact : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. Specific treatment (see ... on this label). First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. HV FAST BONDING PUTTY Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 08/11/2016 EN (English US) 3/10 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : May cause genetic defects (avoid skin contact and inhalation.). May cause cancer (avoid skin contact and inhalation.). Suspected of damaging fertility or the unborn child. Causes damage to organs through prolonged or repeated exposure. Symptoms/injuries after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if inhaled. May cause respiratory irritation. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms/injuries after eye contact : Causes serious eye irritation. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Fire hazard : Highly flammable liquid and vapor. Flammable liquid and vapor. Explosion hazard : May form flammable/explosive vapor-air mixture. Reactivity : No reactivity hazard other than the effects described in sub-sections below. 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No smoking. 6.1.1. For non-emergency personnel Protective equipment : Gloves. Protective goggles. Protective clothing. Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up For containment : Dam up the liquid spill. Contain released substance, pump into suitable containers. Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed : Handle empty containers with care because residual vapors are flammable. Precautions for safe handling : Use only outdoors or in a well-ventilated area. Avoid breathing DUST, FUMES, MIST, OR VAPORS. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Eliminate all ignition sources if safe to do so. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. No open flames. No smoking. Take precautionary measures against static discharge. Use only non-sparking tools. Do not breathe dust/fume/gas/mist/vapors/spray. Hygiene measures : Wash ... thoroughly after handling. Do not eat, drink or smoke when using this product. HV FAST BONDING PUTTY Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 08/11/2016 EN (English US) 4/10 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Storage conditions : Keep in fireproof place. Keep only in the original container in a cool, well ventilated place away from : Keep container tightly closed. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. Heat sources. 7.3. Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection 8.1. Control parameters styrene, inhibited (100-42-5) USA ACGIH ACGIH TWA (ppm) 20 ppm USA ACGIH ACGIH STEL (ppm) 20 ppm talc (14807-96-6) USA ACGIH ACGIH TWA (mg/m ) 2 mg/m fibreglass, diameter > 3 micrometers, length > 5 micrometers (65997-17-3)
USA ACGIH ACGIH TWA (mg/m ) 5 mg/m

8.2. Exposure controls
Appropriate engineering controls : Ensure exposure is below occupational exposure limits (where available).
Personal protective equipment : Avoid all unnecessary exposure.
Hand protection : Wear protective gloves.
Eye protection : Chemical goggles or safety glasses.
Skin and body protection : Wear suitable protective clothing.
Respiratory protection : Wear appropriate mask.
Other information : Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : Liquid

Color : Colourless to yellow.

Odor : characteristic.

Odor threshold : No data available

pH : No data available

Relative evaporation rate (butyl acetate=1) : No data available

Melting point : No data available

Freezing point : No data available

Boiling point : 64 C

Flash point : 30 – 34 C

Auto-ignition temperature : No data available

Decomposition temperature : No data available

Flammability (solid, gas) : No data available

Vapor pressure : No data available

Relative vapor density at 20 C : No data available

Relative density : No data available

Specific gravity / density : 1.43
Solubility : No data available

Log Pow : No data available

Log Kow : No data available

HV FAST BONDING PUTTY
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

08/11/2016 EN (English US) 5/10

Viscosity, kinematic : No data available

Viscosity, dynamic : No data available

Explosive properties : No data available

Oxidizing properties : No data available

Explosive limits : No data available

9.2. Other information
No additional information available
SECTION 10: Stability and reactivity

10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.

10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Highly flammable liquid and vapor. Not established. Flammable liquid and
vapor. May form flammable/explosive vapor-air mixture.

10.3. Possibility of hazardous reactions
Not established.

10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Heat. Sparks.

10.5. Incompatible materials
Strong acids. Strong bases.

10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity : Not classified

HV FAST BONDING PUTTY ( f )mixture
ATE CLP (vapors) 11.000 mg/l/4h

styrene, inhibited (100-42-5)
LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
LD50 dermal rat 2820 mg/kg (Rat; Literature study; OECD 402: Acute Dermal Toxicity; >2000 mg/kg
bodyweight; Rat; Experimental value)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 inhalation rat (mg/l) 12 mg/l/4h (Rat; Literature study)
LC50 inhalation rat (ppm) 2770 ppm/4h (Rat; Literature study)
ATE CLP (oral) 5000.000 mg/kg body weight
ATE CLP (dermal) 2820.000 mg/kg body weight
ATE CLP (gases) 2770.000 ppmV/4h
ATE CLP (vapors) 12.000 mg/l/4h
ATE CLP (dust, mist) 12.000 mg/l/4h

cobalt(II) 2-ethylhexanoate (136-52-7)
LD50 oral rat 3129 mg/kg body weight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat > 2000 mg/kg body weight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)
ATE CLP (oral) 3129.000 mg/kg body weight

Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitization : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Suspected of causing cancer.

styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans

HV FAST BONDING PUTTY
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

08/11/2016 EN (English US) 6/10

cobalt(II) 2-ethylhexanoate (136-52-7)
IARC group 2B – Possibly carcinogenic to humans

talc (14807-96-6)
IARC group 3 – Not classifiable

Reproductive toxicity : Suspected of damaging fertility or the unborn child.
Based on available data, the classification criteria are not met
Specific target organ toxicity (single exposure) : May cause respiratory irritation.

Specific target organ toxicity (repeated
exposure)
: Causes damage to organs through prolonged or repeated exposure.
Based on available data, the classification criteria are not met
Causes damage to organs through prolonged or repeated exposure

Aspiration hazard : Not classified
Based on available data, the classification criteria are not met
Potential Adverse human health effects and
symptoms
: Harmful if inhaled. Based on available data, the classification criteria are not met.
Symptoms/injuries after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled. May cause respiratory irritation.
Symptoms/injuries after skin contact : Causes skin irritation.
Symptoms/injuries after eye contact : Causes serious eye irritation.
SECTION 12: Ecological information

12.1. Toxicity

styrene, inhibited (100-42-5)
LC50 fish 1 25 mg/l (96 h; Lepomis macrochirus; GLP)
LC50 other aquatic organisms 1 10 – 100 mg/l (96 h)
EC50 Daphnia 1 23 mg/l (48 h; Daphnia magna; Locomotor effect)
LC50 fish 2 32 mg/l (96 h; Pimephales promelas)
EC50 Daphnia 2 27 mg/l (24 h; Daphnia magna; GLP)
TLM fish 1 25.1 mg/l (96 h; Lepomis macrochirus; Soft water)
TLM fish 2 46.4 mg/l (96 h; Pimephales promelas; Soft water)
TLM other aquatic organisms 1 10 – 100,96 h
Threshold limit other aquatic organisms 1 10 – 100,96 h; Pseudomonas putida
Threshold limit other aquatic organisms 2 72 mg/l
Threshold limit algae 1 > 200 mg/l (192 h; Scenedesmus quadricauda; Inhibitory)
Threshold limit algae 2 67 mg/l (Microcystis aeruginosa; Inhibitory)

cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 1 54.1 mg/l (96 h; Pimephales promelas)
EC50 Daphnia 1 2618 g/l (48 h)
Threshold limit algae 1 24.1 g/l (7 days)
Threshold limit algae 2 90.1 g/l (7 days; Lemna minor; Growth rate)

talc (14807-96-6)
LC50 fish 1 > 100 g/l (24 h; Brachydanio rerio; Intermittent flow)

12.2. Persistence and degradability
HV FAST BONDING PUTTY (mixture)
Persistence and degradability Not established.

styrene, inhibited (100-42-5)
Persistence and degradability Readily biodegradable in water. Not readily biodegradable in water. Forming sediments in
water. Non degradable in the soil. Adsorbs into the soil. Photodegradation in the air. Not
established.
Chemical oxygen demand (COD) 2.80 g O /g substance
ThOD 3.07 g O /g substance
BOD (% of ThOD) 0.42 % ThOD

HV FAST BONDING PUTTY
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

08/11/2016 EN (English US) 7/10

cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability Biodegradability in water: no data available.

talc (14807-96-6)
Persistence and degradability Biodegradability: not applicable.
Biochemical oxygen demand (BOD) Not applicable
Chemical oxygen demand (COD) Not applicable
ThOD Not applicable
BOD (% of ThOD) Not applicable

fibreglass, diameter > 3 micrometers, length > 5 micrometers (65997-17-3)
Persistence and degradability Biodegradability: not applicable. Not established.
Biochemical oxygen demand (BOD) Not applicable
Chemical oxygen demand (COD) Not applicable
ThOD Not applicable
BOD (% of ThOD) Not applicable

Unsaturated Polyester Resin (TRADE SECRET)
Persistence and degradability Not established.

12.3. Bioaccumulative potential
HV FAST BONDING PUTTY (mixture)
Bioaccumulative potential Not established.

styrene, inhibited (100-42-5)
BCF fish 1 35.5 (Carassius auratus)
BCF other aquatic organisms 1 74
Log Pow 2.96 (Experimental value; OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method; 25 C)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Not established. cobalt(II) 2-ethylhexanoate (136-52-7) Bioaccumulative potential No bioaccumulation data available. fibreglass, diameter > 3 micrometers, length > 5 micrometers (65997-17-3)
Bioaccumulative potential No bioaccumulation data available. Not established.

Unsaturated Polyester Resin (TRADE SECRET)
Bioaccumulative potential Not established.

12.4. Mobility in soil

styrene, inhibited (100-42-5)
Surface tension 0.032 N/m (19 C)

cobalt(II) 2-ethylhexanoate (136-52-7)
Surface tension 0.064 N/m (20 C; 1 g/l)

12.5. Other adverse effects
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations

13.1. Waste treatment methods
Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to …
Additional information : Handle empty containers with care because residual vapors are flammable.
Ecology – waste materials : Avoid release to the environment.
SECTION 14: Transport information

In accordance with DOT
UN-No.(DOT) : UN1866
Proper Shipping Name (DOT) : RESIN SOLUTION

HV FAST BONDING PUTTY
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

08/11/2016 EN (English US) 8/10

Transport hazard class(es) (DOT) : 3 – Class 3 – Flammable and combustible liquid 49 CFR 173.120
Hazard labels (DOT) : 3 – Flammable liquid

Packing group (DOT) : III – Minor Danger

Additional information
Other information : No supplementary information available.

ADR
Transport document description : UN 1866, 3, III, (D/E)
Packing group (ADR) : III
Class (ADR) : 3 – Flammable liquid
Hazard identification number (Kemler No.) : 33
Classification code (ADR) : F1
Hazard labels (ADR) : 3 – Flammable liquids

Orange plates :

Tunnel restriction code : D/E
LQ : 5l
Excepted quantities (ADR) : E2
Transport by sea
UN-No. (IMDG) : 1866
Proper Shipping Name (IMDG) : RESIN SOLUTION
Class (IMDG) : 3 – Flammable liquids
Packing group (IMDG) : III – substances presenting low danger
Air transport
UN-No. (IATA) : 1866
Proper Shipping Name (IATA) : RESIN SOLUTION
Class (IATA) : 3 – Flammable Liquids
Packing group (IATA) : III – Minor Danger
SECTION 15: Regulatory information

15.1. US Federal regulations

styrene, inhibited (100-42-5)
RQ (Reportable quantity, section 304 of EPA’s
List of Lists)
1000 lb
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Reactive hazard
Fire hazard
Delayed (chronic) health hazard

15.2. International regulations
CANADA
No additional information available

HV FAST BONDING PUTTY
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

08/11/2016 EN (English US) 9/10

EU-Regulations
No additional information available

Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flam. Liq. 3 H226
Acute Tox. 4 (Inhalation:vapour) H332
Skin Irrit. 2 H315
Eye Irrit. 2 H319
Muta. 1B H340
Carc. 1B H350

Full text of H-phrases: see section 16

Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]
Carc.Cat.2; R45
Muta.Cat.2; R46
F; R11
Xn; R20
Xi; R36/38
Full text of R-phrases: see section 16
15.2.2. National regulations

styrene, inhibited (100-42-5)
Listed on EPA’s Hazardous Air Pollutants (HAPS)

15.3. US State regulations

styrene, inhibited (100-42-5)
U.S. – California –
Proposition 65 –
Carcinogens List
U.S. – California –
Proposition 65 –
Developmental Toxicity
U.S. – California –
Proposition 65 –
Reproductive Toxicity –
Female
U.S. – California –
Proposition 65 –
Reproductive Toxicity – Male
Non-significant risk level
(NSRL)

styrene, inhibited (100-42-5)
U.S. – Massachusetts – Right To Know List
U.S. – New Jersey – Right to Know Hazardous Substance List
U.S. – Pennsylvania – RTK (Right to Know) – Environmental Hazard List

SECTION 16: Other information

Other information : None.

Full text of H-phrases: see section 16:
—— Acute Tox. 4 (Inhalation:vapour) Acute toxicity (inhalation:vapour) Category 4
—— Carc. 2 Carcinogenicity Category 2
—— Eye Irrit. 2A Serious eye damage/eye irritation Category 2A
—— Flam. Liq. 3 Flammable liquids Category 3
—— Repr. 2 Reproductive toxicity Category 2
—— Skin Irrit. 2 Skin corrosion/irritation Category 2
—— STOT RE 1 Specific target organ toxicity (repeated exposure) Category 1
—— STOT SE 3 Specific target organ toxicity (single exposure) Category 3
—— H226 Flammable liquid and vapor
—— H315 Causes skin irritation
—— H319 Causes serious eye irritation
—— H332 Harmful if inhaled

HV FAST BONDING PUTTY
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

08/11/2016 EN (English US) 10/10

—— H335 May cause respiratory irritation
—— H351 Suspected of causing cancer
—— H361 Suspected of damaging fertility or the unborn child
—— H372 Causes damage to organs through prolonged or repeated exposure

NFPA health hazard : 2 – Intense or continued exposure could cause temporary
incapacitation or possible residual injury unless prompt
medical attention is given.

