by | Sep 27, 2025
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Revision Date: 24 Jun 2010
Page 1 of 10
______________________________________________________________________________________________________________________
MATERIAL SAFETY DATA SHEET
SECTION 1 PRODUCT AND COMPANY IDENTIFICATION
PRODUCT
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Product Description: LLDPE without polymer processing aid, see Section 16 for applicable grades.
Product Code: 19889
Intended Use: Coatings, Extrusion and moulding, Film blowing
COMPANY IDENTIFICATION
Supplier: CIOL – EXXONMOBIL CHEMICAL CANADA
Division of Canada Imperial Oil Limited, an Affiliate of Exxon Mobil Corporation
240 4TH AVENUE S.W.
CALGARY, ALBERTA. T2P 3M9 Canada
24 Hour Health Emergency 519-339-2145
Transportation Emergency Phone 519-339-2145
Product Technical Information 800-668-0177
SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS
No Reportable Hazardous Substance(s) or Complex Substance(s).
NOTE: The product may contain varying levels of additives such as slip and antiblocking agents, antioxidants and
stabilizers.
SECTION 3 HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15).
POTENTIAL PHYSICAL / CHEMICAL EFFECTS
High dust levels may create potential for explosion. Spilled pellets present a slipping hazard on hard
surfaces. Contact with hot material can cause thermal burns which may result in permanent damage.
Material can accumulate static charges which may cause an ignition.
POTENTIAL HEALTH EFFECTS
Material is essentially non-toxic. However, if dust is generated, it could scratch the eyes and cause minor
irritation to the respiratory tract. When heated, the vapors/fumes given off may cause respiratory tract irritation.
NFPA Hazard ID: Health: 1 Flammability: 1 Reactivity: 0
HMIS Hazard ID: Health: 1 Flammability: 1 Reactivity: 0
SECTION 4 FIRST AID MEASURES
INHALATION
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Revision Date: 24 Jun 2010
Page 2 of 10
______________________________________________________________________________________________________________________
In case of adverse exposure to vapors and / or aerosols formed at elevated temperatures, immediately remove
the affected victim from exposure. Administer artificial respiration if breathing is stopped. Keep at rest.
SKIN CONTACT
For hot product: Immediately immerse in or flush affected area with large amounts of cold water to dissipate
heat. Cover with clean cotton sheeting or gauze and get prompt medical attention.
EYE CONTACT
Flush thoroughly with water. If irritation occurs, get medical assistance.
INGESTION
No adverse effects due to ingestion are expected.
SECTION 5 FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish
flames.
Inappropriate Extinguishing Media: Straight Streams of Water
FIRE FIGHTING
Fire Fighting Instructions: Assure an extended cooling down period to prevent re-ignition. Evacuate area.
Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. Firefighters
should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA).
Use water spray to cool fire exposed surfaces and to protect personnel.
Unusual Fire Hazards: High dust levels may create potential for explosion.
Hazardous Combustion Products: Smoke, Fume, Incomplete combustion products, Oxides of carbon,
Flammable hydrocarbons
FLAMMABILITY PROPERTIES
Flash Point [Method]: N/A
Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D
Autoignition Temperature: N/A
SECTION 6 ACCIDENTAL RELEASE MEASURES
NOTIFICATION PROCEDURES
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable
regulations. US regulations require reporting releases of this material to the environment which exceed the
applicable reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The
National Response Center can be reached at (800)424-8802.
SPILL MANAGEMENT
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Revision Date: 24 Jun 2010
Page 3 of 10
______________________________________________________________________________________________________________________
Land Spill: Spilled pellets present a slipping hazard on hard surfaces. Small Dry Spills: With clean shovel
place material into clean, dry container and cover loosely; move containers from spill area.
Water Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Warn other
shipping. Skim from surface.
Water spill and land spill recommendations are based on the most likely spill scenario for this material;
however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction
and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be
consulted. Note: Local regulations may prescribe or limit action to be taken.
ENVIRONMENTAL PRECAUTIONS
Prevent entry into waterways, sewers, basements or confined areas. For Large Spills: Cover spill with plastic
sheet or tarpaulin to minimize spreading.
SECTION 7 HANDLING AND STORAGE
HANDLING
Avoid elevated temperatures for prolonged periods of time. Prevent small spills and leakage to avoid slip
hazard. Avoid conditions which create dust. DO NOT handle, store or open near an open flame, sources of
heat or sources of ignition. Protect material from direct sunlight. Material can accumulate static charges which
may cause an electrical spark (ignition source). Care should be taken when storing and handling this product.
Apart from the specific nature of the polymer product, conditions such as humidity, sunlight, and temperature
have an influence on the way the product behaves during storage and handling. Special attention should be
paid to avoid inappropriate stacking of palletized bags or other package units. Indeed, polymer products may be
dimensionally unstable under certain conditions. Avoid conditions generating heat during transfer operations.
Loading/Unloading Temperature: [Ambient]
Transport Temperature: [Ambient]
Transport Pressure: [Ambient]
Static Accumulator: This material is a static accumulator.
STORAGE
The container choice, for example storage vessel, may effect static accumulation and dissipation. Store in a
cool, dry place with adequate ventilation. Keep away from incompatible materials, open flames, and high
temperatures. Do not store in open or unlabelled containers.
Storage Temperature: [Ambient]
Storage Pressure: [Ambient]
Suitable Containers/Packing: Bulk Containers; Hopper Cars; Bags; Boxes; Drums; Octatainer; Silos
Suitable Materials and Coatings (Chemical Compatibility): Aluminum; Polyethylene Bags
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure limits/standards for materials that can be formed when handling this product: For dusty conditions,
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Revision Date: 24 Jun 2010
Page 4 of 10
______________________________________________________________________________________________________________________
OSHA recommends for particulates not otherwise regulated an 8-hour TWA of 15 mg/m3 (total dust), 5 mg/m3
(respirable fraction); ACGIH recommends for insoluble and poorly soluble particles not otherwise specified an 8-hour
TWA of 10 mg/m3 (inhalable particles), 3 mg/m3 (respirable particles). Product may also contain varying levels of
additives, such as slip and antiblocking agents (talc or silica), antioxidants, stabilizers, and corrosion inhibitors. Certain
grades may contain cristobalite, a form of crystalline silica, as an additive that is encapsulated in the polymer. Inhaled
crystalline silica in an occupational environment is recognized as a known human carcinogen. However, the potential for
release of silica to the air when this polymer is handled has been assessed and the encapsulated silica within the
polymer is not expected to pose a health hazard when processed under normal conditions of use.
NOTE: Limits/standards shown for guidance only. Follow applicable regulations.
ENGINEERING CONTROLS
The level of protection and types of controls necessary will vary depending upon potential exposure conditions.
Control measures to consider:
Adequate ventilation should be provided so that exposure limits are not exceeded. SPECIAL
PRECAUTIONS: Should significant vapors/fumes be generated during thermal processing of this
product, it is recommended that work stations be monitored for the presence of thermal degradation
by-products which may evolve at elevated temperatures (for example, oxygenated components).
Processors of this product should assure that adequate ventilation or other controls are used to control
exposure. It is recommended that the current ACGIH-TLVs for thermal degradation by-products be
observed. Contact your local sales representative for further information.
PERSONAL PROTECTION
Personal protective equipment selections vary based on potential exposure conditions such as applications,
handling practices, concentration and ventilation. Information on the selection of protective equipment for use
with this material, as provided below, is based upon intended, normal usage.
Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a
level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator
selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of
respirators to be considered for this material include:
Half-face filter respirator
For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode.
Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate,
gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded.
Hand Protection: Any specific glove information provided is based on published literature and glove
manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions.
Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use
conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material
include:
If product is hot, thermally protective, chemical resistant gloves are recommended. If contact with
forearms is likely, wear gauntlet style gloves.
Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or
manufacturer data. The types of clothing to be considered for this material include:
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Revision Date: 24 Jun 2010
Page 5 of 10
______________________________________________________________________________________________________________________
If product is hot, thermally protective, chemical resistant apron and long sleeves are recommended.
Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after
handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned.
Practice good housekeeping.
ENVIRONMENTAL CONTROLS
See Sections 6, 7, 12, 13.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Typical physical and chemical properties are given below. Consult the Supplier in Section 1 for additional
data.
GENERAL INFORMATION
Physical State: Solid
Form: Pellet, Granule, Powder
Color: Clear to Opaque, White to Off-White
Odor: None to Mild
Odor Threshold: N/A
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION
Relative Density (at 15 C): 0.9 – 0.95
Bulk Density: 0.4 g/cc at 20 C – 1 g/cc at 20 C
Flash Point [Method]: N/A
Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D
Autoignition Temperature: N/A
Boiling Point / Range: N/A
Vapor Density (Air = 1): N/A
Vapor Pressure: N/A
Evaporation Rate (n-butyl acetate = 1): N/A
pH: N/A
Log Pow (n-Octanol/Water Partition Coefficient): N/A
Solubility in Water: Negligible
Viscosity: N/A
Oxidizing Properties: See Hazards Identification Section.
OTHER INFORMATION
Freezing Point: N/D
Melting Point: 115 C (239 F) – 130 C (266 F)
Molecular Weight: > 25000
Hygroscopic: No
SECTION 10 STABILITY AND REACTIVITY
STABILITY: Material is stable under normal conditions.
CONDITIONS TO AVOID: Avoid elevated temperatures for prolonged periods of time.
MATERIALS TO AVOID: Strong oxidizers
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Revision Date: 24 Jun 2010
Page 6 of 10
______________________________________________________________________________________________________________________
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures.
HAZARDOUS POLYMERIZATION: Will not occur.
SECTION 11 TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
Route of Exposure
Conclusion / Remarks
Inhalation
Toxicity: Data available. Minimally Toxic. Based on test data for structurally similar
materials.
Irritation: Data available. Negligible haz ard at ambient/normal handling temperatures.
Based on test data for structurally similar materials.
Ingestion
Toxicity: Data available. Minimally Toxic. Based on test data for structurally similar
materials.
Skin
Toxicity: Data available. Minimally Toxic. Based on test data for structurally similar
materials.
Irritation: Data available. Negl igible irritation to skin at ambient temperatures. Based on test
data for structurally similar materials.
Eye
Irritation: Data available. May cause mild, s hort-lasting discomfort to eyes. Based on test
data for structurally similar materials.
CHRONIC/OTHER EFFECTS
For the product itself:
Dust may be irritating to the eyes and respiratory tract.
Elevated temperatures or mechanical action may form vapors, mists or fumes which may be irritating to the
eyes and respiratory tract.
Contains additives that are encapsulated in the polymer. Under normal conditions of processing and use the
encapsulated additives are not expected to pose a health hazard, however, grinding of the polymer is not
recommended.
Additional information is available by request.
The following ingredients are cited on the lists below: None.
–REGULATORY LISTS SEARCHED–
1 = NTP CARC 3 = IARC 1 5 = IARC 2B
2 = NTP SUS 4 = IARC 2A 6 = OSHA CARC
SECTION 12 ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials.
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Revision Date: 24 Jun 2010
Page 7 of 10
______________________________________________________________________________________________________________________
ECOTOXICITY
Material — Not expected to be harmful to aquatic organisms.
Material — Not expected to be harmful to terrestrial organisms.
MOBILITY
Material — Low solubility and floats and is expected to migrate from water to the land. Expected to
partition to sediment and wastewater solids.
PERSISTENCE AND DEGRADABILITY
Biodegradation:
Material — Expected to be persistent.
Hydrolysis:
Material — Transformation due to hydrolysis not expected to be significant.
Photolysis:
Material — Transformation due to photolysis not expected to be significant.
Atmospheric Oxidation:
Material — Transformation due to atmospheric oxidation not expected to be significant.
BIOACCUMULATION POTENTIAL
Material — Potential to bioaccumulate is low.
SECTION 13 DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable
laws and regulations, and material characteristics at time of disposal.
DISPOSAL RECOMMENDATIONS
Suitable routes of disposal are supervised incineration, preferentially with energy recovery, or appropriate
recycling methods in accordance with applicable regulations and material characteristics at the time of disposal.
REGULATORY DISPOSAL INFORMATION
RCRA Information: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous
waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed as hazardous wastes. It
does not exhibit the hazardous characteristics of ignitability, corrositivity or reactivity and is not formulated with
contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used
product may be regulated.
SECTION 14 TRANSPORT INFORMATION
LAND (DOT): Not Regulated for Land Transport
LAND (TDG): Not Regulated for Land Transport
SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Revision Date: 24 Jun 2010
Page 8 of 10
______________________________________________________________________________________________________________________
AIR (IATA): Not Regulated for Air Transport
SECTION 15 REGULATORY INFORMATION
OSHA HAZARD COMMUNICATION STANDARD: When used for its intended purposes, this material is not
classified as hazardous in accordance with OSHA 29 CFR 1910.1200.
NATIONAL CHEMICAL INVENTORY LISTING: EINECS, TSCA
EPCRA: This material contains no extremely hazardous substances.
CWA / OPA: Plastic pellets are defined by the US EPA under the Clean Water Act (40CFR122.26) as a “significant
material” which requires any industrial plant that may expose pellets to storm water to secure a storm water permit.
Violations of the rule carry the same penalties as other Clean Water Act violations. Pellets found in storm water runoff
are subject to EPA regulations with the potential for substantial fines and penalties.
SARA (311/312) REPORTABLE HAZARD CATEGORIES: None.
SARA (313) TOXIC RELEASE INVENTORY: This material contains no chemicals subject to the supplier notification
requirements of the SARA 313 Toxic Release Program.
The following ingredients are cited on the lists below:* None.
–REGULATORY LISTS SEARCHED–
1 = ACGIH ALL 6 = TSCA 5a2 11 = CA P65 REPRO 16 = MN RTK
2 = ACGIH A1 7 = TSCA 5e 12 = CA RTK 17 = NJ RTK
3 = ACGIH A2 8 = TSCA 6 13 = IL RTK 18 = PA RTK
4 = OSHA Z 9 = TSCA 12b 14 = LA RTK 19 = RI RTK
5 = TSCA 4 10 = CA P65 CARC 15 = MI 293
Code key: CARC=Carcinogen; REPRO=Reproductive
* EPA recently added new chemical substances to its TSCA Section 4 test rules. Please contact the supplier to
confirm whether the ingredients in this product currently appear on a TSCA 4 or TSCA 12b list.
Contact Sales / Marketing group for complete chemical inventory listing applicable to product.
SECTION 16 OTHER INFORMATION
N/D = Not determined, N/A = Not applicable
THIS SAFETY DATA SHEET CONTAI NS THE FOLLOWING REVISIONS:
Revision Changes:
Section 10 Stability and Reactivity – Header was modified.
Section 13: Disposal Recommendations – Note was modified.
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Revision Date: 24 Jun 2010
Page 9 of 10
______________________________________________________________________________________________________________________
Section 08: Personal Protection was modified.
Section 07: Handling and Storage – Storage Phrases was modified.
Hazard Identification: Physical/Chemical Hazard was modified.
Section 07: Loading/Unloading Temperature C(F) was modified.
Section 07: Transport Temperature C(F) was modified.
Section 07: Transport Pressure kPa was modified.
Section 07: Storage Temperature C(F) was modified.
Section 07: Storage Pressure kPa was modified.
Section 07: Suitable Materials and Coatings – Header was modified.
Section 11: Dermal Lethality Test Comment was modified.
Section 05: Hazardous Combustion Products was modified.
Section 06: Accidental Release – Spill Management – Water was modified.
Section 09: Relative Density – Header was modified.
Section 08: Hand Protection was modified.
Section 14: Sea (IMDG) – Header was modified.
Section 14: Air (IATA) – Header was modified.
Section 14: LAND (TDG) – Header was modified.
Section 14: LAND (DOT) – Header was modified.
Section 15: List Citation Table – Header was modified.
Section 14: LAND (DOT) – Default was modified.
Section 14: LAND (TDG) Default was modified.
Section 14: Sea (IMDG) – Default was modified.
Section 14: Air (IATA) – Default was modified.
Section 15: National Chemical Inventory Listing was modified.
Section 08: Exposure limits/standards was modified.
Section 15: OSHA Hazard Communication Standard was modified.
Hazard Identification: OSHA – May be Hazardous Statement was modified.
Section 06: Notification Procedures was modified.
Composition: Footnotes was modified.
Section 11: Chronic Tox – Product was modified.
Section 09: Oxidizing Properties was modified.
THIS MSDS COVERS THE FOLLOWING MATERIALS: Linear Low Density PE grades for which the grade name
consists of a base polymer designated by a LL or LLP prefix followed by a suffix referring to an additive package.
Applicable designations follow. | Base polymers : | LL 1000S | LL 1001 | LL 1002 | LL 1004 | LL 1015
| LL 1030 | LL 1201 | LL 1433 | LL 3000S | LL 3001 | LL 3002 | LL 3003 | LL 3113 | LL 3201 |
LL 3402 | LL 3403 | LL 3404 | LL 3405 | LL 4004 | LL 5002 | LL 5100 | LL 5202 | LL 5252 | LL
60 | LL 6021 | LL 6100 | LL 6101 | LL 6201 | LL 6202 | LL 6235 | LL 6301 | LL 6407 | LL 8360 |
LL 8446 | LL 8450 | LL 8455 | LL 8460 | LL 8470 | LL 8501 | LL 8555 | LLP 8360 | LLP 8450 |
LLP 8455 | LLP 8460 | LLP 8470 | LLP 8555 | Possible additive packages : | 09 | 17 | 17BG | 19 |
19BG | 21 | 22 | 24 | 25 | 28 | 29 | 31 | 32 | 38 | 39 | 42 | 43 | 45 | 46 | 47 | 48
| 55 | 67 | 74 | 77 | 79 | 80 | 82 | BG | EL | KI | KW | RQ | X29 | X59 | X72 |
X74 | X75 | X76 | XR | XV | XW1 | XW2 | XZ1 | XZ2 | YB | YM | YMEX | ZA | ZB |
ZZ
—————————————————————————————————————————————————–
—————————————————————————————————————————————————–
The information and recommendations contained herein are, to the best of ExxonMobil’s knowledge and belief, accurate
and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current
available from ExxonMobil. The information and recommendations are offered for the user’s consideration and
examination. It is the user’s responsibility to satisfy itself that the product is suitable for the intended use. If buyer
repackages this product, it is the user’s responsibility to insure proper health, safety and other necessary information is
included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to
handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law,
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Revision Date: 24 Jun 2010
Page 10 of 10
______________________________________________________________________________________________________________________
re-publication or retransmission of this document, in whole or in part, is not permitted. The term, “ExxonMobil” is used
for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any
affiliates in which they directly or indirectly hold any interest.
—————————————————————————————————————————————————–
Internal Use Only
MHC: 0, 0, 0, 0, 0, 0
DGN: 4406375KCA (1010937)
—————————————————————————————————————————————————–
Copyright 2002 Exxon Mobil Corporation, All rights reserved
by | Sep 27, 2025
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Revision Date: 24 Jun 2010
Page 1 of 10
______________________________________________________________________________________________________________________
MATERIAL SAFETY DATA SHEET
SECTION 1 PRODUCT AND COMPANY IDENTIFICATION
PRODUCT
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Product Description: LLDPE without polymer processing aid, see Section 16 for applicable grades.
Product Code: 19889
Intended Use: Coatings, Extrusion and moulding, Film blowing
COMPANY IDENTIFICATION
Supplier: CIOL – EXXONMOBIL CHEMICAL CANADA
Division of Canada Imperial Oil Limited, an Affiliate of Exxon Mobil Corporation
240 4TH AVENUE S.W.
CALGARY, ALBERTA. T2P 3M9 Canada
24 Hour Health Emergency 519-339-2145
Transportation Emergency Phone 519-339-2145
Product Technical Information 800-668-0177
SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS
No Reportable Hazardous Substance(s) or Complex Substance(s).
NOTE: The product may contain varying levels of additives such as slip and antiblocking agents, antioxidants and
stabilizers.
SECTION 3 HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15).
POTENTIAL PHYSICAL / CHEMICAL EFFECTS
High dust levels may create potential for explosion. Spilled pellets present a slipping hazard on hard
surfaces. Contact with hot material can cause thermal burns which may result in permanent damage.
Material can accumulate static charges which may cause an ignition.
POTENTIAL HEALTH EFFECTS
Material is essentially non-toxic. However, if dust is generated, it could scratch the eyes and cause minor
irritation to the respiratory tract. When heated, the vapors/fumes given off may cause respiratory tract irritation.
NFPA Hazard ID: Health: 1 Flammability: 1 Reactivity: 0
HMIS Hazard ID: Health: 1 Flammability: 1 Reactivity: 0
SECTION 4 FIRST AID MEASURES
INHALATION
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Revision Date: 24 Jun 2010
Page 2 of 10
______________________________________________________________________________________________________________________
In case of adverse exposure to vapors and / or aerosols formed at elevated temperatures, immediately remove
the affected victim from exposure. Administer artificial respiration if breathing is stopped. Keep at rest.
SKIN CONTACT
For hot product: Immediately immerse in or flush affected area with large amounts of cold water to dissipate
heat. Cover with clean cotton sheeting or gauze and get prompt medical attention.
EYE CONTACT
Flush thoroughly with water. If irritation occurs, get medical assistance.
INGESTION
No adverse effects due to ingestion are expected.
SECTION 5 FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish
flames.
Inappropriate Extinguishing Media: Straight Streams of Water
FIRE FIGHTING
Fire Fighting Instructions: Assure an extended cooling down period to prevent re-ignition. Evacuate area.
Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. Firefighters
should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA).
Use water spray to cool fire exposed surfaces and to protect personnel.
Unusual Fire Hazards: High dust levels may create potential for explosion.
Hazardous Combustion Products: Smoke, Fume, Incomplete combustion products, Oxides of carbon,
Flammable hydrocarbons
FLAMMABILITY PROPERTIES
Flash Point [Method]: N/A
Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D
Autoignition Temperature: N/A
SECTION 6 ACCIDENTAL RELEASE MEASURES
NOTIFICATION PROCEDURES
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable
regulations. US regulations require reporting releases of this material to the environment which exceed the
applicable reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The
National Response Center can be reached at (800)424-8802.
SPILL MANAGEMENT
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Revision Date: 24 Jun 2010
Page 3 of 10
______________________________________________________________________________________________________________________
Land Spill: Spilled pellets present a slipping hazard on hard surfaces. Small Dry Spills: With clean shovel
place material into clean, dry container and cover loosely; move containers from spill area.
Water Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Warn other
shipping. Skim from surface.
Water spill and land spill recommendations are based on the most likely spill scenario for this material;
however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction
and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be
consulted. Note: Local regulations may prescribe or limit action to be taken.
ENVIRONMENTAL PRECAUTIONS
Prevent entry into waterways, sewers, basements or confined areas. For Large Spills: Cover spill with plastic
sheet or tarpaulin to minimize spreading.
SECTION 7 HANDLING AND STORAGE
HANDLING
Avoid elevated temperatures for prolonged periods of time. Prevent small spills and leakage to avoid slip
hazard. Avoid conditions which create dust. DO NOT handle, store or open near an open flame, sources of
heat or sources of ignition. Protect material from direct sunlight. Material can accumulate static charges which
may cause an electrical spark (ignition source). Care should be taken when storing and handling this product.
