3921651C-G_SDS.pdf

by | Sep 27, 2025

SAFETY DATA SHEET
STAN-MASK 21651 CITRUS SWEET GRAS
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product identifier
Product Name STAN-MASK 21651 CITRUS SWEET GRAS
Other means of identification
CAS No Mixture
Synonyms None
Recommended use of the chemical and restrictions on use
Recommended Use Fragrances
Uses advised against No information available
Details of the supplier of the safety data sheet
Manufactured for and Supplied by Harwick Standard Distribution Corporation
P.O. Box 9360
60 S. Seiberling Street
Akron, OH 44305 USA
(330) 798-9300
www.harwickstandard.com
2. HAZARDS IDENTIFICATION
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Skin corrosion/irritation – Category 2
Skin sensitization – Category 1B
Aspiration toxicity – Category 1
Label elements Physical hazards – Flammable liquids – Category 3
Signal word – Danger
Hazard statements
Causes skin irritation
May cause an allergic skin reaction
May be fatal if swallowed and enters airways
_____________________________________________________________________________________________
Page 1 / 9
Product Name: STAN-MASK 21651 CITRUS SWEET GRAS
Flammable liquid and vapor

_____________________________________________________________________________________________
Precautionary Statements
Wash face, hands and any exposed skin thoroughly after handling
Avoid breathing dust/fume/gas/mist/vapors/spray
Contaminated work clothing must not be allowed out of the workplace
Keep away from heat/sparks/open flames/hot surfaces. – No smoking
Keep container tightly closed
Ground/bond container and receiving equipment
Use explosion-proof electrical/ ventilating / lighting/ .? / equipment
Use only non-sparking tools
Take precautionary measures against static discharge
Wear protective gloves/eye protection/face protection
Specific treatment (see .? on this label)
If skin irritation or rash occurs: Get medical advice/attention
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower
Wash contaminated clothing before reuse
IF SWALLOWED: Immediately call a POISON CENTER or doctor
Do NOT induce vomiting
In case of fire: Use CO2, dry chemical, or foam to extinguish
Precautionary Statements – Storage
Store locked up
Store in a well-ventilated place. Keep cool
Precautionary Statements – Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Not applicable Other Information
May be harmful if swallowed May be harmful in contact with skin Toxic to aquatic life with long lasting effects Toxic to aquatic life Unknown acute toxicity 1.9 % of the mixture consists of ingredient(s) of unknown toxicity
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance
Chemical name CAS No Weight-% Trade secret
ORANGE TERPENES 68647-72-3 80 – 90 *
BENZALDEHYDE 100-52-7 1 – 10 *
ANETHOLE 4180-23-8 1 – 10 *
CINNAMIC ALCOHOL 104-54-1 1 – 10 *
ALDEHYDE C-12 LAURIC 112-54-9 <1 * Appearanceclear liquid Physical State @20 C liquid Odor Characteristic _____________________________________________________________________________________________ Page 2 / 9 Product Name: STAN-MASK 21651 CITRUS SWEET GRAS _____________________________________________________________________________________________ *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures Inhalation Remove to fresh air. Eye contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician. Skin contact Wash skin with soap and water. Ingestion Clean mouth with water and drink afterwards plenty of water. Most important symptoms and effects, both acute and delayed Symptoms No information available. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use ex tinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media CAUTION: Use of water spray when fighting fire may be inefficient. Specific hazards arising from the chemical No information available. Explosion data Sensitivity to Mechanical ImpactNone. Sensitivity to Static DischargeNone. Special protective equipment for fire-fighters Firefighters should wear self-contained breathing apparatus and full firefighting turnout gear. Use personal protection equipment. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation. Environmental precautions Environmental precautions See Section 12 for additional Ecological Information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Pick up and transfer to properly labeled containers. _____________________________________________________________________________________________ Page 3 / 9 Product Name: STAN-MASK 21651 CITRUS SWEET GRAS _____________________________________________________________________________________________ Prevention of secondary hazardsClean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Limits The following ingredients are the only ingredients of the product above the cut-off level (or level that contributes to the hazard classification of the mixture) which have an exposure limit applicable in the region for which this safety data sheet is intended or other recommended limit. At this time, the other relevant constituents have no known exposure limits from the sources listed here. Appropriate engineering controls Engineering controls Showers Eyewash stations Ventilation systems. Individual protection measures, such as personal protective equipment Eye/face protection No special protective equipment required. Skin and body protection No special protective equipment required. Respiratory protection No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required. General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State @20 C liquid Appearance clear liquid Odor Characteristic Color Colorless - Pale Yellow Odor threshold No information available _____________________________________________________________________________________________ Page 4 / 9 Product Name: STAN-MASK 21651 CITRUS SWEET GRAS _____________________________________________________________________________________________ Specific gravity 0.8590-0.8790 Refractive Index 1.4740-1.4940 Explosive properties No information available Oxidizing properties No information available Softening point No information available Molecular weight No information available VOC Content (%) No information available Density VALUE No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity No information av ailable. Chemical stability Stable under normal conditions. Possibility of hazardous reactionsNone under normal processing. Conditions to avoid None known based on information supplied. Incompatible materials None known based on information supplied. Hazardous decomposition productsNone known based on information supplied. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Inhalation Specific test data for the substance or mixture is not available. Eye contact Specific test data for the substance or mixture is not available. Skin contact Specific test data for the substance or mixture is not available. Property Values pH No data available Melting point / freezing point No data available Boiling point / boiling range > 35 C / 95 F
Flash point 51 C / 124 F
Evaporation rate No data available
Flammability (solid, gas) No data available
Flammability Limit in Air
Upper flammability limit: No data available
Lower flammability limit: No data available
Vapor pressure No data available
Vapor density No data available
Relative density No data available
Water solubility No data available
Solubility in other solvents No data available
Partition coefficient No data available
Autoignition temperature No data available
Decomposition temperature No data available
Kinematic viscosity No data available
Dynamic viscosity
_____________________________________________________________________________________________
Page 5 / 9
Product Name: STAN-MASK 21651 CITRUS SWEET GRAS
No data available

_____________________________________________________________________________________________
Ingestion Specific test data for the substance or mixture is not available.
Information on toxicological effects
Symptoms No information available.
Numerical measures of toxicity
Acute toxicity
The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral) 4,266.00 mg/kg
ATEmix (dermal) 4,280.00 mg/kg mg/l
ATEmix (inhalation-dust/mist)33.30 mg/l
ATEmix (inhalation-vapor) 244.00 mg/l
Unknown acute toxicity 1.9 % of the mixture consists of ingredient(s) of unknown toxicity
Component Information
Chemical name Oral LD50 LD50/dermal/rat – NO UNITS
(Wizards mg/kg)
Inhalation LC50
BENZALDEHYDE
100-52-7
= 1292 mg/kg ( Rat ) > 1250 mg/kg ( Rabbit ) –
ANETHOLE
4180-23-8
= 2090 mg/kg ( Rat ) – –
CINNAMIC ALCOHOL
104-54-1
= 2 g/kg ( Rat ) > 5 g/kg ( Rabbit ) –
ALDEHYDE C-12 LAURIC
112-54-9
= 23 g/kg ( Rat ) – –
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Skin corrosion/irritation No information available.
Serious eye damage/eye irritationNo information available.
Respiratory or skin sensitizationNo information available.
Germ cell mutagenicity No information available.
Carcinogenicity No information available.
Reproductive toxicity No information available.
STOT – single exposure No information available.
STOT – repeated exposure No information available.
Aspiration hazard No information available.
12. ECOLOGICAL INFORMATION
Ecotoxicity The env
ironmental impact of this product has not been fully investigated.Chemical name Algae/aquatic plants Fish Toxicity to
microorganisms
Crustacea
BENZALDEHYDE
100-52-7
– 0.8 – 1.44: 96 h Lepomis
macrochirus mg/L LC50
flow-through 10.6 – 11.8:
– 50: 24 h Daphnia magna
mg/L EC50
_____________________________________________________________________________________________
Page 6 / 9
Product Name: STAN-MASK 21651 CITRUS SWEET GRAS

_____________________________________________________________________________________________
96 h Oncorhynchus
mykiss mg/L LC50
flow-through 6.8 – 8.53:
96 h Pimephales
promelas mg/L LC50
flow-through 12.69: 96 h
Oncorhynchus mykiss
mg/L LC50 static 7.5: 96
h Lepomis macrochirus
mg/L LC50 static
Persistence and degradability No information available.
Bioaccumulation There is no data for this product.
Component Information
Chemical name Partition coefficient
BENZALDEHYDE
100-52-7
1.48
CINNAMIC ALCOHOL
104-54-1
1.9
Other adverse effects No information available.
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Waste from residues/unused
products
Dispose of in accordance with local regulations. Dispose of waste in accordance with
environmental legislation.
Contaminated packaging Do not reuse empty containers.
14. TRANSPORT INFORMATION
DOT Not regulated
IATA
UN/ID no UN1169
Proper Shipping Name EXTRACTS, AROMATIC, LIQUID
Hazard Class 3
Packing group III
ERG Code 3L
Description UN1169, EXTRACTS, AROMATIC, LIQUID, 3, III
IMDG
UN/ID no UN1169
Proper Shipping Name EXTRACTS, AROMATIC, LIQUID
Hazard Class 3
Packing group III
_____________________________________________________________________________________________
Page 7 / 9
Product Name: STAN-MASK 21651 CITRUS SWEET GRAS

_____________________________________________________________________________________________
EmS No. F-E, S-D
Special Provisions 223, 955
Marine pollutant This product contains a chemical which is listed as a marine pollutant according to
IMDG/IMO
Description UN1169, EXTRACTS, AROMATIC, LIQUID, 3, III, (51 C C.C.)
ADR
UN/ID no UN1169
Proper Shipping Name EXTRACTS, AROMATIC, LIQUID
Hazard Class 3
Packing group III
Classification code F1
Tunnel restriction code D/E
Special Provisions 601, 640E
Description UN1169, EXTRACTS, AROMATIC, LIQUID, 3, III
ADR/RID-Labels 3
15. REGULATORY INFORMATION
International Inventories
TSCA Complies
DSL/NDSL Complies
EINECS/ELINCS Complies
ENCS Complies
IECSC Complies
KECL Complies
PICCS Complies
NZIoC Complies
AICS Complies
Legend: TSCA – United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL – Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS – European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS – Japan Existing and New Chemical Substances
IECSC – China Inventory of Existing Chemical Substances
KECL – Korean Existing and Evaluated Chemical Substances
PICCS – Philippines Inventory of Chemicals and Chemical Substances
NZIoC – New Zealand Inventory of Chemicals
AICS – Australian Inventory of Chemical Substances
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.
SARA 311/312 Hazard Categories
Acute health hazard Yes
Chronic Health Hazard Yes
Fire hazard Yes
Sudden release of pressure hazard No
Reactive Hazard No
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42).
_____________________________________________________________________________________________
Page 8 / 9
Product Name: STAN-MASK 21651 CITRUS SWEET GRAS

_____________________________________________________________________________________________
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material.
US State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations
US State Regulations This product does not contain any substances regulated by state right-to-know regulations
Chemical name New Jersey Massachusetts Pennsylvania
BENZALDEHYDE
100-52-7
X X X
ETHYL BENZOATE
93-89-0
– – X
U.S. EPA Label Information
EPA Pesticide Registration NumberNot applicable
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION
Issue Date:
Revision Date:
Version #:
07-22-2015
08-03-2017
02
Disclaimer: The information and recommendations contained herein are based upon data that are believed to be accurate
and reliable. Application and performance information are provided only as a guide, since the conditions of use are
beyond the control of Harwick Standard Distribution Corporation. Consequently, Harwick Standard makes no warranties,
express or implied, with respect to the goods or use of the goods or the performance of the goods and makes no
warranties of fitness for a particular purpose or merchantability. Buyer acknowledges that Harwick Standard will not be
liable for consequential, incidental, direct or special damages arising, directly or indirectly, in respect to such goods or
the use or failure thereof, whether based on breach of warranty, negligence, strict liability in tort or otherwise.
End of Safety Data Sheet
NFPA Health hazards 2 Flammability 2 Instability 0 Physical and chemical
properties –
HMIS Health hazards 2 Flammability 2 Physical hazards 0 Personal protection X
_____________________________________________________________________________________________
Page 9 / 9
Product Name: STAN-MASK 21651 CITRUS SWEET GRAS

3921651C-F_SDS.pdf

by | Sep 27, 2025

SAFETY DATA SHEET
STAN-MASK 21651 CITRUS SWEET GRAS
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product identifier
Product Name STAN-MASK 21651 CITRUS SWEET GRAS
Other means of identification
CAS No Mixture
Synonyms None
Recommended use of the chemical and restrictions on use
Recommended Use Fragrances
Uses advised against No information available
Details of the supplier of the safety data sheet
Manufactured for and Supplied by Harwick Standard Distribution Corporation
P.O. Box 9360
60 S. Seiberling Street
Akron, OH 44305 USA
(330) 798-9300
www.harwickstandard.com
2. HAZARDS IDENTIFICATION
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Skin corrosion/irritation – Category 2
Skin sensitization – Category 1B
Aspiration toxicity – Category 1
Label elements Physical hazards – Flammable liquids – Category 3
Signal word – Danger
Hazard statements
Causes skin irritation
May cause an allergic skin reaction
May be fatal if swallowed and enters airways
_____________________________________________________________________________________________
Page 1 / 9
Product Name: STAN-MASK 21651 CITRUS SWEET GRAS
Flammable liquid and vapor

_____________________________________________________________________________________________
Precautionary Statements
Wash face, hands and any exposed skin thoroughly after handling
Avoid breathing dust/fume/gas/mist/vapors/spray
Contaminated work clothing must not be allowed out of the workplace
Keep away from heat/sparks/open flames/hot surfaces. – No smoking
Keep container tightly closed
Ground/bond container and receiving equipment
Use explosion-proof electrical/ ventilating / lighting/ .? / equipment
Use only non-sparking tools
Take precautionary measures against static discharge
Wear protective gloves/eye protection/face protection
Specific treatment (see .? on this label)
If skin irritation or rash occurs: Get medical advice/attention
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower
Wash contaminated clothing before reuse
IF SWALLOWED: Immediately call a POISON CENTER or doctor
Do NOT induce vomiting
In case of fire: Use CO2, dry chemical, or foam to extinguish
Precautionary Statements – Storage
Store locked up
Store in a well-ventilated place. Keep cool
Precautionary Statements – Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Not applicable Other Information
May be harmful if swallowed May be harmful in contact with skin Toxic to aquatic life with long lasting effects Toxic to aquatic life Unknown acute toxicity 1.9 % of the mixture consists of ingredient(s) of unknown toxicity
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance
Chemical name CAS No Weight-% Trade secret
ORANGE TERPENES 68647-72-3 80 – 90 *
BENZALDEHYDE 100-52-7 1 – 10 *
ANETHOLE 4180-23-8 1 – 10 *
CINNAMIC ALCOHOL 104-54-1 1 – 10 *
ALDEHYDE C-12 LAURIC 112-54-9 <1 * Appearanceclear liquid Physical State @20 C liquid Odor Characteristic _____________________________________________________________________________________________ Page 2 / 9 Product Name: STAN-MASK 21651 CITRUS SWEET GRAS _____________________________________________________________________________________________ *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures Inhalation Remove to fresh air. Eye contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician. Skin contact Wash skin with soap and water. Ingestion Clean mouth with water and drink afterwards plenty of water. Most important symptoms and effects, both acute and delayed Symptoms No information available. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use ex tinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media CAUTION: Use of water spray when fighting fire may be inefficient. Specific hazards arising from the chemical No information available. Explosion data Sensitivity to Mechanical ImpactNone. Sensitivity to Static DischargeNone. Special protective equipment for fire-fighters Firefighters should wear self-contained breathing apparatus and full firefighting turnout gear. Use personal protection equipment. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation. Environmental precautions Environmental precautions See Section 12 for additional Ecological Information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Pick up and transfer to properly labeled containers. _____________________________________________________________________________________________ Page 3 / 9 Product Name: STAN-MASK 21651 CITRUS SWEET GRAS _____________________________________________________________________________________________ Prevention of secondary hazardsClean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Limits The following ingredients are the only ingredients of the product above the cut-off level (or level that contributes to the hazard classification of the mixture) which have an exposure limit applicable in the region for which this safety data sheet is intended or other recommended limit. At this time, the other relevant constituents have no known exposure limits from the sources listed here. Appropriate engineering controls Engineering controls Showers Eyewash stations Ventilation systems. Individual protection measures, such as personal protective equipment Eye/face protection No special protective equipment required. Skin and body protection No special protective equipment required. Respiratory protection No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required. General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State @20 C liquid Appearance clear liquid Odor Characteristic Color Colorless - Pale Yellow Odor threshold No information available _____________________________________________________________________________________________ Page 4 / 9 Product Name: STAN-MASK 21651 CITRUS SWEET GRAS _____________________________________________________________________________________________ Specific gravity 0.8590-0.8790 Refractive Index 1.4740-1.4940 Explosive properties No information available Oxidizing properties No information available Softening point No information available Molecular weight No information available VOC Content (%) No information available Density VALUE No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity No information av ailable. Chemical stability Stable under normal conditions. Possibility of hazardous reactionsNone under normal processing. Conditions to avoid None known based on information supplied. Incompatible materials None known based on information supplied. Hazardous decomposition productsNone known based on information supplied. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Inhalation Specific test data for the substance or mixture is not available. Eye contact Specific test data for the substance or mixture is not available. Skin contact Specific test data for the substance or mixture is not available. Property Values pH No data available Melting point / freezing point No data available Boiling point / boiling range > 35 C / 95 F
Flash point 51 C / 124 F
Evaporation rate No data available
Flammability (solid, gas) No data available
Flammability Limit in Air
Upper flammability limit: No data available
Lower flammability limit: No data available
Vapor pressure No data available
Vapor density No data available
Relative density No data available
Water solubility No data available
Solubility in other solvents No data available
Partition coefficient No data available
Autoignition temperature No data available
Decomposition temperature No data available
Kinematic viscosity No data available
Dynamic viscosity
_____________________________________________________________________________________________
Page 5 / 9
Product Name: STAN-MASK 21651 CITRUS SWEET GRAS
No data available

