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GREY VE GELCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date: 03/08/2019

05/16/2019 EN (English US) Page 1

SECTION 1: Identification

1.1. Identification
Product form : Mixture
Trade name : GREY VE GELCOAT
CAS-No. : mixture
Product code : 1407-005
Formula : na

1.2. Recommended use and restrictions on use
Use of the substance/mixture : tooling gel

1.3. Supplier
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316

909-546-1162
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887

1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887

SECTION 2: Hazard(s) identification

2.1. Classification of the substance or mixture
GHS US classification
Flammable liquids Category 3 H226 Flammable liquid and vapour
Skin corrosion/irritation Category 2 H315 Causes skin irritation
Serious eye damage/eye irritation Category 2 H319 Causes serious eye irritation
Skin sensitization, Category 1 H317 May cause an allergic skin reaction
Carcinogenicity Category 2 H351 Suspected of causing cancer
Reproductive toxicity Category 2 H361 Suspected of damaging fertility or the unborn child
Specific target organ toxicity (single exposure) Category 3 H335 May cause respiratory irritation
Specific target organ toxicity (repeated exposure) Category 1 H372 Causes damage to organs through prolonged or repeated exposure
Hazardous to the aquatic environment – Acute Hazard Category 3 H402 Harmful to aquatic life

Full text of H statements : see section 16

2.2. GHS Label elements, including precautionary statements
GHS US labeling
Hazard pictograms (GHS US) :

Signal word (GHS US) : Danger
Hazard statements (GHS US) : H226 – Flammable liquid and vapour
H315 – Causes skin irritation
H317 – May cause an allergic skin reaction
H319 – Causes serious eye irritation
H335 – May cause respiratory irritation
H351 – Suspected of causing cancer
H361 – Suspected of damaging fertility or the unborn child
H372 – Causes damage to organs through prolonged or repeated exposure
H402 – Harmful to aquatic life
Precautionary statements (GHS US) : P201 – Obtain special instructions before use.
P202 – Do not handle until all safety precautions have been read and understood.
P210 – Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P233 – Keep container tightly closed.

GREY VE GELCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

05/16/2019 EN (English US) 2/13

P240 – Ground/Bond container and receiving equipment
P241 – Use explosion-proof electrical, lighting, ventilating equipment
P242 – Use only non-sparking tools.
P243 – Take precautionary measures against static discharge.
P260 – Do not breathe vapors, mist, dust.
P261 – Avoid breathing spray.
P264 – Wash EXPOSED AREA. thoroughly after handling.
P270 – Do not eat, drink or smoke when using this product.
P271 – Use only outdoors or in a well-ventilated area.
P272 – Contaminated work clothing must not be allowed out of the workplace
P273 – Avoid release to the environment.
P280 – Wear eye protection, protective clothing, protective gloves.
P302+P352 – If on skin: Wash with plenty of water
P303+P361+P353 – If on skin (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower
P304+P340 – If inhaled: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 – If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P308+P313 – If exposed or concerned: Get medical advice/attention.
P312 – Call a poison center or doctor if you feel unwell
P314 – Get medical advice/attention if you feel unwell.
P321 – Specific treatment (see SEEK MEDICAL AID. on this label)
P332+P313 – If skin irritation occurs: Get medical advice/attention.
P333+P313 – If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 – If eye irritation persists: Get medical advice/attention.
P362+P364 – Take off contaminated clothing and wash it before reuse.
P363 – Wash contaminated clothing before reuse.
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish.
P403+P233 – Store in a well-ventilated place. Keep container tightly closed.
P403+P235 – Store in a well-ventilated place. Keep cool.
P405 – Store locked up.
P501 – Dispose of contents/container to LOCAL, STATE, AND NATIONAL REGULATIONS.

2.3. Other hazards which do not result in classification
No additional information available
2.4. Unknown acute toxicity (GHS US)
Not applicable
SECTION 3: Composition/Information on ingredients