NFPA fire hazard : 3 – Liquids and solids that can be ignited under almost all
ambient conditions.
NFPA reactivity : 2 – Normally unstable and readily undergo violent
decomposition but do not detonate. Also: may react
violently with water or may form potentially explosive
mixtures with water.

HMIS III Rating

Health : 2 Moderate Hazard – Temporary or minor injury may occur
Flammability : 3 Serious Hazard
Physical : 1 Slight Hazard
Personal Protection : H

SDS US (GHS HazCom 2012)

To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied
warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.

40804025D_SDS.pdf

HV FAST BONDING PUTTY
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue: 08/11/2016 Revision date: 08/11/2016 Supersedes: 09/10/2014

08/11/2016 EN (English US) Page 1

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Product form : Mixture
Trade name : HV FAST BONDING PUTTY
CAS No : mixture
Product code : 804-025
Formula : na

1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : BONDING PUTTY

1.3. Details of the supplier of the safety data sheet
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316

909.877.8477
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887

1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
GHS-US classification
Flam. Liq. 3 H226
Skin Irrit. 2 H315
Eye Irrit. 2A H319
Carc. 2 H351
Repr. 2 H361
STOT SE 3 H335
STOT RE 1 H372

2.2. Label elements
GHS-US labeling
Hazard pictograms (GHS-US) :

GHS02

GHS07

GHS08

Signal word (GHS-US) : Danger
Hazard statements (GHS-US) : H226 – Flammable liquid and vapor
H315 – Causes skin irritation
H319 – Causes serious eye irritation
H335 – May cause respiratory irritation
H351 – Suspected of causing cancer
H361 – Suspected of damaging fertility or the unborn child
H372 – Causes damage to organs through prolonged or repeated exposure
Precautionary statements (GHS-US) : P201 – Obtain special instructions before use
P202 – Do not handle until all safety precautions have been read and understood
P210 – Keep away from heat, hot surfaces, open flames, sparks. – No smoking
P233 – Keep container tightly closed
P240 – Ground/bond container and receiving equipment
P241 – Use explosion-proof electrical, lighting, ventilating equipment
P242 – Use only non-sparking tools
P243 – Take precautionary measures against static discharge
P260 – Do not breathe dust/fume/gas/mist/vapors/spray

HV FAST BONDING PUTTY
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

08/11/2016 EN (English US) 2/10

P261 – Avoid breathing dust/fume/gas/mist/vapors/spray
P264 – Wash EXPOSED AREA. thoroughly after handling
P270 – Do not eat, drink or smoke when using this product
P271 – Use only outdoors or in a well-ventilated area
P280 – Wear eye protection, protective clothing, protective gloves
P302+P352 – IF ON SKIN: Wash with plenty of soap and water
P303+P361+P353 – IF ON SKIN (or hair): Remove/Take off immediately all contaminated
clothing. Rinse skin with water/shower
P304+P340 – IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable
for breathing
P305+P351+P338 – If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P308+P313 – IF exposed or concerned: Get medical advice/attention
P312 – Call a POISON CENTER or doctor/physician if you feel unwell
P314 – Get medical advice and attention if you feel unwell
P321 – Specific treatment (see SEEK MEDICAL AID. on this label)
P332+P313 – If skin irritation occurs: Get medical advice/attention
P337+P313 – If eye irritation persists: Get medical advice/attention
P362 – Take off contaminated clothing and wash it before reuse
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish
P403+P233 – Store in a well-ventilated place. Keep container tightly closed
P403+P235 – Store in a well-ventilated place. Keep cool
P405 – Store locked up
P501 – Dispose of contents/container to LOCAL, STATE, AND NATIONAL REGULATIONS.

2.3. Other hazards
No additional information available
2.4. Unknown acute toxicity (GHS-US)
No data available
SECTION 3: Composition/Information on ingredients

3.1. Substance
Not applicable
Full text of H-phrases: see section 16

3.2. Mixture

Name Product identifier % GHS-US classification
Unsaturated Polyester Resin (CAS No) TRADE SECRET <= 38 Not classified styrene, inhibited (CAS No) 100-42-5 <= 22 Flam. Liq. 3, H226 Acute Tox. 4 (Inhalation:vapour), H332 Skin Irrit. 2, H315 Eye Irrit. 2A, H319 Carc. 2, H351 Repr. 2, H361 STOT SE 3, H335 STOT RE 1, H372 fibreglass, diameter > 3 micrometers, length > 5 micrometers (CAS No) 65997-17-3 <= 22 Not classified talc (CAS No) 14807-96-6 <= 12 Not classified cobalt(II) 2-ethylhexanoate (CAS No) 136-52-7 <= 0.5 Carc. 2, H351 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. Suspected of causing cancer. IF exposed or concerned: Get medical advice/attention. First-aid measures after inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. First-aid measures after skin contact : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. Specific treatment (see ... on this label). First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. HV FAST BONDING PUTTY Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 08/11/2016 EN (English US) 3/10 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : May cause genetic defects (avoid skin contact and inhalation.). May cause cancer (avoid skin contact and inhalation.). Suspected of damaging fertility or the unborn child. Causes damage to organs through prolonged or repeated exposure. Symptoms/injuries after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if inhaled. May cause respiratory irritation. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms/injuries after eye contact : Causes serious eye irritation. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Fire hazard : Highly flammable liquid and vapor. Flammable liquid and vapor. Explosion hazard : May form flammable/explosive vapor-air mixture. Reactivity : No reactivity hazard other than the effects described in sub-sections below. 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No smoking. 6.1.1. For non-emergency personnel Protective equipment : Gloves. Protective goggles. Protective clothing. Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up For containment : Dam up the liquid spill. Contain released substance, pump into suitable containers. Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed : Handle empty containers with care because residual vapors are flammable. Precautions for safe handling : Use only outdoors or in a well-ventilated area. Avoid breathing DUST, FUMES, MIST, OR VAPORS. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Eliminate all ignition sources if safe to do so. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. No open flames. No smoking. Take precautionary measures against static discharge. Use only non-sparking tools. Do not breathe dust/fume/gas/mist/vapors/spray. Hygiene measures : Wash ... thoroughly after handling. Do not eat, drink or smoke when using this product. HV FAST BONDING PUTTY Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 08/11/2016 EN (English US) 4/10 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Storage conditions : Keep in fireproof place. Keep only in the original container in a cool, well ventilated place away from : Keep container tightly closed. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. Heat sources. 7.3. Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection 8.1. Control parameters styrene, inhibited (100-42-5) USA ACGIH ACGIH TWA (ppm) 20 ppm USA ACGIH ACGIH STEL (ppm) 20 ppm talc (14807-96-6) USA ACGIH ACGIH TWA (mg/m ) 2 mg/m fibreglass, diameter > 3 micrometers, length > 5 micrometers (65997-17-3)
USA ACGIH ACGIH TWA (mg/m ) 5 mg/m

8.2. Exposure controls
Appropriate engineering controls : Ensure exposure is below occupational exposure limits (where available).
Personal protective equipment : Avoid all unnecessary exposure.
Hand protection : Wear protective gloves.
Eye protection : Chemical goggles or safety glasses.
Skin and body protection : Wear suitable protective clothing.
Respiratory protection : Wear appropriate mask.
Other information : Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : Liquid

Color : Colourless to yellow.

Odor : characteristic.

Odor threshold : No data available

pH : No data available

Relative evaporation rate (butyl acetate=1) : No data available

Melting point : No data available

Freezing point : No data available

Boiling point : 64 C

Flash point : 30 – 34 C

Auto-ignition temperature : No data available

Decomposition temperature : No data available

Flammability (solid, gas) : No data available

Vapor pressure : No data available

Relative vapor density at 20 C : No data available

Relative density : No data available

Specific gravity / density : 1.43
Solubility : No data available

Log Pow : No data available

Log Kow : No data available

HV FAST BONDING PUTTY
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

08/11/2016 EN (English US) 5/10

Viscosity, kinematic : No data available

Viscosity, dynamic : No data available

Explosive properties : No data available

Oxidizing properties : No data available

Explosive limits : No data available

9.2. Other information
No additional information available
SECTION 10: Stability and reactivity

10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.

10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Highly flammable liquid and vapor. Not established. Flammable liquid and
vapor. May form flammable/explosive vapor-air mixture.

10.3. Possibility of hazardous reactions
Not established.

10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Heat. Sparks.

10.5. Incompatible materials
Strong acids. Strong bases.

10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity : Not classified

HV FAST BONDING PUTTY ( f )mixture
ATE CLP (vapors) 11.000 mg/l/4h

styrene, inhibited (100-42-5)
LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
LD50 dermal rat 2820 mg/kg (Rat; Literature study; OECD 402: Acute Dermal Toxicity; >2000 mg/kg
bodyweight; Rat; Experimental value)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 inhalation rat (mg/l) 12 mg/l/4h (Rat; Literature study)
LC50 inhalation rat (ppm) 2770 ppm/4h (Rat; Literature study)
ATE CLP (oral) 5000.000 mg/kg body weight
ATE CLP (dermal) 2820.000 mg/kg body weight
ATE CLP (gases) 2770.000 ppmV/4h
ATE CLP (vapors) 12.000 mg/l/4h
ATE CLP (dust, mist) 12.000 mg/l/4h

cobalt(II) 2-ethylhexanoate (136-52-7)
LD50 oral rat 3129 mg/kg body weight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat > 2000 mg/kg body weight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)
ATE CLP (oral) 3129.000 mg/kg body weight

Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitization : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Suspected of causing cancer.

styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans

HV FAST BONDING PUTTY
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

08/11/2016 EN (English US) 6/10

cobalt(II) 2-ethylhexanoate (136-52-7)
IARC group 2B – Possibly carcinogenic to humans

talc (14807-96-6)
IARC group 3 – Not classifiable

Reproductive toxicity : Suspected of damaging fertility or the unborn child.
Based on available data, the classification criteria are not met
Specific target organ toxicity (single exposure) : May cause respiratory irritation.

Specific target organ toxicity (repeated
exposure)
: Causes damage to organs through prolonged or repeated exposure.
Based on available data, the classification criteria are not met
Causes damage to organs through prolonged or repeated exposure

Aspiration hazard : Not classified
Based on available data, the classification criteria are not met
Potential Adverse human health effects and
symptoms
: Harmful if inhaled. Based on available data, the classification criteria are not met.
Symptoms/injuries after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled. May cause respiratory irritation.
Symptoms/injuries after skin contact : Causes skin irritation.
Symptoms/injuries after eye contact : Causes serious eye irritation.
SECTION 12: Ecological information

12.1. Toxicity

styrene, inhibited (100-42-5)
LC50 fish 1 25 mg/l (96 h; Lepomis macrochirus; GLP)
LC50 other aquatic organisms 1 10 – 100 mg/l (96 h)
EC50 Daphnia 1 23 mg/l (48 h; Daphnia magna; Locomotor effect)
LC50 fish 2 32 mg/l (96 h; Pimephales promelas)
EC50 Daphnia 2 27 mg/l (24 h; Daphnia magna; GLP)
TLM fish 1 25.1 mg/l (96 h; Lepomis macrochirus; Soft water)
TLM fish 2 46.4 mg/l (96 h; Pimephales promelas; Soft water)
TLM other aquatic organisms 1 10 – 100,96 h
Threshold limit other aquatic organisms 1 10 – 100,96 h; Pseudomonas putida
Threshold limit other aquatic organisms 2 72 mg/l
Threshold limit algae 1 > 200 mg/l (192 h; Scenedesmus quadricauda; Inhibitory)
Threshold limit algae 2 67 mg/l (Microcystis aeruginosa; Inhibitory)

cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 1 54.1 mg/l (96 h; Pimephales promelas)
EC50 Daphnia 1 2618 g/l (48 h)
Threshold limit algae 1 24.1 g/l (7 days)
Threshold limit algae 2 90.1 g/l (7 days; Lemna minor; Growth rate)

talc (14807-96-6)
LC50 fish 1 > 100 g/l (24 h; Brachydanio rerio; Intermittent flow)

12.2. Persistence and degradability
HV FAST BONDING PUTTY (mixture)
Persistence and degradability Not established.

styrene, inhibited (100-42-5)
Persistence and degradability Readily biodegradable in water. Not readily biodegradable in water. Forming sediments in
water. Non degradable in the soil. Adsorbs into the soil. Photodegradation in the air. Not
established.
Chemical oxygen demand (COD) 2.80 g O /g substance
ThOD 3.07 g O /g substance
BOD (% of ThOD) 0.42 % ThOD

HV FAST BONDING PUTTY
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

08/11/2016 EN (English US) 7/10

cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability Biodegradability in water: no data available.

talc (14807-96-6)
Persistence and degradability Biodegradability: not applicable.
Biochemical oxygen demand (BOD) Not applicable
Chemical oxygen demand (COD) Not applicable
ThOD Not applicable
BOD (% of ThOD) Not applicable

fibreglass, diameter > 3 micrometers, length > 5 micrometers (65997-17-3)
Persistence and degradability Biodegradability: not applicable. Not established.
Biochemical oxygen demand (BOD) Not applicable
Chemical oxygen demand (COD) Not applicable
ThOD Not applicable
BOD (% of ThOD) Not applicable

Unsaturated Polyester Resin (TRADE SECRET)
Persistence and degradability Not established.

12.3. Bioaccumulative potential
HV FAST BONDING PUTTY (mixture)
Bioaccumulative potential Not established.

styrene, inhibited (100-42-5)
BCF fish 1 35.5 (Carassius auratus)
BCF other aquatic organisms 1 74
Log Pow 2.96 (Experimental value; OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method; 25 C)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Not established. cobalt(II) 2-ethylhexanoate (136-52-7) Bioaccumulative potential No bioaccumulation data available. fibreglass, diameter > 3 micrometers, length > 5 micrometers (65997-17-3)
Bioaccumulative potential No bioaccumulation data available. Not established.

