by | Sep 27, 2025
RED TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue: 01/05/2016 Revision date: 01/05/2016 Supersedes: 09/10/2014
01/05/2016 EN (English US) Page 1
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product form : Mixture
Trade name : RED TOOLING GEL COAT
CAS No : mixture
Product code : 410-001
Formula : na
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : TOOLING GEL COAT
1.3. Details of the supplier of the safety data sheet
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909.877.8477
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
GHS-US classification
Flam. Liq. 3 H226
Skin Irrit. 2 H315
Eye Irrit. 2A H319
Carc. 2 H351
Repr. 2 H361
STOT SE 3 H335
STOT RE 1 H372
2.2. Label elements
GHS-US labeling
Hazard pictograms (GHS-US) :
GHS02
GHS07
GHS08
Signal word (GHS-US) : Danger
Hazard statements (GHS-US) : H226 – Flammable liquid and vapor
H315 – Causes skin irritation
H319 – Causes serious eye irritation
H335 – May cause respiratory irritation
H351 – Suspected of causing cancer
H361 – Suspected of damaging fertility or the unborn child
H372 – Causes damage to organs through prolonged or repeated exposure
Precautionary statements (GHS-US) : P201 – Obtain special instructions before use
P202 – Do not handle until all safety precautions have been read and understood
P210 – Keep away from heat, hot surfaces, open flames, sparks. – No smoking
P233 – Keep container tightly closed
P240 – Ground/bond container and receiving equipment
P241 – Use explosion-proof electrical, lighting, ventilating equipment
P242 – Use only non-sparking tools
P243 – Take precautionary measures against static discharge
P260 – Do not breathe dust, fume, mist, spray, vapors
RED TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/05/2016 EN (English US) 2/10
P264 – Wash EXPOSED AREA. thoroughly after handling
P270 – Do not eat, drink or smoke when using this product
P271 – Use only outdoors or in a well-ventilated area
P280 – Wear eye protection, protective clothing, protective gloves
P302+P352 – IF ON SKIN: Wash with plenty of soap and water
P303+P361+P353 – IF ON SKIN (or hair): Remove/Take off immediately all contaminated
clothing. Rinse skin with water/shower
P304+P340 – IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable
for breathing
P305+P351+P338 – If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P308+P313 – IF exposed or concerned: Get medical advice/attention
P312 – Call a POISON CENTER or doctor/physician if you feel unwell
P314 – Get medical advice and attention if you feel unwell
P321 – Specific treatment (see SEEK MEDICAL AID. on this label)
P332+P313 – If skin irritation occurs: Get medical advice/attention
P337+P313 – If eye irritation persists: Get medical advice/attention
P362 – Take off contaminated clothing and wash it before reuse
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish
P403+P233 – Store in a well-ventilated place. Keep container tightly closed
P403+P235 – Store in a well-ventilated place. Keep cool
P405 – Store locked up
P501 – Dispose of contents/container to LOCAL, STATE, AND NATIONAL REGULATIONS.
2.3. Other hazards
No additional information available
2.4. Unknown acute toxicity (GHS-US)
No data available
SECTION 3: Composition/Information on ingredients
3.1. Substance
Not applicable
Full text of H-phrases: see section 16
3.2. Mixture
Name Product identifier % GHS-US classification
Unsaturated Polyester Resin (CAS No) TRADE SECRET <= 50 Not classified
styrene, inhibited (CAS No) 100-42-5 <= 38.73 Flam. Liq. 3, H226
Acute Tox. 4 (Inhalation:vapour),
H332
Skin Irrit. 2, H315
Eye Irrit. 2A, H319
Carc. 2, H351
Repr. 2, H361
STOT SE 3, H335
STOT RE 1, H372
Asp. Tox. 1, H304
LEADS FREE COLOR DISPERSION (CAS No) Proprietary <= 10 Not classified
methyl ethyl ketone (CAS No) 78-93-3 <= 4 Flam. Liq. 2, H225
STOT SE 3, H336
cobalt(II) 2-ethylhexanoate (CAS No) 136-52-7 <= 0.5 Carc. 2, H351
SECTION 4: First aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice
(show the label where possible).
First-aid measures after inhalation : Allow victim to breathe fresh air. Allow the victim to rest. Remove victim to fresh air and keep at
rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you
feel unwell.
First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Wash
with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs:
wash throughly for five minutes. seek medical attention. Get medical advice/attention. Specific
treatment (see seek medical attention. on this label).
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: SEEK IMMEDIATE MEDICAL ATTENTION. Get
medical advice/attention.
RED TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/05/2016 EN (English US) 3/10
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries : May cause genetic defects (avoid skin contact and inhalation.). May cause cancer (avoid skin
contact and inhalation.).
Symptoms/injuries after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled.
Symptoms/injuries after skin contact : Causes skin irritation.
Symptoms/injuries after eye contact : Causes serious eye irritation.
4.3. Indication of any immediate medical attention and special treatment needed
No additional information available
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Highly flammable liquid and vapor. Flammable liquid and vapor.
Explosion hazard : May form flammable/explosive vapor-air mixture.
Reactivity : No reactivity hazard other than the effects described in sub-sections below.
5.3. Advice for firefighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No
smoking.
6.1.1. For non-emergency personnel
Protective equipment : Gloves. Protective goggles. Protective clothing.
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Dam up the liquid spill. Contain released substance, pump into suitable containers.
Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect
spillage. Store away from other materials.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapors are flammable.
Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Provide good ventilation in process area to prevent formation of
vapor. No open flames. No smoking. Use only non-sparking tools. Use only outdoors or in a well-
ventilated area. Avoid breathing DUST, FUMES, MIST, OR VAPORS. Obtain special instructions
before use. Do not handle until all safety precautions have been read and understood. Eliminate
all ignition sources if safe to do so. Take precautionary measures against static discharge.
Hygiene measures : Wash HANDS thoroughly after handling.
RED TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/05/2016 EN (English US) 4/10
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond
container and receiving equipment. Use explosion-proof electrical, ventilating and lighting
equipment. equipment.
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : HEAT SPARKS
OR OPEN FLAMES. Keep in fireproof place. Keep container tightly closed.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.
7.3. Specific end use(s)
No additional information available
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
styrene, inhibited (100-42-5)
USA ACGIH ACGIH TWA (ppm) 20 ppm
USA ACGIH ACGIH STEL (ppm) 20 ppm
methyl ethyl ketone (78-93-3)
USA ACGIH ACGIH TWA (ppm) 200 ppm
USA ACGIH ACGIH STEL (ppm) 200 ppm
8.2. Exposure controls
Appropriate engineering controls : Ensure exposure is below occupational exposure limits (where available).
Personal protective equipment : Avoid all unnecessary exposure.
Hand protection : Wear protective gloves.
Eye protection : Chemical goggles or safety glasses.
Skin and body protection : Wear suitable protective clothing.
Respiratory protection : Wear appropriate mask.
Other information : Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Color : red.
Odor : characteristic.
Odor threshold : No data available
pH : No data available
Relative evaporation rate (butyl acetate=1) : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : 79 - 146 C
Flash point : -6.67 C
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapor pressure : No data available
Relative vapor density at 20 C : No data available
Relative density : 1.1
Solubility : No data available
Log Pow : No data available
Log Kow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
RED TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/05/2016 EN (English US) 5/10
Oxidizing properties : No data available
Explosive limits : No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Not established. Highly flammable liquid and vapor. May form
flammable/explosive vapor-air mixture. Flammable liquid and vapor.
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Heat. Sparks.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity : Not classified
RED TOOLING GEL COAT ( f )mixture
ATE CLP (vapors) 11.000 mg/l/4h
styrene, inhibited (100-42-5)
LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
LD50 dermal rat 2820 mg/kg (Rat; Literature study; OECD 402: Acute Dermal Toxicity; >2000 mg/kg
bodyweight; Rat; Experimental value)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 inhalation rat (mg/l) 12 mg/l/4h (Rat; Literature study)
LC50 inhalation rat (ppm) 2770 ppm/4h (Rat; Literature study)
ATE CLP (oral) 5000.000 mg/kg body weight
ATE CLP (dermal) 2820.000 mg/kg body weight
ATE CLP (gases) 2770.000 ppmV/4h
ATE CLP (vapors) 12.000 mg/l/4h
ATE CLP (dust, mist) 12.000 mg/l/4h
methyl ethyl ketone (78-93-3)
LD50 oral rat 2737 mg/kg (Rat; Equivalent or similar to OECD 423; Read-across; 2054 mg/kg; Rat;
Equivalent or similar to OECD 423; Read-across; 2328 mg/kg; Rat)
LD50 dermal rabbit 6480 mg/kg (Rabbit; Experimental value; Equivalent or similar to OECD 402; >10; Rabbit)
LC50 inhalation rat (mg/l) 34 mg/l/4h (Rat; Literature study)
LC50 inhalation rat (ppm) 11300 ppm/4h (Rat; Literature study)
ATE CLP (oral) 2737.000 mg/kg body weight
ATE CLP (dermal) 6480.000 mg/kg body weight
ATE CLP (gases) 11300.000 ppmV/4h
ATE CLP (vapors) 34.000 mg/l/4h
ATE CLP (dust, mist) 34.000 mg/l/4h
cobalt(II) 2-ethylhexanoate (136-52-7)
LD50 oral rat 3129 mg/kg body weight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat > 2000 mg/kg body weight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)
ATE CLP (oral) 3129.000 mg/kg body weight
RED TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/05/2016 EN (English US) 6/10
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitization : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Suspected of causing cancer.
styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans
cobalt(II) 2-ethylhexanoate (136-52-7)
IARC group 2B – Possibly carcinogenic to humans
Reproductive toxicity : Suspected of damaging fertility or the unborn child.
Based on available data, the classification criteria are not met
Specific target organ toxicity (single exposure) : May cause respiratory irritation.
Specific target organ toxicity (repeated
exposure)
: Causes damage to organs through prolonged or repeated exposure.
Based on available data, the classification criteria are not met
Aspiration hazard : Not classified
Based on available data, the classification criteria are not met
Potential Adverse human health effects and
symptoms
: Harmful if inhaled. Based on available data, the classification criteria are not met.
Symptoms/injuries after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled.
Symptoms/injuries after skin contact : Causes skin irritation.
Symptoms/injuries after eye contact : Causes serious eye irritation.
SECTION 12: Ecological information
12.1. Toxicity
styrene, inhibited (100-42-5)
LC50 fish 1 25 mg/l (96 h; Lepomis macrochirus; GLP)
LC50 other aquatic organisms 1 10 – 100 mg/l (96 h)
EC50 Daphnia 1 23 mg/l (48 h; Daphnia magna; Locomotor effect)
LC50 fish 2 32 mg/l (96 h; Pimephales promelas)
EC50 Daphnia 2 27 mg/l (24 h; Daphnia magna; GLP)
TLM fish 1 25.1 mg/l (96 h; Lepomis macrochirus; Soft water)
TLM fish 2 46.4 mg/l (96 h; Pimephales promelas; Soft water)
TLM other aquatic organisms 1 10 – 100,96 h
Threshold limit other aquatic organisms 1 10 – 100,96 h; Pseudomonas putida
Threshold limit other aquatic organisms 2 72 mg/l
Threshold limit algae 1 > 200 mg/l (192 h; Scenedesmus quadricauda; Inhibitory)
Threshold limit algae 2 67 mg/l (Microcystis aeruginosa; Inhibitory)
methyl ethyl ketone (78-93-3)
LC50 fish 1 1690 mg/l (96 h; Lepomis macrochirus; Lethal)
EC50 Daphnia 1 308 mg/l (48 h; Daphnia magna; Locomotor effect)
LC50 fish 2 2990 mg/l (96 h; Pimephales promelas)
TLM fish 1 5600 mg/l (96 h; Gambusia affinis)
TLM fish 2 1690 mg/l (96 h; Lepomis macrochirus)
TLM other aquatic organisms 1 > 1000 ppm (96 h)
Threshold limit algae 1 110 mg/l (168 h; Microcystis aeruginosa)
Threshold limit algae 2 4300 mg/l (192 h; Scenedesmus quadricauda)
cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 1 54.1 mg/l (96 h; Pimephales promelas)
EC50 Daphnia 1 2618 g/l (48 h)
Threshold limit algae 1 24.1 g/l (7 days)
RED TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/05/2016 EN (English US) 7/10
cobalt(II) 2-ethylhexanoate (136-52-7)
Threshold limit algae 2 90.1 g/l (7 days; Lemna minor; Growth rate)
12.2. Persistence and degradability
RED TOOLING GEL COAT (mixture)
Persistence and degradability Not established.
styrene, inhibited (100-42-5)
Persistence and degradability Readily biodegradable in water. Not readily biodegradable in water. Forming sediments in
water. Non degradable in the soil. Adsorbs into the soil. Photodegradation in the air. Not
established.
Chemical oxygen demand (COD) 2.80 g O /g substance
ThOD 3.07 g O /g substance
BOD (% of ThOD) 0.42 % ThOD
methyl ethyl ketone (78-93-3)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. Not established.
Biochemical oxygen demand (BOD) 1.92 g O /g substance
Chemical oxygen demand (COD) 2.31 g O /g substance
ThOD 2.44 g O /g substance
BOD (% of ThOD) > % ThOD (5 day(s)) > 0.5
LEADS FREE COLOR DISPERSION (Propr ietary)
Persistence and degradability Not established.
cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability Biodegradability in water: no data available.
Unsaturated Polyester Resin (TRADE SECRET)
Persistence and degradability Not established.
12.3. Bioaccumulative potential
RED TOOLING GEL COAT (mixture)
Bioaccumulative potential Not established.
styrene, inhibited (100-42-5)
BCF fish 1 35.5 (Carassius auratus)
BCF other aquatic organisms 1 74
Log Pow 2.96 (Experimental value; OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method; 25 C)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Not established.
methyl ethyl ketone (78-93-3)
Log Pow 0.3 (Experimental value; OECD 117: Partition Coefficient (n-octanol/water), HPLC method; 40
C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
LEADS FREE COLOR DISPERSION (Proprietary)
Bioaccumulative potential Not established.
cobalt(II) 2-ethylhexanoate (136-52-7)
Bioaccumulative potential No bioaccumulation data available.
Unsaturated Polyester Resin (TRADE SECRET)
Bioaccumulative potential Not established.
12.4. Mobility in soil
styrene, inhibited (100-42-5)
Surface tension 0.032 N/m (19 C)
methyl ethyl ketone (78-93-3)
Surface tension 0.024 N/m (20 C)
Ecology - soil Slightly harmful to plants.
RED TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/05/2016 EN (English US) 8/10
cobalt(II) 2-ethylhexanoate (136-52-7)
Surface tension 0.064 N/m (20 C; 1 g/l)
12.5. Other adverse effects
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to approved disposal site.
Additional information : Handle empty containers with care because residual vapors are flammable.
Ecology - waste materials : Avoid release to the environment.
SECTION 14: Transport information
In accordance with DOT
UN-No.(DOT) : UN1866
Proper Shipping Name (DOT) : RESIN SOLUTION
Transport hazard class(es) (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120
Hazard labels (DOT) : 3 - Flammable liquid
Packing group (DOT) : II - Medium Danger
Additional information
Other information : No supplementary information available.
ADR
Transport document description : UN 1866, 3, II, (D/E)
Packing group (ADR) : II
Class (ADR) : 3 - Flammable liquid
Hazard identification number (Kemler No.) : 33
Classification code (ADR) : F1
Hazard labels (ADR) : 3 - Flammable liquids
Orange plates :
Tunnel restriction code : D/E
LQ : 5l
Excepted quantities (ADR) : E2
Transport by sea
UN-No. (IMDG) : 1866
Proper Shipping Name (IMDG) : RESIN SOLUTION
Class (IMDG) : 3 - Flammable liquids
Packing group (IMDG) : II - substances presenting medium danger
Air transport
UN-No. (IATA) : 1866
RED TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/05/2016 EN (English US) 9/10
Proper Shipping Name (IATA) : RESIN SOLUTION
Class (IATA) : 3 - Flammable Liquids
Packing group (IATA) : II - Medium Danger
SECTION 15: Regulatory information
15.1. US Federal regulations
styrene, inhibited (100-42-5)
RQ (Reportable quantity, section 304 of EPA's
List of Lists)
1000 lb
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Reactive hazard
Fire hazard
Delayed (chronic) health hazard
methyl ethyl ketone (78-93-3)
RQ (Reportable quantity, section 304 of EPA's
List of Lists)
5000 lb
15.2. International regulations
CANADA
No additional information available
EU-Regulations
No additional information available
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flam. Liq. 3 H226
Acute Tox. 4 (Inhalation:vapour) H332
Skin Irrit. 2 H315
Eye Irrit. 2 H319
Muta. 1B H340
Carc. 1B H350
Full text of H-phrases: see section 16
Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]
Carc.Cat.2; R45
Muta.Cat.2; R46
F; R11
Xn; R20
Xi; R36/38
Full text of R-phrases: see section 16
15.2.2. National regulations
styrene, inhibited (100-42-5)
Listed on EPA's Hazardous Air Pollutants (HAPS)
15.3. US State regulations
styrene, inhibited (100-42-5)
U.S. - California -
Proposition 65 -
Carcinogens List
U.S. - California -
Proposition 65 -
Developmental Toxicity
U.S. - California -
Proposition 65 -
Reproductive Toxicity -
Female
U.S. - California -
Proposition 65 -
Reproductive Toxicity - Male
Non-significant risk level
(NSRL)
RED TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/05/2016 EN (English US) 10/10
styrene, inhibited (100-42-5)
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
SECTION 16: Other information
Other information : None.
Full text of H-phrases: see section 16:
------ Acute Tox. 4 (Inhalation:vapour) Acute toxicity (inhalation:vapour) Category 4
------ Asp. Tox. 1 Aspiration hazard Category 1
------ Carc. 2 Carcinogenicity Category 2
------ Eye Irrit. 2A Serious eye damage/eye irritation Category 2A
------ Flam. Liq. 2 Flammable liquids Category 2
------ Flam. Liq. 3 Flammable liquids Category 3
------ Repr. 2 Reproductive toxicity Category 2
------ Skin Irrit. 2 Skin corrosion/irritation Category 2
------ STOT RE 1 Specific target organ toxicity (repeated exposure) Category 1
------ STOT SE 3 Specific target organ toxicity (single exposure) Category 3
------ STOT SE 3 Specific target organ toxicity (single exposure) Category 3
------ H225 Highly flammable liquid and vapor
------ H226 Flammable liquid and vapor
------ H304 May be fatal if swallowed and enters airways
------ H315 Causes skin irritation
------ H319 Causes serious eye irritation
------ H332 Harmful if inhaled
------ H335 May cause respiratory irritation
------ H336 May cause drowsiness or dizziness
------ H351 Suspected of causing cancer
------ H361 Suspected of damaging fertility or the unborn child
------ H372 Causes damage to organs through prolonged or repeated exposure
NFPA health hazard : 2 - Intense or continued exposure could cause temporary
incapacitation or possible residual injury unless prompt
medical attention is given.
NFPA fire hazard : 3 - Liquids and solids that can be ignited under almost all
ambient conditions.
NFPA reactivity : 2 - Normally unstable and readily undergo violent
decomposition but do not detonate. Also: may react
violently with water or may form potentially explosive
mixtures with water.
HMIS III Rating
Health : 2 Moderate Hazard - Temporary or minor injury may occur
Flammability : 3 Serious Hazard
Physical : 1 Slight Hazard
Personal Protection : H
SDS US (GHS HazCom 2012)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied
warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.
by | Sep 27, 2025
ORANGE TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue: 01/04/2016 Revision date: 01/04/2016 Supersedes: 09/10/2014
01/04/2016 EN (English US) Page 1
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product form : Mixture
Trade name : ORANGE TOOLING GEL COAT
CAS No : mixture
Product code : 408-001
Formula : na
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : TOOLING GEL COAT
1.3. Details of the supplier of the safety data sheet
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909.877.8477
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
GHS-US classification
Flam. Liq. 3 H226
Skin Irrit. 2 H315
Eye Irrit. 2A H319
Carc. 2 H351
Repr. 2 H361
STOT SE 3 H335
STOT RE 1 H372
2.2. Label elements
GHS-US labeling
Hazard pictograms (GHS-US) :
GHS02
GHS07
GHS08
Signal word (GHS-US) : Danger
Hazard statements (GHS-US) : H226 – Flammable liquid and vapor
H315 – Causes skin irritation
H319 – Causes serious eye irritation
H335 – May cause respiratory irritation
H351 – Suspected of causing cancer
H361 – Suspected of damaging fertility or the unborn child
H372 – Causes damage to organs through prolonged or repeated exposure
Precautionary statements (GHS-US) : P201 – Obtain special instructions before use
P202 – Do not handle until all safety precautions have been read and understood
P210 – Keep away from heat, hot surfaces, open flames, sparks. – No smoking
P233 – Keep container tightly closed
P240 – Ground/bond container and receiving equipment
P241 – Use explosion-proof electrical, lighting, ventilating equipment
P242 – Use only non-sparking tools
P243 – Take precautionary measures against static discharge
P260 – Do not breathe dust, fume, mist, spray, vapors
ORANGE TOOLING GEL COAT
Safety Data Sheet
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P264 – Wash EXPOSED AREA. thoroughly after handling
P270 – Do not eat, drink or smoke when using this product
P271 – Use only outdoors or in a well-ventilated area
P280 – Wear eye protection, protective clothing, protective gloves
P302+P352 – IF ON SKIN: Wash with plenty of soap and water
P303+P361+P353 – IF ON SKIN (or hair): Remove/Take off immediately all contaminated
clothing. Rinse skin with water/shower
P304+P340 – IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable
for breathing
P305+P351+P338 – If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P308+P313 – IF exposed or concerned: Get medical advice/attention
P312 – Call a POISON CENTER or doctor/physician if you feel unwell
P314 – Get medical advice and attention if you feel unwell
P321 – Specific treatment (see SEEK MEDICAL AID. on this label)
P332+P313 – If skin irritation occurs: Get medical advice/attention
P337+P313 – If eye irritation persists: Get medical advice/attention
P362 – Take off contaminated clothing and wash it before reuse
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish
P403+P233 – Store in a well-ventilated place. Keep container tightly closed
P403+P235 – Store in a well-ventilated place. Keep cool
P405 – Store locked up
P501 – Dispose of contents/container to LOCAL, STATE, AND NATIONAL REGULATIONS.
2.3. Other hazards
No additional information available
2.4. Unknown acute toxicity (GHS-US)
No data available
SECTION 3: Composition/Information on ingredients
3.1. Substance
Not applicable
Full text of H-phrases: see section 16
3.2. Mixture
Name Product identifier % GHS-US classification
Unsaturated Polyester Resin (CAS No) TRADE SECRET <= 50 Not classified
styrene, inhibited (CAS No) 100-42-5 <= 38 Flam. Liq. 3, H226
Acute Tox. 4 (Inhalation:vapour),
H332
Skin Irrit. 2, H315
Eye Irrit. 2A, H319
Carc. 2, H351
Repr. 2, H361
STOT SE 3, H335
STOT RE 1, H372
Asp. Tox. 1, H304
LEAD FREE ORANGE (CAS No) Proprietary <= 10 Not classified
methyl ethyl ketone (CAS No) 78-93-3 <= 4 Flam. Liq. 2, H225
STOT SE 3, H336
cobalt(II) 2-ethylhexanoate (CAS No) 136-52-7 <= 0.5 Carc. 2, H351
SECTION 4: First aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice
(show the label where possible).
First-aid measures after inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a
POISON CENTER or doctor/physician if you feel unwell. Allow victim to breathe fresh air. Allow
the victim to rest.
First-aid measures after skin contact : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash
with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs:
Get medical advice/attention. Specific treatment (see ... on this label).
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
ORANGE TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/04/2016 EN (English US) 3/10
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries : May cause genetic defects (avoid skin contact and inhalation.). May cause cancer (avoid skin
contact and inhalation.).
Symptoms/injuries after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled.
Symptoms/injuries after skin contact : Causes skin irritation.
Symptoms/injuries after eye contact : Causes serious eye irritation.
4.3. Indication of any immediate medical attention and special treatment needed
No additional information available
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Highly flammable liquid and vapor. Flammable liquid and vapor.
Explosion hazard : May form flammable/explosive vapor-air mixture.
Reactivity : No reactivity hazard other than the effects described in sub-sections below.
5.3. Advice for firefighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No
smoking.
6.1.1. For non-emergency personnel
Protective equipment : Gloves. Protective goggles. Protective clothing.
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Dam up the liquid spill. Contain released substance, pump into suitable containers.
Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect
spillage. Store away from other materials.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapors are flammable.
Precautions for safe handling : Use only outdoors or in a well-ventilated area. Avoid breathing DUST, FUMES, MIST, OR
VAPORS. Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Eliminate all ignition sources if safe to do so. Wash hands and other
exposed areas with mild soap and water before eating, drinking or smoking and when leaving
work. Provide good ventilation in process area to prevent formation of vapor. No open flames. No
smoking. Take precautionary measures against static discharge. Use only non-sparking tools.
Hygiene measures : Wash ... thoroughly after handling.
ORANGE TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/04/2016 EN (English US) 4/10
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond
container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/
equipment.
Storage conditions : Keep in fireproof place. Keep only in the original container in a cool, well ventilated place away
from : Keep container tightly closed.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.
7.3. Specific end use(s)
No additional information available
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
styrene, inhibited (100-42-5)
USA ACGIH ACGIH TWA (ppm) 20 ppm
USA ACGIH ACGIH STEL (ppm) 20 ppm
methyl ethyl ketone (78-93-3)
USA ACGIH ACGIH TWA (ppm) 200 ppm
USA ACGIH ACGIH STEL (ppm) 200 ppm
8.2. Exposure controls
Appropriate engineering controls : Ensure exposure is below occupational exposure limits (where available).
Personal protective equipment : Avoid all unnecessary exposure.
Hand protection : Wear protective gloves.
Eye protection : Chemical goggles or safety glasses.
Skin and body protection : Wear suitable protective clothing.
Respiratory protection : Wear appropriate mask.
Other information : Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Color : orange.
Odor : characteristic.
Odor threshold : No data available
pH : No data available
Relative evaporation rate (butyl acetate=1) : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : 135 - 146 C
Flash point : 26.7 C
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapor pressure : No data available
Relative vapor density at 20 C : No data available
Relative density : No data available
Specific gravity / density : 1.2
Solubility : No data available
Log Pow : No data available
Log Kow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
ORANGE TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/04/2016 EN (English US) 5/10
Explosive properties : No data available
Oxidizing properties : No data available
Explosive limits : No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Highly flammable liquid and vapor. Not established. Flammable liquid and
vapor. May form flammable/explosive vapor-air mixture.