_____________________________________________________________________________________________
Ingestion Specific test data for the substance or mixture is not available.
Information on toxicological effects
Symptoms No information available.
Numerical measures of toxicity
Acute toxicity
The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral) 4,266.00 mg/kg
ATEmix (dermal) 4,280.00 mg/kg mg/l
ATEmix (inhalation-dust/mist)33.30 mg/l
ATEmix (inhalation-vapor) 244.00 mg/l
Unknown acute toxicity 1.9 % of the mixture consists of ingredient(s) of unknown toxicity
Component Information
Chemical name Oral LD50 LD50/dermal/rat – NO UNITS
(Wizards mg/kg)
Inhalation LC50
BENZALDEHYDE
100-52-7
= 1292 mg/kg ( Rat ) > 1250 mg/kg ( Rabbit ) –
ANETHOLE
4180-23-8
= 2090 mg/kg ( Rat ) – –
CINNAMIC ALCOHOL
104-54-1
= 2 g/kg ( Rat ) > 5 g/kg ( Rabbit ) –
ALDEHYDE C-12 LAURIC
112-54-9
= 23 g/kg ( Rat ) – –
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Skin corrosion/irritation No information available.
Serious eye damage/eye irritationNo information available.
Respiratory or skin sensitizationNo information available.
Germ cell mutagenicity No information available.
Carcinogenicity No information available.
Reproductive toxicity No information available.
STOT – single exposure No information available.
STOT – repeated exposure No information available.
Aspiration hazard No information available.
12. ECOLOGICAL INFORMATION
Ecotoxicity The env
ironmental impact of this product has not been fully investigated.Chemical name Algae/aquatic plants Fish Toxicity to
microorganisms
Crustacea
BENZALDEHYDE
100-52-7
– 0.8 – 1.44: 96 h Lepomis
macrochirus mg/L LC50
flow-through 10.6 – 11.8:
– 50: 24 h Daphnia magna
mg/L EC50
_____________________________________________________________________________________________
Page 6 / 9
Product Name: STAN-MASK 21651 CITRUS SWEET GRAS

_____________________________________________________________________________________________
96 h Oncorhynchus
mykiss mg/L LC50
flow-through 6.8 – 8.53:
96 h Pimephales
promelas mg/L LC50
flow-through 12.69: 96 h
Oncorhynchus mykiss
mg/L LC50 static 7.5: 96
h Lepomis macrochirus
mg/L LC50 static
Persistence and degradability No information available.
Bioaccumulation There is no data for this product.
Component Information
Chemical name Partition coefficient
BENZALDEHYDE
100-52-7
1.48
CINNAMIC ALCOHOL
104-54-1
1.9
Other adverse effects No information available.
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Waste from residues/unused
products
Dispose of in accordance with local regulations. Dispose of waste in accordance with
environmental legislation.
Contaminated packaging Do not reuse empty containers.
14. TRANSPORT INFORMATION
DOT Not regulated
IATA
UN/ID no UN1169
Proper Shipping Name EXTRACTS, AROMATIC, LIQUID
Hazard Class 3
Packing group III
ERG Code 3L
Description UN1169, EXTRACTS, AROMATIC, LIQUID, 3, III
IMDG
UN/ID no UN1169
Proper Shipping Name EXTRACTS, AROMATIC, LIQUID
Hazard Class 3
Packing group III
_____________________________________________________________________________________________
Page 7 / 9
Product Name: STAN-MASK 21651 CITRUS SWEET GRAS

_____________________________________________________________________________________________
EmS No. F-E, S-D
Special Provisions 223, 955
Marine pollutant This product contains a chemical which is listed as a marine pollutant according to
IMDG/IMO
Description UN1169, EXTRACTS, AROMATIC, LIQUID, 3, III, (51 C C.C.)
ADR
UN/ID no UN1169
Proper Shipping Name EXTRACTS, AROMATIC, LIQUID
Hazard Class 3
Packing group III
Classification code F1
Tunnel restriction code D/E
Special Provisions 601, 640E
Description UN1169, EXTRACTS, AROMATIC, LIQUID, 3, III
ADR/RID-Labels 3
15. REGULATORY INFORMATION
International Inventories
TSCA Complies
DSL/NDSL Complies
EINECS/ELINCS Complies
ENCS Complies
IECSC Complies
KECL Complies
PICCS Complies
NZIoC Complies
AICS Complies
Legend: TSCA – United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL – Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS – European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS – Japan Existing and New Chemical Substances
IECSC – China Inventory of Existing Chemical Substances
KECL – Korean Existing and Evaluated Chemical Substances
PICCS – Philippines Inventory of Chemicals and Chemical Substances
NZIoC – New Zealand Inventory of Chemicals
AICS – Australian Inventory of Chemical Substances
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.
SARA 311/312 Hazard Categories
Acute health hazard Yes
Chronic Health Hazard Yes
Fire hazard Yes
Sudden release of pressure hazard No
Reactive Hazard No
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42).
_____________________________________________________________________________________________
Page 8 / 9
Product Name: STAN-MASK 21651 CITRUS SWEET GRAS

_____________________________________________________________________________________________
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material.
US State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations
US State Regulations This product does not contain any substances regulated by state right-to-know regulations
Chemical name New Jersey Massachusetts Pennsylvania
BENZALDEHYDE
100-52-7
X X X
ETHYL BENZOATE
93-89-0
– – X
U.S. EPA Label Information
EPA Pesticide Registration NumberNot applicable
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION
Issue Date:
Revision Date:
Version #:
07-22-2015
08-03-2017
02
Disclaimer: The information and recommendations contained herein are based upon data that are believed to be accurate
and reliable. Application and performance information are provided only as a guide, since the conditions of use are
beyond the control of Harwick Standard Distribution Corporation. Consequently, Harwick Standard makes no warranties,
express or implied, with respect to the goods or use of the goods or the performance of the goods and makes no
warranties of fitness for a particular purpose or merchantability. Buyer acknowledges that Harwick Standard will not be
liable for consequential, incidental, direct or special damages arising, directly or indirectly, in respect to such goods or
the use or failure thereof, whether based on breach of warranty, negligence, strict liability in tort or otherwise.
End of Safety Data Sheet
NFPA Health hazards 2 Flammability 2 Instability 0 Physical and chemical
properties –
HMIS Health hazards 2 Flammability 2 Physical hazards 0 Personal protection X
_____________________________________________________________________________________________
Page 9 / 9
Product Name: STAN-MASK 21651 CITRUS SWEET GRAS

3921600F_SDS.pdf

by | Sep 27, 2025

HARWICK
STANDARD
SAFETY DATA SHEET
STAN.MASK 21600 LEMON
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product identifier
Product Name STAN-MASK 21600 LEMON
Other means of identification
Recommendqd USe of thlr chemical and restrictions on use
Recommended Use Fragrances
Uses advised against No information available
Details of the supplier of the safety data sheet
CAS No
Synonyms
Manufacturered for and Supplied by:
Mixture
None
Harwick Standard Distribution Corporation
P.O. Box 9360
60 S. Seiberling Street Akron, OH 44305 USA
(330) 798-9300
vyww.ha rwi ckstand a rd. com
Classification
This chemical is considered hazardous by the 2A12 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Skin corrosion/irritation – Category 2
Serious eye damage/eye irritation – Category 24
Skin sensitizaiion – Category 1B
Aspiraiion toxicity – Category 1
Label elements
Signal word – Danger
Hazard statements
Page 1 /9
Product Name: STAN-MASK 21600 LEMON

t
I
Causes skin irritation
Causes serious eye irritation
May cause an allergic skin reaction
May be fatal if swallowed and enters airways
Appearance clear liquid Physical State @20″C liquid
Precautionary Statements
Wash face, hands and any exposed skin thoroughly after handling
Avoid bre ath i n g d usVfu me/g as/misvva pors/spray
Contaminated work clothing must not be allowed out of the workplace
Wear protective gloves/eye protection/face protection
Odor Characteristic
Specific treatment (see supplemenial first aid instructions on this label)
lF lN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
lf eye irritation persists: Get medical adviceiattention
lF ON SKIN: Wash with plenty of water and soap
Take off conlaminated clothing and wash it before reuse
lf skin irritation or rash occurs: Get medical advice/attention
lF SWALLOWED: lmmediately call a POISON CENTER or doctor
Do NOT induce vomiting
Precautionary Statements – Storage
Store locked up
Precautionary Statements – Disposal
Dispose of contents/container io an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Not applicable
Other lnformation
May be harmful if swallowed Toxic to aquatic life with long lasting effects Very toxic to aquatic life
Unknown acute toxicity 0.75645 % of the mixture consists of ingredient(s) of unknown toxicity
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance
Chemical name CAS No Weiqht-% Trade seciet
D’LIMONENE 5989-27-5 20-30
ORANGE OIL CA 8008-57-9 10 – 20
LEMON TERPENES 6891 7-33-9 10-20
CITRUS OIL 68647-72-3 1Q-20
HEXYL CIN NAMIC ALDEHYDE 1 01 -86-0 10-24
LIME TERPENES 68917-71-5 1- 10
DIHYDRO MYRCENOL 1 8479-58-B 1- l0
BENZYL BENZOATE 120-51,4 1-10
Page 2/9
Product Name: STAN-MASK 21600 LEMON

GRAPEFRUIT OIL FLORIDA 8016-20-4 1 – 10
.The
exact percentage (concentration) of composition has been withheld as a trade secret.
4, FIRST AID MEASURES
Description of first aid measures
lnhalation Remove to fresh air,
Eye contact Rinse thoroughly with plenty of water for at least
’15
minutes, lifting lower and upper eyelids.
Consult a physician.
Skin contact Wash skin with soap and water.
lngestion Clean mouth with water and drink afterwards plenty of water.
Most important symptoms and effects. both acute and delaved
Symptoms No information available
lndication of anv i iate meclical attention and soecialtreAimenf needed
Note to physicians Treat symptomatically
5.FIRE-FIGHTNGMEASURES.
Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.
CAUTION: Use of water spray when fighting fire may be inefficient.
No information available.
Unsuitable extinguishing media
Specific hazards arising from the
chemical
Explosion data
Sensitivity to Mechanical lmpact None.
Sensitivity to Static Discharge None.
Special protective equipment for Firefighters should wear self-contained breathing apparatus and full firefighting turnout
fire-fighters gear. Use personal proiection equipment.
Personal precautions, protective eou ipment a nd emerqency procedures
Personal precautions Ensure adequate ventilaiion.
Environmental precautions
Environmental precautions See Section 12 for additional Ecological lnformation.
Methods and material for containment and cleaninq up
Methods for containment Prevent further leakage or spillage if safe to do so.
ACCIDENTAL E MEAS
Page 3/9
Product Name: STAN-MASK 21600 LEMON

Methods for cleaning uP
Preverrtion of secondary hazards
Pick up and transfer to properly labeled containers.
Clean contaminated objects and areas thoroughly observing environmental regulations
7. HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling Handle in accordance with good industrial hygiene and safety practice.
Conditions for safe storage, including anv incompatibilities
Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place.
8.EXPOSUREcoNTROLS/PERSoNALPROTECTION
Control parameters
Exposure Limits
Appropriate engineerinq controls
Engineering controls
Incliviclual protection measures. Such as personal protective equipment
Eye/face protection
Skin and body protection
Respiratory protection
General hygiene considerations
The following ingredients are the only ingredients of the product above the cut-off level (or
level that contributes to the hazard classification of the mixture) which have an exposure
limit applicable in the region for which this safety data sheet is intended or other
recommended limit. At this time, the other relevant constituents have no known exposure
limits from the sources listed here.
Showers
Eyewash stations
Ventilation systems.
No special protective equipment required.
No special protective equipment required.
No protective equipment is needed under normal use conditions. lf exposure limits are
exceeded or irritation is experienced, ventilation and evacuation may be required.
Handle in accordance with good industrial hygiene and safety practice.
lnformation on basic phvsical and chemical Droperties
Physical State @20″C
liquid
Appearance clear liquld
Page 4/9
Product Name: STAN-MASK 21600 LEMON

Odor
Color
Odor threshold
Specific gravity
Refractive lndex
Propertv
pH
Meltirrg point / freezing point
Boiling point / boiling range
Flash point
Evaporation rate
Flammability {solid, gas)
Flammability Limit in Air
Upper flammability limit;
Lower flammability limit:
Vapor pressure
Vapor density
Relative density
Water solubility
Solubility in other solvents
Partition coefficient
Autoi gn ition temperature
Decom position temperature
Kinematic viscosity
Dynamic viscosity
Explosive properties
Oxidizing properties
Softening point
Molecular weight
VOC Content (%)
Density VALUE
Bulk density
Characteristic
Light Yellow – Yellow
No information available
0.8533 – 0.8733
1.4721 – 1.4921
Values
No data available
No data available
>35’C/95’F
94 “C I 202 ‘F CC (closed cup)
No data available
No data available
No data available
No data available
No data available
No data available
No data available
No data available
No daia available
No data available
No data available
No data available
No data available
No data available
No information available
No information available
No information available
No information available
No information available
No information available
No information available
10. STABILITY AND REAGTIVITY
Reactivity No information available.
Chemical stability Stable under normal conditions.
Possibility of hazardous reactions None under normal processing.
Conditions to avoid None known based on information supplied
lncompatible materials None known based on information supplied
Hazardous decomposition products None known based on information supplied
1 1 . TOXICOLOGICAL INFORM,ATION
lnformation on likelv routes of exposure
Product lnformation
lnhalation Specific test data for the substance or mixture is not available,
Page 5/9
Product Namer STAN-MASK 21600 LEMON

