38MS242N_SDS.pdf
1. CHEMICAL PRODUCT/COMPANY IDENTIFICATION
Name: MS-242N Product Use: Freeze Spray
Quik-Freeze
MANUFACTURER/DISTRIBUTOR: Emergency Phone Number:
(800) 424-9300
Miller-Stephenson Chemical
55 Backus Ave.
Danbury, Conn. 06810 USA
(203) 743-4447
2. HAZARDS IDENTIFICATION
Physical Hazard: Gases under pressure Liquefied Gas
Label elements:
Single Word: Warning
Hazard Statements
Contains gas under pressure; may explode if heated.
May displace oxygen and cause rapid suffocation.
Precautionary Statements
Protect from sunlight.
Store in a well-ventilated place.
Pressurized container. Do not pierce or burn, even after use.
Other Hazards
Vapors are heavier than air and can cause suffocation by reducing oxygen available for breathing. Misuse or intentional inhalation
abuse may lead to death without warning symptoms, due to cardiac effects. Rapid evaporation of the product may cause frostbite.
MS-242N pg. 2 of 6
3. INGREDIENTS
Material (s) CAS No. Approximate %
1,1,1,2 Tetrafluoroethane 811-97-2 100
4. FIRST AID MEASURES
Inhalation: Remove patient to fresh air. Get medical attention.
Eye: Get medical attention immediately.
Skin: Thaw frosted parts with lukewarm water. Do not rub affected area. Get medical attention immediately.
Oral: Ingestion is not considered a potential route of exposure.
Most important symptoms/effects, acute and delayed: May cause cardiac arrhythmia.
Other symptoms potentially related to misuse or inhalation abuse: Cardiac sensitization, Anaesthetic effects, Light-headedness,
Dizziness, Confusion, Lack of coordination, Drowsiness, Unconsciousness.
Contact with liquid or refrigerated gas can cause cold burns or frostbite.
Notes to Physician: Treat symptomatically and supportively.
5. FIRE FIGHTING MEASURES
Suitable Extinguishing Media: Not applicable. Will not burn.
Unsuitable extinguishing media: Not applicable. Will not burn.
Special hazards: Aerosol cans may rupture under fire conditions Exposure to combustion products may be hazardous to health.
Hazardous combustion products: Hydrogen fluoride, Carbonyl fluoride, Carbon oxides.
Specific extinguishing methods: Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment. Evacuate personnel to safe areas. Cool containers with water spray. Fight fire remotely due to risk of explosion.
Protective Equipment for Fire-Fighters: Self-contained breathing apparatus if necessary. Use personal protective equipment.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures: Aerosols can explode when heated. Ventilate area. Warn
personnel of this hazard and unprotected personnel should not return until safe to do so. Follow safe handling advice and personal
protective equipment recommendations. Avoid skin contact with leaking liquid (danger of frostbite).
Environmental Precautions: Prevent further leakage or spillage, if safe to do so.
Spill Clean Up Methods: Ventilate area. Local and national regulations may apply to releases and disposal of this material.
MS-242N pg. 3 of 6
7. HANDLING AND STORAGE
Handling: Avoid inhalation of vapors. Use in a well-ventilated area to keep employee exposure below recommended limits. Use an
approved respirator if necessary. Avoid contact with naked flames and hot surfaces as toxic decomposition products can be formed. Do
not get in eyes or on skin.
Storage Conditions: Store in a clean, dry place, not near sources of heat, in direct sunlight or where temperatures exceed 122
o
F/50
o
C.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Limits: TLV (ACGIH) PEL (OSHA) US WEEL
1,1,1,2-Tetrafluoroethane Not Established Not Established 1000 ppm (TWA)
Engineering Measures: Use adequate ventilation. Vapors are heavier than air and if working in confined or poorly ventilated areas,
proper respiratory protection must be used to prevent exceeding the exposure limit.
Respiratory Protection: General and local exhaust ventilation is recommended to maintain vapor exposures below recommended
limits. Where concentrations are above recommended limits or are unknown, appropriate respiratory protection should be worn. Follow
OSHA respirator regulations (29 CFR 1910.134) and use NIOSH/MSHA approved respirators. Protection provided by air purifying
respirators against exposure to any hazardous chemical is limited. Use a positive pressure air supplied respirator if there is any potential
for uncontrolled release, exposure levels are unknown, or any other circumstance where air purifying respirators may not provide
adequate protection.
Eye Protection: Avoid eye contact. Use chemical goggles or safety glasses with side shields.
Skin Protection: Avoid contact with skin. Use gloves impervious to this material. For special applications, we recommend clarifying
the resistance to chemicals of the afore mentioned protective gloves with the glove manufacturer. Wash hands before breaks and at the
end of workday. Breakthrough time is not determined for the product. Change gloves often.
Hygiene Measures: Good personal hygiene practices are always advisable. Do not eat, drink, or smoke when using.
9. PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point: -15
o
F/-26
o
C Percent Volatile by Volume: 100%
Density: 1.21 g/cc at 77
o
F/25
o
C Volatile Organic Compound (VOC): Not applicable
Vapor Density (Air=1): N.A. Vapor Pressure: 5700 hPa at 68
o
F/20
o
C
pH Information: Neutral Solubility in H
2O: 1.5 g/l at 77
o
F/25
o
C
Form: Liquid Gas Aerosol Evaporation Rate (CCl4=1): > 1
Color: Colorless Odor: Faint Ethereal
10. STABILITY AND REACTIVITY
Reactivity: Not classified as a reactivity hazard.
MS-242N pg. 4 of 6
Chemical stability: Stable if used as directed. Follow precautionary advice and avoid incompatible materials and conditions.
Possibility of hazardous reactions: Can react with strong oxidizing agents.
Material and Conditions to Avoid: Heat, flames and sparks. Oxidizing agents.
Decomposition: No hazardous decomposition products are known.
11. TOXICOLOGICAL INFORMATION
Acute Inhalation toxicity:
4 hour, LC50 rat: >567000 ppm
Skin Corrosion/Irritation: Not classified based on available information.
Serious Eye Irritation/ Eye Irritation: Not classified based on available information.
Skin Sensitization: Not classified based on available information.
Respiratory Sensitization: Not classified based on available information
Germ Cell Mutagenicity: Not classified based on available information.
Carcinogenicity: Not classified based on available information.
Reproductive toxicity: Not classified based on available information.
STOT-single exposure: Not classified based on available information.
STOT-repeated exposure: Not classified based on available information.
Aspiration toxicity: Not classified based on available information
12. ECOLOGICAL INFORMATION
Ecotoxicity
96 hour LC50 in Oncorhynchus mykiss (rainbow trout): 450 mg/l
48 hour EC50 in Daphnia magna (Water flea): 980 mg/l
96 hour ErC50 (algae): 142 mg/l
72 hour NOEC in Pseudokirchneriella subcapitata (green algae): 13.2 mg/l
Biodegradability: Not readily biodegradable.
Bioaccumulative potential: Partition coefficient: n-octanol/water: log Pow: 1.06
Mobility in soil: No data available
Other adverse effects
Results of PBT and vPvB assessment: This substance is not considered to be persistent, bioaccumulating and toxic (PBT). This
substance is not considered to be very persistent and very bioaccumulating (vPvB).
13. DISPOSAL CONSIDERATIONS
Dispose of in accordance with local regulations. Do not puncture or incinerate cans.
MS-242N pg. 5 of 6
14. TRANSPORT INFORMATION
U.S. DOT
Proper Shipping Name: Consumer Commodity
Hazard Class: ORM-D
Identification No. None
Packing Group: None
IATA
Proper Shipping Name: 1,1,1,2 Tetrafluoroethane
Hazard Class: 2.2
Identification No. UN 3159
Packing Group: None
(Authorization DOT-SP 10232 for CFR only)
IMDG
Proper Shipping Name: 1,1,1,2 Tetrafluoroethane
Hazard Class: 2.2
Identification No. UN 3159
Packing Group: None
(Authorization DOT-SP 10232 for CFR only)
15. REGULATORY INFORMATION
US FEDERAL REGULATIONS:
TSCA: All ingredients are listed in TSCA inventory.
CERCLA Reportable Quantity: This material does not contain any components with a CERCLA RQ.
SARA 304 Extremely Hazardous Substances Reportable Quantity: This material does not contain any components with a section
304 EHS RQ.
SARA 302 Extremely Hazardous Substances Threshold Planning Quantity: This material does not contain any components with a
section 302 EHS RQ.
SARA 311/312 Hazards: Gases under pressure. Simple Asphyxiant.
SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De
Minimis) reporting levels established by SARA Title III, Section 313.
California Proposition 65: This product does not contain any chemicals known to the State of California to cause cancer and/or birth
defects or other reproductive defects.
INTERNATIONAL INVENTENTORIES:
US TSCA 12(b) Export Notification
None of the ingredients are listed.
CANADA: DSL/NDSL
All ingredients are listed or exempt.
MS-242N pg. 6 of 6
16. OTHER INFORMATION
HMIS Ratings:
Health – 0
Flammability – 0
Physical Hazard – 3
Personal Protective rating to be supplied by user depending on the conditions.
FOR INDUSTRIAL USE ONLY
REVISION DATE: NOVEMBER 2018
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is
designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification.
The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process,
unless specified in the text. Final determination of suitability of any material is the sole responsibility of the user.
38FP4_SDS.pdf
1. IDENTIFICATION
Product identifier
Product Name FIBREEN 208
Other means of identification
Product Code HEF106
Synonyms None
Recommended use of the chemical and restrictions on use
Recommended Use Building and construction work
Uses advised against No information available
2. HAZARDS IDENTIFICATION
Classification
OSHA Regulatory Status
This article doesn’t contain hazardous substances or mixtures intended to be released under normal or reasonably foreseeable
conditions of use This chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR
1910.1200) and Canadian Workplace Hazardous Material Information System (WHMIS)
Label elements
Emergency Overview
Precautionary Statements – Prevention
Not applicable
_____________________________________________________________________________________________
Page 1 / 7
Version 1
Hazard statements
None
SAFETY DATA SHEET
Issue Date 09-Mar-2023
Not classified
Revision Date 09-Mar-2023
Physical state Solid Odor SlightAppearance sheet
_____________________________________________________________________________________________
Precautionary Statements – Response
Not applicable
Hazards not otherwise classified (HNOC)
Not applicable
Other Information
Not applicable. Unknown acute toxicity
0% of the mixture consists of ingredient(s) of unknown toxicity
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance
Not applicable Mixture
This article doesn’t contain hazardous substances or mixtures intended to be released under normal or reasonably foreseeable
conditions of use.
Chemical Name CAS No Weight-%
Kraft paper * PAPER 60 – 80
Asphalt, oxidized * 64742-93-4 15 – 40
Glass, oxide, chemicals * 65997-17-3 1 – 5
*The exact percentage (concentration) of composition has been withheld as a trade secret.
4. FIRST AID MEASURES
Description of first aid measures
General advice In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible). If symptoms persist, call a physician.
Eye contact Keep eye wide open while rinsing. Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. If symptoms persist, call a physician.
Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. If symptoms persist, call a physician. Wash contaminated clothing before reuse.
Inhalation Remove to fresh air. If breathing is irregular or stopped, administer artificial respiration. Avoid direct contact with skin. Use barrier to give mouth-to-mouth resuscitation. If symptoms persist, call a physician.
Ingestion Call a physician or poison control center immediately. Do not induce vomiting without medical advice. Rinse mouth. Never give anything by mouth to an unconscious person.
Self-protection of the first aiderUse personal protective equipment as required.
Most important symptoms and effects, both acute and delayed
Symptoms None known.
Indication of any immediate medical attention and special treatment needed
Note to physicians Treat symptomatically.
_____________________________________________________________________________________________
Page 2 / 7
HEF106 – FIBREEN 208 Revision Date 09-Mar-2023
_____________________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Dry chemical, CO2,
sand, earth, water spray or regular foam.