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Heat. Sparks.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity : Not classified
ORANGE TOOLING GEL COAT ( f )mixture
ATE CLP (vapors) 11.000 mg/l/4h
styrene, inhibited (100-42-5)
LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
LD50 dermal rat 2820 mg/kg (Rat; Literature study; OECD 402: Acute Dermal Toxicity; >2000 mg/kg
bodyweight; Rat; Experimental value)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 inhalation rat (mg/l) 12 mg/l/4h (Rat; Literature study)
LC50 inhalation rat (ppm) 2770 ppm/4h (Rat; Literature study)
ATE CLP (oral) 5000.000 mg/kg body weight
ATE CLP (dermal) 2820.000 mg/kg body weight
ATE CLP (gases) 2770.000 ppmV/4h
ATE CLP (vapors) 12.000 mg/l/4h
ATE CLP (dust, mist) 12.000 mg/l/4h
methyl ethyl ketone (78-93-3)
LD50 oral rat 2737 mg/kg (Rat; Equivalent or similar to OECD 423; Read-across; 2054 mg/kg; Rat;
Equivalent or similar to OECD 423; Read-across; 2328 mg/kg; Rat)
LD50 dermal rabbit 6480 mg/kg (Rabbit; Experimental value; Equivalent or similar to OECD 402; >10; Rabbit)
LC50 inhalation rat (mg/l) 34 mg/l/4h (Rat; Literature study)
LC50 inhalation rat (ppm) 11300 ppm/4h (Rat; Literature study)
ATE CLP (oral) 2737.000 mg/kg body weight
ATE CLP (dermal) 6480.000 mg/kg body weight
ATE CLP (gases) 11300.000 ppmV/4h
ATE CLP (vapors) 34.000 mg/l/4h
ATE CLP (dust, mist) 34.000 mg/l/4h
cobalt(II) 2-ethylhexanoate (136-52-7)
LD50 oral rat 3129 mg/kg body weight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat > 2000 mg/kg body weight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)
ORANGE TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/04/2016 EN (English US) 6/10
cobalt(II) 2-ethylhexanoate (136-52-7)
ATE CLP (oral) 3129.000 mg/kg body weight
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitization : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Suspected of causing cancer.
styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans
cobalt(II) 2-ethylhexanoate (136-52-7)
IARC group 2B – Possibly carcinogenic to humans
Reproductive toxicity : Suspected of damaging fertility or the unborn child.
Based on available data, the classification criteria are not met
Specific target organ toxicity (single exposure) : May cause respiratory irritation.
Specific target organ toxicity (repeated
exposure)
: Causes damage to organs through prolonged or repeated exposure.
Based on available data, the classification criteria are not met
Aspiration hazard : Not classified
Based on available data, the classification criteria are not met
Potential Adverse human health effects and
symptoms
: Harmful if inhaled. Based on available data, the classification criteria are not met.
Symptoms/injuries after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled.
Symptoms/injuries after skin contact : Causes skin irritation.
Symptoms/injuries after eye contact : Causes serious eye irritation.
SECTION 12: Ecological information
12.1. Toxicity
styrene, inhibited (100-42-5)
LC50 fish 1 25 mg/l (96 h; Lepomis macrochirus; GLP)
LC50 other aquatic organisms 1 10 – 100 mg/l (96 h)
EC50 Daphnia 1 23 mg/l (48 h; Daphnia magna; Locomotor effect)
LC50 fish 2 32 mg/l (96 h; Pimephales promelas)
EC50 Daphnia 2 27 mg/l (24 h; Daphnia magna; GLP)
TLM fish 1 25.1 mg/l (96 h; Lepomis macrochirus; Soft water)
TLM fish 2 46.4 mg/l (96 h; Pimephales promelas; Soft water)
TLM other aquatic organisms 1 10 – 100,96 h
Threshold limit other aquatic organisms 1 10 – 100,96 h; Pseudomonas putida
Threshold limit other aquatic organisms 2 72 mg/l
Threshold limit algae 1 > 200 mg/l (192 h; Scenedesmus quadricauda; Inhibitory)
Threshold limit algae 2 67 mg/l (Microcystis aeruginosa; Inhibitory)
methyl ethyl ketone (78-93-3)
LC50 fish 1 1690 mg/l (96 h; Lepomis macrochirus; Lethal)
EC50 Daphnia 1 308 mg/l (48 h; Daphnia magna; Locomotor effect)
LC50 fish 2 2990 mg/l (96 h; Pimephales promelas)
TLM fish 1 5600 mg/l (96 h; Gambusia affinis)
TLM fish 2 1690 mg/l (96 h; Lepomis macrochirus)
TLM other aquatic organisms 1 > 1000 ppm (96 h)
Threshold limit algae 1 110 mg/l (168 h; Microcystis aeruginosa)
Threshold limit algae 2 4300 mg/l (192 h; Scenedesmus quadricauda)
cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 1 54.1 mg/l (96 h; Pimephales promelas)
ORANGE TOOLING GEL COAT
Safety Data Sheet
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cobalt(II) 2-ethylhexanoate (136-52-7)
EC50 Daphnia 1 2618 g/l (48 h)
Threshold limit algae 1 24.1 g/l (7 days)
Threshold limit algae 2 90.1 g/l (7 days; Lemna minor; Growth rate)
12.2. Persistence and degradability
ORANGE TOOLING GEL COAT (mixture)
Persistence and degradability Not established.
styrene, inhibited (100-42-5)
Persistence and degradability Readily biodegradable in water. Not readily biodegradable in water. Forming sediments in
water. Non degradable in the soil. Adsorbs into the soil. Photodegradation in the air. Not
established.
Chemical oxygen demand (COD) 2.80 g O /g substance
ThOD 3.07 g O /g substance
BOD (% of ThOD) 0.42 % ThOD
methyl ethyl ketone (78-93-3)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. Not established.
Biochemical oxygen demand (BOD) 1.92 g O /g substance
Chemical oxygen demand (COD) 2.31 g O /g substance
ThOD 2.44 g O /g substance
BOD (% of ThOD) > % ThOD (5 day(s)) > 0.5
cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability Biodegradability in water: no data available.
Unsaturated Polyester Resin (TRADE SECRET)
Persistence and degradability Not established.
LEAD FREE ORANGE (Proprietary)
Persistence and degradability Not established.
12.3. Bioaccumulative potential
ORANGE TOOLING GEL COAT (mixture)
Bioaccumulative potential Not established.
styrene, inhibited (100-42-5)
BCF fish 1 35.5 (Carassius auratus)
BCF other aquatic organisms 1 74
Log Pow 2.96 (Experimental value; OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method; 25 C)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Not established.
methyl ethyl ketone (78-93-3)
Log Pow 0.3 (Experimental value; OECD 117: Partition Coefficient (n-octanol/water), HPLC method; 40
C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
cobalt(II) 2-ethylhexanoate (136-52-7)
Bioaccumulative potential No bioaccumulation data available.
Unsaturated Polyester Resin (TRADE SECRET)
Bioaccumulative potential Not established.
LEAD FREE ORANGE (Proprietary)
Bioaccumulative potential Not established.
12.4. Mobility in soil
styrene, inhibited (100-42-5)
Surface tension 0.032 N/m (19 C)
ORANGE TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/04/2016 EN (English US) 8/10
methyl ethyl ketone (78-93-3)
Surface tension 0.024 N/m (20 C)
Ecology - soil Slightly harmful to plants.
cobalt(II) 2-ethylhexanoate (136-52-7)
Surface tension 0.064 N/m (20 C; 1 g/l)
12.5. Other adverse effects
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to ...
Additional information : Handle empty containers with care because residual vapors are flammable.
Ecology - waste materials : Avoid release to the environment.
SECTION 14: Transport information
In accordance with DOT
UN-No.(DOT) : UN1866
Proper Shipping Name (DOT) : RESIN SOLUTION
Transport hazard class(es) (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120
Hazard labels (DOT) : 3 - Flammable liquid
Packing group (DOT) : III - Minor Danger
Additional information
Other information : No supplementary information available.
ADR
Transport document description : UN 1866, 3, III, (D/E)
Packing group (ADR) : III
Class (ADR) : 3 - Flammable liquid
Hazard identification number (Kemler No.) : 33
Classification code (ADR) : F1
Hazard labels (ADR) : 3 - Flammable liquids
Orange plates :
Tunnel restriction code : D/E
LQ : 5l
Excepted quantities (ADR) : E2
Transport by sea
UN-No. (IMDG) : 1866
Proper Shipping Name (IMDG) : RESIN SOLUTION
Class (IMDG) : 3 - Flammable liquids
Packing group (IMDG) : III - substances presenting low danger
ORANGE TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/04/2016 EN (English US) 9/10
Air transport
UN-No. (IATA) : 1866
Proper Shipping Name (IATA) : RESIN SOLUTION
Class (IATA) : 3 - Flammable Liquids
Packing group (IATA) : III - Minor Danger
SECTION 15: Regulatory information
15.1. US Federal regulations
styrene, inhibited (100-42-5)
RQ (Reportable quantity, section 304 of EPA's
List of Lists)
1000 lb
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Reactive hazard
Fire hazard
Delayed (chronic) health hazard
methyl ethyl ketone (78-93-3)
RQ (Reportable quantity, section 304 of EPA's
List of Lists)
5000 lb
15.2. International regulations
CANADA
No additional information available
EU-Regulations
No additional information available
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flam. Liq. 3 H226
Acute Tox. 4 (Inhalation:vapour) H332
Skin Irrit. 2 H315
Eye Irrit. 2 H319
Muta. 1B H340
Carc. 1B H350
Full text of H-phrases: see section 16
Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]
Carc.Cat.2; R45
Muta.Cat.2; R46
F; R11
Xn; R20
Xi; R36/38
Full text of R-phrases: see section 16
15.2.2. National regulations
styrene, inhibited (100-42-5)
Listed on EPA's Hazardous Air Pollutants (HAPS)
15.3. US State regulations
styrene, inhibited (100-42-5)
U.S. - California -
Proposition 65 -
Carcinogens List
U.S. - California -
Proposition 65 -
Developmental Toxicity
U.S. - California -
Proposition 65 -
Reproductive Toxicity -
Female
U.S. - California -
Proposition 65 -
Reproductive Toxicity - Male
Non-significant risk level
(NSRL)
ORANGE TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/04/2016 EN (English US) 10/10
styrene, inhibited (100-42-5)
styrene, inhibited (100-42-5)
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
SECTION 16: Other information
Other information : None.
Full text of H-phrases: see section 16:
------ Acute Tox. 4 (Inhalation:vapour) Acute toxicity (inhalation:vapour) Category 4
------ Asp. Tox. 1 Aspiration hazard Category 1
------ Carc. 2 Carcinogenicity Category 2
------ Eye Irrit. 2A Serious eye damage/eye irritation Category 2A
------ Flam. Liq. 2 Flammable liquids Category 2
------ Flam. Liq. 3 Flammable liquids Category 3
------ Repr. 2 Reproductive toxicity Category 2
------ Skin Irrit. 2 Skin corrosion/irritation Category 2
------ STOT RE 1 Specific target organ toxicity (repeated exposure) Category 1
------ STOT SE 3 Specific target organ toxicity (single exposure) Category 3
------ STOT SE 3 Specific target organ toxicity (single exposure) Category 3
------ H225 Highly flammable liquid and vapor
------ H226 Flammable liquid and vapor
------ H304 May be fatal if swallowed and enters airways
------ H315 Causes skin irritation
------ H319 Causes serious eye irritation
------ H332 Harmful if inhaled
------ H335 May cause respiratory irritation
------ H336 May cause drowsiness or dizziness
------ H351 Suspected of causing cancer
------ H361 Suspected of damaging fertility or the unborn child
------ H372 Causes damage to organs through prolonged or repeated exposure
NFPA health hazard : 2 - Intense or continued exposure could cause temporary
incapacitation or possible residual injury unless prompt
medical attention is given.
NFPA fire hazard : 3 - Liquids and solids that can be ignited under almost all
ambient conditions.
NFPA reactivity : 2 - Normally unstable and readily undergo violent
decomposition but do not detonate. Also: may react
violently with water or may form potentially explosive
mixtures with water.
HMIS III Rating
Health : 2 Moderate Hazard - Temporary or minor injury may occur
Flammability : 3 Serious Hazard
Physical : 1 Slight Hazard
Personal Protection : H
SDS US (GHS HazCom 2012)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied
warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.
by | Sep 27, 2025
ORANGE TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue: 01/04/2016 Revision date: 01/04/2016 Supersedes: 09/10/2014
01/04/2016 EN (English US) Page 1
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product form : Mixture
Trade name : ORANGE TOOLING GEL COAT
CAS No : mixture
Product code : 408-001
Formula : na
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : TOOLING GEL COAT
1.3. Details of the supplier of the safety data sheet
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909.877.8477
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
GHS-US classification
Flam. Liq. 3 H226
Skin Irrit. 2 H315
Eye Irrit. 2A H319
Carc. 2 H351
Repr. 2 H361
STOT SE 3 H335
STOT RE 1 H372
2.2. Label elements
GHS-US labeling
Hazard pictograms (GHS-US) :
GHS02
GHS07
GHS08
Signal word (GHS-US) : Danger
Hazard statements (GHS-US) : H226 – Flammable liquid and vapor
H315 – Causes skin irritation
H319 – Causes serious eye irritation
H335 – May cause respiratory irritation
H351 – Suspected of causing cancer
H361 – Suspected of damaging fertility or the unborn child
H372 – Causes damage to organs through prolonged or repeated exposure
Precautionary statements (GHS-US) : P201 – Obtain special instructions before use
P202 – Do not handle until all safety precautions have been read and understood
P210 – Keep away from heat, hot surfaces, open flames, sparks. – No smoking
P233 – Keep container tightly closed
P240 – Ground/bond container and receiving equipment
P241 – Use explosion-proof electrical, lighting, ventilating equipment
P242 – Use only non-sparking tools
P243 – Take precautionary measures against static discharge
P260 – Do not breathe dust, fume, mist, spray, vapors
ORANGE TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/04/2016 EN (English US) 2/10
P264 – Wash EXPOSED AREA. thoroughly after handling
P270 – Do not eat, drink or smoke when using this product
P271 – Use only outdoors or in a well-ventilated area
P280 – Wear eye protection, protective clothing, protective gloves
P302+P352 – IF ON SKIN: Wash with plenty of soap and water
P303+P361+P353 – IF ON SKIN (or hair): Remove/Take off immediately all contaminated
clothing. Rinse skin with water/shower
P304+P340 – IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable
for breathing
P305+P351+P338 – If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P308+P313 – IF exposed or concerned: Get medical advice/attention
P312 – Call a POISON CENTER or doctor/physician if you feel unwell
P314 – Get medical advice and attention if you feel unwell
P321 – Specific treatment (see SEEK MEDICAL AID. on this label)
P332+P313 – If skin irritation occurs: Get medical advice/attention
P337+P313 – If eye irritation persists: Get medical advice/attention
P362 – Take off contaminated clothing and wash it before reuse
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish
P403+P233 – Store in a well-ventilated place. Keep container tightly closed
P403+P235 – Store in a well-ventilated place. Keep cool
P405 – Store locked up
P501 – Dispose of contents/container to LOCAL, STATE, AND NATIONAL REGULATIONS.
2.3. Other hazards
No additional information available
2.4. Unknown acute toxicity (GHS-US)
No data available
SECTION 3: Composition/Information on ingredients
3.1. Substance
Not applicable
Full text of H-phrases: see section 16
3.2. Mixture
Name Product identifier % GHS-US classification
Unsaturated Polyester Resin (CAS No) TRADE SECRET <= 50 Not classified
styrene, inhibited (CAS No) 100-42-5 <= 38 Flam. Liq. 3, H226
Acute Tox. 4 (Inhalation:vapour),
H332
Skin Irrit. 2, H315
Eye Irrit. 2A, H319
Carc. 2, H351
Repr. 2, H361
STOT SE 3, H335
STOT RE 1, H372
Asp. Tox. 1, H304
LEAD FREE ORANGE (CAS No) Proprietary <= 10 Not classified
methyl ethyl ketone (CAS No) 78-93-3 <= 4 Flam. Liq. 2, H225
STOT SE 3, H336
cobalt(II) 2-ethylhexanoate (CAS No) 136-52-7 <= 0.5 Carc. 2, H351
SECTION 4: First aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice
(show the label where possible).
First-aid measures after inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a
POISON CENTER or doctor/physician if you feel unwell. Allow victim to breathe fresh air. Allow
the victim to rest.
First-aid measures after skin contact : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash
with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs:
Get medical advice/attention. Specific treatment (see ... on this label).
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
ORANGE TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/04/2016 EN (English US) 3/10
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries : May cause genetic defects (avoid skin contact and inhalation.). May cause cancer (avoid skin
contact and inhalation.).
Symptoms/injuries after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled.
Symptoms/injuries after skin contact : Causes skin irritation.
Symptoms/injuries after eye contact : Causes serious eye irritation.
4.3. Indication of any immediate medical attention and special treatment needed
No additional information available
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Highly flammable liquid and vapor. Flammable liquid and vapor.
Explosion hazard : May form flammable/explosive vapor-air mixture.
Reactivity : No reactivity hazard other than the effects described in sub-sections below.
5.3. Advice for firefighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No
smoking.
6.1.1. For non-emergency personnel
Protective equipment : Gloves. Protective goggles. Protective clothing.
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Dam up the liquid spill. Contain released substance, pump into suitable containers.
Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect
spillage. Store away from other materials.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapors are flammable.
Precautions for safe handling : Use only outdoors or in a well-ventilated area. Avoid breathing DUST, FUMES, MIST, OR
VAPORS. Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Eliminate all ignition sources if safe to do so. Wash hands and other
exposed areas with mild soap and water before eating, drinking or smoking and when leaving
work. Provide good ventilation in process area to prevent formation of vapor. No open flames. No
smoking. Take precautionary measures against static discharge. Use only non-sparking tools.
Hygiene measures : Wash ... thoroughly after handling.
ORANGE TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/04/2016 EN (English US) 4/10
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond
container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/
equipment.
Storage conditions : Keep in fireproof place. Keep only in the original container in a cool, well ventilated place away
from : Keep container tightly closed.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.
7.3. Specific end use(s)
No additional information available
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
styrene, inhibited (100-42-5)
USA ACGIH ACGIH TWA (ppm) 20 ppm
USA ACGIH ACGIH STEL (ppm) 20 ppm
methyl ethyl ketone (78-93-3)
USA ACGIH ACGIH TWA (ppm) 200 ppm
USA ACGIH ACGIH STEL (ppm) 200 ppm
8.2. Exposure controls
Appropriate engineering controls : Ensure exposure is below occupational exposure limits (where available).
Personal protective equipment : Avoid all unnecessary exposure.
Hand protection : Wear protective gloves.
Eye protection : Chemical goggles or safety glasses.
Skin and body protection : Wear suitable protective clothing.
Respiratory protection : Wear appropriate mask.
Other information : Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Color : orange.
Odor : characteristic.
Odor threshold : No data available
pH : No data available
Relative evaporation rate (butyl acetate=1) : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : 135 - 146 C
Flash point : 26.7 C
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapor pressure : No data available
Relative vapor density at 20 C : No data available
Relative density : No data available
Specific gravity / density : 1.2
Solubility : No data available
Log Pow : No data available
Log Kow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
ORANGE TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/04/2016 EN (English US) 5/10
Explosive properties : No data available
Oxidizing properties : No data available
Explosive limits : No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Highly flammable liquid and vapor. Not established. Flammable liquid and
vapor. May form flammable/explosive vapor-air mixture.
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Heat. Sparks.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity : Not classified
ORANGE TOOLING GEL COAT ( f )mixture
ATE CLP (vapors) 11.000 mg/l/4h
styrene, inhibited (100-42-5)
LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
LD50 dermal rat 2820 mg/kg (Rat; Literature study; OECD 402: Acute Dermal Toxicity; >2000 mg/kg
bodyweight; Rat; Experimental value)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 inhalation rat (mg/l) 12 mg/l/4h (Rat; Literature study)
LC50 inhalation rat (ppm) 2770 ppm/4h (Rat; Literature study)
ATE CLP (oral) 5000.000 mg/kg body weight
ATE CLP (dermal) 2820.000 mg/kg body weight
ATE CLP (gases) 2770.000 ppmV/4h
ATE CLP (vapors) 12.000 mg/l/4h
ATE CLP (dust, mist) 12.000 mg/l/4h
methyl ethyl ketone (78-93-3)
LD50 oral rat 2737 mg/kg (Rat; Equivalent or similar to OECD 423; Read-across; 2054 mg/kg; Rat;
Equivalent or similar to OECD 423; Read-across; 2328 mg/kg; Rat)
LD50 dermal rabbit 6480 mg/kg (Rabbit; Experimental value; Equivalent or similar to OECD 402; >10; Rabbit)
LC50 inhalation rat (mg/l) 34 mg/l/4h (Rat; Literature study)
LC50 inhalation rat (ppm) 11300 ppm/4h (Rat; Literature study)
ATE CLP (oral) 2737.000 mg/kg body weight
ATE CLP (dermal) 6480.000 mg/kg body weight
ATE CLP (gases) 11300.000 ppmV/4h
ATE CLP (vapors) 34.000 mg/l/4h
ATE CLP (dust, mist) 34.000 mg/l/4h
cobalt(II) 2-ethylhexanoate (136-52-7)
LD50 oral rat 3129 mg/kg body weight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat > 2000 mg/kg body weight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)
ORANGE TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/04/2016 EN (English US) 6/10
cobalt(II) 2-ethylhexanoate (136-52-7)
ATE CLP (oral) 3129.000 mg/kg body weight
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitization : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Suspected of causing cancer.
styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans
cobalt(II) 2-ethylhexanoate (136-52-7)
IARC group 2B – Possibly carcinogenic to humans
Reproductive toxicity : Suspected of damaging fertility or the unborn child.
Based on available data, the classification criteria are not met
Specific target organ toxicity (single exposure) : May cause respiratory irritation.
Specific target organ toxicity (repeated
exposure)
: Causes damage to organs through prolonged or repeated exposure.
Based on available data, the classification criteria are not met
Aspiration hazard : Not classified
Based on available data, the classification criteria are not met
Potential Adverse human health effects and
symptoms
: Harmful if inhaled. Based on available data, the classification criteria are not met.
Symptoms/injuries after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled.
Symptoms/injuries after skin contact : Causes skin irritation.
Symptoms/injuries after eye contact : Causes serious eye irritation.
SECTION 12: Ecological information
12.1. Toxicity
styrene, inhibited (100-42-5)
LC50 fish 1 25 mg/l (96 h; Lepomis macrochirus; GLP)
LC50 other aquatic organisms 1 10 – 100 mg/l (96 h)
EC50 Daphnia 1 23 mg/l (48 h; Daphnia magna; Locomotor effect)
LC50 fish 2 32 mg/l (96 h; Pimephales promelas)
EC50 Daphnia 2 27 mg/l (24 h; Daphnia magna; GLP)
TLM fish 1 25.1 mg/l (96 h; Lepomis macrochirus; Soft water)
TLM fish 2 46.4 mg/l (96 h; Pimephales promelas; Soft water)
TLM other aquatic organisms 1 10 – 100,96 h
Threshold limit other aquatic organisms 1 10 – 100,96 h; Pseudomonas putida
Threshold limit other aquatic organisms 2 72 mg/l
Threshold limit algae 1 > 200 mg/l (192 h; Scenedesmus quadricauda; Inhibitory)
Threshold limit algae 2 67 mg/l (Microcystis aeruginosa; Inhibitory)
methyl ethyl ketone (78-93-3)
LC50 fish 1 1690 mg/l (96 h; Lepomis macrochirus; Lethal)
EC50 Daphnia 1 308 mg/l (48 h; Daphnia magna; Locomotor effect)
LC50 fish 2 2990 mg/l (96 h; Pimephales promelas)
TLM fish 1 5600 mg/l (96 h; Gambusia affinis)
TLM fish 2 1690 mg/l (96 h; Lepomis macrochirus)
TLM other aquatic organisms 1 > 1000 ppm (96 h)
Threshold limit algae 1 110 mg/l (168 h; Microcystis aeruginosa)
Threshold limit algae 2 4300 mg/l (192 h; Scenedesmus quadricauda)
cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 1 54.1 mg/l (96 h; Pimephales promelas)
ORANGE TOOLING GEL COAT
Safety Data Sheet
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cobalt(II) 2-ethylhexanoate (136-52-7)
EC50 Daphnia 1 2618 g/l (48 h)
Threshold limit algae 1 24.1 g/l (7 days)
Threshold limit algae 2 90.1 g/l (7 days; Lemna minor; Growth rate)
12.2. Persistence and degradability
ORANGE TOOLING GEL COAT (mixture)
Persistence and degradability Not established.
styrene, inhibited (100-42-5)
Persistence and degradability Readily biodegradable in water. Not readily biodegradable in water. Forming sediments in
water. Non degradable in the soil. Adsorbs into the soil. Photodegradation in the air. Not
established.
Chemical oxygen demand (COD) 2.80 g O /g substance
ThOD 3.07 g O /g substance
BOD (% of ThOD) 0.42 % ThOD
methyl ethyl ketone (78-93-3)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. Not established.
Biochemical oxygen demand (BOD) 1.92 g O /g substance
Chemical oxygen demand (COD) 2.31 g O /g substance
ThOD 2.44 g O /g substance
BOD (% of ThOD) > % ThOD (5 day(s)) > 0.5
cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability Biodegradability in water: no data available.
Unsaturated Polyester Resin (TRADE SECRET)
Persistence and degradability Not established.
LEAD FREE ORANGE (Proprietary)
Persistence and degradability Not established.
12.3. Bioaccumulative potential
ORANGE TOOLING GEL COAT (mixture)
Bioaccumulative potential Not established.
styrene, inhibited (100-42-5)
BCF fish 1 35.5 (Carassius auratus)
BCF other aquatic organisms 1 74
Log Pow 2.96 (Experimental value; OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method; 25 C)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Not established.
methyl ethyl ketone (78-93-3)
Log Pow 0.3 (Experimental value; OECD 117: Partition Coefficient (n-octanol/water), HPLC method; 40
C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
cobalt(II) 2-ethylhexanoate (136-52-7)
Bioaccumulative potential No bioaccumulation data available.
Unsaturated Polyester Resin (TRADE SECRET)
Bioaccumulative potential Not established.
LEAD FREE ORANGE (Proprietary)
Bioaccumulative potential Not established.
12.4. Mobility in soil
styrene, inhibited (100-42-5)
Surface tension 0.032 N/m (19 C)
ORANGE TOOLING GEL COAT
Safety Data Sheet
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01/04/2016 EN (English US) 8/10
methyl ethyl ketone (78-93-3)
Surface tension 0.024 N/m (20 C)
Ecology - soil Slightly harmful to plants.
cobalt(II) 2-ethylhexanoate (136-52-7)
Surface tension 0.064 N/m (20 C; 1 g/l)
12.5. Other adverse effects
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to ...