Eye contact Specific test data for the substance or mixture is not available.
Skin contact Specific test data for the substance or mixture is not available.
lngestion Specific test data for the substance or mixture is not available.
lnformation on toxicolooical effects
Symptoms No information available.
Numerical meas u res
_of toxicity
Acute toxicity Specific test data for the subslance or mixture are not available.
h
Skin corrosion/irritation
Serious eye damage/eye irritation
Respiratory or skin sensitization
Germ cell mutagenicity
Carcinogenicity
Reproductive toxicity
STOT – single exposure
STOT – repeated exposure
Aspiration hazard
No information available.
No information available.
No inforrnation available.
No information available.
No information available.
No information available.
No information available.
No information available.
No information available
table below indicates whether eachenhas listed an asa en
Chemical name- ACGIH IARC
OSHA
D’LIMONENF
_ 5989-27-5
Group 3
X
2.1ECOLOGtcAt-NFORMATION
Ecotoxicity
Persistence and degradability
Bioaccumulation
Other adverse effects
The environmentar impact of this product has not been fuily investigated
No information available.
There is no data for this product.
No information available.
L3.1DISPOSA CONSIDERAto
Waste treatment methods
Waste from residues/unused Dispose of in accordance with local regulations. Dispose of waste in accordance with
Page 6/9
Product Name: STAN-MASK 21600 LEMON

products
Contaminated packaging
environmental legislation.
Do not reuse empty containers.
14. TRANSPORT INFORMATION
DOT Not regulated
IATA
UN/lD no
Proper Shipping Name
Hazard Class
Packing group
ERG Code
Description
IMDG
UN/ID no
Proper Shipping Name
Hazard Class
Packing group
EmS No.
Special Provisions
Marine pollutant
Description
ADR
UN/lD no
Proper Shipping Name
Hazard Class
Packing group
Classification code
Tunnel restriction code
Special Provisions
Description
ADR/RlD.Labels
uN3062
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O S
o
ilt
9L
UN3082, Environmentally hazardous substance, tiquid, n.o.s.(D’ LIMONENE), 9, lll
uN3082
ENVIRONMENTALLY HAZARDOUS SUBSTANCE. LIQUID, N.O.S.
o
ilt
F-A, S-F
274,335
This product contains a chemical which is listed as a marine pollutant according to
IMDG/IMO
UN3082, Environmentally hazardous substance, liquid, n.o s.(D’ LIMONENE), 9, lll
UN3OB2
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIOUID, N,O S.
ilt
M6
E
274,335,601, 375
UN3082, Environmentally hazardous substance, liquid, n.o.s.(D’ LTMONENE), 9, lll
I
-:.
TORYULAREG
lnternational lnventories
TSCA
DSL/NDSL
EINECS/ELINCS
ENCS
IECSC
KECL
Ptccs
Complies
Complies
Complies
No data available
Complies
No data available
Complies
Page 7/9
Product Name: STAN-MASK 21600 LEMON

NZIoC
Atcs
TCSI
No data available
Complies
Complies
section3l3ofTitlelll oftheSuperfundAmendmentsandReauthorizationActof
1gg6(SARA). Thisproductdoesnotcontainany
chemicals which are subject to the reporting requirements of the Act and riile 40 of the code of Federal Regulations, paft372.
Legend:
TSCA – United states Toxic Substances control Act section B(b) lnventory
DSLINDSL – canadian Domestic substances LisvNon-Domestic substanies List
EINE-CS/ELINCS – European. lnventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS – Japan Existing and New Chemical Substances
IECSC – China lnventory of Existing Chemical Substances
KECL – Korean Existing and Evaluated Chemical Substances
Plccs – Philippines rnventory of chemicars and chemicar substances
NZIoC – New Zealand lnventory of Chemicals
AICS – Australian lnventory of Chemical Substances
TCSI – Taiwan Chemical Substance lnventory
US Federal Requlatigns
SARA 313
SARA 3111312 Ha.zard Categories
Acute health hazard
Chronic Health Hazard
Fire hazard
Sudden release of pressure hazard
Reactive Hazard
CWA (Clean Water Act)
This product does not contain any substances
cFR 122.42).
US State Requlations
California Proposition 6E
This product does not contain any proposition
65 chemicals.
U.S, State Riqht-to-Know Regulations
US State Regulations This product may contain substances regulated by state right-to,know regulations
U.S. EPA Label lnformation
EPA Pesticide Registration Number Not applicable
Yes
Yes
No
No
No
regulated as poilutants pursuant to the crean water Act (40 cFR 122.21 and 40
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances underthe Comprehensive
Environmental Response compensation and Liability Act (cEdcLA) (40 cFR 302) or the superfunJ Amendments and
Reaulhorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material.
Page 8/9
Product Name: STAN-MASK 21600 LEMON

1b.OTHERNFoRMATtoNINcLUDINGDATEoFPREPARATONOFTHELA.STREVIsoN
NFPA_
HMIS
lssue Date:
Version #:
Revision Note:
Health hazards 2 Flammability 0
Health hazards 2 Flammability 0
12-08-2017
0’1
No information available
lnstability 0
Physical hazards 0
Physical and chemical
properties –
Personal protection X
Disclaimer: The information and recommendations contained herein are based upon data that are believed to be accurate
and reliable. Application and performance information are provided only as a guide, since the conditions of use are
beyond the control of Harwick Standard Distribution Corporation. Consequently, Hanirick Standard makes no warranties,
express or implied, with respect to the goods or use of the goods or the performance of the goods and makes no
warranties of fitness for a particular purpose or merchantability. Buyer acknowledges that Hinrvick Standard will not be
liable for consequential,,incidental, direct or special damages arising, directly or indirectly, in respect to such goods or
the use orfailure thereof, whether based on breach of warranty, negligence, strict liability in tort or otherwise.
End of Safety Data Sheet
Page 9/9
Product Name: STAN-MASK 21600 LEMON

3921392F_SDS.pdf

by | Sep 27, 2025

SAFETY DATA SHEET
STAN-MASK 21392 BUBBLEGUM GRAS
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product identifier
Product Name STAN-MASK 21392 BUBBLEGUM GRAS
Other means of identification
CAS No Mixture
Synonyms None
Recommended use of the chemical and restrictions on use Recommended Use Fragrances
Uses advised against No information available
Details of the supplier of the safety data sheet
Manufactured for and Supplied by Harwick Standard Distribution Corporation
P.O. Box 9360
60 S. Seiberling Street
Akron, OH 44305 USA
(330) 798-9300
www.harwickstandard.com
2. HAZARDS IDENTIFICATION
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Acute toxicity – Oral – Category 4
Acute toxicity – Dermal – Category 4
Skin corrosion/irritation – Category 2
Serious eye damage/eye irritation – Category 2A
Skin sensitization – Category 1A
Aspiration toxicity – Category 1
Physical hazards – Flammable liquids – Category 3
_____________________________________________________________________________________________
Page 1 / 9
Product Name: STAN-MASK 21392 BUBBLEGUM GRAS

_____________________________________________________________________________________________
Label elements
Precautionary Statements
Wash face, hands and any exposed skin thoroughly after handling
Do not eat, drink or smoke when using this product
Avoid breathing dust/fume/gas/mist/vapors/spray
Contaminated work clothing must not be allowed out of the workplace
Keep away from heat/sparks/open flames/hot surfaces. – No smoking
Keep container tightly closed
Ground/bond container and receiving equipment
Use explosion-proof electrical/ ventilating / lighting/ .? / equipment
Use only non-sparking tools
Take precautionary measures against static discharge
Wear protective gloves/protective clothing/eye protection/face protection
Specific treatment (see supplemental first aid instructions on this label)
Specific treatment (see supplemental first aid instructions on this label)
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
Call a POISON CENTER or doctor if you feel unwell
If skin irritation or rash occurs: Get medical advice/attention
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower
Wash contaminated clothing before reuse
IF SWALLOWED: Immediately call a POISON CENTER or doctor
Do NOT induce vomiting
IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell
Rinse mouth
In case of fire: Use CO2, dry chemical, or foam to extinguish
Precautionary Statements – Storage
Store locked up
Store in a well-ventilated place. Keep cool
Precautionary Statements – Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Not applicable
Signal word – Danger
Hazard statements
Harmful if swallowed
Harmful in contact with skin
Causes skin irritation
Causes serious eye irritation
May cause an allergic skin reaction
May be fatal if swallowed and enters airways
Flammable liquid and vapor
Appearanceclear liquid Physical State @20 C liquid Odor Characteristic
_____________________________________________________________________________________________
Page 2 / 9
Product Name: STAN-MASK 21392 BUBBLEGUM GRAS

_____________________________________________________________________________________________
Other Information
Harmful to aquatic life with long lasting effects Toxic to aquatic life
Unknown acute toxicity 1.57 % of the mixture consists of ingredient(s) of unknown toxicity
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance
Chemical name CAS No Weight-% Trade secret
METHYL SALICYLATE 119-36-8 40 – 50 *
ORANGE TERPENES 68647-72-3 10 – 20 *
ETHYL BUTYRATE 105-54-4 10 – 20 *
CINNAMIC ALDEHYDE 104-55-2 1 – 10 *
ETHYL ACETATE 141-78-6 1 – 10 *
ISO AMYL ACETATE 123-92-2 1 – 10 *
VANILLIN 121-33-5 1 – 10 *
*The exact percentage (concentration) of composition has been withheld as a trade secret.
4. FIRST AID MEASURES
Description of first aid measures
Inhalation Remove to fresh air.
Eye contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids.
Consult a physician.
Skin contact Wash skin with soap and water.
Ingestion Clean mouth with water and drink afterwards plenty of water.
Most important symptoms and effects, both acute and delayed
Symptoms No information available.
Indication of any immediate medical attention and special treatment needed
Note to physicians Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable extinguishing media CAUTION: Use of water spray when fighting fire may be inefficient.
Specific hazards arising from the chemical
No information available.
Explosion data
Sensitivity to Mechanical ImpactNone.
Sensitivity to Static DischargeNone.
_____________________________________________________________________________________________
Page 3 / 9
Product Name: STAN-MASK 21392 BUBBLEGUM GRAS

_____________________________________________________________________________________________
Special protective equipment for
fire-fighters
Firefighters should wear self-contained breathing apparatus and full firefighting turnout
gear. Use personal protection equipment.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions Ensure adequate ventilation.
Environmental precautions
Environmental precautions See Section 12 for additional Ecological Information.
Methods and material for containment and cleaning up
Methods for containment Prevent further leakage or spillage if safe to do so.
Methods for cleaning up Pick up and transfer to properly labeled containers.
Prevention of secondary hazardsClean contaminated objects and areas thoroughly observing environmental regulations.
7. HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling Handle in accordance with good industrial hygiene and safety practice.
Conditions for safe storage, including any incompatibilities
Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Limits The following ingredients are the only ingredients of the product above the cut-off level (or level that contributes to the hazard classification of the mixture) which have an exposure limit applicable in the region for which this safety data sheet is intended or other recommended limit. At this time, the other relevant constituents have no known exposure limits from the sources listed here.
Chemical name ACGIH TLV OSHA PEL NIOSH IDLH
ETHYL ACETATE
141-78-6
TWA: 400 ppm TWA: 400 ppm
TWA: 1400 mg/m
3
(vacated) TWA: 400 ppm
(vacated) TWA: 1400 mg/m
3
IDLH: 2000 ppm
TWA: 400 ppm
TWA: 1400 mg/m
3
ISO AMYL ACETATE
123-92-2
STEL: 100 ppm
TWA: 50 ppm
TWA: 100 ppm
TWA: 525 mg/m
3
(vacated) TWA: 100 ppm
(vacated) TWA: 525 mg/m
3
IDLH: 1000 ppm
TWA: 100 ppm
TWA: 525 mg/m
3
_____________________________________________________________________________________________
Page 4 / 9
Product Name: STAN-MASK 21392 BUBBLEGUM GRAS
Appropriate engineering controls

_____________________________________________________________________________________________
Engineering controls Showers
Eyewash stations
Ventilation systems.
Individual protection measures, such as personal protective equipment
Eye/face protection No special protective equipment required.
Skin and body protection No special protective equipment required.
Respiratory protection No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required.
General hygiene considerations Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical State @20 C liquid
Appearance clear liquid
Odor Characteristic
Color Light Yellow – Yellow
Odor threshold No information available
Specific gravity 1.0077-1.0277
Refractive Index 1.4816-1.4916
Explosive properties No information available
Oxidizing properties No information available
Softening point No information available
Molecular weight No information available
VOC Content (%) No information available
Property Values
pH No data available
Melting point / freezing point No data available
Boiling point / boiling range > 35 C / 95 F
Flash point 35 C / 95 F
Evaporation rate No data available
Flammability (solid, gas) No data available
Flammability Limit in Air
Upper flammability limit: No data available
Lower flammability limit: No data available
Vapor pressure No data available
Vapor density No data available
Relative density No data available
Water solubility No data available
Solubility in other solvents No data available
Partition coefficient No data available
Autoignition temperature No data available
Decomposition temperature No data available
Kinematic viscosity No data available
Dynamic viscosity
_____________________________________________________________________________________________
Page 5 / 9
Product Name: STAN-MASK 21392 BUBBLEGUM GRAS
No data available

_____________________________________________________________________________________________
Density VALUE No information available
Bulk density No information available
10. STABILITY AND REACTIVITY
Reactivity No information available.
Chemical stability Stable under normal conditions.
Possibility of hazardous reactionsNone under normal processing.
Conditions to avoid None known based on information supplied.
Incompatible materials None known based on information supplied.
Hazardous decomposition productsNone known based on information supplied.
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Product Information
Inhalation Specific test data for the substance or mixture is not available.
Eye contact Specific test data for the substance or mixture is not available.
Skin contact Specific test data for the substance or mixture is not available.
Ingestion Specific test data for the substance or mixture is not available.
Information on toxicological effects
Symptoms No information available.
Numerical measures of toxicity
Acute toxicity Specific test data for the substance or mixture are not available.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Skin corrosion/irritation No information available.
Serious eye damage/eye irritationNo information available.
Respiratory or skin sensitizationNo information available.
Germ cell mutagenicity No information available.
Carcinogenicity No information available.
Reproductive toxicity No information available.
STOT – single exposure No information available.
STOT – repeated exposure No information available.
Target organ effects Respiratory system, Eyes, Skin, Central nervous system.
_____________________________________________________________________________________________
Page 6 / 9
Product Name: STAN-MASK 21392 BUBBLEGUM GRAS

_____________________________________________________________________________________________
Aspiration hazard No information available.
12. ECOLOGICAL INFORMATION
Ecotoxicity The environmental impact of this product has not been fully investigated.
Persistence and degradability No information available.
Bioaccumulation There is no data for this product.
Other adverse effects No information available.
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Waste from residues/unused
products
Dispose of in accordance with local regulations. Dispose of waste in accordance with
environmental legislation.
Contaminated packaging Do not reuse empty containers.
14. TRANSPORT INFORMATION
DOT
UN/ID no UN1169
Proper Shipping Name EXTRACTS, AROMATIC, LIQUID
Hazard Class 3
Packing group III
UN/ID no UN1169
Proper Shipping Name EXTRACTS, AROMATIC, LIQUID
Hazard Class 3
Packing group III
Description UN1169, EXTRACTS, AROMATIC, LIQUID, 3, III
UN/ID no UN1169
Proper Shipping Name EXTRACTS, AROMATIC, LIQUID
Hazard Class 3
Packing group III
UN/ID no UN1169
Proper Shipping Name EXTRACTS, AROMATIC, LIQUID
Hazard Class 3
Packing group III
_____________________________________________________________________________________________
Page 7 / 9
Product Name: STAN-MASK 21392 BUBBLEGUM GRAS

_____________________________________________________________________________________________
15. REGULATORY INFORMATION
International Inventories
TSCA Complies
DSL/NDSL Complies
EINECS/ELINCS Complies
ENCS Complies
IECSC Complies
KECL Complies
PICCS Complies
NZIoC Complies
AICS Complies
TCSI Complies
Legend:
TSCA – United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL – Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS – European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS – Japan Existing and New Chemical Substances
IECSC – China Inventory of Existing Chemical Substances
KECL – Korean Existing and Evaluated Chemical Substances
PICCS – Philippines Inventory of Chemicals and Chemical Substances
NZIoC – New Zealand Inventory of Chemicals
AICS – Australian Inventory of Chemical Substances
TCSI – Taiwan Chemical Substance Inventory
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.
SARA 311/312 Hazard Categories
Acute health hazard Yes
Chronic Health Hazard Yes
Fire hazard Yes
Sudden release of pressure hazard No
Reactive Hazard No
CWA (Clean Water Act)
This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21
and 40 CFR 122.42).
Chemical name CWA – Reportable
Quantities
CWA – Toxic PollutantsCWA – Priority PollutantsCWA – Hazardous
Substances
ISO AMYL ACETATE
123-92-2
– – – X
_____________________________________________________________________________________________
Page 8 / 9
Product Name: STAN-MASK 21392 BUBBLEGUM GRAS
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive

_____________________________________________________________________________________________
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
Chemical name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ)
ETHYL ACETATE
141-78-6
5000 lb – RQ 5000 lb final RQ
RQ 2270 kg final RQ
ISO AMYL ACETATE
123-92-2
5000 lb – RQ 5000 lb final RQ
RQ 2270 kg final RQ
US State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals.
U.S. State Right-to-Know Regulations
US State Regulations This product may contain substances regulated by state right-to-know regulations
U.S. EPA Label Information
EPA Pesticide Registration NumberNot applicable
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION
Issue Date:
Version #:
Revision Information 09-05-201701GHS Format
Disclaimer: The information and recommendations contained herein are based upon data that are believed to be accurate
and reliable. Application and performance information are provided only as a guide, since the conditions of use are
beyond the control of Harwick Standard Distribution Corporation. Consequently, Harwick Standard makes no warranties,
express or implied, with respect to the goods or use of the goods or the performance of the goods and makes no
warranties of fitness for a particular purpose or merchantability. Buyer acknowledges that Harwick Standard will not be
liable for consequential, incidental, direct or special damages arising, directly or indirectly, in respect to such goods or
the use or failure thereof, whether based on breach of warranty, negligence, strict liability in tort or otherwise.
End of Safety Data Sheet
NFPA Health hazards 2 Flammability 3 Instability 0 Physical and chemical
properties –
HMIS Health hazards 2 Flammability 3 Physical hazards 0 Personal protection X
_____________________________________________________________________________________________
Page 9 / 9
Product Name: STAN-MASK 21392 BUBBLEGUM GRAS

3916145462_SDS.pdf

by | Sep 27, 2025

Page: 1
SAFETY DATA SHEET
Revision Date: 08/31/2018
Print Date: 2/26/2019
SDS Number: R0718448
BLO butyrolactone
Trademark, Ashland or its subsidiaries, registered
in various countries
826673
Version: 1.4

1 / 20
29 CFR 1910.1200 (OSHA HazCom 2012)
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Product identifier
Trade name : BLO
butyrolactone
Trademark, Ashland or its subsidiaries, registered in
various countries

Substance name : -butyrolactone

Substance No.
EC-No. : 202-509-5

CAS-No. : 96-48-0

Relevant identified uses of the substance or mixture and uses advised against
Recommended use

: Solvent.
Intermediate.
Laboratory chemicals
Viscosity adjustors

Restrictions on use

: Cosmetics
Soluble coatings on children’s toys

Details of the supplier of the safety data
sheet
Ashland
P.O. Box 2219
Columbus, OH 43216
United States of America (USA)
+1-614-790-3333

EHSProductSafety@ashland.com

Emergency telephone number
1-800-ASHLAND (1-800-274-5263)

Regulatory Information Number
1-800-325-3751

Product Information
+1-614-790-3333

SECTION 2. HAZARDS IDENTIFICATION
GHS Classification
Acute toxicity (Oral)

: Category 4
Serious eye damage : Category 1

Page: 2
SAFETY DATA SHEET
Revision Date: 08/31/2018
Print Date: 2/26/2019
SDS Number: R0718448
BLO butyrolactone
Trademark, Ashland or its subsidiaries, registered
in various countries
826673
Version: 1.4

2 / 20

Specific target organ
systemic toxicity – single
exposure

: Category 3 (Central nervous system)
GHS label elements
Hazard pictograms

:

Signal Word

: Danger

Hazard Statements

: Harmful if swallowed.
Causes serious eye damage.
May cause drowsiness or dizziness.

Precautionary Statements

: Prevention:
Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
Wash skin thoroughly after handling.
Do not eat, drink or smoke when using this product.
Use only outdoors or in a well-ventilated area.
Wear eye protection/ face protection.
Response:
IF SWALLOWED: Call a POISON CENTER/doctor if you feel
unwell. Rinse mouth.
IF INHALED: Remove person to fresh air and keep comfortable
for breathing. Call a POISON CENTER/doctor if you feel unwell.
IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue
rinsing. Immediately call a POISON CENTER/doctor.
Storage:
Store in a well-ventilated place. Keep container tightly closed.
Store locked up.
Disposal:
Dispose of contents/ container to an approved waste disposal
plant.

Other hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture

: Substance

Page: 3
SAFETY DATA SHEET
Revision Date: 08/31/2018
Print Date: 2/26/2019
SDS Number: R0718448
BLO butyrolactone
Trademark, Ashland or its subsidiaries, registered
in various countries
826673
Version: 1.4

3 / 20

Hazardous components
Chemical name CAS-No. Classification Concentration (%)
BUTYROLACTONE 96-48-0 Acute Tox. 4; H302

Eye Dam. 1; H318

STOT SE 3; H336

99.80

SECTION 4. FIRST AID MEASURES
General advice

: Move out of dangerous area.
Consult a physician.
Show this safety data sheet to the doctor in attendance.
Do not leave the victim unattended.

If inhaled

: Move to fresh air.
Keep patient warm and at rest.
If unconscious, place in recovery position and seek medical
advice.
Consult a physician after significant exposure.

In case of skin contact

: First aid is not normally required. However, it is
recommended that exposed areas be cleaned by washing
with soap and water.

In case of eye contact

: In the case of contact with eyes, rinse immediately with plenty
of water and seek medical advice.
Continue rinsing eyes during transport to hospital.
Remove contact lenses.
Protect unharmed eye.

If swallowed

: Obtain medical attention.
Do NOT induce vomiting.
Rinse mouth with water.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.

Most important symptoms
and effects, both acute and
delayed

:
Signs and symptoms of exposure to this material through
breathing, swallowing, and/or passage of the material through
the skin may include:
effects on blood pressure

Page: 4
SAFETY DATA SHEET
Revision Date: 08/31/2018
Print Date: 2/26/2019
SDS Number: R0718448
BLO butyrolactone
Trademark, Ashland or its subsidiaries, registered
in various countries
826673
Version: 1.4

4 / 20
Harmful if swallowed.
Causes serious eye damage.
May cause drowsiness or dizziness.

Notes to physician

: No hazards which require special first aid measures.

SECTION 5. FIREFIGHTING MEASURES
Suitable extinguishing media

: Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Water spray
Foam
Carbon dioxide (CO2)
Dry chemical

Unsuitable extinguishing
media

: High volume water jet

Specific hazards during
firefighting

: If product is heated above its flash point it will produce vapors
sufficient to support combustion. Vapors are heavier than air
and may travel along the ground and be ignited by heat, pilot
lights, other flames and ignition sources at locations near the
point of release.
Do not allow run-off from fire fighting to enter drains or water
courses.

Hazardous combustion
products

: carbon dioxide and carbon monoxide
nitrogen oxides (NOx)
Hydrocarbons
toxic fumes

Specific extinguishing
methods

:

Product is compatible with standard fire-fighting agents.

Further information : Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.

Special protective equipment
for firefighters

: In the event of fire, wear self-contained breathing apparatus.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Page: 5
SAFETY DATA SHEET
Revision Date: 08/31/2018
Print Date: 2/26/2019
SDS Number: R0718448
BLO butyrolactone
Trademark, Ashland or its subsidiaries, registered
in various countries
826673
Version: 1.4

5 / 20
Personal precautions,
protective equipment and
emergency procedures

: Use personal protective equipment.
Ensure adequate ventilation.
Persons not wearing protective equipment should be excluded
from area of spill until clean-up has been completed.

Environmental precautions

: Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.

Methods and materials for
containment and cleaning up

: Soak up with inert absorbent material (e.g. sand, silica gel,
acid binder, universal binder, sawdust).
Keep in suitable, closed containers for disposal.

Other information

: Comply with all applicable federal, state, and local regulations.

SECTION 7. HANDLING AND STORAGE
Advice on safe handling

: Avoid formation of aerosol.
Provide sufficient air exchange and/or exhaust in work rooms.
Do not breathe vapours/dust.
Do not smoke.
Container hazardous when empty.
Avoid exposure – obtain special instructions before use.
Avoid contact with skin and eyes.
Smoking, eating and drinking should be prohibited in the
application area.
For personal protection see section 8.
Dispose of rinse water in accordance with local and national
regulations.

Conditions for safe storage

: Keep container tightly closed in a dry and well-ventilated
place.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.
Observe label precautions.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
Contains no substances with occupational exposure limit values.

Hazardous components without workplace control parameters

Page: 6
SAFETY DATA SHEET
Revision Date: 08/31/2018
Print Date: 2/26/2019
SDS Number: R0718448
BLO butyrolactone
Trademark, Ashland or its subsidiaries, registered
in various countries
826673
Version: 1.4

6 / 20
Components CAS-No.
BUTYROLACTONE 96-48-0
Engineering measures : Provide sufficient mechanical (general and/or local exhaust)
ventilation to maintain exposure below exposure guidelines (if
applicable) or below levels that cause known, suspected or
apparent adverse effects.

Personal protective equipment
Respiratory protection : In the case of vapour formation use a respirator with an
approved filter within the capabilities of the respirator/filter
combination.
Where concentrations are above recommended limits or are
unknown, or a cartridge type respirator is not adequate, wear
a positive-pressure supplied-air respirator.

Hand protection
Material : butyl-rubber
Break through time : 480 min
Glove thickness : > 0.5 mm

Remarks : The exact break through time can be obtained from the
protective glove producer and this has to be observed. Gloves
should be discarded and replaced if there is any indication of
degradation or chemical breakthrough.

Eye protection : Wear chemical splash goggles and face shield when there is
potential for exposure of the eyes or face to liquid, vapor or
mist.
Maintain eye wash station in immediate work area.

Skin and body protection : Wear as appropriate:
Impervious clothing
Safety shoes
Choose body protection according to the amount and
concentration of the dangerous substance at the work place.
Wear resistant gloves (consult your safety equipment
supplier).

Hygiene measures : Wash hands before breaks and at the end of workday.
When using do not eat or drink.
When using do not smoke.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state : liquid

Page: 7
SAFETY DATA SHEET
Revision Date: 08/31/2018
Print Date: 2/26/2019
SDS Number: R0718448
BLO butyrolactone
Trademark, Ashland or its subsidiaries, registered
in various countries
826673
Version: 1.4

7 / 20

Colour

: clear

Odour

: mild

Odour Threshold

: No data available

pH

: 4.5
Concentration: 10 %

Melting point/freezing point

: -47 – -44 F / -44 – -42 C

Boiling point/boiling range

: 400.3 F / 204.6 C

Flash point

: 106 C
Evaporation rate

: No data available

Flammability (solid, gas)

: No data available

Upper explosion limit

: No data available
Lower explosion limit

: No data available
Vapour pressure

: 0.344 hPa (20 C)

Relative vapour density

: No data available

Relative density

: No data available

Density

: 1.124 g/cm3 (25 C)

Solubility(ies)
Water solubility

: completely miscible

Solubility in other solvents

: No data available

Partition coefficient: n-
octanol/water

: log Pow: -0.566

Thermal decomposition

: No data available

Viscosity
Viscosity, dynamic : 2 mPa.s (20 C)

Page: 8
SAFETY DATA SHEET
Revision Date: 08/31/2018
Print Date: 2/26/2019
SDS Number: R0718448
BLO butyrolactone
Trademark, Ashland or its subsidiaries, registered
in various countries
826673
Version: 1.4

8 / 20

Viscosity, kinematic

: No data available

Oxidizing properties

: No data available
SECTION 10. STABILITY AND REACTIVITY
Reactivity

: No decomposition if stored and applied as directed.

Chemical stability

: Stable under recommended storage conditions.

Possibility of hazardous
reactions

: Product will not undergo hazardous polymerization.

Incompatible materials

: Strong oxidizing agents

Hazardous decomposition
products

carbon dioxide and carbon monoxide
Hydrocarbons
Nitrogen oxides (NOx)

SECTION 11. TOXICOLOGICAL INFORMATION
Information on likely routes of
exposure
: Inhalation
Skin contact
Eye Contact
Ingestion

Acute toxicity
Harmful if swallowed.
Product:
Acute oral toxicity

: LD50 (Rat): 1,582 mg/kg

Acute inhalation toxicity

: LC50 (Rat): > 5.1 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist

Acute dermal toxicity

: LD50 (Guinea pig): > 5 g/kg

Components:
BUTYROLACTONE :
Acute oral toxicity : LD50 (Rat): 1,582 mg/kg

Page: 9
SAFETY DATA SHEET
Revision Date: 08/31/2018
Print Date: 2/26/2019
SDS Number: R0718448
BLO butyrolactone
Trademark, Ashland or its subsidiaries, registered
in various countries
826673
Version: 1.4

9 / 20

Acute inhalation toxicity

: LC50 (Rat): > 5.1 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist

Acute dermal toxicity

: LD50 (Guinea pig): > 5 g/kg

Skin corrosion/irritation
Not classified based on available information.
Product:
Result: No skin irritation

Components:
BUTYROLACTONE :
Result: No skin irritation

Serious eye damage/eye irritation
Causes serious eye damage.
Product:
Remarks: May cause irreversible eye damage.

Result: Corrosive

Components:
BUTYROLACTONE :
Result: Corrosive

Respiratory or skin sensitisation
Skin sensitisation: Not classified based on available information.
Respiratory sensitisation: Not classified based on available information.
Product:
Test Type: Local lymph node assay
Species: Mouse
Assessment: Does not cause skin sensitisation.
Result: negative

Components:
BUTYROLACTONE :
Test Type: Local lymph node assay
Species: Mouse
Assessment: Does not cause skin sensitisation.
Result: negative

Germ cell mutagenicity
Not classified based on available information.

Page: 10
SAFETY DATA SHEET
Revision Date: 08/31/2018
Print Date: 2/26/2019
SDS Number: R0718448
BLO butyrolactone
Trademark, Ashland or its subsidiaries, registered
in various countries
826673
Version: 1.4

10 / 20
Product:
Genotoxicity in vitro

: Test Type: Ames test
Result: negative

: Test Type: Chromosome aberration test in vitro
Result: negative

Genotoxicity in vivo

: Test Type: In vivo micronucleus test
Test species: Mouse
Result: negative

Components:
BUTYROLACTONE :
Genotoxicity in vitro

: Test Type: Ames test
Result: negative

: Test Type: Chromosome aberration test in vitro
Result: negative

Genotoxicity in vivo

: Test Type: In vivo micronucleus test
Test species: Mouse
Result: negative

Carcinogenicity
Not classified based on available information.
Product:
Species: Rat, (male)
Application Route: Oral
NOAEL: 225 mg/kg bw/day
Result: negative
Target Organs: No specific target organs noted
GLP: yes
Remarks: No significant adverse effects were reported

Species: Rat, (female)
Application Route: Oral
NOAEL: 225 mg/kg bw/day
Result: negative
Target Organs: No specific target organs noted
GLP: yes
Remarks: Significant toxicity observed in testing

Species: Mouse, (male and female)
Application Route: Oral
NOAEL: 262 mg/kg bw/day
Result: negative
Target Organs: No specific target organs noted

Page: 11
SAFETY DATA SHEET
Revision Date: 08/31/2018
Print Date: 2/26/2019
SDS Number: R0718448
BLO butyrolactone
Trademark, Ashland or its subsidiaries, registered
in various countries
826673
Version: 1.4

11 / 20
GLP: yes
Remarks: Significant toxicity observed in testing

Components:
BUTYROLACTONE :
Species: Rat, (male)
Application Route: Oral
NOAEL: 225 mg/kg bw/day
Result: negative
Target Organs: No specific target organs noted
GLP: yes
Remarks: No significant adverse effects were reported

Species: Rat, (female)
Application Route: Oral
NOAEL: 225 mg/kg bw/day
Result: negative
Target Organs: No specific target organs noted
GLP: yes
Remarks: Significant toxicity observed in testing

Species: Mouse, (male and female)
Application Route: Oral
NOAEL: 262 mg/kg bw/day
Result: negative
Target Organs: No specific target organs noted
GLP: yes
Remarks: Significant toxicity observed in testing

Reproductive toxicity
Not classified based on available information.
Product:
Effects on foetal
development

: Species: Rat, male and female
Strain: Sprague-Dawley
Application Route: Oral
Dose: 0,10,50,125,500 mg/kg bw/day
Duration of Single Treatment: 21 d
General Toxicity Maternal: 500 mg/kg bw/day
Teratogenicity: 500 mg/kg bw/day
Result: No teratogenic effects
GLP: no
Remarks: No significant adverse effects were reported

Components:
BUTYROLACTONE :
Effects on foetal
development
: Species: Rat, male and female
Strain: Sprague-Dawley

Page: 12
SAFETY DATA SHEET
Revision Date: 08/31/2018
Print Date: 2/26/2019
SDS Number: R0718448
BLO butyrolactone
Trademark, Ashland or its subsidiaries, registered
in various countries
826673
Version: 1.4

12 / 20
Application Route: Oral
Dose: 0,10,50,125,500 mg/kg bw/day
Duration of Single Treatment: 21 d
General Toxicity Maternal: 500 mg/kg bw/day
Teratogenicity: 500 mg/kg bw/day
Result: No teratogenic effects
GLP: no
Remarks: No significant adverse effects were reported

STOT – single exposure
May cause drowsiness or dizziness.
Components:
BUTYROLACTONE :
Exposure routes: Inhalation
Assessment: The substance or mixture is classified as specific target organ toxicant, single
exposure, category 3 with narcotic effects.