Unsuitable extinguishing mediaDo not use a solid water stream as it may scatter and spread fire.
Specific hazards arising from the chemical
Thermal decomposition can lead to release of irritating and toxic gases and vapors.
Explosion data
Sensitivity to Mechanical ImpactNone.
Sensitivity to Static DischargeNone.
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions Use personal protective equipment as required.
Environmental precautions
Environmental precautions Collect spillage. Dispose of contents/container to an approved waste disposal plant.
Methods and material for containment and cleaning up
Methods for containment No information available.
Methods for cleaning up Pick up and transfer to properly labeled containers.
7. HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Use personal protective equipment as required.
Conditions for safe storage, including any incompatibilities
Storage Conditions Keep container tightly closed in a dry and well-ventilated place.
Incompatible materials Strong oxidizing agents. Strong acids. Strong bases.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines This article doesn’t contain hazardous substances or mixtures intended to be released under normal or reasonably foreseeable conditions of use.
Chemical Name ACGIH TLV OSHA PEL NIOSH REL/IDLH
Glass, oxide, chemicals
65997-17-3
TWA: 1 fiber/cm3 respirable fibers:
length >5 m, aspect ratio >=3:1, as
determined by the membrane filter
method at 400-450X magnification
[4-mm objective], using
phase-contrast illumination
TWA: 5 mg/m
3
inhalable particulate
matter
– –
_____________________________________________________________________________________________
Page 3 / 7
HEF106 – FIBREEN 208 Revision Date 09-Mar-2023
_____________________________________________________________________________________________
Appropriate engineering controls
Engineering Controls Showers
Eyewash stations
Ventilation systems.
Individual protection measures, such as personal protective equipment
Eye/face protection Wear safety glasses with side shields (or goggles).
Skin and body protection Wear protective gloves and protective clothing.
Respiratory protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations.
General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical state Solid
Explosive properties Not an explosive
Oxidizing properties Not applicable
Other Information
Softening point No information available
Molecular weight No information available
VOC Content (%) No information available
Density No information available
Bulk density No information available
10. STABILITY AND REACTIVITY
Reactivity
_____________________________________________________________________________________________
Page 4 / 7
Color
Vapor density No information available
Melting point / freezing point No information available
Relative density >1
Tan To black
Water solubility Insoluble in water
Solubility in other solvents No information available
Boiling point / boiling range No information available
Partition coefficient No information available
Odor threshold
Autoignition temperature >232 C / >450 F
No information available
Flash point
Decomposition temperature No information available
No information available
Appearance
Kinematic viscosity No information available Not applicable
sheet
Dynamic viscosity No information available Not applicable
Evaporation rate No information available
HEF106 – FIBREEN 208
Not applicable
Property
Flammability (solid, gas) No information available
Values
Odor
Flammability Limit in Air
5 H P D U N V 0 H W K R G
Slight
Upper flammability limit: No information available
pH Not applicable
Lower flammability limit: No information available
No data available
Revision Date 09-Mar-2023
Vapor pressure 0
_____________________________________________________________________________________________
Chemical stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None under normal processing. Conditions to avoid
Storage near to reactive materials. elevated temperature. Incompatible materials
Strong oxidizing agents. Strong acids. Strong bases. Hazardous Decomposition Products
Thermal decomposition can lead to release of irritating and toxic gases and vapors.
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Product Information
Inhalation None known.
Eye contact None known.
Skin contact None known.
Ingestion Based on available data, the classification criteria are not met.
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
Asphalt, oxidized
64742-93-4
> 5000 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) –
Information on toxicological effects
Symptoms No information available.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization Based on available data, the classification criteria are not met.
Germ cell mutagenicity Based on available data, the classification criteria are not met.
Carcinogenicity Based on available data, the classification criteria are not met.
Chemical Name ACGIH IARC NTP OSHA
Asphalt, oxidized 64742-93-4
– Group 2A – X
Glass, oxide, chemicals 65997-17-3
– Group 3 – –
IARC (International Agency for Research on Cancer)
Group 2A – Probably Carcinogenic to Humans
Group 3 – Not Classifiable as to Carcinogenicity in Humans
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
X – Present
Reproductive toxicity Based on available data, the classification criteria are not met.
STOT – single exposure Based on available data, the classification criteria are not met.
STOT – repeated exposure Based on available data, the classification criteria are not met.
Aspiration hazard Based on available data, the classification criteria are not met.
Numerical measures of toxicity – Product Information
12. ECOLOGICAL INFORMATION
Ecotoxicity
None known
Chemical Name Algae/aquatic plants Fish Crustacea
Asphalt, oxidized 56: 72 h Pseudokirchneriella – –
_____________________________________________________________________________________________
Page 5 / 7
Revision Date 09-Mar-2023HEF106 – FIBREEN 208
_____________________________________________________________________________________________
64742-93-4 subcapitata mg/L EC50
Persistence and degradability
No information available.
Bioaccumulation
Other adverse effects
No information available
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and
regulations.
Contaminated packaging Do not reuse container.
14. TRANSPORT INFORMATION
DOT Not regulated
TDG Not regulated
IATA Not regulated
IMDG Not regulated
15. REGULATORY INFORMATION
International Inventories
TSCA Complies
DSL/NDSL Complies
EINECS/ELINCS Complies
IECSC Complies
KECL Complies
PICCS Complies
AICS Complies
Legend:
TSCA – United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL – Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS – European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS – Japan Existing and New Chemical Substances
IECSC – China Inventory of Existing Chemical Substances
KECL – Korean Existing and Evaluated Chemical Substances
PICCS – Philippines Inventory of Chemicals and Chemical Substances
AICS – Australian Inventory of Chemical Substances
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
SARA 311/312 Hazard Categories
_____________________________________________________________________________________________
Page 6 / 7
HEF106 – FIBREEN 208 Revision Date 09-Mar-2023
_____________________________________________________________________________________________
Acute health hazard No
Chronic Health Hazard No
Fire hazard No
Sudden release of pressure hazard No
Reactive Hazard No
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material
US State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals
U.S. State Right-to-Know Regulations
Chemical Name New Jersey Massachusetts Pennsylvania
Asphalt, oxidized
64742-93-4
X – –
U.S. EPA Label Information
EPA Pesticide Registration NumberNot applicable
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION
Issue Date 09-Mar-2023
Revision Date 09-Mar-2023
Revision Note
No information available
Procedure used to derive the classification
Disclaimer
The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief
at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text.
End of Safety Data Sheet
_____________________________________________________________________________________________
Page 7 / 7
HMIS
NFPA
Health hazards 0
Revision Date 09-Mar-2023
Flammability 1 Physical hazards 0 Personal protection X
Health hazards 0 Flammability 1 Instability 0
HEF106 – FIBREEN 208
Physical and Chemical Properties –
38FP3_SDS.pdf
1. IDENTIFICATION
Product identifier
Product Name FIBREEN 208
Other means of identification
Product Code HEF106
Synonyms None
Recommended use of the chemical and restrictions on use
Recommended Use Building and construction work
Uses advised against No information available
2. HAZARDS IDENTIFICATION
Classification
OSHA Regulatory Status
This article doesn’t contain hazardous substances or mixtures intended to be released under normal or reasonably foreseeable
conditions of use This chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR
1910.1200) and Canadian Workplace Hazardous Material Information System (WHMIS)
Label elements
Emergency Overview
Precautionary Statements – Prevention
Not applicable
_____________________________________________________________________________________________
Page 1 / 7
Version 1
Hazard statements
None
SAFETY DATA SHEET
Issue Date 09-Mar-2023
Not classified
Revision Date 09-Mar-2023
Physical state Solid Odor SlightAppearance sheet
_____________________________________________________________________________________________
Precautionary Statements – Response
Not applicable
Hazards not otherwise classified (HNOC)
Not applicable
Other Information
Not applicable. Unknown acute toxicity
0% of the mixture consists of ingredient(s) of unknown toxicity
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance
Not applicable Mixture
This article doesn’t contain hazardous substances or mixtures intended to be released under normal or reasonably foreseeable
conditions of use.
Chemical Name CAS No Weight-%
Kraft paper * PAPER 60 – 80
Asphalt, oxidized * 64742-93-4 15 – 40
Glass, oxide, chemicals * 65997-17-3 1 – 5
*The exact percentage (concentration) of composition has been withheld as a trade secret.
4. FIRST AID MEASURES
Description of first aid measures
General advice In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible). If symptoms persist, call a physician.
Eye contact Keep eye wide open while rinsing. Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. If symptoms persist, call a physician.
Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. If symptoms persist, call a physician. Wash contaminated clothing before reuse.
Inhalation Remove to fresh air. If breathing is irregular or stopped, administer artificial respiration. Avoid direct contact with skin. Use barrier to give mouth-to-mouth resuscitation. If symptoms persist, call a physician.
Ingestion Call a physician or poison control center immediately. Do not induce vomiting without medical advice. Rinse mouth. Never give anything by mouth to an unconscious person.
Self-protection of the first aiderUse personal protective equipment as required.
Most important symptoms and effects, both acute and delayed
Symptoms None known.
Indication of any immediate medical attention and special treatment needed
Note to physicians Treat symptomatically.
_____________________________________________________________________________________________
Page 2 / 7
HEF106 – FIBREEN 208 Revision Date 09-Mar-2023
_____________________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Dry chemical, CO2,
sand, earth, water spray or regular foam.
Unsuitable extinguishing mediaDo not use a solid water stream as it may scatter and spread fire.
Specific hazards arising from the chemical
Thermal decomposition can lead to release of irritating and toxic gases and vapors.
Explosion data
Sensitivity to Mechanical ImpactNone.
Sensitivity to Static DischargeNone.
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions Use personal protective equipment as required.
Environmental precautions
Environmental precautions Collect spillage. Dispose of contents/container to an approved waste disposal plant.
Methods and material for containment and cleaning up
Methods for containment No information available.
Methods for cleaning up Pick up and transfer to properly labeled containers.
7. HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Use personal protective equipment as required.
Conditions for safe storage, including any incompatibilities
Storage Conditions Keep container tightly closed in a dry and well-ventilated place.
Incompatible materials Strong oxidizing agents. Strong acids. Strong bases.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines This article doesn’t contain hazardous substances or mixtures intended to be released under normal or reasonably foreseeable conditions of use.
Chemical Name ACGIH TLV OSHA PEL NIOSH REL/IDLH
Glass, oxide, chemicals
65997-17-3
TWA: 1 fiber/cm3 respirable fibers:
length >5 m, aspect ratio >=3:1, as
determined by the membrane filter
method at 400-450X magnification
[4-mm objective], using
phase-contrast illumination
TWA: 5 mg/m
3
inhalable particulate
matter
– –
_____________________________________________________________________________________________
Page 3 / 7
HEF106 – FIBREEN 208 Revision Date 09-Mar-2023
_____________________________________________________________________________________________
Appropriate engineering controls
Engineering Controls Showers
Eyewash stations
Ventilation systems.
Individual protection measures, such as personal protective equipment
Eye/face protection Wear safety glasses with side shields (or goggles).
Skin and body protection Wear protective gloves and protective clothing.
Respiratory protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations.