Unsaturated Polyester Resin (TRADE SECRET)
Bioaccumulative potential Not established.

12.4. Mobility in soil

styrene, inhibited (100-42-5)
Surface tension 0.032 N/m (19 C)

cobalt(II) 2-ethylhexanoate (136-52-7)
Surface tension 0.064 N/m (20 C; 1 g/l)

12.5. Other adverse effects
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations

13.1. Waste treatment methods
Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to …
Additional information : Handle empty containers with care because residual vapors are flammable.
Ecology – waste materials : Avoid release to the environment.
SECTION 14: Transport information

In accordance with DOT
UN-No.(DOT) : UN1866
Proper Shipping Name (DOT) : RESIN SOLUTION

HV FAST BONDING PUTTY
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

08/11/2016 EN (English US) 8/10

Transport hazard class(es) (DOT) : 3 – Class 3 – Flammable and combustible liquid 49 CFR 173.120
Hazard labels (DOT) : 3 – Flammable liquid

Packing group (DOT) : III – Minor Danger

Additional information
Other information : No supplementary information available.

ADR
Transport document description : UN 1866, 3, III, (D/E)
Packing group (ADR) : III
Class (ADR) : 3 – Flammable liquid
Hazard identification number (Kemler No.) : 33
Classification code (ADR) : F1
Hazard labels (ADR) : 3 – Flammable liquids

Orange plates :

Tunnel restriction code : D/E
LQ : 5l
Excepted quantities (ADR) : E2
Transport by sea
UN-No. (IMDG) : 1866
Proper Shipping Name (IMDG) : RESIN SOLUTION
Class (IMDG) : 3 – Flammable liquids
Packing group (IMDG) : III – substances presenting low danger
Air transport
UN-No. (IATA) : 1866
Proper Shipping Name (IATA) : RESIN SOLUTION
Class (IATA) : 3 – Flammable Liquids
Packing group (IATA) : III – Minor Danger
SECTION 15: Regulatory information

15.1. US Federal regulations

styrene, inhibited (100-42-5)
RQ (Reportable quantity, section 304 of EPA’s
List of Lists)
1000 lb
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Reactive hazard
Fire hazard
Delayed (chronic) health hazard

15.2. International regulations
CANADA
No additional information available

HV FAST BONDING PUTTY
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

08/11/2016 EN (English US) 9/10

EU-Regulations
No additional information available

Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flam. Liq. 3 H226
Acute Tox. 4 (Inhalation:vapour) H332
Skin Irrit. 2 H315
Eye Irrit. 2 H319
Muta. 1B H340
Carc. 1B H350

Full text of H-phrases: see section 16

Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]
Carc.Cat.2; R45
Muta.Cat.2; R46
F; R11
Xn; R20
Xi; R36/38
Full text of R-phrases: see section 16
15.2.2. National regulations

styrene, inhibited (100-42-5)
Listed on EPA’s Hazardous Air Pollutants (HAPS)

15.3. US State regulations

styrene, inhibited (100-42-5)
U.S. – California –
Proposition 65 –
Carcinogens List
U.S. – California –
Proposition 65 –
Developmental Toxicity
U.S. – California –
Proposition 65 –
Reproductive Toxicity –
Female
U.S. – California –
Proposition 65 –
Reproductive Toxicity – Male
Non-significant risk level
(NSRL)

styrene, inhibited (100-42-5)
U.S. – Massachusetts – Right To Know List
U.S. – New Jersey – Right to Know Hazardous Substance List
U.S. – Pennsylvania – RTK (Right to Know) – Environmental Hazard List

SECTION 16: Other information

Other information : None.

Full text of H-phrases: see section 16:
—— Acute Tox. 4 (Inhalation:vapour) Acute toxicity (inhalation:vapour) Category 4
—— Carc. 2 Carcinogenicity Category 2
—— Eye Irrit. 2A Serious eye damage/eye irritation Category 2A
—— Flam. Liq. 3 Flammable liquids Category 3
—— Repr. 2 Reproductive toxicity Category 2
—— Skin Irrit. 2 Skin corrosion/irritation Category 2
—— STOT RE 1 Specific target organ toxicity (repeated exposure) Category 1
—— STOT SE 3 Specific target organ toxicity (single exposure) Category 3
—— H226 Flammable liquid and vapor
—— H315 Causes skin irritation
—— H319 Causes serious eye irritation
—— H332 Harmful if inhaled

HV FAST BONDING PUTTY
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

08/11/2016 EN (English US) 10/10

—— H335 May cause respiratory irritation
—— H351 Suspected of causing cancer
—— H361 Suspected of damaging fertility or the unborn child
—— H372 Causes damage to organs through prolonged or repeated exposure

NFPA health hazard : 2 – Intense or continued exposure could cause temporary
incapacitation or possible residual injury unless prompt
medical attention is given.

NFPA fire hazard : 3 – Liquids and solids that can be ignited under almost all
ambient conditions.
NFPA reactivity : 2 – Normally unstable and readily undergo violent
decomposition but do not detonate. Also: may react
violently with water or may form potentially explosive
mixtures with water.

HMIS III Rating

Health : 2 Moderate Hazard – Temporary or minor injury may occur
Flammability : 3 Serious Hazard
Physical : 1 Slight Hazard
Personal Protection : H

SDS US (GHS HazCom 2012)

To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied
warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.

40804024F_SDS.pdf

Durakote Medium Viscosity Bonding Putty
Safety Data Sheet
eiuuirding to Federal Register/Vol. 7?, No. 58/Monday, March 26, 2012/Rules and Regulations
Revision date: 11/30/2021
H:(IJ(lR&fflM4il41!41Hfm’lmiif+f’noli
GHS US classification
Flammable liquids Category 3
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2A
Reproductive toxicity Category 2
Specific target organ toxicity – Single exposure, Category 3, Respiratory tract
irritation
Specific target organ toxicity (repeated exposure) Category 1
Full text of H statements : see section 16
H226 Flammable liquid and vapor
H315 Causes skin irritation
H319 Causes serious eye irritation
H361 Suspected of damaging fertility or the unborn child
H335 May cause respiratory irritation
H372 Causes damage to organs through prolonged or repeated
exposure
GHS US labeling
Hazard pictograms (GHS US)
Signal word (GHS US)
Hazard statements (GHS US)
Precautionary statements (GHS US)
q1/30/2021
Danger
H226 – Flammable liquid and vapor
Hal5 – Causes skin irritation
H319 – Causes serious eye irritation
H335 – May cause respiratory irritation
H361 – Suspected of damaging fertility or the unborn child
H372 – Causes damage to organs through prolonged or repeated exposure
P201 – Obtain special instructions before use.
P202 – Do not handle until all safety precautions have been read and understood.
P21 0 – Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking. heat, hot surfaces, open flames, sparks
P233 – Keep container tightly closed.
P240 – Ground/Bond container and receiving equipment.
P241 – Use explosion-proof electrical, lighting, ventilating equipment.
P242 – Use only non-sparking tools.
Page 1EN (English US)

Durakote Medium Viscosity Bonding Putty
Safety Data Sheet
according to Federal Register/Vol. 77, No. 58 I Monday, March 26, 2012/Rules and Regulations
P243 – Take precautionary measures against static discharge.
P260 – Do not breathe dust, fume, mist, spray, vapors.
P264 – Wash EXPOSED AREA. thoroughly afler handling.
P27D – Do not eat, drink or smoke when using (his product.
P271 – Use only outdoors or in a well-ventilated area.
P280 – Wear eye protection, protective clothing, protective gloves.
P302+P352 – If on skin: Wash with plenty of water.
P303+P361+P353 – If on skin (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower.
P304+P340 – If inhaled: Remove person to fresh air and keep comfortable for breathing.
P305+P351 +P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P313 – If exposed or concerned: Get medical advice/attention.
P:312 – Call a poison center or doctor if you feel unwell.
P:314 – Get medical advice/attention if you feel unwell.
P321 – Specific treatment (see SEEK MEDICAL AID. on this label).
P332+P313 – If skin irritation occurs: Get medical advice/attention.
P337+P313 – If eye irritation persists: Get medical advice/attention.
P362 – Take off contaminated clothing and wash bejore reuse.
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish.
P403+P233 – Store in a well-ventilated place. Keep container tightly closed.
P403+P235 – Store in a well-ventilated place. Keep cool.
P405 – Store locked up.
P501 – Dispose of contents/container to LOCAL, STATE, AND NATIONAL REGtJLATIONS..
No additional information available
Not applicable
H’4dJlllS*’ffl4;liila!-!!mali?JliTaliiihl!taJit;ti@lif51daTal!=lil!
Not applicable
Name
Product identifier % GH3 US classification
styrene, inhibited
I
I
(CAS-No ) 100-42-5 <= 23.5 Flam. Liq. 3, H226 Acute Tox. 4 (Inhalation), H332 Acute Tox. 4 (lnhala)ion:vapour), H332 Skin mit. 2, H315 Eye Irrit. 2A, H319 Carc. 2, H351 Repr. 2, H361 STOT SE 3, H335 STOT RE 1, H372 Aquatic Acute 2, H401 talc (CAS-No ) 14807-96-6 <= ll Carc. 2, H351 silicon dioxide, amorphous (CAS-No ) 763'i-86-9 <= 10 Not classified cobalt(II) 2-eithylhexanoate (CAS-No ) 136-52-7 <= 0.5 Eye I rrit. 2, H3 19 Skin Sens. 1, H317 Carc. 2, H351 Aquatic Acute ', H400 Aquatic Chronic 2, H41 1 Full text of hazard classes and H-statements : see section 16 H:(pJmlfaf!"itlr* iif:4:!dll!4- First-aid measures general First-aid measures afker inhalation First-aid measures after skin contacf First-aid measures after eye contact Never give anything by mouth to an unconscious person. IF exposed or concerned: Get medical advice/attention. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Remove/T ake offimmediately all contaminated clothing. Rinse skin with water/shower. Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. Specific treatment (see supplemental first aid instruction on this label). Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue tinsing. If eye irritation persists: Get medical advice/attention. 11/30/2021 EN (English US) 2/1 1 Durakote Medium Viscosity Bonding Putty Safety Data Sheet according to Federal Register/Vol. 77, No. 58/Monday, March 26, 20'l2/Rules and Regulations First-aid measures afier ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. No additional information available Firefighting instructions : use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent tire-fighting water from entering environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. H-t041;),y**:rq'lf"r-lii!"tsiqt"h!f*i'itah!111!4- Prevent enfry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. See Heading 8. Exposure controls and personal protection. Additional hazards when processed Handle empty containers with care because residual vapors are flammable. 1113012021 EN (English US) 3/1 1 Durakote Medium Viscosity Bonding Putty Safety Data Sheet according to Federal Register/Vol. 77, No. 58/ Monday, March 26, 2[)12/ Rules and Regulations Precautions for safe handling Hygiene measures Use only outdoors or in a well-ventilated area. Avoid breathing DUST, FUMES, MIST, OR VAPORS. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Eliminate all ignition sources if safe to do so. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. No open flames. No smoking. Take precautionary measures against static discharge. Use only non- sparking tools. Do not breathe dust/fume/gas/mist/vapors/spray. Wash hands, forearms and face thoroughly affer handling. Do not eat, drink or smoke when using this product. Technical measures Storage conditions Incompatible products Incompatible materials Proper grounding procedures to avoid static elec(ricity should be followed. Ground/bond container and receiving equipment. lJse explosion-proof electrical/ventilating/lighting equipment. Keep in fireproof place. Keep onlyin the original container in a cool, well ventilated place away from : Keep container tightly closed. Strong bases. Strong acids. Sources of ignition. Direct sunlight. Heat sources. H:MJmS :44:4*Ti!-illi44*1il 5 pm; aspect
ratio > 3:1, as determined by the membrane filter
method at 400-450X magnification (4-mm objective),
using phase-contrast illumination)
silicon dioxide, amorphous (7631-86-9)
Not applicable
Personal protective equipment:
Avoid all unnecessary exposure.
Hand protection:
Wear proter.tive gloves.
Eye protection:
Chemical goggles or safety glasses
Skin and body protection:
Wear suitable protective clothing
Respiratory protection:
Wear appropriate mask
Other information:
Do not eat, drink or smoke during use.
11/30/2021
EN (English US)
4/1 1

Durakote Medium Viscosity Bonding Putty
Safety Data Sheet
according to Federal Register/Vol. 77, No 58/ Monday, March 28, 2012 I Rules and Regulations
H41MH;W=lM=*ttitst’litiiitt’!”tr#>’!ltlr4-
Physical state
Color
Odor
Odor threshold
pH
Melting point
Freezing point
Boiling point
Flash point
Relative evaporation rate (butyl acetate=1)
Flammability (solid, gas)
Vapor pressure
Relative vapor density at 20 “C
Relative density
Solubility
Log Pow
Auto-ignition temperature
Decomposition temperature
Viscosity, kinemafic
Viscosity, dynamic
Explosion limits
Explosive properties
Oxidizing properties
Liquid
Colourless to yellow
characteristic
No data available
No data available
No data available
No data available
275-295aF
86 “F
No data available
Highly flammable liquid and vapor. Flammable liquid and vapor.
No data available
No data available
i .41
No data available
No data available
No data available
No data available
No data available
No data available
No data available
Explosive under influence of a flame.
No data available
VOC content
“a 2j ‘!/o
t’l:(04(IJQ,ll4$1-!Itl’!ta@!#!)k’J ‘
No reactivity hazard other than the effects described in sub-sec(ions below.
Polymerization can result in formation of solid deposits, even iri vapour space. Highly flammable liquid and vapor. Not established. Flammable liquid and
vapor. May form flammable/explosive vapor-air mixture.
Not established.
Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Heat. Sparks.
Strong acids. Strong bases.
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
H:MJ(I)’lkRff4T:!:l’!’;T:lfa’ThmiMii’iffm-!i
Acute toxicity (oral)
Acute toxicity (dermal)
Acute toxicity (inhalation)
Not classified
Not classified
Not classified
sLkDy5re0noer’i:nrahtb’kad (100A2-5) 5000 mg/kg (Rat Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
I1/30/2021
EN (English US)
5/1 1