Additional information : Handle empty containers with care because residual vapors are flammable.
Ecology - waste materials : Avoid release to the environment.
SECTION 14: Transport information
In accordance with DOT
UN-No.(DOT) : UN1866
Proper Shipping Name (DOT) : RESIN SOLUTION
Transport hazard class(es) (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120
Hazard labels (DOT) : 3 - Flammable liquid
Packing group (DOT) : III - Minor Danger
Additional information
Other information : No supplementary information available.
ADR
Transport document description : UN 1866, 3, III, (D/E)
Packing group (ADR) : III
Class (ADR) : 3 - Flammable liquid
Hazard identification number (Kemler No.) : 33
Classification code (ADR) : F1
Hazard labels (ADR) : 3 - Flammable liquids
Orange plates :
Tunnel restriction code : D/E
LQ : 5l
Excepted quantities (ADR) : E2
Transport by sea
UN-No. (IMDG) : 1866
Proper Shipping Name (IMDG) : RESIN SOLUTION
Class (IMDG) : 3 - Flammable liquids
Packing group (IMDG) : III - substances presenting low danger
ORANGE TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/04/2016 EN (English US) 9/10
Air transport
UN-No. (IATA) : 1866
Proper Shipping Name (IATA) : RESIN SOLUTION
Class (IATA) : 3 - Flammable Liquids
Packing group (IATA) : III - Minor Danger
SECTION 15: Regulatory information
15.1. US Federal regulations
styrene, inhibited (100-42-5)
RQ (Reportable quantity, section 304 of EPA's
List of Lists)
1000 lb
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Reactive hazard
Fire hazard
Delayed (chronic) health hazard
methyl ethyl ketone (78-93-3)
RQ (Reportable quantity, section 304 of EPA's
List of Lists)
5000 lb
15.2. International regulations
CANADA
No additional information available
EU-Regulations
No additional information available
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flam. Liq. 3 H226
Acute Tox. 4 (Inhalation:vapour) H332
Skin Irrit. 2 H315
Eye Irrit. 2 H319
Muta. 1B H340
Carc. 1B H350
Full text of H-phrases: see section 16
Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]
Carc.Cat.2; R45
Muta.Cat.2; R46
F; R11
Xn; R20
Xi; R36/38
Full text of R-phrases: see section 16
15.2.2. National regulations
styrene, inhibited (100-42-5)
Listed on EPA's Hazardous Air Pollutants (HAPS)
15.3. US State regulations
styrene, inhibited (100-42-5)
U.S. - California -
Proposition 65 -
Carcinogens List
U.S. - California -
Proposition 65 -
Developmental Toxicity
U.S. - California -
Proposition 65 -
Reproductive Toxicity -
Female
U.S. - California -
Proposition 65 -
Reproductive Toxicity - Male
Non-significant risk level
(NSRL)
ORANGE TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/04/2016 EN (English US) 10/10
styrene, inhibited (100-42-5)
styrene, inhibited (100-42-5)
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
SECTION 16: Other information
Other information : None.
Full text of H-phrases: see section 16:
------ Acute Tox. 4 (Inhalation:vapour) Acute toxicity (inhalation:vapour) Category 4
------ Asp. Tox. 1 Aspiration hazard Category 1
------ Carc. 2 Carcinogenicity Category 2
------ Eye Irrit. 2A Serious eye damage/eye irritation Category 2A
------ Flam. Liq. 2 Flammable liquids Category 2
------ Flam. Liq. 3 Flammable liquids Category 3
------ Repr. 2 Reproductive toxicity Category 2
------ Skin Irrit. 2 Skin corrosion/irritation Category 2
------ STOT RE 1 Specific target organ toxicity (repeated exposure) Category 1
------ STOT SE 3 Specific target organ toxicity (single exposure) Category 3
------ STOT SE 3 Specific target organ toxicity (single exposure) Category 3
------ H225 Highly flammable liquid and vapor
------ H226 Flammable liquid and vapor
------ H304 May be fatal if swallowed and enters airways
------ H315 Causes skin irritation
------ H319 Causes serious eye irritation
------ H332 Harmful if inhaled
------ H335 May cause respiratory irritation
------ H336 May cause drowsiness or dizziness
------ H351 Suspected of causing cancer
------ H361 Suspected of damaging fertility or the unborn child
------ H372 Causes damage to organs through prolonged or repeated exposure
NFPA health hazard : 2 - Intense or continued exposure could cause temporary
incapacitation or possible residual injury unless prompt
medical attention is given.
NFPA fire hazard : 3 - Liquids and solids that can be ignited under almost all
ambient conditions.
NFPA reactivity : 2 - Normally unstable and readily undergo violent
decomposition but do not detonate. Also: may react
violently with water or may form potentially explosive
mixtures with water.
HMIS III Rating
Health : 2 Moderate Hazard - Temporary or minor injury may occur
Flammability : 3 Serious Hazard
Physical : 1 Slight Hazard
Personal Protection : H
SDS US (GHS HazCom 2012)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied
warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.
by | Sep 27, 2025
ORANGE TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue: 01/04/2016 Revision date: 01/04/2016 Supersedes: 09/10/2014
01/04/2016 EN (English US) Page 1
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product form : Mixture
Trade name : ORANGE TOOLING GEL COAT
CAS No : mixture
Product code : 408-001
Formula : na
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : TOOLING GEL COAT
1.3. Details of the supplier of the safety data sheet
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909.877.8477
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
GHS-US classification
Flam. Liq. 3 H226
Skin Irrit. 2 H315
Eye Irrit. 2A H319
Carc. 2 H351
Repr. 2 H361
STOT SE 3 H335
STOT RE 1 H372
2.2. Label elements
GHS-US labeling
Hazard pictograms (GHS-US) :
GHS02
GHS07
GHS08
Signal word (GHS-US) : Danger
Hazard statements (GHS-US) : H226 – Flammable liquid and vapor
H315 – Causes skin irritation
H319 – Causes serious eye irritation
H335 – May cause respiratory irritation
H351 – Suspected of causing cancer
H361 – Suspected of damaging fertility or the unborn child
H372 – Causes damage to organs through prolonged or repeated exposure
Precautionary statements (GHS-US) : P201 – Obtain special instructions before use
P202 – Do not handle until all safety precautions have been read and understood
P210 – Keep away from heat, hot surfaces, open flames, sparks. – No smoking
P233 – Keep container tightly closed
P240 – Ground/bond container and receiving equipment
P241 – Use explosion-proof electrical, lighting, ventilating equipment
P242 – Use only non-sparking tools
P243 – Take precautionary measures against static discharge
P260 – Do not breathe dust, fume, mist, spray, vapors
ORANGE TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/04/2016 EN (English US) 2/10
P264 – Wash EXPOSED AREA. thoroughly after handling
P270 – Do not eat, drink or smoke when using this product
P271 – Use only outdoors or in a well-ventilated area
P280 – Wear eye protection, protective clothing, protective gloves
P302+P352 – IF ON SKIN: Wash with plenty of soap and water
P303+P361+P353 – IF ON SKIN (or hair): Remove/Take off immediately all contaminated
clothing. Rinse skin with water/shower
P304+P340 – IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable
for breathing
P305+P351+P338 – If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P308+P313 – IF exposed or concerned: Get medical advice/attention
P312 – Call a POISON CENTER or doctor/physician if you feel unwell
P314 – Get medical advice and attention if you feel unwell
P321 – Specific treatment (see SEEK MEDICAL AID. on this label)
P332+P313 – If skin irritation occurs: Get medical advice/attention
P337+P313 – If eye irritation persists: Get medical advice/attention
P362 – Take off contaminated clothing and wash it before reuse
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish
P403+P233 – Store in a well-ventilated place. Keep container tightly closed
P403+P235 – Store in a well-ventilated place. Keep cool
P405 – Store locked up
P501 – Dispose of contents/container to LOCAL, STATE, AND NATIONAL REGULATIONS.
2.3. Other hazards
No additional information available
2.4. Unknown acute toxicity (GHS-US)
No data available
SECTION 3: Composition/Information on ingredients
3.1. Substance
Not applicable
Full text of H-phrases: see section 16
3.2. Mixture
Name Product identifier % GHS-US classification
Unsaturated Polyester Resin (CAS No) TRADE SECRET <= 50 Not classified
styrene, inhibited (CAS No) 100-42-5 <= 38 Flam. Liq. 3, H226
Acute Tox. 4 (Inhalation:vapour),
H332
Skin Irrit. 2, H315
Eye Irrit. 2A, H319
Carc. 2, H351
Repr. 2, H361
STOT SE 3, H335
STOT RE 1, H372
Asp. Tox. 1, H304
LEAD FREE ORANGE (CAS No) Proprietary <= 10 Not classified
methyl ethyl ketone (CAS No) 78-93-3 <= 4 Flam. Liq. 2, H225
STOT SE 3, H336
cobalt(II) 2-ethylhexanoate (CAS No) 136-52-7 <= 0.5 Carc. 2, H351
SECTION 4: First aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice
(show the label where possible).
First-aid measures after inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a
POISON CENTER or doctor/physician if you feel unwell. Allow victim to breathe fresh air. Allow
the victim to rest.
First-aid measures after skin contact : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash
with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs:
Get medical advice/attention. Specific treatment (see ... on this label).
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
ORANGE TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/04/2016 EN (English US) 3/10
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries : May cause genetic defects (avoid skin contact and inhalation.). May cause cancer (avoid skin
contact and inhalation.).
Symptoms/injuries after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled.
Symptoms/injuries after skin contact : Causes skin irritation.
Symptoms/injuries after eye contact : Causes serious eye irritation.
4.3. Indication of any immediate medical attention and special treatment needed
No additional information available
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Highly flammable liquid and vapor. Flammable liquid and vapor.
Explosion hazard : May form flammable/explosive vapor-air mixture.
Reactivity : No reactivity hazard other than the effects described in sub-sections below.
5.3. Advice for firefighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No
smoking.
6.1.1. For non-emergency personnel
Protective equipment : Gloves. Protective goggles. Protective clothing.
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Dam up the liquid spill. Contain released substance, pump into suitable containers.
Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect
spillage. Store away from other materials.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapors are flammable.
Precautions for safe handling : Use only outdoors or in a well-ventilated area. Avoid breathing DUST, FUMES, MIST, OR
VAPORS. Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Eliminate all ignition sources if safe to do so. Wash hands and other
exposed areas with mild soap and water before eating, drinking or smoking and when leaving
work. Provide good ventilation in process area to prevent formation of vapor. No open flames. No
smoking. Take precautionary measures against static discharge. Use only non-sparking tools.
Hygiene measures : Wash ... thoroughly after handling.
ORANGE TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/04/2016 EN (English US) 4/10
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond
container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/
equipment.
Storage conditions : Keep in fireproof place. Keep only in the original container in a cool, well ventilated place away
from : Keep container tightly closed.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.
7.3. Specific end use(s)
No additional information available
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
styrene, inhibited (100-42-5)
USA ACGIH ACGIH TWA (ppm) 20 ppm
USA ACGIH ACGIH STEL (ppm) 20 ppm
methyl ethyl ketone (78-93-3)
USA ACGIH ACGIH TWA (ppm) 200 ppm
USA ACGIH ACGIH STEL (ppm) 200 ppm
8.2. Exposure controls
Appropriate engineering controls : Ensure exposure is below occupational exposure limits (where available).
Personal protective equipment : Avoid all unnecessary exposure.
Hand protection : Wear protective gloves.
Eye protection : Chemical goggles or safety glasses.
Skin and body protection : Wear suitable protective clothing.
Respiratory protection : Wear appropriate mask.
Other information : Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Color : orange.
Odor : characteristic.
Odor threshold : No data available
pH : No data available
Relative evaporation rate (butyl acetate=1) : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : 135 - 146 C
Flash point : 26.7 C
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapor pressure : No data available
Relative vapor density at 20 C : No data available
Relative density : No data available
Specific gravity / density : 1.2
Solubility : No data available
Log Pow : No data available
Log Kow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
ORANGE TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/04/2016 EN (English US) 5/10
Explosive properties : No data available
Oxidizing properties : No data available
Explosive limits : No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Highly flammable liquid and vapor. Not established. Flammable liquid and
vapor. May form flammable/explosive vapor-air mixture.
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Heat. Sparks.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity : Not classified
ORANGE TOOLING GEL COAT ( f )mixture
ATE CLP (vapors) 11.000 mg/l/4h
styrene, inhibited (100-42-5)
LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
LD50 dermal rat 2820 mg/kg (Rat; Literature study; OECD 402: Acute Dermal Toxicity; >2000 mg/kg
bodyweight; Rat; Experimental value)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 inhalation rat (mg/l) 12 mg/l/4h (Rat; Literature study)
LC50 inhalation rat (ppm) 2770 ppm/4h (Rat; Literature study)
ATE CLP (oral) 5000.000 mg/kg body weight
ATE CLP (dermal) 2820.000 mg/kg body weight
ATE CLP (gases) 2770.000 ppmV/4h
ATE CLP (vapors) 12.000 mg/l/4h
ATE CLP (dust, mist) 12.000 mg/l/4h
methyl ethyl ketone (78-93-3)
LD50 oral rat 2737 mg/kg (Rat; Equivalent or similar to OECD 423; Read-across; 2054 mg/kg; Rat;
Equivalent or similar to OECD 423; Read-across; 2328 mg/kg; Rat)
LD50 dermal rabbit 6480 mg/kg (Rabbit; Experimental value; Equivalent or similar to OECD 402; >10; Rabbit)
LC50 inhalation rat (mg/l) 34 mg/l/4h (Rat; Literature study)
LC50 inhalation rat (ppm) 11300 ppm/4h (Rat; Literature study)
ATE CLP (oral) 2737.000 mg/kg body weight
ATE CLP (dermal) 6480.000 mg/kg body weight
ATE CLP (gases) 11300.000 ppmV/4h
ATE CLP (vapors) 34.000 mg/l/4h
ATE CLP (dust, mist) 34.000 mg/l/4h
cobalt(II) 2-ethylhexanoate (136-52-7)
LD50 oral rat 3129 mg/kg body weight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat > 2000 mg/kg body weight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)
ORANGE TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/04/2016 EN (English US) 6/10
cobalt(II) 2-ethylhexanoate (136-52-7)
ATE CLP (oral) 3129.000 mg/kg body weight
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitization : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Suspected of causing cancer.
styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans
cobalt(II) 2-ethylhexanoate (136-52-7)
IARC group 2B – Possibly carcinogenic to humans
Reproductive toxicity : Suspected of damaging fertility or the unborn child.
Based on available data, the classification criteria are not met
Specific target organ toxicity (single exposure) : May cause respiratory irritation.
Specific target organ toxicity (repeated
exposure)
: Causes damage to organs through prolonged or repeated exposure.
Based on available data, the classification criteria are not met
Aspiration hazard : Not classified
Based on available data, the classification criteria are not met
Potential Adverse human health effects and
symptoms
: Harmful if inhaled. Based on available data, the classification criteria are not met.
Symptoms/injuries after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled.
Symptoms/injuries after skin contact : Causes skin irritation.
Symptoms/injuries after eye contact : Causes serious eye irritation.
SECTION 12: Ecological information
12.1. Toxicity
styrene, inhibited (100-42-5)
LC50 fish 1 25 mg/l (96 h; Lepomis macrochirus; GLP)
LC50 other aquatic organisms 1 10 – 100 mg/l (96 h)
EC50 Daphnia 1 23 mg/l (48 h; Daphnia magna; Locomotor effect)
LC50 fish 2 32 mg/l (96 h; Pimephales promelas)
EC50 Daphnia 2 27 mg/l (24 h; Daphnia magna; GLP)
TLM fish 1 25.1 mg/l (96 h; Lepomis macrochirus; Soft water)
TLM fish 2 46.4 mg/l (96 h; Pimephales promelas; Soft water)
TLM other aquatic organisms 1 10 – 100,96 h
Threshold limit other aquatic organisms 1 10 – 100,96 h; Pseudomonas putida
Threshold limit other aquatic organisms 2 72 mg/l
Threshold limit algae 1 > 200 mg/l (192 h; Scenedesmus quadricauda; Inhibitory)
Threshold limit algae 2 67 mg/l (Microcystis aeruginosa; Inhibitory)
methyl ethyl ketone (78-93-3)
LC50 fish 1 1690 mg/l (96 h; Lepomis macrochirus; Lethal)
EC50 Daphnia 1 308 mg/l (48 h; Daphnia magna; Locomotor effect)
LC50 fish 2 2990 mg/l (96 h; Pimephales promelas)
TLM fish 1 5600 mg/l (96 h; Gambusia affinis)
TLM fish 2 1690 mg/l (96 h; Lepomis macrochirus)
TLM other aquatic organisms 1 > 1000 ppm (96 h)
Threshold limit algae 1 110 mg/l (168 h; Microcystis aeruginosa)
Threshold limit algae 2 4300 mg/l (192 h; Scenedesmus quadricauda)
cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 1 54.1 mg/l (96 h; Pimephales promelas)
ORANGE TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/04/2016 EN (English US) 7/10
cobalt(II) 2-ethylhexanoate (136-52-7)
EC50 Daphnia 1 2618 g/l (48 h)
Threshold limit algae 1 24.1 g/l (7 days)
Threshold limit algae 2 90.1 g/l (7 days; Lemna minor; Growth rate)
12.2. Persistence and degradability
ORANGE TOOLING GEL COAT (mixture)
Persistence and degradability Not established.
styrene, inhibited (100-42-5)
Persistence and degradability Readily biodegradable in water. Not readily biodegradable in water. Forming sediments in
water. Non degradable in the soil. Adsorbs into the soil. Photodegradation in the air. Not
established.
Chemical oxygen demand (COD) 2.80 g O /g substance
ThOD 3.07 g O /g substance
BOD (% of ThOD) 0.42 % ThOD
methyl ethyl ketone (78-93-3)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. Not established.
Biochemical oxygen demand (BOD) 1.92 g O /g substance
Chemical oxygen demand (COD) 2.31 g O /g substance
ThOD 2.44 g O /g substance
BOD (% of ThOD) > % ThOD (5 day(s)) > 0.5
cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability Biodegradability in water: no data available.
Unsaturated Polyester Resin (TRADE SECRET)
Persistence and degradability Not established.
LEAD FREE ORANGE (Proprietary)
Persistence and degradability Not established.
12.3. Bioaccumulative potential
ORANGE TOOLING GEL COAT (mixture)
Bioaccumulative potential Not established.
styrene, inhibited (100-42-5)
BCF fish 1 35.5 (Carassius auratus)
BCF other aquatic organisms 1 74
Log Pow 2.96 (Experimental value; OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method; 25 C)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Not established.
methyl ethyl ketone (78-93-3)
Log Pow 0.3 (Experimental value; OECD 117: Partition Coefficient (n-octanol/water), HPLC method; 40
C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
cobalt(II) 2-ethylhexanoate (136-52-7)
Bioaccumulative potential No bioaccumulation data available.
Unsaturated Polyester Resin (TRADE SECRET)
Bioaccumulative potential Not established.
LEAD FREE ORANGE (Proprietary)
Bioaccumulative potential Not established.
12.4. Mobility in soil
styrene, inhibited (100-42-5)
Surface tension 0.032 N/m (19 C)
ORANGE TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/04/2016 EN (English US) 8/10
methyl ethyl ketone (78-93-3)
Surface tension 0.024 N/m (20 C)
Ecology - soil Slightly harmful to plants.
cobalt(II) 2-ethylhexanoate (136-52-7)
Surface tension 0.064 N/m (20 C; 1 g/l)
12.5. Other adverse effects
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to ...
Additional information : Handle empty containers with care because residual vapors are flammable.
Ecology - waste materials : Avoid release to the environment.
SECTION 14: Transport information
In accordance with DOT
UN-No.(DOT) : UN1866
Proper Shipping Name (DOT) : RESIN SOLUTION
Transport hazard class(es) (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120
Hazard labels (DOT) : 3 - Flammable liquid
Packing group (DOT) : III - Minor Danger
Additional information
Other information : No supplementary information available.
ADR
Transport document description : UN 1866, 3, III, (D/E)
Packing group (ADR) : III
Class (ADR) : 3 - Flammable liquid
Hazard identification number (Kemler No.) : 33
Classification code (ADR) : F1
Hazard labels (ADR) : 3 - Flammable liquids
Orange plates :
Tunnel restriction code : D/E
LQ : 5l
Excepted quantities (ADR) : E2
Transport by sea
UN-No. (IMDG) : 1866
Proper Shipping Name (IMDG) : RESIN SOLUTION
Class (IMDG) : 3 - Flammable liquids
Packing group (IMDG) : III - substances presenting low danger
ORANGE TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/04/2016 EN (English US) 9/10
Air transport
UN-No. (IATA) : 1866
Proper Shipping Name (IATA) : RESIN SOLUTION
Class (IATA) : 3 - Flammable Liquids
Packing group (IATA) : III - Minor Danger
SECTION 15: Regulatory information
15.1. US Federal regulations
styrene, inhibited (100-42-5)
RQ (Reportable quantity, section 304 of EPA's
List of Lists)
1000 lb
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Reactive hazard
Fire hazard
Delayed (chronic) health hazard
methyl ethyl ketone (78-93-3)
RQ (Reportable quantity, section 304 of EPA's
List of Lists)
5000 lb
15.2. International regulations
CANADA
No additional information available
EU-Regulations
No additional information available
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flam. Liq. 3 H226
Acute Tox. 4 (Inhalation:vapour) H332
Skin Irrit. 2 H315
Eye Irrit. 2 H319
Muta. 1B H340
Carc. 1B H350
Full text of H-phrases: see section 16
Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]
Carc.Cat.2; R45
Muta.Cat.2; R46
F; R11
Xn; R20
Xi; R36/38
Full text of R-phrases: see section 16
15.2.2. National regulations
styrene, inhibited (100-42-5)
Listed on EPA's Hazardous Air Pollutants (HAPS)
15.3. US State regulations
styrene, inhibited (100-42-5)
U.S. - California -
Proposition 65 -
Carcinogens List
U.S. - California -
Proposition 65 -
Developmental Toxicity
U.S. - California -
Proposition 65 -
Reproductive Toxicity -
Female
U.S. - California -
Proposition 65 -
Reproductive Toxicity - Male
Non-significant risk level
(NSRL)
ORANGE TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/04/2016 EN (English US) 10/10
styrene, inhibited (100-42-5)
styrene, inhibited (100-42-5)
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
SECTION 16: Other information
Other information : None.
Full text of H-phrases: see section 16:
------ Acute Tox. 4 (Inhalation:vapour) Acute toxicity (inhalation:vapour) Category 4
------ Asp. Tox. 1 Aspiration hazard Category 1
------ Carc. 2 Carcinogenicity Category 2
------ Eye Irrit. 2A Serious eye damage/eye irritation Category 2A
------ Flam. Liq. 2 Flammable liquids Category 2
------ Flam. Liq. 3 Flammable liquids Category 3
------ Repr. 2 Reproductive toxicity Category 2
------ Skin Irrit. 2 Skin corrosion/irritation Category 2
------ STOT RE 1 Specific target organ toxicity (repeated exposure) Category 1
------ STOT SE 3 Specific target organ toxicity (single exposure) Category 3
------ STOT SE 3 Specific target organ toxicity (single exposure) Category 3
------ H225 Highly flammable liquid and vapor
------ H226 Flammable liquid and vapor
------ H304 May be fatal if swallowed and enters airways
------ H315 Causes skin irritation
------ H319 Causes serious eye irritation
------ H332 Harmful if inhaled
------ H335 May cause respiratory irritation
------ H336 May cause drowsiness or dizziness
------ H351 Suspected of causing cancer
------ H361 Suspected of damaging fertility or the unborn child
------ H372 Causes damage to organs through prolonged or repeated exposure
NFPA health hazard : 2 - Intense or continued exposure could cause temporary
incapacitation or possible residual injury unless prompt
medical attention is given.
NFPA fire hazard : 3 - Liquids and solids that can be ignited under almost all
ambient conditions.
NFPA reactivity : 2 - Normally unstable and readily undergo violent
decomposition but do not detonate. Also: may react
violently with water or may form potentially explosive
mixtures with water.
HMIS III Rating
Health : 2 Moderate Hazard - Temporary or minor injury may occur
Flammability : 3 Serious Hazard
Physical : 1 Slight Hazard
Personal Protection : H
SDS US (GHS HazCom 2012)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied
warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.
by | Sep 27, 2025
HI FLEX GREEN TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue: 01/05/2016 Revision date: 01/05/2016 Supersedes: 09/10/2014
01/05/2016 EN (English US) Page 1
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product form : Mixture
Trade name : HI FLEX GREEN TOOLING GEL COAT
CAS No : mixture
Product code : 406-009
Formula : na
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : TOOLING GEL COAT
1.3. Details of the supplier of the safety data sheet
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909.877.8477
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
GHS-US classification
Flam. Liq. 3 H226
Skin Irrit. 2 H315
Eye Irrit. 2A H319
Carc. 2 H351
Repr. 2 H361
STOT SE 3 H335
STOT RE 1 H372
2.2. Label elements
GHS-US labeling
Hazard pictograms (GHS-US) :
GHS02
GHS07
GHS08
Signal word (GHS-US) : Danger
Hazard statements (GHS-US) : H226 – Flammable liquid and vapor
H315 – Causes skin irritation
H319 – Causes serious eye irritation
H335 – May cause respiratory irritation
H351 – Suspected of causing cancer
H361 – Suspected of damaging fertility or the unborn child
H372 – Causes damage to organs through prolonged or repeated exposure
Precautionary statements (GHS-US) : P201 – Obtain special instructions before use
P202 – Do not handle until all safety precautions have been read and understood
P210 – Keep away from heat, hot surfaces, open flames, sparks. – No smoking
P233 – Keep container tightly closed
P240 – Ground/bond container and receiving equipment
P241 – Use explosion-proof electrical, lighting, ventilating equipment
P242 – Use only non-sparking tools
P243 – Take precautionary measures against static discharge
P260 – Do not breathe dust, fume, mist, spray, vapors
HI FLEX GREEN TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/05/2016 EN (English US) 2/10
P264 – Wash EXPOSED AREA. thoroughly after handling
P270 – Do not eat, drink or smoke when using this product
P271 – Use only outdoors or in a well-ventilated area
P280 – Wear eye protection, protective clothing, protective gloves
P302+P352 – IF ON SKIN: Wash with plenty of soap and water
P303+P361+P353 – IF ON SKIN (or hair): Remove/Take off immediately all contaminated
clothing. Rinse skin with water/shower
P304+P340 – IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable
for breathing
P305+P351+P338 – If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P308+P313 – IF exposed or concerned: Get medical advice/attention
P312 – Call a POISON CENTER or doctor/physician if you feel unwell
P314 – Get medical advice and attention if you feel unwell
P321 – Specific treatment (see SEEK MEDICAL AID. on this label)
P332+P313 – If skin irritation occurs: Get medical advice/attention
P337+P313 – If eye irritation persists: Get medical advice/attention
P362 – Take off contaminated clothing and wash it before reuse
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish
P403+P233 – Store in a well-ventilated place. Keep container tightly closed
P403+P235 – Store in a well-ventilated place. Keep cool
P405 – Store locked up
P501 – Dispose of contents/container to LOCAL, STATE, AND NATIONAL REGULATIONS.