General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical state Solid
Explosive properties Not an explosive
Oxidizing properties Not applicable
Other Information
Softening point No information available
Molecular weight No information available
VOC Content (%) No information available
Density No information available
Bulk density No information available
10. STABILITY AND REACTIVITY
Reactivity
_____________________________________________________________________________________________
Page 4 / 7
Color
Vapor density No information available
Melting point / freezing point No information available
Relative density >1
Tan To black
Water solubility Insoluble in water
Solubility in other solvents No information available
Boiling point / boiling range No information available
Partition coefficient No information available
Odor threshold
Autoignition temperature >232 C / >450 F
No information available
Flash point
Decomposition temperature No information available
No information available
Appearance
Kinematic viscosity No information available Not applicable
sheet
Dynamic viscosity No information available Not applicable
Evaporation rate No information available
HEF106 – FIBREEN 208
Not applicable
Property
Flammability (solid, gas) No information available
Values
Odor
Flammability Limit in Air
5 H P D U N V 0 H W K R G
Slight
Upper flammability limit: No information available
pH Not applicable
Lower flammability limit: No information available
No data available
Revision Date 09-Mar-2023
Vapor pressure 0
_____________________________________________________________________________________________
Chemical stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None under normal processing. Conditions to avoid
Storage near to reactive materials. elevated temperature. Incompatible materials
Strong oxidizing agents. Strong acids. Strong bases. Hazardous Decomposition Products
Thermal decomposition can lead to release of irritating and toxic gases and vapors.
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Product Information
Inhalation None known.
Eye contact None known.
Skin contact None known.
Ingestion Based on available data, the classification criteria are not met.
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
Asphalt, oxidized
64742-93-4
> 5000 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) –
Information on toxicological effects
Symptoms No information available.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization Based on available data, the classification criteria are not met.
Germ cell mutagenicity Based on available data, the classification criteria are not met.
Carcinogenicity Based on available data, the classification criteria are not met.
Chemical Name ACGIH IARC NTP OSHA
Asphalt, oxidized 64742-93-4
– Group 2A – X
Glass, oxide, chemicals 65997-17-3
– Group 3 – –
IARC (International Agency for Research on Cancer)
Group 2A – Probably Carcinogenic to Humans
Group 3 – Not Classifiable as to Carcinogenicity in Humans
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
X – Present
Reproductive toxicity Based on available data, the classification criteria are not met.
STOT – single exposure Based on available data, the classification criteria are not met.
STOT – repeated exposure Based on available data, the classification criteria are not met.
Aspiration hazard Based on available data, the classification criteria are not met.
Numerical measures of toxicity – Product Information
12. ECOLOGICAL INFORMATION
Ecotoxicity
None known
Chemical Name Algae/aquatic plants Fish Crustacea
Asphalt, oxidized 56: 72 h Pseudokirchneriella – –
_____________________________________________________________________________________________
Page 5 / 7
Revision Date 09-Mar-2023HEF106 – FIBREEN 208
_____________________________________________________________________________________________
64742-93-4 subcapitata mg/L EC50
Persistence and degradability
No information available.
Bioaccumulation
Other adverse effects
No information available
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and
regulations.
Contaminated packaging Do not reuse container.
14. TRANSPORT INFORMATION
DOT Not regulated
TDG Not regulated
IATA Not regulated
IMDG Not regulated
15. REGULATORY INFORMATION
International Inventories
TSCA Complies
DSL/NDSL Complies
EINECS/ELINCS Complies
IECSC Complies
KECL Complies
PICCS Complies
AICS Complies
Legend:
TSCA – United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL – Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS – European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS – Japan Existing and New Chemical Substances
IECSC – China Inventory of Existing Chemical Substances
KECL – Korean Existing and Evaluated Chemical Substances
PICCS – Philippines Inventory of Chemicals and Chemical Substances
AICS – Australian Inventory of Chemical Substances
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
SARA 311/312 Hazard Categories
_____________________________________________________________________________________________
Page 6 / 7
HEF106 – FIBREEN 208 Revision Date 09-Mar-2023
_____________________________________________________________________________________________
Acute health hazard No
Chronic Health Hazard No
Fire hazard No
Sudden release of pressure hazard No
Reactive Hazard No
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material
US State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals
U.S. State Right-to-Know Regulations
Chemical Name New Jersey Massachusetts Pennsylvania
Asphalt, oxidized
64742-93-4
X – –
U.S. EPA Label Information
EPA Pesticide Registration NumberNot applicable
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION
Issue Date 09-Mar-2023
Revision Date 09-Mar-2023
Revision Note
No information available
Procedure used to derive the classification
Disclaimer
The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief
at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text.
End of Safety Data Sheet
_____________________________________________________________________________________________
Page 7 / 7
HMIS
NFPA
Health hazards 0
Revision Date 09-Mar-2023
Flammability 1 Physical hazards 0 Personal protection X
Health hazards 0 Flammability 1 Instability 0
HEF106 – FIBREEN 208
Physical and Chemical Properties –
38FP2_SDS.pdf
1. IDENTIFICATION
Product identifier
Product Name FIBREEN 208
Other means of identification
Product Code HEF106
Synonyms None
Recommended use of the chemical and restrictions on use
Recommended Use Building and construction work
Uses advised against No information available
2. HAZARDS IDENTIFICATION
Classification
OSHA Regulatory Status
This article doesn’t contain hazardous substances or mixtures intended to be released under normal or reasonably foreseeable
conditions of use This chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR
1910.1200) and Canadian Workplace Hazardous Material Information System (WHMIS)
Label elements
Emergency Overview
Precautionary Statements – Prevention
Not applicable
_____________________________________________________________________________________________
Page 1 / 7
Version 1
Hazard statements
None
SAFETY DATA SHEET
Issue Date 09-Mar-2023
Not classified
Revision Date 09-Mar-2023
Physical state Solid Odor SlightAppearance sheet
_____________________________________________________________________________________________
Precautionary Statements – Response
Not applicable
Hazards not otherwise classified (HNOC)
Not applicable
Other Information
Not applicable. Unknown acute toxicity
0% of the mixture consists of ingredient(s) of unknown toxicity
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance
Not applicable Mixture
This article doesn’t contain hazardous substances or mixtures intended to be released under normal or reasonably foreseeable
conditions of use.
Chemical Name CAS No Weight-%
Kraft paper * PAPER 60 – 80
Asphalt, oxidized * 64742-93-4 15 – 40
Glass, oxide, chemicals * 65997-17-3 1 – 5
*The exact percentage (concentration) of composition has been withheld as a trade secret.
4. FIRST AID MEASURES
Description of first aid measures
General advice In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible). If symptoms persist, call a physician.
Eye contact Keep eye wide open while rinsing. Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. If symptoms persist, call a physician.
Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. If symptoms persist, call a physician. Wash contaminated clothing before reuse.
Inhalation Remove to fresh air. If breathing is irregular or stopped, administer artificial respiration. Avoid direct contact with skin. Use barrier to give mouth-to-mouth resuscitation. If symptoms persist, call a physician.
Ingestion Call a physician or poison control center immediately. Do not induce vomiting without medical advice. Rinse mouth. Never give anything by mouth to an unconscious person.
Self-protection of the first aiderUse personal protective equipment as required.
Most important symptoms and effects, both acute and delayed
Symptoms None known.
Indication of any immediate medical attention and special treatment needed
Note to physicians Treat symptomatically.
_____________________________________________________________________________________________
Page 2 / 7
HEF106 – FIBREEN 208 Revision Date 09-Mar-2023
_____________________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Dry chemical, CO2,
sand, earth, water spray or regular foam.
Unsuitable extinguishing mediaDo not use a solid water stream as it may scatter and spread fire.
Specific hazards arising from the chemical
Thermal decomposition can lead to release of irritating and toxic gases and vapors.
Explosion data
Sensitivity to Mechanical ImpactNone.
Sensitivity to Static DischargeNone.
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions Use personal protective equipment as required.
Environmental precautions
Environmental precautions Collect spillage. Dispose of contents/container to an approved waste disposal plant.
Methods and material for containment and cleaning up
Methods for containment No information available.
Methods for cleaning up Pick up and transfer to properly labeled containers.
7. HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Use personal protective equipment as required.
Conditions for safe storage, including any incompatibilities
Storage Conditions Keep container tightly closed in a dry and well-ventilated place.
Incompatible materials Strong oxidizing agents. Strong acids. Strong bases.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines This article doesn’t contain hazardous substances or mixtures intended to be released under normal or reasonably foreseeable conditions of use.
Chemical Name ACGIH TLV OSHA PEL NIOSH REL/IDLH
Glass, oxide, chemicals
65997-17-3
TWA: 1 fiber/cm3 respirable fibers:
length >5 m, aspect ratio >=3:1, as
determined by the membrane filter
method at 400-450X magnification
[4-mm objective], using
phase-contrast illumination
TWA: 5 mg/m
3
inhalable particulate
matter
– –
_____________________________________________________________________________________________
Page 3 / 7
HEF106 – FIBREEN 208 Revision Date 09-Mar-2023
_____________________________________________________________________________________________
Appropriate engineering controls
Engineering Controls Showers
Eyewash stations
Ventilation systems.
Individual protection measures, such as personal protective equipment
Eye/face protection Wear safety glasses with side shields (or goggles).
Skin and body protection Wear protective gloves and protective clothing.
Respiratory protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations.
General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical state Solid
Explosive properties Not an explosive
Oxidizing properties Not applicable
Other Information
Softening point No information available
Molecular weight No information available
VOC Content (%) No information available
Density No information available
Bulk density No information available
10. STABILITY AND REACTIVITY
Reactivity
_____________________________________________________________________________________________
Page 4 / 7
Color
Vapor density No information available
Melting point / freezing point No information available
Relative density >1
Tan To black
Water solubility Insoluble in water
Solubility in other solvents No information available
Boiling point / boiling range No information available
Partition coefficient No information available
Odor threshold
Autoignition temperature >232 C / >450 F
No information available
Flash point
Decomposition temperature No information available
No information available
Appearance
Kinematic viscosity No information available Not applicable
sheet
Dynamic viscosity No information available Not applicable
Evaporation rate No information available
HEF106 – FIBREEN 208
Not applicable
Property
Flammability (solid, gas) No information available
Values
Odor
Flammability Limit in Air
5 H P D U N V 0 H W K R G
Slight
Upper flammability limit: No information available
pH Not applicable
Lower flammability limit: No information available
No data available
Revision Date 09-Mar-2023
Vapor pressure 0
_____________________________________________________________________________________________
Chemical stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None under normal processing. Conditions to avoid
Storage near to reactive materials. elevated temperature. Incompatible materials
Strong oxidizing agents. Strong acids. Strong bases. Hazardous Decomposition Products
Thermal decomposition can lead to release of irritating and toxic gases and vapors.
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Product Information
Inhalation None known.
Eye contact None known.
Skin contact None known.
Ingestion Based on available data, the classification criteria are not met.
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
Asphalt, oxidized
64742-93-4
> 5000 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) –
Information on toxicological effects
Symptoms No information available.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization Based on available data, the classification criteria are not met.
Germ cell mutagenicity Based on available data, the classification criteria are not met.
Carcinogenicity Based on available data, the classification criteria are not met.
Chemical Name ACGIH IARC NTP OSHA
Asphalt, oxidized 64742-93-4
– Group 2A – X
Glass, oxide, chemicals 65997-17-3
– Group 3 – –
IARC (International Agency for Research on Cancer)
Group 2A – Probably Carcinogenic to Humans
Group 3 – Not Classifiable as to Carcinogenicity in Humans
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
X – Present
Reproductive toxicity Based on available data, the classification criteria are not met.
STOT – single exposure Based on available data, the classification criteria are not met.
STOT – repeated exposure Based on available data, the classification criteria are not met.
Aspiration hazard Based on available data, the classification criteria are not met.
Numerical measures of toxicity – Product Information
12. ECOLOGICAL INFORMATION
Ecotoxicity
None known
Chemical Name Algae/aquatic plants Fish Crustacea
Asphalt, oxidized 56: 72 h Pseudokirchneriella – –
_____________________________________________________________________________________________
Page 5 / 7
Revision Date 09-Mar-2023HEF106 – FIBREEN 208
_____________________________________________________________________________________________
64742-93-4 subcapitata mg/L EC50
Persistence and degradability
No information available.
Bioaccumulation
Other adverse effects
No information available
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and
regulations.
Contaminated packaging Do not reuse container.