Durakote Medium Viscosity Bonding Putty
Safety Data Sheet
according to Federal Register/Vol. 77, No. 58 I Monday, March 28, 2012/Rules and Regulations
styrene, inhibited (10042-5)
LD50 dermal rat
I
> 2000 mg/kg body weight (OECD 402: Acute Dermal Toxicity, 24 h, Rat, Male/female,
Experimental value, Dermal)
I LD50 dermal rabbit
5010 mg/kg (Rabbit: Literature study)
LC50 Inhalation – Rat
11.8 mg/l air (4 h, Rat, Inconclusive, insufficient data, Inhalation (vapours))
, LC50 Inhalation – Rat [ppml 2770 ppm/4h (Rat; Literature study)
‘ ATE US (oral)
5000 mg/kg body weight
I ATE US (dermal)
5010 mg/kg body weight
i ATE US (gases) 2770 ppmV/4h
ATE US (vapors)
1l mg/1/4h
ATE US (dust, mist)
1.5 mg/1/4h
cobalt(II) 2-ethylhexanoate (1 36-!52-7)
LD50 oral rat
13E1x2p9ermlmge/kngtab. ovdayiuew>eight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure; “”LD50 dermal rat
> 2000 mg/kg body weight (Rat: Weight of evidence; OECD 402: Acute Dermal Toxicity)
ATE US (oral)
3129 mg/kg body weight
silicon dioxide, amorphous (7631-86-9)
LD50 oral rat
> 4 0000 mg/kg (Rat, Oral)
LD50 dermal rabbit
> 5000 mg/kg (Rabbit, Dermal)
Skin corrosion/irritation
Serious eye damage/irritation
Respiratory or skin sensitization
Germ cell mutagenicity
Carcinogenicity
Causes skin irritation.
Causes serious eye irritation.
Not classified
Not classified
Not classified.
istyrene,inhibited(100-42-5)
IIARC group ‘ 2B – Possibly carcinogenic to humans
National Toxicology Program (NTP) Status I Reasonably anticipated to be Human Carcinogen
7cobalt(II)2-ettiylhexanoate(136-52-7)
“‘
IARC group
i 2B – Possibly carcinogenic to humans
talc (14807-96-6)
IARC group
i 3 – Not claffisifiable, 2B – Possibly carcinogenic to HUMANS
Reproductive toxicity
STOT-single exposure
: Suspected of damaging fertility or the unborn child.
: May cause respiratory irritation.
istyrene, inhibited (100-42-5)
ISTOT-single exposure I May cause respiratory irritation.
STOT-repeated exposure
: Causes damage to organs through prolonged or repeated exposure.
styrene, inhibited (100-42-5)
STOT-repeated exposure
Causes damage to organs through prolonged or repeated exposure.
Aspiration hazard
Viscosity, kinematic
Potential Adverse human health effects and
symptoms
Symptoms/effects
Symptoms/effects afier inhalation
Symptoms/effects affer skin contact
Symptoms/effects afler eye contact
: Not classified
: No data available
: Harmful if inhaled. Based on available data, the classifica(ion criteria are not met.
May cause genetic defects (avoid skin contact and inhalation.). May cause cancer (avoid skin
contact and inhalation.). Suspected of damaging fertility or the unborn child. Causes damage to
organs through prolonged or repeated exposure.
Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled. May cause respiratory irritation.
Causes skin irritation.
Causes serious eye irritation.
11/30/2021
EN (English 11S)
6/1 1

Durakote Medium Viscosity Bonding Putty
Safety Data Sheet
according to Federal Register/Vol 77, No 58/Monday, March 26, 2012/Rules and Regulations
H4m!*isiva:$+ttoiair+iiiiffaiiiihiitaii
Ecology – general
Dangerous for the environment. Harmful to aquatic life.
styrene, inhibited (100-42-5)
LC50 fish 1
10 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Flow-through
system, Fresh water, Experimental value, GLP)
EC50 Daphnia 1
4.7 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Flow-
through system, Fresh water, Experimental value, GLP)
ErC50 (algae)
4.9 mg/l (EPA OTS 797.1050, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, GLP)
cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 1
46.51 mg/l (LOEC: ASTM; 96 h; Pimephales promelas; Flow-through system: Fresh water;
Read-across)
EC50 Daphnia 1
0.212 mg/l (NOEC; ASTM: 48 h; Ceriodaphnia dubia; Static system: Salt water; Read-across)
LC50 fish 2
54.1 mg/l (LC50; ASTM: 96 h; Pimephales promelas Flow-through system Fresh water;
Read-across)
EC50 Daphnia 2
0.605 mg/l (LC50: ASTM; 48 h Ceriodaphnia dubia Static system; Salt water; Read-across)
Threshold limit algae 1
144 pg/1 (ErC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
Threshold limit algae 2
32.2 pg/l (NOEC; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
talc (14807-96-6)
LC50 fish 1 i > 100 g/l (24 h, Brachydanio rerio, Semi-static system)
silicon dioxide, amorphous (7631-86-9)
LC50 fish I
> 10000 mg/l (96 h, Brachydanio rerio, Literature)
EC50 Daphnia 1
> 10000 mg/l (24 h, Daphnia magna, Literature)
Persistence and degradabilify I Not established.
styrene, inhibited (100-42-6)
Persistence and degradability
Biodegrad’a61e in the soil. Readily biodegradable in water. I
Chemical oxygen demand (COD) II 2.8 g Oz/g substance
I
ThOD I
3.07 g Ojg substance
BOD (% ofThOD) , 0.42(Literaturestudy) “‘
“‘ “‘
cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability i Readily biodegradable in water. No (test)data on mobility of the substance available.
talc (14807-96-6)
Persistence and degradability
i Biodegradability: not applicable.
Biochemical oxygen demand (BOD) IiNot applicable
Chemical oxygen demand (COD) i
I
I
I
Not applicable
‘ThOD I
Not applicable
‘ BOD (% or “rhoo) i
Not applicable
silicon dioxide, amorphous (7631-86-9)
Persistence and degradability
Biodegradability in soil: not applicable. Biodegradability: not applicable.
Chemical oxygen demand (COD)
Not applicable (inorganic)
ThOD
I
Not applicable (inorganic)
11 /30/2021
EN (English LIS)
7/1 1

Durakote Medium Viscosity Bonding Putty
Safety Data Sheet
according to Federal Register/ Vol. 77, No. 58/Monday, March 26, 2012/Rules and Regulations
styrene, inhibited (100-42-5)
BCF fish 1
35.5 (Carassius auratus, Literature study)
i Log Pow 2.96 (Experimental value, OECD 107: Partition Coefficient (n-ocfanol/water): Shake Flask
Method, 25 oC)
Bioaccumulative potential
Low potential for bioaccumulation (Log Kow < 4). cobalt(II) 2-ethylhexanoate (1 36-52-7) BCF fish 1 ..._ i 1.2 (BCF 131 days; Seriola quinqueradiata; Static system; Salt water; Read-across) Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). silicon dioxide, amorphous (7631-86-9) styrene, inhibited (100-42-5) Suface tension 0.032 N/m (20 oC) Log Koc 2.55 (log Koc, Estimated value) Ecology - soil Low potential for adsorption in soil. cobalt(II) 2-ethylhexanoate (1 36-52-7) Surface tension i O.064 N/m (20 oC 1 g/l) silicon dioxide, amorphous (763'l-86-9) Other information : Avoid release to the environment. H:%Jt*R&J4elH*!#lfa"re)i!I!*f=)t'!tMi! Regional legislation (waste) Waste treatment methods Product/Packaging disposal recommendations Additional information Ecology - waste materials CI:(*JllR,if:,ffltt'1i!I-T-Ig4mtalmhl

40658776_SDS.pdf

Page 1/12
Safety Data Sheet
acc. to OSHA HCS
Printing date 10/24/2019 Reviewed on 10/24/2019
49.1.7
1 Identification
Product identifier
Trade name: APG1750 S Black
Article number:I025761
Application of the substance / the mixturePolyester resin
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
ehs-us@axson.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
* 2 Hazard(s) identification
Classification of the substance or mixture
GHS02 Flame
Flam. Liq. 3 H226 Flammable liquid and vapor.
GHS08 Health hazard
Carc. 2 H351 Suspected of causing cancer.
GHS09 Environment
Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
(Contd. on page 2)
US

Page 2/12
Safety Data Sheet
acc. to OSHA HCS
Printing date 10/24/2019 Reviewed on 10/24/2019
Trade name: APG1750 S Black
(Contd. of page 1)
49.1.7
Skin Sens. 1 H317 May cause an allergic skin reaction.
Aquatic Acute 3 H402 Harmful to aquatic life.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS02GHS07GHS08GHS09
Signal wordWarning
Hazard-determining components of labeling:
methyl methacrylate
cobalt(II) 2-ethylhexanoate
Hazard statements
Flammable liquid and vapor.
Causes skin irritation.
Causes serious eye irritation.
May cause an allergic skin reaction.
Suspected of causing cancer.
Harmful to aquatic life.
Toxic to aquatic life with long lasting effects.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Keep away from heat/sparks/open flames/hot surfaces. – No smoking.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting/equipment.
Avoid breathing dust/fume/gas/mist/vapors/spray
Wear protective gloves/protective clothing/eye protection/face protection.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Wash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
2
3
0
Health = 2
Fire = 3
Reactivity = 0
(Contd. on page 3)
US