3.1. Substances
Not applicable
3.2. Mixtures

Name Product identifier % GHS US classification
Unsaturated VINYL ESTER Resin

(CAS-No.) TRADE SECRET <= 55 Not classified styrene, inhibited (CAS-No.) 100-42-5 <= 27.41 Flam. Liq. 3, H226 Acute Tox. 4 (Inhalation), H332 Acute Tox. 4 (Inhalation:vapour), H332 Skin Irrit. 2, H315 Eye Irrit. 2A, H319 Carc. 2, H351 Repr. 2, H361 STOT SE 3, H335 STOT RE 1, H372 talc (CAS-No.) 14807-96-6 <= 9 Not classified titanium(IV) oxide (CAS-No.) 13463-67-7 <= 7 Aquatic Acute 3, H402 BLACK DISPERSION (CAS-No.) Proprietary <= 2 Not classified methyl ethyl ketone (CAS-No.) 78-93-3 <= 1 Flam. Liq. 2, H225 Eye Irrit. 2, H319 STOT SE 3, H336 cobalt(II) 2-ethylhexanoate (CAS-No.) 136-52-7 <= 0.5 Eye Irrit. 2, H319 Skin Sens. 1, H317 Carc. 2, H351 Aquatic Acute 1, H400 Aquatic Chronic 2, H411 GREY VE GELCOAT Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/16/2019 EN (English US) 3/13 Full text of hazard classes and H-statements : see section 16 SECTION 4: First-aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. Suspected of causing cancer. IF exposed or concerned: Get medical advice/attention. First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor/physician if you feel unwell. First-aid measures after skin contact : Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. Specific treatment (see supplemental first aid instruction on this label). Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. If skin irritation or rash occurs: Get medical advice/attention. First-aid measures after eye contact : If eye irritation persists: Get medical advice/attention. Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a poison center/doctor/physician if you feel unwell. 4.2. Most important symptoms and effects (acute and delayed) Potential Adverse human health effects and symptoms : Harmful if inhaled. Symptoms/effects : May cause genetic defects. Suspected of damaging fertility or the unborn child. Causes damage to organs. Symptoms/effects after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if inhaled. May cause respiratory irritation. Symptoms/effects after skin contact : Causes skin irritation. Irritation. May cause an allergic skin reaction. Symptoms/effects after eye contact : Causes serious eye irritation. Eye irritation. 4.3. Immediate medical attention and special treatment, if necessary Treat symptomatically. SECTION 5: Fire-fighting measures 5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media : Sand. Water spray. Dry powder. Foam. Carbon dioxide. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Specific hazards arising from the chemical Fire hazard : Flammable liquid and vapour. Explosion hazard : May form flammable/explosive vapor-air mixture. Reactivity in case of fire : No reactivity hazard other than the effects described in sub-sections below. 5.3. Special protective equipment and precautions for fire-fighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No smoking. 6.1.1. For non-emergency personnel Protective equipment : Gloves. Protective goggles. Protective clothing. Emergency procedures : Ventilate spillage area. Evacuate unnecessary personnel. No open flames, no sparks, and no smoking. Do not breathe dust/fume/gas/mist/vapors/spray. Avoid contact with skin and eyes. 6.1.2. For emergency responders Protective equipment : Do not attempt to take action without suitable protective equipment. Equip cleanup crew with proper protection. For further information refer to section 8: "Exposure controls/personal protection". GREY VE GELCOAT Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/16/2019 EN (English US) 4/13 Emergency procedures : Ventilate area. 6.2. Environmental precautions Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up For containment : Dam up the liquid spill. Contain released product, pump into suitable containers. Collect spillage. Methods for cleaning up : Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. Notify authorities if product enters sewers or public waters. Other information : Dispose of materials or solid residues at an authorized site. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed : Handle empty containers with care because residual vapors are flammable. Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. No open flames. No smoking. Eliminate all ignition sources if safe to do so. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Flammable vapors may accumulate in the container. Use explosion-proof equipment. Wear personal protective equipment. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well- ventilated area. Avoid contact with skin and eyes. Hygiene measures : Wash hands, forearms and face thoroughly after handling. Wash contaminated clothing before reuse. Contaminated work clothing should not be allowed out of the workplace. Do not eat, drink or smoke when using this product. Always wash hands after handling the product. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Proper grounding procedures to avoid static electricity should be followed. Use explosion-proof electrical/ventilating/lighting equipment. Ground/bond container and receiving equipment. Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Store in a well- ventilated place. Keep cool. Keep container tightly closed. Store locked up. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. Heat sources. SECTION 8: Exposure controls/personal protection 8.1. Control parameters styrene, inhibited (100-42-5) ACGIH ACGIH TWA (ppm) 20 ppm (Styrene, monomer; USA; Time-weighted average exposure limit 8 h; TLV - Adopted Value) ACGIH ACGIH STEL (ppm) 40 ppm (Styrene, monomer; USA; Short time value; TLV - Adopted Value) Unsaturated VINYL ESTER Resin (TRADE SECRET) Not applicable BLACK DISPERSION (Proprietary) Not applicable methyl ethyl ketone (78-93-3) ACGIH ACGIH TWA (ppm) 200 ppm ACGIH ACGIH STEL (ppm) 300 ppm titanium(IV) oxide (13463-67-7) ACGIH ACGIH TWA (mg/m ) 10 mg/m GREY VE GELCOAT Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/16/2019 EN (English US) 5/13 talc (14807-96-6) ACGIH ACGIH TWA (mg/m ) 2 mg/m (Respirable fraction. The value is for particulate matter containing no asbestos and < 1% crystalline silica) 0.1 fibers/cm (Respirable fibers: length > 5 m; aspect
ratio 3:1, as determined by the membrane filter
method at 400-450X magnification (4-mm objective),
using phase-contrast illumination)

cobalt(II) 2-ethylhexanoate (136-52-7)
Not applicable

8.2. Appropriate engineering controls
Appropriate engineering controls : Ensure exposure is below occupational exposure limits (where available). Ensure good
ventilation of the work station.
Environmental exposure controls : Avoid release to the environment.

8.3. Individual protection measures/Personal protective equipment
Personal protective equipment:
Avoid all unnecessary exposure.

Hand protection:
Wear protective gloves.

Eye protection:
Chemical goggles or safety glasses. Safety glasses

Skin and body protection:
Wear suitable protective clothing

Respiratory protection:
Wear appropriate mask. Wear respiratory protection.

Other information:
Do not eat, drink or smoke during use.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : Liquid

Color : Gray

Odor : characteristic

Odor threshold : No data available

pH : No data available

Melting point : Not applicable

Freezing point : No data available

Boiling point : 135 – 146 C

Flash point : 32.2 C

Relative evaporation rate (butyl acetate=1) : No data available

Flammability (solid, gas) : Flammable liquid and vapour.