Apart from the specific nature of the polymer product, conditions such as humidity, sunlight, and temperature
have an influence on the way the product behaves during storage and handling. Special attention should be
paid to avoid inappropriate stacking of palletized bags or other package units. Indeed, polymer products may be
dimensionally unstable under certain conditions. Avoid conditions generating heat during transfer operations.
Loading/Unloading Temperature: [Ambient]
Transport Temperature: [Ambient]
Transport Pressure: [Ambient]
Static Accumulator: This material is a static accumulator.
STORAGE
The container choice, for example storage vessel, may effect static accumulation and dissipation. Store in a
cool, dry place with adequate ventilation. Keep away from incompatible materials, open flames, and high
temperatures. Do not store in open or unlabelled containers.
Storage Temperature: [Ambient]
Storage Pressure: [Ambient]
Suitable Containers/Packing: Bulk Containers; Hopper Cars; Bags; Boxes; Drums; Octatainer; Silos
Suitable Materials and Coatings (Chemical Compatibility): Aluminum; Polyethylene Bags
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure limits/standards for materials that can be formed when handling this product: For dusty conditions,
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Revision Date: 24 Jun 2010
Page 4 of 10
______________________________________________________________________________________________________________________
OSHA recommends for particulates not otherwise regulated an 8-hour TWA of 15 mg/m3 (total dust), 5 mg/m3
(respirable fraction); ACGIH recommends for insoluble and poorly soluble particles not otherwise specified an 8-hour
TWA of 10 mg/m3 (inhalable particles), 3 mg/m3 (respirable particles). Product may also contain varying levels of
additives, such as slip and antiblocking agents (talc or silica), antioxidants, stabilizers, and corrosion inhibitors. Certain
grades may contain cristobalite, a form of crystalline silica, as an additive that is encapsulated in the polymer. Inhaled
crystalline silica in an occupational environment is recognized as a known human carcinogen. However, the potential for
release of silica to the air when this polymer is handled has been assessed and the encapsulated silica within the
polymer is not expected to pose a health hazard when processed under normal conditions of use.
NOTE: Limits/standards shown for guidance only. Follow applicable regulations.
ENGINEERING CONTROLS
The level of protection and types of controls necessary will vary depending upon potential exposure conditions.
Control measures to consider:
Adequate ventilation should be provided so that exposure limits are not exceeded. SPECIAL
PRECAUTIONS: Should significant vapors/fumes be generated during thermal processing of this
product, it is recommended that work stations be monitored for the presence of thermal degradation
by-products which may evolve at elevated temperatures (for example, oxygenated components).
Processors of this product should assure that adequate ventilation or other controls are used to control
exposure. It is recommended that the current ACGIH-TLVs for thermal degradation by-products be
observed. Contact your local sales representative for further information.
PERSONAL PROTECTION
Personal protective equipment selections vary based on potential exposure conditions such as applications,
handling practices, concentration and ventilation. Information on the selection of protective equipment for use
with this material, as provided below, is based upon intended, normal usage.
Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a
level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator
selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of
respirators to be considered for this material include:
Half-face filter respirator
For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode.
Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate,
gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded.
Hand Protection: Any specific glove information provided is based on published literature and glove
manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions.
Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use
conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material
include:
If product is hot, thermally protective, chemical resistant gloves are recommended. If contact with
forearms is likely, wear gauntlet style gloves.
Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or
manufacturer data. The types of clothing to be considered for this material include:
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Revision Date: 24 Jun 2010
Page 5 of 10
______________________________________________________________________________________________________________________
If product is hot, thermally protective, chemical resistant apron and long sleeves are recommended.
Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after
handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned.
Practice good housekeeping.
ENVIRONMENTAL CONTROLS
See Sections 6, 7, 12, 13.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Typical physical and chemical properties are given below. Consult the Supplier in Section 1 for additional
data.
GENERAL INFORMATION
Physical State: Solid
Form: Pellet, Granule, Powder
Color: Clear to Opaque, White to Off-White
Odor: None to Mild
Odor Threshold: N/A
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION
Relative Density (at 15 C): 0.9 – 0.95
Bulk Density: 0.4 g/cc at 20 C – 1 g/cc at 20 C
Flash Point [Method]: N/A
Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D
Autoignition Temperature: N/A
Boiling Point / Range: N/A
Vapor Density (Air = 1): N/A
Vapor Pressure: N/A
Evaporation Rate (n-butyl acetate = 1): N/A
pH: N/A
Log Pow (n-Octanol/Water Partition Coefficient): N/A
Solubility in Water: Negligible
Viscosity: N/A
Oxidizing Properties: See Hazards Identification Section.
OTHER INFORMATION
Freezing Point: N/D
Melting Point: 115 C (239 F) – 130 C (266 F)
Molecular Weight: > 25000
Hygroscopic: No
SECTION 10 STABILITY AND REACTIVITY
STABILITY: Material is stable under normal conditions.
CONDITIONS TO AVOID: Avoid elevated temperatures for prolonged periods of time.
MATERIALS TO AVOID: Strong oxidizers
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Revision Date: 24 Jun 2010
Page 6 of 10
______________________________________________________________________________________________________________________
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures.
HAZARDOUS POLYMERIZATION: Will not occur.
SECTION 11 TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
Route of Exposure
Conclusion / Remarks
Inhalation
Toxicity: Data available. Minimally Toxic. Based on test data for structurally similar
materials.
Irritation: Data available. Negligible haz ard at ambient/normal handling temperatures.
Based on test data for structurally similar materials.
Ingestion
Toxicity: Data available. Minimally Toxic. Based on test data for structurally similar
materials.
Skin
Toxicity: Data available. Minimally Toxic. Based on test data for structurally similar
materials.
Irritation: Data available. Negl igible irritation to skin at ambient temperatures. Based on test
data for structurally similar materials.
Eye
Irritation: Data available. May cause mild, s hort-lasting discomfort to eyes. Based on test
data for structurally similar materials.
CHRONIC/OTHER EFFECTS
For the product itself:
Dust may be irritating to the eyes and respiratory tract.
Elevated temperatures or mechanical action may form vapors, mists or fumes which may be irritating to the
eyes and respiratory tract.
Contains additives that are encapsulated in the polymer. Under normal conditions of processing and use the
encapsulated additives are not expected to pose a health hazard, however, grinding of the polymer is not
recommended.
Additional information is available by request.
The following ingredients are cited on the lists below: None.
–REGULATORY LISTS SEARCHED–
1 = NTP CARC 3 = IARC 1 5 = IARC 2B
2 = NTP SUS 4 = IARC 2A 6 = OSHA CARC
SECTION 12 ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials.
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Revision Date: 24 Jun 2010
Page 7 of 10
______________________________________________________________________________________________________________________
ECOTOXICITY
Material — Not expected to be harmful to aquatic organisms.
Material — Not expected to be harmful to terrestrial organisms.
MOBILITY
Material — Low solubility and floats and is expected to migrate from water to the land. Expected to
partition to sediment and wastewater solids.
PERSISTENCE AND DEGRADABILITY
Biodegradation:
Material — Expected to be persistent.
Hydrolysis:
Material — Transformation due to hydrolysis not expected to be significant.
Photolysis:
Material — Transformation due to photolysis not expected to be significant.
Atmospheric Oxidation:
Material — Transformation due to atmospheric oxidation not expected to be significant.
BIOACCUMULATION POTENTIAL
Material — Potential to bioaccumulate is low.
SECTION 13 DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable
laws and regulations, and material characteristics at time of disposal.
DISPOSAL RECOMMENDATIONS
Suitable routes of disposal are supervised incineration, preferentially with energy recovery, or appropriate
recycling methods in accordance with applicable regulations and material characteristics at the time of disposal.
REGULATORY DISPOSAL INFORMATION
RCRA Information: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous
waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed as hazardous wastes. It
does not exhibit the hazardous characteristics of ignitability, corrositivity or reactivity and is not formulated with
contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used
product may be regulated.
SECTION 14 TRANSPORT INFORMATION
LAND (DOT): Not Regulated for Land Transport
LAND (TDG): Not Regulated for Land Transport
SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Revision Date: 24 Jun 2010
Page 8 of 10
______________________________________________________________________________________________________________________
AIR (IATA): Not Regulated for Air Transport
SECTION 15 REGULATORY INFORMATION
OSHA HAZARD COMMUNICATION STANDARD: When used for its intended purposes, this material is not
classified as hazardous in accordance with OSHA 29 CFR 1910.1200.
NATIONAL CHEMICAL INVENTORY LISTING: EINECS, TSCA
EPCRA: This material contains no extremely hazardous substances.
CWA / OPA: Plastic pellets are defined by the US EPA under the Clean Water Act (40CFR122.26) as a “significant
material” which requires any industrial plant that may expose pellets to storm water to secure a storm water permit.
Violations of the rule carry the same penalties as other Clean Water Act violations. Pellets found in storm water runoff
are subject to EPA regulations with the potential for substantial fines and penalties.
SARA (311/312) REPORTABLE HAZARD CATEGORIES: None.
SARA (313) TOXIC RELEASE INVENTORY: This material contains no chemicals subject to the supplier notification
requirements of the SARA 313 Toxic Release Program.
The following ingredients are cited on the lists below:* None.
–REGULATORY LISTS SEARCHED–
1 = ACGIH ALL 6 = TSCA 5a2 11 = CA P65 REPRO 16 = MN RTK
2 = ACGIH A1 7 = TSCA 5e 12 = CA RTK 17 = NJ RTK
3 = ACGIH A2 8 = TSCA 6 13 = IL RTK 18 = PA RTK
4 = OSHA Z 9 = TSCA 12b 14 = LA RTK 19 = RI RTK
5 = TSCA 4 10 = CA P65 CARC 15 = MI 293
Code key: CARC=Carcinogen; REPRO=Reproductive
* EPA recently added new chemical substances to its TSCA Section 4 test rules. Please contact the supplier to
confirm whether the ingredients in this product currently appear on a TSCA 4 or TSCA 12b list.
Contact Sales / Marketing group for complete chemical inventory listing applicable to product.
SECTION 16 OTHER INFORMATION
N/D = Not determined, N/A = Not applicable
THIS SAFETY DATA SHEET CONTAI NS THE FOLLOWING REVISIONS:
Revision Changes:
Section 10 Stability and Reactivity – Header was modified.
Section 13: Disposal Recommendations – Note was modified.
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Revision Date: 24 Jun 2010
Page 9 of 10
______________________________________________________________________________________________________________________
Section 08: Personal Protection was modified.
Section 07: Handling and Storage – Storage Phrases was modified.
Hazard Identification: Physical/Chemical Hazard was modified.
Section 07: Loading/Unloading Temperature C(F) was modified.
Section 07: Transport Temperature C(F) was modified.
Section 07: Transport Pressure kPa was modified.
Section 07: Storage Temperature C(F) was modified.
Section 07: Storage Pressure kPa was modified.
Section 07: Suitable Materials and Coatings – Header was modified.
Section 11: Dermal Lethality Test Comment was modified.
Section 05: Hazardous Combustion Products was modified.
Section 06: Accidental Release – Spill Management – Water was modified.
Section 09: Relative Density – Header was modified.
Section 08: Hand Protection was modified.
Section 14: Sea (IMDG) – Header was modified.
Section 14: Air (IATA) – Header was modified.
Section 14: LAND (TDG) – Header was modified.
Section 14: LAND (DOT) – Header was modified.
Section 15: List Citation Table – Header was modified.
Section 14: LAND (DOT) – Default was modified.
Section 14: LAND (TDG) Default was modified.
Section 14: Sea (IMDG) – Default was modified.
Section 14: Air (IATA) – Default was modified.
Section 15: National Chemical Inventory Listing was modified.
Section 08: Exposure limits/standards was modified.
Section 15: OSHA Hazard Communication Standard was modified.
Hazard Identification: OSHA – May be Hazardous Statement was modified.
Section 06: Notification Procedures was modified.
Composition: Footnotes was modified.
Section 11: Chronic Tox – Product was modified.
Section 09: Oxidizing Properties was modified.
THIS MSDS COVERS THE FOLLOWING MATERIALS: Linear Low Density PE grades for which the grade name
consists of a base polymer designated by a LL or LLP prefix followed by a suffix referring to an additive package.
Applicable designations follow. | Base polymers : | LL 1000S | LL 1001 | LL 1002 | LL 1004 | LL 1015
| LL 1030 | LL 1201 | LL 1433 | LL 3000S | LL 3001 | LL 3002 | LL 3003 | LL 3113 | LL 3201 |
LL 3402 | LL 3403 | LL 3404 | LL 3405 | LL 4004 | LL 5002 | LL 5100 | LL 5202 | LL 5252 | LL
60 | LL 6021 | LL 6100 | LL 6101 | LL 6201 | LL 6202 | LL 6235 | LL 6301 | LL 6407 | LL 8360 |
LL 8446 | LL 8450 | LL 8455 | LL 8460 | LL 8470 | LL 8501 | LL 8555 | LLP 8360 | LLP 8450 |
LLP 8455 | LLP 8460 | LLP 8470 | LLP 8555 | Possible additive packages : | 09 | 17 | 17BG | 19 |
19BG | 21 | 22 | 24 | 25 | 28 | 29 | 31 | 32 | 38 | 39 | 42 | 43 | 45 | 46 | 47 | 48
| 55 | 67 | 74 | 77 | 79 | 80 | 82 | BG | EL | KI | KW | RQ | X29 | X59 | X72 |
X74 | X75 | X76 | XR | XV | XW1 | XW2 | XZ1 | XZ2 | YB | YM | YMEX | ZA | ZB |
ZZ
—————————————————————————————————————————————————–
—————————————————————————————————————————————————–
The information and recommendations contained herein are, to the best of ExxonMobil’s knowledge and belief, accurate
and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current
available from ExxonMobil. The information and recommendations are offered for the user’s consideration and
examination. It is the user’s responsibility to satisfy itself that the product is suitable for the intended use. If buyer
repackages this product, it is the user’s responsibility to insure proper health, safety and other necessary information is
included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to
handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law,
Product Name: LINEAR LOW DENSITY POLYETHYLENE – Grades designated by LL or LLP prefix
Revision Date: 24 Jun 2010
Page 10 of 10
______________________________________________________________________________________________________________________
re-publication or retransmission of this document, in whole or in part, is not permitted. The term, “ExxonMobil” is used
for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any
affiliates in which they directly or indirectly hold any interest.
—————————————————————————————————————————————————–
Internal Use Only
MHC: 0, 0, 0, 0, 0, 0
DGN: 4406375KCA (1010937)
—————————————————————————————————————————————————–
Copyright 2002 Exxon Mobil Corporation, All rights reserved
by | Sep 27, 2025
3M Platinum Plus , PN 0032, 01130, 01131, 01132, 01135B, 31181, 31139, 31632 08/03/23
________________________________________________________________________________________________________
Page 1 of 2
Safety Data Sheet
Copyright,2023, 3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed
provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither
the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document Group:24-8735-3Version Number:6.03Issue Date:08/03/23Supercedes Date:03/10/23
Product identifier
3M Platinum Plus , PN 0032, 01130, 01131, 01132, 01135B, 31181, 31139, 31632
ID Number(s):
41-0003-6598-5, 41-0003-6676-9, 41-0003-6712-2, 41-0003-6733-8, 41-0003-6789-0, 60-4550-4436-6, 60-4550-4793-0, 60-4550-
5371-4, 60-4550-5544-6, 60-4550-5548-7, 60-4550-6546-0, 60-4550-8115-2, 60-4550-8621-9, 70-0080-0095-5, 70-0080-0096-3
7000001498, 7010314197, 7000119981, 7000120072, 7100142876
Recommended use
Automotive, Auto Body Repair
Supplier’s details
MANUFACTURER:3MDIVISION:Automotive AftermarketADDRESS:3M Center, St. Paul, MN 55144-1000, USATelephone:1-888-3M HELPS (1-888-364-3577)
Emergency telephone number
1-800-364-3577 or (651) 737-6501 (24 hours)
This product is a kit or a multipart product which consists of multiple, independently packaged components. A Safety Data
Sheet (SDS), Article Information Sheet (AIS), or Article Information Letter (AIL) for each of these components is included.
Please do not separate the component documents from this cover page. The document numbers for components of this
product are:
29-5993-0, 24-8206-5
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO
WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user’s method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user’s knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user’s method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
3M Platinum Plus , PN 0032, 01130, 01131, 01132, 01135B, 31181, 31139, 31632 08/03/23
________________________________________________________________________________________________________
Page 2 of 2
In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M.
3M USA SDSs are available at www.3M.com
3M Cream Hardener (Red, White & Blue) 02/24/22
__________________________________________________________________________________________
Page 1 of 12
Safety Data Sheet
Copyright,2022, 3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document Group:29-5993-0Version Number:6.00Issue Date:02/24/22Supercedes Date:12/07/21
SECTION 1: Identification
1.1. Product identifier
3M Cream Hardener (Red, White & Blue)
Product Identification Numbers
LB-K100-0965-7, LB-K100-0965-8, LB-K100-0965-9, LB-K100-0966-0, LB-K100-0966-1, LB-K100-0966-2, LB-K100-
0966-3, LB-K100-1035-6, LB-K100-1045-4, LB-K100-1286-7, 41-0003-6674-4, 41-0003-6682-7, 41-0003-6685-0, 41-0003-
6686-8, 41-0003-6687-6, 41-0003-7901-0, 41-0003-7903-6, 41-0003-7904-4, 41-0003-7922-6, 41-0003-7928-3, 41-0003-
7930-9, 41-0003-7931-7, 41-0003-7932-5, 41-0003-7933-3, 41-0003-7935-8, 41-0003-7987-9, 41-0003-8059-6, 41-0003-
8072-9, 41-0003-8073-7, 41-0003-8074-5, 41-0003-8146-1, 60-4550-6617-9, 60-4550-6830-8, 60-4550-6981-9, 60-4550-
6982-7, 60-4550-8123-6, 60-4551-0388-1
7000120090, 7010327931, 7000120133, 7100191003
1.2. Recommended use and restrictions on use
Recommended use
Automotive, hardener for body fillers & glazes
1.3. Supplier s details
MANUFACTURER:3MDIVISION:Automotive AftermarketADDRESS:3M Center, St. Paul, MN 55144-1000, USATelephone:1-888-3M HELPS (1-888-364-3577)
1.4. Emergency telephone number
1-800-364-3577 or (651) 737-6501 (24 hours)
SECTION 2: Hazard identification
The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200.
This information may be different from the actual product label information for labels regulated by other agencies.
2.1. Hazard classification
Organic Peroxide: Type E.
Serious Eye Damage/Irritation: Category 2A.
Skin Sensitizer: Category 1B.
Specific Target Organ Toxicity (single exposure): Category 1.
2.2. Label elements
3M Cream Hardener (Red, White & Blue) 02/24/22
__________________________________________________________________________________________
Page 2 of 12
Signal word
Danger
Symbols
Flame | Exclamation mark | Health Hazard |
Pictograms
Hazard Statements
Heating may cause a fire. Causes serious eye irritation. May cause an allergic skin reaction. Causes damage to organs: cardiovascular system | nervous system | kidney/urinary tract | respiratory system |
Precautionary Statements
General:
Keep out of reach of children.
Prevention:
Keep away from heat/sparks/open flames/hot surfaces. – No smoking. Keep away from clothing and other combustible materials. Keep only in original container. Do not breathe dust/fume/gas/mist/vapors/spray. Wear protective gloves and eye/face protection. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace.
Response:
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. IF exposed: Call a POISON CENTER or doctor/physician. Specific treatment (see Notes to Physician on this label).
Storage:
Protect from sunlight. Store at temperatures not exceeding 32C/90F. Keep cool. Store locked up. Store away from other materials.
3M Cream Hardener (Red, White & Blue) 02/24/22
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Page 3 of 12
Disposal:
Dispose of contents/container in accordance with applicable local/regional/national/international regulations.
Notes to Physician:
This product contains ethylene glycol. If there is reasonable suspicion of ethylene glycol poisoning, intravenous (IV)
administration with either fomepizole (preferred) or ethanol (if fomepizole is unavailable) should be considered as part of the
medical management.
SECTION 3: Composition/information on ingredients
IngredientC.A.S. No.% by WtBenzoyl Peroxide94-36-0 30 – 60 Trade Secret *Benzoic Acid, C9-11-Branched Alkyl Esters131298-44-7 10 – 30 Trade Secret *Water7732-18-5 10 – 30 Trade Secret *Calcium Sulfate7778-18-9 1 – 10 Trade Secret *Zinc Stearate557-05-1 1 – 10 Trade Secret *Ethylene Glycol107-21-1<= 7.5 Trade Secret *Iron Oxide (FE2O3)1309-37-1<= 5 Trade Secret *Oxirane, Polymer with Methyloxirane, Monobutyl Ether9038-95-3<= 5 Trade Secret *Ferric Ammonium Ferrocyanide25869-00-5<= 1 Trade Secret *Ferric Ferrocyanide14038-43-8<= 1 Trade Secret *
*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.
Skin Contact:
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get
medical attention.
Eye Contact:
Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention.
If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
Allergic skin reaction (redness, swelling, blistering, and itching). Target organ effects. See Section 11 for additional details.
4.3. Indication of any immediate medical attention and special treatment required
This product contains ethylene glycol. If there is reasonable suspicion of ethylene glycol poisoning, intravenous (IV) administration with
either fomepizole (preferred) or ethanol (if fomepizole is unavailable) should be considered as part of the medical management.
SECTION 5: Fire-fighting measures
5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.
5.2. Special hazards arising from the substance or mixture
3M Cream Hardener (Red, White & Blue) 02/24/22
__________________________________________________________________________________________
Page 4 of 12
Closed containers exposed to heat from fire may build pressure and explode. Part of the oxygen for combustion is supplied
by the peroxide itself.
5.3. Special protective actions for fire-fighters
Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus,
bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Eliminate all ignition sources if safe to do so. Keep away from heat/sparks/open flames/hot surfaces. - No
smoking. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces,
provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning!
A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to
other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and
personal protective equipment.
6.2. Environmental precautions
Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or
bodies of water.
6.3. Methods and material for containment and cleaning up
Collect as much of the spilled material as possible using non-sparking tools. Place in a closed container approved for
transportation by appropriate authorities. Clean up residue. Seal the container. Dispose of collected material as soon as
possible in accordance with applicable local/regional/national/international regulations.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Do not use in a confined area with minimal air exchange. Keep out of reach of children. Keep away from heat/sparks/open
flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on
clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work
clothing should not be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing
before reuse.