14. TRANSPORT INFORMATION
DOT Not regulated
TDG Not regulated
IATA Not regulated
IMDG Not regulated
15. REGULATORY INFORMATION
International Inventories
TSCA Complies
DSL/NDSL Complies
EINECS/ELINCS Complies
IECSC Complies
KECL Complies
PICCS Complies
AICS Complies
Legend:
TSCA – United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL – Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS – European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS – Japan Existing and New Chemical Substances
IECSC – China Inventory of Existing Chemical Substances
KECL – Korean Existing and Evaluated Chemical Substances
PICCS – Philippines Inventory of Chemicals and Chemical Substances
AICS – Australian Inventory of Chemical Substances
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
SARA 311/312 Hazard Categories
_____________________________________________________________________________________________
Page 6 / 7
HEF106 – FIBREEN 208 Revision Date 09-Mar-2023
_____________________________________________________________________________________________
Acute health hazard No
Chronic Health Hazard No
Fire hazard No
Sudden release of pressure hazard No
Reactive Hazard No
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material
US State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals
U.S. State Right-to-Know Regulations
Chemical Name New Jersey Massachusetts Pennsylvania
Asphalt, oxidized
64742-93-4
X – –
U.S. EPA Label Information
EPA Pesticide Registration NumberNot applicable
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION
Issue Date 09-Mar-2023
Revision Date 09-Mar-2023
Revision Note
No information available
Procedure used to derive the classification
Disclaimer
The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief
at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text.
End of Safety Data Sheet
_____________________________________________________________________________________________
Page 7 / 7
HMIS
NFPA
Health hazards 0
Revision Date 09-Mar-2023
Flammability 1 Physical hazards 0 Personal protection X
Health hazards 0 Flammability 1 Instability 0
HEF106 – FIBREEN 208
Physical and Chemical Properties –
38CLAY221_SDS.pdf
Revision date: 4/12/2016 Revision: 1 Supersedes date: 4/12/2016
SAFETY DATA SHEET
Gruber Care Cream Clay
Product identifier
Product name Gruber Care Cream Clay
Recommended use of the chemical and restrictions on use
Application Modelling Clay
Details of the supplier of the safety data sheet
Supplier Marshall-Gruber Company LLC
220 Airport Dr.
Mansfield, TX 76063
USA
Emergency telephone number
Emergency telephone 866-260-6457 Mon-Fri, 0800-1700 CST
Classification of the substance or mixture
Physical hazards Not Classified
Health hazards Not Classified
Environmental hazards Not Classified
Label elements
Hazard statements NC Not Classified
Other hazards
none present.
Mixtures
Composition comments Only ingredients listed above are notifiable for this product. If none are shown then all
ingredients are exempt.
Description of first aid measures
Inhalation Unlikely route of exposure as the product does not contain volatile substances.
Ingestion Do not induce vomiting. Rinse mouth thoroughly with water. Give a few small glasses of water
or milk to drink. Get medical attention if any discomfort continues.
Skin Contact Wash skin thoroughly with soap and water.
Eye contact Rinse with water.
Most important symptoms and effects, both acute and delayed
Inhalation Read Section 2 for any specific precautions associated with this product. In general, breathing
any type of dust/mist can and may aggravate irritation of the throat and lungs.
1/6
4. First-aid measures
3. Composition/information on ingredients
2. Hazard(s) identification
1. Identification
Revision date: 4/12/2016 Revision: 1 Supersedes date: 4/12/2016
Gruber Care Cream Clay
Ingestion Read Section 2 for any specific precautions associated with the use of this product. Products
with specific warnings about ingestion will give guidance there.
Skin contact Read Section 2 for any specific precautions associated with the use of this product. In general
most ceramic glazes, clays and special products will tend to have a drying effect on the skin
and may cause some sensitivity to users with sensitive skin.
Eye contact Read Section 2 for any specific precautions associated with the use of this product. In general
most ceramic and special products contain materials that maybe abrasive to eyes. Keeping
materials from contacting the eyes is prudent. If contact does occur, flush with clean water, do
not rub.
Indication of immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.
Extinguishing media
Suitable extinguishing media Use fire-extinguishing media suitable for the surrounding fire.
Special hazards arising from the substance or mixture
Specific hazards The product is not believed to present a hazard due to its physical nature.
Advice for firefighters
Special protective equipment Use protective equipment appropriate for surrounding materials.
for firefighters
Personal precautions, protective equipment and emergency procedures
Personal precautions For personal protection, see Section 8.
Environmental precautions
Environmental precautions Please read Section 2 completely. If any environmental warnings such as; H411 or H412 are
listed in Section 2, please use appropriate procedures when disposing of product and
container. Do not put materials into waterways or sewers.
Methods and material for containment and cleaning up
Methods for cleaning up Collect spillage for reclamation or absorb in vermiculite, dry sand or similar material.
Reference to other sections For waste disposal, see Section 13. For personal protection, see Section 8.
Precautions for safe handling
Usage precautions Read label before use. Do not eat, drink or smoke when using this product. Good personal
hygiene procedures should be implemented. Wash hands and any other contaminated areas
of the body with soap and water before leaving the work site.
Conditions for safe storage, including any incompatibilities
Storage precautions Store in tightly-closed, original container in a dry and cool place.
Specific end uses(s)
Specific end use(s) The identified uses for this product are detailed in Section 1.2.
2/6
8. Exposure Controls/personal protection
7. Handling and storage
6. Accidental release measures
5.Fire-fighting measures
Revision date: 4/12/2016 Revision: 1 Supersedes date: 4/12/2016
Gruber Care Cream Clay
Ingredient comments Only ingredients listed n Section 3 are notifiable for this product. If none are shown then all
ingredients are exempt.
Exposure controls
Appropriate engineering
controls
No specific ventilations requirements unless the FAN pictogram is shown above or specified
in Section 2.
Eye/face protection No specific eye protection required unless the “EYE PROTECTION pictogram is shown
above or specified in Section 2.
Hand protection No specific hand protection required unless the HAND PROTECTION pictogram is shown
above or specified in Section 2.
Hygiene measures Using good personal hygiene practices is always appropriate. Keeping a clean work space,
cleaning up properly when done, and not eating, drinking or smoking when using this product.
Respiratory protection No specific respiratory protection required unless the RESPIRATOR pictogram is shown
above or specified in Section 2. Using the appropriate certified protection for the operation is
important if required.
Information on basic physical and chemical properties
Appearance Solid.
Color Various colors.
Odor Almost odorless.
Odor threshold No information available.
pH 6-8
Melting point No information available.
Initial boiling point and range No information available.
Flash point No information available.
Evaporation rate No information available.
Flammability (solid, gas) No information available.
Upper/lower flammability or
explosive limits
No information available.
Vapour pressure No information available.
Relative density Greater than 1.0
Solubility(ies) Not applicable.
Partition coefficient No information available.
Auto-ignition temperature Not applicable.
Decomposition Temperature No information available.
Viscosity No information available.
Explosive properties none
Oxidising properties none
Other information Not applicable.
3/6
9. Physical and Chemical Properties
Revision date: 4/12/2016 Revision: 1 Supersedes date: 4/12/2016
Gruber Care Cream Clay
Reactivity There are no known reactivity hazards associated with this product.
Stability No particular stability concerns.
Possibility of hazardous
reactions
None known.
Conditions to avoid None known.
Materials to avoid None known.
Hazardous decomposition
products
None known.
Information on toxicological effects
Toxicological effects Please read Section 2 thoroughly to understand the toxicological risks, (if any) and
precautions for safe use (if any).
Skin corrosion/irritation
Skin sensitization
Skin sensitisation Based on available data the classification criteria are not met.
Eye contact May cause temporary eye irritation.
Ecotoxicity Please read Section 2 completely. If any environmental warnings such as; H411 or H412 are
listed in Section 2, please use appropriate procedures when disposing of product and
container. Do not put materials into waterways or sewers.
Toxicity
Toxicity Please read Section 2 completely. If any environmental warnings such as; H411 or H412 are
listed in Section 2, please use appropriate procedures when disposing of product and
container. Do not put materials into waterways or sewers.
Persistence and degradability
Persistence and degradability No data available.
Biodegradation Not inherently biodegradable.
Bioaccumulative potential
Partition coefficient No information available.
Mobility in soil
Mobility Semi-mobile.
Results of PBT and vPvB assessment
Results of PBT and vPvB
assessment
This product does not contain any substances classified as PBT or vPvB.
Other adverse effects
4/6
12. Ecological Information
11. Toxicological information
10. Stability and reactivity
Revision date: 4/12/2016 Revision: 1 Supersedes date: 4/12/2016
Gruber Care Cream Clay
Other adverse effects None known.
Waste treatment methods
General information Dispose of waste product or used containers in accordance with local regulations When
handling waste, the safety precautions applying to handling of the product should be
considered.
General The product is not covered by international regulations on the transport of dangerous goods
(IMDG, IATA, DoT).
UN Number
Not applicable.
UN proper shipping name
Not applicable.
Transport hazard class(es)
No transport warning sign required.
Packing group
Not applicable.
Environmental hazards
Environmentally Hazardous Substance
Please refer to Section 2 for any environmental hazards associated with this product. If H411/H412 warnings are shown then
please verify packaging and labeling requirements for larger volumes.
Special precautions for user
Not applicable.
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code
US State Regulations
California Proposition 65 Carcinogens and Reproductive Toxins
None of the ingredients are listed or exempt.
Inventories
Canada – DSL/NDSL
All the ingredients are listed or exempt.
US – TSCA
All the ingredients are listed or exempt.
US – TSCA 12(b) Export Notification
All the ingredients are listed or exempt.
5/6
16. Other information
15. Regulatory information
14. Transport information
13. Disposal considerations
Revision date: 4/12/2016 Revision: 1 Supersedes date: 4/12/2016
Gruber Care Cream Clay
General information The following are the top 5 materials by weight listed for New Jersey (if applicable):- Calcium
Sulfate7778-18-9, Hydrated Aluminum Silicate1332-58-7, Petrolaum8009-03-8, Various
Pigments
Revision date 4/12/2016
Revision 1
Supersedes date 4/12/2016
SDS No. 5928
This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is, to the best of the company’s knowledge and belief, accurate
and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or
completeness. It is the user’s responsibility to satisfy himself as to the suitability of such information for his own particular use.
6/6
382986_SDS.pdf
PRODUCT NAME: Flame-a-guard 2 & 3 booth floor papers SDS#: SDS-26
Page 1 of 7
SAFETY DATA SHEET
Carlisle Fluid Technologies, Inc .
PRODUCT RELATED HEALTH DATA SHEET
1. IDENTIFICATION of the SUBSTANCE/MIXTURE and of the
COMPANY
1.1 Product identifier
Product Name : Flame-a-guard 2 & 3 booth floor papers
Product Code : Part No.29-843, 29-844, 29-863, 29-864, 29-865, 29-866, 29-872,
29-873, 29-874 and 29-875
Product Description : Spray Booth Floor Paper
SDS # : SDS-26 REVISION #: 2.0.4
CHEMICAL FORMULA: Coated Paper
CAS NUMBER : Not Applicable.
Article Code : Not Applicable.
GENERAL USE : Paint booth floor covering.
DATE REVISED: 02/01/2017 DATE PREPARED: 05/12/2015
1.2 Relevant identified uses of the substance or mixture and uses advised against
Not applicable.
1.3 Details of the supplier of the safety data sheet
Carlisle Fluid Technologies, Inc.
16430 North Scottsdale Road
Scottsdale, AZ 85254
Technical service number 1-888-992-4657
1.4 Emergency telephone number
Emergency Number – INFOTRAC
EMERGENCY PHONE (24 HOURS):
1-8OO-535-5053
2. HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture
Product definition : Article
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS] : Not classified.
Ingredients of unknown : None known.
toxicity
Ingredients of unknown : None known.
ecotoxicity
Classification according to Directive 1999/45/EC [DPD]
The product is not classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification : Not classified.
See Section 16 for the full text of the R phrases or H statements declared above.
See Section 11 for more detailed information on health effects and symptoms.