Vapor pressure : No data available

Relative vapor density at 20 C : No data available

Relative density : 1.1

Solubility : No data available

Log Pow : No data available

Auto-ignition temperature : No data available

Decomposition temperature : No data available

Viscosity, kinematic : No data available

GREY VE GELCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

05/16/2019 EN (English US) 6/13

Viscosity, dynamic : No data available

Explosion limits : No data available

Explosive properties : No data available

Oxidizing properties : No data available

9.2. Other information
No additional information available
SECTION 10: Stability and reactivity

10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below. Flammable liquid and vapour.

10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Flammable liquid and vapour. May form flammable/explosive vapor-air
mixture.

10.3. Possibility of hazardous reactions
Not established.

10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Sparks. Avoid contact with hot surfaces. Heat. No flames, no sparks.
Eliminate all sources of ignition.

10.5. Incompatible materials
Strong acids. Strong bases.

10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified

styrene, inhibited (100-42-5)
LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
LD50 dermal rat 2820 mg/kg (Rat; Literature study; OECD 402: Acute Dermal Toxicity; >2000 mg/kg
bodyweight; Rat; Experimental value)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 inhalation rat (mg/l) 12 mg/l/4h (Rat; Literature study)
LC50 inhalation rat (ppm) 2770 ppm/4h (Rat; Literature study)
ATE US (oral) 5000 mg/kg body weight
ATE US (dermal) 2820 mg/kg body weight
ATE US (gases) 2770 ppmV/4h
ATE US (vapors) 12 mg/l/4h
ATE US (dust, mist) 1.5 mg/l/4h

methyl ethyl ketone (78-93-3)
LD50 oral rat 2193 mg/kg body weight (Equivalent or similar to OECD 423, Rat, Male / female, Read-
across, Oral)
LD50 dermal rabbit > 10 ml/kg (Equivalent or similar to OECD 402, 24 h, Rabbit, Male, Experimental value,
Dermal)
ATE US (oral) 2193 mg/kg body weight

titanium(IV) oxide (13463-67-7)
LD50 oral rat > 5000 mg/kg body weight (OECD 425: Acute Oral Toxicity: Up-and-Down Procedure, Rat,
Female, Experimental value, Oral, 14 day(s))
LC50 inhalation rat (mg/l) > 6.82 mg/l (Other, 4 h, Rat, Male, Experimental value, Inhalation (dust), 14 day(s))

cobalt(II) 2-ethylhexanoate (136-52-7)
LD50 oral rat 3129 mg/kg body weight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)

GREY VE GELCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

05/16/2019 EN (English US) 7/13

cobalt(II) 2-ethylhexanoate (136-52-7)
LD50 dermal rat > 2000 mg/kg body weight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)
ATE US (oral) 3129 mg/kg body weight

Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitization : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified
Carcinogenicity : Suspected of causing cancer.

styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans
National Toxicology Program (NTP) Status Reasonably anticipated to be Human Carcinogen

cobalt(II) 2-ethylhexanoate (136-52-7)
IARC group 2B – Possibly carcinogenic to humans

Reproductive toxicity : Suspected of damaging fertility or the unborn child.
Specific target organ toxicity single exposure : May cause respiratory irritation.

styrene, inhibited (100-42-5)
Specific target organ toxicity single exposure May cause respiratory irritation.

methyl ethyl ketone (78-93-3)
Specific target organ toxicity single exposure May cause drowsiness or dizziness.

Specific target organ toxicity repeated
exposure
: Causes damage to organs through prolonged or repeated exposure.

styrene, inhibited (100-42-5)
Specific target organ toxicity repeated
exposure
Causes damage to organs through prolonged or repeated exposure.

Aspiration hazard : Not classified
Viscosity, kinematic : No data available

Potential Adverse human health effects and
symptoms
: Harmful if inhaled.
Symptoms/effects : May cause genetic defects. Suspected of damaging fertility or the unborn child. Causes
damage to organs.
Symptoms/effects after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled. May cause respiratory irritation.
Symptoms/effects after skin contact : Causes skin irritation. Irritation. May cause an allergic skin reaction.
Symptoms/effects after eye contact : Causes serious eye irritation. Eye irritation.

SECTION 12: Ecological information

12.1. Toxicity
Ecology – general : Harmful to aquatic life.

methyl ethyl ketone (78-93-3)
LC50 fish 1 2993 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Static system,
Fresh water, Experimental value, GLP)
EC50 Daphnia 1 308 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Static
system, Fresh water, Experimental value, GLP)
ErC50 (algae) 1972 mg/l (OECD 201: Alga, Growth Inhibition Test, 72 h, Pseudokirchneriella subcapitata,
Static system, Fresh water, Experimental value, GLP)

titanium(IV) oxide (13463-67-7)
LC50 fish 1 > 100 mg/l (Equivalent or similar to OECD 203, 96 h, Oncorhynchus mykiss, Static system,
Fresh water, Experimental value, Nominal concentration)

GREY VE GELCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

05/16/2019 EN (English US) 8/13

titanium(IV) oxide (13463-67-7)
ErC50 (algae) 61 mg/l (EPA 600/9-78-018, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, Nominal concentration)

talc (14807-96-6)
LC50 fish 1 > 100 g/l (24 h, Brachydanio rerio, Semi-static system)

cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 1 46.51 mg/l (LOEC; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 1 0.212 mg/l (NOEC; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
LC50 fish 2 54.1 mg/l (LC50; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 2 0.605 mg/l (LC50; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
Threshold limit algae 1 144 g/l (ErC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
Threshold limit algae 2 32.2 g/l (NOEC; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)

12.2. Persistence and degradability
GREY VE GELCOAT (mixture)
Persistence and degradability Not established.

styrene, inhibited (100-42-5)
Persistence and degradability Readily biodegradable in water. Not readily biodegradable in water. Forming sediments in
water. Non degradable in the soil. Adsorbs into the soil. Photodegradation in the air. Not
established.
Chemical oxygen demand (COD)
2.8 g O /g substance
ThOD
3.07 g O /g substance
BOD (% of ThOD) 0.42

Unsaturated VINYL ESTER Resin (TRADE SECRET)
Persistence and degradability Not established.