STOT – repeated exposure
Not classified based on available information.
Repeated dose toxicity
Product:
Species: Rat, male
NOAEL: 225 mg/kg
Application Route: Oral
Exposure time: CUST-N11.00322330
Method: Gavage
GLP: yes
Target Organs: No specific target organs noted

Species: Rat, female
NOAEL: 450 mg/kg
Application Route: Oral
Exposure time: CUST-N11.00322330
Method: Gavage
GLP: yes
Target Organs: No specific target organs noted

Species: Mouse, male and female
NOAEL: 525 mg/kg
Application Route: Oral
Exposure time: CUST-N11.00322330
Method: Gavage
GLP: yes
Target Organs: No specific target organs noted

Components:
BUTYROLACTONE :

Page: 13
SAFETY DATA SHEET
Revision Date: 08/31/2018
Print Date: 2/26/2019
SDS Number: R0718448
BLO butyrolactone
Trademark, Ashland or its subsidiaries, registered
in various countries
826673
Version: 1.4

13 / 20
Species: Rat, male
NOAEL: 225 mg/kg
Application Route: Oral
Exposure time: CUST-N11.00322330
Method: Gavage
GLP: yes
Target Organs: No specific target organs noted

Species: Rat, female
NOAEL: 450 mg/kg
Application Route: Oral
Exposure time: CUST-N11.00322330
Method: Gavage
GLP: yes
Target Organs: No specific target organs noted

Species: Mouse, male and female
NOAEL: 525 mg/kg
Application Route: Oral
Exposure time: CUST-N11.00322330
Method: Gavage
GLP: yes
Target Organs: No specific target organs noted

Aspiration toxicity
Not classified based on available information.
Further information
Product:
Remarks: Symptoms of overexposure may be headache, dizziness, tiredness, nausea and
vomiting., Concentrations substantially above the TLV value may cause narcotic effects.,
Solvents may degrease the skin.

Carcinogenicity:
IARC

No component of this product present at levels greater than or
equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.

OSHA

No component of this product present at levels greater than or
equal to 0.1% is on OSHA s list of regulated carcinogens.

NTP

No component of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.

Page: 14
SAFETY DATA SHEET
Revision Date: 08/31/2018
Print Date: 2/26/2019
SDS Number: R0718448
BLO butyrolactone
Trademark, Ashland or its subsidiaries, registered
in various countries
826673
Version: 1.4

14 / 20
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Product:
Toxicity to fish

: LC50 (Lepomis macrochirus (Bluegill sunfish)): 56 mg/l
Exposure time: 96 h
Test Type: static test

Toxicity to daphnia and other
aquatic invertebrates

: EC50 (Daphnia magna (Water flea)): > 500 mg/l
Exposure time: 48 h

Toxicity to algae

: ErC50 (Desmodesmus subspicatus (green algae)): > 1,000
mg/l

EC10 (Desmodesmus subspicatus (green algae)): 84.4 mg/l

Toxicity to bacteria

: IC50 (Ciliate (Tetrahymena pyriformis)): 4,518 mg/l

Ecotoxicology Assessment
Short-term (acute) aquatic
hazard

: Acute aquatic toxicity Category 3; Harmful to aquatic life.

Long-term (chronic) aquatic
hazard

: Not classified based on available information.

Components:
BUTYROLACTONE :
Toxicity to fish

: LC50 (Lepomis macrochirus (Bluegill sunfish)): 56 mg/l
Exposure time: 96 h
Test Type: static test

Toxicity to daphnia and other
aquatic invertebrates

: EC50 (Daphnia magna (Water flea)): > 500 mg/l
Exposure time: 48 h

Toxicity to algae

: ErC50 (Desmodesmus subspicatus (green algae)): > 1,000
mg/l

EC10 (Desmodesmus subspicatus (green algae)): 84.4 mg/l

Toxicity to bacteria

: IC50 (Ciliate (Tetrahymena pyriformis)): 4,518 mg/l

Persistence and degradability
Product:
Biodegradability

: Result: Readily biodegradable.
Biodegradation: 95 %
Exposure time: 14 d

Page: 15
SAFETY DATA SHEET
Revision Date: 08/31/2018
Print Date: 2/26/2019
SDS Number: R0718448
BLO butyrolactone
Trademark, Ashland or its subsidiaries, registered
in various countries
826673
Version: 1.4

15 / 20

Components:
BUTYROLACTONE :
Biodegradability

: Result: Readily biodegradable.
Biodegradation: 95 %
Exposure time: 14 d

No data available
Bioaccumulative potential
Components:
BUTYROLACTONE :
Partition coefficient: n-
octanol/water

: log Pow: -0.566 (25 C)

No data available
Mobility in soil
Components:
No data available
Other adverse effects
Product:
Additional ecological
information

: An environmental hazard cannot be excluded in the event of
unprofessional handling or disposal., Harmful to aquatic life.
Components:
BUTYROLACTONE :
Results of PBT and vPvB
assessment

: This substance is not considered to be persistent,
bioaccumulating and toxic (PBT). This substance is not
considered to be very persistent and very bioaccumulating
(vPvB).

SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
General advice : The product should not be allowed to enter drains, water
courses or the soil.
Do not contaminate ponds, waterways or ditches with
chemical or used container.
Send to a licensed waste management company.

Dispose of in accordance with all applicable local, state and
federal regulations.

Contaminated packaging : Empty remaining contents.
Dispose of as unused product.
Empty containers should be taken to an approved waste

Page: 16
SAFETY DATA SHEET
Revision Date: 08/31/2018
Print Date: 2/26/2019
SDS Number: R0718448
BLO butyrolactone
Trademark, Ashland or its subsidiaries, registered
in various countries
826673
Version: 1.4

16 / 20
handling site for recycling or disposal.
Do not re-use empty containers.

SECTION 14. TRANSPORT INFORMATION
International transport regulations
REGULATION
ID NUMBER PROPER SHIPPING NAME *HAZARD
CLASS
SUBSIDIARY
HAZARDS
PACKING
GROUP
MARINE
POLLUTANT /
LTD. QTY.

MX_DG
Not dangerous goods

INTERNATIONAL AIR TRANSPORT ASSOCIATION – PASSENGER
Not dangerous goods

INTERNATIONAL AIR TRANSPORT ASSOCIATION – CARGO
Not dangerous goods

INTERNATIONAL MARITIME DANGEROUS GOODS
Not dangerous goods

TDG_INWT_C
Not dangerous goods

TDG_RAIL_C
Not dangerous goods

TDG_ROAD_C
Not dangerous goods

U.S. DOT – INLAND WATERWAYS
Not dangerous goods

CFR_RAIL_C

Page: 17
SAFETY DATA SHEET
Revision Date: 08/31/2018
Print Date: 2/26/2019
SDS Number: R0718448
BLO butyrolactone
Trademark, Ashland or its subsidiaries, registered
in various countries
826673
Version: 1.4

17 / 20
Not dangerous goods

U.S. DOT – ROAD
Not dangerous goods

*ORM = ORM-D, CBL = COMBUSTIBLE LIQUID

Marine pollutant no

Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific
exceptions that can be applied. Consult shipping documents for descriptions that are specific to the
shipment.

SECTION 15. REGULATORY INFORMATION
EPCRA – Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity
This material does not contain any components with a CERCLA RQ.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.

SARA 311/312 Hazards

: Acute toxicity (any route of exposure)
Serious eye damage or eye irritation
Specific target organ toxicity (single or repeated exposure)

SARA 302

: This material does not contain any components with a section
302 EHS TPQ.

SARA 313 This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.
Pennsylvania Right To Know
BUTYROLACTONE

96-48-0
New Jersey Right To Know
BUTYROLACTONE

96-48-0

California Prop. 65
This product does not contain any chemicals known to State of California to cause cancer, birth
defects, or any other reproductive harm.
The components of this product are reported in the following inventories:

Page: 18
SAFETY DATA SHEET
Revision Date: 08/31/2018
Print Date: 2/26/2019
SDS Number: R0718448
BLO butyrolactone
Trademark, Ashland or its subsidiaries, registered
in various countries
826673
Version: 1.4

18 / 20
DSL

: All components of this product are on the Canadian DSL

AICS

: On the inventory, or in compliance with the inventory

ENCS

: On the inventory, or in compliance with the inventory

KECI

: On the inventory, or in compliance with the inventory

PICCS

: On the inventory, or in compliance with the inventory

IECSC

: On the inventory, or in compliance with the inventory

TSCA

: For Cosmetic Use Only

Inventories
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL
(Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA)

SECTION 16. OTHER INFORMATION
Further information
Revision Date: 08/31/2018

NFPA: HMIS III:

NFPA Flammable and Combustible Liquids Classification
Combustible Liquid Class IIIB

Full text of H-Statements
H302 Harmful if swallowed.
Flammability

Health

Instability

3
1

0

FLAMMABILITY
PHYSICAL HAZARD
HEALTH
1

0

3/

Special hazard.
0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic

Page: 19
SAFETY DATA SHEET
Revision Date: 08/31/2018
Print Date: 2/26/2019
SDS Number: R0718448
BLO butyrolactone
Trademark, Ashland or its subsidiaries, registered
in various countries
826673
Version: 1.4

19 / 20
H318 Causes serious eye damage.
H336 May cause drowsiness or dizziness.

Further information

Exposure scenario : http://www.ashland.com/file_source/Ashland/About/Document
s/R0718448_Annex_EN.pdf

Sources of key data used to compile the Safety Data Sheet
Ashland internal data including own and sponsored test reports
The UNECE administers regional agreements implementing harmonised classification for
labelling (GHS) and transport.

The information accumulated herein is believed to be accurate but is not warranted to be whether
originating with the company or not. Recipients are advised to confirm in advance of need that the
information is current, applicable, and suitable to their circumstances. This SDS has been
prepared by Ashland’s Environmental Health and Safety Department (1-800-325-3751).

Full text of other abbreviations
AICS – Australian Inventory of Chemical Substances; ASTM – American Society for the Testing of
Materials; bw – Body weight; CERCLA – Comprehensive Environmental Response,
Compensation, and Liability Act; CMR – Carcinogen, Mutagen or Reproductive Toxicant; DIN –
Standard of the German Institute for Standardisation; DOT – Department of Transportation; DSL –
Domestic Substances List (Canada); ECx – Concentration associated with x% response; EHS –
Extremely Hazardous Substance; ELx – Loading rate associated with x% response; EmS –
Emergency Schedule; ENCS – Existing and New Chemical Substances (Japan); ErCx –
Concentration associated with x% growth rate response; ERG – Emergency Response Guide;
GHS – Globally Harmonized System; GLP – Good Laboratory Practice; HMIS – Hazardous
Materials Identification System; IARC – International Agency for Research on Cancer; IATA –
International Air Transport Association; IBC – International Code for the Construction and
Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 – Half maximal inhibitory
concentration; ICAO – International Civil Aviation Organization; IECSC – Inventory of Existing
Chemical Substances in China; IMDG – International Maritime Dangerous Goods; IMO –
International Maritime Organization; ISHL – Industrial Safety and Health Law (Japan); ISO –
International Organisation for Standardization; KECI – Korea Existing Chemicals Inventory; LC50 –
Lethal Concentration to 50 % of a test population; LD50 – Lethal Dose to 50% of a test population
(Median Lethal Dose); MARPOL – International Convention for the Prevention of Pollution from
Ships; MSHA – Mine Safety and Health Administration; n.o.s. – Not Otherwise Specified; NFPA –
National Fire Protection Association; NO(A)EC – No Observed (Adverse) Effect Concentration;
NO(A)EL – No Observed (Adverse) Effect Level; NOELR – No Observable Effect Loading Rate;
NTP – National Toxicology Program; NZIoC – New Zealand Inventory of Chemicals; OECD –
Organization for Economic Co-operation and Development; OPPTS – Office of Chemical Safety

Page: 20
SAFETY DATA SHEET
Revision Date: 08/31/2018
Print Date: 2/26/2019
SDS Number: R0718448
BLO butyrolactone
Trademark, Ashland or its subsidiaries, registered
in various countries
826673
Version: 1.4

20 / 20
and Pollution Prevention; PBT – Persistent, Bioaccumulative and Toxic substance; PICCS –
Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR – (Quantitative) Structure
Activity Relationship; RCRA – Resource Conservation and Recovery Act; REACH – Regulation
(EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration,
Evaluation, Authorisation and Restriction of Chemicals; RQ – Reportable Quantity; SADT – Self-
Accelerating Decomposition Temperature; SARA – Superfund Amendments and Reauthorization
Act; SDS – Safety Data Sheet; TCSI – Taiwan Chemical Substance Inventory; TSCA – Toxic
Substances Control Act (United States); UN – United Nations; UNRTDG – United Nations
Recommendations on the Transport of Dangerous Goods; vPvB – Very Persistent and Very
Bioaccumulative

38WHITE20_SDS.pdf

by | Sep 27, 2025

SAFETY DATA SHEET
1. Identification
Product identifier USG White Art Plaster – 5 Minute, 20 Minute, Slow Set
Other means of identification
SDS number 52000000120
Synonyms Plaster
Recommended use Surface Hardening Enhanced Plaster
Recommended restrictions Use in accordance with manufacturer’s recommendations.
Manufacturer/Importer/Supplier/Distributor information
Company name United States Gypsum Company
Address 550 West Adams Street
Chicago, Illinois 60661-3637
Telephone 1-800-874-4968
Website www.usg.com
Emergency phone number 1-800-507-8899
2. Hazard(s) identification
Not classified.Physical hazards
Not classified.Health hazards
Not classified.OSHA defined hazards
Label elements
None.Hazard symbol
Signal word None.
Hazard statement None.
Precautionary statement
Prevention Observe good industrial hygiene practices.
Response Get medical attention/advice if you feel unwell.
Storage Store as indicated in Section 7.
Disposal Dispose of in accordance with local, state, and federal regulations.
Hazard(s) not otherwise
classified (HNOC)
None known.
Supplemental information
Steel products as sold do not present an inhalation, ingestion, or skin hazard. However, individual customer processes, (such a
welding, sawing, brazing, grinding, abrasive blasting, and machining) may result in the formation of fumes, dust (combustible o
otherwise), and/or particulate that may present a variety of health hazards. Molten steel is also hazardous.
3. Composition/information on ingredients
Mixtures
26499-65-0 > 95Plaster of Paris (Calcium Sulfate Hemihydrate CAS 10034-76-1)
CAS number %Chemical name
Composition comments All concentrations are in percent by weight unless ingredient is a gas.
4. First-aid measures
Inhalation Dust irritates the respiratory system, and may cause coughing and difficulties in breathing. Move injured person into fresh air and keep person calm under observation. Get medical attention if symptoms persist.
Skin contact Contact with dust: Rinse area with plenty of water. Get medical attention if irritation develops or persists.
USG White Art Plaster – 5 Minute, 20 Minute, Slow Set SDS US
920096 Version #: 01 Revision date: – Issue date: 18-April-2014
1 / 6www.Lagunaclay.com 800-452-4862 info@lagunaclay.com