Page 3/12
Safety Data Sheet
acc. to OSHA HCS
Printing date 10/24/2019 Reviewed on 10/24/2019
Trade name: APG1750 S Black
(Contd. of page 2)
49.1.7
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
2
3
0
Health = 2
Fire = 3
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
* 3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 25013-15-4
EINECS: 246-562-2
Vinyl toluene 25- 50%
CAS: 80-62-6
EINECS: 201-297-1
methyl methacrylate 1-5%
CAS: 136-52-7
EINECS: 205-250-6
cobalt(II) 2-ethylhexanoate 0.25-<1% CAS: 91-99-6 N,N-Bishydroxyethyl-m-toluidine 0.1-1% * 4 First-aid measures Description of first aid measures General information:Immediately remove any clothing soiled by the product. After inhalation: Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in side position for transportation. After skin contact:Immediately wash with water and soap and rinse thoroughly. After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. After swallowing:If symptoms persist consult doctor. Information for doctor: Most important symptoms and effects, both acute and delayedNo further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available. US (Contd. on page 4) Page 4/12 Safety Data Sheet acc. to OSHA HCS Printing date 10/24/2019 Reviewed on 10/24/2019 Trade name: APG1750 S Black (Contd. of page 3) 49.1.7 * 5 Fire-fighting measures Extinguishing media Suitable extinguishing agents: Sand. Do not use water. CO2, sand, extinguishing powder. Do not use water. For safety reasons unsuitable extinguishing agents:Water Special hazards arising from the substance or mixtureNo further relevant information available. Advice for firefighters Protective equipment:Wear self-contained respiratory protective device. Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. * 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. Environmental precautions: Do not allow product to reach sewage system or any water course. Inform respective authorities in case of seepage into water course or sewage system. Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. Do not flush with water or aqueous cleansing agents Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. Protective Action Criteria for Chemicals PAC-1: 80-62-6 methyl methacrylate 17 ppm PAC-2: 80-62-6 methyl methacrylate 120 ppm PAC-3: 80-62-6 methyl methacrylate 570 ppm US (Contd. on page 5) Page 5/12 Safety Data Sheet acc. to OSHA HCS Printing date 10/24/2019 Reviewed on 10/24/2019 Trade name: APG1750 S Black (Contd. of page 4) 49.1.7 * 7 Handling and storage Handling: Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Open and handle receptacle with care. Prevent formation of aerosols. Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. Protect against electrostatic charges. Keep respiratory protective device available. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles:No special requirements. Information about storage in one common storage facility:Not required. Further information about storage conditions:Keep receptacle tightly sealed. Specific end use(s)No further relevant information available. * 8 Exposure controls/personal protection Additional information about design of technical systems:No further data; see item 7. Control parameters Components with limit values that require monitoring at the workplace: The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit. At this time, the other constituents have no known exposure limits. 25013-15-4 Vinyl toluene PEL Long-term value: 480 mg/m , 100 ppm REL Long-term value: 480 mg/m , 100 ppm TLV Short-term value: 483 mg/m , 100 ppm Long-term value: 242 mg/m , 50 ppm 80-62-6 methyl methacrylate PEL Long-term value: 410 mg/m , 100 ppm REL Long-term value: 410 mg/m , 100 ppm TLV Short-term value: 410 mg/m , 100 ppm Long-term value: 205 mg/m , 50 ppm DSEN Additional information:The lists that were valid during the creation were used as basis. (Contd. on page 6) US Page 6/12 Safety Data Sheet acc. to OSHA HCS Printing date 10/24/2019 Reviewed on 10/24/2019 Trade name: APG1750 S Black (Contd. of page 5) 49.1.7 Exposure controls Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Store protective clothing separately. Avoid contact with the eyes and skin. Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Tightly sealed goggles * 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Liquid Color: Black Odor: Strong, aromatic Odor threshold: Not determined. (Contd. on page 7) US Page 7/12 Safety Data Sheet acc. to OSHA HCS Printing date 10/24/2019 Reviewed on 10/24/2019 Trade name: APG1750 S Black (Contd. of page 6) 49.1.7 pH-value: Not determined. Change in condition Melting point/Melting range:Undetermined. Boiling point/Boiling range:170 C (338 F) Flash point: 32 C (89.6 F) Flammability (solid, gaseous):Not applicable. Decomposition temperature: Not determined. Auto igniting: Product is not selfigniting. Danger of explosion: Product is not explosive. However, formation of explosive air/vapor mixtures are possible. Explosion limits: Lower: Not determined. Upper: Not determined. Vapor pressure: Not determined. Density at 20 C (68 F): 1.39 g/cm (11.6 lbs/gal) Relative density Not determined. Vapor density Not determined. Evaporation rate Not determined. Solubility in / Miscibility with Water: Not miscible or difficult to mix. Partition coefficient (n-octanol/water):Not determined. Viscosity: Dynamic: Not determined. Kinematic: Not determined. Solvent content: Organic solvents: 27.5 % VOC content: 31.62 % 439.5 g/l / 3.67 lb/gal Solids content: 33.1 % Other information No further relevant information available. * 10 Stability and reactivity ReactivityNo further relevant information available. Chemical stability Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications. Possibility of hazardous reactionsNo dangerous reactions known. (Contd. on page 8) US Page 8/12 Safety Data Sheet acc. to OSHA HCS Printing date 10/24/2019 Reviewed on 10/24/2019 Trade name: APG1750 S Black (Contd. of page 7) 49.1.7 Conditions to avoidNo further relevant information available. Incompatible materials:No further relevant information available. Hazardous decomposition products:Carbon monoxide and carbon dioxide * 11 Toxicological information Information on toxicological effects Acute toxicity: LD/LC50 values that are relevant for classification: Oral LD50 4,000 mg/kg (rat) Dermal LD50 4,000 mg/kg (rat) Inhalative LC50/4 h 7,093 mg/l (rat) Primary irritant effect: on the skin:Irritant to skin and mucous membranes. on the eye:Irritating effect. Sensitization:Sensitization possible through skin contact. Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Irritant Carcinogenic categories IARC (International Agency for Research on Cancer) 25013-15-4 Vinyl toluene 3 80-62-6 methyl methacrylate 3 64-17-5 ethanol 1 136-52-7 cobalt(II) 2-ethylhexanoate 2B NTP (National Toxicology Program) None of the ingredients is listed. OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. * 12 Ecological information Toxicity Aquatic toxicity:No further relevant information available. Persistence and degradabilityNo further relevant information available. Behavior in environmental systems: Bioaccumulative potentialNo further relevant information available. Mobility in soilNo further relevant information available. Ecotoxical effects: Remark:Toxic for fish (Contd. on page 9) US Page 9/12 Safety Data Sheet acc. to OSHA HCS Printing date 10/24/2019 Reviewed on 10/24/2019 Trade name: APG1750 S Black (Contd. of page 8) 49.1.7 Additional ecological information: General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. Also poisonous for fish and plankton in water bodies. Toxic for aquatic organisms Results of PBT and vPvB assessment PBT:Not applicable. vPvB:Not applicable. Other adverse effectsNo further relevant information available. 13 Disposal considerations Waste treatment methods Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. Uncleaned packagings: Recommendation:Disposal must be made according to official regulations. * 14 Transport information UN-Number DOT, IMDG, IATA UN1866 UN proper shipping name As stated below: DOT Resin solution IMDG, IATA RESIN SOLUTION Transport hazard class(es) DOT Class 3 Flammable liquids Label 3 Packing group DOT III Environmental hazards: Marine pollutant: No Special precautions for user Not applicable. (Contd. on page 10) US Page 10/12 Safety Data Sheet acc. to OSHA HCS Printing date 10/24/2019 Reviewed on 10/24/2019 Trade name: APG1750 S Black (Contd. of page 9) 49.1.7 EMS Number: F-E,S-E Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. UN "Model Regulation": not regulated * 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Sara Section 355 (extremely hazardous substances): None of the ingredients is listed. Section 313 (Specific toxic chemical listings): 80-62-6 methyl methacrylate 136-52-7 cobalt(II) 2-ethylhexanoate TSCA (Toxic Substances Control Act): All components have the value ACTIVE. Chemicals regulated by TSCA Section 12(b) None of the ingredients is listed. Chemical regulated by TSCA 5(a)(2)rule: None of the ingredients is listed. Hazardous Air Pollutants 80-62-6 methyl methacrylate 136-52-7 cobalt(II) 2-ethylhexanoate 7439-96-5 manganese 108-10-1 4-methylpentan-2-one Proposition 65 Chemicals known to cause cancer: 1317-65-3 Calcium Carbonate 14808-60-7 Quartz (SiO2) 108-10-1 4-methylpentan-2-one Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. Chemicals known to cause developmental toxicity: 64-17-5 ethanol (Contd. on page 11) US Page 11/12 Safety Data Sheet acc. to OSHA HCS Printing date 10/24/2019 Reviewed on 10/24/2019 Trade name: APG1750 S Black (Contd. of page 10) 49.1.7 108-10-1 4-methylpentan-2-one Carcinogenic categories EPA (Environmental Protection Agency) 80-62-6 methyl methacrylate E, NL TLV (Threshold Limit Value established by ACGIH) 25013-15-4 Vinyl toluene A4 80-62-6 methyl methacrylate A4 NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. Listed in CWC Regulations None of the ingredients is listed. GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS). Hazard pictograms GHS02GHS07GHS08GHS09 Signal wordWarning Hazard-determining components of labeling: methyl methacrylate cobalt(II) 2-ethylhexanoate Hazard statements Flammable liquid and vapor. Causes skin irritation. Causes serious eye irritation. May cause an allergic skin reaction. Suspected of causing cancer. Harmful to aquatic life. Toxic to aquatic life with long lasting effects. Precautionary statements Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/equipment. Avoid breathing dust/fume/gas/mist/vapors/spray Wear protective gloves/protective clothing/eye protection/face protection. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Wash contaminated clothing before reuse. Store locked up. (Contd. on page 12) US Page 12/12 Safety Data Sheet acc. to OSHA HCS Printing date 10/24/2019 Reviewed on 10/24/2019 Trade name: APG1750 S Black (Contd. of page 11) 49.1.7 Dispose of contents/container in accordance with local/regional/national/international regulations. Chemical safety assessment:A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Date of preparation / last revision10/24/2019 / 8 Abbreviations and acronyms: IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) VOC: Volatile Organic Compounds (USA, EU) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative NIOSH: National Institute for Occupational Safety OSHA: Occupational Safety & Health TLV: Threshold Limit Value PEL: Permissible Exposure Limit REL: Recommended Exposure Limit Flam. Liq. 3: Flammable liquids Category 3 Skin Irrit. 2: Skin corrosion/irritation Category 2 Eye Irrit. 2A: Serious eye damage/eye irritation Category 2A Skin Sens. 1: Skin sensitisation Category 1 Carc. 2: Carcinogenicity Category 2 Aquatic Acute 3: Hazardous to the aquatic environment - acute aquatic hazard Category 3 Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard Category 2 * Data compared to the previous version altered. US

406303E75D_SDS.pdf

Dura-Kote Marine Mact Shaw All Blue
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date: 11/07/2022

11/07/2022 EN (English US) Page 1

SECTION 1: Identification

1.1. Identification
Product form : Mixture
Trade name : Dura-Kote Marine Mact Shaw All Blue
CAS-No. : mixture
Product code : 6303-XXX
Formula : N/A
Other means of identification : Unsaturated Polyester Resin Gel Coat

1.2. Recommended use and restrictions on use
Use of the substance/mixture : coatings

1.3. Supplier
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316

909-546-1162
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887

1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887

SECTION 2: Hazard(s) identification

2.1. Classification of the substance or mixture
GHS US classification
Flammable liquids Category 3 H226 Flammable liquid and vapor
Skin corrosion/irritation Category 2 H315 Causes skin irritation
Serious eye damage/eye irritation Category 2 H319 Causes serious eye irritation
Skin sensitization, Category 1 H317 May cause an allergic skin reaction
Reproductive toxicity Category 1B H360 May damage fertility or the unborn child
Specific target organ toxicity (repeated exposure) Category 1 H372 Causes damage to organs through prolonged or repeated exposure
Hazardous to the aquatic environment – Acute Hazard Category 2 H401 Toxic to aquatic life

Full text of H statements : see section 16

2.2. GHS Label elements, including precautionary statements
GHS US labeling
Hazard pictograms (GHS US) :

Signal word (GHS US) : Danger
Hazard statements (GHS US) : H226 – Flammable liquid and vapor
H315 – Causes skin irritation
H317 – May cause an allergic skin reaction
H319 – Causes serious eye irritation
H360 – May damage fertility or the unborn child
H372 – Causes damage to organs through prolonged or repeated exposure
H401 – Toxic to aquatic life
Precautionary statements (GHS US) : P201 – Obtain special instructions before use.
P202 – Do not handle until all safety precautions have been read and understood.
P210 – Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P233 – Keep container tightly closed.
P240 – Ground/Bond container and receiving equipment.
P241 – Use explosion-proof electrical, lighting, ventilating equipment.
P242 – Use only non-sparking tools.

Dura-Kote Marine Mact Shaw All Blue
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according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

11/07/2022 EN (English US) 2/10

P243 – Take precautionary measures against static discharge.
P260 – Do not breathe dust, fume, mist, spray, vapors.
P261 – Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 – Wash EXPOSED AREA. thoroughly after handling.
P270 – Do not eat, drink or smoke when using this product.
P272 – Contaminated work clothing must not be allowed out of the workplace.
P273 – Avoid release to the environment.
P280 – Wear eye protection, protective clothing, protective gloves.
P302+P352 – If on skin: Wash with plenty of water.
P303+P361+P353 – If on skin (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower.
P305+P351+P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P313 – If exposed or concerned: Get medical advice/attention.
P314 – Get medical advice/attention if you feel unwell.
P321 – Specific treatment (see SEEK MEDICAL AID. on this label).
P332+P313 – If skin irritation occurs: Get medical advice/attention.
P333+P313 – If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 – If eye irritation persists: Get medical advice/attention.
P362+P364 – Take off contaminated clothing and wash it before reuse.
P363 – Wash contaminated clothing before reuse.
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish.
P403+P235 – Store in a well-ventilated place. Keep cool.
P405 – Store locked up.
P501 – Dispose of contents/container to LOCAL, STATE, AND NATIONAL REGULATIONS..

2.3. Other hazards which do not result in classification
No additional information available
2.4. Unknown acute toxicity (GHS US)
Not applicable
SECTION 3: Composition/Information on ingredients

3.1. Substances
Not applicable
3.2. Mixtures
Comments : VOC < 37 % Name Product identifier % GHS US classification styrene, inhibited (CAS-No.) 100-42-5 18 - 44 Flam. Liq. 3, H226 Acute Tox. 4 (Inhalation:vapour), H332 Skin Irrit. 2, H315 Eye Irrit. 2, H319 STOT RE 1, H372 Asp. Tox. 1, H304 Aquatic Acute 2, H401 1,6-hexanediol diacrylate (CAS-No.) 13048-33-4 1 - 5 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 cobalt(II) 2-ethylhexanoate (CAS-No.) 136-52-7 0.1 - 0.5 Eye Irrit. 2, H319 Skin Sens. 1, H317 Repr. 1B, H360 Aquatic Acute 1, H400 Aquatic Chronic 2, H411 Full text of hazard classes and H-statements : see section 16 SECTION 4: First-aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Allow affected person to breathe fresh air. Allow the victim to rest. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: wash throughly for five minutes. seek medical attention. Get medical advice/attention. Specific treatment (see seek medical attention. on this label). Dura-Kote Marine Mact Shaw All Blue Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 11/07/2022 EN (English US) 3/10 First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: SEEK IMMEDIATE MEDICAL ATTENTION. Get medical advice/attention. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a poison center/doctor/physician if you feel unwell. 4.2. Most important symptoms and effects (acute and delayed) Potential Adverse human health effects and symptoms : Harmful if inhaled. Based on available data, the classification criteria are not met. Symptoms/effects : May cause genetic defects (avoid skin contact and inhalation.). May cause cancer (avoid skin contact and inhalation.). Symptoms/effects after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if inhaled. Symptoms/effects after skin contact : Causes skin irritation. Symptoms/effects after eye contact : Causes serious eye irritation. 4.3. Immediate medical attention and special treatment, if necessary Treat symptomatically. SECTION 5: Fire-fighting measures 5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media : Sand. Water spray. Dry powder. Foam. Carbon dioxide. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Specific hazards arising from the chemical Fire hazard : Highly flammable liquid and vapor. Flammable liquid and vapor. Explosion hazard : May form flammable/explosive vapor-air mixture. Reactivity in case of fire : No reactivity hazard other than the effects described in sub-sections below. 5.3. Special protective equipment and precautions for fire-fighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No smoking. 6.1.1. For non-emergency personnel Protective equipment : Gloves. Protective goggles. Protective clothing. Emergency procedures : Ventilate spillage area. Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Do not attempt to take action without suitable protective equipment. Equip cleanup crew with proper protection. For further information refer to section 8: "Exposure controls/personal protection". Emergency procedures : Ventilate area. 6.2. Environmental precautions Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up For containment : Dam up the liquid spill. Contain released product, pump into suitable containers. Methods for cleaning up : Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. Other information : Dispose of materials or solid residues at an authorized site. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. For further information refer to section 13. Dura-Kote Marine Mact Shaw All Blue Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 11/07/2022 EN (English US) 4/10 SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed : Handle empty containers with care because residual vapors are flammable. Precautions for safe handling : Wear personal protective equipment. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. No open flames. No smoking. Use only non- sparking tools. Use only outdoors or in a well-ventilated area. Avoid breathing DUST, FUMES, MIST, OR VAPORS. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Eliminate all ignition sources if safe to do so. Take precautionary measures against static discharge. Hygiene measures : Wash HANDS thoroughly after handling. Do not eat, drink or smoke when using this product. Always wash hands after handling the product. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical, ventilating and lighting equipment. equipment. Storage conditions : Keep only in the original container in a cool, well ventilated place away from : HEAT SPARKS OR OPEN FLAMES. Keep in fireproof place. Keep container tightly closed. Store in a well- ventilated place. Keep cool. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. Heat sources. SECTION 8: Exposure controls/personal protection 8.1. Control parameters styrene, inhibited (100-42-5) ACGIH ACGIH TWA (ppm) 20 ppm ACGIH ACGIH STEL (ppm) 40 ppm cobalt(II) 2-ethylhexanoate (136-52-7) Not applicable 1,6-hexanediol diacrylate (13048-33-4) Not applicable 8.2. Appropriate engineering controls Appropriate engineering controls : Ensure exposure is below occupational exposure limits (where available). Ensure good ventilation of the work station. Environmental exposure controls : Avoid release to the environment. 8.3. Individual protection measures/Personal protective equipment Personal protective equipment: Avoid all unnecessary exposure. Hand protection: Wear protective gloves. Eye protection: Chemical goggles or safety glasses. Safety glasses Skin and body protection: Wear suitable protective clothing Respiratory protection: Wear appropriate mask Other information: Do not eat, drink or smoke during use. Dura-Kote Marine Mact Shaw All Blue Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 11/07/2022 EN (English US) 5/10 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Color : Variable in colour, depending on the composition Odor : characteristic Odor threshold : No data available pH : No data available Melting point : Not applicable Freezing point : No data available Boiling point : >= 393 F

Flash point : >= 87 F

Relative evaporation rate (butyl acetate=1) : No data available

Flammability (solid, gas) : Highly flammable liquid and vapor. Flammable liquid and vapor.