2.2 Label elements
Hazard pictograms : No pictogram.
Signal word : No signal word.
Hazard statements : No known significant effects or critical hazards
Precautionary statements
Prevention : Caution.
Response : Not applicable.
Storage : P210: Keep away from heat/sparks/open flames/hot surfaces No smoking.
Disposal : Not applicable.
PRODUCT NAME: Flame-a-guard 2 & 3 booth floor papers SDS#: SDS-26
Page 2 of 7
Hazardous ingredients : None known.
Supplemental label : Cellulose pulp, recycled, biodegradable
elements
Special packaging requirements
Containers to be fitted : Not applicable.
with child-resistant
fastenings
Tactile warning of danger :Not applicable.
2.3 Other hazards
Other hazards which do not result in classification
Properties affecting health : Harmful if swallowed.
Principle routes of exposure : Skin, eye, inhalation, ingestion.
Skin contact : Superficial laceration (paper cuts) may occur.
Eye contact : Direct contact with eyes may cause temporary irritation as a foreign object in the eye.
Inhalation : No health effects expected with normal use of product.
Ingestion : May result in obstruction and temporary irritation of the digestive tract.
Chronic Effects: not applicable
Medical Conditions Aggravated by Long-Term Exposure: asthma, allergies
Target Organs: skin and eyes
Signs and Symptoms: Adverse allergic reactions to paper dust may result in, but are not limited to, redness and irritation of
the eyes and skin. If such a reaction occurs, seek medical attention.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Ingredient: Cellulose pulp, recycled, biodegradable Wt. %: 60 100 CAS#: 65996-61-4
This material is considered to be an Article under 29 CFR 1910.1200 (Hazard Communication). The information in
this MSDS is provided for situations where this article may be deformed creating dusts which may be potentially
hazardous. The trade secret components of this product are non-hazardous based on the manufacturer s hazard
evaluation.
4. FIRST AID MEASURES
4.1 Description of first aid measures
EYE CONTACT : If irritation occurs, flush eyes with water. Remove contact lenses if worn. If abrasion or
scratch occurs, seek medical attention.
INHALATION : Not a normal route of exposure.
SKIN CONTACT : If irritation occurs due to dust, flush skin with water. If minor laceration occurs, wash with
antibacterial soap and bandage.
INGESTION : If product is swallowed and obstruction occurs, seek medical attention.
Protection of first-aiders : No known significant effects or critical hazards.
4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact : No known significant effects or critical hazards.
Inhalation : No known significant effects or critical hazards.
Skin contact : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : No specific data.
Inhalation : No specific data.
Skin contact : No specific data.
Ingestion : No specific data.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : Symptoms may not appear immediately.
Specific treatments : No specific treatment.
PRODUCT NAME: Flame-a-guard 2 & 3 booth floor papers SDS#: SDS-26
Page 3 of 7
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media
Suitable extinguishing media : Water, multi-purpose dry chemical.
Unsuitable extinguishing media : None known.
5.2 Special hazards arising from the substance or mixture
Flammability class : None. Fire retardant paper will not add to flammability.
Fire retardant method : T461 cm-00
Flash Point : 662 F, 350 C
Autoignition Temperature : Unknown.
Sensitivity to Static Discharge : None.
Hazards from the substance or mixture : None.
Unusual Fire and Explosion Hazards : Undetermined.
Hazardous combustion products : Carbon monoxide, carbon dioxide.
5.3 Advice for firefighters
Special precautions for fire-fighters : None.
Special protective equipment for : Fire-fighters should wear appropriate protective equipment and self-
fire-fighters contained breathing apparatus (SCBA) with a full face-piece operated in
positive pressure mode. Clothing for fire-fighters (including helmets,
protective boots and gloves) conforming to European standard EN 469 will
provide a basic level of protection for chemical incidents.
NFPA RATING: See Section 15.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any
information regarding personal protective equipment in Section 8.
6.2 Environmental precautions : Keep out of drains, sewers, ditches and waterways. If paper material does not have any
paint on the surface it is biodegradable and incinerable.
6.3 Methods and materials for containment and cleaning up
Small spill : Scoop up material and place in a disposal container.
Large spill : Pick up large pieces and place in a suitable container. Dispose of via a licensed waste
disposal contractor depending on paper contamination. Note: see section 13 for waste
disposal.
6.4 Reference to other sections : See Section 1 for emergency contact information.
See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling
Protective measures : Gloves recommended for the protection of hands against superficial lacerations (paper
cuts) and in case of allergic reaction. Handle with care to prevent physical damage to
product. Avoid product contact with water. (see Section 8 for additional information)
Advice on general occupational : Eating, drinking and smoking should be prohibited in areas where this material is
hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking.
7.2 Conditions for safe storage, : Store in a cool, dry location away from flames and sparks. Avoid prolonged
including any incompatibilities exposure in direct sunlight.
P210: Keep away from heat/sparks/open flames/hot surfaces No smoking
PRODUCT NAME: Flame-a-guard 2 & 3 booth floor papers SDS#: SDS-26
Page 4 of 7
7.3 Specific end use(s)
Recommendations : Not available.
Industrial sector specific solutions : Not available.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 Control parameters
Ingredients
Exposure Limits
Cellulose pulp OSHA-PEL: not available ACGIH-TLV: not available
Kaolin OSHA-PEL: 15 mg/m ACGIH-TLV: 2 mg/m
Ammonium hydrogen sulfate OSHA-PEL: not available ACGIH-TLV: not available
8.2 Exposure controls
Appropriate engineering : Use ventilation adequate to keep exposures (airborne levels of dust, fume,
controls vapor, etc.) below recommended exposure limits.
Personal Protection Equipment
Eye Protection : Safety glasses recommended, none required.
Skin Protection : Gloves recommended, none required.
Respiratory Protection : None required.
Other protective clothing: None.
Hygienic Practices: Handle according to established hygiene and safety practices. Wash hands after handling
recommended.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties
Physical state : Solid.
Color : White.
Odor : Odorless.
Appearance : Opaque paper.
pH : Not available.
Melting point/freezing point : Not available.
Initial boiling point and : Not available.
boiling range
Flash point : 662 F, 350 C.
Flammability (solid, gas) : Not available.
Burning time : Not applicable.
Burning rate : Not applicable.
Upper/lower flammability or : Not available.
explosive limits
Vapor pressure : Not available.
Density : Not available.
Solubility(ies) : Not available.
Partition coefficient: : Not available.
n- octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Not available.
Explosive properties : Not available.
VOC : None.
Oxidizing properties : Not available.
9.2 Other information
No additional information.
PRODUCT NAME: Flame-a-guard 2 & 3 booth floor papers SDS#: SDS-26
Page 5 of 7
10. STABILITY AND REACTIVITY
10.1 Reactivity : Avoid open flames and sparks.
10.2 Chemical stability : Stable under normal storage conditions.
10.3 Possibility of hazardous : No dangerous reaction known under conditions of normal use.
reactions
10.4 Conditions to avoid : Avoid open flames and sparks.
10.5 Incompatible materials : None known.
10.6 Hazardous decomposition : May include, and are not limited to, oxides of carbon.
products
11. TOXICOLOGICAL INFORMATION
11.1 Acute toxicity
Effects of Acute Exposure : Not applicable.
(LD50 oral and LC50)
11.2 Acute toxicity estimates
Conclusion/Summary : Not applicable.
11.3 Irritation/Corrosion
Conclusion/Summary : Not available.
11.4 Sensitizer
Conclusion/Summary : Not available.
11.5 Mutagenicity
Conclusion/Summary : Not available.
11.6 Carcinogenicity
Conclusion/Summary : Not available.
11.7 Reproductive toxicity
Conclusion/Summary : Not available.
11.8 Teratogenicity
Conclusion/Summary : Not available.
11.9 Specific target organ toxicity (single exposure)
Not hazardous.
11.10 Specific target organ toxicity (repeated exposure)
Conclusion/Summary : Not hazardous.
11.11 Aspiration hazard
Conclusion/Summary : Not hazardous.
11.12 Information on the likely routes of exposure : Not hazardous.
11.13 Potential acute health effects
Inhalation : Not applicable for product in purchased form.
Ingestion : May result in obstruction and temporary irritation of the digestive tract.
Skin contact : Not applicable for product in purchased form. Adverse allergic reactions may
result in, but are not limited to, redness and irritation.
Eye contact : Not applicable for product in purchased form. Adverse allergic reactions may
result in, but are not limited to, redness and irritation.
11.4 Symptoms related to the physical, chemical and toxicological characteristics
Inhalation : No specific data.
Ingestion : No specific data.
Skin contact : No specific data.
Eye contact : No specific data.
11.15 Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate effects : Not available.
Potential delayed effects : Not available.
Long term exposure
Potential immediate effects : Not hazardous.
PRODUCT NAME: Flame-a-guard 2 & 3 booth floor papers SDS#: SDS-26
Page 6 of 7
Potential delayed effects : Not hazardous.
11.16 Potential chronic health effects
Effects of Chronic Exposure : Not hazardous.
General : No known significant effects or critical hazards.
Carcinogenicity (IARC, ACGIH) : None
Mutagenicity : Not hazardous.
Teratogenicity : Not hazardous.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
11.17 Other information : Not available.
12. ECOLOGICAL INFORMATION
12.1 Toxicity
Aquatic
Conclusion/Summary : May cause long-term adverse effects in the aquatic environment. Not
expected to produce significant ecotoxicity upon exposure to aquatic
organisms and aquatic systems.
R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
12.2 Persistence
Conclusion/Summary : Not available.
12.3 Bioaccumulation/Accumulation
Conclusion/Summary : Not available.
12.4 Mobility/Persistence in soil
Conclusion/Summary : Not available.
12.5 Degradability/Leaching
Conclusion/Summary : Not available.
12.6 Environmental Fate
Conclusion/Summary : Not available.
12.7 Other adverse effects : No known significant effects or critical hazards.
13. DISPOSAL CONSIDERATIONS
The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).
13.1 Waste treatment methods
Methods of disposal : Clean floor paper may be discarded as non-hazardous material. Loaded floor paper must be
disposed of in the same manner as any paint-laden waste material. Coatings containing regulated
chemicals or that have flammable (flash point below 140 F), toxic and/or corrosive
characteristics must be disposed of as hazardous waste through a hazardous waste disposal
service.
Hazardous waste : Refer to federal, state and local requirements for disposal (OSHA 1910.107, NFPA 33, 40CFR63
parts 260-262, state AQMD and WQMD, local Waste Management Authority).
13.2 Packaging
Methods of disposal : Clean floor paper packaging may be discarded as non-hazardous material.
13.3 Special precautions : None known.
14. TRANSPORT INFORMATION
US DOT ADR/RID IMDG IATA CAN TDG
14.1 UN number Not regulated. Not regulated. Not regulated. Not regulated. Not regulated.
14.2 UN proper shipping name None. None. None. None. None.
14.3 Transport Not restricted. Not restricted. Not restricted. Not restricted. Not restricted.
hazard class(s)
PRODUCT NAME: Flame-a-guard 2 & 3 booth floor papers SDS#: SDS-26
Page 7 of 7
14.4 Packing None. None. None. None. None.
group
14.5 Environmental hazards No. No. No. No. No.
14.6 Special precautions Not available. Not available. Not available. Not available. Not available.
for user
Additional information None. None. None. None. None.
14.7 Transport in bulk Not available. Not available. Not available. Not available. Not available.
according to Annex II of
MARPOL 73/78 and the
IBC Code
15. REGULATORY INFORMATION
15.1 Federal Regulations
Global Inventories: All ingredients are on DSL/NDSL and TSCA inventories.
Canada: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
(CPR) and the MSDS contains all information required by the CPR.
WHMIS Classification: exempt
NSNR/NPRI: no reportable substances
United States of America: SDS prepared pursuant to the Hazard Communication Standard (29CFR1910.1200).