Eye contact Dust in the eyes: Do not rub eyes. Flush thoroughly with water. If irritation occurs, get medical
assistance.
Ingestion Plaster of Paris hardens and if ingested may result in stomach and intestinal blockage. Drinking
gelatin solutions or large volumes of water may delay setting.
Most important
symptoms/effects, acute and
delayed
Under normal conditions of intended use, this product is not expected to be a health risk. Dust may
irritate throat and respiratory system and cause coughing.
Indication of immediate
medical attention and special
treatment needed
Provide general supportive measures and treat symptomatically.
General information Ensure that medical personnel are aware of the material(s) involved.
5. Fire-fighting measures
Suitable extinguishing media Use fire-extinguishing media appropriate for surrounding materials.
Unsuitable extinguishing
media
Not applicable.
Specific hazards arising from
the chemical
Not a fire hazard.
Special protective equipment
and precautions for firefighters
Selection of respiratory protection for firefighting: follow the general fire precautions indicated in
the workplace. Self-contained breathing apparatus and full protective clothing must be worn in
case of fire.
Fire-fighting
equipment/instructions
Use standard firefighting procedures and consider the hazards of other involved materials.
Specific methods Cool material exposed to heat with water spray and remove it if no risk is involved.
6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures
See Section 8 of the SDS for Personal Protective Equipment.
Methods and materials for
containment and cleaning up
Vacuum up the spilled material. Vacuums used for this purpose should be equipped with HEPA
filters. Containers must be labeled. Collect in approved containers and seal securely. For waste
disposal, see Section 13 of the SDS.
Environmental precautions Avoid discharge to drains, sewers, and other water systems.
7. Handling and storage
Precautions for safe handlingMinimize dust production when mixing, or opening and closing bags. Avoid inhalation of dust.
Wear appropriate personal protective equipment. Wash hands after handling. Observe good
industrial hygiene practices and use appropriate lifting techniques.
Conditions for safe storage,
including any incompatibilities
Store in a cool, dry, well-ventilated place. Store away from incompatible materials. Avoid contact
with acids, water, and moisture.
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
ValueType FormComponents
PEL 5 mg/m3 Respirable fraction.Plaster of Paris (Calcium Sulfate Hemihydrate CAS 10034-76-1) (CAS 26499-65-0)
15 mg/m3 Total dust.
US. ACGIH Threshold Limit Values
ValueType FormComponents
TWA 10 mg/m3 Inhalable fraction.Plaster of Paris (Calcium Sulfate Hemihydrate CAS 10034-76-1) (CAS 26499-65-0)
USG White Art Plaster – 5 Minute, 20 Minute, Slow Set SDS US
920096 Version #: 01 Revision date: – Issue date: 18-April-2014 2 / 6www.Lagunaclay.com 800-452-4862 info@lagunaclay.com

US. NIOSH: Pocket Guide to Chemical Hazards
ValueType FormComponents
TWA 5 mg/m3 Respirable.Plaster of Paris (Calcium
Sulfate Hemihydrate CAS
10034-76-1) (CAS
26499-65-0)
10 mg/m3 Total
Biological limit values No biological exposure limits noted for the ingredient(s).
Appropriate engineering
controls
Provide sufficient ventilation for operations causing dust formation. Observe occupational
exposure limits and minimize the risk of exposure.
Individual protection measures, such as personal protective equipment
Eye/face protection Wear approved safety goggles.
Skin protection
Hand protection It is a good industrial hygiene practice to minimize skin contact. For prolonged or repeated skin
contact use suitable protective gloves.
Other Normal work clothing (long sleeved shirts and long pants) is recommended.
Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn. Use a NIOSH/MSHA approved air
purifying respirator as needed to control exposure. Consult with respirator manufacturer to
determine respirator selection, use, and limitations. Use positive pressure, air-supplied respirator
for uncontrolled releases or when air purifying respirator limitations may be exceeded. Follow
respirator protection program requirements (OSHA 1910.134 and ANSI Z88.2) for all respirator
use.
Thermal hazards None.
General hygiene
considerations
Always observe good personal hygiene measures, such as washing after handling the material
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment separately from regular wash. Observe any medical surveillance requirements.
9. Physical and chemical properties
Appearance
Physical state Solid.
Form Powder.
Color White to off-white.
Odor Low to no odor.
Odor threshold Not applicable.
pH 6 – 8
Melting point/freezing pointNot applicable.
Not applicable.
Initial boiling point and boiling
range
Not applicable.
Flash point Not applicable.
Evaporation rate Not applicable.
Flammability (solid, gas) Not applicable.
Upper/lower flammability or explosive limits
Flammability limit – lower
(%)
Not applicable.
Flammability limit – upper
(%)
Not applicable.
Explosive limit – lower (%)Not applicable.
Explosive limit – upper (%)Not applicable.
Vapor pressure Not applicable.
Vapor density Not applicable.
Relative density 2.96 – 3.15 (H2O=1)
Solubility(ies)
Solubility (water) 0.15 – 1 g/100 g (H2O)
USG White Art Plaster – 5 Minute, 20 Minute, Slow Set SDS US
920096 Version #: 01 Revision date: – Issue date: 18-April-2014
3 / 6www.Lagunaclay.com 800-452-4862 info@lagunaclay.com

Partition coefficient
(n-octanol/water)
Not applicable.
Auto-ignition temperature Not applicable.
Decomposition temperature 2642 F (1450 C)
Viscosity Not applicable.
Other information
Bulk density 55 – 70 lb/ft
Particle size Varies.
VOC (Weight %) 0 %
10. Stability and reactivity
Reactivity Not available.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous
reactions
Hazardous polymerization does not occur.
Conditions to avoid When mixed with water this product can become very hot. Encasing or making moulds of any body
part can cause serious burns that may require surgical removal of affected tissue and even
amputation of encased body part.
Incompatible materials Acids. Exposure to water and acids must be supervised because the reactions are vigorous and
produce large amounts of heat.
Hazardous decomposition
products
Calcium oxides. Sulfur oxides.
11. Toxicological information
Information on likely routes of exposure
Ingestion Ingestion may cause irritation and stomach discomfort.
Inhalation Airborne dust may irritate throat and upper respiratory system causing coughing.
Skin contact Under normal conditions of intended use, this product does not pose a skin hazard.
Eye contac
t Direct contact with airborne particulates may cause temporary irritation.
Symptoms related to the physical, chemical and toxicological characteristics
Dust may irritate eyes and mucous membranes of the nose, throat and upper respiratory system
causing sneezing and/or coughing.
Information on toxicological effects
Acute toxicit
y Not expected to be a hazard under normal conditions of intended use.
Skin corrosion/irritation Not a skin irritant.
Serious eye damage/eye
irritation
Direct contact with eyes may cause temporary irritation.
Respiratory or skin sensitization
Respiratory sensitizationNot expected to cause respiratory sensitization based on non-skin sensitization history.
Skin sensitization Not a skin sensitizer. Plaster of Paris has displayed little sensitization potential.
Germ cell mutagenicity No evidence of mutagenicty found in Ames bacterial tests.
Carcinogenicity This material is not classified as a carcinogen by IARC, ACGIH, NTP or OSHA.
Reproductive toxicity Not expected to be a reproductive hazard.
Specific target organ toxicity – single exposure
No data available, but none expected.
Specific target organ toxicity – repeated exposure
No data available, but none expected.
Aspiration hazard Due to the physical form of the product it is not an aspiration hazard.
Chronic effects No other specific acute or chronic health impact noted.
12. Ecological information
Ecotoxicity Toxic to aquatic life with long lasting effects.
USG White Art Plaster – 5 Minute, 20 Minute, Slow Set SDS US
920096 Version #: 01 Revision date: – Issue date: 18-April-2014
4 / 6www.Lagunaclay.com 800-452-4862 info@lagunaclay.com

Components Test ResultsSpecies
Plaster of Paris (Calcium Sulfate Hemihydrate CAS 10034-76-1) (CAS 26499-65-0)
Aquatic
LC50Fish > 1970 mg/l, 96 hoursFathead minnow (Pimephales promelas)
Persistence and degradabilityCalcium sulfate dissolves in water forming calcium and sulfate ions.
Bioaccumulative potential Bioaccumulation is not expected.
Mobility in soil No data available.
Other adverse effects None expected.
13. Disposal considerations
Disposal instructions Dispose in accordance with applicable federal, state, and local regulations. Recycle responsibly.
Local disposal regulations Dispose of in accordance with local regulations.
Hazardous waste code Not regulated.
Waste from residues / unused
products
Dispose of in accordance with local regulations.
Contaminated packaging Dispose of in accordance with local regulations.
14. Transport information
DOT
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
Not applicable. This product is a solid. Therefore, bulk transport is governed by IMSBC code.Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
15. Regulatory information
US federal regulations This product is a “Hazardous Chemical” as defined by the OSHA Hazard Communication Standard
29 CFR 1910.1200 (OSHA) and 8 CCR 5194 (Cal/OSHA).
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard – Yes
Delayed Hazard – No
Fire Hazard – No
Pressure Hazard – No
Reactivity Hazard – No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous
chemical
No
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act
(SDWA)
Not regulated.
USG White Art Plaster – 5 Minute, 20 Minute, Slow Set SDS US
920096 Version #: 01 Revision date: – Issue date: 18-April-2014
5 / 6www.Lagunaclay.com 800-452-4862 info@lagunaclay.com

US state regulations
US. Massachusetts RTK – Substance List
Plaster of Paris (Calcium Sulfate Hemihydrate CAS 10034-76-1) (CAS 26499-65-0)
US. New Jersey Worker and Community Right-to-Know Act
Plaster of Paris (Calcium Sulfate Hemihydrate CAS 10034-76-1) (CAS 26499-65-0)
US. Pennsylvania Worker and Community Right-to-Know Law
Plaster of Paris (Calcium Sulfate Hemihydrate CAS 10034-76-1) (CAS 26499-65-0)
US. Rhode Island RTK
Not regulated.
US. California Proposition 65
This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive
harm.
US – California Proposition 65 – Carcinogens & Reproductive Toxicity (CRT): Listed substance
Not listed.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
*A “Yes” indicates this product complies with the inventory requirements administered by the governing country(s).
A “No” indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico
16. Other information, including date of preparation or last revision
Issue date 18-April-2014
Revision date –
Version # 01
Further information Plaster of Paris: Is classified as a hazardous substance but is generally considered a safe material
for routine use. When plaster of Paris is used responsibly it is not considered as a dangerous
material. However, when mixed with water this product can become very hot. DO NOT attempt to
make a cast enclosing any part of the body. Encasing any body part can cause serious burns and
even amputation of the encased body part.
NFPA Ratings:
Health: 1
Flammability: 0
Physical hazard: 0
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
NFPA Ratings
0
0
1
Disclaimer This information is provided without warranty. The information is believed to be correct. This
information should be used to make an independent determination of the methods to safeguard
workers and the environment.
USG White Art Plaster – 5 Minute, 20 Minute, Slow Set SDS US
920096 Version #: 01 Revision date: – Issue date: 18-April-2014 6 / 6www.Lagunaclay.com 800-452-4862 info@lagunaclay.com

38SWEEP_SDS.pdf

by | Sep 27, 2025

38STALUBE_SDS.pdf

by | Sep 27, 2025

SAFETY DATA SHEET
1. Identification
Air Tool OilProduct identifier
Other means of identification
74095Product code
Lubricant for pneumatic equipmentRecommended use
None known.Recommended restrictions
Manufacturer/Importer/Supplier/Distributor information
Manufactured or sold by:
CRC Canada Co.
Address 2-1246 Lorimar Dr.
Company name
Website
Telephone 905-670-2291
Emergency phone number 24-Hour Emergency 800-424-9300 (Canada)
(CHEMTREC) 703-527-3887 (International)
E-mail
Canada
www.crc-canada.ca
Support.CA@crcindustries.com
Mississauga, Ontario L5S 1R2
2. Hazard(s) identification
Not classified.Physical hazards
Not classified.Health hazards
Not classified.Environmental hazards
Label elements
None.Hazard symbol
Signal word None.
Hazard statement The mixture does not meet the criteria for classification.
Precautionary statement
Prevention Observe good industrial hygiene practices.
Response Wash hands after handling.
Storage Store away from incompatible materials.
Disposal Dispose of waste and residues in accordance with local authority requirements.
Other hazards None known.
3. Composition/information on ingredients
Mixtures
CAS number %Chemical name Common name and synonyms
64742-53-6distillates (petroleum), hydrotreated
light naphthenic
90 – 100
64741-96-4distillates (petroleum),
solvent-refined heavy naphthenic
3 – 5
68649-42-3phosphorodithioic acid,
o,o-di-c1-14-alkyl esters, zinc salts
1 – 3
The exact percentage (concentration) of composition has been withheld as a trade secret.
All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.
4. First-aid measures
If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.
If breathing stops, provide artificial respiration. Call a physician if symptoms develop or persist.
Inhalation
Remove contaminated clothing. Wash off with soap and water. Get medical attention if irritation
develops and persists.
Skin contact
1 / 7
Material name: Air Tool Oil
74095 Version #: 01 Issue date: 05-10-2017
SDS CANADA

Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Get medical attention if irritation develops and persists.
Eye contact
Rinse mouth. Do not induce vomiting without advice from poison control center. If vomiting occurs,
keep head low so that stomach content doesn’t get into the lungs. Never give anything by mouth to
a victim who is unconscious or is having convulsions.
Ingestion
Direct contact with eyes may cause temporary irritation. Repeated exposure may cause skin
dryness or cracking.
Most important
symptoms/effects, acute and
delayed
Treat symptomatically.Indication of immediate
medical attention and special
treatment needed
Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves.
General information
5. Fire-fighting measures
Water spray. Foam. Dry chemical powder. Dry chemicals. Carbon dioxide (CO2).Suitable extinguishing media
Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing
media
During fire, gases hazardous to health may be formed.Specific hazards arising from
the chemical
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipment
and precautions for firefighters
Cool containers exposed to heat with water spray and remove container, if no risk is involved.Fire fighting
equipment/instructions
No unusual fire or explosion hazards noted.General fire hazards
6. Accidental release measures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
low areas. Do not touch damaged containers or spilled material unless wearing appropriate
protective clothing. Use with adequate ventilation. Open doors and windows or use other means to
ensure a fresh air supply during use and while product is drying. For personal protection, see
section 8 of the SDS.
Personal precautions,
protective equipment and
emergency procedures
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Prevent entry into waterways, sewer, basements or confined areas.
Methods and materials for
containment and cleaning up
Avoid discharge into drains, water courses or onto the ground.Environmental precautions
7. Handling and storage
Avoid prolonged or repeated contact with skin. Avoid prolonged exposure. Use with adequate
ventilation. Open doors and windows or use other means to ensure a fresh air supply during use
and while product is drying. For product usage instructions, please see the product label.
Precautions for safe handling
Keep away from heat and sources of ignition. Store in a cool, dry place out of direct sunlight. Keep
container tightly closed. Store away from incompatible materials (see Section 10 of the SDS).
Conditions for safe storage,
including any incompatibilities
8. Exposure controls/personal protection
Occupational exposure limits
US. ACGIH Threshold Limit Values
ValueComponents FormType
TWA 5 mg/m3 Inhalable fraction.distillates (petroleum),
hydrotreated light
naphthenic (CAS
64742-53-6)
TWA 5 mg/m3 Inhalable fraction.distillates (petroleum),
solvent-refined heavy
naphthenic (CAS
64741-96-4)
2 / 7
Material name: Air Tool Oil
74095 Version #: 01 Issue date: 05-10-2017
SDS CANADA

Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2)
ValueComponents FormType
STEL 10 mg/m3 Mist.distillates (petroleum),
hydrotreated light
naphthenic (CAS
64742-53-6)
TWA 5 mg/m3 Mist.
STEL 10 mg/m3 Mist.distillates (petroleum),
solvent-refined heavy
naphthenic (CAS
64741-96-4)
TWA 5 mg/m3 Mist.
Canada. Manitoba OELs (Reg. 217/2006, The Workplace Safety And Health Act)
ValueComponents FormType
TWA 5 mg/m3 Inhalable fraction.distillates (petroleum),
hydrotreated light
naphthenic (CAS
64742-53-6)
TWA 5 mg/m3 Inhalable fraction.distillates (petroleum),
solvent-refined heavy
naphthenic (CAS
64741-96-4)
Canada. Quebec OELs. (Ministry of Labor – Regulation Respecting the Quality of the Work Environment)
ValueComponents FormType
STEL 10 mg/m3 Mist.distillates (petroleum),
hydrotreated light
naphthenic (CAS
64742-53-6)
TWA 5 mg/m3 Mist.
STEL 10 mg/m3 Mist.distillates (petroleum),
solvent-refined heavy
naphthenic (CAS
64741-96-4)
TWA 5 mg/m3 Mist.
No biological exposure limits noted for the ingredient(s).Biological limit values
No exposure standards allocated.Exposure guidelines
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level.
General ventilation normally adequate.
Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Wear safety glasses with side shields (or goggles).Eye/face protection
Skin protection
Wear protective gloves such as: Nitrile. Polyvinyl chloride (PVC).Hand protection
Wear appropriate chemical resistant clothing. Wear suitable protective clothing.Other
If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a
NIOSH-approved cartridge respirator with an organic vapor cartridge. Use a self-contained
breathing apparatus in confined spaces and for emergencies. Air monitoring is needed to
determine actual employee exposure levels.
Respiratory protection
Wear appropriate thermal protective clothing, when necessary.Thermal hazards
Handle in accordance with good industrial hygiene and safety practice.General hygiene
considerations
9. Physical and chemical properties
Appearance
Liquid.Physical state
Liquid.Form
Amber.Color
3 / 7
Material name: Air Tool Oil
74095 Version #: 01 Issue date: 05-10-2017
SDS CANADA

Mild petroleum.Odor
Odor threshold Not available.
pH Not available.
Melting point/freezing pointNot available.
Initial boiling point and boiling
range
680 F (360 C) estimated
Flash point 320 F (160 C) Cleveland Open Cup
Evaporation rate Slow.
Not available.Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit – lower
(%)
Not available.
Flammability limit – upper
(%)
Not available.
Vapor pressure Not available.
Vapor density > 1 (air = 1)
Relative density 0.9 – 0.92
Solubility(ies)
Solubility (water) Insoluble.
Partition coefficient
(n-octanol/water)
Not available.
Auto-ignition temperature 500 F (260 C) estimated
Decomposition temperature Not available.
Viscosity 22.5 – 27.5 mm /s (104 F (40 C))
10. Stability and reactivity
The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity
Material is stable under normal conditions.Chemical stability
No dangerous reaction known under conditions of normal use.Possibility of hazardous
reactions
Contact with incompatible materials.Conditions to avoid
Strong oxidizing agents.Incompatible materials
Carbon oxides.Hazardous decomposition
products
11. Toxicological information
Information on likely routes of exposure
Inhalation Prolonged inhalation may be harmful.
Skin contact Prolonged skin contact may cause temporary irritation.
Eye contact Direct contact with eyes may cause temporary irritation.
Ingestion Health injuries are not known or expected under normal use.
Symptoms related to the
physical, chemical and
toxicological characteristics
Irritation of eyes and mucous membranes. Skin irritation.
Information on toxicological effects
Acute toxicity Not classified.
Test ResultsComponents Species
distillates (petroleum), hydrotreated light naphthenic (CAS 64742-53-6)
Dermal
Acute
LD50 Rabbit > 5000 mg/kg
Inhalation
LC50 Rat 2180 mg/m , 4 hours
4 / 7
Material name: Air Tool Oil
74095 Version #: 01 Issue date: 05-10-2017
SDS CANADA

Test ResultsComponents Species
Oral
LD50 Rat > 5000 mg/kg
distillates (petroleum), solvent-refined heavy naphthenic (CAS 64741-96-4)
Dermal
Acute
LD50 Rabbit > 5000 mg/kg
Oral
* Estimates for product may be based on additional component data not shown.
LD50 Rat > 5000 mg/kg
Prolonged skin contact may cause temporary irritation.Skin corrosion/irritation
Direct contact with eyes may cause temporary irritation.Serious eye damage/eye
irritation
Respiratory sensitization Not a respiratory sensitizer.
This product is not expected to cause skin sensitization.Skin sensitization
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Germ cell mutagenicity
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
ACGIH Carcinogens
distillates (petroleum), hydrotreated light naphthenic
(CAS 64742-53-6)
A4 Not classifiable as a human carcinogen.
distillates (petroleum), solvent-refined heavy naphthenic
(CAS 64741-96-4)
A4 Not classifiable as a human carcinogen.
Canada – Manitoba OELs: carcinogenicity
distillates (petroleum), hydrotreated light naphthenic
(CAS 64742-53-6)
Not classifiable as a human carcinogen.
distillates (petroleum), solvent-refined heavy naphthenic
(CAS 64741-96-4)
Not classifiable as a human carcinogen.
This product is not expected to cause reproductive or developmental effects.Reproductive toxicity
Specific target organ toxicity –
single exposure
Not classified.
Specific target organ toxicity –
repeated exposure
Not classified.
Aspiration hazard Based on available data, the classification criteria are not met.
Chronic effects Prolonged inhalation may be harmful.
Further information This product has no known adverse effect on human health.
12. Ecological information
The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Ecotoxicity
Components Test ResultsSpecies
phosphorodithioic acid, o,o-di-c1-14-alkyl esters, zinc salts (CAS 68649-42-3)
Aquatic
EC50Crustacea 1 – 5 mg/l, 48 hoursWater flea (Daphnia magna)
* Estimates for product may be based on additional component data not shown.
LC50Fish 1 – 5 mg/l, 96 hoursFathead minnow (Pimephales promelas)
No data is available on the degradability of this product.Persistence and degradability
No data available.Bioaccumulative potential
No data available.Mobility in soil
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
5 / 7
Material name: Air Tool Oil
74095 Version #: 01 Issue date: 05-10-2017
SDS CANADA

13. Disposal considerations
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow
this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches
with chemical or used container. Dispose of contents/container in accordance with
local/regional/national/international regulations.
Disposal of waste from
residues / unused products
Dispose in accordance with all applicable regulations.Local disposal regulations
Not regulated.Hazardous waste code
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.
Contaminated packaging
14. Transport information
TDG
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
Not established.Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
15. Regulatory information
This product has been classified in accordance with the hazard criteria of the HPR and the SDS
contains all the information required by the HPR.
Canadian regulations
Controlled Drugs and Substances Act
Not regulated.
Export Control List (CEPA 1999, Schedule 3)
Not listed.
Greenhouse Gases
Not listed.
Ontario. Toxic Substances. Toxic Reduction Act, 2009. Regulation 455/09 (July 1, 2011)
phosphorodithioic acid, o,o-di-c1-14-alkyl esters, zinc salts (CAS 68649-42-3)
Precursor Control Regulations
Not regulated.
International regulations
Stockholm Convention
Not applicable.
Rotterdam Convention
Not applicable.
Kyoto protocol
Not applicable.
Montreal Protocol
Not applicable.
Basel Convention
Not applicable.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
YesAustralia Australian Inventory of Chemical Substances (AICS)
YesCanada Domestic Substances List (DSL)
NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)
YesEurope European Inventory of Existing Commercial Chemical
Substances (EINECS)
NoEurope European List of Notified Chemical Substances (ELINCS)
NoJapan Inventory of Existing and New Chemical Substances (ENCS)
6 / 7
Material name: Air Tool Oil
74095 Version #: 01 Issue date: 05-10-2017
SDS CANADA

Country(s) or region Inventory name On inventory (yes/no)*
YesKorea Existing Chemicals List (ECL)
YesNew Zealand New Zealand Inventory
YesPhilippines Philippine Inventory of Chemicals and Chemical Substances
(PICCS)
YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A “Yes” indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A “No” indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other information
05-10-2017Issue date
Version # 01
The information contained in this document applies to this specific material as supplied. It may not
be valid for this material if it is used in combination with any other materials. This information is
accurate to the best of CRC Canada Co.’s knowledge or obtained from sources believed by CRC
to be accurate. Before using any product, read all warnings and directions on the label. For further
clarification of any information contained on this (M)SDS consult your supervisor, a health & safety
professional, or CRC Canada Co.
Disclaimer
7 / 7
Material name: Air Tool Oil
74095 Version #: 01 Issue date: 05-10-2017
SDS CANADA

38SQUEE-36_SDS.pdf

by | Sep 27, 2025

38PRIMER6_SDS.pdf

by | Sep 27, 2025

CHT UK BRIDGWATER LTD
PRIMER NO 6
Revision nr.2
Dated 2/2/2024
Printed on 2/2/2024
Page n. 1 / 11
Replaced revision:1 (Dated 11/3/2020)
EN
EPY 11.6.1 – SDS 1004.14
Safety Data Sheet

According to U.S.A. Federal Hazcom 2012
1. Identification

1.1. Product identifier

Product name PRIMER NO 6

1.2. Relevant identified uses of the substance or mixture and uses advised against

Intended use Primer.

1.3. Details of the supplier of the safety data sheet

Name CHT UK BRIDGWATER LTD
Full address Amber House Showground Road
District and Country TA6 6AJ Bridgwater (Somerset)
England
Tel. +44(0)1278411400
Fax +44(0)1278411444
e-mail address of the competent person
responsible for the Safety Data Sheet info.uk@cht.com

Supplier: CHT USA, Inc.
805 Wolfe Avenue
Cassopolis, MI 49031

1.4. Emergency telephone number

For urgent inquiries refer to Transport: +1-703-527-3887 CHEMTREC (North America, 24 hours) (CCN 1014369)
Toll Free: 1-800-424-9300 CHEMTREC (North America, 24 hours)
+52 55 8526 4930 CHEMTREC (Central America, 24 hours)
+55 11 4349 1359 CHEMTREC (South America, 24 hours)

2. Hazards identification

2.1. Classification of the substance or mixture

The product is classified as hazardous pursuant to the provisions set forth in OSHA Hazard Communication Standard (HCS) (29 CFR
1910.1200). The product thus requires a safety datasheet.
Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet.

Classification and Hazard Statement
Flammable liquid, category 3 Flammable liquid and vapour.
Acute toxicity, category 4 Harmful if swallowed.
Specific target organ toxicity – repeated exposure,
category 2
May cause damage to organs through prolonged or repeated
exposure.
Serious eye damage, category 1 Causes serious eye damage.
Skin irritation, category 2 Causes skin irritation.
Hazard pictograms:

Signal words: Danger

Hazard statements:
H226 Flammable liquid and vapour.
H302 Harmful if swallowed.
H373 May cause damage to organs through prolonged or repeated exposure.
H318 Causes serious eye damage.
H315 Causes skin irritation.

CHT UK BRIDGWATER LTD
PRIMER NO 6
Revision nr.2
Dated 2/2/2024
Printed on 2/2/2024
Page n. 2 / 11
Replaced revision:1 (Dated 11/3/2020)
EN
EPY 11.6.1 – SDS 1004.14
2. Hazards identification… / >>
Precautionary statements:
Prevention:
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P260 Do not breathe dust / fume / gas / mist / vapours / spray.
P242 Use only non-sparking tools.
P233 Keep container tightly closed.
P280 Wear protective gloves / eye protection / face protection.
P270 Do not eat, drink or smoke when using this product.
P264 Wash . . . thoroughly after handling.
P240 Ground / bond container and receiving equipment.
P243 Take precautionary measures against static discharge.
P241 Use explosion-proof electrical / ventilating / lighting / . . . / equipment.
Response:
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water / shower.
P310 Immediately call a POISON CENTER / doctor / . . .
P330 Rinse mouth.
P302+P352 IF ON SKIN: wash with plenty of water / . . .
P362+P364 Take off contaminated clothing and wash it before reuse.
P370+P378 In case of fire: use . . . to extinguish.
Storage:
P403+P235 Store in a well-ventilated place. Keep cool.
Disposal:
P501 Dispose of contents / container to . . .

The mixture contains 10.38% of components of unknown acute oral toxicity.

2.2. Other hazards

Information not available

3. Composition/information on ingredients

3.1. Substances

Information not relevant

3.2. Mixtures

Contains:

Identification x = Conc. % Classification:

TETRA N BUTYL TITANATE
5 x < 6 Flammable liquid, category 3 H226, Serious eye damage, category 1 H318, Skin irritation, category 2 H315, Specific target organ toxicity - single exposure, category 3 H335, Specific target organ toxicity - single exposure, category 3 H336 EC 227-006-8 CAS 5593-70-4 REACH Reg. 01-2119967423-33 TETRAKIS (2-BUTOXYETHYL) ORTHOSILICATE 4,5 x < 5 Specific target organ toxicity - repeated exposure, category 2 H373, Skin irritation, category 2 H315 EC 242-560-0 CAS 18765-38-3 REACH Reg. 01-2120761533-55-0002 * There is a batch to batch variation. The full wording of hazard (H) phrases is given in section 16 of the sheet. 4. First-aid measures 4.1. Description of first aid measures EYES: Remove contact lenses, if present. Wash immediately with plenty of water for at least 30-60 minutes, opening the eyelids fully. Get medical advice/attention. SKIN: Remove contaminated clothing. Rinse skin with a shower immediately. Get medical advice/attention. CHT UK BRIDGWATER LTD PRIMER NO 6 Revision nr.2 Dated 2/2/2024 Printed on 2/2/2024 Page n. 3 / 11 Replaced revision:1 (Dated 11/3/2020) EN EPY 11.6.1 - SDS 1004.14 4. First-aid measures... / >>
INGESTION: Have the subject drink as much water as possible. Get medical advice/attention. Do not induce vomiting unless explicitly
authorised by a doctor.
INHALATION: Get medical advice/attention immediately. Remove victim to fresh air, away from the accident scene. If the subject stops
breathing, administer artificial respiration. Take suitable precautions for rescue workers.

4.2. Most important symptoms and effects, both acute and delayed

Specific information on symptoms and effects caused by the product are unknown.

4.3. Indication of any immediate medical attention and special treatment needed

Information not available

5. Fire-fighting measures

5.1. Extinguishing media

SUITABLE EXTINGUISHING EQUIPMENT
Extinguishing substances are: carbon dioxide, foam, chemical powder. For product loss or leakage that has not caught fire, water spray can
be used to disperse flammable vapours and protect those trying to stem the leak.
UNSUITABLE EXTINGUISHING EQUIPMENT
Do not use jets of water. Water is not effective for putting out fires but can be used to cool containers exposed to flames to prevent
explosions.

5.2. Special hazards arising from the substance or mixture

HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE
Excess pressure may form in containers exposed to fire at a risk of explosion. Do not breathe combustion products.

5.3. Advice for firefighters

GENERAL INFORMATION
Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for
health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of
contaminated water used for extinction and the remains of the fire according to applicable regulations.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS
Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with
self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137).

6. Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Block the leakage if there is no hazard.
Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent
any contamination of skin, eyes and personal clothing. These indications apply for both processing staff and those involved in emergency
procedures.

6.2. Environmental precautions

The product must not penetrate into the sewer system or come into contact with surface water or ground water.

6.3. Methods and material for containment and cleaning up

Collect the leaked product into a suitable container. Evaluate the compatibility of the container to be used, by checking section 10. Absorb
the remainder with inert absorbent material.
Make sure the leakage site is well aired. Contaminated material should be disposed of in compliance with the provisions set forth in point
13.

6.4. Reference to other sections

Any information on personal protection and disposal is given in sections 8 and 13.