Vapor pressure : No data available

Relative vapor density at 20 C : No data available

Relative density : 1.3

Density : 1.3 kg/l
Solubility : No data available

Log Pow : No data available

Auto-ignition temperature : No data available

Decomposition temperature : No data available

Viscosity, kinematic : No data available
Viscosity, dynamic : No data available

Explosion limits : No data available

Explosive properties : No data available

Oxidizing properties : No data available

9.2. Other information
No additional information available
SECTION 10: Stability and reactivity

10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.

10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Not established. Highly flammable liquid and vapor. May form
flammable/explosive vapor-air mixture. Flammable liquid and vapor.

10.3. Possibility of hazardous reactions
Not established.

10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Heat. Sparks.

10.5. Incompatible materials
Strong acids. Strong bases.

10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified

styrene, inhibited (100-42-5)
LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)

Dura-Kote Marine Mact Shaw All Blue
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

11/07/2022 EN (English US) 6/10

styrene, inhibited (100-42-5)
LD50 dermal rat > 2000 mg/kg body weight (OECD 402: Acute Dermal Toxicity, 24 h, Rat, Male / female,
Experimental value, Dermal)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 Inhalation – Rat 11.8 mg/l air (4 h, Rat, Inconclusive, insufficient data, Inhalation (vapours))
LC50 Inhalation – Rat [ppm] 2770 ppm/4h (Rat; Literature study)
ATE US (vapors) 11 mg/l/4h

cobalt(II) 2-ethylhexanoate (136-52-7)
LD50 oral rat 3129 mg/kg body weight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat > 2000 mg/kg body weight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)
ATE US (oral) 3129 mg/kg body weight

Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitization : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified

styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans
National Toxicology Program (NTP) Status Reasonably anticipated to be Human Carcinogen

cobalt(II) 2-ethylhexanoate (136-52-7)
IARC group 2B – Possibly carcinogenic to humans

Reproductive toxicity : May damage fertility or the unborn child.
STOT-single exposure : Not classified

STOT-repeated exposure : Causes damage to organs through prolonged or repeated exposure.

styrene, inhibited (100-42-5)
STOT-repeated exposure Causes damage to organs through prolonged or repeated exposure.

Aspiration hazard : Not classified
Viscosity, kinematic : No data available

Potential Adverse human health effects and
symptoms
: Harmful if inhaled. Based on available data, the classification criteria are not met.
Symptoms/effects : May cause genetic defects (avoid skin contact and inhalation.). May cause cancer (avoid skin
contact and inhalation.).
Symptoms/effects after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.

SECTION 12: Ecological information

12.1. Toxicity
Ecology – general : Dangerous for the environment. Harmful to aquatic life.

styrene, inhibited (100-42-5)
LC50 fish 1 10 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Flow-through
system, Fresh water, Experimental value, GLP)
EC50 Daphnia 1 4.7 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Flow-
through system, Fresh water, Experimental value, GLP)
ErC50 (algae) 4.9 mg/l (EPA OTS 797.1050, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, GLP)

cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 1 46.51 mg/l (LOEC; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 1 0.212 mg/l (NOEC; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)

Dura-Kote Marine Mact Shaw All Blue
Safety Data Sheet
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11/07/2022 EN (English US) 7/10

cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 2 54.1 mg/l (LC50; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 2 0.605 mg/l (LC50; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
Threshold limit algae 1 144 g/l (ErC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
Threshold limit algae 2 32.2 g/l (NOEC; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)

12.2. Persistence and degradability
Dura-Kote Marine Mact Shaw All Blue (mixture)
Persistence and degradability Not established.

styrene, inhibited (100-42-5)
Persistence and degradability Biodegradable in the soil. Readily biodegradable in water.
Chemical oxygen demand (COD)
2.8 g O /g substance
ThOD
3.07 g O /g substance
BOD (% of ThOD) 0.42 (Literature study)

cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability Readily biodegradable in water. No (test)data on mobility of the substance available.

1,6-hexanediol diacrylate (13048-33-4)
Persistence and degradability Inherently biodegradable.

12.3. Bioaccumulative potential
Dura-Kote Marine Mact Shaw All Blue (mixture)
Bioaccumulative potential Not established.

styrene, inhibited (100-42-5)
BCF fish 1 35.5 (Carassius auratus, Literature study)
Log Pow 2.96 (Experimental value, OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). cobalt(II) 2-ethylhexanoate (136-52-7) BCF fish 1 1.2 (BCF; 131 days; Seriola quinqueradiata; Static system; Salt water; Read-across) Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). 1,6-hexanediol diacrylate (13048-33-4) Bioaccumulative potential No bioaccumulation data available. 12.4. Mobility in soil styrene, inhibited (100-42-5) Surface tension 0.032 N/m (20 C) Log Koc 2.55 (log Koc, Estimated value) Ecology - soil Low potential for adsorption in soil. cobalt(II) 2-ethylhexanoate (136-52-7) Surface tension 0.064 N/m (20 C; 1 g/l) 12.5. Other adverse effects Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Disposal methods Regional legislation (waste) : Disposal must be done according to official regulations. Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions. Sewage disposal recommendations : Do not discharge into drains. Dura-Kote Marine Mact Shaw All Blue Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 11/07/2022 EN (English US) 8/10 Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to approved disposal site.. Additional information : Handle empty containers with care because residual vapors are flammable. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Transport document description : UN1866 Resin solution, 3, III UN-No.(DOT) : UN1866 Proper Shipping Name (DOT) : Resin solution Class (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120 Packing group (DOT) : III - Minor Danger Hazard labels (DOT) : 3 - Flammable liquid DOT Packaging Non Bulk (49 CFR 173.xxx) : 173 DOT Packaging Bulk (49 CFR 173.xxx) : 242 DOT Special Provisions (49 CFR 172.102) : B1 - If the material has a flash point at or above 38 C (100 F) and below 93 C (200 F), then the bulk packaging requirements of 173.241 of this subchapter are applicable. If the material has a flash point of less than 38 C (100 F), then the bulk packaging requirements of 173.242 of this subchapter are applicable. B52 - Notwithstanding the provisions of 173.24b of this subchapter, non-reclosing pressure relief devices are authorized on DOT 57 portable tanks. IB3 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1 and 31HA2, 31HB2, 31HN2, 31HD2 and 31HH2). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized, except for UN2672 (also see Special Provision IP8 in Table 2 for UN2672). T2 - 1.5 178.274(d)(2) Normal............. 178.275(d)(3) TP1 - The maximum degree of filling must not exceed the degree of filling determined by the following: Degree of filling = 97 / 1 + a (tr - tf) Where: tr is the maximum mean bulk temperature during transport, and tf is the temperature in degrees celsius of the liquid during filling. DOT Packaging Exceptions (49 CFR 173.xxx) : 150 DOT Quantity Limitations Passenger aircraft/rail (49 CFR 173.27) : 60 L DOT Quantity Limitations Cargo aircraft only (49 CFR 175.75) : 220 L DOT Vessel Stowage Location : A - The material may be stowed on deck or under deck on a cargo vessel and on a passenger vessel. Emergency Response Guide (ERG) Number : 127 Other information : No supplementary information available. Transportation of Dangerous Goods Transport by sea Transport document description (IMDG) : UN 1866 RESIN SOLUTION, 3, III UN-No. (IMDG) : 1866 Proper Shipping Name (IMDG) : RESIN SOLUTION Class (IMDG) : 3 - Flammable liquids Packing group (IMDG) : III - substances presenting low danger Air transport Transport document description (IATA) : UN 1866 Resin solution, 3, III UN-No. (IATA) : 1866 Dura-Kote Marine Mact Shaw All Blue Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 11/07/2022 EN (English US) 9/10 Proper Shipping Name (IATA) : Resin solution Class (IATA) : 3 - Flammable Liquids Packing group (IATA) : III - Minor Danger SECTION 15: Regulatory information 15.1. US Federal regulations styrene, inhibited (100-42-5) Listed on the United States TSCA (Toxic Substances Control Act) inventory Subject to reporting requirements of United States SARA Section 313 Listed on EPA Hazardous Air Pollutant (HAPS) CERCLA RQ 1000 lb SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Reactive hazard Fire hazard Delayed (chronic) health hazard cobalt(II) 2-ethylhexanoate (136-52-7) Listed on the United States TSCA (Toxic Substances Control Act) inventory 1,6-hexanediol diacrylate (13048-33-4) Listed on the United States TSCA (Toxic Substances Control Act) inventory 15.2. International regulations CANADA styrene, inhibited (100-42-5) Listed on the Canadian DSL (Domestic Substances List) cobalt(II) 2-ethylhexanoate (136-52-7) Listed on the Canadian DSL (Domestic Substances List) 1,6-hexanediol diacrylate (13048-33-4) Listed on the Canadian DSL (Domestic Substances List) EU-Regulations No additional information available National regulations styrene, inhibited (100-42-5) Listed on IARC (International Agency for Research on Cancer) Listed as carcinogen on NTP (National Toxicology Program) 15.3. US State regulations Dura-Kote Marine Mact Shaw All Blue (mixture) State or local regulations U.S. - Pennsylvania - RTK (Right to Know) List U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List U.S. - New Jersey - TCPA - Extraordinarily Hazardous Substances (EHS) U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Massachusetts - Right To Know List styrene, inhibited (100-42-5) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significant risk level (NSRL) Maximum allowable dose level (MADL) Yes No No No 27 g/day Dura-Kote Marine Mact Shaw All Blue Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 11/07/2022 EN (English US) 10/10 Component State or local regulations styrene, inhibited(100-42-5) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List SECTION 16: Other information according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision date : 11/07/2022 Other information : None. Full text of H-phrases: H226 Flammable liquid and vapor H304 May be fatal if swallowed and enters airways H315 Causes skin irritation H317 May cause an allergic skin reaction H319 Causes serious eye irritation H332 Harmful if inhaled H360 May damage fertility or the unborn child H372 Causes damage to organs through prolonged or repeated exposure H400 Very toxic to aquatic life H401 Toxic to aquatic life H411 Toxic to aquatic life with long lasting effects NFPA health hazard : 2 - Materials that, under emergency conditions, can cause temporary incapacitation or residual injury. NFPA fire hazard : 3 - Liquids and solids (including finely divided suspended solids) that can be ignited under almost all ambient temperature conditions. NFPA reactivity : 2 - Materials that readily undergo violent chemical change at elevated temperatures and pressures. Hazard Rating Health : 2 Moderate Hazard - Temporary or minor injury may occur Flammability : 3 Serious Hazard - Materials capable of ignition under almost all normal temperature conditions. Includes flammable liquids with flash points below 73 F and boiling points above 100 F. as well as liquids with flash points between 73 F and 100 F. (Classes IB IC) Physical : 1 Slight Hazard - Materials that are normally stable but can become unstable (self-react) at high temperatures and pressures. Materials may react non-violently with water or undergo hazardous polymerization in the absence of inhibitors. Personal protection : H H - Splash goggles, Gloves, Synthetic apron, Vapor respirator SDS US (GHS HazCom 2012) To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.