EPA Hazardous Waste Number and Classification (40CFR261.22): none required
Toxic Substances Control Act (TSCA): not on list
EPA SARA Title III/CERCLA: Product is not reportable under Sections 311/312 hazard categories and contains no
chemicals reportable under Section 313 (40CFR372). This product does not contain chemicals that are regulated under
Section 304/CERCLA (40CFR302.4).
OSHA Hazard Status: Not considered hazardous as defined by the US OSHA Hazard Communication Standard
(29CFR1910.1200).
15.2 State Regulations
California Proposition 65: This product does not contain a chemical known to the state of California to cause cancer, birth
defect or other reproductive harm.
15.3 HMIS RATING: Health 0, Flammability 0, Reactivity 0
15.4 NFPA RATING: Health 0, Flammability 0, Reactivity 0
16. OTHER INFORMATION
16.1 Full text of abbreviated H : None.
statements
16.2 Full text of classifications : None
16.3 Full text of abbreviated R : R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in
phrases the aquatic environment.
16.4 Full text of classifications :None.
[DSD/DPD]
16.5 SDS PREPARED BY: Director of Chemical Safety
The information contained herein is based on data available to us and is accurate and reliable to the best of our knowledge
and belief. However, Carlisle Fluid Technologies, Inc. makes no representations as to its completeness or accuracy.
Information is supplied on condition that persons receiving such information will make their own determination as to its
suitability for their purposes prior to use. In no event will Carlisle Fluid Technologies, Inc. be responsible for damages of any
nature whatsoever resulting from the use of or reliance upon the information contained herein.
*** END OF SDS ***
3829865_SDS.pdf
PRODUCT NAME: Flame-a-guard 2 & 3 booth floor papers SDS#: SDS-26
Page 1 of 7
SAFETY DATA SHEET
Carlisle Fluid Technologies, Inc .
PRODUCT RELATED HEALTH DATA SHEET
1. IDENTIFICATION of the SUBSTANCE/MIXTURE and of the
COMPANY
1.1 Product identifier
Product Name : Flame-a-guard 2 & 3 booth floor papers
Product Code : Part No.29-843, 29-844, 29-863, 29-864, 29-865, 29-866, 29-872,
29-873, 29-874 and 29-875
Product Description : Spray Booth Floor Paper
SDS # : SDS-26 REVISION #: 2.0.4
CHEMICAL FORMULA: Coated Paper
CAS NUMBER : Not Applicable.
Article Code : Not Applicable.
GENERAL USE : Paint booth floor covering.
DATE REVISED: 02/01/2017 DATE PREPARED: 05/12/2015
1.2 Relevant identified uses of the substance or mixture and uses advised against
Not applicable.
1.3 Details of the supplier of the safety data sheet
Carlisle Fluid Technologies, Inc.
16430 North Scottsdale Road
Scottsdale, AZ 85254
Technical service number 1-888-992-4657
1.4 Emergency telephone number
Emergency Number – INFOTRAC
EMERGENCY PHONE (24 HOURS):
1-8OO-535-5053
2. HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture
Product definition : Article
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS] : Not classified.
Ingredients of unknown : None known.
toxicity
Ingredients of unknown : None known.
ecotoxicity
Classification according to Directive 1999/45/EC [DPD]
The product is not classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification : Not classified.
See Section 16 for the full text of the R phrases or H statements declared above.
See Section 11 for more detailed information on health effects and symptoms.
2.2 Label elements
Hazard pictograms : No pictogram.
Signal word : No signal word.
Hazard statements : No known significant effects or critical hazards
Precautionary statements
Prevention : Caution.
Response : Not applicable.
Storage : P210: Keep away from heat/sparks/open flames/hot surfaces No smoking.
Disposal : Not applicable.
PRODUCT NAME: Flame-a-guard 2 & 3 booth floor papers SDS#: SDS-26
Page 2 of 7
Hazardous ingredients : None known.
Supplemental label : Cellulose pulp, recycled, biodegradable
elements
Special packaging requirements
Containers to be fitted : Not applicable.
with child-resistant
fastenings
Tactile warning of danger :Not applicable.
2.3 Other hazards
Other hazards which do not result in classification
Properties affecting health : Harmful if swallowed.
Principle routes of exposure : Skin, eye, inhalation, ingestion.
Skin contact : Superficial laceration (paper cuts) may occur.
Eye contact : Direct contact with eyes may cause temporary irritation as a foreign object in the eye.
Inhalation : No health effects expected with normal use of product.
Ingestion : May result in obstruction and temporary irritation of the digestive tract.
Chronic Effects: not applicable
Medical Conditions Aggravated by Long-Term Exposure: asthma, allergies
Target Organs: skin and eyes
Signs and Symptoms: Adverse allergic reactions to paper dust may result in, but are not limited to, redness and irritation of
the eyes and skin. If such a reaction occurs, seek medical attention.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Ingredient: Cellulose pulp, recycled, biodegradable Wt. %: 60 100 CAS#: 65996-61-4
This material is considered to be an Article under 29 CFR 1910.1200 (Hazard Communication). The information in
this MSDS is provided for situations where this article may be deformed creating dusts which may be potentially
hazardous. The trade secret components of this product are non-hazardous based on the manufacturer s hazard
evaluation.
4. FIRST AID MEASURES
4.1 Description of first aid measures
EYE CONTACT : If irritation occurs, flush eyes with water. Remove contact lenses if worn. If abrasion or
scratch occurs, seek medical attention.
INHALATION : Not a normal route of exposure.
SKIN CONTACT : If irritation occurs due to dust, flush skin with water. If minor laceration occurs, wash with
antibacterial soap and bandage.
INGESTION : If product is swallowed and obstruction occurs, seek medical attention.
Protection of first-aiders : No known significant effects or critical hazards.
4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact : No known significant effects or critical hazards.
Inhalation : No known significant effects or critical hazards.
Skin contact : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : No specific data.
Inhalation : No specific data.
Skin contact : No specific data.
Ingestion : No specific data.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : Symptoms may not appear immediately.
Specific treatments : No specific treatment.
PRODUCT NAME: Flame-a-guard 2 & 3 booth floor papers SDS#: SDS-26
Page 3 of 7
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media
Suitable extinguishing media : Water, multi-purpose dry chemical.
Unsuitable extinguishing media : None known.
5.2 Special hazards arising from the substance or mixture
Flammability class : None. Fire retardant paper will not add to flammability.
Fire retardant method : T461 cm-00
Flash Point : 662 F, 350 C
Autoignition Temperature : Unknown.
Sensitivity to Static Discharge : None.
Hazards from the substance or mixture : None.
Unusual Fire and Explosion Hazards : Undetermined.
Hazardous combustion products : Carbon monoxide, carbon dioxide.
5.3 Advice for firefighters
Special precautions for fire-fighters : None.
Special protective equipment for : Fire-fighters should wear appropriate protective equipment and self-
fire-fighters contained breathing apparatus (SCBA) with a full face-piece operated in
positive pressure mode. Clothing for fire-fighters (including helmets,
protective boots and gloves) conforming to European standard EN 469 will
provide a basic level of protection for chemical incidents.
NFPA RATING: See Section 15.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any
information regarding personal protective equipment in Section 8.
6.2 Environmental precautions : Keep out of drains, sewers, ditches and waterways. If paper material does not have any
paint on the surface it is biodegradable and incinerable.
6.3 Methods and materials for containment and cleaning up
Small spill : Scoop up material and place in a disposal container.
Large spill : Pick up large pieces and place in a suitable container. Dispose of via a licensed waste
disposal contractor depending on paper contamination. Note: see section 13 for waste
disposal.
6.4 Reference to other sections : See Section 1 for emergency contact information.
See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling
Protective measures : Gloves recommended for the protection of hands against superficial lacerations (paper
cuts) and in case of allergic reaction. Handle with care to prevent physical damage to
product. Avoid product contact with water. (see Section 8 for additional information)
Advice on general occupational : Eating, drinking and smoking should be prohibited in areas where this material is
hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking.
7.2 Conditions for safe storage, : Store in a cool, dry location away from flames and sparks. Avoid prolonged
including any incompatibilities exposure in direct sunlight.
P210: Keep away from heat/sparks/open flames/hot surfaces No smoking
PRODUCT NAME: Flame-a-guard 2 & 3 booth floor papers SDS#: SDS-26
Page 4 of 7
7.3 Specific end use(s)
Recommendations : Not available.
Industrial sector specific solutions : Not available.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 Control parameters
Ingredients
Exposure Limits
Cellulose pulp OSHA-PEL: not available ACGIH-TLV: not available
Kaolin OSHA-PEL: 15 mg/m ACGIH-TLV: 2 mg/m
Ammonium hydrogen sulfate OSHA-PEL: not available ACGIH-TLV: not available
8.2 Exposure controls
Appropriate engineering : Use ventilation adequate to keep exposures (airborne levels of dust, fume,
controls vapor, etc.) below recommended exposure limits.
Personal Protection Equipment
Eye Protection : Safety glasses recommended, none required.
Skin Protection : Gloves recommended, none required.
Respiratory Protection : None required.
Other protective clothing: None.
Hygienic Practices: Handle according to established hygiene and safety practices. Wash hands after handling
recommended.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties
Physical state : Solid.
Color : White.
Odor : Odorless.
Appearance : Opaque paper.
pH : Not available.
Melting point/freezing point : Not available.
Initial boiling point and : Not available.
boiling range
Flash point : 662 F, 350 C.
Flammability (solid, gas) : Not available.
Burning time : Not applicable.
Burning rate : Not applicable.
Upper/lower flammability or : Not available.
explosive limits
Vapor pressure : Not available.
Density : Not available.
Solubility(ies) : Not available.
Partition coefficient: : Not available.
n- octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Not available.
Explosive properties : Not available.
VOC : None.
Oxidizing properties : Not available.
9.2 Other information
No additional information.
PRODUCT NAME: Flame-a-guard 2 & 3 booth floor papers SDS#: SDS-26
Page 5 of 7
10. STABILITY AND REACTIVITY
10.1 Reactivity : Avoid open flames and sparks.
10.2 Chemical stability : Stable under normal storage conditions.
10.3 Possibility of hazardous : No dangerous reaction known under conditions of normal use.
reactions
10.4 Conditions to avoid : Avoid open flames and sparks.
10.5 Incompatible materials : None known.
10.6 Hazardous decomposition : May include, and are not limited to, oxides of carbon.
products
11. TOXICOLOGICAL INFORMATION
11.1 Acute toxicity
Effects of Acute Exposure : Not applicable.
(LD50 oral and LC50)
11.2 Acute toxicity estimates
Conclusion/Summary : Not applicable.
11.3 Irritation/Corrosion
Conclusion/Summary : Not available.
11.4 Sensitizer
Conclusion/Summary : Not available.
11.5 Mutagenicity
Conclusion/Summary : Not available.
11.6 Carcinogenicity
Conclusion/Summary : Not available.
11.7 Reproductive toxicity
Conclusion/Summary : Not available.
11.8 Teratogenicity
Conclusion/Summary : Not available.
11.9 Specific target organ toxicity (single exposure)
Not hazardous.
11.10 Specific target organ toxicity (repeated exposure)
Conclusion/Summary : Not hazardous.
11.11 Aspiration hazard
Conclusion/Summary : Not hazardous.
11.12 Information on the likely routes of exposure : Not hazardous.
11.13 Potential acute health effects
Inhalation : Not applicable for product in purchased form.
Ingestion : May result in obstruction and temporary irritation of the digestive tract.
Skin contact : Not applicable for product in purchased form. Adverse allergic reactions may
result in, but are not limited to, redness and irritation.
Eye contact : Not applicable for product in purchased form. Adverse allergic reactions may
result in, but are not limited to, redness and irritation.
11.4 Symptoms related to the physical, chemical and toxicological characteristics
Inhalation : No specific data.
Ingestion : No specific data.
Skin contact : No specific data.