BLACK DISPERSION (Proprietary)
Persistence and degradability Not established.

methyl ethyl ketone (78-93-3)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. Not established.
Biochemical oxygen demand (BOD)
2.03 g O /g substance
Chemical oxygen demand (COD)
2.31 g O /g substance
ThOD
2.44 g O /g substance

titanium(IV) oxide (13463-67-7)
Persistence and degradability Biodegradability: not applicable.
Chemical oxygen demand (COD)
Not applicable (inorganic)
ThOD
Not applicable (inorganic)

talc (14807-96-6)
Persistence and degradability Biodegradability: not applicable.
Biochemical oxygen demand (BOD)
Not applicable
Chemical oxygen demand (COD)
Not applicable
ThOD
Not applicable
BOD (% of ThOD) Not applicable

cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability Readily biodegradable in water. No (test)data on mobility of the substance available.

GREY VE GELCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

05/16/2019 EN (English US) 9/13

12.3. Bioaccumulative potential
GREY VE GELCOAT (mixture)
Bioaccumulative potential Not established.

styrene, inhibited (100-42-5)
BCF fish 1 35.5 (BCF)
Log Pow 2.96 (Experimental value; OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method; 25 C)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Not established. Unsaturated VINYL ESTER Resin (TRADE SECRET) Bioaccumulative potential Not established. BLACK DISPERSION (Proprietary) Bioaccumulative potential Not established. methyl ethyl ketone (78-93-3) Log Pow 0.3 (Experimental value, OECD 117: Partition Coefficient (n-octanol/water), HPLC method, 40 C) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established. titanium(IV) oxide (13463-67-7) Bioaccumulative potential Not bioaccumulative. cobalt(II) 2-ethylhexanoate (136-52-7) BCF fish 1 1.2 (BCF; 131 days; Seriola quinqueradiata; Static system; Salt water; Read-across) Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). 12.4. Mobility in soil styrene, inhibited (100-42-5) Surface tension 0.032 N/m (19 C) Log Koc Koc,352; Estimated value; log Koc; 2.55; Estimated value methyl ethyl ketone (78-93-3) Surface tension 0.024 N/m (20 C) Log Koc 1.53 (log Koc, Calculated value) Ecology - soil Highly mobile in soil. Slightly harmful to plants. titanium(IV) oxide (13463-67-7) Ecology - soil Low potential for mobility in soil. cobalt(II) 2-ethylhexanoate (136-52-7) Surface tension 0.064 N/m (20 C; 1 g/l) 12.5. Other adverse effects Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Disposal methods Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions. Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. Additional information : Handle empty containers with care because residual vapors are flammable. Flammable vapors may accumulate in the container. Ecology - waste materials : Avoid release to the environment. GREY VE GELCOAT Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/16/2019 EN (English US) 10/13 SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Transport document description : UN1866 Resin solution, 3, II UN-No.(DOT) : UN1866 Proper Shipping Name (DOT) : Resin solution Class (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120 Packing group (DOT) : II - Medium Danger Hazard labels (DOT) : 3 - Flammable liquid DOT Packaging Non Bulk (49 CFR 173.xxx) : 173 DOT Packaging Bulk (49 CFR 173.xxx) : 242 DOT Special Provisions (49 CFR 172.102) : 149 - When transported as a limited quantity or a consumer commodity, the maximum net capacity specified in 173.150(b)(2) of this subchapter for inner packaging may be increased to 5 L (1.3 gallons). 383 - Packages containing toy plastic or paper caps for toy pistols described as UN0349, Articles, explosive, n.o.s. (Toy caps), 1.4S or NA0337, Toy caps, 1.4S are not subject to the subpart E (labeling) requirements of this part when offered for transportation by motor vehicle, rail freight, cargo vessel, and cargo aircraft and, notwithstanding the packing method assigned in 173.62 of this subchapter, in conformance with the following conditions: B52 - Notwithstanding the provisions of 173.24b of this subchapter, non-reclosing pressure relief devices are authorized on DOT 57 portable tanks. IB2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized. T4 - 2.65 178.274(d)(2) Normal............. 178.275(d)(3) TP1 - The maximum degree of filling must not exceed the degree of filling determined by the following: Degree of filling = 97 / 1 + a (tr - tf) Where: tr is the maximum mean bulk temperature during transport, and tf is the temperature in degrees celsius of the liquid during filling. TP8 - A portable tank having a minimum test pressure of 1.5 bar (150 kPa) may be used when the flash point of the hazardous material transported is greater than 0 C (32 F). DOT Packaging Exceptions (49 CFR 173.xxx) : 150 DOT Quantity Limitations Passenger aircraft/rail (49 CFR 173.27) : 5 L DOT Quantity Limitations Cargo aircraft only (49 CFR 175.75) : 60 L DOT Vessel Stowage Location : B - (i) The material may be stowed on deck or under deck on a cargo vessel and on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers, or one passenger per each 3 m of overall vessel length; and (ii) On deck only on passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this section is exceeded. Emergency Response Guide (ERG) Number : 127 Other information : No supplementary information available. Transportation of Dangerous Goods Not applicable Transport by sea Transport document description (IMDG) : UN 1866 RESIN