7.2. Conditions for safe storage including any incompatibilities
Keep container tightly closed. Protect from sunlight. Store away from heat. Store at temperatures not exceeding
32C/90F. Keep cool. Keep only in original container. Store away from other materials. Keep/store away from clothing
and other combustible materials.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Occupational exposure limits
If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
IngredientC.A.S. No.AgencyLimit typeAdditional CommentsEthylene Glycol107-21-1ACGIHTWA(Vapor fraction):25
ppm;STEL(Vapor fraction):50
ppm;STEL(Inhalable
aerosol):10 mg/m3
A4: Not class. as human
carcin
Iron Oxide (FE2O3)1309-37-1ACGIHTWA(respirable fraction):5
mg/m3
A4: Not class. as human
carcin
3M Cream Hardener (Red, White & Blue) 02/24/22
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Iron Oxide (FE2O3)1309-37-1OSHATWA(as fume):10 mg/m3CYANIDES14038-43-8OSHATWA(as CN):5 mg/m3SKINZinc Stearate557-05-1OSHATWA(as total dust):15
mg/m3;TWA(respirable
fraction):5 mg/m3
Calcium Sulfate7778-18-9ACGIHTWA(inhalable fraction):10
mg/m3
Calcium Sulfate7778-18-9OSHATWA(as total dust):15
mg/m3;TWA(respirable
fraction):5 mg/m3
Benzoyl Peroxide94-36-0ACGIHTWA:5 mg/m3A4: Not class. as human
carcin
Benzoyl Peroxide94-36-0OSHATWA:5 mg/m3
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Guidelines
OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Provide ventilation adequate to maintain dust concentration below minimum explosive concentrations. Use general dilution
ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control
dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Indirect Vented Goggles
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity.
Gloves made from the following material(s) are recommended: Polymer laminate
If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then
use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an
exposure assessment. The following protective clothing material(s) are recommended: Apron - polymer laminate
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part
of a full respiratory protection program. Based on the results of the exposure assessment, select from the following
respirator type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
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SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance
Physical state
Color
Solid
Red
Specific Physical Form: PasteOdorSlight EsterOdor thresholdNo Data AvailablepHNo Data AvailableMelting pointNo Data AvailableBoiling PointNo Data AvailableFlash Point111 C [ Test Method:Estimated]Evaporation rateNo Data AvailableFlammability (solid, gas)Organic Peroxide: Type E.Flammable Limits(LEL)Not ApplicableFlammable Limits(UEL)Not ApplicableVapor PressureNot ApplicableVapor DensityNot ApplicableDensity1.2 g/cm3Specific Gravity1.2 [@ 25 C] [Ref Std:WATER=1]Solubility in WaterNegligibleSolubility- non-waterNo Data AvailablePartition coefficient: n-octanol/ waterNo Data AvailableAutoignition temperatureNo Data AvailableDecomposition temperatureNo Data AvailableViscosityNo Data AvailableHazardous Air Pollutants0 - 0.1209 lb HAPS/lb solids [Test Method:Calculated]Molecular weightNot ApplicableVolatile Organic Compounds0 - 90 g/l [ Test Method:calculated SCAQMD rule 443.1]Volatile Organic Compounds0 % weight [Test Method: calculated per CARB title 2]Percent volatile21 - 28.5 %VOC Less H2O & Exempt Solvents0 - 121 g/l [ Test Method:calculated SCAQMD rule 443.1]
SECTION 10: Stability and reactivity
10.1. Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section.
10.2. Chemical stability
Stable. Stable unless exposed to heat, flames and drying conditions.
10.3. Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4. Conditions to avoid
Heat
10.5. Incompatible materials
Accelerators
10.6. Hazardous decomposition products
SubstanceCondition Carbon monoxide Not Specified
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Carbon dioxide Not Specified Toxic Vapor, Gas, Particulate Not Specified
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1. Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.
Skin Contact:
May be harmful in contact with skin.
Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.
Eye Contact:
Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the
cornea, and impaired vision.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
May cause additional health effects (see below).
Additional Health Effects:
Single exposure may cause target organ effects:
Cardiac Effects: Signs/symptoms may include irregular heartbeat (arrhythmia), changes in heart rate, damage to heart
muscle, heart attack, and may be fatal.
Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or
numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate.
Respiratory Effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart
rate, bluish colored skin (cyanosis), sputum production, changes in lung function tests, and/or respiratory failure.
Kidney/Bladder Effects: Signs/symptoms may include changes in urine production, abdominal or lower back pain,
increased protein in urine, increased blood urea nitrogen (BUN), blood in urine, and painful urination.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
NameRouteSpeciesValue
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Overall productDermalNo data available; calculated ATE >2,000 – 5,000
mg/kg
Overall productInhalation-
Dust/Mist(4
hr)
No data available; calculated ATE >12.5 mg/lOverall productIngestionNo data available; calculated ATE >5,000 mg/kgBenzoyl PeroxideDermalLD50 estimated to be 2,000 – 5,000 mg/kgBenzoyl PeroxideInhalation-
Dust/Mist
(4 hours)
RatLC50 > 24.3 mg/lBenzoyl PeroxideIngestionRatLD50 > 5,000 mg/kgBenzoic Acid, C9-11-Branched Alkyl EstersDermalRabbitLD50 > 2,000 mg/kgBenzoic Acid, C9-11-Branched Alkyl EstersInhalation-
Dust/Mist
(4 hours)
RatLC50 > 5 mg/lBenzoic Acid, C9-11-Branched Alkyl EstersIngestionRatLD50 > 5,000 mg/kgCalcium SulfateDermalProfessio
nal
judgeme
nt
LD50 estimated to be > 5,000 mg/kgCalcium SulfateIngestionRatLD50 > 5,000 mg/kgZinc StearateDermalRabbitLD50 > 2,000 mg/kgZinc StearateInhalation-
Dust/Mist
(4 hours)
RatLC50 > 50 mg/lZinc StearateIngestionRatLD50 > 5,000 mg/kgEthylene GlycolIngestionHumanLD50 1,600 mg/kgEthylene GlycolInhalation-
Dust/Mist
(4 hours)
OtherLC50 estimated to be 5 – 12.5 mg/lEthylene GlycolDermalRabbit 9,530 mg/kgIron Oxide (FE2O3)DermalNot
available
LD50 3,100 mg/kgIron Oxide (FE2O3)IngestionNot
available
LD50 3,700 mg/kgOxirane, Polymer with Methyloxirane, Monobutyl EtherDermalRabbitLD50 > 16,960 mg/kgOxirane, Polymer with Methyloxirane, Monobutyl EtherInhalation-
Dust/Mist
(4 hours)
RatLC50 > 5 mg/lOxirane, Polymer with Methyloxirane, Monobutyl EtherIngestionRatLD50 4,240 mg/kgFerric Ammonium FerrocyanideDermalLD50 estimated to be > 5,000 mg/kgFerric FerrocyanideDermalLD50 estimated to be > 5,000 mg/kgFerric Ammonium FerrocyanideIngestionRatLD50 > 5,110 mg/kgFerric FerrocyanideIngestionRatLD50 > 8,000 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
NameSpeciesValueBenzoyl PeroxideRabbitMinimal irritationZinc StearateRabbitNo significant irritationEthylene GlycolRabbitMinimal irritationIron Oxide (FE2O3)RabbitNo significant irritationOxirane, Polymer with Methyloxirane, Monobutyl EtherRabbitMinimal irritation
Serious Eye Damage/Irritation
NameSpeciesValueBenzoyl PeroxideRabbitSevere irritantZinc StearateRabbitNo significant irritationEthylene GlycolRabbitMild irritantIron Oxide (FE2O3)RabbitNo significant irritationOxirane, Polymer with Methyloxirane, Monobutyl EtherRabbitNo significant irritation
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Skin Sensitization
NameSpeciesValueBenzoyl PeroxideGuinea
pig
SensitizingEthylene GlycolHumanNot classifiedIron Oxide (FE2O3)HumanNot classified
Respiratory Sensitization
For the component/components, either no data are currently available or the data are not sufficient for classification.
Germ Cell Mutagenicity
NameRouteValueBenzoyl PeroxideIn VitroNot mutagenicBenzoyl PeroxideIn vivoNot mutagenicEthylene GlycolIn VitroNot mutagenicEthylene GlycolIn vivoNot mutagenicIron Oxide (FE2O3)In VitroNot mutagenic
Carcinogenicity
NameRouteSpeciesValueBenzoyl PeroxideIngestionMultiple
animal
species
Not carcinogenicBenzoyl PeroxideDermalMouseSome positive data exist, but the data are not
sufficient for classification
Ethylene GlycolIngestionMultiple
animal
species
Not carcinogenicIron Oxide (FE2O3)InhalationHumanSome positive data exist, but the data are not
sufficient for classification
Oxirane, Polymer with Methyloxirane, Monobutyl EtherIngestionRatNot carcinogenic
Reproductive Toxicity
Reproductive and/or Developmental Effects
NameRouteValueSpeciesTest Result Exposure
Duration
Benzoyl PeroxideIngestionNot classified for female reproductionRatNOAEL 1,000
mg/kg/day
premating &
during
gestation
Benzoyl PeroxideIngestionNot classified for male reproductionRatNOAEL 500
mg/kg/day
premating &
during
gestation
Benzoyl PeroxideIngestionNot classified for developmentRatNOAEL 500
mg/kg/day
premating &
during
gestation
Ethylene GlycolDermalNot classified for developmentMouseNOAEL 3,549
mg/kg/day
during
organogenesi
s
Ethylene GlycolIngestionNot classified for developmentMouseLOAEL 750
mg/kg/day
during
organogenesi
s
Ethylene GlycolInhalationNot classified for developmentMouseNOAEL 1,000
mg/kg/day
during
organogenesi
s
Oxirane, Polymer with Methyloxirane,
Monobutyl Ether
InhalationNot classified for male reproductionRatNOAEL 1
mg/l
2 weeks
Target Organ(s)
Specific Target Organ Toxicity – single exposure
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NameRouteTarget Organ(s)ValueSpeciesTest Result Exposure
Duration
Ethylene GlycolIngestionheart | nervous
system | kidney
and/or bladder |
respiratory system
Causes damage to organsHumanNOAEL Not
available
poisoning
and/or abuse
Ethylene GlycolIngestioncentral nervous
system depression
May cause drowsiness or
dizziness
HumanNOAEL Not
available
poisoning
and/or abuse
Ethylene GlycolIngestionliverNot classifiedHumanNOAEL Not
available
poisoning
and/or abuse
Oxirane, Polymer with
Methyloxirane, Monobutyl
Ether
Ingestionnervous systemNot classifiedRatNOAEL Not
available
Specific Target Organ Toxicity – repeated exposure
NameRouteTarget Organ(s)ValueSpeciesTest Result Exposure
Duration
Ethylene GlycolIngestionkidney and/or
bladder
Some positive data exist, but the
data are not sufficient for
classification
RatNOAEL 200
mg/kg/day
2 yearsEthylene GlycolIngestionvascular systemNot classifiedRatNOAEL 200
mg/kg/day
2 yearsEthylene GlycolIngestionheart |
hematopoietic
system | liver |
immune system |
muscles
Not classifiedRatNOAEL
1,000
mg/kg/day
2 yearsEthylene GlycolIngestionrespiratory systemNot classifiedMouseNOAEL
12,000
mg/kg/day
2 yearsEthylene GlycolIngestionskin | endocrine
system | bone, teeth,
nails, and/or hair |
nervous system |
eyes
Not classifiedMultiple
animal
species
NOAEL
1,000
mg/kg/day
2 yearsIron Oxide (FE2O3)Inhalationpulmonary fibrosis |
pneumoconiosis
Not classifiedHumanNOAEL Not
available
occupational
exposure
Oxirane, Polymer with
Methyloxirane, Monobutyl
Ether
Inhalationendocrine system |
hematopoietic
system | liver |
nervous system
Not classifiedRatNOAEL 1
mg/l
2 weeksOxirane, Polymer with
Methyloxirane, Monobutyl
Ether
Inhalationkidney and/or
bladder
Not classifiedRatNOAEL
0.005 mg/l
2 weeksOxirane, Polymer with
Methyloxirane, Monobutyl
Ether
Inhalationrespiratory systemNot classifiedRatLOAEL
0.001 mg/l
2 weeksOxirane, Polymer with
Methyloxirane, Monobutyl
Ether
InhalationheartNot classifiedRatNOAEL 0.5
mg/l
2 weeksOxirane, Polymer with
Methyloxirane, Monobutyl
Ether
Ingestionliver | kidney and/or
bladder
Some positive data exist, but the
data are not sufficient for
classification
RatNOAEL 145
mg/kg/day
90 daysOxirane, Polymer with
Methyloxirane, Monobutyl
Ether
Ingestionhematopoietic
system
Not classifiedRatNOAEL 500
mg/kg/day
2 yearsOxirane, Polymer with
Methyloxirane, Monobutyl
Ether
Ingestionheart | endocrine
system | respiratory
system
Not classifiedRatNOAEL
3,770
mg/kg/day
90 days
Aspiration Hazard
For the component/components, either no data are currently available or the data are not sufficient for classification.
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
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SECTION 12: Ecological information
Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.
SECTION 13: Disposal considerations
13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.
Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste
incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Empty
drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations
classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes
unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the
available treatment and disposal facilities.
SECTION 14: Transport Information
For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.
SECTION 15: Regulatory information
15.1. US Federal Regulations
Contact 3M for more information.
EPCRA 311/312 Hazard Classifications:
Physical HazardsOrganic peroxideHealth HazardsRespiratory or Skin SensitizationSerious eye damage or eye irritationSpecific target organ toxicity (single or repeated exposure)
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
IngredientC.A.S. No% by WtEthylene Glycol 107-21-1 Trade Secret <= 7.5Zinc Stearate (ZINC COMPOUNDS) 557-05-1 Trade Secret 1 - 10Benzoyl Peroxide 94-36-0 Trade Secret 30 - 60Ferric Ferrocyanide (CYANIDES) 14038-43-8 Trade Secret <= 1
15.2. State Regulations
Contact 3M for more information.
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15.3. Chemical Inventories
The components of this product are in compliance with the chemical notification requirements of TSCA. All required
components of this product are listed on the active portion of the TSCA Inventory.
Contact 3M for more information.
15.4. International Regulations
Contact 3M for more information.
This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: Other information
NFPA Hazard Classification
Health: 2 Flammability: 1 Instability: 0 Special Hazards: Oxidizer
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
HMIS Hazard Classification
Health: 4 Flammability: 1 Physical Hazard: 0 Personal Protection: X - See PPE section.
Hazardous Material Identification System (HMIS IV) hazard ratings are designed to inform employees of chemical hazards
in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use
and are not intended for use in emergency situations. HMIS IV ratings are to be used with a fully implemented HMIS IV
program. HMIS is a registered mark of the American Coatings Association (ACA).
Document Group:29-5993-0Version Number:6.00Issue Date:02/24/22Supercedes Date:12/07/21
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M.
3M USA SDSs are available at www.3M.com
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Page 1 of 15
Safety Data Sheet
Copyright,2023, 3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document Group:24-8206-5Version Number:11.00Issue Date:02/15/23Supercedes Date:11/09/22
SECTION 1: Identification
1.1. Product identifier
3M Platinum Plus Filler, PN 0032, 01130, 01131, 01132, 01135, 01135B, 31135, 31181, 31139, 31361
Product Identification Numbers
LB-K100-0535-1, LB-K100-0535-2, LB-K100-0535-3, LB-K100-0601-5, LB-K100-1029-4, LB-K100-1959-7, LB-K100-
0913-2, 41-0003-6573-8, 41-0003-6595-1, 41-0003-7943-2, 41-3588-1070-7, 60-4550-5270-8, 60-4550-7279-7, 70-0080-
0094-8, 70-0080-0097-1
7000125034, 4010033246
1.2. Recommended use and restrictions on use
Recommended use
Automotive, Body Repair
1.3. Supplier s details
MANUFACTURER:3MDIVISION:Automotive AftermarketADDRESS:3M Center, St. Paul, MN 55144-1000, USATelephone:1-888-3M HELPS (1-888-364-3577)
1.4. Emergency telephone number
1-800-364-3577 or (651) 737-6501 (24 hours)
SECTION 2: Hazard identification
The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200.
This information may be different from the actual product label information for labels regulated by other agencies.
2.1. Hazard classification
Flammable Liquid: Category 3.
Serious Eye Damage/Irritation: Category 2A.
Skin Corrosion/Irritation: Category 2.
Carcinogenicity: Category 1A.
Specific Target Organ Toxicity (single exposure): Category 1.
Specific Target Organ Toxicity (single exposure): Category 3.
Specific Target Organ Toxicity (repeated exposure): Category 1.
2.2. Label elements
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Signal word
Danger
Symbols
Flame | Exclamation mark | Health Hazard |
Pictograms
Hazard Statements
Flammable liquid and vapor. Causes serious eye irritation. Causes skin irritation. May cause respiratory irritation. May cause drowsiness or dizziness. May cause cancer. Causes damage to organs: liver | sensory organs | Causes damage to organs through prolonged or repeated exposure: respiratory system | sensory organs | May cause damage to organs through prolonged or repeated exposure: liver |
Precautionary Statements
General:
Keep out of reach of children.
Prevention:
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use explosion-proof electrical/ventilating/lighting equipment. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves and eye/face protection. Do not eat, drink or smoke when using this product. Wash thoroughly after handling.
Response:
IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
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Wash contaminated clothing before reuse. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention. If skin irritation occurs: Get medical advice/attention. IF exposed or concerned: Get medical advice/attention. In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to
extinguish.
Storage:
Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up.
Disposal:
Dispose of contents/container in accordance with applicable local/regional/national/international regulations.
24% of the mixture consists of ingredients of unknown acute oral toxicity.
24% of the mixture consists of ingredients of unknown acute dermal toxicity.
26% of the mixture consists of ingredients of unknown acute inhalation toxicity.
SECTION 3: Composition/information on ingredients
IngredientC.A.S. No.% by WtStyrene Monomer100-42-5 10 - 30 Trade Secret *Talc14807-96-6 7 - 30 Trade Secret *Polyester PolymerTrade Secret* 10 - 30 Trade Secret *Proprietary Polyester ResinTrade Secret* 10 - 30 Trade Secret *Inert FillerTrade Secret* 5 - 10 Trade Secret *Limestone1317-65-3 1 - 5 Trade Secret *Magnesium Carbonate546-93-0 1 - 5 Trade Secret *Titanium Dioxide13463-67-7 1 - 5 Trade Secret *Organophilic PhyllosilicateTrade Secret* 1 - 5 Trade Secret *Chlorite (Mineral)1318-59-8< 3 Trade Secret *Zinc Phosphate7779-90-0 0.5 - 2.5 Trade Secret *PolyamideTrade Secret*< 2 Trade Secret *Paraffin Wax8002-74-2 0.1 - 1 Trade Secret *Poly(oxypropylene)diamine9046-10-0 0.1 - 1 Trade Secret *Quartz Silica14808-60-7< 0.3 Trade Secret *
*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.
Skin Contact:
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get
medical attention.
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Eye Contact:
Immediately flush with large amounts of water for at least 15 minutes. Remove contact lenses if easy to do. Continue rinsing.
Immediately get medical attention.
If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
Irritating to the respiratory tract (coughing, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain). Central nervous
system depression (headache, dizziness, drowsiness, incoordination, nausea, slurred speech, giddiness, and unconsciousness). Target organ
effects. See Section 11 for additional details. Target organ effects following prolonged or repeated exposure. See Section 11 for
additional details.
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish.
5.2. Special hazards arising from the substance or mixture
Closed containers exposed to heat from fire may build pressure and explode.
Hazardous Decomposition or By-Products
Substance ConditionHydrocarbonsDuring CombustionCarbon monoxideDuring CombustionCarbon dioxideDuring Combustion
5.3. Special protective actions for fire-fighters
Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and
prevent explosive rupture. Wear full protective clothing, including helmet, self-contained, positive pressure or pressure
demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering
for exposed areas of the head.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools.
Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or
exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and
could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for
information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions
Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or
bodies of water.
6.3. Methods and material for containment and cleaning up
Contain spill. Cover spill area with a fire-extinguishing foam. Working from around the edges of the spill inward, cover
with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it
appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard.
Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for
transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and
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authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal
the container. Dispose of collected material as soon as possible in accordance with applicable
local/regional/national/international regulations.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Keep away from
heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Take precautionary measures against
static discharge. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat,
drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. Avoid
contact with oxidizing agents (eg. chlorine, chromic acid etc.) Wear low static or properly grounded shoes. Use personal
protective equipment (gloves, respirators, etc.) as required. To minimize the risk of ignition, determine applicable electrical
classifications for the process using this product and select specific local exhaust ventilation equipment to avoid flammable
vapor accumulation. Ground/bond container and receiving equipment if there is potential for static electricity accumulation
during transfer.
7.2. Conditions for safe storage including any incompatibilities
Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store away from heat. Store away from
acids. Store away from strong bases. Store away from oxidizing agents.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Occupational exposure limits
If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
IngredientC.A.S. No.AgencyLimit typeAdditional CommentsStyrene Monomer100-42-5ACGIHTWA:10 ppm;STEL:20 ppmA3: Confirmed animal
carcin., Ototoxicant
Styrene Monomer100-42-5OSHATWA:100 ppm;CEIL:200 ppmLimestone1317-65-3OSHATWA(as total dust):15
mg/m3;TWA(respirable
fraction):5 mg/m3
Titanium Dioxide13463-67-7ACGIHTWA(Respirable nanoscale
particles):0.2
mg/m3;TWA(Respirable
finescale particles):2.5 mg/m3
A3: Confirmed animal
carcin.
Titanium Dioxide13463-67-7OSHATWA(as total dust):15 mg/m3Talc14807-96-6ACGIHTWA(respirable fraction):2
mg/m3
A4: Not class. as human
carcin
Talc14807-96-6OSHATWA
concentration(respirable):0.1
mg/m3(2.4 millions of
particles/cu. ft.);TWA:20
millions of particles/cu. ft.
Quartz Silica14808-60-7ACGIHTWA(respirable
fraction):0.025 mg/m3
A2: Suspected human
carcin.
Quartz Silica14808-60-7OSHATWA Table Z-
1(respirable):0.05
mg/m3;TWA Table Z-
3(respirable):0.1 mg/m3;TWA
concentration(respirable):0.1
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mg/m3(2.4 millions of
particles/cu. ft.)
Magnesium Carbonate546-93-0OSHATWA(as total dust):15
mg/m3;TWA(respirable
fraction):5 mg/m3
Paraffin Wax8002-74-2ACGIHTWA(as fume):2 mg/m3Inert FillerTrade
Secret
Manufacturer
determined
TWA(as non-fibrous,
respirable)(8 hours):3
mg/m3;TWA(as non-fibrous,
inhalable fraction)(8 hours):10
mg/m3
Inert FillerTrade
Secret
ACGIHTWA(as fiber):0.2 fiber/ccA2: Suspected human
carcin.
Inert FillerTrade
Secret
ACGIHTWA(as fiber):1 fiber/ccA3: Confirmed animal
carcin.
Inert FillerTrade
Secret
ACGIHTWA(as fiber):1 fiber/ccA4: Not class. as human
carcin
Inert FillerTrade
Secret
ACGIHTWA(inhalable fraction):5
mg/m3
A4: Not class. as human
carcin
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Guidelines
OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.
Use explosion-proof ventilation equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Safety Glasses with side shields
Indirect Vented Goggles
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity.