Eye contact : No specific data.
11.15 Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate effects : Not available.
Potential delayed effects : Not available.
Long term exposure
Potential immediate effects : Not hazardous.
PRODUCT NAME: Flame-a-guard 2 & 3 booth floor papers SDS#: SDS-26
Page 6 of 7
Potential delayed effects : Not hazardous.
11.16 Potential chronic health effects
Effects of Chronic Exposure : Not hazardous.
General : No known significant effects or critical hazards.
Carcinogenicity (IARC, ACGIH) : None
Mutagenicity : Not hazardous.
Teratogenicity : Not hazardous.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
11.17 Other information : Not available.
12. ECOLOGICAL INFORMATION
12.1 Toxicity
Aquatic
Conclusion/Summary : May cause long-term adverse effects in the aquatic environment. Not
expected to produce significant ecotoxicity upon exposure to aquatic
organisms and aquatic systems.
R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
12.2 Persistence
Conclusion/Summary : Not available.
12.3 Bioaccumulation/Accumulation
Conclusion/Summary : Not available.
12.4 Mobility/Persistence in soil
Conclusion/Summary : Not available.
12.5 Degradability/Leaching
Conclusion/Summary : Not available.
12.6 Environmental Fate
Conclusion/Summary : Not available.
12.7 Other adverse effects : No known significant effects or critical hazards.
13. DISPOSAL CONSIDERATIONS
The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).
13.1 Waste treatment methods
Methods of disposal : Clean floor paper may be discarded as non-hazardous material. Loaded floor paper must be
disposed of in the same manner as any paint-laden waste material. Coatings containing regulated
chemicals or that have flammable (flash point below 140 F), toxic and/or corrosive
characteristics must be disposed of as hazardous waste through a hazardous waste disposal
service.
Hazardous waste : Refer to federal, state and local requirements for disposal (OSHA 1910.107, NFPA 33, 40CFR63
parts 260-262, state AQMD and WQMD, local Waste Management Authority).
13.2 Packaging
Methods of disposal : Clean floor paper packaging may be discarded as non-hazardous material.
13.3 Special precautions : None known.
14. TRANSPORT INFORMATION
US DOT ADR/RID IMDG IATA CAN TDG
14.1 UN number Not regulated. Not regulated. Not regulated. Not regulated. Not regulated.
14.2 UN proper shipping name None. None. None. None. None.
14.3 Transport Not restricted. Not restricted. Not restricted. Not restricted. Not restricted.
hazard class(s)
PRODUCT NAME: Flame-a-guard 2 & 3 booth floor papers SDS#: SDS-26
Page 7 of 7
14.4 Packing None. None. None. None. None.
group
14.5 Environmental hazards No. No. No. No. No.
14.6 Special precautions Not available. Not available. Not available. Not available. Not available.
for user
Additional information None. None. None. None. None.
14.7 Transport in bulk Not available. Not available. Not available. Not available. Not available.
according to Annex II of
MARPOL 73/78 and the
IBC Code
15. REGULATORY INFORMATION
15.1 Federal Regulations
Global Inventories: All ingredients are on DSL/NDSL and TSCA inventories.
Canada: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
(CPR) and the MSDS contains all information required by the CPR.
WHMIS Classification: exempt
NSNR/NPRI: no reportable substances
United States of America: SDS prepared pursuant to the Hazard Communication Standard (29CFR1910.1200).
EPA Hazardous Waste Number and Classification (40CFR261.22): none required
Toxic Substances Control Act (TSCA): not on list
EPA SARA Title III/CERCLA: Product is not reportable under Sections 311/312 hazard categories and contains no
chemicals reportable under Section 313 (40CFR372). This product does not contain chemicals that are regulated under
Section 304/CERCLA (40CFR302.4).
OSHA Hazard Status: Not considered hazardous as defined by the US OSHA Hazard Communication Standard
(29CFR1910.1200).
15.2 State Regulations
California Proposition 65: This product does not contain a chemical known to the state of California to cause cancer, birth
defect or other reproductive harm.
15.3 HMIS RATING: Health 0, Flammability 0, Reactivity 0
15.4 NFPA RATING: Health 0, Flammability 0, Reactivity 0
16. OTHER INFORMATION
16.1 Full text of abbreviated H : None.
statements
16.2 Full text of classifications : None
16.3 Full text of abbreviated R : R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in
phrases the aquatic environment.
16.4 Full text of classifications :None.
[DSD/DPD]
16.5 SDS PREPARED BY: Director of Chemical Safety
The information contained herein is based on data available to us and is accurate and reliable to the best of our knowledge
and belief. However, Carlisle Fluid Technologies, Inc. makes no representations as to its completeness or accuracy.
Information is supplied on condition that persons receiving such information will make their own determination as to its
suitability for their purposes prior to use. In no event will Carlisle Fluid Technologies, Inc. be responsible for damages of any
nature whatsoever resulting from the use of or reliance upon the information contained herein.
*** END OF SDS ***
38206250FS_SDS.pdf
Safety Data Sheet
Freeman 266PSA Thermo-Stable Sheet Wax
Date of Preparation: June 20, 2022 Page 1 of 4
Section 1 Chemical Product and Company Identification
1.1 Product identifiers
Product name: Freeman 266PSA Thermo-Stable Sheet Wax
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses: Specialty Tooling Wax, Thermo-Stable Sheet Wax (Adhesive Back)
1.3 Details of the supplier of the safety data sheet
Freeman Manufacturing & Supply Company
1101 Moore Road, Avon, OH 44011 1.4 Emergency telephone number
Telephone (440) 934-1902 CHEMTREC (800) 424-9300
www.freemansupply.com
Section 2 Hazards Identification
2.1 Classification of the substance or mixture
Not classified according to OSHA 29 CFR 1910.1200 HCS
2.2 GHS Label elements, including precautionary statements
No label element(s) required
2.3 Hazards not otherwise classified
Molten product can cause serious burns.
Section 3 Composition/Information on Ingredients
3.1 Mixture of Substances
Proprietary mixture of synthetic waxes, resin(s), and additive(s) with a non-hazardous water-based adhesive
coating. No components need to be disclosed according to the applicable regulations.
Section 4 First Aid Measures
4.1 Description of first aid measures
Inhalation Get medical assistance if irritation develops or persists. If breathing is difficult,
move the person to fresh air. Give artificial respiration if person is not breathing.
Skin contact For thermal burns, flush or submerge effected area in cold water to dissipate heat.
Cover with clean bandage material. Do not peel material from skin. Get medical attention.
For contact at ambient temperatures, wash with soap and water.
Eye contact Immediately flush with plenty of water for at least 15 minutes.
If irritation persists, get medical attention immediately, preferably an ophthalmologist.
Ingestion If swallowed, rinse mouth with water. Never give anything by mouth to an unconscious person.
Do NOT induce vomiting. Consult a physician if necessary.
Section 5 Fire Fighting Measures
5.1 Extinguishing media
Suitable extinguishing media: Water fog, dry chemical, foam, carbon dioxide.
Unsuitable extinguishing media: Do not use a solid water stream as it may scatter and spread fire.
5.2 Special hazards arising from the substance or mixture
Unusual Fire and Explosion Hazards: Avoid generating dust; fine dust dispersed in air in sufficient
concentrations, and in the presence of an ignition source is a potential dust explosion hazard.
See Section 10 for possible products of hazardous combustion.
5.3 Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
Freeman 266PSA Thermo-Stable Sheet Wax
Date of Preparation: June 20, 2022 Page 2 of 4
Section 6 Accidental Release Measures
6.1 Personal precautions, protective equipment and emergency procedures
Avoid contact with skin and eyes. Wear appropriate personal protective equipment, see Section 8.
6.2 Environmental precautions
Should not be released into the environment. Prevent product from entering drains.
6.3 Methods and materials for containment and cleaning up
Contain spillage and use clean non-sparking tools to collect material.
Shovel spillage into suitable container for disposal.
Section 7 Handling and Storage
7.1 Precautions for safe handling
Wear appropriate personal protective equipment, see Section 8. Avoid contact with skin and eyes. Wash
thoroughly with soap and water after handling. Do not use in areas without adequate ventilation. Avoid
breathing fumes. Avoid contact with molten material.
7.2 Conditions for safe storage, including any incompatibilities
Store at ambient temperatures. Keep in closed container when not in use. Keep away from ignition sources,
heat, open flames, and direct sunlight. Do not store with incompatible materials, see Section 10.
Section 8 Exposure Controls/Personal Protection
8.1 Control parameters
None established
8.2 Exposure controls
Appropriate engineering controls
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be
matched to conditions. Supplementary local exhaust ventilation may be needed in special circumstances, such
as poorly ventilated spaces, very hot processing, mechanical generation of dusts, etc.
8.3 Personal protective equipment
Eye/Face
Wear safety glasses equipped with side shields, or safety goggles.
Hands
Chemical protective gloves should not be needed when handling this material. Use gloves to protect from
mechanical injury. Use gloves with insulation for thermal protection when needed.
Skin/Body
No precautions other than clean body-covering clothing should be needed.
Respiratory
The need for respiratory protection is not anticipated under normal use conditions and with adequate
ventilation. If elevated airborne concentrations above applicable workplace exposure levels are anticipated, or
when adverse effects such as respiratory irritation has been experienced, or where indicated by your risk
assessment process, then use an approved air-purifying respirator. Use an approved air-purifying respirator
with organic vapor cartridge and particulate pre-filter when vapors are generated at increased temperatures.
Safety Stations
Make emergency eyewash stations and washing facilities available in work area.
General Hygienic Practices
Wash thoroughly after handling, and before eating, drinking or smoking. Remove contaminated clothing
promptly and clean thoroughly before reuse. Avoid contamination of food, beverages, or smoking
Freeman 266PSA Thermo-Stable Sheet Wax
Date of Preparation: June 20, 2022 Page 3 of 4
Section 9 Physical and Chemical Properties
9.1 Information on basic physical and chemical properties
Physical State & Color Dark yellow/medium brown solid
Odor Mild
Odor Threshold No data available
pH No data available
Melting Point >279 F (137 C)
VOC Content 0
Boiling Point No data available
Flash Point 465 F (240 C)
Evaporation rate No data available
Flammability (solid, gas) No data available
Upper/lower flammability No data available
Vapor Pressure No data available
Vapor Density No data available
Relative Density (g/cc) 0.9 0.05
Water Solubility Negligible
Coefficient: n-octanol/ water No data available
Auto-Ignition Temperature No data available
Viscosity Solid at room temperature
Explosive Properties None
Oxidizing Properties None
Section 10 Stability and Reactivity
10.1 Reactivity: No dangerous reaction known under conditions of normal use.
10.2 Chemical stability: Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions: Hazardous polymerization does not occur.
10.4 Conditions to avoid: Heat, sparks, open flame.
10.5 Incompatible materials: Strong oxidizing agents, strong acids, strong bases.
10.6 Hazardous decomposition products Carbon monoxide, carbon dioxide, n-Butyl methacrylate.
Section 11 Toxicological Information
11.1 Information on likely routes of exposure:
Acute Oral Toxicity Expected to be a low ingestion hazard.
Acute Dermal Toxicity No adverse effects anticipated from skin absorption.
Acute Inhalation Toxicity Vapors released during thermal processing may cause
respiratory irritation.
Skin Corrosion/Irritation Classification criteria not met
Serious Eye Damage/Eye Irritation Classification criteria not met
Respiratory or Skin Sensitization Classification criteria not met
Germ Cell Mutagenicity Classification criteria not met
Carcinogenicity No component of this product present at levels greater than
or equal to 0.1% is identified as an anticipated, potential,
probable, possible, known, or confirmed carcinogen.