40616831_SDS.pdf

Page 1/13
Safety Data Sheet
acc. to OSHA HCS
Printing date 10/24/2019 Reviewed on 10/24/2019
49.1.7
1 Identification
Product identifier
Trade name: APG 1750 S Orange Resin
Article number:I025505
Application of the substance / the mixtureSprayable polyester gel coat
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
ehs-us@axson.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
* 2 Hazard(s) identification
Classification of the substance or mixture
GHS02 Flame
Flam. Liq. 3 H226 Flammable liquid and vapor.
GHS08 Health hazard
Carc. 2 H351 Suspected of causing cancer.
GHS09 Environment
Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
(Contd. on page 2)
US

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Safety Data Sheet
acc. to OSHA HCS
Printing date 10/24/2019 Reviewed on 10/24/2019
Trade name: APG 1750 S Orange Resin
(Contd. of page 1)
49.1.7
Skin Sens. 1 H317 May cause an allergic skin reaction.
Aquatic Acute 3 H402 Harmful to aquatic life.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS02GHS07GHS08GHS09
Signal wordWarning
Hazard-determining components of labeling:
methyl methacrylate
cobalt(II) 2-ethylhexanoate
Hazard statements
Flammable liquid and vapor.
Causes skin irritation.
Causes serious eye irritation.
May cause an allergic skin reaction.
Suspected of causing cancer.
Harmful to aquatic life.
Toxic to aquatic life with long lasting effects.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Keep away from heat/sparks/open flames/hot surfaces. – No smoking.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting/equipment.
Avoid breathing dust/fume/gas/mist/vapors/spray
Wear protective gloves/protective clothing/eye protection/face protection.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Wash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
2
2
0
Health = 2
Fire = 2
Reactivity = 0
(Contd. on page 3)
US

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Safety Data Sheet
acc. to OSHA HCS
Printing date 10/24/2019 Reviewed on 10/24/2019
Trade name: APG 1750 S Orange Resin
(Contd. of page 2)
49.1.7
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
2
2
0
Health = 2
Fire = 2
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
* 3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 25013-15-4
EINECS: 246-562-2
Vinyl toluene 25- 50%
CAS: 80-62-6
EINECS: 201-297-1
methyl methacrylate 1-5%
CAS: 136-52-7
EINECS: 205-250-6
cobalt(II) 2-ethylhexanoate 0.25-<1% CAS: 91-99-6 N,N-Bishydroxyethyl-m-toluidine 0.1-1% 4 First-aid measures Description of first aid measures General information:Immediately remove any clothing soiled by the product. After inhalation: Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in side position for transportation. After skin contact:Immediately wash with water and soap and rinse thoroughly. After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. After swallowing:If symptoms persist consult doctor. Information for doctor: Most important symptoms and effects, both acute and delayedNo further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available. US (Contd. on page 4) Page 4/13 Safety Data Sheet acc. to OSHA HCS Printing date 10/24/2019 Reviewed on 10/24/2019 Trade name: APG 1750 S Orange Resin (Contd. of page 3) 49.1.7 5 Fire-fighting measures Extinguishing media Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Special hazards arising from the substance or mixtureNo further relevant information available. Advice for firefighters Protective equipment:Wear self-contained respiratory protective device. Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. * 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. Environmental precautions: Do not allow product to reach sewage system or any water course. Inform respective authorities in case of seepage into water course or sewage system. Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. Protective Action Criteria for Chemicals PAC-1: 80-62-6 methyl methacrylate 17 ppm PAC-2: 80-62-6 methyl methacrylate 120 ppm PAC-3: 80-62-6 methyl methacrylate 570 ppm 7 Handling and storage Handling: Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Open and handle receptacle with care. Prevent formation of aerosols. (Contd. on page 5) US Page 5/13 Safety Data Sheet acc. to OSHA HCS Printing date 10/24/2019 Reviewed on 10/24/2019 Trade name: APG 1750 S Orange Resin (Contd. of page 4) 49.1.7 Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. Protect against electrostatic charges. Keep respiratory protective device available. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles:No special requirements. Information about storage in one common storage facility:Not required. Further information about storage conditions:Keep receptacle tightly sealed. Specific end use(s)No further relevant information available. * 8 Exposure controls/personal protection Additional information about design of technical systems:No further data; see item 7. Control parameters Components with limit values that require monitoring at the workplace: The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit. At this time, the other constituents have no known exposure limits. 25013-15-4 Vinyl toluene PEL Long-term value: 480 mg/m , 100 ppm REL Long-term value: 480 mg/m , 100 ppm TLV Short-term value: 483 mg/m , 100 ppm Long-term value: 242 mg/m , 50 ppm 80-62-6 methyl methacrylate PEL Long-term value: 410 mg/m , 100 ppm REL Long-term value: 410 mg/m , 100 ppm TLV Short-term value: 410 mg/m , 100 ppm Long-term value: 205 mg/m , 50 ppm DSEN Additional information:The lists that were valid during the creation were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Store protective clothing separately. Avoid contact with the eyes and skin. Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. (Contd. on page 6) US Page 6/13 Safety Data Sheet acc. to OSHA HCS Printing date 10/24/2019 Reviewed on 10/24/2019 Trade name: APG 1750 S Orange Resin (Contd. of page 5) 49.1.7 Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Tightly sealed goggles * 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Pasty Color: Orange Odor: Aromatic Odor threshold: Not determined. pH-value: Not determined. Change in condition Melting point/Melting range:Undetermined. Boiling point/Boiling range:170 C (338 F) Flash point: 50 C (122 F) Flammability (solid, gaseous):Not applicable. Ignition temperature: 494 C (921.2 F) Decomposition temperature: Not determined. (Contd. on page 7) US Page 7/13 Safety Data Sheet acc. to OSHA HCS Printing date 10/24/2019 Reviewed on 10/24/2019 Trade name: APG 1750 S Orange Resin (Contd. of page 6) 49.1.7 Auto igniting: Product is not selfigniting. Danger of explosion: Product is not explosive. However, formation of explosive air/vapor mixtures are possible. Explosion limits: Lower: 1.1 Vol % Upper: 5.2 Vol % Vapor pressure at 20 C (68 F):1 hPa (0.8 mm Hg) Density at 20 C (68 F): 1.29 g/cm (10.77 lbs/gal) Relative density Not determined. Vapor density Not determined. Evaporation rate Not determined. Solubility in / Miscibility with Water: Not miscible or difficult to mix. Partition coefficient (n-octanol/water):Not determined. Viscosity: Dynamic: Not determined. Kinematic: Not determined. Solvent content: Organic solvents: 28.4 % VOC content: 32.58 % 420.3 g/l / 3.51 lb/gal Solids content: 30.8 % Other information No further relevant information available. 10 Stability and reactivity ReactivityNo further relevant information available. Chemical stability Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications. Possibility of hazardous reactionsNo dangerous reactions known. Conditions to avoidNo further relevant information available. Incompatible materials:No further relevant information available. Hazardous decomposition products:Carbon monoxide and carbon dioxide US (Contd. on page 8) Page 8/13 Safety Data Sheet acc. to OSHA HCS Printing date 10/24/2019 Reviewed on 10/24/2019 Trade name: APG 1750 S Orange Resin (Contd. of page 7) 49.1.7 * 11 Toxicological information Information on toxicological effects Acute toxicity: Primary irritant effect: on the skin:Irritant to skin and mucous membranes. on the eye:Irritating effect. Sensitization:Sensitization possible through skin contact. Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Irritant Carcinogenic categories IARC (International Agency for Research on Cancer) 25013-15-4 Vinyl toluene 3 80-62-6 methyl methacrylate 3 64-17-5 ethanol 1 136-52-7 cobalt(II) 2-ethylhexanoate 2B NTP (National Toxicology Program) None of the ingredients is listed. OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. * 12 Ecological information Toxicity Aquatic toxicity:No further relevant information available. Persistence and degradabilityNo further relevant information available. Behavior in environmental systems: Bioaccumulative potentialNo further relevant information available. Mobility in soilNo further relevant information available. Ecotoxical effects: Remark:Toxic for fish Additional ecological information: General notes: Water hazard class 3 (Self-assessment): extremely hazardous for water Do not allow product to reach ground water, water course or sewage system, even in small quantities. Danger to drinking water if even extremely small quantities leak into the ground. Also poisonous for fish and plankton in water bodies. Toxic for aquatic organisms Results of PBT and vPvB assessment PBT:Not applicable. vPvB:Not applicable. (Contd. on page 9) US Page 9/13 Safety Data Sheet acc. to OSHA HCS Printing date 10/24/2019 Reviewed on 10/24/2019 Trade name: APG 1750 S Orange Resin (Contd. of page 8) 49.1.7 Other adverse effectsNo further relevant information available. 13 Disposal considerations Waste treatment methods Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. Uncleaned packagings: Recommendation:Disposal must be made according to official regulations. * 14 Transport information UN-Number DOT, IMDG, IATA UN1866 UN proper shipping name DOT Resin solution IMDG RESIN SOLUTION, MARINE POLLUTANT IATA RESIN SOLUTION Transport hazard class(es) DOT Class 3 Flammable liquids Label 3 IMDG Class 3 Flammable liquids Label 3 IATA Class 3 Flammable liquids (Contd. on page 10) US Page 10/13 Safety Data Sheet acc. to OSHA HCS Printing date 10/24/2019 Reviewed on 10/24/2019 Trade name: APG 1750 S Orange Resin (Contd. of page 9) 49.1.7 Label 3 Packing group DOT, IMDG, IATA III Environmental hazards: Marine pollutant: Yes Yes Symbol (fish and tree) Special precautions for user Warning: Flammable liquids Danger code (Kemler): III EMS Number: F-E,S-E Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. Transport/Additional information: DOT Quantity limitations On passenger aircraft/rail: 60 L On cargo aircraft only: 220 L IMDG Limited quantities (LQ) 5L Excepted quantities (EQ) Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml UN "Model Regulation": UN 1866 RESIN SOLUTION, 3, III, ENVIRONMENTALLY HAZARDOUS * 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Sara Section 355 (extremely hazardous substances): None of the ingredients is listed. Section 313 (Specific toxic chemical listings): 80-62-6 methyl methacrylate 136-52-7 cobalt(II) 2-ethylhexanoate TSCA (Toxic Substances Control Act): All components have the value ACTIVE. Chemicals regulated by TSCA Section 12(b) None of the ingredients is listed. (Contd. on page 11) US Page 11/13 Safety Data Sheet acc. to OSHA HCS Printing date 10/24/2019 Reviewed on 10/24/2019 Trade name: APG 1750 S Orange Resin (Contd. of page 10) 49.1.7 Chemical regulated by TSCA 5(a)(2)rule: None of the ingredients is listed. Hazardous Air Pollutants 80-62-6 methyl methacrylate 136-52-7 cobalt(II) 2-ethylhexanoate 108-10-1 4-methylpentan-2-one Proposition 65 Chemicals known to cause cancer: 1317-65-3 Calcium Carbonate 14808-60-7 Quartz (SiO2) 108-10-1 4-methylpentan-2-one Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. Chemicals known to cause developmental toxicity: 64-17-5 ethanol 108-10-1 4-methylpentan-2-one Carcinogenic categories EPA (Environmental Protection Agency) 80-62-6 methyl methacrylate E, NL TLV (Threshold Limit Value established by ACGIH) 25013-15-4 Vinyl toluene A4 80-62-6 methyl methacrylate A4 NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. Listed in CWC Regulations None of the ingredients is listed. GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS). Hazard pictograms GHS02GHS07GHS08GHS09 Signal wordWarning (Contd. on page 12) US Page 12/13 Safety Data Sheet acc. to OSHA HCS Printing date 10/24/2019 Reviewed on 10/24/2019 Trade name: APG 1750 S Orange Resin (Contd. of page 11) 49.1.7 Hazard-determining components of labeling: methyl methacrylate cobalt(II) 2-ethylhexanoate Hazard statements Flammable liquid and vapor. Causes skin irritation. Causes serious eye irritation. May cause an allergic skin reaction. Suspected of causing cancer. Harmful to aquatic life. Toxic to aquatic life with long lasting effects. Precautionary statements Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/equipment. Avoid breathing dust/fume/gas/mist/vapors/spray Wear protective gloves/protective clothing/eye protection/face protection. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations. Chemical safety assessment:A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Date of preparation / last revision10/24/2019 / 13 Abbreviations and acronyms: IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) VOC: Volatile Organic Compounds (USA, EU) PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative NIOSH: National Institute for Occupational Safety OSHA: Occupational Safety & Health TLV: Threshold Limit Value PEL: Permissible Exposure Limit REL: Recommended Exposure Limit (Contd. on page 13) US Page 13/13 Safety Data Sheet acc. to OSHA HCS Printing date 10/24/2019 Reviewed on 10/24/2019 Trade name: APG 1750 S Orange Resin (Contd. of page 12) 49.1.7 Flam. Liq. 3: Flammable liquids Category 3 Skin Irrit. 2: Skin corrosion/irritation Category 2 Eye Irrit. 2A: Serious eye damage/eye irritation Category 2A Skin Sens. 1: Skin sensitisation Category 1 Carc. 2: Carcinogenicity Category 2 Aquatic Acute 3: Hazardous to the aquatic environment - acute aquatic hazard Category 3 Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard Category 2 * Data compared to the previous version altered. US

4051506102_SDS.pdf

TRANSPARENT TINTS ALL COLORS
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date: 12/17/2019

12/17/2019 EN (English US) Page 1

SECTION 1: Identification

1.1. Identification
Product form : Mixture
Trade name : TRANSPARENT TINTS ALL COLORS
CAS-No. : mixture
Product code : 515-XXX
Formula : na

1.2. Recommended use and restrictions on use
No additional information available

1.3. Supplier
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316

909-546-1162
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887

1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887

SECTION 2: Hazard(s) identification

2.1. Classification of the substance or mixture
GHS US classification
Not classified

2.2. GHS Label elements, including precautionary statements
GHS US labeling
No labeling applicable

2.3. Other hazards which do not result in classification
No additional information available
2.4. Unknown acute toxicity (GHS US)
Not applicable
SECTION 3: Composition/Information on ingredients