Gloves made from the following material(s) are recommended: Polymer laminate
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part
of a full respiratory protection program. Based on the results of the exposure assessment, select from the following
respirator type(s) to reduce inhalation exposure:
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Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance
Physical state
Color
Liquid
Gold
Specific Physical Form: PasteOdorPungent StyreneOdor thresholdNo Data AvailablepHNo Data AvailableMelting pointNo Data AvailableBoiling Point293 FFlash Point88 F [Test Method:Closed Cup]Evaporation rate0.1 - 0.5 [Ref Std:BUOAC=1]Flammability (solid, gas)Not ApplicableFlammable Limits(LEL)0.9 % [Details:based on styrene]Flammable Limits(UEL)6.8 % [Details:based on styrene]Vapor Pressure4.5 mmHgVapor Density3.6 [Ref Std:AIR=1]Density0.984 g/mlSpecific Gravity0.984 [Ref Std:WATER=1]Solubility in WaterNegligibleSolubility- non-waterNo Data AvailablePartition coefficient: n-octanol/ waterNo Data AvailableAutoignition temperatureNo Data AvailableDecomposition temperatureNo Data AvailableViscosity144,000 centipoise - 168,000 centipoiseHazardous Air Pollutants0.617 lb HAPS/lb solids [Test Method:Calculated]Volatile Organic Compounds23.7 % weight [Test Method: calculated per CARB title 2]Volatile Organic Compounds233 g/l [Test Method:calculated SCAQMD rule 443.1]Percent volatile24.1 % weightPercent volatile26.2 % volumeVOC Less H2O & Exempt Solvents234 g/l [Test Method:calculated SCAQMD rule 443.1]Solids Content38.2 % weight
SECTION 10: Stability and reactivity
10.1. Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section.
10.2. Chemical stability
Stable. Stable under normal conditions. May become unstable at elevated temperatures and/or pressure.
10.3. Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4. Conditions to avoid
Sparks and/or flames
Heat
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10.5. Incompatible materials
Strong acids
Strong oxidizing agents
Alkali and alkaline earth metals
Strong bases
10.6. Hazardous decomposition products
SubstanceCondition None known.
Refer to section 5.2 for hazardous decomposition products during combustion.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1. Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation:
May be harmful if inhaled.
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and
nose and throat pain.
May cause additional health effects (see below).
Skin Contact:
Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain.
Eye Contact:
Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the
cornea, and impaired vision.
Ingestion:
May be harmful if swallowed.
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
May cause additional health effects (see below).
Additional Health Effects:
Single exposure may cause target organ effects:
Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears.
Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and
jaundice.
Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination,
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nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness.
Prolonged or repeated exposure may cause target organ effects:
Pneumoconiosis: Sign/symptoms may include persistent cough, breathlessness, chest pain, increased amounts of sputum,
and changes in lung function tests.
Ocular Effects: Signs/symptoms may include blurred or significantly impaired vision.
Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears.
Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and
jaundice.
Carcinogenicity:
Contains a chemical or chemicals which can cause cancer.
IngredientCAS No.Class DescriptionRegulationSilica, Crystalline (Respirable Size)14808-60-7Known To Be Human Carcinogen.National Toxicology Program CarcinogensInert FillerTrade SecretGrp. 2B: Possible human carc.International Agency for Research on CancerInert FillerTrade SecretAnticipated human carcinogenNational Toxicology Program CarcinogensSilica dust, crystalline, in the form of quartz
or cristobalite
14808-60-7Grp. 1: Carcinogenic to humansInternational Agency for Research on CancerStyrene100-42-5Grp. 2A: Probable human carc.International Agency for Research on CancerStyrene100-42-5Anticipated human carcinogenNational Toxicology Program CarcinogensTitanium dioxide13463-67-7Grp. 2B: Possible human carc.International Agency for Research on Cancer
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
NameRouteSpeciesValueOverall productDermalNo data available; calculated ATE >5,000 mg/kgOverall productInhalation-
Vapor(4 hr)
No data available; calculated ATE >20 – =50 mg/lOverall productIngestionNo data available; calculated ATE >2,000 – =5,000
mg/kg
Styrene MonomerDermalRatLD50 > 2,000 mg/kgStyrene MonomerInhalation-
Vapor (4
hours)
RatLC50 11.8 mg/lStyrene MonomerIngestionRatLD50 5,000 mg/kgTalcDermalLD50 estimated to be > 5,000 mg/kgTalcIngestionLD50 estimated to be > 5,000 mg/kgPolyester PolymerDermalLD50 estimated to be > 5,000 mg/kgPolyester PolymerIngestionLD50 estimated to be 2,000 – 5,000 mg/kgInert FillerDermalLD50 estimated to be > 5,000 mg/kgInert FillerIngestionLD50 estimated to be 2,000 – 5,000 mg/kgLimestoneDermalRatLD50 > 2,000 mg/kgLimestoneInhalation-
Dust/Mist
(4 hours)
RatLC50 3 mg/lLimestoneIngestionRatLD50 6,450 mg/kgMagnesium CarbonateDermalProfessio
nal
judgeme
nt
LD50 estimated to be 2,000 – 5,000 mg/kgMagnesium CarbonateIngestionRatLD50 > 2,000 mg/kgChlorite (Mineral)DermalLD50 estimated to be > 5,000 mg/kg
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Chlorite (Mineral)IngestionLD50 estimated to be > 5,000 mg/kgTitanium DioxideDermalRabbitLD50 > 10,000 mg/kgTitanium DioxideInhalation-
Dust/Mist
(4 hours)
RatLC50 > 6.82 mg/lTitanium DioxideIngestionRatLD50 > 10,000 mg/kgZinc PhosphateDermalLD50 estimated to be > 5,000 mg/kgZinc PhosphateIngestionRatLD50 > 5,000 mg/kgPolyamideDermalLD50 estimated to be > 5,000 mg/kgPolyamideIngestionLD50 estimated to be 2,000 – 5,000 mg/kgPoly(oxypropylene)diamineDermalRabbitLD50 2,090 mg/kgParaffin WaxDermalRatLD50 > 5,000 mg/kgParaffin WaxIngestionRatLD50 > 5,000 mg/kgPoly(oxypropylene)diamineIngestionRatLD50 475 mg/kgQuartz SilicaDermalLD50 estimated to be > 5,000 mg/kgQuartz SilicaIngestionLD50 estimated to be > 5,000 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
NameSpeciesValueStyrene MonomerProfessio
nal
judgeme
nt
Mild irritantTalcRabbitNo significant irritationInert FillerProfessio
nal
judgeme
nt
No significant irritationLimestoneRabbitNo significant irritationMagnesium CarbonateIn vitro
data
No significant irritationChlorite (Mineral)Professio
nal
judgeme
nt
No significant irritationTitanium DioxideRabbitNo significant irritationParaffin WaxRabbitNo significant irritationPoly(oxypropylene)diamineRabbitCorrosiveQuartz SilicaProfessio
nal
judgeme
nt
No significant irritation
Serious Eye Damage/Irritation
NameSpeciesValueStyrene MonomerProfessio
nal
judgeme
nt
Moderate irritantTalcRabbitNo significant irritationInert FillerProfessio
nal
judgeme
nt
No significant irritationLimestoneRabbitNo significant irritationMagnesium CarbonateRabbitMild irritantChlorite (Mineral)Professio
nal
judgeme
nt
No significant irritation
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Titanium DioxideRabbitNo significant irritationParaffin WaxRabbitNo significant irritationPoly(oxypropylene)diamineRabbitCorrosive
Skin Sensitization
NameSpeciesValueStyrene MonomerGuinea
pig
Not classifiedTitanium DioxideHuman
and
animal
Not classifiedParaffin WaxGuinea
pig
Not classified
Respiratory Sensitization
NameSpeciesValueTalcHumanNot classified
Germ Cell Mutagenicity
NameRouteValueStyrene MonomerIn VitroSome positive data exist, but the data are not
sufficient for classification
Styrene MonomerIn vivoSome positive data exist, but the data are not
sufficient for classification
TalcIn VitroNot mutagenicTalcIn vivoNot mutagenicInert FillerIn VitroSome positive data exist, but the data are not
sufficient for classification
Titanium DioxideIn VitroNot mutagenicTitanium DioxideIn vivoNot mutagenicParaffin WaxIn VitroNot mutagenicPoly(oxypropylene)diamineIn VitroNot mutagenicPoly(oxypropylene)diamineIn vivoNot mutagenicQuartz SilicaIn VitroSome positive data exist, but the data are not
sufficient for classification
Quartz SilicaIn vivoSome positive data exist, but the data are not
sufficient for classification
Carcinogenicity
NameRouteSpeciesValueStyrene MonomerIngestionMouseCarcinogenicStyrene MonomerInhalationHuman
and
animal
CarcinogenicTalcInhalationRatSome positive data exist, but the data are not
sufficient for classification
Inert FillerInhalationMultiple
animal
species
Some positive data exist, but the data are not
sufficient for classification
Titanium DioxideIngestionMultiple
animal
species
Not carcinogenicTitanium DioxideInhalationRatCarcinogenicParaffin WaxIngestionRatNot carcinogenicQuartz SilicaInhalationHuman
and
animal
Carcinogenic
Reproductive Toxicity
Reproductive and/or Developmental Effects
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NameRouteValueSpeciesTest Result Exposure
Duration
Styrene MonomerIngestionNot classified for female reproductionRatNOAEL 21
mg/kg/day
3 generationStyrene MonomerInhalationNot classified for female reproductionRatNOAEL 2.1
mg/l
2 generationStyrene MonomerInhalationNot classified for male reproductionRatNOAEL 2.1
mg/l
2 generationStyrene MonomerIngestionNot classified for male reproductionRatNOAEL 400
mg/kg/day
60 daysStyrene MonomerIngestionNot classified for developmentRatNOAEL 400
mg/kg/day
during
gestation
Styrene MonomerInhalationNot classified for developmentMultiple
animal
species
NOAEL 2.1
mg/l
during
gestation
TalcIngestionNot classified for developmentRatNOAEL 1,600
mg/kg
during
organogenesi
s
LimestoneIngestionNot classified for developmentRatNOAEL 625
mg/kg/day
premating &
during
gestation
Target Organ(s)
Specific Target Organ Toxicity – single exposure
NameRouteTarget Organ(s)ValueSpeciesTest Result Exposure
Duration
Styrene MonomerInhalationauditory systemCauses damage to organsMultiple
animal
species
LOAEL 4.3
mg/l
not availableStyrene MonomerInhalationliverCauses damage to organsMouseLOAEL 2.1
mg/l
not availableStyrene MonomerInhalationcentral nervous
system depression
May cause drowsiness or
dizziness
HumanNOAEL Not
available
occupational
exposure
Styrene MonomerInhalationrespiratory irritationMay cause respiratory irritationHuman
and
animal
NOAEL Not
available
Styrene MonomerInhalationendocrine systemNot classifiedRatNOAEL Not
available
not availableStyrene MonomerInhalationkidney and/or
bladder
Not classifiedMultiple
animal
species
NOAEL 2.1
mg/l
not availableLimestoneInhalationrespiratory systemNot classifiedRatNOAEL
0.812 mg/l
90 minutesPoly(oxypropylene)diamin
e
Inhalationrespiratory irritationSome positive data exist, but the
data are not sufficient for
classification
similar
health
hazards
NOAEL Not
available
Specific Target Organ Toxicity – repeated exposure
NameRouteTarget Organ(s)ValueSpeciesTest Result Exposure
Duration
Styrene MonomerInhalationauditory systemCauses damage to organs through
prolonged or repeated exposure
HumanNOAEL not
available
occupational
exposure
Styrene MonomerInhalationeyesCauses damage to organs through
prolonged or repeated exposure
HumanNOAEL Not
available
occupational
exposure
Styrene MonomerInhalationliverMay cause damage to organs
though prolonged or repeated
exposure
MouseLOAEL 0.85
mg/l
13 weeksStyrene MonomerInhalationnervous systemSome positive data exist, but the
data are not sufficient for
classification
Multiple
animal
species
LOAEL 1.1
mg/l
not availableStyrene MonomerInhalationhematopoietic
system
Not classifiedRatNOAEL 0.85
mg/l
7 daysStyrene MonomerInhalationendocrine systemNot classifiedRatNOAEL 0.6
mg/l
10 days
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Styrene MonomerInhalationrespiratory systemNot classifiedMultiple
animal
species
LOAEL 0.09
mg/l
not availableStyrene MonomerInhalationheart |
gastrointestinal tract
| bone, teeth, nails,
and/or hair |
muscles | kidney
and/or bladder
Not classifiedMultiple
animal
species
NOAEL 4.3
mg/l
2 yearsStyrene MonomerIngestionnervous systemSome positive data exist, but the
data are not sufficient for
classification
RatLOAEL 500
mg/kg/day
8 weeksStyrene MonomerIngestionimmune systemSome positive data exist, but the
data are not sufficient for
classification
Multiple
animal
species
NOAEL Not
available
not availableStyrene MonomerIngestionliver | kidney and/or
bladder
Not classifiedRatNOAEL 677
mg/kg/day
6 monthsStyrene MonomerIngestionhematopoietic
system
Not classifiedDogNOAEL 600
mg/kg/day
470 daysStyrene MonomerIngestionheart | respiratory
system
Not classifiedRatNOAEL 35
mg/kg/day
105 weeksTalcInhalationpneumoconiosisCauses damage to organs through
prolonged or repeated exposure
HumanNOAEL Not
available
occupational
exposure
TalcInhalationpulmonary fibrosis |
respiratory system
Not classifiedRatNOAEL 18
mg/m3
113 weeksInert FillerInhalationrespiratory systemNot classifiedHumanNOAEL not
available
occupational
exposure
LimestoneInhalationrespiratory systemNot classifiedHumanNOAEL Not
available
occupational
exposure
Titanium DioxideInhalationrespiratory systemSome positive data exist, but the
data are not sufficient for
classification
RatLOAEL 0.01
mg/l
2 yearsTitanium DioxideInhalationpulmonary fibrosisNot classifiedHumanNOAEL Not
available
occupational
exposure
Paraffin WaxIngestionheartSome positive data exist, but the
data are not sufficient for
classification
RatNOAEL 15
mg/kg/day
90 daysParaffin WaxIngestionhematopoietic
system | liver |
immune system |
skin | endocrine
system | bone, teeth,
nails, and/or hair |
muscles | nervous
system | eyes |
kidney and/or
bladder | respiratory
system | vascular
system
Not classifiedRatNOAEL
1,500
mg/kg/day
90 daysQuartz SilicaInhalationsilicosisCauses damage to organs through
prolonged or repeated exposure
HumanNOAEL Not
available
occupational
exposure
Aspiration Hazard
NameValueStyrene MonomerAspiration hazardPoly(oxypropylene)diamineSome positive data exist, but the data are not sufficient for
classification
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
SECTION 12: Ecological information
Ecotoxicological information
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Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.
SECTION 13: Disposal considerations
13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.
Incinerate uncured product in a permitted waste incineration facility. As a disposal alternative, utilize an acceptable permitted
waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical
substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated
& disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective
regulating authorities to determine the available treatment and disposal facilities.
SECTION 14: Transport Information
For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.
SECTION 15: Regulatory information
15.1. US Federal Regulations
Contact manufacturer for more information
EPCRA 311/312 Hazard Classifications:
Physical HazardsFlammable (gases, aerosols, liquids, or solids)Health HazardsCarcinogenicitySerious eye damage or eye irritationSkin Corrosion or IrritationSpecific target organ toxicity (single or repeated exposure)
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
IngredientC.A.S. No% by WtStyrene Monomer 100-42-5 Trade Secret 10 – 30Zinc Phosphate (ZINC COMPOUNDS) 7779-90-0 Trade Secret 0.5 – 2.5
15.2. State Regulations
Contact manufacturer for more information
15.3. Chemical Inventories
The components of this product are in compliance with the chemical notification requirements of TSCA. All required
components of this product are listed on the active portion of the TSCA Inventory.
Contact manufacturer for more information
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15.4. International Regulations
Contact manufacturer for more information
This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: Other information
NFPA Hazard Classification
Health: 2 Flammability: 3 Instability: 1 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
Document Group:24-8206-5Version Number:11.00Issue Date:02/15/23Supercedes Date:11/09/22
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user’s method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user’s knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user’s method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M.
3M USA SDSs are available at www.3M.com
by | Sep 27, 2025
DURAGLAS FIBERGLASS REINFORCED FILLER
Not available.
Liquid.
(888) 345-5732
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Emergency telephone
number of the company
Section 1. Identification
:
:
:
:
Manufacturer :U.S. CHEMICAL & PLASTICS
600 Nova Dr. S.E.
Massillon, OH 44646
USA
Relevant identified uses of the substance or mixture and uses advised against
Paint or paint related material.
24030
24030Product code :
Product Information
Telephone Number
:(330) 830-6000
Regulatory Information
Telephone Number
:(216) 566-2902
Transportation Emergency
Telephone Number
:(800) 424-9300
Section 2. Hazards identification
FLAMMABLE LIQUIDS – Category 3
SKIN CORROSION/IRRITATION – Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION – Category 2A
CARCINOGENICITY – Category 1B
TOXIC TO REPRODUCTION – Category 2
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) – Category 1
ASPIRATION HAZARD – Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard pictograms :
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown acute dermal toxicity:
13.6%
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
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24030 DURAGLAS FIBERGLASS REINFORCED FILLER SHW-85-NA-GHS-US
Section 2. Hazards identification
Precautionary statements
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves, protective clothing and eye or face
protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking. Use explosion-proof electrical, ventilating or lighting equipment.
Use non-sparking tools. Take action to prevent static discharges. Keep container
tightly closed. Do not breathe vapor. Do not eat, drink or smoke when using this
product. Wash thoroughly after handling.
Response :IF exposed or concerned: Get medical advice or attention. IF SWALLOWED:
Immediately call a POISON CENTER or doctor. Do NOT induce vomiting. IF ON SKIN
(or hair): Take off immediately all contaminated clothing. Rinse skin with water. IF ON
SKIN: Wash with plenty of water. If skin irritation occurs: Get medical advice or
attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical
advice or attention.
Storage :Store locked up. Store in a well-ventilated place. Keep cool.
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise
classified
:DANGER: Rags, steel wool, other waste soaked with this product, and sanding residue
may spontaneously catch fire if improperly discarded. Immediately place rags, steel
wool, other waste soaked with this product, and sanding residue in a sealed, water-filled,
metal container. Dispose of in accordance with local fire regulations.
Flammable liquid and vapor.
May be fatal if swallowed and enters airways.
Causes skin irritation.
Causes serious eye irritation.
May cause cancer.
Suspected of damaging fertility or the unborn child.
Causes damage to organs through prolonged or repeated exposure. (hearing organs,
lungs)
:Hazard statements
Please refer to the SDS for additional information. Keep out of reach of children. Do not
transfer contents to other containers for storage.
Supplemental label
elements
DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which
can cause permanent brain and nervous system damage. Intentional misuse by
deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING:
This product contains chemicals known to the State of California to cause cancer and
birth defects or other reproductive harm. FOR PROFESSIONAL USE ONLY. This
product must be mixed with other components before use. Before opening the
packages, READ AND FOLLOW WARNING LABELS ON ALL COMPONENTS.
:
Section 3. Composition/information on ingredients
Talc 25 – 50 14807-96-6
Styrene 13 100-42-5
Magnesium Carbonate 10 – 25 546-93-0
Wollastonite 10 13983-17-0
Calcium Carbonate 10 471-34-1
Ingredient name CAS number% by weight
Other means of
identification
:Not available.
Substance/mixture
CAS number/other identifiers
:Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
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24030 DURAGLAS FIBERGLASS REINFORCED FILLER SHW-85-NA-GHS-US
Section 3. Composition/information on ingredients
Occupational exposure limits, if available, are listed in Section 8.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified and hence require reporting in this section.
Get medical attention immediately. Call a poison center or physician. Wash out mouth
with water. Remove dentures if any. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Stop if the exposed person
feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter
lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Never give anything by mouth to an
unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Wash contaminated clothing thoroughly with water before removing it, or wear
gloves. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place
in recovery position and get medical attention immediately. Maintain an open airway.
Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Inhalation :No known significant effects or critical hazards.
May be fatal if swallowed and enters airways.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Inhalation Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
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24030 DURAGLAS FIBERGLASS REINFORCED FILLER SHW-85-NA-GHS-US
Section 4. First aid measures
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Ingestion Adverse symptoms may include the following:
nausea or vomiting
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides
Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a
fire or if heated, a pressure increase will occur and the container may burst, with the risk
of a subsequent explosion. The vapor/gas is heavier than air and will spread along the
ground. Vapors may accumulate in low or confined areas or travel a considerable
distance to a source of ignition and flash back.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use dry chemical, CO , water spray (fog) or foam.
Extinguishing media
:
:
:
Flammable liquid.Remark :
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
For non-emergency
personnel
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Section 6. Accidental release measures
Environmental precautions
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
:Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in “For non-
emergency personnel”.
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Store in accordance with local regulations. Store in a segregated and approved area.
Store in original container protected from direct sunlight in a dry, cool and well-ventilated
area, away from incompatible materials (see Section 10) and food and drink. Store
locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental
contamination. See Section 10 for incompatible materials before handling or use.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure –
obtain special instructions before use. Avoid exposure during pregnancy. Do not
handle until all safety precautions have been read and understood. Do not get in eyes
or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Use only with
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do
not enter storage areas and confined spaces unless adequately ventilated. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Store and use away from heat, sparks, open flame or
any other ignition source. Use explosion-proof electrical (ventilating, lighting and
material handling) equipment. Use only non-sparking tools. Take precautionary
measures against electrostatic discharges. Empty containers retain product residue
and can be hazardous. Do not reuse container.
:
Precautions for safe handling
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Talc 14807-96-6 NIOSH REL (United States, 10/2020).
TWA: 2 mg/m 10 hours. Form: Respirable
fraction
ACGIH TLV (United States, 1/2022).
TWA: 2 mg/m 8 hours. Form: Respirable
fraction
Styrene 100-42-5 ACGIH TLV (United States, 1/2022).
Ototoxicant.
TWA: 10 ppm 8 hours.
STEL: 20 ppm 15 minutes.
OSHA PEL Z2 (United States, 2/2013).
TWA: 100 ppm 8 hours.
CEIL: 200 ppm
AMP: 600 ppm 5 minutes.
NIOSH REL (United States, 10/2020).
TWA: 50 ppm 10 hours.
TWA: 215 mg/m 10 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
Magnesium Carbonate 546-93-0 NIOSH REL (United States, 10/2020).
TWA: 5 mg/m 10 hours. Form: Respirable
fraction
TWA: 10 mg/m 10 hours. Form: Total
OSHA PEL (United States, 5/2018).
TWA: 5 mg/m 8 hours. Form: Respirable
fraction
TWA: 15 mg/m 8 hours. Form: Total dust
Wollastonite 13983-17-0 ACGIH TLV (United States, 1/2022).
TWA: 1 mg/m 8 hours. Form: Inhalable
fraction
Calcium Carbonate 471-34-1 NIOSH REL (United States, 10/2020).
[calcium carbonate]
TWA: 5 mg/m 10 hours. Form: Respirable
fraction
TWA: 10 mg/m 10 hours. Form: Total
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits (OSHA United States)
talc (none asbestiform) 14807-96-6 CA British Columbia Provincial (Canada,
3/2022).
TWA: 2 mg/m 8 hours. Form: Respirable
CA Quebec Provincial (Canada, 6/2021).