SOLUTION, 3, II UN-No. (IMDG) : 1866 Proper Shipping Name (IMDG) : RESIN SOLUTION Class (IMDG) : 3 - Flammable liquids Packing group (IMDG) : II - substances presenting medium danger GREY VE GELCOAT Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/16/2019 EN (English US) 11/13 Air transport Transport document description (IATA) : UN 1866 Resin solution, 3, II UN-No. (IATA) : 1866 Proper Shipping Name (IATA) : Resin solution Class (IATA) : 3 - Flammable Liquids Packing group (IATA) : II - Medium Danger SECTION 15: Regulatory information 15.1. US Federal regulations styrene, inhibited (100-42-5) Listed on the United States TSCA (Toxic Substances Control Act) inventory Subject to reporting requirements of United States SARA Section 313 Listed on EPA Hazardous Air Pollutant (HAPS) CERCLA RQ 1000 lb SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Reactive hazard Fire hazard Delayed (chronic) health hazard Unsaturated VINYL ESTER Resin (TRADE SECRET) Not listed on the United States TSCA (Toxic Substances Control Act) inventory BLACK DISPERSION (Proprietary) Not listed on the United States TSCA (Toxic Substances Control Act) inventory methyl ethyl ketone (78-93-3) Listed on the United States TSCA (Toxic Substances Control Act) inventory Not subject to reporting requirements of the United States SARA Section 313 Listed on EPA Hazardous Air Pollutant (HAPS) CERCLA RQ 5000 lb titanium(IV) oxide (13463-67-7) Listed on the United States TSCA (Toxic Substances Control Act) inventory talc (14807-96-6) Listed on the United States TSCA (Toxic Substances Control Act) inventory cobalt(II) 2-ethylhexanoate (136-52-7) Listed on the United States TSCA (Toxic Substances Control Act) inventory 15.2. International regulations CANADA styrene, inhibited (100-42-5) Listed on the Canadian DSL (Domestic Substances List) Unsaturated VINYL ESTER Resin (TRADE SECRET) Not listed on the Canadian DSL (Domestic Substances List)/NDSL (Non-Domestic Substances List) BLACK DISPERSION (Proprietary) Not listed on the Canadian DSL (Domestic Substances List)/NDSL (Non-Domestic Substances List) methyl ethyl ketone (78-93-3) Listed on the Canadian DSL (Domestic Substances List) titanium(IV) oxide (13463-67-7) Listed on the Canadian DSL (Domestic Substances List) talc (14807-96-6) Listed on the Canadian DSL (Domestic Substances List) cobalt(II) 2-ethylhexanoate (136-52-7) Listed on the Canadian DSL (Domestic Substances List) GREY VE GELCOAT Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/16/2019 EN (English US) 12/13 EU-Regulations No additional information available National regulations styrene, inhibited (100-42-5) Listed on IARC (International Agency for Research on Cancer) Listed as carcinogen on NTP (National Toxicology Program) titanium(IV) oxide (13463-67-7) Listed on IARC (International Agency for Research on Cancer) 15.3. US State regulations styrene, inhibited (100-42-5) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significant risk level (NSRL) Maximum allowable dose level (MADL) Yes No No No 27 g/day Component State or local regulations styrene, inhibited(100-42-5) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List methyl ethyl ketone(78-93-3) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List talc(14807-96-6) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List titanium(IV) oxide(13463-67-7) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List SECTION 16: Other information according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision date : 03/08/2019 Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labeling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. Other information : None. GREY VE GELCOAT Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/16/2019 EN (English US) 13/13 Full text of H-phrases: H225 Highly flammable liquid and vapour H226 Flammable liquid and vapour H315 Causes skin irritation H317 May cause an allergic skin reaction H319 Causes serious eye irritation H332 Harmful if inhaled H335 May cause respiratory irritation H336 May cause drowsiness or dizziness H351 Suspected of causing cancer H361 Suspected of damaging fertility or the unborn child H372 Causes damage to organs through prolonged or repeated exposure H400 Very toxic to aquatic life H402 Harmful to aquatic life H411 Toxic to aquatic life with long lasting effects NFPA health hazard : 2 - Materials that, under emergency conditions, can cause temporary incapacitation or residual injury. NFPA fire hazard : 3 - Liquids and solids (including finely divided suspended solids) that can be ignited under almost all ambient temperature conditions. NFPA reactivity : 2 - Materials that readily undergo violent chemical change at elevated temperatures and pressures. Hazard Rating Health : 2 Moderate Hazard - Temporary or minor injury may occur Flammability : 3 Serious Hazard - Materials capable of ignition under almost all normal temperature conditions. Includes flammable liquids with flash points below 73 F and boiling points above 100 F. as well as liquids with flash points between 73 F and 100 F. (Classes IB & IC) Physical : 1 Slight Hazard - Materials that are normally stable but can become unstable (self-react) at high temperatures and pressures. Materials may react non-violently with water or undergo hazardous polymerization in the absence of inhibitors. Personal protection : H H - Splash goggles, Gloves, Synthetic apron, Vapor respirator SDS US (GHS HazCom 2012) To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.