3.1. Substances
Not applicable
3.2. Mixtures

Name Product identifier % GHS US classification
styrene, inhibited

(CAS-No.) 100-42-5 <= 87 Flam. Liq. 3, H226 Acute Tox. 4 (Inhalation), H332 Acute Tox. 4 (Inhalation:vapour), H332 Skin Irrit. 2, H315 Eye Irrit. 2A, H319 Carc. 2, H351 Repr. 2, H361 STOT SE 3, H335 STOT RE 1, H372 Aquatic Acute 2, H401 Full text of hazard classes and H-statements : see section 16 SECTION 4: First-aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). TRANSPARENT TINTS ALL COLORS Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 12/17/2019 EN (English US) 2/9 First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Allow affected person to breathe fresh air. Allow the victim to rest. First-aid measures after skin contact : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. First-aid measures after eye contact : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists. Rinse eyes with water as a precaution. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a poison center/doctor/physician if you feel unwell. 4.2. Most important symptoms and effects (acute and delayed) Potential Adverse human health effects and symptoms : Harmful if inhaled. Based on available data, the classification criteria are not met. Symptoms/effects : May cause genetic defects (avoid skin contact and inhalation.). May cause cancer (avoid skin contact and inhalation.). Not expected to present a significant hazard under anticipated conditions of normal use. Symptoms/effects after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if inhaled. 4.3. Immediate medical attention and special treatment, if necessary Treat symptomatically. SECTION 5: Fire-fighting measures 5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media : Sand. Water spray. Dry powder. Foam. Carbon dioxide. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Specific hazards arising from the chemical Fire hazard : Highly flammable liquid and vapour. Flammable liquid and vapour. Explosion hazard : May form flammable/explosive vapor-air mixture. Reactivity in case of fire : No reactivity hazard other than the effects described in sub-sections below. 5.3. Special protective equipment and precautions for fire-fighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No smoking. 6.1.1. For non-emergency personnel Protective equipment : Gloves. Protective goggles. Protective clothing. Emergency procedures : Ventilate spillage area. Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Do not attempt to take action without suitable protective equipment. Equip cleanup crew with proper protection. For further information refer to section 8: "Exposure controls/personal protection". Emergency procedures : Ventilate area. 6.2. Environmental precautions Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up For containment : Dam up the liquid spill. Contain released product, pump into suitable containers. Methods for cleaning up : Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. Other information : Dispose of materials or solid residues at an authorized site. TRANSPARENT TINTS ALL COLORS Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 12/17/2019 EN (English US) 3/9 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed : Handle empty containers with care because residual vapors are flammable. Precautions for safe handling : Wear personal protective equipment. Use only outdoors or in a well-ventilated area. Avoid breathing DUST, FUMES, MIST, OR VAPORS. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Eliminate all ignition sources if safe to do so. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. No open flames. No smoking. Take precautionary measures against static discharge. Use only non-sparking tools. Hygiene measures : Do not eat, drink or smoke when using this product. Always wash hands after handling the product. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Storage conditions : Keep in fireproof place. Keep only in the original container in a cool, well ventilated place away from : Keep container tightly closed. Store in a well-ventilated place. Keep cool. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. Heat sources. SECTION 8: Exposure controls/personal protection 8.1. Control parameters styrene, inhibited (100-42-5) ACGIH ACGIH TWA (ppm) 20 ppm ACGIH ACGIH STEL (ppm) 40 ppm 8.2. Appropriate engineering controls Appropriate engineering controls : Ensure exposure is below occupational exposure limits (where available). Ensure good ventilation of the work station. Environmental exposure controls : Avoid release to the environment. 8.3. Individual protection measures/Personal protective equipment Personal protective equipment: Avoid all unnecessary exposure. Hand protection: Wear protective gloves. Eye protection: Chemical goggles or safety glasses. Safety glasses Skin and body protection: Wear suitable protective clothing Respiratory protection: Wear appropriate mask Other information: Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid TRANSPARENT TINTS ALL COLORS Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 12/17/2019 EN (English US) 4/9 Color : Colors Odor : characteristic Odor threshold : No data available pH : No data available Melting point : Not applicable Freezing point : No data available Boiling point : 64 C Flash point : 30 - 34 C Relative evaporation rate (butyl acetate=1) : No data available Flammability (solid, gas) : Highly flammable liquid and vapour. Flammable liquid and vapour. Vapor pressure : No data available Relative vapor density at 20 C : No data available Relative density : 0.9 - 1.2 Specific gravity / density : 8.6 - 8.9 g/l Solubility : No data available Log Pow : No data available Auto-ignition temperature : No data available Decomposition temperature : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosion limits : No data available Explosive properties : No data available Oxidizing properties : No data available 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity No reactivity hazard other than the effects described in sub-sections below. 10.2. Chemical stability Polymerization can result in formation of solid deposits, even in vapour space. Highly flammable liquid and vapour. Not established. Flammable liquid and vapour. May form flammable/explosive vapor-air mixture. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Heat. Sparks. 10.5. Incompatible materials Strong acids. Strong bases. 10.6. Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. May release flammable gases. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity (oral) : Not classified Acute toxicity (dermal) : Not classified Acute toxicity (inhalation) : Not classified styrene, inhibited (100-42-5) LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
LD50 dermal rat > 2000 mg/kg body weight (OECD 402: Acute Dermal Toxicity, 24 h, Rat, Male / female,
Experimental value, Dermal)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 inhalation rat (mg/l) 11.8 mg/l air (4 h, Rat, Inconclusive, insufficient data, Inhalation (vapours))

TRANSPARENT TINTS ALL COLORS
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

12/17/2019 EN (English US) 5/9

styrene, inhibited (100-42-5)
LC50 inhalation rat (ppm) 2770 ppm/4h (Rat; Literature study)
ATE US (oral) 5000 mg/kg body weight
ATE US (dermal) 5010 mg/kg body weight
ATE US (gases) 2770 ppmV/4h
ATE US (vapors) 11 mg/l/4h
ATE US (dust, mist) 1.5 mg/l/4h

Skin corrosion/irritation : Not classified
Serious eye damage/irritation : Not classified
Respiratory or skin sensitization : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified.

styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans
National Toxicology Program (NTP) Status Reasonably anticipated to be Human Carcinogen

Reproductive toxicity : Not classified
STOT-single exposure : Not classified

styrene, inhibited (100-42-5)
STOT-single exposure May cause respiratory irritation.

STOT-repeated exposure : Not classified

styrene, inhibited (100-42-5)
STOT-repeated exposure Causes damage to organs through prolonged or repeated exposure.

Aspiration hazard : Not classified
Viscosity, kinematic : No data available

Potential Adverse human health effects and
symptoms
: Harmful if inhaled. Based on available data, the classification criteria are not met.
Symptoms/effects : May cause genetic defects (avoid skin contact and inhalation.). May cause cancer (avoid skin
contact and inhalation.). Not expected to present a significant hazard under anticipated
conditions of normal use.
Symptoms/effects after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled.

SECTION 12: Ecological information

12.1. Toxicity
Ecology – general : The product is not considered harmful to aquatic organisms or to cause long-term adverse
effects in the environment.

styrene, inhibited (100-42-5)
LC50 fish 1 10 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Flow-through
system, Fresh water, Experimental value, GLP)
EC50 Daphnia 1 4.7 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Flow-
through system, Fresh water, Experimental value, GLP)
ErC50 (algae) 4.9 mg/l (EPA OTS 797.1050, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, GLP)

12.2. Persistence and degradability
TRANSPARENT TINTS ALL COLORS (mixture)
Persistence and degradability Not established.

styrene, inhibited (100-42-5)
Persistence and degradability Biodegradable in the soil. Readily biodegradable in water.
Chemical oxygen demand (COD)
2.8 g O /g substance
ThOD
3.07 g O /g substance
BOD (% of ThOD) 0.42 (Literature study)

TRANSPARENT TINTS ALL COLORS
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

12/17/2019 EN (English US) 6/9

12.3. Bioaccumulative potential
TRANSPARENT TINTS ALL COLORS (mixture)
Bioaccumulative potential Not established.

styrene, inhibited (100-42-5)
BCF fish 1 35.5 (Carassius auratus, Literature study)
Log Pow 2.96 (Experimental value, OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). 12.4. Mobility in soil styrene, inhibited (100-42-5) Surface tension 0.032 N/m (20 C) Log Koc 2.55 (log Koc, Estimated value) Ecology - soil Low potential for adsorption in soil. 12.5. Other adverse effects Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Disposal methods Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions. Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. Additional information : Handle empty containers with care because residual vapors are flammable. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Transport document description : UN1866 Resin solution, 3, II UN-No.(DOT) : UN1866 Proper Shipping Name (DOT) : Resin solution Class (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120 Packing group (DOT) : II - Medium Danger Hazard labels (DOT) : 3 - Flammable liquid DOT Packaging Non Bulk (49 CFR 173.xxx) : 173 DOT Packaging Bulk (49 CFR 173.xxx) : 242 TRANSPARENT TINTS ALL COLORS Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 12/17/2019 EN (English US) 7/9 DOT Special Provisions (49 CFR 172.102) : 149 - When transported as a limited quantity or a consumer commodity, the maximum net capacity specified in 173.150(b)(2) of this subchapter for inner packaging may be increased to 5 L (1.3 gallons). 383 - Packages containing toy plastic or paper caps for toy pistols described as UN0349, Articles, explosive, n.o.s. (Toy caps), 1.4S or NA0337, Toy caps, 1.4S are not subject to the subpart E (labeling) requirements of this part when offered for transportation by motor vehicle, rail freight, cargo vessel, and cargo aircraft and, notwithstanding the packing method assigned in 173.62 of this subchapter, in conformance with the following conditions: B52 - Notwithstanding the provisions of 173.24b of this subchapter, non-reclosing pressure relief devices are authorized on DOT 57 portable tanks. IB2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized. T4 - 2.65 178.274(d)(2) Normal............. 178.275(d)(3) TP1 - The maximum degree of filling must not exceed the degree of filling determined by the following: Degree of filling = 97 / 1 + a (tr - tf) Where: tr is the maximum mean bulk temperature during transport, and tf is the temperature in degrees celsius of the liquid during filling. TP8 - A portable tank having a minimum test pressure of 1.5 bar (150 kPa) may be used when the flash point of the hazardous material transported is greater than 0 C (32 F). DOT Packaging Exceptions (49 CFR 173.xxx) : 150 DOT Quantity Limitations Passenger aircraft/rail (49 CFR 173.27) : 5 L DOT Quantity Limitations Cargo aircraft only (49 CFR 175.75) : 60 L DOT Vessel Stowage Location : B - (i) The material may be stowed on deck or under deck on a cargo vessel and on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers, or one passenger per each 3 m of overall vessel length; and (ii) On deck only on passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this section is exceeded. Emergency Response Guide (ERG) Number : 127 Other information : No supplementary information available. Transportation of Dangerous Goods Not applicable Transport by sea Transport document description (IMDG) : UN 1866 RESIN SOLUTION, 3, II UN-No. (IMDG) : 1866 Proper Shipping Name (IMDG) : RESIN SOLUTION Class (IMDG) : 3 - Flammable liquids Packing group (IMDG) : II - substances presenting medium danger Air transport Transport document description (IATA) : UN 1866 Resin solution, 3, II UN-No. (IATA) : 1866 Proper Shipping Name (IATA) : Resin solution Class (IATA) : 3 - Flammable Liquids Packing group (IATA) : II - Medium Danger SECTION 15: Regulatory information 15.1. US Federal regulations styrene, inhibited (100-42-5) Listed on the United States TSCA (Toxic Substances Control Act) inventory Subject to reporting requirements of United States SARA Section 313 Listed on EPA Hazardous Air Pollutant (HAPS) CERCLA RQ 1000 lb SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Reactive hazard Fire hazard Delayed (chronic) health hazard TRANSPARENT TINTS ALL COLORS Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 12/17/2019 EN (English US) 8/9 15.2. International regulations CANADA styrene, inhibited (100-42-5) Listed on the Canadian DSL (Domestic Substances List) EU-Regulations No additional information available National regulations styrene, inhibited (100-42-5) Listed on IARC (International Agency for Research on Cancer) Listed as carcinogen on NTP (National Toxicology Program) 15.3. US State regulations TRANSPARENT TINTS ALL COLORS (mixture) State or local regulations U.S. - Pennsylvania - RTK (Right to Know) List U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List U.S. - New Jersey - TCPA - Extraordinarily Hazardous Substances (EHS) U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Massachusetts - Right To Know List styrene, inhibited (100-42-5) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significant risk level (NSRL) Maximum allowable dose level (MADL) Yes No No No 27 g/day Component State or local regulations styrene, inhibited(100-42-5) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List SECTION 16: Other information according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision date : 12/17/2019 Other information : None. Full text of H-phrases: H226 Flammable liquid and vapour H315 Causes skin irritation H319 Causes serious eye irritation H332 Harmful if inhaled H335 May cause respiratory irritation H351 Suspected of causing cancer H361 Suspected of damaging fertility or the unborn child H372 Causes damage to organs through prolonged or repeated exposure H401 Toxic to aquatic life TRANSPARENT TINTS ALL COLORS Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 12/17/2019 EN (English US) 9/9 NFPA health hazard : 1 - Materials that, under emergency conditions, can cause significant irritation. NFPA fire hazard : 2 - Materials that must be moderately heated or exposed to relatively high ambient temperatures before ignition can occur. NFPA reactivity : 1 - Materials that in themselves are normally stable but can become unstable at elevated temperatures and pressures. Hazard Rating Health : 1 Slight Hazard - Irritation or minor reversible injury possible Flammability : 1 Slight Hazard - Materials that must be preheated before ignition will occur. Includes liquids, solids and semi solids having a flash point above 200 F. (Class IIIB) Physical : 1 Slight Hazard - Materials that are normally stable but can become unstable (self-react) at high temperatures and pressures. Materials may react non-violently with water or undergo hazardous polymerization in the absence of inhibitors. Personal protection : H H - Splash goggles, Gloves, Synthetic apron, Vapor respirator SDS US (GHS HazCom 2012) To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.