2.3. Other hazards
No additional information available
2.4. Unknown acute toxicity (GHS-US)
No data available
SECTION 3: Composition/Information on ingredients
3.1. Substance
Not applicable
Full text of H-phrases: see section 16
3.2. Mixture
Name Product identifier % GHS-US classification
Unsaturated Polyester Resin (CAS No) TRADE SECRET <= 45 Not classified
styrene, inhibited (CAS No) 100-42-5 <= 37.78 Flam. Liq. 3, H226
Acute Tox. 4 (Inhalation:vapour),
H332
Skin Irrit. 2, H315
Eye Irrit. 2A, H319
Carc. 2, H351
Repr. 2, H361
STOT SE 3, H335
STOT RE 1, H372
Asp. Tox. 1, H304
methyl ethyl ketone (CAS No) 78-93-3 <= 4.2 Flam. Liq. 2, H225
STOT SE 3, H336
cobalt(II) 2-ethylhexanoate (CAS No) 136-52-7 <= 0.5 Carc. 2, H351
SECTION 4: First aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice
(show the label where possible).
First-aid measures after inhalation : Allow victim to breathe fresh air. Allow the victim to rest. Remove victim to fresh air and keep at
rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you
feel unwell.
First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Wash
with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs:
wash throughly for five minutes. seek medical attention. Get medical advice/attention. Specific
treatment (see seek medical attention. on this label).
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: SEEK IMMEDIATE MEDICAL ATTENTION. Get
medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
HI FLEX GREEN TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/05/2016 EN (English US) 3/10
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries : May cause genetic defects (avoid skin contact and inhalation.). May cause cancer (avoid skin
contact and inhalation.).
Symptoms/injuries after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled.
Symptoms/injuries after skin contact : Causes skin irritation.
Symptoms/injuries after eye contact : Causes serious eye irritation.
4.3. Indication of any immediate medical attention and special treatment needed
No additional information available
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Highly flammable liquid and vapor. Flammable liquid and vapor.
Explosion hazard : May form flammable/explosive vapor-air mixture.
Reactivity : No reactivity hazard other than the effects described in sub-sections below.
5.3. Advice for firefighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No
smoking.
6.1.1. For non-emergency personnel
Protective equipment : Gloves. Protective goggles. Protective clothing.
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Dam up the liquid spill. Contain released substance, pump into suitable containers.
Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect
spillage. Store away from other materials.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapors are flammable.
Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Provide good ventilation in process area to prevent formation of
vapor. No open flames. No smoking. Use only non-sparking tools. Use only outdoors or in a well-
ventilated area. Avoid breathing DUST, FUMES, MIST, OR VAPORS. Obtain special instructions
before use. Do not handle until all safety precautions have been read and understood. Eliminate
all ignition sources if safe to do so. Take precautionary measures against static discharge.
Hygiene measures : Wash HANDS thoroughly after handling.
HI FLEX GREEN TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/05/2016 EN (English US) 4/10
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond
container and receiving equipment. Use explosion-proof electrical, ventilating and lighting
equipment. equipment.
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : HEAT SPARKS
OR OPEN FLAMES. Keep in fireproof place. Keep container tightly closed.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.
7.3. Specific end use(s)
No additional information available
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
styrene, inhibited (100-42-5)
USA ACGIH ACGIH TWA (ppm) 20 ppm
USA ACGIH ACGIH STEL (ppm) 20 ppm
methyl ethyl ketone (78-93-3)
USA ACGIH ACGIH TWA (ppm) 200 ppm
USA ACGIH ACGIH STEL (ppm) 200 ppm
8.2. Exposure controls
Appropriate engineering controls : Ensure exposure is below occupational exposure limits (where available).
Personal protective equipment : Avoid all unnecessary exposure.
Hand protection : Wear protective gloves.
Eye protection : Chemical goggles or safety glasses.
Skin and body protection : Wear suitable protective clothing.
Respiratory protection : Wear appropriate mask.
Other information : Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Color : Green.
Odor : characteristic.
Odor threshold : No data available
pH : No data available
Relative evaporation rate (butyl acetate=1) : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : 79 - 146 C
Flash point : -6.67 C
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapor pressure : No data available
Relative vapor density at 20 C : No data available
Relative density : 1.1
Solubility : No data available
Log Pow : No data available
Log Kow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
HI FLEX GREEN TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/05/2016 EN (English US) 5/10
Oxidizing properties : No data available
Explosive limits : No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Not established. Highly flammable liquid and vapor. May form
flammable/explosive vapor-air mixture. Flammable liquid and vapor.
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Heat. Sparks.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity : Not classified
HI FLEX GREEN TOOLING GEL COAT ( f )mixture
ATE CLP (vapors) 11.000 mg/l/4h
styrene, inhibited (100-42-5)
LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
LD50 dermal rat 2820 mg/kg (Rat; Literature study; OECD 402: Acute Dermal Toxicity; >2000 mg/kg
bodyweight; Rat; Experimental value)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 inhalation rat (mg/l) 12 mg/l/4h (Rat; Literature study)
LC50 inhalation rat (ppm) 2770 ppm/4h (Rat; Literature study)
ATE CLP (oral) 5000.000 mg/kg body weight
ATE CLP (dermal) 2820.000 mg/kg body weight
ATE CLP (gases) 2770.000 ppmV/4h
ATE CLP (vapors) 12.000 mg/l/4h
ATE CLP (dust, mist) 12.000 mg/l/4h
methyl ethyl ketone (78-93-3)
LD50 oral rat 2737 mg/kg (Rat; Equivalent or similar to OECD 423; Read-across; 2054 mg/kg; Rat;
Equivalent or similar to OECD 423; Read-across; 2328 mg/kg; Rat)
LD50 dermal rabbit 6480 mg/kg (Rabbit; Experimental value; Equivalent or similar to OECD 402; >10; Rabbit)
LC50 inhalation rat (mg/l) 34 mg/l/4h (Rat; Literature study)
LC50 inhalation rat (ppm) 11300 ppm/4h (Rat; Literature study)
ATE CLP (oral) 2737.000 mg/kg body weight
ATE CLP (dermal) 6480.000 mg/kg body weight
ATE CLP (gases) 11300.000 ppmV/4h
ATE CLP (vapors) 34.000 mg/l/4h
ATE CLP (dust, mist) 34.000 mg/l/4h
cobalt(II) 2-ethylhexanoate (136-52-7)
LD50 oral rat 3129 mg/kg body weight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat > 2000 mg/kg body weight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)
ATE CLP (oral) 3129.000 mg/kg body weight
HI FLEX GREEN TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/05/2016 EN (English US) 6/10
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitization : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Suspected of causing cancer.
styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans
cobalt(II) 2-ethylhexanoate (136-52-7)
IARC group 2B – Possibly carcinogenic to humans
Reproductive toxicity : Suspected of damaging fertility or the unborn child.
Based on available data, the classification criteria are not met
Specific target organ toxicity (single exposure) : May cause respiratory irritation.
Specific target organ toxicity (repeated
exposure)
: Causes damage to organs through prolonged or repeated exposure.
Based on available data, the classification criteria are not met
Aspiration hazard : Not classified
Based on available data, the classification criteria are not met
Potential Adverse human health effects and
symptoms
: Harmful if inhaled. Based on available data, the classification criteria are not met.
Symptoms/injuries after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled.
Symptoms/injuries after skin contact : Causes skin irritation.
Symptoms/injuries after eye contact : Causes serious eye irritation.
SECTION 12: Ecological information
12.1. Toxicity
styrene, inhibited (100-42-5)
LC50 fish 1 25 mg/l (96 h; Lepomis macrochirus; GLP)
LC50 other aquatic organisms 1 10 – 100 mg/l (96 h)
EC50 Daphnia 1 23 mg/l (48 h; Daphnia magna; Locomotor effect)
LC50 fish 2 32 mg/l (96 h; Pimephales promelas)
EC50 Daphnia 2 27 mg/l (24 h; Daphnia magna; GLP)
TLM fish 1 25.1 mg/l (96 h; Lepomis macrochirus; Soft water)
TLM fish 2 46.4 mg/l (96 h; Pimephales promelas; Soft water)
TLM other aquatic organisms 1 10 – 100,96 h
Threshold limit other aquatic organisms 1 10 – 100,96 h; Pseudomonas putida
Threshold limit other aquatic organisms 2 72 mg/l
Threshold limit algae 1 > 200 mg/l (192 h; Scenedesmus quadricauda; Inhibitory)
Threshold limit algae 2 67 mg/l (Microcystis aeruginosa; Inhibitory)
methyl ethyl ketone (78-93-3)
LC50 fish 1 1690 mg/l (96 h; Lepomis macrochirus; Lethal)
EC50 Daphnia 1 308 mg/l (48 h; Daphnia magna; Locomotor effect)
LC50 fish 2 2990 mg/l (96 h; Pimephales promelas)
TLM fish 1 5600 mg/l (96 h; Gambusia affinis)
TLM fish 2 1690 mg/l (96 h; Lepomis macrochirus)
TLM other aquatic organisms 1 > 1000 ppm (96 h)
Threshold limit algae 1 110 mg/l (168 h; Microcystis aeruginosa)
Threshold limit algae 2 4300 mg/l (192 h; Scenedesmus quadricauda)
cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 1 54.1 mg/l (96 h; Pimephales promelas)
EC50 Daphnia 1 2618 g/l (48 h)
Threshold limit algae 1 24.1 g/l (7 days)
HI FLEX GREEN TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/05/2016 EN (English US) 7/10
cobalt(II) 2-ethylhexanoate (136-52-7)
Threshold limit algae 2 90.1 g/l (7 days; Lemna minor; Growth rate)
12.2. Persistence and degradability
HI FLEX GREEN TOOLING GEL COAT (mixture)
Persistence and degradability Not established.
styrene, inhibited (100-42-5)
Persistence and degradability Readily biodegradable in water. Not readily biodegradable in water. Forming sediments in
water. Non degradable in the soil. Adsorbs into the soil. Photodegradation in the air. Not
established.
Chemical oxygen demand (COD) 2.80 g O /g substance
ThOD 3.07 g O /g substance
BOD (% of ThOD) 0.42 % ThOD
methyl ethyl ketone (78-93-3)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. Not established.
Biochemical oxygen demand (BOD) 1.92 g O /g substance
Chemical oxygen demand (COD) 2.31 g O /g substance
ThOD 2.44 g O /g substance
BOD (% of ThOD) > % ThOD (5 day(s)) > 0.5
cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability Biodegradability in water: no data available.
Unsaturated Polyester Resin (TRADE SECRET)
Persistence and degradability Not established.
12.3. Bioaccumulative potential
HI FLEX GREEN TOOLING GEL COAT (mixture)
Bioaccumulative potential Not established.
styrene, inhibited (100-42-5)
BCF fish 1 35.5 (Carassius auratus)
BCF other aquatic organisms 1 74
Log Pow 2.96 (Experimental value; OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method; 25 C)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Not established.
methyl ethyl ketone (78-93-3)
Log Pow 0.3 (Experimental value; OECD 117: Partition Coefficient (n-octanol/water), HPLC method; 40
C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
cobalt(II) 2-ethylhexanoate (136-52-7)
Bioaccumulative potential No bioaccumulation data available.
Unsaturated Polyester Resin (TRADE SECRET)
Bioaccumulative potential Not established.
12.4. Mobility in soil
styrene, inhibited (100-42-5)
Surface tension 0.032 N/m (19 C)
methyl ethyl ketone (78-93-3)
Surface tension 0.024 N/m (20 C)
Ecology - soil Slightly harmful to plants.
cobalt(II) 2-ethylhexanoate (136-52-7)
Surface tension 0.064 N/m (20 C; 1 g/l)
12.5. Other adverse effects
Other information : Avoid release to the environment.
HI FLEX GREEN TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/05/2016 EN (English US) 8/10
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to approved disposal site.
Additional information : Handle empty containers with care because residual vapors are flammable.
Ecology - waste materials : Avoid release to the environment.
SECTION 14: Transport information
In accordance with DOT
UN-No.(DOT) : UN1866
Proper Shipping Name (DOT) : RESIN SOLUTION
Transport hazard class(es) (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120
Hazard labels (DOT) : 3 - Flammable liquid
Packing group (DOT) : II - Medium Danger
Additional information
Other information : No supplementary information available.
ADR
Transport document description : UN 1866, 3, II, (D/E)
Packing group (ADR) : II
Class (ADR) : 3 - Flammable liquid
Hazard identification number (Kemler No.) : 33
Classification code (ADR) : F1
Hazard labels (ADR) : 3 - Flammable liquids
Orange plates :
Tunnel restriction code : D/E
LQ : 5l
Excepted quantities (ADR) : E2
Transport by sea
UN-No. (IMDG) : 1866
Proper Shipping Name (IMDG) : RESIN SOLUTION
Class (IMDG) : 3 - Flammable liquids
Packing group (IMDG) : II - substances presenting medium danger
Air transport
UN-No. (IATA) : 1866
Proper Shipping Name (IATA) : RESIN SOLUTION
Class (IATA) : 3 - Flammable Liquids
Packing group (IATA) : II - Medium Danger
SECTION 15: Regulatory information
15.1. US Federal regulations
HI FLEX GREEN TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/05/2016 EN (English US) 9/10
styrene, inhibited (100-42-5)
RQ (Reportable quantity, section 304 of EPA's
List of Lists)
1000 lb
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Reactive hazard
Fire hazard
Delayed (chronic) health hazard
methyl ethyl ketone (78-93-3)
RQ (Reportable quantity, section 304 of EPA's
List of Lists)
5000 lb
15.2. International regulations
CANADA
No additional information available
EU-Regulations
No additional information available
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flam. Liq. 3 H226
Acute Tox. 4 (Inhalation:vapour) H332
Skin Irrit. 2 H315
Eye Irrit. 2 H319
Muta. 1B H340
Carc. 1B H350
Full text of H-phrases: see section 16
Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]
Carc.Cat.2; R45
Muta.Cat.2; R46
F; R11
Xn; R20
Xi; R36/38
Full text of R-phrases: see section 16
15.2.2. National regulations
styrene, inhibited (100-42-5)
Listed on EPA's Hazardous Air Pollutants (HAPS)
15.3. US State regulations
styrene, inhibited (100-42-5)
U.S. - California -
Proposition 65 -
Carcinogens List
U.S. - California -
Proposition 65 -
Developmental Toxicity
U.S. - California -
Proposition 65 -
Reproductive Toxicity -
Female
U.S. - California -
Proposition 65 -
Reproductive Toxicity - Male
Non-significant risk level
(NSRL)
styrene, inhibited (100-42-5)
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
HI FLEX GREEN TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/05/2016 EN (English US) 10/10
SECTION 16: Other information
Other information : None.
Full text of H-phrases: see section 16:
------ Acute Tox. 4 (Inhalation:vapour) Acute toxicity (inhalation:vapour) Category 4
------ Asp. Tox. 1 Aspiration hazard Category 1
------ Carc. 2 Carcinogenicity Category 2
------ Eye Irrit. 2A Serious eye damage/eye irritation Category 2A
------ Flam. Liq. 2 Flammable liquids Category 2
------ Flam. Liq. 3 Flammable liquids Category 3
------ Repr. 2 Reproductive toxicity Category 2
------ Skin Irrit. 2 Skin corrosion/irritation Category 2
------ STOT RE 1 Specific target organ toxicity (repeated exposure) Category 1
------ STOT SE 3 Specific target organ toxicity (single exposure) Category 3
------ STOT SE 3 Specific target organ toxicity (single exposure) Category 3
------ H225 Highly flammable liquid and vapor
------ H226 Flammable liquid and vapor
------ H304 May be fatal if swallowed and enters airways
------ H315 Causes skin irritation
------ H319 Causes serious eye irritation
------ H332 Harmful if inhaled
------ H335 May cause respiratory irritation
------ H336 May cause drowsiness or dizziness
------ H351 Suspected of causing cancer
------ H361 Suspected of damaging fertility or the unborn child
------ H372 Causes damage to organs through prolonged or repeated exposure
NFPA health hazard : 2 - Intense or continued exposure could cause temporary
incapacitation or possible residual injury unless prompt
medical attention is given.
NFPA fire hazard : 3 - Liquids and solids that can be ignited under almost all
ambient conditions.
NFPA reactivity : 2 - Normally unstable and readily undergo violent
decomposition but do not detonate. Also: may react
violently with water or may form potentially explosive
mixtures with water.
HMIS III Rating
Health : 2 Moderate Hazard - Temporary or minor injury may occur
Flammability : 3 Serious Hazard
Physical : 1 Slight Hazard
Personal Protection : H
SDS US (GHS HazCom 2012)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied
warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.
by | Sep 27, 2025
HI FLEX GREEN TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue: 01/05/2016 Revision date: 01/05/2016 Supersedes: 09/10/2014
01/05/2016 EN (English US) Page 1
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product form : Mixture
Trade name : HI FLEX GREEN TOOLING GEL COAT
CAS No : mixture
Product code : 406-009
Formula : na
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : TOOLING GEL COAT
1.3. Details of the supplier of the safety data sheet
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909.877.8477
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
GHS-US classification
Flam. Liq. 3 H226
Skin Irrit. 2 H315
Eye Irrit. 2A H319
Carc. 2 H351
Repr. 2 H361
STOT SE 3 H335
STOT RE 1 H372
2.2. Label elements
GHS-US labeling
Hazard pictograms (GHS-US) :
GHS02
GHS07
GHS08
Signal word (GHS-US) : Danger
Hazard statements (GHS-US) : H226 – Flammable liquid and vapor
H315 – Causes skin irritation
H319 – Causes serious eye irritation
H335 – May cause respiratory irritation
H351 – Suspected of causing cancer
H361 – Suspected of damaging fertility or the unborn child
H372 – Causes damage to organs through prolonged or repeated exposure
Precautionary statements (GHS-US) : P201 – Obtain special instructions before use
P202 – Do not handle until all safety precautions have been read and understood
P210 – Keep away from heat, hot surfaces, open flames, sparks. – No smoking
P233 – Keep container tightly closed
P240 – Ground/bond container and receiving equipment
P241 – Use explosion-proof electrical, lighting, ventilating equipment
P242 – Use only non-sparking tools
P243 – Take precautionary measures against static discharge
P260 – Do not breathe dust, fume, mist, spray, vapors
HI FLEX GREEN TOOLING GEL COAT
Safety Data Sheet
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P264 – Wash EXPOSED AREA. thoroughly after handling
P270 – Do not eat, drink or smoke when using this product
P271 – Use only outdoors or in a well-ventilated area
P280 – Wear eye protection, protective clothing, protective gloves
P302+P352 – IF ON SKIN: Wash with plenty of soap and water
P303+P361+P353 – IF ON SKIN (or hair): Remove/Take off immediately all contaminated
clothing. Rinse skin with water/shower
P304+P340 – IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable
for breathing
P305+P351+P338 – If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P308+P313 – IF exposed or concerned: Get medical advice/attention
P312 – Call a POISON CENTER or doctor/physician if you feel unwell
P314 – Get medical advice and attention if you feel unwell
P321 – Specific treatment (see SEEK MEDICAL AID. on this label)
P332+P313 – If skin irritation occurs: Get medical advice/attention
P337+P313 – If eye irritation persists: Get medical advice/attention
P362 – Take off contaminated clothing and wash it before reuse
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish
P403+P233 – Store in a well-ventilated place. Keep container tightly closed
P403+P235 – Store in a well-ventilated place. Keep cool
P405 – Store locked up
P501 – Dispose of contents/container to LOCAL, STATE, AND NATIONAL REGULATIONS.
2.3. Other hazards
No additional information available
2.4. Unknown acute toxicity (GHS-US)
No data available
SECTION 3: Composition/Information on ingredients
3.1. Substance
Not applicable
Full text of H-phrases: see section 16
3.2. Mixture
Name Product identifier % GHS-US classification
Unsaturated Polyester Resin (CAS No) TRADE SECRET <= 45 Not classified
styrene, inhibited (CAS No) 100-42-5 <= 37.78 Flam. Liq. 3, H226
Acute Tox. 4 (Inhalation:vapour),
H332
Skin Irrit. 2, H315
Eye Irrit. 2A, H319
Carc. 2, H351
Repr. 2, H361
STOT SE 3, H335
STOT RE 1, H372
Asp. Tox. 1, H304
methyl ethyl ketone (CAS No) 78-93-3 <= 4.2 Flam. Liq. 2, H225
STOT SE 3, H336
cobalt(II) 2-ethylhexanoate (CAS No) 136-52-7 <= 0.5 Carc. 2, H351
SECTION 4: First aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice
(show the label where possible).
First-aid measures after inhalation : Allow victim to breathe fresh air. Allow the victim to rest. Remove victim to fresh air and keep at
rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you
feel unwell.
First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Wash
with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs:
wash throughly for five minutes. seek medical attention. Get medical advice/attention. Specific
treatment (see seek medical attention. on this label).
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: SEEK IMMEDIATE MEDICAL ATTENTION. Get
medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
HI FLEX GREEN TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/05/2016 EN (English US) 3/10
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries : May cause genetic defects (avoid skin contact and inhalation.). May cause cancer (avoid skin
contact and inhalation.).
Symptoms/injuries after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled.
Symptoms/injuries after skin contact : Causes skin irritation.
Symptoms/injuries after eye contact : Causes serious eye irritation.
4.3. Indication of any immediate medical attention and special treatment needed
No additional information available
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Highly flammable liquid and vapor. Flammable liquid and vapor.
Explosion hazard : May form flammable/explosive vapor-air mixture.
Reactivity : No reactivity hazard other than the effects described in sub-sections below.
5.3. Advice for firefighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No
smoking.
6.1.1. For non-emergency personnel
Protective equipment : Gloves. Protective goggles. Protective clothing.
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Dam up the liquid spill. Contain released substance, pump into suitable containers.
Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect
spillage. Store away from other materials.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapors are flammable.
Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Provide good ventilation in process area to prevent formation of
vapor. No open flames. No smoking. Use only non-sparking tools. Use only outdoors or in a well-
ventilated area. Avoid breathing DUST, FUMES, MIST, OR VAPORS. Obtain special instructions
before use. Do not handle until all safety precautions have been read and understood. Eliminate
all ignition sources if safe to do so. Take precautionary measures against static discharge.
Hygiene measures : Wash HANDS thoroughly after handling.
HI FLEX GREEN TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/05/2016 EN (English US) 4/10
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond
container and receiving equipment. Use explosion-proof electrical, ventilating and lighting
equipment. equipment.
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : HEAT SPARKS
OR OPEN FLAMES. Keep in fireproof place. Keep container tightly closed.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.
7.3. Specific end use(s)
No additional information available
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
styrene, inhibited (100-42-5)
USA ACGIH ACGIH TWA (ppm) 20 ppm
USA ACGIH ACGIH STEL (ppm) 20 ppm
methyl ethyl ketone (78-93-3)
USA ACGIH ACGIH TWA (ppm) 200 ppm
USA ACGIH ACGIH STEL (ppm) 200 ppm
8.2. Exposure controls
Appropriate engineering controls : Ensure exposure is below occupational exposure limits (where available).
Personal protective equipment : Avoid all unnecessary exposure.
Hand protection : Wear protective gloves.
Eye protection : Chemical goggles or safety glasses.
Skin and body protection : Wear suitable protective clothing.
Respiratory protection : Wear appropriate mask.
Other information : Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Color : Green.
Odor : characteristic.
Odor threshold : No data available
pH : No data available
Relative evaporation rate (butyl acetate=1) : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : 79 - 146 C
Flash point : -6.67 C
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapor pressure : No data available
Relative vapor density at 20 C : No data available
Relative density : 1.1
Solubility : No data available
Log Pow : No data available
Log Kow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
HI FLEX GREEN TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/05/2016 EN (English US) 5/10
Oxidizing properties : No data available
Explosive limits : No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Not established. Highly flammable liquid and vapor. May form
flammable/explosive vapor-air mixture. Flammable liquid and vapor.
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Heat. Sparks.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity : Not classified
HI FLEX GREEN TOOLING GEL COAT ( f )mixture
ATE CLP (vapors) 11.000 mg/l/4h
styrene, inhibited (100-42-5)
LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
LD50 dermal rat 2820 mg/kg (Rat; Literature study; OECD 402: Acute Dermal Toxicity; >2000 mg/kg
bodyweight; Rat; Experimental value)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 inhalation rat (mg/l) 12 mg/l/4h (Rat; Literature study)
LC50 inhalation rat (ppm) 2770 ppm/4h (Rat; Literature study)
ATE CLP (oral) 5000.000 mg/kg body weight
ATE CLP (dermal) 2820.000 mg/kg body weight
ATE CLP (gases) 2770.000 ppmV/4h
ATE CLP (vapors) 12.000 mg/l/4h
ATE CLP (dust, mist) 12.000 mg/l/4h
methyl ethyl ketone (78-93-3)
LD50 oral rat 2737 mg/kg (Rat; Equivalent or similar to OECD 423; Read-across; 2054 mg/kg; Rat;
Equivalent or similar to OECD 423; Read-across; 2328 mg/kg; Rat)
LD50 dermal rabbit 6480 mg/kg (Rabbit; Experimental value; Equivalent or similar to OECD 402; >10; Rabbit)
LC50 inhalation rat (mg/l) 34 mg/l/4h (Rat; Literature study)
LC50 inhalation rat (ppm) 11300 ppm/4h (Rat; Literature study)
ATE CLP (oral) 2737.000 mg/kg body weight
ATE CLP (dermal) 6480.000 mg/kg body weight
ATE CLP (gases) 11300.000 ppmV/4h
ATE CLP (vapors) 34.000 mg/l/4h
ATE CLP (dust, mist) 34.000 mg/l/4h
cobalt(II) 2-ethylhexanoate (136-52-7)
LD50 oral rat 3129 mg/kg body weight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat > 2000 mg/kg body weight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)
ATE CLP (oral) 3129.000 mg/kg body weight
HI FLEX GREEN TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/05/2016 EN (English US) 6/10
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitization : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Suspected of causing cancer.
styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans
cobalt(II) 2-ethylhexanoate (136-52-7)
IARC group 2B – Possibly carcinogenic to humans
Reproductive toxicity : Suspected of damaging fertility or the unborn child.