TWAEV: 2 mg/m 8 hours. Form: Respirable
dust.
CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 2 mg/m 8 hours. Form:
Respirable particulate
CA Ontario Provincial (Canada, 6/2019).
TWA: 2 mg/m 8 hours. Form: Respirable
particulate matter.
TWA: 2 f/cc 8 hours.
CA Saskatchewan Provincial (Canada,
Ingredient name Exposure limits
Occupational exposure limits (Canada)
CAS #
CAS #
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24030 DURAGLAS FIBERGLASS REINFORCED FILLER SHW-85-NA-GHS-US
Section 8. Exposure controls/personal protection
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
7/2013).
TWA: 2 mg/m 8 hours. Form: respirable
fraction
Vinyl benzene 100-42-5 CA Alberta Provincial (Canada, 6/2018).
15 min OEL: 40 ppm 15 minutes.
15 min OEL: 170 mg/m 15 minutes.
8 hrs OEL: 85 mg/m 8 hours.
8 hrs OEL: 20 ppm 8 hours.
CA British Columbia Provincial (Canada,
3/2022).
TWA: 20 ppm 8 hours.
STEL: 40 ppm 15 minutes.
CA Ontario Provincial (Canada, 6/2019).
TWA: 35 ppm 8 hours.
STEL: 100 ppm 15 minutes.
CA Quebec Provincial (Canada, 6/2021).
Absorbed through skin.
TWAEV: 50 ppm 8 hours.
TWAEV: 213 mg/m 8 hours.
STEV: 100 ppm 15 minutes.
STEV: 426 mg/m 15 minutes.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 40 ppm 15 minutes.
TWA: 20 ppm 8 hours.
Environmental exposure
controls
:
Styrene 100-42-5 NOM-010-STPS-2014 (Mexico, 4/2016).
TWA: 20 ppm 8 hours.
STEL: 40 ppm 15 minutes.
N,N-dimethylaniline 121-69-7 NOM-010-STPS-2014 (Mexico, 4/2016).
Absorbed through skin.
TWA: 5 ppm 8 hours.
STEL: 10 ppm 15 minutes.
Exposure limits
Occupational exposure limits (Mexico)
CAS #
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24030 DURAGLAS FIBERGLASS REINFORCED FILLER SHW-85-NA-GHS-US
Section 8. Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point/freezing point
Vapor pressure
Relative density
Liquid.
Not available.
1.7
3.6 [Air = 1]
Not available.Odor
pH
Not available.Color
Evaporation rate 0.49 (butyl acetate = 1)
Flash point Closed cup: 29 C (84.2 F) [Pensky-Martens Closed Cup]
Not applicable.
Not applicable.
Not available.Odor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
:145 C (293 F)
:Flammable liquid.
:Lower: 1.1%
Upper: 6.1%
Boiling point, initial boiling
point, and boiling range
Flammability
Lower and upper explosion
limit/flammability limit
Relative vapor density
The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.
0.57 kPa (4.3 mm Hg)
Solubility(ies) :
Media Result
cold water Not soluble
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Section 9. Physical and chemical properties
Auto-ignition temperature Not available.
Viscosity Kinematic (40 C (104 F)): <20.5 mm
2
/s (<20.5 cSt)
:
:
Decomposition temperature:Not available.
Heat of combustion :5.954 kJ/g
Aerosol product
Molecular weight :Not applicable.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
Styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours
LC50 Inhalation Vapor Rat 11800 mg/m 4 hours
LD50 Oral Rat 2650 mg/kg -
Magnesium Carbonate LD50 Oral Rat 8000 mg/kg -
Calcium Carbonate LD50 Oral Rat 6450 mg/kg -
Product/ingredient name Result Species Dose Exposure
Irritation/Corrosion
Talc Skin - Mild irritant Human - 72 hours 300
ug I
-
Styrene Eyes - Mild irritant Human - 50 ppm -
Eyes - Moderate irritantRabbit - 24 hours 100
mg
-
Eyes - Severe irritantRabbit - 100 mg -
Skin - Mild irritant Rabbit - 500 mg -
Skin - Moderate irritantRabbit - 100 % -
Calcium Carbonate Eyes - Severe irritantRabbit - 24 hours 750
ug
-
Skin - Moderate irritantRabbit - 24 hours 500
mg
-
Product/ingredient name Result Score Exposure Observation
Sensitization
Species
Information on toxicological effects
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Section 11. Toxicological information
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Not available.
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Styrene Category 3 - Respiratory tract
irritation
Category 3 Narcotic effects
Name Category
Name Category
Talc Category 1 inhalation lungs
Styrene Category 1 - hearing organs
Aspiration hazard
Name Result
Styrene ASPIRATION HAZARD - Category 1
Route of
exposure
Target organs
Route of
exposure
Target organs
Classification
Talc - 3 -
Styrene - 2A Reasonably anticipated to be a human carcinogen.
Wollastonite - 3 -
Product/ingredient name NTPIARCOSHA
Information on the likely
routes of exposure
Inhalation :No known significant effects or critical hazards.
May be fatal if swallowed and enters airways.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
:Not available.
Potential acute health effects
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Section 11. Toxicological information
Not available.
Causes damage to organs through prolonged or repeated exposure.General :
May cause cancer. Risk of cancer depends on duration and level of exposure.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
Suspected of damaging the unborn child.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
nausea or vomiting
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
:
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Oral 19424.58 mg/kg
Inhalation (gases) 20304.19 ppm
Inhalation (vapors) 86.49 mg/l
Route ATE value
Acute toxicity estimates
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
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Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Product/ingredient name
Styrene - 13.49 low
Toxicity
Styrene Acute EC50 78000 g/l Marine waterAlgae - Skeletonema costatum96 hours
Acute EC50 4700 g/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 52 mg/l Marine water Crustaceans - Artemia salina48 hours
Acute LC50 4020 g/l Fresh water Fish - Pimephales promelas 96 hours
Calcium Carbonate Acute LC50 >56000 ppm Fresh water Fish – Gambusia affinis – Adult96 hours
Chronic NOEC 16.5 mg/l Fresh waterFish – Rhamdia quelen 30 days
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Not available.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
Section 14. Transport information
RESIN SOLUTION RESIN SOLUTION
UN1866 UN1866
DOT
Classification
IMDG
UN number
UN proper
shipping name
TDG
Classification
UN1866
RESIN SOLUTION
Mexico
Classification
UN1866
RESIN SOLUTION
IATA
UN1866
RESIN
SOLUTION
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Section 14. Transport information
3
III
3
III
– Emergency
schedules F-E, S-
E
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
Special precautions for user
Transport in bulk according
to IMO instruments
No. No.
Not available.
:
Proper shipping name :
Not available.
:
3
III
No.
Product classified
as per the
following sections
of the
Transportation of
Dangerous Goods
Regulations:
2.18-2.19 (Class
3).
3
III
No.
–
Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability prior
to shipment, and compliance with the applicable regulations is the sole responsibility
of the person offering the product for transport. People loading and unloading
dangerous goods must be trained on all of the risks deriving from the substances
and on all actions in case of emergency situations.
3
III
No.
–
127
ERG No.
127 127
ERG No. ERG No.
Section 15. Regulatory information
SARA 313
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.
California Prop. 65
Australia inventory (AIIC): Not determined.
China inventory (IECSC): Not determined.
Japan inventory (CSCL): Not determined.
Japan inventory (ISHL): Not determined.
Korea inventory (KECI): Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
Taiwan Chemical Substances Inventory (TCSI): Not determined.
International regulations
International lists :
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24030 DURAGLAS FIBERGLASS REINFORCED FILLER SHW-85-NA-GHS-US
Section 15. Regulatory information
Thailand inventory: Not determined.
Turkey inventory: Not determined.
Vietnam inventory: Not determined.
Section 16. Other information
4/5/2023
History
Date of printing
Date of issue/Date of
revision
Version
Date of previous issue
:
:
:
:
Indicates information that has changed from previously issued version.
Key to abbreviations :
4/5/2023
11/29/2022
9.01
Hazardous Material Information System (U.S.A.)
3
3
0
*
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS
ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS
Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual.
FLAMMABLE LIQUIDS – Category 3 On basis of test data
SKIN CORROSION/IRRITATION – Category 2 Calculation method
SERIOUS EYE DAMAGE/ EYE IRRITATION – Category 2A Calculation method
CARCINOGENICITY – Category 1B Calculation method
TOXIC TO REPRODUCTION – Category 2 Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) – Category 1 Calculation method
ASPIRATION HAZARD – Category 1 Calculation method
Procedure used to derive the classification
Classification Justification
Notice to reader
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. (“Marpol” = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
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24030 DURAGLAS FIBERGLASS REINFORCED FILLER SHW-85-NA-GHS-US
Section 16. Other information
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer,
or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements
are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is
responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The
conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is
responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user
should not use the product for any purpose other than the purpose shown in the applicable section of this SDS
without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of
sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs
obtained from any other source.
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24030 DURAGLAS FIBERGLASS REINFORCED FILLER SHW-85-NA-GHS-US
by | Sep 27, 2025
DURAGLAS FIBERGLASS REINFORCED FILLER
Not available.
Liquid.
(888) 345-5732
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Emergency telephone
number of the company
Section 1. Identification
:
:
:
:
Manufacturer :U.S. CHEMICAL & PLASTICS
600 Nova Dr. S.E.
Massillon, OH 44646
USA
Relevant identified uses of the substance or mixture and uses advised against
Paint or paint related material.
24035
24035Product code :
Product Information
Telephone Number
:(330) 830-6000
Transportation Emergency
Telephone Number
:(800) 424-9300
Section 2. Hazards identification
FLAMMABLE LIQUIDS – Category 3
ACUTE TOXICITY (inhalation) – Category 4
SKIN CORROSION/IRRITATION – Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION – Category 2A
SKIN SENSITIZATION – Category 1
CARCINOGENICITY – Category 1B
TOXIC TO REPRODUCTION – Category 2
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) – Category 1
ASPIRATION HAZARD – Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard pictograms :
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 17.3%
(oral), 30.8% (dermal), 17.3% (inhalation)
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
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24035 DURAGLAS FIBERGLASS REINFORCED FILLER SHW-85-NA-GHS-US
Section 2. Hazards identification
Precautionary statements
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves, protective clothing and eye or face
protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking. Use explosion-proof electrical, ventilating or lighting equipment.
Use non-sparking tools. Take action to prevent static discharges. Keep container
tightly closed. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Do
not eat, drink or smoke when using this product. Wash thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.
Response :IF exposed or concerned: Get medical advice or attention. IF INHALED: Remove
person to fresh air and keep comfortable for breathing. Call a POISON CENTER or
doctor if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or
doctor. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all
contaminated clothing. Rinse skin with water. Wash contaminated clothing before
reuse. IF ON SKIN: Wash with plenty of water. If skin irritation or rash occurs: Get
medical advice or attention. IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye
irritation persists: Get medical advice or attention.
Storage :Store locked up. Store in a well-ventilated place. Keep cool.
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise
classified
:DANGER: Rags, steel wool, other waste soaked with this product, and sanding residue
may spontaneously catch fire if improperly discarded. Immediately place rags, steel
wool, other waste soaked with this product, and sanding residue in a sealed, water-filled,
metal container. Dispose of in accordance with local fire regulations.
Flammable liquid and vapor.
May be fatal if swallowed and enters airways.
Causes skin irritation.
May cause an allergic skin reaction.
Causes serious eye irritation.
Harmful if inhaled.
May cause cancer.
Suspected of damaging fertility or the unborn child.
Causes damage to organs through prolonged or repeated exposure. (hearing organs,
lungs)
:Hazard statements
Please refer to the SDS for additional information. Keep out of reach of children. Do not
transfer contents to other containers for storage.
Supplemental label
elements
DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which
can cause permanent brain and nervous system damage. Intentional misuse by
deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING:
This product contains chemicals known to the State of California to cause cancer and
birth defects or other reproductive harm. FOR PROFESSIONAL USE ONLY. This
product must be mixed with other components before use. Before opening the
packages, READ AND FOLLOW WARNING LABELS ON ALL COMPONENTS.
:
Section 3. Composition/information on ingredients
Other means of
identification
:Not available.
Substance/mixture
CAS number/other identifiers
:Mixture
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Section 3. Composition/information on ingredients
Talc 25 – 50 14807-96-6
Unsaturated Polyester 10 – 25 –
Styrene 10 – <20 100-42-5
Magnesium Carbonate 10 - 25 546-93-0
Wollastonite 10 13983-17-0
Calcium Carbonate 10 471-34-1
Ingredient name CAS number% by weight
Occupational exposure limits, if available, are listed in Section 8.
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified and hence require reporting in this section.
Get medical attention immediately. Call a poison center or physician. Wash out mouth
with water. Remove dentures if any. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Stop if the exposed person
feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter
lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Never give anything by mouth to an
unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Get medical attention. In the event of any
complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean
shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Inhalation :Harmful if inhaled.
May be fatal if swallowed and enters airways.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
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Section 4. First aid measures
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
nausea or vomiting
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
:
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides
Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a
fire or if heated, a pressure increase will occur and the container may burst, with the risk
of a subsequent explosion. The vapor/gas is heavier than air and will spread along the
ground. Vapors may accumulate in low or confined areas or travel a considerable
distance to a source of ignition and flash back.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use dry chemical, CO , water spray (fog) or foam.
Extinguishing media
:
:
:
Flammable liquid.Remark :
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
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Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
Section 7. Handling and storage
Advice on general
occupational hygiene
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Avoid exposure - obtain special instructions before use. Avoid
exposure during pregnancy. Do not handle until all safety precautions have been read
and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist.
Do not swallow. Use only with adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Do not enter storage areas and confined spaces unless
adequately ventilated. Keep in the original container or an approved alternative made
from a compatible material, kept tightly closed when not in use. Store and use away
from heat, sparks, open flame or any other ignition source. Use explosion-proof
electrical (ventilating, lighting and material handling) equipment. Use only non-sparking
tools. Take precautionary measures against electrostatic discharges. Empty containers
retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
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Section 7. Handling and storage
Conditions for safe storage,
including any
incompatibilities
Store in accordance with local regulations. Store in a segregated and approved area.
Store in original container protected from direct sunlight in a dry, cool and well-ventilated
area, away from incompatible materials (see Section 10) and food and drink. Store
locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental
contamination. See Section 10 for incompatible materials before handling or use.
:
Talc 14807-96-6 NIOSH REL (United States, 10/2020).
TWA: 2 mg/m 10 hours. Form: Respirable
fraction
ACGIH TLV (United States, 1/2024).
TWA: 2 mg/m 8 hours. Form: Respirable
fraction
Unsaturated Polyester None.
Styrene 100-42-5 ACGIH TLV (United States, 1/2024).
Ototoxicant.
TWA: 10 ppm 8 hours.
STEL: 20 ppm 15 minutes.
OSHA PEL Z2 (United States, 2/2013).
TWA: 100 ppm 8 hours.
CEIL: 200 ppm
AMP: 600 ppm 5 minutes.
NIOSH REL (United States, 10/2020).
TWA: 50 ppm 10 hours.
TWA: 215 mg/m 10 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
Magnesium Carbonate 546-93-0 NIOSH REL (United States, 10/2020).
TWA: 5 mg/m 10 hours. Form: Respirable
fraction
TWA: 10 mg/m 10 hours. Form: Total
OSHA PEL (United States, 5/2018).
TWA: 5 mg/m 8 hours. Form: Respirable
fraction
TWA: 15 mg/m 8 hours. Form: Total dust
Wollastonite 13983-17-0 ACGIH TLV (United States, 1/2024).
TWA: 1 mg/m 8 hours. Form: Inhalable
fraction
Calcium Carbonate 471-34-1 NIOSH REL (United States, 10/2020).
[calcium carbonate]
TWA: 5 mg/m 10 hours. Form: Respirable
fraction
TWA: 10 mg/m 10 hours. Form: Total
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits (OSHA United States)
Occupational exposure limits (Canada)
CAS #
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Section 8. Exposure controls/personal protection
talc (none asbestiform) 14807-96-6 CA British Columbia Provincial (Canada,
8/2023). Notes: the value is for particulate
matter containing no asbestos and less
than 1% crystalline silica.
TWA: 2 mg/m 8 hours. Form: Respirable
CA Alberta Provincial (Canada, 3/2023).
OEL: 2 mg/m 8 hours. Form: Respirable
particulate
CA Ontario Provincial (Canada, 6/2019).
TWA: 2 mg/m 8 hours. Form: Respirable
particulate matter.
TWA: 2 f/cc 8 hours.
CA Quebec Provincial (Canada, 2/2024).
TWAEV: 2 mg/m 8 hours. Form: respirable
aerosol fraction
CA Saskatchewan Provincial (Canada,
4/2021).
TWA: 2 mg/m 8 hours. Form: respirable
fraction
Vinyl benzene 100-42-5 CA Alberta Provincial (Canada, 3/2023).
OEL: 40 ppm 15 minutes.
OEL: 170 mg/m 15 minutes.
OEL: 85 mg/m 8 hours.
OEL: 20 ppm 8 hours.
CA British Columbia Provincial (Canada,
8/2023).
TWA: 20 ppm 8 hours.
STEL: 40 ppm 15 minutes.
CA Ontario Provincial (Canada, 6/2019).
TWA: 35 ppm 8 hours.
STEL: 100 ppm 15 minutes.
CA Quebec Provincial (Canada, 2/2024).
TWAEV: 50 ppm 8 hours.
STEV: 75 ppm 15 minutes.
CA Saskatchewan Provincial (Canada,
4/2021).
STEL: 40 ppm 15 minutes.
TWA: 20 ppm 8 hours.
Ingredient name Exposure limits
Styrene 100-42-5 NOM-010-STPS-2014 (Mexico, 4/2016).
TWA: 20 ppm 8 hours.
STEL: 40 ppm 15 minutes.
N,N-dimethylaniline 121-69-7 NOM-010-STPS-2014 (Mexico, 4/2016).
Absorbed through skin.
TWA: 5 ppm 8 hours.
STEL: 10 ppm 15 minutes.
Exposure limits
Occupational exposure limits (Mexico)
CAS #
CAS #
Biological exposure indices (United States)
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Section 8. Exposure controls/personal protection
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection :
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Environmental exposure
controls
:
Styrene ACGIH BEI (United States, 1/2024)
BEI: 150 mg/g creatinine, mandelic acid plus
phenylglyoxylic acid [in urine]. Sampling time:
end of shift.
BEI: 20 g/l, styrene [in urine]. Sampling time:
end of shift.
Ingredient name Exposure indices
Biological exposure indices (Canada)
Biological exposure indices (Mexico)
No exposure indices known.
Styrene Official Mexican STANDARD NOM-
047-SSA1-2011, Environmental Health-
Biological exposure indices for personnel
occupationally exposed to chemical
substances. (Mexico, 6/2012)
BEI: 0.2 mg/L [semi-quantitative.The
biological determinant is an indicator of
chemical exposure, but the quantitative
interpretation of the measure is ambiguous.
These biological determinants should be used
as a screening test if a quantitative test is not
possible.], styrene [in venous blood]. Sampling
time: at the end of the work shift.
BEI: 400 mg/g creatinine [non-specific.The
determinant is nonspecific, since it can be
found after exposure to other chemicals.],
mandelic Acid plus Phenylglyoxylic Acid [in
urine]. Sampling time: at the end of the work
shift.
Ingredient name Exposure indices
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Section 8. Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Respiratory protection :
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point/freezing point
Vapor pressure
Relative density
Liquid.
Not available.
1.66
3.6 [Air = 1]
Not available.Odor
pH
Green.Color
Evaporation rate 0.49 (butyl acetate = 1)
Auto-ignition temperature
Flash point
Not available.
Closed cup: 29 C (84.2 F) [Pensky-Martens Closed Cup]
Not applicable.
Not applicable.
Viscosity Kinematic (40 C (104 F)): <20.5 mm
2
/s (<20.5 cSt)
Not available.Odor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
:145 C (293 F)
:Flammable liquid.
:Lower: 1.1%
Upper: 6.1%
Decomposition temperature:Not available.
Molecular weight :Not applicable.
Boiling point, initial boiling
point, and boiling range
Flammability
Lower and upper explosion
limit/flammability limit
Relative vapor density
The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.
0.57 kPa (4.3 mm Hg)
Solubility(ies) :
Media Result
cold water Not soluble
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Section 9. Physical and chemical properties
Heat of combustion :5.88 kJ/g
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
Styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours
LC50 Inhalation Vapor Rat 11800 mg/m 4 hours
LD50 Oral Rat 2650 mg/kg -
Magnesium Carbonate LD50 Oral Rat 8000 mg/kg -
Calcium Carbonate LD50 Oral Rat 6450 mg/kg -
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Not available.
Mutagenicity
Not available.
Irritation/Corrosion
Talc Skin - Mild irritant Human - 72 hours 300
ug I
-
Styrene Eyes - Mild irritant Human - 50 ppm -
Eyes - Moderate irritantRabbit - 24 hours 100
mg
-
Eyes - Severe irritantRabbit - 100 mg -
Skin - Mild irritant Rabbit - 500 mg -
Skin - Moderate irritantRabbit - 100 % -
Calcium Carbonate Eyes - Severe irritantRabbit - 24 hours 750
ug
-
Skin - Moderate irritantRabbit - 24 hours 500
mg
-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Information on toxicological effects
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24035 DURAGLAS FIBERGLASS REINFORCED FILLER SHW-85-NA-GHS-US
Section 11. Toxicological information
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Styrene Category 3 - Respiratory tract
irritation
Name Category
Name Category
Talc Category 1 inhalation lungs
Styrene Category 1 - hearing organs
Aspiration hazard
Name Result
Styrene ASPIRATION HAZARD - Category 1
Route of
exposure
Target organs
Route of
exposure
Target organs
Classification
Talc - 3 -
Styrene - 2A Reasonably anticipated to be a human carcinogen.
Wollastonite - 3 -
Product/ingredient name NTPIARCOSHA
Information on the likely
routes of exposure
Inhalation :Harmful if inhaled.
May be fatal if swallowed and enters airways.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Inhalation Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
:Not available.
Potential acute health effects
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Section 11. Toxicological information
Not available.
Causes damage to organs through prolonged or repeated exposure. Once sensitized, a
severe allergic reaction may occur when subsequently exposed to very low levels.
General :
May cause cancer. Risk of cancer depends on duration and level of exposure.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
Suspected of damaging the unborn child.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Ingestion Adverse symptoms may include the following:
nausea or vomiting
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Oral 16248.31 mg/kg
Inhalation (gases) 16984.08 ppm
Inhalation (vapors) 72.35 mg/l
Route ATE value
Acute toxicity estimates
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
Section 12. Ecological information
Toxicity
Styrene Acute EC50 1400 g/l Fresh water Algae - Raphidocelis subcapitata72 hours
Acute EC50 720 g/l Fresh water Algae - Raphidocelis subcapitata96 hours
Acute EC50 4700 g/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 52 mg/l Marine water Crustaceans - Artemia salina 48 hours
Acute LC50 4020 g/l Fresh water Fish - Pimephales promelas 96 hours
Chronic NOEC 63 g/l Fresh water Algae - Raphidocelis subcapitata96 hours
Calcium Carbonate Acute LC50 >56000 ppm Fresh water Fish – Gambusia affinis – Adult96 hours
Chronic NOEC 16.5 mg/l Fresh waterFish – Rhamdia quelen 30 days
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Not available.