401402005F_SDS.pdf

by | Sep 27, 2025

BLACK VE TOOLING gel coat
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue: 10/14/2015 Revision date: 10/14/2015 Supersedes: 09/10/2014

10/14/2015 EN (English US) Page 1

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Product form : Mixture
Trade name : BLACK VE TOOLING gel coat
CAS No : mixture
Product code : 1402-005
Formula : na

1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : tooling gel

1.3. Details of the supplier of the safety data sheet
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316

909.877.8477
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887

1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
GHS-US classification
Flam. Liq. 3 H226
Skin Irrit. 2 H315
Eye Irrit. 2A H319
Carc. Not classified
Repr. 2 H361
STOT SE 3 H335
STOT RE 1 H372

2.2. Label elements
GHS-US labeling
Hazard pictograms (GHS-US) :

GHS02

GHS07

GHS08

Signal word (GHS-US) : Danger
Hazard statements (GHS-US) : H226 – Flammable liquid and vapor
H315 – Causes skin irritation
H319 – Causes serious eye irritation
H335 – May cause respiratory irritation
H361 – Suspected of damaging fertility or the unborn child
H372 – Causes damage to organs through prolonged or repeated exposure
Precautionary statements (GHS-US) : P201 – Obtain special instructions before use
P202 – Do not handle until all safety precautions have been read and understood
P210 – Keep away from heat, hot surfaces, open flames, sparks. – No smoking
P233 – Keep container tightly closed
P240 – Ground/bond container and receiving equipment
P241 – Use explosion-proof electrical, lighting, ventilating equipment
P242 – Use only non-sparking tools
P243 – Take precautionary measures against static discharge
P260 – Do not breathe vapors, mist, dust
P261 – Avoid breathing spray

BLACK VE TOOLING gel coat
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

10/14/2015 EN (English US) 2/10

P264 – Wash EXPOSED AREA. thoroughly after handling
P270 – Do not eat, drink or smoke when using this product
P271 – Use only outdoors or in a well-ventilated area
P280 – Wear eye protection, protective clothing, protective gloves
P302+P352 – IF ON SKIN: Wash with plenty of soap and water
P303+P361+P353 – IF ON SKIN (or hair): Remove/Take off immediately all contaminated
clothing. Rinse skin with water/shower
P304+P340 – IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable
for breathing
P305+P351+P338 – If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P308+P313 – IF exposed or concerned: Get medical advice/attention
P312 – Call a POISON CENTER or doctor/physician if you feel unwell
P314 – Get medical advice and attention if you feel unwell
P321 – Specific treatment (see SEEK MEDICAL AID. on this label)
P332+P313 – If skin irritation occurs: Get medical advice/attention
P337+P313 – If eye irritation persists: Get medical advice/attention
P362 – Take off contaminated clothing and wash it before reuse
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish
P403+P233 – Store in a well-ventilated place. Keep container tightly closed
P403+P235 – Store in a well-ventilated place. Keep cool
P405 – Store locked up
P501 – Dispose of contents/container to LOCAL, STATE, AND NATIONAL REGULATIONS.

2.3. Other hazards
No additional information available
2.4. Unknown acute toxicity (GHS-US)
No data available
SECTION 3: Composition/Information on ingredients