Based on available data, the classification criteria are not met
Specific target organ toxicity (single exposure) : May cause respiratory irritation.
Specific target organ toxicity (repeated
exposure)
: Causes damage to organs through prolonged or repeated exposure.
Based on available data, the classification criteria are not met
Aspiration hazard : Not classified
Based on available data, the classification criteria are not met
Potential Adverse human health effects and
symptoms
: Harmful if inhaled. Based on available data, the classification criteria are not met.
Symptoms/injuries after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled.
Symptoms/injuries after skin contact : Causes skin irritation.
Symptoms/injuries after eye contact : Causes serious eye irritation.
SECTION 12: Ecological information
12.1. Toxicity
styrene, inhibited (100-42-5)
LC50 fish 1 25 mg/l (96 h; Lepomis macrochirus; GLP)
LC50 other aquatic organisms 1 10 – 100 mg/l (96 h)
EC50 Daphnia 1 23 mg/l (48 h; Daphnia magna; Locomotor effect)
LC50 fish 2 32 mg/l (96 h; Pimephales promelas)
EC50 Daphnia 2 27 mg/l (24 h; Daphnia magna; GLP)
TLM fish 1 25.1 mg/l (96 h; Lepomis macrochirus; Soft water)
TLM fish 2 46.4 mg/l (96 h; Pimephales promelas; Soft water)
TLM other aquatic organisms 1 10 – 100,96 h
Threshold limit other aquatic organisms 1 10 – 100,96 h; Pseudomonas putida
Threshold limit other aquatic organisms 2 72 mg/l
Threshold limit algae 1 > 200 mg/l (192 h; Scenedesmus quadricauda; Inhibitory)
Threshold limit algae 2 67 mg/l (Microcystis aeruginosa; Inhibitory)
methyl ethyl ketone (78-93-3)
LC50 fish 1 1690 mg/l (96 h; Lepomis macrochirus; Lethal)
EC50 Daphnia 1 308 mg/l (48 h; Daphnia magna; Locomotor effect)
LC50 fish 2 2990 mg/l (96 h; Pimephales promelas)
TLM fish 1 5600 mg/l (96 h; Gambusia affinis)
TLM fish 2 1690 mg/l (96 h; Lepomis macrochirus)
TLM other aquatic organisms 1 > 1000 ppm (96 h)
Threshold limit algae 1 110 mg/l (168 h; Microcystis aeruginosa)
Threshold limit algae 2 4300 mg/l (192 h; Scenedesmus quadricauda)
cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 1 54.1 mg/l (96 h; Pimephales promelas)
EC50 Daphnia 1 2618 g/l (48 h)
Threshold limit algae 1 24.1 g/l (7 days)
HI FLEX GREEN TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/05/2016 EN (English US) 7/10
cobalt(II) 2-ethylhexanoate (136-52-7)
Threshold limit algae 2 90.1 g/l (7 days; Lemna minor; Growth rate)
12.2. Persistence and degradability
HI FLEX GREEN TOOLING GEL COAT (mixture)
Persistence and degradability Not established.
styrene, inhibited (100-42-5)
Persistence and degradability Readily biodegradable in water. Not readily biodegradable in water. Forming sediments in
water. Non degradable in the soil. Adsorbs into the soil. Photodegradation in the air. Not
established.
Chemical oxygen demand (COD) 2.80 g O /g substance
ThOD 3.07 g O /g substance
BOD (% of ThOD) 0.42 % ThOD
methyl ethyl ketone (78-93-3)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. Not established.
Biochemical oxygen demand (BOD) 1.92 g O /g substance
Chemical oxygen demand (COD) 2.31 g O /g substance
ThOD 2.44 g O /g substance
BOD (% of ThOD) > % ThOD (5 day(s)) > 0.5
cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability Biodegradability in water: no data available.
Unsaturated Polyester Resin (TRADE SECRET)
Persistence and degradability Not established.
12.3. Bioaccumulative potential
HI FLEX GREEN TOOLING GEL COAT (mixture)
Bioaccumulative potential Not established.
styrene, inhibited (100-42-5)
BCF fish 1 35.5 (Carassius auratus)
BCF other aquatic organisms 1 74
Log Pow 2.96 (Experimental value; OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method; 25 C)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Not established.
methyl ethyl ketone (78-93-3)
Log Pow 0.3 (Experimental value; OECD 117: Partition Coefficient (n-octanol/water), HPLC method; 40
C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
cobalt(II) 2-ethylhexanoate (136-52-7)
Bioaccumulative potential No bioaccumulation data available.
Unsaturated Polyester Resin (TRADE SECRET)
Bioaccumulative potential Not established.
12.4. Mobility in soil
styrene, inhibited (100-42-5)
Surface tension 0.032 N/m (19 C)
methyl ethyl ketone (78-93-3)
Surface tension 0.024 N/m (20 C)
Ecology - soil Slightly harmful to plants.
cobalt(II) 2-ethylhexanoate (136-52-7)
Surface tension 0.064 N/m (20 C; 1 g/l)
12.5. Other adverse effects
Other information : Avoid release to the environment.
HI FLEX GREEN TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/05/2016 EN (English US) 8/10
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to approved disposal site.
Additional information : Handle empty containers with care because residual vapors are flammable.
Ecology - waste materials : Avoid release to the environment.
SECTION 14: Transport information
In accordance with DOT
UN-No.(DOT) : UN1866
Proper Shipping Name (DOT) : RESIN SOLUTION
Transport hazard class(es) (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120
Hazard labels (DOT) : 3 - Flammable liquid
Packing group (DOT) : II - Medium Danger
Additional information
Other information : No supplementary information available.
ADR
Transport document description : UN 1866, 3, II, (D/E)
Packing group (ADR) : II
Class (ADR) : 3 - Flammable liquid
Hazard identification number (Kemler No.) : 33
Classification code (ADR) : F1
Hazard labels (ADR) : 3 - Flammable liquids
Orange plates :
Tunnel restriction code : D/E
LQ : 5l
Excepted quantities (ADR) : E2
Transport by sea
UN-No. (IMDG) : 1866
Proper Shipping Name (IMDG) : RESIN SOLUTION
Class (IMDG) : 3 - Flammable liquids
Packing group (IMDG) : II - substances presenting medium danger
Air transport
UN-No. (IATA) : 1866
Proper Shipping Name (IATA) : RESIN SOLUTION
Class (IATA) : 3 - Flammable Liquids
Packing group (IATA) : II - Medium Danger
SECTION 15: Regulatory information
15.1. US Federal regulations
HI FLEX GREEN TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/05/2016 EN (English US) 9/10
styrene, inhibited (100-42-5)
RQ (Reportable quantity, section 304 of EPA's
List of Lists)
1000 lb
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Reactive hazard
Fire hazard
Delayed (chronic) health hazard
methyl ethyl ketone (78-93-3)
RQ (Reportable quantity, section 304 of EPA's
List of Lists)
5000 lb
15.2. International regulations
CANADA
No additional information available
EU-Regulations
No additional information available
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flam. Liq. 3 H226
Acute Tox. 4 (Inhalation:vapour) H332
Skin Irrit. 2 H315
Eye Irrit. 2 H319
Muta. 1B H340
Carc. 1B H350
Full text of H-phrases: see section 16
Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]
Carc.Cat.2; R45
Muta.Cat.2; R46
F; R11
Xn; R20
Xi; R36/38
Full text of R-phrases: see section 16
15.2.2. National regulations
styrene, inhibited (100-42-5)
Listed on EPA's Hazardous Air Pollutants (HAPS)
15.3. US State regulations
styrene, inhibited (100-42-5)
U.S. - California -
Proposition 65 -
Carcinogens List
U.S. - California -
Proposition 65 -
Developmental Toxicity
U.S. - California -
Proposition 65 -
Reproductive Toxicity -
Female
U.S. - California -
Proposition 65 -
Reproductive Toxicity - Male
Non-significant risk level
(NSRL)
styrene, inhibited (100-42-5)
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
HI FLEX GREEN TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/05/2016 EN (English US) 10/10
SECTION 16: Other information
Other information : None.
Full text of H-phrases: see section 16:
------ Acute Tox. 4 (Inhalation:vapour) Acute toxicity (inhalation:vapour) Category 4
------ Asp. Tox. 1 Aspiration hazard Category 1
------ Carc. 2 Carcinogenicity Category 2
------ Eye Irrit. 2A Serious eye damage/eye irritation Category 2A
------ Flam. Liq. 2 Flammable liquids Category 2
------ Flam. Liq. 3 Flammable liquids Category 3
------ Repr. 2 Reproductive toxicity Category 2
------ Skin Irrit. 2 Skin corrosion/irritation Category 2
------ STOT RE 1 Specific target organ toxicity (repeated exposure) Category 1
------ STOT SE 3 Specific target organ toxicity (single exposure) Category 3
------ STOT SE 3 Specific target organ toxicity (single exposure) Category 3
------ H225 Highly flammable liquid and vapor
------ H226 Flammable liquid and vapor
------ H304 May be fatal if swallowed and enters airways
------ H315 Causes skin irritation
------ H319 Causes serious eye irritation
------ H332 Harmful if inhaled
------ H335 May cause respiratory irritation
------ H336 May cause drowsiness or dizziness
------ H351 Suspected of causing cancer
------ H361 Suspected of damaging fertility or the unborn child
------ H372 Causes damage to organs through prolonged or repeated exposure
NFPA health hazard : 2 - Intense or continued exposure could cause temporary
incapacitation or possible residual injury unless prompt
medical attention is given.
NFPA fire hazard : 3 - Liquids and solids that can be ignited under almost all
ambient conditions.
NFPA reactivity : 2 - Normally unstable and readily undergo violent
decomposition but do not detonate. Also: may react
violently with water or may form potentially explosive
mixtures with water.
HMIS III Rating
Health : 2 Moderate Hazard - Temporary or minor injury may occur
Flammability : 3 Serious Hazard
Physical : 1 Slight Hazard
Personal Protection : H
SDS US (GHS HazCom 2012)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied
warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.
by | Sep 27, 2025
HI FLEX UNTINTED TOOLING GEL COAT
Hoja de datos de seguridad
seg n el Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Fecha de emisi n: 09/10/2014Fecha de revisi n: 09/27/2014Reemplaza: 09/10/2014
12/05/2014 ES (- MX) Page 1
SECCI N 1: Identificaci n de la sustancia o la mezcla y de la sociedad o la empresa
1.1. Grupo de productos
Forma de producto :Mezcla
Nombre comercial :HI FLEX UNTINTED TOOLING GEL COAT
CAS N :mixture
C digo de producto :404-009
F rmula :na
1.2. Uso recomendado del producto qu mico y restricciones
Use of the substance/mixture
:TOOLING GEL COAT
1.3. Datos sobre el proveedor de la hojas de datos de seguridad
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909.877.8477
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
1.4. N mero de tel fono en caso de emergencia
N mero de emergencia :ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300
SECCI N 2: Identificaci n de los peligros
2.1. Clasificaci n de la sustancia o mezcla
Clasificaci n de SAC-US2
Flam. Liq. 3 H226
Skin Irrit. 2 H315
Eye Irrit. 2A H319
Carc. Not classified
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2.2. Elementos de las etiquetas
Etiquetado GHS-US
Pictogramas de peligro (GHS-US) :
GHS02
GHS07
Palabra de advertencia (GHS-US) :Atenci n
Indicaciones de peligro (GHS-US) :H226 – L quido y vapores inflamables
H315 – Provoca irritaci n cut nea
H319 – Provoca irritaci n ocular grave
Consejos de precauci n (GHS-US) :P210 – Mantener alejado calor, superficies calientes, llama abierta, chispas. No fumar
P233 – Mantener el recipiente herm ticamente cerrado
P240 – Toma de tierra/enlace equipotencial del recipiente y del equipo receptor
P241 – Utilizar un material el ctrico, iluminaci n, ventilaci n antideflagrante
P242 – No utilizar herramientas que produzcan chispas
P243 – Tomar medidas de precauci n contra descargas electrost ticas
P264 – Lavarse EXPOSED AREA. cuidadosamente despu s la manipulaci n
P280 – Usar protecci n ocular, ropas de protecci n, guantes de protecci n
P302+P352 – EN CASO DE CONTACTO CON LA PIEL: Lavar con abundante agua y jab n
P303+P361+P353 – EN CASO DE CONTACTO CON LA PIEL (o el pelo): Quitar
inmediatamente la ropa contaminada. Enjuagar la piel con agua/ducharse
P305+P351+P338 – En caso de contacto con los ojos: Enjuagar con agua cuidadosamente
durante varios minutos. Quitar las lentes de contacto cuando est n presentes y pueda hacerse
con facilidad. Proseguir con el lavado
P321 – Tratamiento espec fico (v ase SEEK MEDICAL AID. en esta etiqueta)
P332+P313 – En caso de irritaci n cut nea: consultar a un m dico
P337+P313 – Si la irritaci n ocular persiste, consultar a un m dico
P362 – Quitar la ropa contaminada y lavarsela antes de volverla a usar
P370+P378 – En caso de incendio: Utilizar carbon dioxide (CO2), dry chemical powder, foam
en la extinci n
P403+P235 – Almacenar en un lugar bien ventilado
P501 – Eliminar el contenido/recipiente LOCAL, STATE, AND NATIONAL REGULATIONS.
2.3. Otros peligros que no figuren en la clasificaci n
No additional information available
2.4. (GHS-US)
No hay datos disponibles
SECCI N 3: Composici n/informaci n sobre los ingredientes
3.1. Sustancia
No aplicable
Full text of H-phrases: see section 16
3.2. Mezcla
Nombre Grupo de productos % Clasificaci n de SAC-US2
Unsaturated Polyester Resin (CAS N )TRADE SECRET <= 50 No est clasificado
styrene, inhibited (CAS N )100-42-5 <= 42.3 Flam. Liq. 3, H226
Acute Tox. 4 (Inhalation:vapour),
H332
Skin Irrit. 2, H315
Eye Irrit. 2A, H319
Carc. 2, H351
methyl ethyl ketone (CAS N )78-93-3 <= 4.7 Flam. Liq. 2, H225
cobalt(II) 2-ethylhexanoate (CAS N )136-52-7 <= 0.5 Carc. 2, H351
HI FLEX UNTINTED TOOLING GEL COAT
Hoja de datos de seguridad
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SECCI N 4: Medidas de primeros auxilios
4.1. Descripci n de los primeros auxilios
Medidas de primeros auxilios general :Never give anything by mouth to an unconscious person. If you feel unwell, seek medical
advice (show the label where possible).
Medidas de primeros auxilios tras una inhalaci n:Assure fresh air breathing. Allow the victim to rest. Transportar la v ctima al aire libre y
mantenerla en reposo en una posici n que le facilite la respiraci n. Llamar a un CENTRO DE
TOXICOLOG A o a un m dico si la persona se encuentra mal.
Medidas de primeros auxilios tras el contacto
con la piel
:Enjuagar la piel con agua/ducharse. Quitar inmediatamente toda la ropa contaminada. Lavar
con abundante agua y jab n. Lavar la ropa contaminada antes de volverla a usar. En caso de
irritaci n cut nea: wash throughly for five minutes. seek medical attention. Consultar a un
m dico. Tratamiento espec fico (v ase seek medical attention. en esta etiqueta).
Medidas de primeros auxilios tras un contacto
con los ojos
:Enjuagar con agua cuidadosamente durante varios minutos. Quitar los lentes de contacto
cuando est n presentes y pueda hacerse con facilidad. Proseguir con el lavado. Si la irritaci n
ocular persiste: SEEK IMMEDIATE MEDICAL ATTENTION. Consultar a un m dico.
Medidas de primeros auxilios tras una ingesti n:Enjuagarse la boca. NO provocar el v mito. Obtain emergency medical attention.
4.2. S ntomas/efectos m s importantes, agudos y retardados
S ntomas/lesiones :Puede provocar defectos gen ticos (avoid skin contact and inhalation.). Puede provocar c ncer
(avoid skin contact and inhalation.).
S ntomas/lesiones despu s de inhalaci n :Danger of serious damage to health by prolonged exposure through inhalation. Nocivo si se
inhala.
S ntomas/lesiones despu s de contacto con la
piel
:Provoca irritaci n cut nea.
S ntomas/lesiones despu s del contacto con el
ojo
:Provoca irritaci n ocular grave.
4.3. Indicaci n de la necesidad de recibir atenci n m dica inmediata y tratamiento especial requerido en caso necesario
No additional information available
SECCI N 5: Medidas de combate a incendios
5.1. Medios de extinci n
Suitable extinguishing media :Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Material extintor inadecuado :Do not use a heavy water stream.
5.2. Peligros espec ficos de los productos qu micos
Peligro de incendio :L quido y vapores muy inflamables. L quido y vapores inflamables.
Peligro de explosi n :May form flammable/explosive vapour-air mixture.
Reactividad :No reactivity hazard other than the effects described in sub-sections below.
5.3. Equipo de protecci n especial y precauciones para los
equipos de lucha contra incendios
Instrucciones para extinci n de incendio :Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Avoid (reject) fire-fighting water to enter environment.
Protecci n durante la extinci n de incendios:Do not enter fire area without proper protective equipment, including respiratory protection.
SECCI N 6: Medidas en caso de liberaci n accidental
6.1. Precauciones individuales, equipos de protecci n y procedimientos de emergencia
Medidas generales :Remove ignition sources. Use special care to avoid static electric charges. No naked lights. No
smoking.
6.1.1.Para el personal que no forma parte de los servicios de emergencia
Equipo de protecci n :Gloves. Protective goggles. Protective clothing.
Planos de emergencia :Evacuate unnecessary personnel.
6.1.2.Para el personal de los servicios de emergencia
Equipo de protecci n :Equip cleanup crew with proper protection.
Planos de emergencia :Ventilate area.
6.2. Precauciones ambientales
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
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6.3. M todos y materiales de aislamiento y limpieza
Para la contenci n :Dam up the liquid spill. Contain released substance, pump into suitable containers.
M todos de limpieza :Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible.
Recoger los vertidos. Almacenar alejado de otras materias.
6.4. Motivo de utilizaci n desaconsejado
See Heading 8. Exposure controls and personal protection.
SECCI N 7: Manipulaci n y almacenamiento
7.1. Precauciones para una manipulaci n segura
Peligros adicionales cuando procesado :Handle empty containers with care because residual vapours are flammable.
Precauciones para una manipulaci n segura:Wash hands and other exposed areas with mild soap and water before eat, drink or smoke and
when leaving work. Provide good ventilation in process area to prevent formation of vapour. No
naked lights. No smoking. No utilizar herramientas que produzcan chispas. Utilizar s lo al aire
libre o en un lugar bien ventilado. Evitar respirar DUST, FUMES, MIST, OR VAPORS.
Procurarse las instrucciones antes del uso. No manipular la sustancia antes de haber le do y
comprendido todas las precauciones de seguridad. Eliminar todas las fuentes de ignici n si
puede hacerse sin riesgo. Tomar medidas de precauci n contra descargas electrost ticas.
Medidas de higiene :Lavarse HANDS cuidadosamente despu s la manipulaci n.
7.2. Condiciones de almacenamiento seguro, incluidas cualesquiera incompatibilidades
Medidas t cnicas :Proper grounding procedures to avoid static electricity should be followed. Toma de
tierra/enlace equipotencial del recipiente y del equipo receptor. Utilizar un material electrical,
ventilating and lighting equipment. antideflagrante.
Condiciones de almacenamiento :Keep only in the original container in a cool, well ventilated place away from : HEAT SPARKS
OR OPEN FLAMES. Keep in fireproof place. Mantener el recipiente herm ticamente cerrado.
Productos incompatibles :Strong bases. strong acids.
Materiales incompatibles :Sources of ignition. Direct sunlight. Heat sources.
7.3. Specific end use(s)
No additional information available
SECCI N 8: Controles de exposici n/protecci n individual
8.1. Par metros de control
styrene, inhibited (100-42-5)
USA ACGIH ACGIH TWA (ppm) 20 ppm
USA ACGIH ACGIH STEL (ppm) 40 ppm
methyl ethyl ketone (78-93-3)
USA ACGIH ACGIH TWA (ppm) 200 ppm
USA ACGIH ACGIH STEL (ppm) 300 ppm
8.2. Controles de exposici n
Controles apropiados de ingenier a :Ensure exposure is below occupational exposure limits (where available).
Equipo de protecci n personal :Avoid all unnecessary exposure.
Protecci n de las manos :Usar guantes de protecci n.
Protecci n ocular :Chemical goggles or safety glasses.
Protecci n de la piel y del cuerpo :Wear suitable protective clothing.
Protecci n de las v as respiratorias :Wear approved mask.
Otra informaci n :When using, do not eat, drink or smoke.
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SECCI N 9: Propiedades f sicas y qu micas
9.1. Information on basic physical and chemical properties
Estado f sico :L quido
Color :Negro.
Olor :characteristic.
Umbral olfativo :No hay datos disponibles
pH :No hay datos disponibles
Grado relativo de evaporaci n (acetato de
butilo=1)
:No hay datos disponibles
Punto de fusi n :No hay datos disponibles
Punto de solidificaci n :No hay datos disponibles
Punto de ebullic on : 64 C
Punto de inflamaci n :30 - 34 C
Temperatura de autoignici n :No hay datos disponibles
Temperatura de descomposici n :No hay datos disponibles
Inflamabilidad (s lido, gas) :No hay datos disponibles
Presi n de vapor :No hay datos disponibles
Densidad relativa de vapor a 20 C :No hay datos disponibles
Densidad relativa : 1.1
Solubilidad :No hay datos disponibles
Log Pow :No hay datos disponibles
Log Kow :No hay datos disponibles
Viscosidad, cinem tico :No hay datos disponibles
Viscosidad, din mico :No hay datos disponibles
Propiedades explosivas :No hay datos disponibles
Propiedades comburentes :No hay datos disponibles
Explosive limits :No hay datos disponibles
9.2. Otra informaci n
No additional information available
SECCI N 10: Estabilidad y reactividad
10.1.Reactividad
No reactivity hazard other than the effects described in sub-sections below.
10.2.Estabilidad qu mica
Polymerization can result in formation of solid deposits, even in vapour space. Not established. L quido y vapores muy inflamables. May form
flammable/explosive vapour-air mixture. L quido y vapores inflamables.
10.3.Posibilidad de reacciones peligrosas
Not established.
10.4.Condiciones que deben evitarse
Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Heat.
10.5.Materiales incompatibles
strong acids. Strong bases.
10.6.Productos de descomposici n peligrosos
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECCI N 11: Informaci n toxicol gica
11.1.Informaci n sobre los efectos toxicol gicos
Toxicidad aguda :No est clasificado
HI FLEX UNTINTED TOOLING GEL COAT( )mixture
ETA CLP (vapores) 11.000 mg/l/4h
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styrene, inhibited (100-42-5)
DL50 oral rata 5000 mg/kg (>6000 mg/kg bodyweight; Rat; Rat)
DL50 cut neo rata 2820 mg/kg (>2000 mg/kg bodyweight; Rat; Rat; Experimental value)
DL50 cut neo conejo 5010 mg/kg (Rabbit)
CL50 inhalaci n rata (mg/l) 12 mg/l/4h (Rat)
CL50 inhalaci n rata (ppm) 2770 ppm/4h (Rat)
ETA CLP (oral) 5000.000 mg/kg bodyweight
ETA CLP (cut nea) 2820.000 mg/kg bodyweight
ETA CLP (gases) 2770.000 ppmv/4h
ETA CLP (vapores) 12.000 mg/l/4h
ETA CLP (polvos,niebla) 12.000 mg/l/4h
methyl ethyl ketone (78-93-3)
DL50 oral rata 2737 mg/kg (2054 mg/kg; 2328 mg/kg; Rat; Rat; Rat)
DL50 cut neo conejo 6480 mg/kg (>10; Rabbit; Rabbit; Experimental value,>10; Rabbit; Rabbit; Experimental value)
CL50 inhalaci n rata (mg/l) 34 mg/l/4h (Rat)
CL50 inhalaci n rata (ppm) 11300 ppm/4h (Rat)
ETA CLP (oral) 2737.000 mg/kg bodyweight
ETA CLP (cut nea) 6480.000 mg/kg bodyweight
ETA CLP (gases) 11300.000 ppmv/4h
ETA CLP (vapores) 34.000 mg/l/4h
ETA CLP (polvos,niebla) 34.000 mg/l/4h
Corrosi n/irritaci n en la piel :Provoca irritaci n cut nea.
Lesiones/irritaciones graves en los ojos :Provoca irritaci n ocular grave.
Sensibilizaci n respiratoria o de la piel:No est clasificado
Mutagenidad de c lulas germinativas :No est clasificado
Carcinogenicidad :No est clasificado.
styrene, inhibited (100-42-5)
Grupo IARC 2B – Posiblemente Carcin geno para los Seres Humanos
cobalt(II) 2-ethylhexanoate (136-52-7)
Grupo IARC 2B – Posiblemente Carcin geno para los Seres Humanos
Toxicidad a la reproducci n :No est clasificado
Seg n datos disponibles, los criterios de clasificaci n no se cumplen
Toxicidad sist mica para rganos diana
(exposici n nica)
:No est clasificado
Toxicidad sist mica para rganos diana
(exposici n repetida)
:No est clasificado
Seg n datos disponibles, los criterios de clasificaci n no se cumplen
Peligro por aspiraci n :No est clasificado
Seg n datos disponibles, los criterios de clasificaci n no se cumplen
S ntomas y posibles efectos adversos para la
salud humana
:Nocivo si se inhala. Seg n datos disponibles, los criterios de clasificaci n no se cumplen.
S ntomas/lesiones despu s de inhalaci n :Danger of serious damage to health by prolonged exposure through inhalation. Nocivo si se
inhala.
S ntomas/lesiones despu s de contacto con la
piel
:Provoca irritaci n cut nea.
S ntomas/lesiones despu s del contacto con el
ojo
:Provoca irritaci n ocular grave.