Reproductive Toxicity Classification criteria not met
Aspiration Hazard Not relevant
Specific Target Organ Toxicity (STOT)
Single Exposure Classification criteria not met
Repeated Exposure Classification criteria not met
Freeman 266PSA Thermo-Stable Sheet Wax
Date of Preparation: June 20, 2022 Page 4 of 4
Section 12 Ecological Information
12.1 Toxicity Not expected to be harmful to aquatic organisms
12.2 Persistence and degradability No data available
12.3 Bioaccumulative potential No data available
12.4 Mobility in soil No data available
12.5 Results of PBT & vPvB assessment No data available
Section 13 Disposal Considerations
13.1 Disposal Follow applicable Federal, State, and local regulations.
Section 14 Transport Information
14.1 DOT, TDG, IMO/IMDG, IATA/ICOA: Not regulated
Section 15 Regulatory Information
15.1 Safety, health and environmental regulations/legislation specific for the product
Inventories
DSL (Canada): All components of this product are on the Canadian DSL
ENCS (Japan): On the inventory, or in compliance with the inventory
EICSC (China): On the inventory, or in compliance with the inventory
KECI (Korea): On the inventory, or in compliance with the inventory
REACH (European Union): All chemicals in this product comply with REACH regulations.
TSCA (United States): Inventory Status: All ingredients listed on the EPA TSCA inventory
SARA 311/312 Hazards Classifications: None
SARA 313 Components: This material does not contain any chemical components with known CAS numbers
that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
RCRA: In the form delivered, this product is not considered as hazardous waste, and is not subject to
reporting under the Resource Conservation and Recovery Act.
California Proposition 65: This product is not known to contain any components for which the State of
California has found to cause cancer, birth defects or other reproductive harm.
Section 16 Other Information
16.1 Disclaimer
The following supersedes Buyer s documents. SELLER MAKES NO REPRESENTATION OR WARRANTY,
EXPRESSED OR IMPLIED, INCLUDING ANY WARRANTY OF MERCHANTABILITY OR FITNESS FOR A
PARTICULAR PURPOSE. No statements herein are to be construed as inducements to infringe any relevant
patent. Under no circumstances shall Seller be liable for incidental, consequential or indirect damages for
alleged negligence, breach of warranty, strict of liability arising in connection with the product(s). Buyer s
sole remedy and Seller s sole liability for any claims shall be Buyer s purchase price. Data and results are
based on controlled lab work and must be confirmed by Buyer by testing for its intended conditions of use.
The product(s) has not been tested for, and is therefore not recommended for, uses for which prolonged
contact with mucous membranes, abraded skin, or blood is intended; or for uses for which implantation
within the human body is intended.
Issue Date: June 1, 2015
Revision Date: June 20, 2022
38206188_TDS.pdf
Safety Data Sheet
Freeman 266PSA Thermo-Stable Sheet Wax
Date of Preparation: June 20, 2022 Page 1 of 4
Section 1 Chemical Product and Company Identification
1.1 Product identifiers
Product name: Freeman 266PSA Thermo-Stable Sheet Wax
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses: Specialty Tooling Wax, Thermo-Stable Sheet Wax (Adhesive Back)
1.3 Details of the supplier of the safety data sheet
Freeman Manufacturing & Supply Company
1101 Moore Road, Avon, OH 44011 1.4 Emergency telephone number
Telephone (440) 934-1902 CHEMTREC (800) 424-9300
www.freemansupply.com
Section 2 Hazards Identification
2.1 Classification of the substance or mixture
Not classified according to OSHA 29 CFR 1910.1200 HCS
2.2 GHS Label elements, including precautionary statements
No label element(s) required
2.3 Hazards not otherwise classified
Molten product can cause serious burns.
Section 3 Composition/Information on Ingredients
3.1 Mixture of Substances
Proprietary mixture of synthetic waxes, resin(s), and additive(s) with a non-hazardous water-based adhesive
coating. No components need to be disclosed according to the applicable regulations.
Section 4 First Aid Measures
4.1 Description of first aid measures
Inhalation Get medical assistance if irritation develops or persists. If breathing is difficult,
move the person to fresh air. Give artificial respiration if person is not breathing.
Skin contact For thermal burns, flush or submerge effected area in cold water to dissipate heat.
Cover with clean bandage material. Do not peel material from skin. Get medical attention.
For contact at ambient temperatures, wash with soap and water.
Eye contact Immediately flush with plenty of water for at least 15 minutes.
If irritation persists, get medical attention immediately, preferably an ophthalmologist.
Ingestion If swallowed, rinse mouth with water. Never give anything by mouth to an unconscious person.
Do NOT induce vomiting. Consult a physician if necessary.
Section 5 Fire Fighting Measures
5.1 Extinguishing media
Suitable extinguishing media: Water fog, dry chemical, foam, carbon dioxide.
Unsuitable extinguishing media: Do not use a solid water stream as it may scatter and spread fire.
5.2 Special hazards arising from the substance or mixture
Unusual Fire and Explosion Hazards: Avoid generating dust; fine dust dispersed in air in sufficient
concentrations, and in the presence of an ignition source is a potential dust explosion hazard.
See Section 10 for possible products of hazardous combustion.
5.3 Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
Freeman 266PSA Thermo-Stable Sheet Wax
Date of Preparation: June 20, 2022 Page 2 of 4
Section 6 Accidental Release Measures
6.1 Personal precautions, protective equipment and emergency procedures
Avoid contact with skin and eyes. Wear appropriate personal protective equipment, see Section 8.
6.2 Environmental precautions
Should not be released into the environment. Prevent product from entering drains.
6.3 Methods and materials for containment and cleaning up
Contain spillage and use clean non-sparking tools to collect material.
Shovel spillage into suitable container for disposal.
Section 7 Handling and Storage
7.1 Precautions for safe handling
Wear appropriate personal protective equipment, see Section 8. Avoid contact with skin and eyes. Wash
thoroughly with soap and water after handling. Do not use in areas without adequate ventilation. Avoid
breathing fumes. Avoid contact with molten material.
7.2 Conditions for safe storage, including any incompatibilities
Store at ambient temperatures. Keep in closed container when not in use. Keep away from ignition sources,
heat, open flames, and direct sunlight. Do not store with incompatible materials, see Section 10.
Section 8 Exposure Controls/Personal Protection
8.1 Control parameters
None established
8.2 Exposure controls
Appropriate engineering controls
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be
matched to conditions. Supplementary local exhaust ventilation may be needed in special circumstances, such
as poorly ventilated spaces, very hot processing, mechanical generation of dusts, etc.
8.3 Personal protective equipment
Eye/Face
Wear safety glasses equipped with side shields, or safety goggles.
Hands
Chemical protective gloves should not be needed when handling this material. Use gloves to protect from
mechanical injury. Use gloves with insulation for thermal protection when needed.
Skin/Body
No precautions other than clean body-covering clothing should be needed.
Respiratory
The need for respiratory protection is not anticipated under normal use conditions and with adequate
ventilation. If elevated airborne concentrations above applicable workplace exposure levels are anticipated, or
when adverse effects such as respiratory irritation has been experienced, or where indicated by your risk
assessment process, then use an approved air-purifying respirator. Use an approved air-purifying respirator
with organic vapor cartridge and particulate pre-filter when vapors are generated at increased temperatures.
Safety Stations
Make emergency eyewash stations and washing facilities available in work area.
General Hygienic Practices
Wash thoroughly after handling, and before eating, drinking or smoking. Remove contaminated clothing
promptly and clean thoroughly before reuse. Avoid contamination of food, beverages, or smoking
Freeman 266PSA Thermo-Stable Sheet Wax
Date of Preparation: June 20, 2022 Page 3 of 4
Section 9 Physical and Chemical Properties
9.1 Information on basic physical and chemical properties
Physical State & Color Dark yellow/medium brown solid
Odor Mild
Odor Threshold No data available
pH No data available
Melting Point >279 F (137 C)
VOC Content 0
Boiling Point No data available
Flash Point 465 F (240 C)
Evaporation rate No data available
Flammability (solid, gas) No data available
Upper/lower flammability No data available
Vapor Pressure No data available
Vapor Density No data available
Relative Density (g/cc) 0.9 0.05
Water Solubility Negligible
Coefficient: n-octanol/ water No data available
Auto-Ignition Temperature No data available
Viscosity Solid at room temperature
Explosive Properties None
Oxidizing Properties None
Section 10 Stability and Reactivity
10.1 Reactivity: No dangerous reaction known under conditions of normal use.
10.2 Chemical stability: Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions: Hazardous polymerization does not occur.
10.4 Conditions to avoid: Heat, sparks, open flame.
10.5 Incompatible materials: Strong oxidizing agents, strong acids, strong bases.
10.6 Hazardous decomposition products Carbon monoxide, carbon dioxide, n-Butyl methacrylate.
Section 11 Toxicological Information
11.1 Information on likely routes of exposure:
Acute Oral Toxicity Expected to be a low ingestion hazard.
Acute Dermal Toxicity No adverse effects anticipated from skin absorption.
Acute Inhalation Toxicity Vapors released during thermal processing may cause
respiratory irritation.
Skin Corrosion/Irritation Classification criteria not met
Serious Eye Damage/Eye Irritation Classification criteria not met
Respiratory or Skin Sensitization Classification criteria not met
Germ Cell Mutagenicity Classification criteria not met
Carcinogenicity No component of this product present at levels greater than
or equal to 0.1% is identified as an anticipated, potential,
probable, possible, known, or confirmed carcinogen.
Reproductive Toxicity Classification criteria not met
Aspiration Hazard Not relevant
Specific Target Organ Toxicity (STOT)
Single Exposure Classification criteria not met
Repeated Exposure Classification criteria not met
Freeman 266PSA Thermo-Stable Sheet Wax
Date of Preparation: June 20, 2022 Page 4 of 4
Section 12 Ecological Information
12.1 Toxicity Not expected to be harmful to aquatic organisms
12.2 Persistence and degradability No data available
12.3 Bioaccumulative potential No data available
12.4 Mobility in soil No data available
12.5 Results of PBT & vPvB assessment No data available
Section 13 Disposal Considerations
13.1 Disposal Follow applicable Federal, State, and local regulations.
Section 14 Transport Information
14.1 DOT, TDG, IMO/IMDG, IATA/ICOA: Not regulated
Section 15 Regulatory Information
15.1 Safety, health and environmental regulations/legislation specific for the product
Inventories
DSL (Canada): All components of this product are on the Canadian DSL
ENCS (Japan): On the inventory, or in compliance with the inventory
EICSC (China): On the inventory, or in compliance with the inventory
KECI (Korea): On the inventory, or in compliance with the inventory
REACH (European Union): All chemicals in this product comply with REACH regulations.
TSCA (United States): Inventory Status: All ingredients listed on the EPA TSCA inventory
SARA 311/312 Hazards Classifications: None
SARA 313 Components: This material does not contain any chemical components with known CAS numbers
that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
RCRA: In the form delivered, this product is not considered as hazardous waste, and is not subject to
reporting under the Resource Conservation and Recovery Act.
California Proposition 65: This product is not known to contain any components for which the State of
California has found to cause cancer, birth defects or other reproductive harm.
Section 16 Other Information
16.1 Disclaimer
The following supersedes Buyer s documents. SELLER MAKES NO REPRESENTATION OR WARRANTY,
EXPRESSED OR IMPLIED, INCLUDING ANY WARRANTY OF MERCHANTABILITY OR FITNESS FOR A
PARTICULAR PURPOSE. No statements herein are to be construed as inducements to infringe any relevant
patent. Under no circumstances shall Seller be liable for incidental, consequential or indirect damages for
alleged negligence, breach of warranty, strict of liability arising in connection with the product(s). Buyer s
sole remedy and Seller s sole liability for any claims shall be Buyer s purchase price. Data and results are
based on controlled lab work and must be confirmed by Buyer by testing for its intended conditions of use.
The product(s) has not been tested for, and is therefore not recommended for, uses for which prolonged
contact with mucous membranes, abraded skin, or blood is intended; or for uses for which implantation
within the human body is intended.
Issue Date: June 1, 2015
Revision Date: June 20, 2022