3.1. Substance
Not applicable
Full text of H-phrases: see section 16

3.2. Mixture

Name Product identifier % GHS-US classification
Unsaturated VINYL ESTER Resin (CAS No) TRADE SECRET <= 55 Not classified styrene, inhibited (CAS No) 100-42-5 <= 39 Flam. Liq. 3, H226 Acute Tox. 4 (Inhalation:vapour), H332 Skin Irrit. 2, H315 Eye Irrit. 2A, H319 Carc. 2, H351 Repr. 2, H361 STOT SE 3, H335 STOT RE 1, H372 Asp. Tox. 1, H304 cobalt(II) 2-ethylhexanoate (CAS No) 136-52-7 <= 0.5 Carc. 2, H351 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : Allow victim to breathe fresh air. Allow the victim to rest. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: wash throughly for five minutes. seek medical attention. Get medical advice/attention. Specific treatment (see seek medical attention. on this label). First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: SEEK IMMEDIATE MEDICAL ATTENTION. Get medical advice/attention. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. BLACK VE TOOLING gel coat Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 10/14/2015 EN (English US) 3/10 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : May cause genetic defects (avoid skin contact and inhalation.). May cause cancer (avoid skin contact and inhalation.). Symptoms/injuries after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if inhaled. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms/injuries after eye contact : Causes serious eye irritation. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Fire hazard : Highly flammable liquid and vapor. Explosion hazard : May form flammable/explosive vapor-air mixture. Reactivity : No reactivity hazard other than the effects described in sub-sections below. 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No smoking. 6.1.1. For non-emergency personnel Protective equipment : Gloves. Protective goggles. Protective clothing. Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up For containment : Dam up the liquid spill. Contain released substance, pump into suitable containers. Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed : Handle empty containers with care because residual vapors are flammable. Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. No open flames. No smoking. Use only non-sparking tools. Use only outdoors or in a well- ventilated area. Avoid breathing DUST, FUMES, MIST, OR VAPORS. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Eliminate all ignition sources if safe to do so. Hygiene measures : Wash HANDS thoroughly after handling. BLACK VE TOOLING gel coat Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 10/14/2015 EN (English US) 4/10 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical, ventilating and lighting equipment. equipment. Storage conditions : Keep only in the original container in a cool, well ventilated place away from : HEAT SPARKS OR OPEN FLAMES. Keep in fireproof place. Keep container tightly closed. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. Heat sources. 7.3. Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection 8.1. Control parameters styrene, inhibited (100-42-5) USA ACGIH ACGIH TWA (ppm) 20 ppm USA ACGIH ACGIH STEL (ppm) 20 ppm 8.2. Exposure controls Appropriate engineering controls : Ensure exposure is below occupational exposure limits (where available). Personal protective equipment : Avoid all unnecessary exposure. Hand protection : Wear protective gloves. Eye protection : Chemical goggles or safety glasses. Skin and body protection : Wear suitable protective clothing. Respiratory protection : Wear appropriate mask. Other information : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Color : Black. Odor : characteristic. Odor threshold : No data available pH : No data available Relative evaporation rate (butyl acetate=1) : No data available Melting point : No data available Freezing point : No data available Boiling point : 64 C Flash point : 30 - 34 C Auto-ignition temperature : No data available Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapor pressure : No data available Relative vapor density at 20 C : No data available Relative density : 1.1 Solubility : No data available Log Pow : No data available Log Kow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosive properties : No data available Oxidizing properties : No data available Explosive limits : No data available BLACK VE TOOLING gel coat Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 10/14/2015 EN (English US) 5/10 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity No reactivity hazard other than the effects described in sub-sections below. 10.2. Chemical stability Polymerization can result in formation of solid deposits, even in vapour space. Not established. Highly flammable liquid and vapor. May form flammable/explosive vapor-air mixture. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. Open flame. 10.5. Incompatible materials Strong acids. Strong bases. 10.6. Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. May release flammable gases. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified BLACK VE TOOLING gel coat ( f )mixture ATE CLP (vapors) 11.000 mg/l/4h styrene, inhibited (100-42-5) LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
LD50 dermal rat 2820 mg/kg (Rat; Literature study; OECD 402: Acute Dermal Toxicity; >2000 mg/kg
bodyweight; Rat; Experimental value)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 inhalation rat (mg/l) 12 mg/l/4h (Rat; Literature study)
LC50 inhalation rat (ppm) 2770 ppm/4h (Rat; Literature study)
ATE CLP (oral) 5000.000 mg/kg body weight
ATE CLP (dermal) 2820.000 mg/kg body weight
ATE CLP (gases) 2770.000 ppmV/4h
ATE CLP (vapors) 12.000 mg/l/4h
ATE CLP (dust, mist) 12.000 mg/l/4h

cobalt(II) 2-ethylhexanoate (136-52-7)
LD50 oral rat 3129 mg/kg body weight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat > 2000 mg/kg body weight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)
ATE CLP (oral) 3129.000 mg/kg body weight

Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitization : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified.

styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans

cobalt(II) 2-ethylhexanoate (136-52-7)
IARC group 2B – Possibly carcinogenic to humans

Reproductive toxicity : Suspected of damaging fertility or the unborn child.
Based on available data, the classification criteria are not met

BLACK VE TOOLING gel coat
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

10/14/2015 EN (English US) 6/10

Specific target organ toxicity (single exposure) : May cause respiratory irritation.

Specific target organ toxicity (repeated
exposure)
: Causes damage to organs through prolonged or repeated exposure.
Based on available data, the classification criteria are not met

Aspiration hazard : Not classified
Based on available data, the classification criteria are not met
Potential Adverse human health effects and
symptoms
: Harmful if inhaled.
Symptoms/injuries after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled.
Symptoms/injuries after skin contact : Causes skin irritation.
Symptoms/injuries after eye contact : Causes serious eye irritation.
SECTION 12: Ecological information

12.1. Toxicity

styrene, inhibited (100-42-5)
LC50 fish 1 25 mg/l (96 h; Lepomis macrochirus; GLP)
LC50 other aquatic organisms 1 10 – 100 mg/l (96 h)
EC50 Daphnia 1 23 mg/l (48 h; Daphnia magna; Locomotor effect)
LC50 fish 2 32 mg/l (96 h; Pimephales promelas)
EC50 Daphnia 2 27 mg/l (24 h; Daphnia magna; GLP)
TLM fish 1 25.1 mg/l (96 h; Lepomis macrochirus; Soft water)
TLM fish 2 46.4 mg/l (96 h; Pimephales promelas; Soft water)
TLM other aquatic organisms 1 10 – 100,96 h
Threshold limit other aquatic organisms 1 10 – 100,96 h; Pseudomonas putida
Threshold limit other aquatic organisms 2 72 mg/l
Threshold limit algae 1 > 200 mg/l (192 h; Scenedesmus quadricauda; Inhibitory)
Threshold limit algae 2 67 mg/l (Microcystis aeruginosa; Inhibitory)

cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 1 54.1 mg/l (96 h; Pimephales promelas)
EC50 Daphnia 1 2618 g/l (48 h)
Threshold limit algae 1 24.1 g/l (7 days)
Threshold limit algae 2 90.1 g/l (7 days; Lemna minor; Growth rate)

12.2. Persistence and degradability
BLACK VE TOOLING gel coat (mixture)
Persistence and degradability Not established.

styrene, inhibited (100-42-5)
Persistence and degradability Readily biodegradable in water. Not readily biodegradable in water. Forming sediments in
water. Non degradable in the soil. Adsorbs into the soil. Photodegradation in the air. Not
established.
Chemical oxygen demand (COD) 2.80 g O /g substance
ThOD 3.07 g O /g substance
BOD (% of ThOD) 0.42 % ThOD

cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability Biodegradability in water: no data available.