SECCI N 12: Informaci n ecol gica
12.1.Toxicidad
styrene, inhibited (100-42-5)
CL50 peces 1 25 mg/l (96 h; Lepomis macrochirus)
CL50 otros organismos acu ticos 1 10 – 100 mg/l (96 h)
CE50 Daphnia 1 23 mg/l (48 h; Daphnia magna; LOCOMOTOR EFFECT)
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styrene, inhibited (100-42-5)
CL50 peces 2 32 mg/l (96 h; Pimephales promelas)
CE50 Daphnia 2 27 mg/l (24 h; Daphnia magna)
TLM peces 1 25.1 mg/l (96 h; Lepomis macrochirus; SOFT WATER)
TLM peces 2 46.4 mg/l (96 h; Pimephales promelas; SOFT WATER)
TLM otros organismos acu ticos 1 10 – 100,96 h
Umbral l mite para otros orgnismos acu ticos 110 – 100,96 h; Pseudomonas putida
Umbral l mite para otros orgnismos acu ticos 272 mg/l
Umbral l mite algas 1 > 200 mg/l (192 h; Scenedesmus quadricauda; INHIBITORY)
Umbral l mite algas 2 67 mg/l (Microcystis aeruginosa; INHIBITORY)
methyl ethyl ketone (78-93-3)
CL50 peces 1 1690 mg/l (96 h; Lepomis macrochirus; LETHAL)
CE50 Daphnia 1 308 mg/l (48 h; Daphnia magna; LOCOMOTOR EFFECT)
CL50 peces 2 2990 mg/l (96 h; Pimephales promelas)
TLM peces 1 5600 mg/l (96 h; Gambusia affinis)
TLM peces 2 1690 mg/l (96 h; Lepomis macrochirus)
TLM otros organismos acu ticos 1 > 1000 ppm (96 h)
Umbral l mite algas 1 110 mg/l (168 h; Microcystis aeruginosa)
Umbral l mite algas 2 4300 mg/l (192 h; Scenedesmus quadricauda)
12.2.Persistencia y degradabilidad
HI FLEX UNTINTED TOOLING GEL COAT(mixture)
Persistencia y degradabilidad Not established.
styrene, inhibited (100-42-5)
Persistencia y degradabilidad Readily biodegradable in water. Not readily biodegradable in water. Forming sediments in
water. Non degradable in the soil. Adsorbs into the soil. Photodegradation in the air. Not
established.
Demanda qu mica de ox geno (COD) 2.80 g O /g substance
ThOD 3.07 g O /g substance
DBO (% of ThOD) 0.42 % ThOD
methyl ethyl ketone (78-93-3)
Persistencia y degradabilidad Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. Not established.
Biochemical oxygen demand (BOD) 1.92 g O /g substance
Demanda qu mica de ox geno (COD) 2.31 g O /g substance
ThOD 2.44 g O /g substance
DBO (% of ThOD) 0.79 % ThOD
cobalt(II) 2-ethylhexanoate (136-52-7)
Persistencia y degradabilidad Biodegradability in water: no data available.
Unsaturated Polyester Resin (TRADE SECRET)
Persistencia y degradabilidad Not established.
12.3.Potencial de bioacumulaci n
HI FLEX UNTINTED TOOLING GEL COAT(mixture)
Potencial de bioacumulaci n Not established.
styrene, inhibited (100-42-5)
BCF peces 1 12 – 77 (QSAR)
BCF peces 2 35.5 (Carassius auratus)
Log Pow 2.95 – 3.16 (Experimental value)
Potencial de bioacumulaci n Low potential for bioaccumulation (BCF < 500). Not established.
methyl ethyl ketone (78-93-3)
Log Pow 0.3 (Experimental value; 40 C,Experimental value; 40 C)
Potencial de bioacumulaci n Low potential for bioaccumulation (Log Kow < 4). Not established.
cobalt(II) 2-ethylhexanoate (136-52-7)
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Potencial de bioacumulaci n No bioaccumulation data available.
Unsaturated Polyester Resin (TRADE SECRET)
Potencial de bioacumulaci n Not established.
12.4.Movilidad en suelo
styrene, inhibited (100-42-5)
Tensi n de superficie 0.032 N/m (19 C)
methyl ethyl ketone (78-93-3)
Tensi n de superficie 0.024 N/m (20 C)
Ecolog a - suelo Slightly harmful to plants.
12.5.Otros efectos adversos
Otra informaci n :No dispersar en el medio ambiente.
SECCI N 13: Consideraciones relativas a la eliminaci n
13.1.Descripci n de los residuos e informaci n sobre la manera de manipularlos sin peligro, as como sus m todos de eliminaci n
Recomendaciones para la eliminaci n de
residuos
:Dispose in a safe manner in accordance with local/national regulations. Eliminar el
contenido/recipiente approved disposal site.
Informaci n adicional :Handle empty containers with care because residual vapours are flammable.
Ecolog a - residuos materiales :No dispersar en el medio ambiente.
SECCI N 14: Informaci n del transporte
In accordance with DOT
N ONU (DOT) :UN1866
DOT Designaci n Oficial de Transporte :RESIN SOLUTION
Departamento de Transporte (DOT) Clases de
Peligro
:3 - Clase 3 - L quido inflamable y combustible 49 CFR 173.120
Etiquetas de peligro (DOT) :3 - Flammable liquid
Grupo de embalaje (DOT) :III - Riesgo peque o
Informaci n adicional
Otra informaci n :No hay informaci n adicional disponible.
HI FLEX UNTINTED TOOLING GEL COAT
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ADR
Descripci n del documento del transporte :UN 1866, 3, III, (D/E)
Grupo de embalaje (ADR) :III
Clase (ADR) :3 - L quido inflamable
N mero de identificaci n de peligro (N Kemler):33
C digo de clasificaci n (ADR) :F1
Etiquetas de peligro (ADR) :3 - L quido inflamable
Panel naranja :
C digo de restricci n de t nel :D/E
LQ :5L
Cantidades exceptuadas (ADR) :E2
Producto comercial
N ONU (IMDG) :1866
Designaci n Oficial de Transporte (IMDG) :RESIN SOLUTION
Clase (IMDG) :3 - L quido inflamable
Grupo de embalaje (IMDG) :III - substances presenting low danger
Air transport
N ONU (IATA) :1866
Designaci n Oficial de Transporte (IATA) :RESIN SOLUTION
Clase (IATA) :3 - Flammable Liquids
Grupo de embalaje (IATA) :III - Riesgo peque o
SECCI N 15: Informaci n reglamentaria
15.1. Regulaciones federales de EE.UU
styrene, inhibited (100-42-5)
RQ (Cantidad reportable, secci n 304 de Lista
de listas de la EPA):
1000 lb
SARA Secci n 311/312 Clases de Peligro Peligro inmediato para la salud (agudo)
Peligro reactivo
Peligro de incendio
Peligro para la salud tardio (cr nico)
methyl ethyl ketone (78-93-3)
RQ (Cantidad reportable, secci n 304 de Lista
de listas de la EPA):
5000 lb
15.2. Regulaciones Internacionales
CANADA
No additional information available
EU-Regulations
No additional information available
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Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flam. Liq. 3 H226
Acute Tox. 4 (Inhalation:vapour) H332
Skin Irrit. 2 H315
Eye Irrit. 2 H319
Muta. 1B H340
Carc. 1B H350
Full text of H-phrases: see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Carc.Cat.2; R45
Muta.Cat.2; R46
F; R11
Xn; R20
Xi; R36/38
Full text of R-phrases: see section 16
15.2.2.National regulations
styrene, inhibited (100-42-5)
Listed on EPA's Hazardous Air Pollutants (HAPS)
15.3. Regulaciones Estatales de EE.UU
styrene, inhibited (100-42-5)
EE.UU - California -
Proposici n 65 - Lista de
Carcin genos
EE.UU - California -
Proposici n 65 - Toxicidad
para el Desarrollo
EE.UU - California -
Proposici n 65 - Toxicidad
Reproductiva - Feminino
EE.UU - California -
Proposici n 65 - Toxicidad
Reproductiva - Masculino
Ning n nivel de riesgo de
importancia (NSRL)
styrene, inhibited (100-42-5)
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
SECCI N 16: Otra informaci n
Otra informaci n :Ninguno.
Full text of H-phrases: see section 16:
------Acute Tox. 4 (Inhalation:vapour) Acute toxicity (inhalation:vapour) Category 4
------Carc. 2 Carcinogenicity, Category 2
------Carc. Not classified Carcinogenicity Not classified
------Eye Irrit. 2A Serious eye damage/eye irritation, Category 2A
------Flam. Liq. 2 Flammable liquids, Category 2
------Flam. Liq. 3 Flammable liquids, Category 3
------Skin Irrit. 2 Skin corrosion/irritation, Category 2
------H225 L quido y vapores muy inflamables
------H226 L quido y vapores inflamables
------H315 Provoca irritaci n cut nea
------H319 Provoca irritaci n ocular grave
------H332 Nocivo si se inhala
------H351 Suseptible de provocar c ncer
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NFPA peligro para la salud :2 - Una exposici n intensiva o continua podr a causar
incapacidad temporal o posible da o residual, a menos
que se reciba atenci n m dica inmediata.
NFPA peligro de incendio :3 - L quidos y s lidos que pueden inflamarse en casi todas
las condiciones ambientales.
NFPA reactividad :2 - Normalmente inestable y f cilmente sufre
descomposici n violento pero no detona. Tambi n: puede
reaccionar violentamente con el agua o puede formar
mezclas potencialmente explosivas con agua.
HMIS III Rating
Salud :2 Moderate Hazard - Puede ocurrir una lesi n temporal o menor
Inflamabilidad :3 Serious Hazard
F sico :1 Slight Hazard
Protecci n personal :H
SDS US (GHS HazCom 2012)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied
warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.
by | Sep 27, 2025
HI FLEX BLACK TOOLING GEL COAT
Hoja de datos de seguridad
seg n el Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Fecha de emisi n: 09/10/2014Fecha de revisi n: 09/27/2014Reemplaza: 09/10/2014
12/05/2014 ES (- MX) Page 1
SECCI N 1: Identificaci n de la sustancia o la mezcla y de la sociedad o la empresa
1.1. Grupo de productos
Forma de producto :Mezcla
Nombre comercial :HI FLEX BLACK TOOLING GEL COAT
CAS N :mixture
C digo de producto :402-009
F rmula :na
1.2. Uso recomendado del producto qu mico y restricciones
Use of the substance/mixture
:TOOLING GEL COAT
1.3. Datos sobre el proveedor de la hojas de datos de seguridad
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909.877.8477
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
1.4. N mero de tel fono en caso de emergencia
N mero de emergencia :ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300
SECCI N 2: Identificaci n de los peligros
2.1. Clasificaci n de la sustancia o mezcla
Clasificaci n de SAC-US2
Flam. Liq. 3 H226
Skin Irrit. 2 H315
Eye Irrit. 2A H319
Carc. Not classified
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2.2. Elementos de las etiquetas
Etiquetado GHS-US
Pictogramas de peligro (GHS-US) :
GHS02
GHS07
Palabra de advertencia (GHS-US) :Atenci n
Indicaciones de peligro (GHS-US) :H226 – L quido y vapores inflamables
H315 – Provoca irritaci n cut nea
H319 – Provoca irritaci n ocular grave
Consejos de precauci n (GHS-US) :P210 – Mantener alejado calor, superficies calientes, llama abierta, chispas. No fumar
P233 – Mantener el recipiente herm ticamente cerrado
P240 – Toma de tierra/enlace equipotencial del recipiente y del equipo receptor
P241 – Utilizar un material el ctrico, iluminaci n, ventilaci n antideflagrante
P242 – No utilizar herramientas que produzcan chispas
P243 – Tomar medidas de precauci n contra descargas electrost ticas
P264 – Lavarse EXPOSED AREA. cuidadosamente despu s la manipulaci n
P280 – Usar protecci n ocular, ropas de protecci n, guantes de protecci n
P302+P352 – EN CASO DE CONTACTO CON LA PIEL: Lavar con abundante agua y jab n
P303+P361+P353 – EN CASO DE CONTACTO CON LA PIEL (o el pelo): Quitar
inmediatamente la ropa contaminada. Enjuagar la piel con agua/ducharse
P305+P351+P338 – En caso de contacto con los ojos: Enjuagar con agua cuidadosamente
durante varios minutos. Quitar las lentes de contacto cuando est n presentes y pueda hacerse
con facilidad. Proseguir con el lavado
P321 – Tratamiento espec fico (v ase SEEK MEDICAL AID. en esta etiqueta)
P332+P313 – En caso de irritaci n cut nea: consultar a un m dico
P337+P313 – Si la irritaci n ocular persiste, consultar a un m dico
P362 – Quitar la ropa contaminada y lavarsela antes de volverla a usar
P370+P378 – En caso de incendio: Utilizar carbon dioxide (CO2), dry chemical powder, foam
en la extinci n
P403+P235 – Almacenar en un lugar bien ventilado
P501 – Eliminar el contenido/recipiente LOCAL, STATE, AND NATIONAL REGULATIONS.
2.3. Otros peligros que no figuren en la clasificaci n
No additional information available
2.4. (GHS-US)
No hay datos disponibles
SECCI N 3: Composici n/informaci n sobre los ingredientes
3.1. Sustancia
No aplicable
Full text of H-phrases: see section 16
3.2. Mezcla
Nombre Grupo de productos % Clasificaci n de SAC-US2
Unsaturated Polyester Resin (CAS N )TRADE SECRET <= 50 No est clasificado
styrene, inhibited (CAS N )100-42-5 <= 40.48 Flam. Liq. 3, H226
Acute Tox. 4 (Inhalation:vapour),
H332
Skin Irrit. 2, H315
Eye Irrit. 2A, H319
Carc. 2, H351
methyl ethyl ketone (CAS N )78-93-3 <= 4.7 Flam. Liq. 2, H225
carbon black (CAS N )1333-86-4 <= 2 Carc. 2, H351
cobalt(II) 2-ethylhexanoate (CAS N )136-52-7 <= 0.5 Carc. 2, H351
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SECCI N 4: Medidas de primeros auxilios
4.1. Descripci n de los primeros auxilios
Medidas de primeros auxilios general :Never give anything by mouth to an unconscious person. If you feel unwell, seek medical
advice (show the label where possible).
Medidas de primeros auxilios tras una inhalaci n:Assure fresh air breathing. Allow the victim to rest. Transportar la v ctima al aire libre y
mantenerla en reposo en una posici n que le facilite la respiraci n. Llamar a un CENTRO DE
TOXICOLOG A o a un m dico si la persona se encuentra mal.
Medidas de primeros auxilios tras el contacto
con la piel
:Enjuagar la piel con agua/ducharse. Quitar inmediatamente toda la ropa contaminada. Lavar
con abundante agua y jab n. Lavar la ropa contaminada antes de volverla a usar. En caso de
irritaci n cut nea: wash throughly for five minutes. seek medical attention. Consultar a un
m dico. Tratamiento espec fico (v ase seek medical attention. en esta etiqueta).
Medidas de primeros auxilios tras un contacto
con los ojos
:Enjuagar con agua cuidadosamente durante varios minutos. Quitar los lentes de contacto
cuando est n presentes y pueda hacerse con facilidad. Proseguir con el lavado. Si la irritaci n
ocular persiste: SEEK IMMEDIATE MEDICAL ATTENTION. Consultar a un m dico.
Medidas de primeros auxilios tras una ingesti n:Enjuagarse la boca. NO provocar el v mito. Obtain emergency medical attention.
4.2. S ntomas/efectos m s importantes, agudos y retardados
S ntomas/lesiones :Puede provocar defectos gen ticos (avoid skin contact and inhalation.). Puede provocar c ncer
(avoid skin contact and inhalation.).
S ntomas/lesiones despu s de inhalaci n :Danger of serious damage to health by prolonged exposure through inhalation. Nocivo si se
inhala.
S ntomas/lesiones despu s de contacto con la
piel
:Provoca irritaci n cut nea.
S ntomas/lesiones despu s del contacto con el
ojo
:Provoca irritaci n ocular grave.
4.3. Indicaci n de la necesidad de recibir atenci n m dica inmediata y tratamiento especial requerido en caso necesario
No additional information available
SECCI N 5: Medidas de combate a incendios
5.1. Medios de extinci n
Suitable extinguishing media :Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Material extintor inadecuado :Do not use a heavy water stream.
5.2. Peligros espec ficos de los productos qu micos
Peligro de incendio :L quido y vapores muy inflamables. L quido y vapores inflamables.
Peligro de explosi n :May form flammable/explosive vapour-air mixture.
Reactividad :No reactivity hazard other than the effects described in sub-sections below.
5.3. Equipo de protecci n especial y precauciones para los
equipos de lucha contra incendios
Instrucciones para extinci n de incendio :Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Avoid (reject) fire-fighting water to enter environment.
Protecci n durante la extinci n de incendios:Do not enter fire area without proper protective equipment, including respiratory protection.
SECCI N 6: Medidas en caso de liberaci n accidental
6.1. Precauciones individuales, equipos de protecci n y procedimientos de emergencia
Medidas generales :Remove ignition sources. Use special care to avoid static electric charges. No naked lights. No
smoking.
6.1.1.Para el personal que no forma parte de los servicios de emergencia
Equipo de protecci n :Gloves. Protective goggles. Protective clothing.
Planos de emergencia :Evacuate unnecessary personnel.
6.1.2.Para el personal de los servicios de emergencia
Equipo de protecci n :Equip cleanup crew with proper protection.
Planos de emergencia :Ventilate area.
6.2. Precauciones ambientales
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
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6.3. M todos y materiales de aislamiento y limpieza
Para la contenci n :Dam up the liquid spill. Contain released substance, pump into suitable containers.
M todos de limpieza :Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible.
Recoger los vertidos. Almacenar alejado de otras materias.
6.4. Motivo de utilizaci n desaconsejado
See Heading 8. Exposure controls and personal protection.
SECCI N 7: Manipulaci n y almacenamiento
7.1. Precauciones para una manipulaci n segura
Peligros adicionales cuando procesado :Handle empty containers with care because residual vapours are flammable.
Precauciones para una manipulaci n segura:Wash hands and other exposed areas with mild soap and water before eat, drink or smoke and
when leaving work. Provide good ventilation in process area to prevent formation of vapour. No
naked lights. No smoking. No utilizar herramientas que produzcan chispas. Utilizar s lo al aire
libre o en un lugar bien ventilado. Evitar respirar DUST, FUMES, MIST, OR VAPORS.
Procurarse las instrucciones antes del uso. No manipular la sustancia antes de haber le do y
comprendido todas las precauciones de seguridad. Eliminar todas las fuentes de ignici n si
puede hacerse sin riesgo. Tomar medidas de precauci n contra descargas electrost ticas.
Medidas de higiene :Lavarse HANDS cuidadosamente despu s la manipulaci n.
7.2. Condiciones de almacenamiento seguro, incluidas cualesquiera incompatibilidades
Medidas t cnicas :Proper grounding procedures to avoid static electricity should be followed. Toma de
tierra/enlace equipotencial del recipiente y del equipo receptor. Utilizar un material electrical,
ventilating and lighting equipment. antideflagrante.
Condiciones de almacenamiento :Keep only in the original container in a cool, well ventilated place away from : HEAT SPARKS
OR OPEN FLAMES. Keep in fireproof place. Mantener el recipiente herm ticamente cerrado.
Productos incompatibles :Strong bases. strong acids.
Materiales incompatibles :Sources of ignition. Direct sunlight. Heat sources.
7.3. Specific end use(s)
No additional information available
SECCI N 8: Controles de exposici n/protecci n individual
8.1. Par metros de control
carbon black (1333-86-4)
USA ACGIH ACGIH TWA (mg/m ) 3 mg/m
styrene, inhibited (100-42-5)
USA ACGIH ACGIH TWA (ppm) 20 ppm
USA ACGIH ACGIH STEL (ppm) 40 ppm
methyl ethyl ketone (78-93-3)
USA ACGIH ACGIH TWA (ppm) 200 ppm
USA ACGIH ACGIH STEL (ppm) 300 ppm
8.2. Controles de exposici n
Controles apropiados de ingenier a :Ensure exposure is below occupational exposure limits (where available).
Equipo de protecci n personal :Avoid all unnecessary exposure.
Protecci n de las manos :Usar guantes de protecci n.
Protecci n ocular :Chemical goggles or safety glasses.
Protecci n de la piel y del cuerpo :Wear suitable protective clothing.
Protecci n de las v as respiratorias :Wear approved mask.
Otra informaci n :When using, do not eat, drink or smoke.
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SECCI N 9: Propiedades f sicas y qu micas
9.1. Information on basic physical and chemical properties
Estado f sico :L quido
Color :Negro.
Olor :characteristic.
Umbral olfativo :No hay datos disponibles
pH :No hay datos disponibles
Grado relativo de evaporaci n (acetato de
butilo=1)
:No hay datos disponibles
Punto de fusi n :No hay datos disponibles
Punto de solidificaci n :No hay datos disponibles
Punto de ebullic on : 64 C
Punto de inflamaci n :30 - 34 C
Temperatura de autoignici n :No hay datos disponibles
Temperatura de descomposici n :No hay datos disponibles
Inflamabilidad (s lido, gas) :No hay datos disponibles
Presi n de vapor :No hay datos disponibles
Densidad relativa de vapor a 20 C :No hay datos disponibles
Densidad relativa : 1.1
Solubilidad :No hay datos disponibles
Log Pow :No hay datos disponibles
Log Kow :No hay datos disponibles
Viscosidad, cinem tico :No hay datos disponibles
Viscosidad, din mico :No hay datos disponibles
Propiedades explosivas :No hay datos disponibles
Propiedades comburentes :No hay datos disponibles
Explosive limits :No hay datos disponibles
9.2. Otra informaci n
No additional information available
SECCI N 10: Estabilidad y reactividad
10.1.Reactividad
No reactivity hazard other than the effects described in sub-sections below.
10.2.Estabilidad qu mica
Polymerization can result in formation of solid deposits, even in vapour space. Not established. L quido y vapores muy inflamables. May form
flammable/explosive vapour-air mixture. L quido y vapores inflamables.
10.3.Posibilidad de reacciones peligrosas
Not established.
10.4.Condiciones que deben evitarse
Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Heat.
10.5.Materiales incompatibles
strong acids. Strong bases.
10.6.Productos de descomposici n peligrosos
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECCI N 11: Informaci n toxicol gica
11.1.Informaci n sobre los efectos toxicol gicos
Toxicidad aguda :No est clasificado
HI FLEX BLACK TOOLING GEL COAT( )mixture
ETA CLP (vapores) 11.000 mg/l/4h
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carbon black (1333-86-4)
DL50 oral rata > 15400 mg/kg (Rat)
DL50 cut neo conejo > 3000 mg/kg (Rabbit)
styrene, inhibited (100-42-5)
DL50 oral rata 5000 mg/kg (>6000 mg/kg bodyweight; Rat; Rat)
DL50 cut neo rata 2820 mg/kg (>2000 mg/kg bodyweight; Rat; Rat; Experimental value)
DL50 cut neo conejo 5010 mg/kg (Rabbit)
CL50 inhalaci n rata (mg/l) 12 mg/l/4h (Rat)
CL50 inhalaci n rata (ppm) 2770 ppm/4h (Rat)
ETA CLP (oral) 5000.000 mg/kg bodyweight
ETA CLP (cut nea) 2820.000 mg/kg bodyweight
ETA CLP (gases) 2770.000 ppmv/4h
ETA CLP (vapores) 12.000 mg/l/4h
ETA CLP (polvos,niebla) 12.000 mg/l/4h
methyl ethyl ketone (78-93-3)
DL50 oral rata 2737 mg/kg (2054 mg/kg; 2328 mg/kg; Rat; Rat; Rat)
DL50 cut neo conejo 6480 mg/kg (>10; Rabbit; Rabbit; Experimental value,>10; Rabbit; Rabbit; Experimental value)
CL50 inhalaci n rata (mg/l) 34 mg/l/4h (Rat)
CL50 inhalaci n rata (ppm) 11300 ppm/4h (Rat)
ETA CLP (oral) 2737.000 mg/kg bodyweight
ETA CLP (cut nea) 6480.000 mg/kg bodyweight
ETA CLP (gases) 11300.000 ppmv/4h
ETA CLP (vapores) 34.000 mg/l/4h
ETA CLP (polvos,niebla) 34.000 mg/l/4h
Corrosi n/irritaci n en la piel :Provoca irritaci n cut nea.
Lesiones/irritaciones graves en los ojos :Provoca irritaci n ocular grave.
Sensibilizaci n respiratoria o de la piel:No est clasificado
Mutagenidad de c lulas germinativas :No est clasificado
Carcinogenicidad :No est clasificado.
carbon black (1333-86-4)
Grupo IARC 2B – Posiblemente Carcin geno para los Seres Humanos
styrene, inhibited (100-42-5)
Grupo IARC 2B – Posiblemente Carcin geno para los Seres Humanos
cobalt(II) 2-ethylhexanoate (136-52-7)
Grupo IARC 2B – Posiblemente Carcin geno para los Seres Humanos
Toxicidad a la reproducci n :No est clasificado
Seg n datos disponibles, los criterios de clasificaci n no se cumplen
Toxicidad sist mica para rganos diana
(exposici n nica)
:No est clasificado
Toxicidad sist mica para rganos diana
(exposici n repetida)
:No est clasificado
Seg n datos disponibles, los criterios de clasificaci n no se cumplen
Peligro por aspiraci n :No est clasificado
Seg n datos disponibles, los criterios de clasificaci n no se cumplen
S ntomas y posibles efectos adversos para la
salud humana
:Nocivo si se inhala. Seg n datos disponibles, los criterios de clasificaci n no se cumplen.
S ntomas/lesiones despu s de inhalaci n :Danger of serious damage to health by prolonged exposure through inhalation. Nocivo si se
inhala.
S ntomas/lesiones despu s de contacto con la
piel
:Provoca irritaci n cut nea.
S ntomas/lesiones despu s del contacto con el
ojo
:Provoca irritaci n ocular grave.
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SECCI N 12: Informaci n ecol gica
12.1.Toxicidad
carbon black (1333-86-4)
CL50 peces 1 > 1000 mg/l (96 h; Brachydanio rerio)
CE50 Daphnia 1 > 5600 mg/l (24 h; Daphnia magna)
styrene, inhibited (100-42-5)
CL50 peces 1 25 mg/l (96 h; Lepomis macrochirus)
CL50 otros organismos acu ticos 1 10 – 100 mg/l (96 h)
CE50 Daphnia 1 23 mg/l (48 h; Daphnia magna; LOCOMOTOR EFFECT)
CL50 peces 2 32 mg/l (96 h; Pimephales promelas)
CE50 Daphnia 2 27 mg/l (24 h; Daphnia magna)
TLM peces 1 25.1 mg/l (96 h; Lepomis macrochirus; SOFT WATER)
TLM peces 2 46.4 mg/l (96 h; Pimephales promelas; SOFT WATER)
TLM otros organismos acu ticos 1 10 – 100,96 h
Umbral l mite para otros orgnismos acu ticos 110 – 100,96 h; Pseudomonas putida
Umbral l mite para otros orgnismos acu ticos 272 mg/l
Umbral l mite algas 1 > 200 mg/l (192 h; Scenedesmus quadricauda; INHIBITORY)
Umbral l mite algas 2 67 mg/l (Microcystis aeruginosa; INHIBITORY)
methyl ethyl ketone (78-93-3)
CL50 peces 1 1690 mg/l (96 h; Lepomis macrochirus; LETHAL)
CE50 Daphnia 1 308 mg/l (48 h; Daphnia magna; LOCOMOTOR EFFECT)
CL50 peces 2 2990 mg/l (96 h; Pimephales promelas)
TLM peces 1 5600 mg/l (96 h; Gambusia affinis)
TLM peces 2 1690 mg/l (96 h; Lepomis macrochirus)
TLM otros organismos acu ticos 1 > 1000 ppm (96 h)
Umbral l mite algas 1 110 mg/l (168 h; Microcystis aeruginosa)
Umbral l mite algas 2 4300 mg/l (192 h; Scenedesmus quadricauda)
12.2.Persistencia y degradabilidad
HI FLEX BLACK TOOLING GEL COAT(mixture)
Persistencia y degradabilidad Not established.
carbon black (1333-86-4)
Persistencia y degradabilidad Biodegradability: not applicable. Biodegradability in soil: not applicable. Adsorbs into the soil.