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24035 DURAGLAS FIBERGLASS REINFORCED FILLER SHW-85-NA-GHS-US
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Product/ingredient name
Styrene – 13.49 Low
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
Section 14. Transport information
RESIN SOLUTION
3
III
RESIN SOLUTION
3
III
UN1866 UN1866
– Emergency
schedules F-E, S-
E
DOT
Classification
IMDG
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
No. No.
TDG
Classification
UN1866
RESIN SOLUTION
3
III
No.
Product classified
as per the
following sections
of the
Transportation of
Dangerous Goods
Regulations:
2.18-2.19 (Class
Mexico
Classification
UN1866
RESIN SOLUTION
3
III
No.
–
IATA
UN1866
RESIN
SOLUTION
3
III
No.
–
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24035 DURAGLAS FIBERGLASS REINFORCED FILLER SHW-85-NA-GHS-US
Section 14. Transport information
Special precautions for user
Transport in bulk according
to IMO instruments
Not available.
:
Proper shipping name :
Not available.
:
3).
Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability prior
to shipment, and compliance with the applicable regulations is the sole responsibility
of the person offering the product for transport. People loading and unloading
dangerous goods must be trained on all of the risks deriving from the substances
and on all actions in case of emergency situations.
127
ERG No.
127 127
ERG No. ERG No.
Section 15. Regulatory information
All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED
and rely on information provided to us by our raw material suppliers. Our suppliers often provide an estimated value or
range less than a certain upper limit. We calculate MAXIMUM THEORETICAL VALUES using defined values, if provided,
or the upper limit reported by our supplier. Additionally, the suppliers information may include amounts present in the
product as unintentional byproducts or impurities. Variations may occur in individual batches due to adjustments made
during production. Reporting of chemicals in this section does not necessarily indicate their presence in the final
formulated product.
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.
California Prop. 65
Australia inventory (AIIC): Not determined.
China inventory (IECSC): Not determined.
Japan inventory (CSCL): Not determined.
Japan inventory (ISHL): Not determined.
Korea inventory (KECI): Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
Taiwan Chemical Substances Inventory (TCSI): Not determined.
Thailand inventory: Not determined.
International regulations
International lists :
Montreal Protocol
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Lead (as Pb) 0.000009
Styrene 13 100-42-5
Ingredient name CAS number% by weight
SARA 313
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24035 DURAGLAS FIBERGLASS REINFORCED FILLER SHW-85-NA-GHS-US
Section 15. Regulatory information
Turkey inventory: Not determined.
Vietnam inventory: Not determined.
Section 16. Other information
1/13/2025
History
Date of printing
Date of issue/Date of
revision
Version
Date of previous issue
:
:
:
:
Indicates information that has changed from previously issued version.
Key to abbreviations :
1/13/2025
12/13/2024
15
Hazardous Material Information System (U.S.A.)
3
3
0
*
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS
ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS
Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual.
FLAMMABLE LIQUIDS – Category 3 On basis of test data
ACUTE TOXICITY (inhalation) – Category 4 Calculation method
SKIN CORROSION/IRRITATION – Category 2 Calculation method
SERIOUS EYE DAMAGE/ EYE IRRITATION – Category 2A Calculation method
SKIN SENSITIZATION – Category 1 Calculation method
CARCINOGENICITY – Category 1B Calculation method
TOXIC TO REPRODUCTION – Category 2 Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) – Category 1 Calculation method
ASPIRATION HAZARD – Category 1 Calculation method
Procedure used to derive the classification
Classification Justification
Notice to reader
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. (“Marpol” = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
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24035 DURAGLAS FIBERGLASS REINFORCED FILLER SHW-85-NA-GHS-US
Section 16. Other information
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer,
or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements
are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is
responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The
conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is
responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user
should not use the product for any purpose other than the purpose shown in the applicable section of this SDS
without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of
sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs
obtained from any other source.
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24035 DURAGLAS FIBERGLASS REINFORCED FILLER SHW-85-NA-GHS-US
by | Sep 27, 2025
FEATHER-RITE QUALITY LIGHTWEIGHT AUTOBODY FILLER
Not available.
Liquid.
(888) 345-5732
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Emergency telephone
number of the company
Section 1. Identification
:
:
:
:
Manufacturer :U.S. CHEMICAL & PLASTICS
600 Nova Dr. S.E.
Massillon, OH 44646
USA
Relevant identified uses of the substance or mixture and uses advised against
Paint or paint related material.
21335
21335Product code :
Product Information
Telephone Number
:(330) 830-6000
Transportation Emergency
Telephone Number
:(800) 424-9300
Section 2. Hazards identification
FLAMMABLE LIQUIDS – Category 3
ACUTE TOXICITY (inhalation) – Category 4
SKIN CORROSION/IRRITATION – Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION – Category 2A
SKIN SENSITIZATION – Category 1
CARCINOGENICITY – Category 1B
TOXIC TO REPRODUCTION – Category 2
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) – Category 1
ASPIRATION HAZARD – Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard pictograms :
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 31.5%
(oral), 48.2% (dermal), 31.5% (inhalation)
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Date of issue/Date of revision :1/13/2025Date of previous issue :12/14/2024 Version:14 1/17
21335 FEATHER-RITE QUALITY LIGHTWEIGHT AUTOBODY
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SHW-85-NA-GHS-US
Section 2. Hazards identification
Precautionary statements
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves, protective clothing and eye or face
protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking. Use explosion-proof electrical, ventilating or lighting equipment.
Use non-sparking tools. Take action to prevent static discharges. Keep container
tightly closed. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Do
not eat, drink or smoke when using this product. Wash thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.
Response :IF exposed or concerned: Get medical advice or attention. IF INHALED: Remove
person to fresh air and keep comfortable for breathing. Call a POISON CENTER or
doctor if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or
doctor. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all
contaminated clothing. Rinse skin with water. Wash contaminated clothing before
reuse. IF ON SKIN: Wash with plenty of water. If skin irritation or rash occurs: Get
medical advice or attention. IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye
irritation persists: Get medical advice or attention.
Storage :Store locked up. Store in a well-ventilated place. Keep cool.
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise
classified
:None known.
Flammable liquid and vapor.
May be fatal if swallowed and enters airways.
Causes skin irritation.
May cause an allergic skin reaction.
Causes serious eye irritation.
Harmful if inhaled.
May cause cancer.
Suspected of damaging fertility or the unborn child.
Causes damage to organs through prolonged or repeated exposure. (hearing organs,
lungs)
:Hazard statements
Please refer to the SDS for additional information. Keep out of reach of children. Do not
transfer contents to other containers for storage.
Supplemental label
elements
DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which
can cause permanent brain and nervous system damage. Intentional misuse by
deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING:
This product contains chemicals known to the State of California to cause cancer and
birth defects or other reproductive harm. FOR PROFESSIONAL USE ONLY. This
product must be mixed with other components before use. Before opening the
packages, READ AND FOLLOW WARNING LABELS ON ALL COMPONENTS.
:
Section 3. Composition/information on ingredients
Other means of
identification
:Not available.
Substance/mixture
CAS number/other identifiers
:Mixture
Date of issue/Date of revision :1/13/2025Date of previous issue :12/14/2024 Version:14 2/17
21335 FEATHER-RITE QUALITY LIGHTWEIGHT AUTOBODY
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Section 3. Composition/information on ingredients
Calcium Carbonate 25 – 50 471-34-1
Unsaturated Polyester 25 – 50 –
Styrene 10 – <20 100-42-5
Talc 10 14807-96-6
Silica gel, pptd., cryst.-free 3 112926-00-8
Titanium Dioxide 0.3 13463-67-7
Ingredient name CAS number% by weight
Occupational exposure limits, if available, are listed in Section 8.
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified and hence require reporting in this section.
Get medical attention immediately. Call a poison center or physician. Wash out mouth
with water. Remove dentures if any. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Stop if the exposed person
feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter
lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Never give anything by mouth to an
unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Get medical attention. In the event of any
complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean
shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Inhalation :Harmful if inhaled.
May be fatal if swallowed and enters airways.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
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21335 FEATHER-RITE QUALITY LIGHTWEIGHT AUTOBODY
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Section 4. First aid measures
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
nausea or vomiting
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
:
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides
Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a
fire or if heated, a pressure increase will occur and the container may burst, with the risk
of a subsequent explosion. The vapor/gas is heavier than air and will spread along the
ground. Vapors may accumulate in low or confined areas or travel a considerable
distance to a source of ignition and flash back.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use dry chemical, CO , water spray (fog) or foam.
Extinguishing media
:
:
:
Flammable liquid.Remark :
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
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21335 FEATHER-RITE QUALITY LIGHTWEIGHT AUTOBODY
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Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
Section 7. Handling and storage
Advice on general
occupational hygiene
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Avoid exposure - obtain special instructions before use. Avoid
exposure during pregnancy. Do not handle until all safety precautions have been read
and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist.
Do not swallow. Use only with adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Do not enter storage areas and confined spaces unless
adequately ventilated. Keep in the original container or an approved alternative made
from a compatible material, kept tightly closed when not in use. Store and use away
from heat, sparks, open flame or any other ignition source. Use explosion-proof
electrical (ventilating, lighting and material handling) equipment. Use only non-sparking
tools. Take precautionary measures against electrostatic discharges. Empty containers
retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
Date of issue/Date of revision :1/13/2025Date of previous issue :12/14/2024 Version:14 5/17
21335 FEATHER-RITE QUALITY LIGHTWEIGHT AUTOBODY
FILLER
SHW-85-NA-GHS-US
Section 7. Handling and storage
Conditions for safe storage,
including any
incompatibilities
Store in accordance with local regulations. Store in a segregated and approved area.
Store in original container protected from direct sunlight in a dry, cool and well-ventilated
area, away from incompatible materials (see Section 10) and food and drink. Store
locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental
contamination. See Section 10 for incompatible materials before handling or use.
:
Calcium Carbonate 471-34-1 NIOSH REL (United States, 10/2020).
[calcium carbonate]
TWA: 5 mg/m 10 hours. Form: Respirable
fraction
TWA: 10 mg/m 10 hours. Form: Total
Unsaturated Polyester None.
Styrene 100-42-5 ACGIH TLV (United States, 1/2024).
Ototoxicant.
TWA: 10 ppm 8 hours.
STEL: 20 ppm 15 minutes.
OSHA PEL Z2 (United States, 2/2013).
TWA: 100 ppm 8 hours.
CEIL: 200 ppm
AMP: 600 ppm 5 minutes.
NIOSH REL (United States, 10/2020).
TWA: 50 ppm 10 hours.
TWA: 215 mg/m 10 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
Talc 14807-96-6 NIOSH REL (United States, 10/2020).
TWA: 2 mg/m 10 hours. Form: Respirable
fraction
ACGIH TLV (United States, 1/2024).
TWA: 2 mg/m 8 hours. Form: Respirable
fraction
Silica gel, pptd., cryst.-free 112926-00-8 NIOSH REL (United States, 10/2020).
[SILICA, AMORPHOUS]
TWA: 6 mg/m 10 hours.
Titanium Dioxide 13463-67-7 OSHA PEL (United States, 5/2018).
TWA: 15 mg/m 8 hours. Form: Total dust
ACGIH TLV (United States, 1/2024).
TWA: 2.5 mg/m 8 hours. Form: respirable
fraction, finescale particles
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits (OSHA United States)
Occupational exposure limits (Canada)
CAS #
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Section 8. Exposure controls/personal protection
Vinyl benzene 100-42-5 CA Alberta Provincial (Canada, 3/2023).
OEL: 40 ppm 15 minutes.
OEL: 170 mg/m 15 minutes.
OEL: 85 mg/m 8 hours.
OEL: 20 ppm 8 hours.
CA British Columbia Provincial (Canada,
8/2023).
TWA: 20 ppm 8 hours.
STEL: 40 ppm 15 minutes.
CA Ontario Provincial (Canada, 6/2019).
TWA: 35 ppm 8 hours.
STEL: 100 ppm 15 minutes.
CA Quebec Provincial (Canada, 2/2024).
TWAEV: 50 ppm 8 hours.
STEV: 75 ppm 15 minutes.
CA Saskatchewan Provincial (Canada,
4/2021).
STEL: 40 ppm 15 minutes.
TWA: 20 ppm 8 hours.
talc (none asbestiform) 14807-96-6 CA British Columbia Provincial (Canada,
8/2023). Notes: the value is for particulate
matter containing no asbestos and less
than 1% crystalline silica.
TWA: 2 mg/m 8 hours. Form: Respirable
CA Alberta Provincial (Canada, 3/2023).
OEL: 2 mg/m 8 hours. Form: Respirable
particulate
CA Ontario Provincial (Canada, 6/2019).
TWA: 2 mg/m 8 hours. Form: Respirable
particulate matter.
TWA: 2 f/cc 8 hours.
CA Quebec Provincial (Canada, 2/2024).
TWAEV: 2 mg/m 8 hours. Form: respirable
aerosol fraction
CA Saskatchewan Provincial (Canada,
4/2021).
TWA: 2 mg/m 8 hours. Form: respirable
fraction
Ingredient name Exposure limits
Styrene 100-42-5 NOM-010-STPS-2014 (Mexico, 4/2016).
TWA: 20 ppm 8 hours.
STEL: 40 ppm 15 minutes.
N,N-dimethylaniline 121-69-7 NOM-010-STPS-2014 (Mexico, 4/2016).
Absorbed through skin.
TWA: 5 ppm 8 hours.
STEL: 10 ppm 15 minutes.
Exposure limits
Occupational exposure limits (Mexico)
CAS #
CAS #
Biological exposure indices (United States)
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Section 8. Exposure controls/personal protection
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection :
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Environmental exposure
controls
:
Styrene ACGIH BEI (United States, 1/2024)
BEI: 150 mg/g creatinine, mandelic acid plus
phenylglyoxylic acid [in urine]. Sampling time:
end of shift.
BEI: 20 g/l, styrene [in urine]. Sampling time:
end of shift.
Ingredient name Exposure indices
Biological exposure indices (Canada)
Biological exposure indices (Mexico)
No exposure indices known.
Styrene Official Mexican STANDARD NOM-
047-SSA1-2011, Environmental Health-
Biological exposure indices for personnel
occupationally exposed to chemical
substances. (Mexico, 6/2012)
BEI: 0.2 mg/L [semi-quantitative.The
biological determinant is an indicator of
chemical exposure, but the quantitative
interpretation of the measure is ambiguous.
These biological determinants should be used
as a screening test if a quantitative test is not
possible.], styrene [in venous blood]. Sampling
time: at the end of the work shift.
BEI: 400 mg/g creatinine [non-specific.The
determinant is nonspecific, since it can be
found after exposure to other chemicals.],
mandelic Acid plus Phenylglyoxylic Acid [in
urine]. Sampling time: at the end of the work
shift.
Ingredient name Exposure indices
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Section 8. Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Respiratory protection :
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point/freezing point
Vapor pressure
Relative density
Liquid.
Not available.
0.98
3.6 [Air = 1]
Not available.Odor
pH
White.Color
Evaporation rate 0.49 (butyl acetate = 1)
Auto-ignition temperature
Flash point
Not available.
Closed cup: 41 C (105.8 F) [Pensky-Martens Closed Cup]
Not applicable.
Not applicable.
Viscosity Kinematic (40 C (104 F)): <20.5 mm
2
/s (<20.5 cSt)
Not available.Odor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
:145 C (293 F)
:Flammable liquid.
:Lower: 1.1%
Upper: 6.1%
Decomposition temperature:Not available.
Molecular weight :Not applicable.
Boiling point, initial boiling
point, and boiling range
Flammability
Lower and upper explosion
limit/flammability limit
Relative vapor density
The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.
0.57 kPa (4.3 mm Hg)
Solubility(ies) :
Media Result
cold water Not soluble
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Section 9. Physical and chemical properties
Heat of combustion :7.622 kJ/g
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
Calcium Carbonate LD50 Oral Rat 6450 mg/kg -
Styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours
LC50 Inhalation Vapor Rat 11800 mg/m 4 hours
LD50 Oral Rat 2650 mg/kg -
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Mutagenicity
Not available.
Irritation/Corrosion
Calcium Carbonate Eyes - Severe irritantRabbit - 24 hours 750
ug
-
Skin - Moderate irritantRabbit - 24 hours 500
mg
-
Styrene Eyes - Mild irritant Human - 50 ppm -
Eyes - Moderate irritantRabbit - 24 hours 100
mg
-
Eyes - Severe irritantRabbit - 100 mg -
Skin - Mild irritant Rabbit - 500 mg -
Skin - Moderate irritantRabbit - 100 % -
Talc Skin - Mild irritant Human - 72 hours 300
ug I
-
Titanium Dioxide Skin - Mild irritant Human - 72 hours 300
ug I
-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Information on toxicological effects
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Section 11. Toxicological information
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Styrene Category 3 - Respiratory tract
irritation
Name Category
Name Category
Styrene Category 1 - hearing organs
Talc Category 1 inhalation lungs
Aspiration hazard
Name Result
Styrene ASPIRATION HAZARD - Category 1
Route of
exposure
Target organs
Route of
exposure
Target organs
Classification
Styrene - 2A Reasonably anticipated to be a human carcinogen.
Talc - 3 -
Silica gel, pptd., cryst.-free- 3 -
Titanium Dioxide - 2B -
Product/ingredient name NTPIARCOSHA
Information on the likely
routes of exposure
Inhalation :Harmful if inhaled.
May be fatal if swallowed and enters airways.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Inhalation Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
:Not available.
Potential acute health effects
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Section 11. Toxicological information
Not available.
Causes damage to organs through prolonged or repeated exposure. Once sensitized, a
severe allergic reaction may occur when subsequently exposed to very low levels.
General :
May cause cancer. Risk of cancer depends on duration and level of exposure.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
Suspected of damaging the unborn child.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Skin contact
Ingestion Adverse symptoms may include the following:
nausea or vomiting
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Oral 10827.83 mg/kg
Inhalation (gases) 11318.14 ppm
Inhalation (vapors) 48.21 mg/l
Route ATE value
Acute toxicity estimates
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
Section 12. Ecological information
Toxicity
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Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Product/ingredient name
Styrene - 13.49 Low
Calcium Carbonate Acute LC50 >56000 ppm Fresh water Fish – Gambusia affinis – Adult96 hours
Chronic NOEC 16.5 mg/l Fresh waterFish – Rhamdia quelen 30 days
Styrene Acute EC50 1400 g/l Fresh water Algae – Raphidocelis subcapitata72 hours
Acute EC50 720 g/l Fresh water Algae – Raphidocelis subcapitata96 hours
Acute EC50 4700 g/l Fresh water Daphnia – Daphnia magna 48 hours
Acute LC50 52 mg/l Marine water Crustaceans – Artemia salina 48 hours
Acute LC50 4020 g/l Fresh water Fish – Pimephales promelas 96 hours
Chronic NOEC 63 g/l Fresh water Algae – Raphidocelis subcapitata96 hours
Titanium Dioxide Acute LC50 >1000000 g/l Marine waterFish – Fundulus heteroclitus 96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Not available.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
Section 14. Transport information
RESIN SOLUTION RESIN SOLUTION
UN1866 UN1866
DOT
Classification
IMDG
UN number
UN proper
shipping name
TDG
Classification
UN1866
RESIN SOLUTION
Mexico
Classification
UN1866
RESIN SOLUTION
IATA
UN1866
RESIN
SOLUTION
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Section 14. Transport information
3
III
3
III
This product may
be re-classified as
“Combustible
Liquid,” unless
transported by
vessel or aircraft.
Non-bulk
packages (less
than or equal to
119 gal) of
combustible
liquids are not
regulated as
hazardous
materials in
package sizes
less than the
product reportable
quantity.
Emergency
schedules F-E, S-
E
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
Special precautions for user
Transport in bulk according
to IMO instruments
No. No.
Not available.
:
Proper shipping name :
Not available.
:
3
III
No.
Product classified
as per the
following sections
of the
Transportation of
Dangerous Goods
Regulations:
2.18-2.19 (Class
3).
3
III
No.
–
Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability prior
to shipment, and compliance with the applicable regulations is the sole responsibility
of the person offering the product for transport. People loading and unloading
dangerous goods must be trained on all of the risks deriving from the substances
and on all actions in case of emergency situations.
3
III
No.
–
127
ERG No.
127 127
ERG No. ERG No.
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Section 15. Regulatory information
All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED
and rely on information provided to us by our raw material suppliers. Our suppliers often provide an estimated value or
range less than a certain upper limit. We calculate MAXIMUM THEORETICAL VALUES using defined values, if provided,
or the upper limit reported by our supplier. Additionally, the suppliers information may include amounts present in the
product as unintentional byproducts or impurities. Variations may occur in individual batches due to adjustments made
during production. Reporting of chemicals in this section does not necessarily indicate their presence in the final
formulated product.
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.
California Prop. 65
Australia inventory (AIIC): Not determined.
China inventory (IECSC): Not determined.
Japan inventory (CSCL): Not determined.
Japan inventory (ISHL): Not determined.
Korea inventory (KECI): Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
Taiwan Chemical Substances Inventory (TCSI): Not determined.
Thailand inventory: Not determined.
Turkey inventory: Not determined.
Vietnam inventory: Not determined.
International regulations
International lists :
Montreal Protocol
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Lead (as Pb) 0.0000005
Styrene 17 100-42-5
Ingredient name CAS number% by weight
SARA 313
Section 16. Other information
Hazardous Material Information System (U.S.A.)
3
3
0
*
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS
ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS
Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual.
Procedure used to derive the classification
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Section 16. Other information
1/13/2025
History
Date of printing
Date of issue/Date of
revision
Version
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer,
or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements
are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is
responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The
conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is
responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user
should not use the product for any purpose other than the purpose shown in the applicable section of this SDS
without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of
sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs
obtained from any other source.
Date of previous issue
:
:
:
:
Indicates information that has changed from previously issued version.
Key to abbreviations :
1/13/2025
12/14/2024
14
FLAMMABLE LIQUIDS – Category 3 On basis of test data
ACUTE TOXICITY (inhalation) – Category 4 Calculation method
SKIN CORROSION/IRRITATION – Category 2 Calculation method
SERIOUS EYE DAMAGE/ EYE IRRITATION – Category 2A Calculation method
SKIN SENSITIZATION – Category 1 Calculation method
CARCINOGENICITY – Category 1B Calculation method
TOXIC TO REPRODUCTION – Category 2 Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) – Category 1 Calculation method
ASPIRATION HAZARD – Category 1 Calculation method
Classification Justification
Notice to reader
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. (“Marpol” = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
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by | Sep 27, 2025
CREAM HARDENER
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Not available.
Solid.
(888) 345-5732
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Emergency telephone
number of the company
Section 1. Identification
:
:
:
:
Manufacturer :U.S. CHEMICAL & PLASTICS
600 Nova Dr. S.E.
Massillon, OH 44646
USA
Relevant identified uses of the substance or mixture and uses advised against
Paint or paint related material.