Unsaturated VINYL ESTER Resin (TRADE SECRET)
Persistence and degradability Not established.

12.3. Bioaccumulative potential
BLACK VE TOOLING gel coat (mixture)
Bioaccumulative potential Not established.

styrene, inhibited (100-42-5)
BCF fish 1 35.5 (Carassius auratus)

BLACK VE TOOLING gel coat
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

10/14/2015 EN (English US) 7/10

styrene, inhibited (100-42-5)
BCF other aquatic organisms 1 74
Log Pow 2.96 (Experimental value; OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method; 25 C)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Not established. cobalt(II) 2-ethylhexanoate (136-52-7) Bioaccumulative potential No bioaccumulation data available. Unsaturated VINYL ESTER Resin (TRADE SECRET) Bioaccumulative potential Not established. 12.4. Mobility in soil styrene, inhibited (100-42-5) Surface tension 0.032 N/m (19 C) cobalt(II) 2-ethylhexanoate (136-52-7) Surface tension 0.064 N/m (20 C; 1 g/l) 12.5. Other adverse effects Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to approved disposal site. Additional information : Handle empty containers with care because residual vapors are flammable. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with DOT UN-No.(DOT) : UN1866 Proper Shipping Name (DOT) : RESIN SOLUTION Transport hazard class(es) (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120 Hazard labels (DOT) : 3 - Flammable liquid Packing group (DOT) : III - Minor Danger Additional information Other information : No supplementary information available. ADR Transport document description : UN 1866, 3, III, (D/E) Packing group (ADR) : III Class (ADR) : 3 - Flammable liquid Hazard identification number (Kemler No.) : 33 Classification code (ADR) : F1 Hazard labels (ADR) : 3 - Flammable liquids BLACK VE TOOLING gel coat Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 10/14/2015 EN (English US) 8/10 Orange plates : Tunnel restriction code : D/E LQ : 5l Excepted quantities (ADR) : E2 Transport by sea UN-No. (IMDG) : 1866 Proper Shipping Name (IMDG) : RESIN SOLUTION Class (IMDG) : 3 - Flammable liquids Packing group (IMDG) : III - substances presenting low danger Air transport UN-No. (IATA) : 1866 Proper Shipping Name (IATA) : RESIN SOLUTION Class (IATA) : 3 - Flammable Liquids Packing group (IATA) : III - Minor Danger SECTION 15: Regulatory information 15.1. US Federal regulations styrene, inhibited (100-42-5) RQ (Reportable quantity, section 304 of EPA's List of Lists) 1000 lb SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Reactive hazard Fire hazard Delayed (chronic) health hazard 15.2. International regulations CANADA No additional information available EU-Regulations No additional information available Classification according to Regulation (EC) No. 1272/2008 [CLP] Flam. Liq. 3 H226 Acute Tox. 4 (Inhalation:vapour) H332 Skin Irrit. 2 H315 Eye Irrit. 2 H319 Muta. 1B H340 Carc. 2 H351 Repr. 2 H361 STOT RE 2 H373 Full text of H-phrases: see section 16 Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Carc.Cat.2; R45 Muta.Cat.2; R46 F; R11 Xn; R20 Xi; R36/38 Full text of R-phrases: see section 16 BLACK VE TOOLING gel coat Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 10/14/2015 EN (English US) 9/10 15.2.2. National regulations styrene, inhibited (100-42-5) Listed on EPA's Hazardous Air Pollutants (HAPS) 15.3. US State regulations styrene, inhibited (100-42-5) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male Non-significant risk level (NSRL) styrene, inhibited (100-42-5) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List SECTION 16: Other information Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labeling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. Other information : None. Full text of H-phrases: see section 16: ------ Acute Tox. 4 (Inhalation:vapour) Acute toxicity (inhalation:vapour) Category 4 ------ Asp. Tox. 1 Aspiration hazard Category 1 ------ Carc. 2 Carcinogenicity Category 2 ------ Carc. Not classified Carcinogenicity Not classified ------ Eye Irrit. 2A Serious eye damage/eye irritation Category 2A ------ Flam. Liq. 3 Flammable liquids Category 3 ------ Repr. 2 Reproductive toxicity Category 2 ------ Skin Irrit. 2 Skin corrosion/irritation Category 2 ------ STOT RE 1 Specific target organ toxicity (repeated exposure) Category 1 ------ STOT SE 3 Specific target organ toxicity (single exposure) Category 3 ------ H226 Flammable liquid and vapor ------ H304 May be fatal if swallowed and enters airways ------ H315 Causes skin irritation ------ H319 Causes serious eye irritation ------ H332 Harmful if inhaled ------ H335 May cause respiratory irritation ------ H351 Suspected of causing cancer ------ H361 Suspected of damaging fertility or the unborn child ------ H372 Causes damage to organs through prolonged or repeated exposure NFPA health hazard : 2 - Intense or continued exposure could cause temporary incapacitation or possible residual injury unless prompt medical attention is given. NFPA fire hazard : 3 - Liquids and solids that can be ignited under almost all ambient conditions. NFPA reactivity : 2 - Normally unstable and readily undergo violent decomposition but do not detonate. Also: may react violently with water or may form potentially explosive mixtures with water. BLACK VE TOOLING gel coat Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 10/14/2015 EN (English US) 10/10 HMIS III Rating Health : 2 Moderate Hazard - Temporary or minor injury may occur Flammability : 3 Serious Hazard Physical : 1 Slight Hazard Personal Protection : H SDS US (GHS HazCom 2012) To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.

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