Biochemical oxygen demand (BOD) Not applicable
Demanda qu mica de ox geno (COD) Not applicable
ThOD Not applicable
DBO (% of ThOD) Not applicable
styrene, inhibited (100-42-5)
Persistencia y degradabilidad Readily biodegradable in water. Not readily biodegradable in water. Forming sediments in
water. Non degradable in the soil. Adsorbs into the soil. Photodegradation in the air. Not
established.
Demanda qu mica de ox geno (COD) 2.80 g O /g substance
ThOD 3.07 g O /g substance
DBO (% of ThOD) 0.42 % ThOD
methyl ethyl ketone (78-93-3)
Persistencia y degradabilidad Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. Not established.
Biochemical oxygen demand (BOD) 1.92 g O /g substance
Demanda qu mica de ox geno (COD) 2.31 g O /g substance
ThOD 2.44 g O /g substance
DBO (% of ThOD) 0.79 % ThOD
cobalt(II) 2-ethylhexanoate (136-52-7)
Persistencia y degradabilidad Biodegradability in water: no data available.
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Unsaturated Polyester Resin (TRADE SECRET)
Persistencia y degradabilidad Not established.
12.3.Potencial de bioacumulaci n
HI FLEX BLACK TOOLING GEL COAT(mixture)
Potencial de bioacumulaci n Not established.
carbon black (1333-86-4)
Potencial de bioacumulaci n Not bioaccumulative.
styrene, inhibited (100-42-5)
BCF peces 1 12 – 77 (QSAR)
BCF peces 2 35.5 (Carassius auratus)
Log Pow 2.95 – 3.16 (Experimental value)
Potencial de bioacumulaci n Low potential for bioaccumulation (BCF < 500). Not established.
methyl ethyl ketone (78-93-3)
Log Pow 0.3 (Experimental value; 40 C,Experimental value; 40 C)
Potencial de bioacumulaci n Low potential for bioaccumulation (Log Kow < 4). Not established.
cobalt(II) 2-ethylhexanoate (136-52-7)
Potencial de bioacumulaci n No bioaccumulation data available.
Unsaturated Polyester Resin (TRADE SECRET)
Potencial de bioacumulaci n Not established.
12.4.Movilidad en suelo
carbon black (1333-86-4)
Ecolog a - suelo Not toxic to plants. Not toxic to animals.
styrene, inhibited (100-42-5)
Tensi n de superficie 0.032 N/m (19 C)
methyl ethyl ketone (78-93-3)
Tensi n de superficie 0.024 N/m (20 C)
Ecolog a - suelo Slightly harmful to plants.
12.5.Otros efectos adversos
Otra informaci n :No dispersar en el medio ambiente.
SECCI N 13: Consideraciones relativas a la eliminaci n
13.1.Descripci n de los residuos e informaci n sobre la manera de manipularlos sin peligro, as como sus m todos de eliminaci n
Recomendaciones para la eliminaci n de
residuos
:Dispose in a safe manner in accordance with local/national regulations. Eliminar el
contenido/recipiente approved disposal site.
Informaci n adicional :Handle empty containers with care because residual vapours are flammable.
Ecolog a - residuos materiales :No dispersar en el medio ambiente.
SECCI N 14: Informaci n del transporte
In accordance with DOT
N ONU (DOT) :UN1866
DOT Designaci n Oficial de Transporte :RESIN SOLUTION
Departamento de Transporte (DOT) Clases de
Peligro
:3 - Clase 3 - L quido inflamable y combustible 49 CFR 173.120
Etiquetas de peligro (DOT) :3 - Flammable liquid
Grupo de embalaje (DOT) :III - Riesgo peque o
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Informaci n adicional
Otra informaci n :No hay informaci n adicional disponible.
ADR
Descripci n del documento del transporte :UN 1866, 3, III, (D/E)
Grupo de embalaje (ADR) :III
Clase (ADR) :3 - L quido inflamable
N mero de identificaci n de peligro (N Kemler):33
C digo de clasificaci n (ADR) :F1
Etiquetas de peligro (ADR) :3 - L quido inflamable
Panel naranja :
C digo de restricci n de t nel :D/E
LQ :5L
Cantidades exceptuadas (ADR) :E2
Producto comercial
N ONU (IMDG) :1866
Designaci n Oficial de Transporte (IMDG) :RESIN SOLUTION
Clase (IMDG) :3 - L quido inflamable
Grupo de embalaje (IMDG) :III - substances presenting low danger
Air transport
N ONU (IATA) :1866
Designaci n Oficial de Transporte (IATA) :RESIN SOLUTION
Clase (IATA) :3 - Flammable Liquids
Grupo de embalaje (IATA) :III - Riesgo peque o
SECCI N 15: Informaci n reglamentaria
15.1. Regulaciones federales de EE.UU
styrene, inhibited (100-42-5)
RQ (Cantidad reportable, secci n 304 de Lista
de listas de la EPA):
1000 lb
SARA Secci n 311/312 Clases de Peligro Peligro inmediato para la salud (agudo)
Peligro reactivo
Peligro de incendio
Peligro para la salud tardio (cr nico)
methyl ethyl ketone (78-93-3)
RQ (Cantidad reportable, secci n 304 de Lista
de listas de la EPA):
5000 lb
15.2. Regulaciones Internacionales
CANADA
No additional information available
EU-Regulations
No additional information available
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Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flam. Liq. 3 H226
Acute Tox. 4 (Inhalation:vapour) H332
Skin Irrit. 2 H315
Eye Irrit. 2 H319
Muta. 1B H340
Carc. 1B H350
Full text of H-phrases: see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Carc.Cat.2; R45
Muta.Cat.2; R46
F; R11
Xn; R20
Xi; R36/38
Full text of R-phrases: see section 16
15.2.2.National regulations
styrene, inhibited (100-42-5)
Listed on EPA's Hazardous Air Pollutants (HAPS)
15.3. Regulaciones Estatales de EE.UU
styrene, inhibited (100-42-5)
EE.UU - California -
Proposici n 65 - Lista de
Carcin genos
EE.UU - California -
Proposici n 65 - Toxicidad
para el Desarrollo
EE.UU - California -
Proposici n 65 - Toxicidad
Reproductiva - Feminino
EE.UU - California -
Proposici n 65 - Toxicidad
Reproductiva - Masculino
Ning n nivel de riesgo de
importancia (NSRL)
styrene, inhibited (100-42-5)
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
SECCI N 16: Otra informaci n
Otra informaci n :Ninguno.
Full text of H-phrases: see section 16:
------Acute Tox. 4 (Inhalation:vapour) Acute toxicity (inhalation:vapour) Category 4
------Carc. 2 Carcinogenicity, Category 2
------Carc. Not classified Carcinogenicity Not classified
------Eye Irrit. 2A Serious eye damage/eye irritation, Category 2A
------Flam. Liq. 2 Flammable liquids, Category 2
------Flam. Liq. 3 Flammable liquids, Category 3
------Skin Irrit. 2 Skin corrosion/irritation, Category 2
------H225 L quido y vapores muy inflamables
------H226 L quido y vapores inflamables
------H315 Provoca irritaci n cut nea
------H319 Provoca irritaci n ocular grave
------H332 Nocivo si se inhala
------H351 Suseptible de provocar c ncer
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NFPA peligro para la salud :2 - Una exposici n intensiva o continua podr a causar
incapacidad temporal o posible da o residual, a menos
que se reciba atenci n m dica inmediata.
NFPA peligro de incendio :3 - L quidos y s lidos que pueden inflamarse en casi todas
las condiciones ambientales.
NFPA reactividad :2 - Normalmente inestable y f cilmente sufre
descomposici n violento pero no detona. Tambi n: puede
reaccionar violentamente con el agua o puede formar
mezclas potencialmente explosivas con agua.
HMIS III Rating
Salud :2 Moderate Hazard - Puede ocurrir una lesi n temporal o menor
Inflamabilidad :3 Serious Hazard
F sico :1 Slight Hazard
Protecci n personal :H
SDS US (GHS HazCom 2012)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied
warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.
by | Sep 27, 2025
Durakote Black Tooling GC GT 17-23
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue: 10/18/2023 Revision date: 4/23/2024
4/23/2024 (Revision date) EN (English US) 1/15
SECTION 1: Identification
1.1. Identification
Product form : Mixture
Trade name : Durakote Black Tooling GC GT 17-23
CAS-No. : mixture
Product code : 402-001XT
Formula : N/A
Other means of identification : Unsaturated Polyester Resin Gel Coat
1.2. Recommended use and restrictions on use
Use of the substance/mixture : Coatings
1.3. Supplier
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909-546-1162
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300
SECTION 2: Hazard(s) identification
2.1. Classification of the substance or mixture
GHS US classification
Flammable liquids Category 2 H225 Highly flammable liquid and vapor
Acute toxicity (inhalation:vapor) Category 4 H332 Harmful if inhaled
Skin corrosion/irritation Category 2 H315 Causes skin irritation
Serious eye damage/eye irritation Category 2 H319 Causes serious eye irritation
Skin sensitization, Category 1 H317 May cause an allergic skin reaction
Reproductive toxicity Category 1B H360 May damage fertility or the unborn child
Specific target organ toxicity (repeated exposure) Category 1 H372 Causes damage to organs through prolonged or repeated
exposure
Full text of H statements : see section 16
2.2. GHS Label elements, including precautionary statements
GHS US labeling
Hazard pictograms (GHS US) :
Signal word (GHS US) : Danger
Hazard statements (GHS US) : H225 – Highly flammable liquid and vapor
H315 – Causes skin irritation
H317 – May cause an allergic skin reaction
Durakote Black Tooling GC GT 17-23
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
4/23/2024 (Revision date) EN (English US) 2/15
H319 – Causes serious eye irritation
H332 – Harmful if inhaled
H360 – May damage fertility or the unborn child
H372 – Causes damage to organs through prolonged or repeated exposure
Precautionary statements (GHS US) : P201 – Obtain special instructions before use.
P202 – Do not handle until all safety precautions have been read and understood.
P210 – Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P233 – Keep container tightly closed.
P240 – Ground/Bond container and receiving equipment.
P241 – Use explosion-proof electrical, lighting, ventilating equipment.
P242 – Use only non-sparking tools.
P243 – Take precautionary measures against static discharge.
P260 – Do not breathe dust, fume, mist, spray, vapors.
P261 – Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 – Wash EXPOSED AREA. thoroughly after handling.
P270 – Do not eat, drink or smoke when using this product.
P271 – Use only outdoors or in a well-ventilated area.
P272 – Contaminated work clothing must not be allowed out of the workplace.
P280 – Wear eye protection, protective clothing, protective gloves.
P302+P352 – If on skin: Wash with plenty of water.
P303+P361+P353 – If on skin (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower.
P304+P340 – If inhaled: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P313 – If exposed or concerned: Get medical advice/attention.
P312 – Call a poison center or doctor if you feel unwell.
P314 – Get medical advice/attention if you feel unwell.
P321 – Specific treatment (see SEEK MEDICAL AID. on this label).
P332+P313 – If skin irritation occurs: Get medical advice/attention.
P333+P313 – If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 – If eye irritation persists: Get medical advice/attention.
P362+P364 – Take off contaminated clothing and wash it before reuse.
P363 – Wash contaminated clothing before reuse.
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish.
P403+P235 – Store in a well-ventilated place. Keep cool.
P405 – Store locked up.
P501 – Dispose of contents/container to LOCAL, STATE, AND NATIONAL REGULATIONS..
2.3. Other hazards which do not result in classification
No additional information available
2.4. Unknown acute toxicity (GHS US)
No additional information available
SECTION 3: Composition/Information on ingredients
3.1. Substances
Not applicable
Durakote Black Tooling GC GT 17-23
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
4/23/2024 (Revision date) EN (English US) 3/15
3.2. Mixtures
Name Product identifier % GHS US classification
styrene, inhibited CAS-No.: 100-42-5 40 Flam. Liq. 3, H226
Acute Tox. 4 (Inhalation:vapour),
H332
Skin Irrit. 2, H315
Eye Irrit. 2, H319
STOT RE 1, H372
Aquatic Acute 2, H401
methyl ethyl ketone CAS-No.: 78-93-3 4.5 Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
cobalt(II) 2-ethylhexanoate CAS-No.: 136-52-7 0.3 Eye Irrit. 2, H319
Skin Sens. 1, H317
Repr. 1B, H360
Aquatic Acute 1, H400
Aquatic Chronic 2, H411
Full text of hazard classes and H-statements : see section 16
SECTION 4: First-aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice
(show the label where possible).
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Allow affected person to breathe
fresh air. Allow the victim to rest. Remove victim to fresh air and keep at rest in a position
comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell.
First-aid measures after skin contact : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash
with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs:
Get medical advice/attention. Specific treatment (see supplemental first aid instruction on this
label).
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a poison
center/doctor/physician if you feel unwell.
4.2. Most important symptoms and effects (acute and delayed)
Potential Adverse human health effects and
symptoms
: Harmful if inhaled.
Symptoms/effects : May cause genetic defects. May cause cancer.
Symptoms/effects after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
4.3. Immediate medical attention and special treatment, if necessary
Treat symptomatically.
Durakote Black Tooling GC GT 17-23
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
4/23/2024 (Revision date) EN (English US) 4/15
SECTION 5: Fire-fighting measures
5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media : Sand. Water spray. Dry powder. Foam. Carbon dioxide.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Specific hazards arising from the chemical
Fire hazard : Flammable liquid and vapor.
Explosion hazard : May form flammable/explosive vapor-air mixture.
Reactivity in case of fire : No reactivity hazard other than the effects described in sub-sections below.
Hazardous decomposition products in case of fire : Toxic fumes may be released.
5.3. Special protective equipment and precautions for fire-fighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Do
not attempt to take action without suitable protective equipment. Self-contained breathing
apparatus. Complete protective clothing.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No
smoking.
6.1.1. For non-emergency personnel
Protective equipment : Gloves. Protective goggles. Protective clothing.
Emergency procedures : Ventilate spillage area. Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Do not attempt to take action without suitable protective equipment. Equip cleanup crew with
proper protection. For further information refer to section 8: “Exposure controls/personal
protection”.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Dam up the liquid spill. Contain released product, pump into suitable containers.
Methods for cleaning up : Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or
diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
Other information : Dispose of materials or solid residues at an authorized site.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection. For further information refer to section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapors are flammable.
Durakote Black Tooling GC GT 17-23
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
4/23/2024 (Revision date) EN (English US) 5/15
Precautions for safe handling : Wear personal protective equipment. Wash hands and other exposed areas with mild soap and
water before eating, drinking or smoking and when leaving work. Provide good ventilation in
process area to prevent formation of vapor. No open flames. No smoking. Take precautionary
measures against static discharge. Use only non-sparking tools. Use only outdoors or in a well-
ventilated area. Avoid breathing dust/fume/gas/mist/vapors/spray. Obtain special instructions
before use. Do not handle until all safety precautions have been read and understood. Eliminate
all ignition sources if safe to do so.
Hygiene measures : Wash hands, forearms and face thoroughly after handling. Do not eat, drink or smoke when
using this product. Always wash hands after handling the product.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond
container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment.
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Keep container
tightly closed. Store in a well-ventilated place. Keep cool.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Durakote Black Tooling GC GT 17-23 (mixture)
No additional information available
styrene, inhibited (100-42-5)
USA – ACGIH – Occupational Exposure Limits
ACGIH OEL TWA [ppm] 20 ppm
ACGIH OEL STEL [ppm] 40 ppm
cobalt(II) 2-ethylhexanoate (136-52-7)
No additional information available
methyl ethyl ketone (78-93-3)
USA – ACGIH – Occupational Exposure Limits
ACGIH OEL TWA [ppm] 200 ppm
ACGIH OEL STEL [ppm] 300 ppm
8.2. Appropriate engineering controls
Appropriate engineering controls : Ensure exposure is below occupational exposure limits (where available). Ensure good
ventilation of the work station.
Environmental exposure controls : Avoid release to the environment.
8.3. Individual protection measures/Personal protective equipment
Personal protective equipment:
Avoid all unnecessary exposure.
Hand protection:
Wear protective gloves.
Durakote Black Tooling GC GT 17-23
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
4/23/2024 (Revision date) EN (English US) 6/15
Eye protection:
Chemical goggles or safety glasses. Safety glasses
Skin and body protection:
Wear suitable protective clothing
Respiratory protection:
Wear appropriate mask
Personal protective equipment symbol(s):
Other information:
Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Color : Black
Odor : characteristic
Odor threshold : No data available
pH : No data available
Melting point : Not applicable
Freezing point : No data available
Boiling point : 172 F
Flash point : 16 F
Relative evaporation rate (butyl acetate=1) : No data available
Flammability (solid, gas) : Flammable liquid and vapor.
Vapor pressure : No data available
Relative vapor density at 20 C : No data available
Relative density : 1.05
Specific gravity / density : 1.05 kg/l
Solubility : No data available
Partition coefficient n-octanol/water (Log Pow) : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosion limits : No data available
Explosive properties : No data available
Oxidizing properties : No data available
9.2. Other information
VOC content : 448 g/l VOC is assuming 100 % evaporation of Monomers
SECTION 10: Stability and reactivity
10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.
Durakote Black Tooling GC GT 17-23
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
4/23/2024 (Revision date) EN (English US) 7/15
10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Flammable liquid and vapor. May form flammable/explosive vapor-air
mixture.
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Heat. Sparks.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Harmful if inhaled.
Durakote Black Tooling GC GT 17-23 (mixture)
ATE US (vapors) 11 mg/l/4h
styrene, inhibited (100-42-5)
LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
LD50 oral > 6000 mg/kg body weight (Hamster, Male, Weight of evidence, Oral)
LD50 dermal rat > 2000 mg/kg body weight (OECD 402: Acute Dermal Toxicity, 24 h, Rat, Male / female,
Experimental value, Dermal)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 Inhalation – Rat 11.8 mg/l air (4 h, Rat, Inconclusive, insufficient data, Inhalation (vapours))
LC50 Inhalation – Rat [ppm] 2770 ppm/4h (Rat; Literature study)
ATE US (gases) 4500 ppmV/4h
ATE US (vapors) 11 mg/l/4h
ATE US (dust, mist) 1.5 mg/l/4h
cobalt(II) 2-ethylhexanoate (136-52-7)
LD50 oral rat 3129 mg/kg body weight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat > 2000 mg/kg body weight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)
ATE US (oral) 3129 mg/kg body weight
methyl ethyl ketone (78-93-3)
LD50 oral rat 2193 mg/kg body weight (Equivalent or similar to OECD 423, Rat, Male / female, Read-across,
Oral)
Durakote Black Tooling GC GT 17-23
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
4/23/2024 (Revision date) EN (English US) 8/15
methyl ethyl ketone (78-93-3)
LD50 dermal rabbit > 10 ml/kg (Equivalent or similar to OECD 402, 24 h, Rabbit, Male, Experimental value,
Dermal)
ATE US (oral) 2193 mg/kg body weight
Skin corrosion/irritation : Causes skin irritation.
styrene, inhibited (100-42-5)
pH Not applicable
cobalt(II) 2-ethylhexanoate (136-52-7)
pH 6.8 (4.03 %; 20 C)
Serious eye damage/irritation : Causes serious eye irritation.
styrene, inhibited (100-42-5)
pH Not applicable
cobalt(II) 2-ethylhexanoate (136-52-7)
pH 6.8 (4.03 %; 20 C)
Respiratory or skin sensitization : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans
National Toxicology Program (NTP) Status Reasonably anticipated to be Human Carcinogen
cobalt(II) 2-ethylhexanoate (136-52-7)
IARC group 2B – Possibly carcinogenic to humans
Reproductive toxicity : May damage fertility or the unborn child.
Specific target organ toxicity single exposure : Not classified
methyl ethyl ketone (78-93-3)
Specific target organ toxicity single exposure May cause drowsiness or dizziness.
Specific target organ toxicity repeated exposure : Causes damage to organs through prolonged or repeated exposure.
styrene, inhibited (100-42-5)
Specific target organ toxicity repeated exposure Causes damage to organs through prolonged or repeated exposure.
Aspiration hazard : Not classified
Viscosity, kinematic : No data available
styrene, inhibited (100-42-5)
Viscosity, kinematic 0.8 mm /s
methyl ethyl ketone (78-93-3)
Viscosity, kinematic 0.494 mm /s
Potential Adverse human health effects and
symptoms
: Harmful if inhaled.
Symptoms/effects : May cause genetic defects. May cause cancer.
Symptoms/effects after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
Durakote Black Tooling GC GT 17-23
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
4/23/2024 (Revision date) EN (English US) 9/15
SECTION 12: Ecological information
12.1. Toxicity
Ecology – general : Dangerous for the environment. Harmful to aquatic life.
styrene, inhibited (100-42-5)
LC50 – Fish [1] 10 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Flow-through
system, Fresh water, Experimental value, GLP)
EC50 – Crustacea [1] 4.7 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Flow-
through system, Fresh water, Experimental value, GLP)
ErC50 algae 4.9 mg/l (EPA OTS 797.1050, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, GLP)
cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 – Fish [1] 46.51 mg/l (LOEC; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 – Crustacea [1] 0.212 mg/l (NOEC; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
LC50 – Fish [2] 54.1 mg/l (LC50; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water; Read-
across)
EC50 – Crustacea [2] 0.605 mg/l (LC50; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
Threshold limit – Algae [1] 144 g/l (ErC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
Threshold limit – Algae [2] 32.2 g/l (NOEC; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
methyl ethyl ketone (78-93-3)
LC50 – Fish [1] 2993 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Static system,
Fresh water, Experimental value, GLP)
EC50 – Crustacea [1] 308 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Static
system, Fresh water, Experimental value, GLP)
ErC50 algae 1972 mg/l (OECD 201: Alga, Growth Inhibition Test, 72 h, Pseudokirchneriella subcapitata,
Static system, Fresh water, Experimental value, GLP)
12.2. Persistence and degradability
Durakote Black Tooling GC GT 17-23 (mixture)
Persistence and degradability Not established.
styrene, inhibited (100-42-5)
Persistence and degradability Biodegradable in the soil. Readily biodegradable in water.
Chemical oxygen demand (COD) 2.8 g O /g substance
ThOD 3.07 g O /g substance
BOD (% of ThOD) 0.42 (Literature study)
cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability Readily biodegradable in water. No (test)data on mobility of the substance available.
Durakote Black Tooling GC GT 17-23
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
4/23/2024 (Revision date) EN (English US) 10/15
methyl ethyl ketone (78-93-3)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. Not established.
Biochemical oxygen demand (BOD) 2.03 g O /g substance
Chemical oxygen demand (COD) 2.31 g O /g substance
ThOD 2.44 g O /g substance
12.3. Bioaccumulative potential
Durakote Black Tooling GC GT 17-23 (mixture)
Bioaccumulative potential Not established.
styrene, inhibited (100-42-5)
BCF – Fish [1] 35.5 (Carassius auratus, Literature study)
Partition coefficient n-octanol/water (Log Pow) 2.96 (Experimental value, OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
cobalt(II) 2-ethylhexanoate (136-52-7)
BCF - Fish [1] 1.2 (BCF; 131 days; Seriola quinqueradiata; Static system; Salt water; Read-across)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).
methyl ethyl ketone (78-93-3)
Partition coefficient n-octanol/water (Log Pow) 0.3 (Experimental value, OECD 117: Partition Coefficient (n-octanol/water), HPLC method, 40
C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
12.4. Mobility in soil
styrene, inhibited (100-42-5)
Surface tension 0.032 N/m (20 C)
Organic Carbon Normalized Adsorption Coefficient
(Log Koc)
2.55 (log Koc, Estimated value)
Ecology - soil Low potential for adsorption in soil.
cobalt(II) 2-ethylhexanoate (136-52-7)
Surface tension 0.064 N/m (20 C; 1 g/l)
methyl ethyl ketone (78-93-3)
Surface tension 0.024 N/m (20 C)
Organic Carbon Normalized Adsorption Coefficient
(Log Koc)
1.53 (log Koc, Calculated value)
Ecology - soil Highly mobile in soil. Slightly harmful to plants.
12.5. Other adverse effects
Other information : Avoid release to the environment.
Durakote Black Tooling GC GT 17-23
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
4/23/2024 (Revision date) EN (English US) 11/15
SECTION 13: Disposal considerations
13.1. Disposal methods
Regional legislation (waste) : Disposal must be done according to official regulations.
Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions.
Sewage disposal recommendations : Do not discharge into drains.
Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to hazardous or special waste collection point, in accordance with local,
regional, national and/or international regulation.
Additional information : Handle empty containers with care because residual vapors are flammable.
Ecology - waste materials : Avoid release to the environment.
SECTION 14: Transport information
In accordance with DOT / TDG / IMDG / IATA
14.1. UN number
DOT NA No : UN1866
UN-No. (TDG) : UN1866
UN-No. (IMDG) : 1866
UN-No. (IATA) : 1866
14.2. UN proper shipping name
Proper Shipping Name (DOT) : Resin solution
Proper Shipping Name (TDG) : RESIN SOLUTION
Proper Shipping Name (IMDG) : RESIN SOLUTION
Proper Shipping Name (IATA) : Resin solution
14.3. Transport hazard class(es)
DOT
Transport hazard class(es) (DOT) : 3
Hazard labels (DOT) : 3
TDG
Transport hazard class(es) (TDG) : 3
Hazard labels (TDG) : 3
IMDG
Transport hazard class(es) (IMDG) : 3
Hazard labels (IMDG) : 3
Durakote Black Tooling GC GT 17-23
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
4/23/2024 (Revision date) EN (English US) 12/15
IATA
Transport hazard class(es) (IATA) : 3
Hazard labels (IATA) : 3
14.4. Packing group
Packing group (DOT) : II
Packing group (TDG) : II
Packing group (IMDG) : II
Packing group (IATA) : II
14.5. Environmental hazards
Other information : No supplementary information available.