27110
27110Product code :
Product Information
Telephone Number
:(330) 830-6000
Transportation Emergency
Telephone Number
:(800) 424-9300
Section 2. Hazards identification
ORGANIC PEROXIDES – Type E
SKIN CORROSION/IRRITATION – Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION – Category 2A
SKIN SENSITIZATION – Category 1
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) – Category 2
Classification of the
substance or mixture
:
Signal word :Warning
Hazard pictograms :
Precautionary statements
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 1%
(oral), 57% (dermal), 57% (inhalation)
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Heating may cause a fire.
Causes skin irritation.
May cause an allergic skin reaction.
Causes serious eye irritation.
May cause damage to organs through prolonged or repeated exposure. (lungs)
:Hazard statements
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Section 2. Hazards identification
Prevention :Wear protective gloves, protective clothing and eye or face protection. Keep away from
heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep
away from clothing and other combustible materials. Keep only in original packaging.
Do not breathe dust. Wash thoroughly after handling. Contaminated work clothing
must not be allowed out of the workplace.
Response :Get medical advice or attention if you feel unwell. Take off contaminated clothing and
wash it before reuse. Wash contaminated clothing before reuse. IF ON SKIN: Wash
with plenty of water. If skin irritation or rash occurs: Get medical advice or attention. IF
IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or
attention.
Storage :Protect from sunlight. Store at temperatures not exceeding 25 C/77 F. Keep cool.
Store separately.
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise
classified
:None known.
Please refer to the SDS for additional information. Keep out of reach of children. Do not
transfer contents to other containers for storage.
Supplemental label
elements
WARNING: This product contains a chemical known to the State of California to cause
cancer. FOR PROFESSIONAL USE ONLY. This product must be mixed with other
components before use. Before opening the packages, READ AND FOLLOW
WARNING LABELS ON ALL COMPONENTS.
:
Section 3. Composition/information on ingredients
Dibenzoyl peroxide 50 – 75 94-36-0
Zinc Stearate 10 557-05-1
Calcium Sulfate 5 7778-18-9
Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-, hydrolysis products with silica 3 68909-20-6
Iron Oxide 3 1309-37-1
Ingredient name CAS number% by weight
Other means of
identification
:Not available.
Substance/mixture
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified and hence require reporting in this section.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Section 4. First aid measures
Eye contact :
Description of necessary first aid measures
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Section 4. First aid measures
Wash out mouth with water. Remove dentures if any. If material has been swallowed
and the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention following
exposure or if feeling unwell. Never give anything by mouth to an unconscious person.
If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Get medical attention. In the event of any
complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean
shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention following exposure or if
feeling unwell. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt
or waistband. In case of inhalation of decomposition products in a fire, symptoms may
be delayed. The exposed person may need to be kept under medical surveillance for
48 hours.
Skin contact
Inhalation
Ingestion :
:
:
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Notes to physician :In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
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Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
nitrogen oxides
sulfur oxides
metal oxide/oxides
Runoff to sewer may create fire or explosion hazard. This material increases the risk of
fire and may aid combustion. Heating may cause a fire. May re-ignite itself after fire is
extinguished. Hazardous decomposition may occur.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
:
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Move containers from spill area. Use spark-proof tools and explosion-proof equipment.
Approach release from upwind. Prevent entry into sewers, water courses, basements
or confined areas. Avoid contamination with reactive substances. Avoid dust
generation. Do not dry sweep. Vacuum dust with equipment fitted with a HEPA filter
and place in a closed, labeled waste container. Dispose of via a licensed waste
disposal contractor. Note: see Section 1 for emergency contact information and Section
13 for waste disposal.
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Provide adequate ventilation. Wear
appropriate respirator when ventilation is inadequate. Put on appropriate personal
protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Move containers from spill area. Use spark-proof tools and explosion-proof equipment.
Avoid contamination with reactive substances. Avoid dust generation. Do not dry
sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a closed,
labeled waste container. Place spilled material in a designated, labeled waste container.
Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in “For non-
emergency personnel”.
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Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
To avoid the risk of formation of shock-sensitive crystals or loss of stability, it is
important to store the product within the recommended temperature range.
Temperature control may be required. Store in accordance with local regulations. Store
in a segregated and approved area. Store in original container protected from direct
sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see
Section 10) and food and drink. Store at temperatures not exceeding 25 C/77 F.
Eliminate all ignition sources. Separate from reducing agents and combustible
materials. Keep away from rust, iron and copper. Keep container tightly closed and
sealed until ready for use. Prevent product contamination. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental
contamination. See Section 10 for incompatible materials before handling or use.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Do not get in eyes or on skin or clothing. Do not ingest. Use only
with adequate ventilation. Do not enter storage areas and confined spaces unless
adequately ventilated. Keep in the original container or an approved alternative made
from a compatible material, kept tightly closed when not in use. Store and use away
from heat, sparks, open flame or any other ignition source. Use explosion-proof
electrical (ventilating, lighting and material handling) equipment. Use only non-sparking
tools. Keep away from clothing, incompatible materials and combustible materials.
Temperature control may be required. Empty containers retain product residue and can
be hazardous. Do not reuse container.
:
Precautions for safe handling
Dibenzoyl peroxide 94-36-0 ACGIH TLV (United States, 1/2024).
TWA: 5 mg/m 8 hours.
NIOSH REL (United States, 10/2020).
TWA: 5 mg/m 10 hours.
OSHA PEL (United States, 5/2018).
TWA: 5 mg/m 8 hours.
Zinc Stearate 557-05-1 ACGIH TLV (United States, 1/2024).
[Stearates]
TWA: 10 mg/m 8 hours. Form: Inhalable
fraction
TWA: 3 mg/m 8 hours. Form: Respirable
fraction
NIOSH REL (United States, 10/2020).
TWA: 5 mg/m 10 hours. Form: Respirable
fraction
TWA: 10 mg/m 10 hours. Form: Total
OSHA PEL (United States, 5/2018).
TWA: 5 mg/m 8 hours. Form: Respirable
fraction
TWA: 15 mg/m 8 hours. Form: Total dust
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits (OSHA United States)
CAS #
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Section 8. Exposure controls/personal protection
Calcium Sulfate 7778-18-9 ACGIH TLV (United States, 1/2024).
[Calcium sulfate]
TWA: 10 mg/m 8 hours. Form: Inhalable
fraction
NIOSH REL (United States, 10/2020).
TWA: 5 mg/m 10 hours. Form: Respirable
fraction
TWA: 10 mg/m 10 hours. Form: Total
OSHA PEL (United States, 5/2018).
TWA: 5 mg/m 8 hours. Form: Respirable
fraction
TWA: 15 mg/m 8 hours. Form: Total dust
Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-,
hydrolysis products with silica
68909-20-6 None.
Iron Oxide 1309-37-1 NIOSH REL (United States, 10/2020). [iron
oxide dust and fume]
TWA: 5 mg/m , (as Fe) 10 hours. Form: Dust
and fumes
ACGIH TLV (United States, 1/2024).
TWA: 5 mg/m 8 hours. Form: Respirable
fraction
OSHA PEL (United States, 5/2018).
TWA: 5 mg/m 8 hours. Form: Respirable
fraction
TWA: 15 mg/m 8 hours. Form: Total dust
Dibenzoyl peroxide 94-36-0 CA Alberta Provincial (Canada, 3/2023).
OEL: 5 mg/m 8 hours.
CA British Columbia Provincial (Canada,
8/2023).
TWA: 5 mg/m 8 hours.
CA Ontario Provincial (Canada, 6/2019).
TWA: 5 mg/m 8 hours.
CA Quebec Provincial (Canada, 2/2024).
TWAEV: 5 mg/m 8 hours.
CA Saskatchewan Provincial (Canada,
4/2021).
STEL: 10 mg/m 15 minutes.
TWA: 5 mg/m 8 hours.
Ingredient name Exposure limits
Occupational exposure limits (Canada)
Dibenzoyl peroxide 94-36-0 NOM-010-STPS-2014 (Mexico, 4/2016).
TWA: 5 mg/m 8 hours.
Exposure limits
Occupational exposure limits (Mexico)
CAS #
CAS #
Biological exposure indices (United States)
No exposure indices known.
Biological exposure indices (Canada)
Biological exposure indices (Mexico)
No exposure indices known.
No exposure indices known.
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Section 8. Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
:
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,
local exhaust ventilation or other engineering controls to keep worker exposure to
airborne contaminants below any recommended or statutory limits. The engineering
controls also need to keep gas, vapor or dust concentrations below any lower explosive
limits. Use explosion-proof ventilation equipment. Use with adequate ventilation.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Environmental exposure
controls
:
Section 9. Physical and chemical properties
Physical state
Melting point/freezing point
Solid.
Not available.
Not available.Odor
pH
Red.Color
Flash point Closed cup: 94 C (201.2 F) [Pensky-Martens Closed Cup]
Not applicable.
Not available.Odor threshold
:
:
:
:
:
:
:
Appearance
:100 C (212 F)Boiling point, initial boiling
point, and boiling range
The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.
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Section 9. Physical and chemical properties
Vapor pressure
Relative density 1.19
1 [Air = 1]
Evaporation rate 0.09 (butyl acetate = 1)
Auto-ignition temperature Not applicable.
Not applicable.
Viscosity Kinematic (40 C (104 F)): >20.5 mm
2
/s (>20.5 cSt)
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:Not available.
:Not applicable.
SADT 50 C (122 F):
Decomposition temperature:Not available.
Heat of combustion :21.85 kJ/g
Molecular weight :Not applicable.
Flammability
Lower and upper explosion
limit/flammability limit
Relative vapor density
2.3 kPa (17.5 mm Hg)
Solubility(ies) :
Media Result
cold water Partially soluble
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Avoid increased storage
temperature.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
combustible materials
reducing materials
copper
iron
rust
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Hazardous reactions or instability may occur under certain conditions of storage or use.
Conditions may include the following:
temperature increase
high temperature
Reactions may include the following:
hazardous decomposition
risk of causing fire
Reactivity :This product, in laboratory testing, neither detonates nor deflagrates and only shows low
or no effect when heated under confinement.
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Section 11. Toxicological information
Acute toxicity
Dibenzoyl peroxide LD50 Oral Rat 6400 mg/kg –
Zinc Stearate LD50 Oral Rat >10 g/kg –
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
Dibenzoyl peroxide Eyes – Mild irritant Rabbit – 24 hours 500
mg
–
Skin – Moderate irritantWoman – 1 % –
Skin – Severe irritantHuman – 1344 hours 5
% I
–
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Not available.
Name Category
Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-, hydrolysis
products with silica
Category 2 inhalation lungs
Aspiration hazard
Not available.
Route of
exposure
Target organs
Information on toxicological effects
Classification
Dibenzoyl peroxide – 3 –
Iron Oxide – 3 –
Product/ingredient name NTPIARCOSHA
Information on the likely
routes of exposure
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
:Not available.
Potential acute health effects
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Section 11. Toxicological information
Not available.
May cause damage to organs through prolonged or repeated exposure. Once
sensitized, a severe allergic reaction may occur when subsequently exposed to very low
levels.
General :
No known significant effects or critical hazards.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Not available.
Acute toxicity estimates
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
Section 12. Ecological information
Toxicity
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Section 12. Ecological information
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Not available.
Product/ingredient name Aquatic half-life Photolysis Biodegradability
Dibenzoyl peroxide – – Inherent
Dibenzoyl peroxide EC10 0.001 mg/l Daphnia 21 days
EC50 0.0711 mg/l Algae 72 hours
Acute EC50 0.11 mg/l Daphnia 48 hours
Calcium Sulfate Acute LC50 >1910 mg/l Fresh water Crustaceans – Ceriodaphnia
dubia
48 hours
Acute LC50 >1970 mg/l Fresh water Daphnia – Daphnia magna 48 hours
Acute LC50 2980 ppm Fresh water Fish – Lepomis macrochirus 96 hours
Chronic NOEC 360 mg/l Fresh water Daphnia – Daphnia magna –
Neonate
3 weeks
Chronic NOEC 233 mg/l Fresh water Fish – Coregonus albula – Egg 60 days
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Do not cut, weld or grind used containers unless they have been cleaned thoroughly
internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways,
drains and sewers.
:Disposal methods
Section 14. Transport information
UN3108 UN3108
DOT
Classification
IMDG
UN number
TDG
Classification
UN3108
Mexico
Classification
UN3108
IATA
UN3108
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Section 14. Transport information
ORGANIC
PEROXIDE TYPE
E, SOLID
(Dibenzoyl
peroxide)
5.2
–
ORGANIC
PEROXIDE TYPE
E, SOLID
(Dibenzoyl
peroxide). Marine
pollutant
(Dibenzoyl
peroxide, Zinc
Stearate)
5.2
–
– The marine
pollutant mark is
not required when
transported in
sizes of 5 L or 5
kg.
Emergency
schedules F-J, S-
R
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
Special precautions for user
Transport in bulk according
to IMO instruments
No. Yes.
Not available.
:
Proper shipping name :
Not available.
:
ORGANIC
PEROXIDE TYPE
E, SOLID
(Dibenzoyl
peroxide)
5.2
–
No.
Product classified
as per the
following sections
of the
Transportation of
Dangerous Goods
Regulations:
2.23-2.25 (Class
5).
ORGANIC
PEROXIDE TYPE
E, SOLID
(Dibenzoyl
peroxide)
5.2
–
No.
–
Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability prior
to shipment, and compliance with the applicable regulations is the sole responsibility
of the person offering the product for transport. People loading and unloading
dangerous goods must be trained on all of the risks deriving from the substances
and on all actions in case of emergency situations.
ORGANIC
PEROXIDE
TYPE E, SOLID
(Dibenzoyl
peroxide)
5.2
–
Yes. The
environmentally
hazardous
substance mark
is not required.
The
environmentally
hazardous
substance mark
may appear if
required by other
transportation
regulations.
145
ERG No.
145 145
ERG No. ERG No.
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Section 15. Regulatory information
All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED
and rely on information provided to us by our raw material suppliers. Our suppliers often provide an estimated value or
range less than a certain upper limit. We calculate MAXIMUM THEORETICAL VALUES using defined values, if provided,
or the upper limit reported by our supplier. Additionally, the suppliers information may include amounts present in the
product as unintentional byproducts or impurities. Variations may occur in individual batches due to adjustments made
during production. Reporting of chemicals in this section does not necessarily indicate their presence in the final
formulated product.
WARNING: This product contains a chemical known to the State of California to cause cancer.
California Prop. 65
Australia inventory (AIIC): Not determined.
China inventory (IECSC): Not determined.
Japan inventory (CSCL): Not determined.
Japan inventory (ISHL): Not determined.
Korea inventory (KECI): Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
Taiwan Chemical Substances Inventory (TCSI): Not determined.
Thailand inventory: Not determined.
Turkey inventory: Not determined.
Vietnam inventory: Not determined.
International regulations
International lists :
Montreal Protocol
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Zinc Compound 6
Dibenzoyl peroxide 50 94-36-0
Ingredient name CAS number% by weight
SARA 313
Section 16. Other information
Hazardous Material Information System (U.S.A.)
2
0
4
*
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS
ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS
Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual.
Procedure used to derive the classification
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Section 16. Other information
1/15/2025
History
Date of printing
Date of issue/Date of
revision
Version
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer,
or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements
are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is
responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The
conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is
responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user
should not use the product for any purpose other than the purpose shown in the applicable section of this SDS
without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of
sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs
obtained from any other source.
Date of previous issue
:
:
:
:
Indicates information that has changed from previously issued version.
Key to abbreviations :
1/15/2025
12/13/2024
13.02
ORGANIC PEROXIDES – Type E Expert judgment
SKIN CORROSION/IRRITATION – Category 2 Calculation method
SERIOUS EYE DAMAGE/ EYE IRRITATION – Category 2A Calculation method
SKIN SENSITIZATION – Category 1 Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) – Category 2 Calculation method
Classification Justification
Notice to reader
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. (“Marpol” = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
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Liquid.
(888) 345-5732
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Emergency telephone
number of the company
Section 1. Identification
:
:
:
:
Manufacturer :U.S. CHEMICAL & PLASTICS
600 Nova Dr. S.E.
Massillon, OH 44646
USA
Relevant identified uses of the substance or mixture and uses advised against
Paint or paint related material.
21330
21330Product code :
Product Information
Telephone Number
:(330) 830-6000
Regulatory Information
Telephone Number
:(216) 566-2902
Transportation Emergency
Telephone Number
:(800) 424-9300
Section 2. Hazards identification
FLAMMABLE LIQUIDS – Category 3
ACUTE TOXICITY (inhalation) – Category 4
SKIN CORROSION/IRRITATION – Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION – Category 2A
CARCINOGENICITY – Category 1B
TOXIC TO REPRODUCTION – Category 2
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) – Category 1
ASPIRATION HAZARD – Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard pictograms :
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown acute dermal toxicity:
17%
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
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Section 2. Hazards identification
Precautionary statements
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves, protective clothing and eye or face
protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking. Use explosion-proof electrical, ventilating or lighting equipment.
Use non-sparking tools. Take action to prevent static discharges. Keep container
tightly closed. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Do
not eat, drink or smoke when using this product. Wash thoroughly after handling.
Response :IF exposed or concerned: Get medical advice or attention. IF INHALED: Remove
person to fresh air and keep comfortable for breathing. Call a POISON CENTER or
doctor if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or
doctor. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all
contaminated clothing. Rinse skin with water. IF ON SKIN: Wash with plenty of water.
If skin irritation occurs: Get medical advice or attention. IF IN EYES: Rinse cautiously
with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. If eye irritation persists: Get medical advice or attention.
Storage :Store locked up. Store in a well-ventilated place. Keep cool.
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise
classified
:None known.
Flammable liquid and vapor.
May be fatal if swallowed and enters airways.
Causes skin irritation.
Causes serious eye irritation.
Harmful if inhaled.
May cause cancer.
Suspected of damaging fertility or the unborn child.
Causes damage to organs through prolonged or repeated exposure. (hearing organs,
lungs)
:Hazard statements
Please refer to the SDS for additional information. Keep out of reach of children. Do not
transfer contents to other containers for storage.
Supplemental label
elements
DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which
can cause permanent brain and nervous system damage. Intentional misuse by
deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING:
This product contains chemicals known to the State of California to cause cancer and
birth defects or other reproductive harm. FOR PROFESSIONAL USE ONLY. This
product must be mixed with other components before use. Before opening the
packages, READ AND FOLLOW WARNING LABELS ON ALL COMPONENTS.
:
Section 3. Composition/information on ingredients
Calcium Carbonate 25 – 50 471-34-1
Styrene 10 – <20 100-42-5
Talc 10 14807-96-6
Silica gel, pptd., cryst.-free 3 112926-00-8
Titanium Dioxide 0.3 13463-67-7
Ingredient name CAS number% by weight
Other means of
identification
:Not available.
Substance/mixture
CAS number/other identifiers
:Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
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Section 3. Composition/information on ingredients
Occupational exposure limits, if available, are listed in Section 8.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified and hence require reporting in this section.
Get medical attention immediately. Call a poison center or physician. Wash out mouth
with water. Remove dentures if any. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Stop if the exposed person
feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter
lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Never give anything by mouth to an
unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Wash contaminated clothing thoroughly with water before removing it, or wear
gloves. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Inhalation :Harmful if inhaled.
May be fatal if swallowed and enters airways.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Inhalation Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
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Section 4. First aid measures
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Ingestion Adverse symptoms may include the following:
nausea or vomiting
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides
Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a
fire or if heated, a pressure increase will occur and the container may burst, with the risk
of a subsequent explosion. The vapor/gas is heavier than air and will spread along the
ground. Vapors may accumulate in low or confined areas or travel a considerable
distance to a source of ignition and flash back.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use dry chemical, CO , water spray (fog) or foam.
Extinguishing media
:
:
:
Flammable liquid.Remark :
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
For non-emergency
personnel
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Section 6. Accidental release measures
Environmental precautions
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
:Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Store in accordance with local regulations. Store in a segregated and approved area.
Store in original container protected from direct sunlight in a dry, cool and well-ventilated
area, away from incompatible materials (see Section 10) and food and drink. Store
locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental
contamination. See Section 10 for incompatible materials before handling or use.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure -
obtain special instructions before use. Avoid exposure during pregnancy. Do not
handle until all safety precautions have been read and understood. Do not get in eyes
or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Use only with
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do
not enter storage areas and confined spaces unless adequately ventilated. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Store and use away from heat, sparks, open flame or
any other ignition source. Use explosion-proof electrical (ventilating, lighting and
material handling) equipment. Use only non-sparking tools. Take precautionary
measures against electrostatic discharges. Empty containers retain product residue
and can be hazardous. Do not reuse container.
:
Precautions for safe handling
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Calcium Carbonate 471-34-1 NIOSH REL (United States, 10/2020).
[calcium carbonate]
TWA: 5 mg/m 10 hours. Form: Respirable
fraction
TWA: 10 mg/m 10 hours. Form: Total
Styrene 100-42-5 ACGIH TLV (United States, 1/2022).
Ototoxicant.
TWA: 10 ppm 8 hours.
STEL: 20 ppm 15 minutes.
OSHA PEL Z2 (United States, 2/2013).
TWA: 100 ppm 8 hours.
CEIL: 200 ppm
AMP: 600 ppm 5 minutes.
NIOSH REL (United States, 10/2020).
TWA: 50 ppm 10 hours.
TWA: 215 mg/m 10 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
Talc 14807-96-6 NIOSH REL (United States, 10/2020).
TWA: 2 mg/m 10 hours. Form: Respirable
fraction
ACGIH TLV (United States, 1/2022).
TWA: 2 mg/m 8 hours. Form: Respirable
fraction
Silica gel, pptd., cryst.-free 112926-00-8 NIOSH REL (United States, 10/2020).
[SILICA, AMORPHOUS]
TWA: 6 mg/m 10 hours.
Titanium Dioxide 13463-67-7 OSHA PEL (United States, 5/2018).
TWA: 15 mg/m 8 hours. Form: Total dust
ACGIH TLV (United States, 1/2022).
TWA: 2.5 mg/m 8 hours. Form: respirable
fraction, finescale particles
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits (OSHA United States)
Vinyl benzene 100-42-5 CA Alberta Provincial (Canada, 6/2018).
15 min OEL: 40 ppm 15 minutes.
15 min OEL: 170 mg/m 15 minutes.
8 hrs OEL: 85 mg/m 8 hours.
8 hrs OEL: 20 ppm 8 hours.
CA British Columbia Provincial (Canada,
3/2022).
TWA: 20 ppm 8 hours.
STEL: 40 ppm 15 minutes.
CA Ontario Provincial (Canada, 6/2019).
TWA: 35 ppm 8 hours.
STEL: 100 ppm 15 minutes.
CA Quebec Provincial (Canada, 6/2021).
Absorbed through skin.
TWAEV: 50 ppm 8 hours.
TWAEV: 213 mg/m 8 hours.
STEV: 100 ppm 15 minutes.
Ingredient name Exposure limits
Occupational exposure limits (Canada)
CAS #
CAS #
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Section 8. Exposure controls/personal protection
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
STEV: 426 mg/m 15 minutes.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 40 ppm 15 minutes.