CHT UK BRIDGWATER LTD
PRIMER NO 6
Revision nr.2
Dated 2/2/2024
Printed on 2/2/2024
Page n. 4 / 11
Replaced revision:1 (Dated 11/3/2020)
EN
EPY 11.6.1 – SDS 1004.14
7. Handling and storage

7.1. Precautions for safe handling

Keep away from heat, sparks and naked flames; do not smoke or use matches or lighters. Without adequate ventilation, vapours may
accumulate at ground level and, if ignited, catch fire even at a distance, with the danger of backfire. Avoid bunching of electrostatic charges.
Do not eat, drink or smoke during use. Remove any contaminated clothes and personal protective equipment before entering places in
which people eat. Avoid leakage of the product into the environment.

7.2. Conditions for safe storage, including any incompatibilities

Store only in the original container. Store in a cool and well ventilated place, keep far away from sources of heat, naked flames and sparks
and other sources of ignition. Keep containers away from any incompatible materials, see section 10 for details.

7.3. Specific end use(s)

Information not available

8. Exposure controls/personal protection

8.1. Control parameters

Regulatory references:

EU OEL EU Directive (EU) 2022/431; Directive (EU) 2019/1831; Directive (EU) 2019/130; Directive (EU)
2019/983; Directive (EU) 2017/2398; Directive (EU) 2017/164; Directive 2009/161/EU; Directive
2006/15/EC; Directive 2004/37/EC; Directive 2000/39/EC; Directive 98/24/EC; Directive
91/322/EEC.

TETRAKIS (2-BUTOXYETHYL) ORTHOSILICATE
Threshold Limit Value
Type Country TWA/8h STEL/15min Remarks / Observations
mg/m3 ppm mg/m3 ppm
OEL EU 98

INHAL

Legend:
(C) = CEILING ; INHAL = Inhalable Fraction ; RESP = Respirable Fraction ; THORA = Thoracic Fraction.

8.2. Exposure controls

As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is
well aired through effective local aspiration. Personal protective equipment must comply with current regulations.
HAND PROTECTION
Protect hands with category III work gloves.
The following should be considered when choosing work glove material (OSHA 29 CFR 1910.138): compatibility, degradation, failure time
and permeability.
The work gloves’ resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves’ wear time depends
on the duration and type of use.
SKIN PROTECTION
Wear category I professional long-sleeved overalls and safety footwear. Wash body with soap and water after removing protective clothing.
EYE PROTECTION
Wear airtight protective goggles (OSHA 29 CFR 1910.133).
RESPIRATORY PROTECTION
If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, wear a mask with a
NIOSH certified filter, whose class must be chosen according to the limit of use concentration (NIOSH 42 CFR 84, OSHA 29 CFR
1910.134). In the presence of gases or vapours of various kinds and/or gases or vapours containing particulate (aerosol sprays, fumes,
mists, etc.) combined filters are required.
Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker’s exposure to the
threshold values considered. The protection provided by masks is in any case limited.
If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an
emergency, wear open-circuit compressed air breathing apparatus or external air-intake breathing apparatus. For a correct choice of
respiratory protection device, see standard NIOSH 42 CFR 84, OSHA 29 CFR 1910.134.
ENVIRONMENTAL EXPOSURE CONTROLS
The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure
compliance with environmental standards.

CHT UK BRIDGWATER LTD
PRIMER NO 6
Revision nr.2
Dated 2/2/2024
Printed on 2/2/2024
Page n. 5 / 11
Replaced revision:1 (Dated 11/3/2020)
EN
EPY 11.6.1 – SDS 1004.14
9. Physical and chemical properties

9.1. Information on basic physical and chemical properties

Properties Value Information
Appearance liquid
Colour straw-coloured
Odour characteristic of solvent
Odour threshold not available
pH not available
Melting point / freezing point not available
Initial boiling point not available
Boiling range not available
Flash point 28 C (82.4 F)
Evaporation rate not available
Flammability not available
Lower inflammability limit not available
Upper inflammability limit not available
Lower explosive limit not available
Upper explosive limit not available
Vapour pressure not available
Vapour density not available
Relative density 0.83
Solubility immiscible with water
Partition coefficient: n-octanol/water not available
Auto-ignition temperature not available
Decomposition temperature not available
Viscosity 1.2048 cSt Temperature: 23 C
Explosive properties not available
Oxidising properties not available
9.2. Other information

Information not available

10. Stability and reactivity

10.1. Reactivity

There are no particular risks of reaction with other substances in normal conditions of use.

10.2. Chemical stability

The product is stable in normal conditions of use and storage.

10.3. Possibility of hazardous reactions

The vapours may also form explosive mixtures with the air.

10.4. Conditions to avoid

Avoid overheating. Avoid bunching of electrostatic charges. Avoid all sources of ignition.

10.5. Incompatible materials

Information not available

10.6. Hazardous decomposition products

In the event of thermal decomposition or fire, gases and vapours that are potentially dangerous to health may be released.

11. Toxicological information

In the absence of experimental data for the product itself, health hazards are evaluated according to the properties of the substances it
contains, using the criteria specified in the applicable regulation for classification.
It is therefore necessary to take into account the concentration of the individual hazardous substances indicated in section 3, to evaluate the
toxicological effects of exposure to the product.

CHT UK BRIDGWATER LTD
PRIMER NO 6
Revision nr.2
Dated 2/2/2024
Printed on 2/2/2024
Page n. 6 / 11
Replaced revision:1 (Dated 11/3/2020)
EN
EPY 11.6.1 – SDS 1004.14
11. Toxicological information… / >>
11.1. Information on toxicological effects

Metabolism, toxicokinetics, mechanism of action and other information

Information not available

Information on likely routes of exposure

Information not available

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Information not available

Interactive effects

Information not available

ACUTE TOXICITY

TETRAKIS (2-BUTOXYETHYL) ORTHOSILICATE
> 2000 mg/kg (Rat)LD50 (Oral):

SKIN CORROSION / IRRITATION

Causes skin irritation

SERIOUS EYE DAMAGE / IRRITATION

Causes serious eye damage

RESPIRATORY OR SKIN SENSITISATION

Does not meet the classification criteria for this hazard class

GERM CELL MUTAGENICITY

Does not meet the classification criteria for this hazard class

CARCINOGENICITY

Does not meet the classification criteria for this hazard class
Carcinogenicity Assessment:
111-76-2 2-BUTOXYETHANOL
ACGIH:: A3
IARC:3

REPRODUCTIVE TOXICITY

Does not meet the classification criteria for this hazard class

STOT – SINGLE EXPOSURE

Does not meet the classification criteria for this hazard class

STOT – REPEATED EXPOSURE

May cause damage to organs

ASPIRATION HAZARD

Does not meet the classification criteria for this hazard class

CHT UK BRIDGWATER LTD
PRIMER NO 6
Revision nr.2
Dated 2/2/2024
Printed on 2/2/2024
Page n. 7 / 11
Replaced revision:1 (Dated 11/3/2020)
EN
EPY 11.6.1 – SDS 1004.14
12. Ecological information

Use this product according to good working practices. Avoid littering. Inform the competent authorities, should the product reach waterways
or contaminate soil or vegetation.

12.1. Toxicity

TETRAKIS (2-BUTOXYETHYL) ORTHOSILICATE

EC50 – for Algae / Aquatic Plants > 161 mg/l/72h (Scenedesmus subspicatus)

12.2. Persistence and degradability

TETRAKIS (2-BUTOXYETHYL) ORTHOSILICATE
Rapidly degradable

12.3. Bioaccumulative potential

Information not available

12.4. Mobility in soil

Information not available

12.5. Results of PBT and vPvB assessment

On the basis of available data, the product does not contain any PBT or vPvB in percentage than 0,1%.

12.6. Other adverse effects

Information not available

13. Disposal considerations

13.1. Waste treatment methods
Reuse, when possible. Neat product residues should be considered special non-hazardous waste.
Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations.
CONTAMINATED PACKAGING
Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations.

14. Transport information

14.1. UN number

ADR / RID, IMDG, IATA: UN 1993

14.2. UN proper shipping name

ADR / RID: FLAMMABLE LIQUID, N.O.S. (OCTAMETHYLTRISILOXANE; TETRA N BUTYL TITANATE)
IMDG: FLAMMABLE LIQUID, N.O.S. (OCTAMETHYLTRISILOXANE; TETRA N BUTYL TITANATE)
IATA: FLAMMABLE LIQUID, N.O.S. (OCTAMETHYLTRISILOXANE; TETRA N BUTYL TITANATE)

CHT UK BRIDGWATER LTD
PRIMER NO 6
Revision nr.2
Dated 2/2/2024
Printed on 2/2/2024
Page n. 8 / 11
Replaced revision:1 (Dated 11/3/2020)
EN
EPY 11.6.1 – SDS 1004.14
14. Transport information… / >>
14.3. Transport hazard class(es)

ADR / RID: Class: 3 Label: 3
IMDG: Class: 3 Label: 3
IATA: Class: 3 Label: 3

14.4. Packing group

ADR / RID, IMDG, IATA: III

14.5. Environmental hazards

ADR / RID: NO
IMDG: NO
IATA: NO

14.6. Special precautions for user

ADR / RID: HIN – Kemler: 30 Limited Quantities: 5 L Tunnel restriction code: (D/E)
Special provision: 274, 601
IMDG: EMS: F-E, S-E Limited Quantities: 5 L
IATA: Cargo: Maximum quantity: 220 L Packaging instructions: 366
Passengers: Maximum quantity: 60 L Packaging instructions: 355
Special provision: A3

14.7. Transport in bulk according to Annex II of Marpol and the IBC Code

Information not relevant

15. Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

U.S. Federal Regulations

TSCA:
All components of this product are listed on US Toxic Substances Control Act (TSCA) Inventory or are exempt from the listing / notification
requirements.

Clean Air Act Section 112(b):
No component(s) listed.

Clean Air Act Section 602 Class I Substances:
No component(s) listed.

Clean Air Act Section 602 Class II Substances:
No component(s) listed.

Clean Water Act Priority Pollutants:
No component(s) listed.

Clean Water Act Toxic Pollutants:
No component(s) listed.

DEA List I Chemicals (Precursor Chemicals):
No component(s) listed.

CHT UK BRIDGWATER LTD
PRIMER NO 6
Revision nr.2
Dated 2/2/2024
Printed on 2/2/2024
Page n. 9 / 11
Replaced revision:1 (Dated 11/3/2020)
EN
EPY 11.6.1 – SDS 1004.14
15. Regulatory information… / >>
DEA List II Chemicals (Essential Chemicals):
No component(s) listed.

EPA List of Lists:
313 Category Code:
No component(s) listed.

EPCRA 302 EHS TPQ:
No component(s) listed.

EPCRA 304 EHS RQ:
No component(s) listed.

CERCLA RQ:
No component(s) listed.

EPCRA 313 TRI:
No component(s) listed.

RCRA Code:
No component(s) listed.

CAA 112 (r) RMP TQ:
No component(s) listed.

State Regulations

Massachussetts:
78-10-4 ETHYL SILICATE

Minnesota:
78-10-4 ETHYL SILICATE

New Jersey:
78-10-4 ETHYL SILICATE

New York:
No component(s) listed.

Pennsylvania:
78-10-4 ETHYL SILICATE

California:
78-10-4 ETHYL SILICATE

Proposition 65:
This product does not contain any substances know to the State of California to cause cancer, reproductive harm or birth defects.

International Regulations
Substances subject to exportation reporting pursuant to Regulation (EU) 649/2012:
None

Substances subject to the Rotterdam Convention:
None

Substances subject to the Stockholm Convention:
None

16. Other information

Text of hazard (H) indications mentioned in section 2-3 of the sheet:

H226 Flammable liquid and vapour.
H302 Harmful if swallowed.
H373 May cause damage to organs through prolonged or repeated exposure.
H318 Causes serious eye damage.
H315 Causes skin irritation.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.

CHT UK BRIDGWATER LTD
PRIMER NO 6
Revision nr.2
Dated 2/2/2024
Printed on 2/2/2024
Page n. 10 / 11
Replaced revision:1 (Dated 11/3/2020)
EN
EPY 11.6.1 – SDS 1004.14
16. Other information… / >>
LEGEND:
– 313 CATEGORY CODE: Emergency Planning and Community Right-to Know Act Section 313 Category Code
– ADR: European Agreement concerning the carriage of Dangerous goods by Road
– ATE: Acute Toxicity Estimate
– CAA 112 RMP TQ: Risk Management Plan Threshold Quantity (Clean Air Act Section 112 )
– CAS: Chemical Abstract Service Number
– CE50: Effective concentration (required to induce a 50% effect)
– CERCLA RQ: Reportable Quantity (Comprehensive Environment Response, Compensation, and Liability Act)
– CLP: Regulation (EC) 1272/2008
– DEA: Drug Enforcement Administration
– EmS: Emergency Schedule
– EPA: US Environmental Protection Agency
– EPCRA: Emergency Planning and Community Right-to Know Act
– EPCRA 302 EHS TPQ: Extremely Hazardous Substance Threshold Planning Quantity (Section 302 Category Code)
– EPCRA 304 EHS RQ: Extremely Hazardous Substance Reportable Quantity (Section 304 Category Code)
– EPCRA 313 TRI: Toxics Release Inventory (Section 313 Category Code)
– GHS: Globally Harmonized System of classification and labeling of chemicals
– IATA DGR: International Air Transport Association Dangerous Goods Regulation
– IC50: Immobilization Concentration 50%
– IMDG: International Maritime Code for dangerous goods
– IMO: International Maritime Organization
– LC50: Lethal Concentration 50%
– LD50: Lethal dose 50%
– OEL: Occupational Exposure Level
– PEL: Predicted exposure level
– RCRA Code: Resource Conservation and Recovery Act Code
– REACH: Regulation (EC) 1907/2006
– REL: Recommended exposure limit
– RID: Regulation concerning the international transport of dangerous goods by train
– TLV: Threshold Limit Value
– TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure.
– TSCA: Toxic Substances Control Act
– TWA: Time-weighted average exposure limit
– TWA STEL: Short-term exposure limit
– VOC: Volatile organic Compounds
– WHMIS: Workplace Hazardous Materials Information System.

GENERAL BIBLIOGRAPHY:
– GHS rev. 3
– The Merck Index. 10th Edition
– Handling Chemical Safety
– Niosh – Registry of Toxic Effects of Chemical Substances
– INRS – Fiche Toxicologique (toxicological sheet)
– Patty – Industrial Hygiene and Toxicology
– N.I. Sax – Dangerous properties of Industrial Materials-7, 1989 Edition
– ECHA website
– Database of SDS models for chemicals – Ministry of Health and ISS (Istituto Superiore di Sanit ) – Italy

– 6 NYCRR part 597
– Cal/OSHA website
– California Safe Drinking Water and Toxic Enforcement Act
– EPA website
– Hazard Comunication Standard (HCS 2012)
– IARC website
– List Of Lists EPA: Consolidated List of Chemicals Subject to EPCRA, CERCLA and Section 112 of the Clean Air Act
– Massachussetts 105 CMR Department of public health 670.000: “Right to Know”
– Minensota Chapter 5206 Departemnt Of Labor and Industry Hazardous Substances, Employee “Right to Know”.
– New Jersey Worker and Community Right to know Act N.J.S.A.
– NTP. 2011. Report on Carcinogens, 12th Edition.
– OSHA website
– Pennsylvania, Hazardous Substance List, Chapter 323

Note for users:
The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the
suitability and thoroughness of provided information according to each specific use of the product.
This document must not be regarded as a guarantee on any specific product property.
The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current

CHT UK BRIDGWATER LTD
PRIMER NO 6
Revision nr.2
Dated 2/2/2024
Printed on 2/2/2024
Page n. 11 / 11
Replaced revision:1 (Dated 11/3/2020)
EN
EPY 11.6.1 – SDS 1004.14
16. Other information… / >>
health and safety laws and regulations. The producer is relieved from any liability arising from improper uses.
Provide appointed staff with adequate training on how to use chemical products.

CALCULATION METHODS FOR CLASSIFICATION
Product classification derives from criteria established by the OSHA Hazard Communication Standard (HCS) (29 CFR 1910.1200), unless
determined otherwise in Section 11 and 12. The data for evaluation of chemical-physical properties are reported in section 9.

Changes to previous review:
The following sections were modified:
02 / 03 / 09 / 11 / 14 / 16.