14.6. Special precautions for user
DOT
UN-No.(DOT) : UN1866
DOT Special Provisions (49 CFR 172.102) : 149 - When transported as a limited quantity or a consumer commodity, the maximum net
capacity specified in 173.150(b)(2) of this subchapter for inner packaging may be increased to 5
L (1.3 gallons).
383 - Packages containing toy plastic or paper caps for toy pistols described as UN0349,
Articles, explosive, n.o.s. (Toy caps), 1.4S or NA0337, Toy caps, 1.4S are not subject to the
subpart E (labeling) requirements of this part when offered for transportation by motor vehicle,
rail freight, cargo vessel, and cargo aircraft and, notwithstanding the packing method assigned in
173.62 of this subchapter, in conformance with the following conditions:
B52 - Notwithstanding the provisions of 173.24b of this subchapter, non-reclosing pressure relief
devices are authorized on DOT 57 portable tanks.
IB2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite
(31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110
kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized.
T4 - 2.65 178.274(d)(2) Normal............. 178.275(d)(3)
TP1 - The maximum degree of filling must not exceed the degree of filling determined by the
following: Degree of filling = 97 / 1 + a (tr - tf) Where: tr is the maximum mean bulk temperature
during transport, and tf is the temperature in degrees celsius of the liquid during filling.
TP8 - A portable tank having a minimum test pressure of 1.5 bar (150 kPa) may be used when
the flash point of the hazardous material transported is greater than 0 C (32 F).
DOT Packaging Exceptions (49 CFR 173.xxx) : 150
DOT Packaging Non Bulk (49 CFR 173.xxx) : 173
DOT Packaging Bulk (49 CFR 173.xxx) : 242
DOT Quantity Limitations Passenger aircraft/rail (49
CFR 173.27)
: 5 L
DOT Quantity Limitations Cargo aircraft only (49
CFR 175.75)
: 60 L
DOT Vessel Stowage Location : B - (i) The material may be stowed on deck or under deck on a cargo vessel and on a
passenger vessel carrying a number of passengers limited to not more than the larger of 25
passengers, or one passenger per each 3 m of overall vessel length; and (ii) On deck only on
passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this
section is exceeded.
TDG
UN-No. (TDG) : UN1866
Explosive Limit and Limited Quantity Index : 5 L
Excepted quantities (TDG) : E2
Durakote Black Tooling GC GT 17-23
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
4/23/2024 (Revision date) EN (English US) 13/15
Passenger Carrying Road Vehicle or Passenger
Carrying Railway Vehicle Index
: 5 L
Emergency Response Guide (ERG) Number : 127
IMDG
Packing instructions (IMDG) : P001
Packing provisions (IMDG) : PP1
IBC packing instructions (IMDG) : IBC02
Tank instructions (IMDG) : T4
Tank special provisions (IMDG) : TP1, TP8
EmS-No. (Fire) : F-E - FIRE SCHEDULE Echo - NON-WATER-REACTIVE FLAMMABLE LIQUIDS
EmS-No. (Spillage) : S-E - SPILLAGE SCHEDULE Echo - FLAMMABLE LIQUIDS, FLOATING ON WATER
Stowage category (IMDG) : B
Properties and observations (IMDG) : Miscibility with water depends upon the composition.
IATA
PCA Excepted quantities (IATA) : E2
PCA Limited quantities (IATA) : Y341
PCA limited quantity max net quantity (IATA) : 1L
PCA packing instructions (IATA) : 353
PCA max net quantity (IATA) : 5L
CAO packing instructions (IATA) : 364
CAO max net quantity (IATA) : 60L
Special provision (IATA) : A3
ERG code (IATA) : 3L
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
SECTION 15: Regulatory information
15.1. US Federal regulations
Commercial status of components according to the United States Environmental Protection Agency s Toxic Substances Control Act (TSCA):
Name CAS-No. Listing Commercial
status
Flags
styrene, inhibited 100-42-5 Present Active
cobalt(II) 2-ethylhexanoate 136-52-7 Present Active
methyl ethyl ketone 78-93-3 Present Active
styrene, inhibited (100-42-5)
Subject to reporting requirements of United States SARA Section 313
Listed on EPA Hazardous Air Pollutant (HAPS)
CERCLA RQ 1000 lb
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Reactive hazard
Fire hazard
Delayed (chronic) health hazard
methyl ethyl ketone (78-93-3)
Not subject to reporting requirements of the United States SARA Section 313
Listed on EPA Hazardous Air Pollutant (HAPS)
Durakote Black Tooling GC GT 17-23
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
4/23/2024 (Revision date) EN (English US) 14/15
methyl ethyl ketone (78-93-3)
CERCLA RQ 5000 lb
15.2. International regulations
CANADA
styrene, inhibited (100-42-5)
Listed on the Canadian DSL (Domestic Substances List)
cobalt(II) 2-ethylhexanoate (136-52-7)
Listed on the Canadian DSL (Domestic Substances List)
methyl ethyl ketone (78-93-3)
Listed on the Canadian DSL (Domestic Substances List)
EU-Regulations
No additional information available
National regulations
styrene, inhibited (100-42-5)
Listed on IARC (International Agency for Research on Cancer)
Listed as carcinogen on NTP (National Toxicology Program)
15.3. US State regulations
styrene, inhibited (100-42-5)
U.S. - California -
Proposition 65 -
Carcinogens List
U.S. - California -
Proposition 65 -
Developmental Toxicity
U.S. - California -
Proposition 65 -
Reproductive Toxicity
- Female
U.S. - California -
Proposition 65 -
Reproductive Toxicity
- Male
No significant risk
level (NSRL)
Maximum allowable
dose level (MADL)
Yes No No No 27 g/day
Component State or local regulations
styrene, inhibited(100-42-5) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know Hazardous
Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
methyl ethyl ketone(78-93-3) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know Hazardous
Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
SECTION 16: Other information
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date : 4/23/2024
Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE
COUNCIL of 16 December 2008 on classification, labeling and packaging of substances and
mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending
Regulation (EC) No 1907/2006.
Other information : None.
Durakote Black Tooling GC GT 17-23
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
4/23/2024 (Revision date) EN (English US) 15/15
Full text of H-phrases
H225 Highly flammable liquid and vapor
H226 Flammable liquid and vapor
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H332 Harmful if inhaled
H336 May cause drowsiness or dizziness
H360 May damage fertility or the unborn child
H372 Causes damage to organs through prolonged or repeated exposure
H400 Very toxic to aquatic life
H401 Toxic to aquatic life
H411 Toxic to aquatic life with long lasting effects
NFPA health hazard : 2 - Materials that, under emergency conditions, can cause temporary
incapacitation or residual injury.
NFPA fire hazard : 3 - Liquids and solids (including finely divided suspended solids) that can
be ignited under almost all ambient temperature conditions.
NFPA reactivity : 2 - Materials that readily undergo violent chemical change at elevated
temperatures and pressures.
Hazard Rating
Health : 2 Moderate Hazard - Temporary or minor injury may occur
Flammability : 3 Serious Hazard - Materials capable of ignition under almost all normal temperature conditions.
Includes flammable liquids with flash points below 73 F and boiling points above 100 F. as well
as liquids with flash points between 73 F and 100 F. (Classes IB IC)
Physical : 1 Slight Hazard - Materials that are normally stable but can become unstable (self-react) at high
temperatures and pressures. Materials may react non-violently with water or undergo hazardous
polymerization in the absence of inhibitors.
Personal protection : H - Splash goggles, Gloves, Synthetic apron, Vapor respirator
Safety Data Sheet (SDS), USA
by | Sep 27, 2025
BLACK TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue: 01/05/2016 Revision date: 01/05/2016 Supersedes: 09/10/2014
01/05/2016 EN (English US) Page 1
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product form : Mixture
Trade name : BLACK TOOLING GEL COAT
CAS No : mixture
Product code : 402-001
Formula : na
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : TOOLING GEL COAT
1.3. Details of the supplier of the safety data sheet
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909.877.8477
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
GHS-US classification
Flam. Liq. 3 H226
Skin Irrit. 2 H315
Eye Irrit. 2A H319
Carc. 2 H351
Repr. 2 H361
STOT SE 3 H335
STOT RE 1 H372
2.2. Label elements
GHS-US labeling
Hazard pictograms (GHS-US) :
GHS02
GHS07
GHS08
Signal word (GHS-US) : Danger
Hazard statements (GHS-US) : H226 – Flammable liquid and vapor
H315 – Causes skin irritation
H319 – Causes serious eye irritation
H335 – May cause respiratory irritation
H351 – Suspected of causing cancer
H361 – Suspected of damaging fertility or the unborn child
H372 – Causes damage to organs through prolonged or repeated exposure
Precautionary statements (GHS-US) : P201 – Obtain special instructions before use
P202 – Do not handle until all safety precautions have been read and understood
P210 – Keep away from heat, hot surfaces, open flames, sparks. – No smoking
P233 – Keep container tightly closed
P240 – Ground/bond container and receiving equipment
P241 – Use explosion-proof electrical, lighting, ventilating equipment
P242 – Use only non-sparking tools
P243 – Take precautionary measures against static discharge
P260 – Do not breathe dust, fume, mist, spray, vapors
BLACK TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/05/2016 EN (English US) 2/10
P264 – Wash EXPOSED AREA. thoroughly after handling
P270 – Do not eat, drink or smoke when using this product
P271 – Use only outdoors or in a well-ventilated area
P280 – Wear eye protection, protective clothing, protective gloves
P302+P352 – IF ON SKIN: Wash with plenty of soap and water
P303+P361+P353 – IF ON SKIN (or hair): Remove/Take off immediately all contaminated
clothing. Rinse skin with water/shower
P304+P340 – IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable
for breathing
P305+P351+P338 – If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P308+P313 – IF exposed or concerned: Get medical advice/attention
P312 – Call a POISON CENTER or doctor/physician if you feel unwell
P314 – Get medical advice and attention if you feel unwell
P321 – Specific treatment (see SEEK MEDICAL AID. on this label)
P332+P313 – If skin irritation occurs: Get medical advice/attention
P337+P313 – If eye irritation persists: Get medical advice/attention
P362 – Take off contaminated clothing and wash it before reuse
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish
P403+P233 – Store in a well-ventilated place. Keep container tightly closed
P403+P235 – Store in a well-ventilated place. Keep cool
P405 – Store locked up
P501 – Dispose of contents/container to LOCAL, STATE, AND NATIONAL REGULATIONS.
2.3. Other hazards
No additional information available
2.4. Unknown acute toxicity (GHS-US)
No data available
SECTION 3: Composition/Information on ingredients
3.1. Substance
Not applicable
Full text of H-phrases: see section 16
3.2. Mixture
Name Product identifier % GHS-US classification
Unsaturated Polyester Resin (CAS No) TRADE SECRET <= 50 Not classified
styrene, inhibited (CAS No) 100-42-5 <= 41 Flam. Liq. 3, H226
Acute Tox. 4 (Inhalation:vapour),
H332
Skin Irrit. 2, H315
Eye Irrit. 2A, H319
Carc. 2, H351
Repr. 2, H361
STOT SE 3, H335
STOT RE 1, H372
Asp. Tox. 1, H304
methyl ethyl ketone (CAS No) 78-93-3 <= 5 Flam. Liq. 2, H225
STOT SE 3, H336
cobalt(II) 2-ethylhexanoate (CAS No) 136-52-7 <= 0.5 Carc. 2, H351
SECTION 4: First aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice
(show the label where possible).
First-aid measures after inhalation : Allow victim to breathe fresh air. Allow the victim to rest. Remove victim to fresh air and keep at
rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you
feel unwell.
First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Wash
with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs:
wash throughly for five minutes. seek medical attention. Get medical advice/attention. Specific
treatment (see seek medical attention. on this label).
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: SEEK IMMEDIATE MEDICAL ATTENTION. Get
medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
BLACK TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/05/2016 EN (English US) 3/10
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries : May cause genetic defects (avoid skin contact and inhalation.). May cause cancer (avoid skin
contact and inhalation.).
Symptoms/injuries after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled.
Symptoms/injuries after skin contact : Causes skin irritation.
Symptoms/injuries after eye contact : Causes serious eye irritation.
4.3. Indication of any immediate medical attention and special treatment needed
No additional information available
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Highly flammable liquid and vapor.
Explosion hazard : May form flammable/explosive vapor-air mixture.
Reactivity : No reactivity hazard other than the effects described in sub-sections below.
5.3. Advice for firefighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No
smoking.
6.1.1. For non-emergency personnel
Protective equipment : Gloves. Protective goggles. Protective clothing.
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Dam up the liquid spill. Contain released substance, pump into suitable containers.
Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect
spillage. Store away from other materials.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapors are flammable.
Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Provide good ventilation in process area to prevent formation of
vapor. No open flames. No smoking. Use only non-sparking tools. Use only outdoors or in a well-
ventilated area. Avoid breathing DUST, FUMES, MIST, OR VAPORS. Obtain special instructions
before use. Do not handle until all safety precautions have been read and understood. Eliminate
all ignition sources if safe to do so.
Hygiene measures : Wash HANDS thoroughly after handling.
BLACK TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/05/2016 EN (English US) 4/10
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond
container and receiving equipment. Use explosion-proof electrical, ventilating and lighting
equipment. equipment.
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : HEAT SPARKS
OR OPEN FLAMES. Keep in fireproof place. Keep container tightly closed.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.
7.3. Specific end use(s)
No additional information available
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
styrene, inhibited (100-42-5)
USA ACGIH ACGIH TWA (ppm) 20 ppm
USA ACGIH ACGIH STEL (ppm) 20 ppm
methyl ethyl ketone (78-93-3)
USA ACGIH ACGIH TWA (ppm) 200 ppm
USA ACGIH ACGIH STEL (ppm) 200 ppm
8.2. Exposure controls
Appropriate engineering controls : Ensure exposure is below occupational exposure limits (where available).
Personal protective equipment : Avoid all unnecessary exposure.
Hand protection : Wear protective gloves.
Eye protection : Chemical goggles or safety glasses.
Skin and body protection : Wear suitable protective clothing.
Respiratory protection : Wear appropriate mask.
Other information : Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Color : Black.
Odor : characteristic.
Odor threshold : No data available
pH : No data available
Relative evaporation rate (butyl acetate=1) : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : 79.4 - 146 C
Flash point : -6.7 C
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapor pressure : No data available
Relative vapor density at 20 C : No data available
Relative density : No data available
Specific gravity / density : <= 1.1
Solubility : No data available
Log Pow : No data available
Log Kow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
BLACK TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/05/2016 EN (English US) 5/10
Explosive properties : No data available
Oxidizing properties : No data available
Explosive limits : No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Not established. Highly flammable liquid and vapor. May form
flammable/explosive vapor-air mixture.
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity : Not classified
BLACK TOOLING GEL COAT ( f )mixture
ATE CLP (dust, mist) 1.500 mg/l/4h
styrene, inhibited (100-42-5)
LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
LD50 dermal rat 2820 mg/kg (Rat; Literature study; OECD 402: Acute Dermal Toxicity; >2000 mg/kg
bodyweight; Rat; Experimental value)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 inhalation rat (mg/l) 12 mg/l/4h (Rat; Literature study)
LC50 inhalation rat (ppm) 2770 ppm/4h (Rat; Literature study)
ATE CLP (oral) 5000.000 mg/kg body weight
ATE CLP (dermal) 2820.000 mg/kg body weight
ATE CLP (gases) 2770.000 ppmV/4h
ATE CLP (vapors) 12.000 mg/l/4h
ATE CLP (dust, mist) 12.000 mg/l/4h
methyl ethyl ketone (78-93-3)
LD50 oral rat 2737 mg/kg (Rat; Equivalent or similar to OECD 423; Read-across; 2054 mg/kg; Rat;
Equivalent or similar to OECD 423; Read-across; 2328 mg/kg; Rat)
LD50 dermal rabbit 6480 mg/kg (Rabbit; Experimental value; Equivalent or similar to OECD 402; >10; Rabbit)
LC50 inhalation rat (mg/l) 34 mg/l/4h (Rat; Literature study)
LC50 inhalation rat (ppm) 11300 ppm/4h (Rat; Literature study)
ATE CLP (oral) 2737.000 mg/kg body weight
ATE CLP (dermal) 6480.000 mg/kg body weight
ATE CLP (gases) 11300.000 ppmV/4h
ATE CLP (vapors) 34.000 mg/l/4h
ATE CLP (dust, mist) 34.000 mg/l/4h
cobalt(II) 2-ethylhexanoate (136-52-7)
LD50 oral rat 3129 mg/kg body weight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat > 2000 mg/kg body weight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)
BLACK TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/05/2016 EN (English US) 6/10
cobalt(II) 2-ethylhexanoate (136-52-7)
ATE CLP (oral) 3129.000 mg/kg body weight
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitization : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Suspected of causing cancer.
styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans
cobalt(II) 2-ethylhexanoate (136-52-7)
IARC group 2B – Possibly carcinogenic to humans
Reproductive toxicity : Suspected of damaging fertility or the unborn child.
Based on available data, the classification criteria are not met
Specific target organ toxicity (single exposure) : May cause respiratory irritation.
Specific target organ toxicity (repeated
exposure)
: Causes damage to organs through prolonged or repeated exposure.
Based on available data, the classification criteria are not met
Aspiration hazard : Not classified
Based on available data, the classification criteria are not met
Potential Adverse human health effects and
symptoms
: Harmful if inhaled.
Symptoms/injuries after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled.
Symptoms/injuries after skin contact : Causes skin irritation.
Symptoms/injuries after eye contact : Causes serious eye irritation.
SECTION 12: Ecological information
12.1. Toxicity
styrene, inhibited (100-42-5)
LC50 fish 1 25 mg/l (96 h; Lepomis macrochirus; GLP)
LC50 other aquatic organisms 1 10 – 100 mg/l (96 h)
EC50 Daphnia 1 23 mg/l (48 h; Daphnia magna; Locomotor effect)
LC50 fish 2 32 mg/l (96 h; Pimephales promelas)
EC50 Daphnia 2 27 mg/l (24 h; Daphnia magna; GLP)
TLM fish 1 25.1 mg/l (96 h; Lepomis macrochirus; Soft water)
TLM fish 2 46.4 mg/l (96 h; Pimephales promelas; Soft water)
TLM other aquatic organisms 1 10 – 100,96 h
Threshold limit other aquatic organisms 1 10 – 100,96 h; Pseudomonas putida
Threshold limit other aquatic organisms 2 72 mg/l
Threshold limit algae 1 > 200 mg/l (192 h; Scenedesmus quadricauda; Inhibitory)
Threshold limit algae 2 67 mg/l (Microcystis aeruginosa; Inhibitory)
methyl ethyl ketone (78-93-3)
LC50 fish 1 1690 mg/l (96 h; Lepomis macrochirus; Lethal)
EC50 Daphnia 1 308 mg/l (48 h; Daphnia magna; Locomotor effect)
LC50 fish 2 2990 mg/l (96 h; Pimephales promelas)
TLM fish 1 5600 mg/l (96 h; Gambusia affinis)
TLM fish 2 1690 mg/l (96 h; Lepomis macrochirus)
TLM other aquatic organisms 1 > 1000 ppm (96 h)
Threshold limit algae 1 110 mg/l (168 h; Microcystis aeruginosa)
Threshold limit algae 2 4300 mg/l (192 h; Scenedesmus quadricauda)
cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 1 54.1 mg/l (96 h; Pimephales promelas)
BLACK TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/05/2016 EN (English US) 7/10
cobalt(II) 2-ethylhexanoate (136-52-7)
EC50 Daphnia 1 2618 g/l (48 h)
Threshold limit algae 1 24.1 g/l (7 days)
Threshold limit algae 2 90.1 g/l (7 days; Lemna minor; Growth rate)
12.2. Persistence and degradability
BLACK TOOLING GEL COAT (mixture)
Persistence and degradability Not established.
styrene, inhibited (100-42-5)
Persistence and degradability Readily biodegradable in water. Not readily biodegradable in water. Forming sediments in
water. Non degradable in the soil. Adsorbs into the soil. Photodegradation in the air. Not
established.
Chemical oxygen demand (COD) 2.80 g O /g substance
ThOD 3.07 g O /g substance
BOD (% of ThOD) 0.42 % ThOD
methyl ethyl ketone (78-93-3)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. Not established.
Biochemical oxygen demand (BOD) 1.92 g O /g substance
Chemical oxygen demand (COD) 2.31 g O /g substance
ThOD 2.44 g O /g substance
BOD (% of ThOD) > % ThOD (5 day(s)) > 0.5
cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability Biodegradability in water: no data available.
Unsaturated Polyester Resin (TRADE SECRET)
Persistence and degradability Not established.
12.3. Bioaccumulative potential
BLACK TOOLING GEL COAT (mixture)
Bioaccumulative potential Not established.
styrene, inhibited (100-42-5)
BCF fish 1 35.5 (Carassius auratus)
BCF other aquatic organisms 1 74
Log Pow 2.96 (Experimental value; OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method; 25 C)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Not established.
methyl ethyl ketone (78-93-3)
Log Pow 0.3 (Experimental value; OECD 117: Partition Coefficient (n-octanol/water), HPLC method; 40
C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
cobalt(II) 2-ethylhexanoate (136-52-7)
Bioaccumulative potential No bioaccumulation data available.
Unsaturated Polyester Resin (TRADE SECRET)
Bioaccumulative potential Not established.
12.4. Mobility in soil
styrene, inhibited (100-42-5)
Surface tension 0.032 N/m (19 C)
methyl ethyl ketone (78-93-3)
Surface tension 0.024 N/m (20 C)
Ecology - soil Slightly harmful to plants.
cobalt(II) 2-ethylhexanoate (136-52-7)
Surface tension 0.064 N/m (20 C; 1 g/l)
BLACK TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/05/2016 EN (English US) 8/10
12.5. Other adverse effects
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to approved disposal site.
Additional information : Handle empty containers with care because residual vapors are flammable.
Ecology - waste materials : Avoid release to the environment.
SECTION 14: Transport information
In accordance with DOT
UN-No.(DOT) : UN1866
Proper Shipping Name (DOT) : RESIN SOLUTION
Transport hazard class(es) (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120
Hazard labels (DOT) : 3 - Flammable liquid
Packing group (DOT) : II - Medium Danger
Additional information
Other information : No supplementary information available.
ADR
Transport document description : UN 1866, 3, II, (D/E)
Packing group (ADR) : II
Class (ADR) : 3 - Flammable liquid
Hazard identification number (Kemler No.) : 33
Classification code (ADR) : F1
Hazard labels (ADR) : 3 - Flammable liquids
Orange plates :
Tunnel restriction code : D/E
LQ : 5l
Excepted quantities (ADR) : E2
Transport by sea
UN-No. (IMDG) : 1866
Proper Shipping Name (IMDG) : RESIN SOLUTION
Class (IMDG) : 3 - Flammable liquids
Packing group (IMDG) : II - substances presenting medium danger
Air transport
UN-No. (IATA) : 1866
Proper Shipping Name (IATA) : RESIN SOLUTION
Class (IATA) : 3 - Flammable Liquids
Packing group (IATA) : II - Medium Danger
BLACK TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/05/2016 EN (English US) 9/10
SECTION 15: Regulatory information
15.1. US Federal regulations
styrene, inhibited (100-42-5)
RQ (Reportable quantity, section 304 of EPA's
List of Lists)
1000 lb
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Reactive hazard
Fire hazard
Delayed (chronic) health hazard
methyl ethyl ketone (78-93-3)
RQ (Reportable quantity, section 304 of EPA's
List of Lists)
5000 lb
15.2. International regulations
CANADA
No additional information available
EU-Regulations
No additional information available
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flam. Liq. 2 H225
Acute Tox. 4 (Inhalation:dust,mist) H332
Skin Irrit. 2 H315
Eye Irrit. 2 H319
Muta. 1B H340
Carc. 1B H350
Full text of H-phrases: see section 16
Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]
Carc.Cat.2; R45
Muta.Cat.2; R46
F; R11
Xn; R20
Xi; R36/38
Full text of R-phrases: see section 16
15.2.2. National regulations
styrene, inhibited (100-42-5)
Listed on EPA's Hazardous Air Pollutants (HAPS)
15.3. US State regulations
styrene, inhibited (100-42-5)
U.S. - California -
Proposition 65 -
Carcinogens List
U.S. - California -
Proposition 65 -
Developmental Toxicity
U.S. - California -
Proposition 65 -
Reproductive Toxicity -
Female
U.S. - California -
Proposition 65 -
Reproductive Toxicity - Male
Non-significant risk level
(NSRL)
styrene, inhibited (100-42-5)
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
BLACK TOOLING GEL COAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/05/2016 EN (English US) 10/10
SECTION 16: Other information
Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN P ARLIAMENT AND OF THE
COUNCIL of 16 December 2008 on classification, labeling and packaging of substances and
mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending
Regulation (EC) No 1907/2006.
Other information : None.
Full text of H-phrases: see section 16:
------ Acute Tox. 4 (Inhalation:vapour) Acute toxicity (inhalation:vapour) Category 4
------ Asp. Tox. 1 Aspiration hazard Category 1
------ Carc. 2 Carcinogenicity Category 2
------ Eye Irrit. 2A Serious eye damage/eye irritation Category 2A
------ Flam. Liq. 2 Flammable liquids Category 2
------ Flam. Liq. 3 Flammable liquids Category 3
------ Repr. 2 Reproductive toxicity Category 2
------ Skin Irrit. 2 Skin corrosion/irritation Category 2
------ STOT RE 1 Specific target organ toxicity (repeated exposure) Category 1
------ STOT SE 3 Specific target organ toxicity (single exposure) Category 3
------ STOT SE 3 Specific target organ toxicity (single exposure) Category 3
------ H225 Highly flammable liquid and vapor
------ H226 Flammable liquid and vapor
------ H304 May be fatal if swallowed and enters airways
------ H315 Causes skin irritation
------ H319 Causes serious eye irritation
------ H332 Harmful if inhaled
------ H335 May cause respiratory irritation
------ H336 May cause drowsiness or dizziness
------ H351 Suspected of causing cancer
------ H361 Suspected of damaging fertility or the unborn child
------ H372 Causes damage to organs through prolonged or repeated exposure
NFPA health hazard : 2 - Intense or continued exposure could cause temporary
incapacitation or possible residual injury unless prompt
medical attention is given.
NFPA fire hazard : 3 - Liquids and solids that can be ignited under almost all
ambient conditions.
NFPA reactivity : 2 - Normally unstable and readily undergo violent
decomposition but do not detonate. Also: may react
violently with water or may form potentially explosive
mixtures with water.
HMIS III Rating
Health : 2 Moderate Hazard - Temporary or minor injury may occur
Flammability : 3 Serious Hazard
Physical : 1 Slight Hazard
Personal Protection : H
SDS US (GHS HazCom 2012)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied
warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.