TWA: 20 ppm 8 hours.
talc (none asbestiform) 14807-96-6 CA British Columbia Provincial (Canada,
3/2022).
TWA: 2 mg/m 8 hours. Form: Respirable
CA Quebec Provincial (Canada, 6/2021).
TWAEV: 2 mg/m 8 hours. Form: Respirable
dust.
CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 2 mg/m 8 hours. Form:
Respirable particulate
CA Ontario Provincial (Canada, 6/2019).
TWA: 2 mg/m 8 hours. Form: Respirable
particulate matter.
TWA: 2 f/cc 8 hours.
CA Saskatchewan Provincial (Canada,
7/2013).
TWA: 2 mg/m 8 hours. Form: respirable
fraction
Titanium dioxide 13463-67-7 CA British Columbia Provincial (Canada,
3/2022).
TWA: 10 mg/m 8 hours. Form: Total dust
TWA: 3 mg/m 8 hours. Form: respirable
fraction
CA Quebec Provincial (Canada, 6/2021).
TWAEV: 10 mg/m 8 hours. Form: Total dust.
CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 10 mg/m 8 hours.
CA Ontario Provincial (Canada, 6/2019).
TWA: 10 mg/m 8 hours.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 20 mg/m 15 minutes.
TWA: 10 mg/m 8 hours.
Styrene 100-42-5 NOM-010-STPS-2014 (Mexico, 4/2016).
TWA: 20 ppm 8 hours.
STEL: 40 ppm 15 minutes.
N,N-dimethylaniline 121-69-7 NOM-010-STPS-2014 (Mexico, 4/2016).
Absorbed through skin.
TWA: 5 ppm 8 hours.
STEL: 10 ppm 15 minutes.
Exposure limits
Occupational exposure limits (Mexico)
CAS #
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Section 8. Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Environmental exposure
controls
:
Section 9. Physical and chemical properties
Physical state
Melting point/freezing point
Liquid.
Not available.
Not available.Odor
pH
Not available.Color
Evaporation rate 0.49 (butyl acetate = 1)
Flash point Closed cup: 41 C (105.8 F) [Pensky-Martens Closed Cup]
Not applicable.
Not available.Odor threshold
:
:
:
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:
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:
:
Appearance
:145 C (293 F)
:Flammable liquid.
:Lower: 1.1%
Upper: 6.1%
Boiling point, initial boiling
point, and boiling range
Flammability
Lower and upper explosion
limit/flammability limit
The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.
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Section 9. Physical and chemical properties
Vapor pressure
Relative density 1
3.6 [Air = 1]
Auto-ignition temperature Not available.
Not applicable.
Viscosity Kinematic (40 C (104 F)): <20.5 mm
2
/s (<20.5 cSt)
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
Decomposition temperature:Not available.
Heat of combustion :7.756 kJ/g
Aerosol product
Molecular weight :Not applicable.
Relative vapor density
0.57 kPa (4.3 mm Hg)
Solubility(ies) :
Media Result
cold water Not soluble
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
Calcium Carbonate LD50 Oral Rat 6450 mg/kg -
Styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours
LC50 Inhalation Vapor Rat 11800 mg/m 4 hours
LD50 Oral Rat 2650 mg/kg -
Product/ingredient name Result Species Dose Exposure
Irritation/Corrosion
Information on toxicological effects
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Section 11. Toxicological information
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Calcium Carbonate Eyes - Severe irritantRabbit - 24 hours 750
ug
-
Skin - Moderate irritantRabbit - 24 hours 500
mg
-
Styrene Eyes - Mild irritant Human - 50 ppm -
Eyes - Moderate irritantRabbit - 24 hours 100
mg
-
Eyes - Severe irritantRabbit - 100 mg -
Skin - Mild irritant Rabbit - 500 mg -
Skin - Moderate irritantRabbit - 100 % -
Talc Skin - Mild irritant Human - 72 hours 300
ug I
-
Titanium Dioxide Skin - Mild irritant Human - 72 hours 300
ug I
-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Styrene Category 3 - Respiratory tract
irritation
Category 3 Narcotic effects
Name Category
Name Category
Styrene Category 1 - hearing organs
Talc Category 1 inhalation lungs
Aspiration hazard
Name Result
Styrene ASPIRATION HAZARD - Category 1
Route of
exposure
Target organs
Route of
exposure
Target organs
Classification
Styrene - 2A Reasonably anticipated to be a human carcinogen.
Talc - 3 -
Silica gel, pptd., cryst.-free- 3 -
Titanium Dioxide - 2B -
Product/ingredient name NTPIARCOSHA
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Section 11. Toxicological information
Not available.
Information on the likely
routes of exposure
Inhalation :Harmful if inhaled.
May be fatal if swallowed and enters airways.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
Causes damage to organs through prolonged or repeated exposure.General :
May cause cancer. Risk of cancer depends on duration and level of exposure.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
Suspected of damaging the unborn child.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
nausea or vomiting
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Acute toxicity estimates
:Not available.
Potential acute health effects
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
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Section 11. Toxicological information
Oral 15544.54 mg/kg
Inhalation (gases) 16248.44 ppm
Inhalation (vapors) 69.22 mg/l
Route ATE value
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Product/ingredient name
Styrene - 13.49 low
Toxicity
Calcium Carbonate Acute LC50 >56000 ppm Fresh water Fish – Gambusia affinis – Adult96 hours
Chronic NOEC 16.5 mg/l Fresh waterFish – Rhamdia quelen 30 days
Styrene Acute EC50 78000 g/l Marine waterAlgae – Skeletonema costatum96 hours
Acute EC50 4700 g/l Fresh water Daphnia – Daphnia magna 48 hours
Acute LC50 52 mg/l Marine water Crustaceans – Artemia salina48 hours
Acute LC50 4020 g/l Fresh water Fish – Pimephales promelas 96 hours
Titanium Dioxide Acute LC50 >1000000 g/l Marine waterFish – Fundulus heteroclitus96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Not available.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
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21330 FEATHER-RITE QUALITY LIGHTWEIGHT AUTOBODY
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Section 14. Transport information
RESIN SOLUTION
3
III
RESIN SOLUTION
3
III
UN1866 UN1866
This product may
be re-classified as
“Combustible
Liquid,” unless
transported by
vessel or aircraft.
Non-bulk
packages (less
than or equal to
119 gal) of
combustible
liquids are not
regulated as
hazardous
materials in
package sizes
less than the
product reportable
quantity.
Emergency
schedules F-E, S-
E
DOT
Classification
IMDG
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
Special precautions for user
Transport in bulk according
to IMO instruments
No. No.
Not available.
:
Proper shipping name :
Not available.
:
TDG
Classification
UN1866
RESIN SOLUTION
3
III
No.
Product classified
as per the
following sections
of the
Transportation of
Dangerous Goods
Regulations:
2.18-2.19 (Class
3).
Mexico
Classification
UN1866
RESIN SOLUTION
3
III
No.
–
Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability prior
to shipment, and compliance with the applicable regulations is the sole responsibility
of the person offering the product for transport. People loading and unloading
dangerous goods must be trained on all of the risks deriving from the substances
and on all actions in case of emergency situations.
IATA
UN1866
RESIN
SOLUTION
3
III
No.
–
127
ERG No.
127 127
ERG No. ERG No.
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21330 FEATHER-RITE QUALITY LIGHTWEIGHT AUTOBODY
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Section 15. Regulatory information
SARA 313
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.
California Prop. 65
Australia inventory (AIIC): Not determined.
China inventory (IECSC): Not determined.
Japan inventory (CSCL): Not determined.
Japan inventory (ISHL): Not determined.
Korea inventory (KECI): Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
Taiwan Chemical Substances Inventory (TCSI): Not determined.
Thailand inventory: Not determined.
Turkey inventory: Not determined.
Vietnam inventory: Not determined.
International regulations
International lists :
Section 16. Other information
11/29/2022
History
Date of printing
Date of issue/Date of
revision
Version
Date of previous issue
:
:
:
:
11/29/2022
6/20/2022
8
Hazardous Material Information System (U.S.A.)
3
2
0
*
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS
ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS
Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual.
FLAMMABLE LIQUIDS – Category 3 On basis of test data
ACUTE TOXICITY (inhalation) – Category 4 Calculation method
SKIN CORROSION/IRRITATION – Category 2 Calculation method
SERIOUS EYE DAMAGE/ EYE IRRITATION – Category 2A Calculation method
CARCINOGENICITY – Category 1B Calculation method
TOXIC TO REPRODUCTION – Category 2 Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) – Category 1 Calculation method
ASPIRATION HAZARD – Category 1 Calculation method
Procedure used to derive the classification
Classification Justification
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21330 FEATHER-RITE QUALITY LIGHTWEIGHT AUTOBODY
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Section 16. Other information
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer,
or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements
are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is
responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The
conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is
responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user
should not use the product for any purpose other than the purpose shown in the applicable section of this SDS
without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of
sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs
obtained from any other source.
Indicates information that has changed from previously issued version.
Key to abbreviations :
Notice to reader
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. (“Marpol” = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
Date of issue/Date of revision :11/29/2022Date of previous issue :6/20/2022 Version:8 15/15
21330 FEATHER-RITE QUALITY LIGHTWEIGHT AUTOBODY
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by | Sep 27, 2025
CREAM HARDENER
RED
Not available.
Solid.
(888) 345-5732
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Emergency telephone
number of the company
Section 1. Identification
:
:
:
:
Manufacturer :U.S. CHEMICAL & PLASTICS
600 Nova Dr. S.E.
Massillon, OH 44646
USA
Relevant identified uses of the substance or mixture and uses advised against
Paint or paint related material.
27120
27120Product code :
Product Information
Telephone Number
:(330) 830-6000
Transportation Emergency
Telephone Number
:(800) 424-9300
Section 2. Hazards identification
ORGANIC PEROXIDES – Type E
SKIN CORROSION/IRRITATION – Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION – Category 2A
SKIN SENSITIZATION – Category 1
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) – Category 2
Classification of the
substance or mixture
:
Signal word :Warning
Hazard pictograms :
Precautionary statements
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 1%
(oral), 57% (dermal), 57% (inhalation)
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Heating may cause a fire.
Causes skin irritation.
May cause an allergic skin reaction.
Causes serious eye irritation.
May cause damage to organs through prolonged or repeated exposure. (lungs)
:Hazard statements
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Section 2. Hazards identification
Prevention :Wear protective gloves, protective clothing and eye or face protection. Keep away from
heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep
away from clothing and other combustible materials. Keep only in original packaging.
Do not breathe dust. Wash thoroughly after handling. Contaminated work clothing
must not be allowed out of the workplace.
Response :Get medical advice or attention if you feel unwell. Take off contaminated clothing and
wash it before reuse. Wash contaminated clothing before reuse. IF ON SKIN: Wash
with plenty of water. If skin irritation or rash occurs: Get medical advice or attention. IF
IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or
attention.
Storage :Protect from sunlight. Store at temperatures not exceeding 25 C/77 F. Keep cool.
Store separately.
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise
classified
:None known.
Please refer to the SDS for additional information. Keep out of reach of children. Do not
transfer contents to other containers for storage.
Supplemental label
elements
WARNING: This product contains a chemical known to the State of California to cause
cancer. FOR PROFESSIONAL USE ONLY. This product must be mixed with other
components before use. Before opening the packages, READ AND FOLLOW
WARNING LABELS ON ALL COMPONENTS.
:
Section 3. Composition/information on ingredients
Dibenzoyl peroxide 50 – 75 94-36-0
Zinc Stearate 10 557-05-1
Calcium Sulfate 5 7778-18-9
Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-, hydrolysis products with silica 3 68909-20-6
Iron Oxide 3 1309-37-1
Ingredient name CAS number% by weight
Other means of
identification
:Not available.
Substance/mixture
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified and hence require reporting in this section.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Section 4. First aid measures
Eye contact :
Description of necessary first aid measures
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Section 4. First aid measures
Wash out mouth with water. Remove dentures if any. If material has been swallowed
and the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention following
exposure or if feeling unwell. Never give anything by mouth to an unconscious person.
If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Get medical attention. In the event of any
complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean
shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention following exposure or if
feeling unwell. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt
or waistband. In case of inhalation of decomposition products in a fire, symptoms may
be delayed. The exposed person may need to be kept under medical surveillance for
48 hours.
Skin contact
Inhalation
Ingestion :
:
:
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Notes to physician :In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
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Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
nitrogen oxides
sulfur oxides
metal oxide/oxides
Runoff to sewer may create fire or explosion hazard. This material increases the risk of
fire and may aid combustion. Heating may cause a fire. May re-ignite itself after fire is
extinguished. Hazardous decomposition may occur.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
:
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Move containers from spill area. Use spark-proof tools and explosion-proof equipment.
Approach release from upwind. Prevent entry into sewers, water courses, basements
or confined areas. Avoid contamination with reactive substances. Avoid dust
generation. Do not dry sweep. Vacuum dust with equipment fitted with a HEPA filter
and place in a closed, labeled waste container. Dispose of via a licensed waste
disposal contractor. Note: see Section 1 for emergency contact information and Section
13 for waste disposal.
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Provide adequate ventilation. Wear
appropriate respirator when ventilation is inadequate. Put on appropriate personal
protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Move containers from spill area. Use spark-proof tools and explosion-proof equipment.
Avoid contamination with reactive substances. Avoid dust generation. Do not dry
sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a closed,
labeled waste container. Place spilled material in a designated, labeled waste container.
Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in “For non-
emergency personnel”.
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Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
To avoid the risk of formation of shock-sensitive crystals or loss of stability, it is
important to store the product within the recommended temperature range.
Temperature control may be required. Store in accordance with local regulations. Store
in a segregated and approved area. Store in original container protected from direct
sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see
Section 10) and food and drink. Store at temperatures not exceeding 25 C/77 F.
Eliminate all ignition sources. Separate from reducing agents and combustible
materials. Keep away from rust, iron and copper. Keep container tightly closed and
sealed until ready for use. Prevent product contamination. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental
contamination. See Section 10 for incompatible materials before handling or use.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Do not get in eyes or on skin or clothing. Do not ingest. Use only
with adequate ventilation. Do not enter storage areas and confined spaces unless
adequately ventilated. Keep in the original container or an approved alternative made
from a compatible material, kept tightly closed when not in use. Store and use away
from heat, sparks, open flame or any other ignition source. Use explosion-proof
electrical (ventilating, lighting and material handling) equipment. Use only non-sparking
tools. Keep away from clothing, incompatible materials and combustible materials.
Temperature control may be required. Empty containers retain product residue and can
be hazardous. Do not reuse container.
:
Precautions for safe handling
Dibenzoyl peroxide 94-36-0 ACGIH TLV (United States, 1/2024).
TWA: 5 mg/m 8 hours.
NIOSH REL (United States, 10/2020).
TWA: 5 mg/m 10 hours.
OSHA PEL (United States, 5/2018).
TWA: 5 mg/m 8 hours.
Zinc Stearate 557-05-1 ACGIH TLV (United States, 1/2024).
[Stearates]
TWA: 10 mg/m 8 hours. Form: Inhalable
fraction
TWA: 3 mg/m 8 hours. Form: Respirable
fraction
NIOSH REL (United States, 10/2020).
TWA: 5 mg/m 10 hours. Form: Respirable
fraction
TWA: 10 mg/m 10 hours. Form: Total
OSHA PEL (United States, 5/2018).
TWA: 5 mg/m 8 hours. Form: Respirable
fraction
TWA: 15 mg/m 8 hours. Form: Total dust
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits (OSHA United States)
CAS #
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Section 8. Exposure controls/personal protection
Calcium Sulfate 7778-18-9 ACGIH TLV (United States, 1/2024).
[Calcium sulfate]
TWA: 10 mg/m 8 hours. Form: Inhalable
fraction
NIOSH REL (United States, 10/2020).
TWA: 5 mg/m 10 hours. Form: Respirable
fraction
TWA: 10 mg/m 10 hours. Form: Total
OSHA PEL (United States, 5/2018).
TWA: 5 mg/m 8 hours. Form: Respirable
fraction
TWA: 15 mg/m 8 hours. Form: Total dust
Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-,
hydrolysis products with silica
68909-20-6 None.
Iron Oxide 1309-37-1 NIOSH REL (United States, 10/2020). [iron
oxide dust and fume]
TWA: 5 mg/m , (as Fe) 10 hours. Form: Dust
and fumes
ACGIH TLV (United States, 1/2024).
TWA: 5 mg/m 8 hours. Form: Respirable
fraction
OSHA PEL (United States, 5/2018).
TWA: 5 mg/m 8 hours. Form: Respirable
fraction
TWA: 15 mg/m 8 hours. Form: Total dust
Dibenzoyl peroxide 94-36-0 CA Alberta Provincial (Canada, 3/2023).
OEL: 5 mg/m 8 hours.
CA British Columbia Provincial (Canada,
8/2023).
TWA: 5 mg/m 8 hours.
CA Ontario Provincial (Canada, 6/2019).
TWA: 5 mg/m 8 hours.
CA Quebec Provincial (Canada, 2/2024).
TWAEV: 5 mg/m 8 hours.
CA Saskatchewan Provincial (Canada,
4/2021).
STEL: 10 mg/m 15 minutes.
TWA: 5 mg/m 8 hours.
Ingredient name Exposure limits
Occupational exposure limits (Canada)
Dibenzoyl peroxide 94-36-0 NOM-010-STPS-2014 (Mexico, 4/2016).
TWA: 5 mg/m 8 hours.
Exposure limits
Occupational exposure limits (Mexico)
CAS #
CAS #
Biological exposure indices (United States)
No exposure indices known.
Biological exposure indices (Canada)
Biological exposure indices (Mexico)
No exposure indices known.
No exposure indices known.
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Section 8. Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
:
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,
local exhaust ventilation or other engineering controls to keep worker exposure to
airborne contaminants below any recommended or statutory limits. The engineering
controls also need to keep gas, vapor or dust concentrations below any lower explosive
limits. Use explosion-proof ventilation equipment. Use with adequate ventilation.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Environmental exposure
controls
:
Section 9. Physical and chemical properties
Physical state
Melting point/freezing point
Solid.
Not available.
Not available.Odor
pH
Red.Color
Flash point Closed cup: 94 C (201.2 F) [Pensky-Martens Closed Cup]
Not applicable.
Not available.Odor threshold
:
:
:
:
:
:
:
Appearance
:100 C (212 F)Boiling point, initial boiling
point, and boiling range
The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.
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Section 9. Physical and chemical properties
Vapor pressure
Relative density 1.19
1 [Air = 1]
Evaporation rate 0.09 (butyl acetate = 1)
Auto-ignition temperature Not applicable.
Not applicable.
Viscosity Kinematic (40 C (104 F)): >20.5 mm
2
/s (>20.5 cSt)
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:Not available.
:Not applicable.
SADT 50 C (122 F):
Decomposition temperature:Not available.
Heat of combustion :21.85 kJ/g
Molecular weight :Not applicable.
Flammability
Lower and upper explosion
limit/flammability limit
Relative vapor density
2.3 kPa (17.5 mm Hg)
Solubility(ies) :
Media Result
cold water Partially soluble
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Avoid increased storage
temperature.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
combustible materials
reducing materials
copper
iron
rust
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Hazardous reactions or instability may occur under certain conditions of storage or use.
Conditions may include the following:
temperature increase
high temperature
Reactions may include the following:
hazardous decomposition
risk of causing fire
Reactivity :This product, in laboratory testing, neither detonates nor deflagrates and only shows low
or no effect when heated under confinement.
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Section 11. Toxicological information
Acute toxicity
Dibenzoyl peroxide LD50 Oral Rat 6400 mg/kg –
Zinc Stearate LD50 Oral Rat >10 g/kg –
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
Dibenzoyl peroxide Eyes – Mild irritant Rabbit – 24 hours 500
mg
–
Skin – Moderate irritantWoman – 1 % –
Skin – Severe irritantHuman – 1344 hours 5
% I
–
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Not available.
Name Category
Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-, hydrolysis
products with silica
Category 2 inhalation lungs
Aspiration hazard
Not available.
Route of
exposure
Target organs
Information on toxicological effects
Classification
Dibenzoyl peroxide – 3 –
Iron Oxide – 3 –
Product/ingredient name NTPIARCOSHA
Information on the likely
routes of exposure
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
:Not available.
Potential acute health effects
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Section 11. Toxicological information
Not available.
May cause damage to organs through prolonged or repeated exposure. Once
sensitized, a severe allergic reaction may occur when subsequently exposed to very low
levels.
General :
No known significant effects or critical hazards.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Not available.
Acute toxicity estimates
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
Section 12. Ecological information
Toxicity
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Section 12. Ecological information
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Not available.
Product/ingredient name Aquatic half-life Photolysis Biodegradability
Dibenzoyl peroxide – – Inherent
Dibenzoyl peroxide EC10 0.001 mg/l Daphnia 21 days
EC50 0.0711 mg/l Algae 72 hours
Acute EC50 0.11 mg/l Daphnia 48 hours
Calcium Sulfate Acute LC50 >1910 mg/l Fresh water Crustaceans – Ceriodaphnia
dubia
48 hours
Acute LC50 >1970 mg/l Fresh water Daphnia – Daphnia magna 48 hours
Acute LC50 2980 ppm Fresh water Fish – Lepomis macrochirus 96 hours
Chronic NOEC 360 mg/l Fresh water Daphnia – Daphnia magna –
Neonate
3 weeks
Chronic NOEC 233 mg/l Fresh water Fish – Coregonus albula – Egg 60 days
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Do not cut, weld or grind used containers unless they have been cleaned thoroughly
internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways,
drains and sewers.
:Disposal methods
Section 14. Transport information
UN3108 UN3108
DOT
Classification
IMDG
UN number
TDG
Classification
UN3108
Mexico
Classification
UN3108
IATA
UN3108
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Section 14. Transport information
ORGANIC
PEROXIDE TYPE
E, SOLID
(Dibenzoyl
peroxide)
5.2
–
ORGANIC
PEROXIDE TYPE
E, SOLID
(Dibenzoyl
peroxide). Marine
pollutant
(Dibenzoyl
peroxide, Zinc
Stearate)
5.2
–
– The marine
pollutant mark is
not required when
transported in
sizes of 5 L or 5
kg.
Emergency
schedules F-J, S-
R
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
Special precautions for user
Transport in bulk according
to IMO instruments
No. Yes.
Not available.
:
Proper shipping name :
Not available.
:
ORGANIC
PEROXIDE TYPE
E, SOLID
(Dibenzoyl
peroxide)
5.2
–
No.
Product classified
as per the
following sections
of the
Transportation of
Dangerous Goods
Regulations:
2.23-2.25 (Class
5).
ORGANIC
PEROXIDE TYPE
E, SOLID
(Dibenzoyl
peroxide)
5.2
–
No.
–
Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability prior
to shipment, and compliance with the applicable regulations is the sole responsibility
of the person offering the product for transport. People loading and unloading
dangerous goods must be trained on all of the risks deriving from the substances
and on all actions in case of emergency situations.
ORGANIC
PEROXIDE
TYPE E, SOLID
(Dibenzoyl
peroxide)
5.2
–
Yes. The
environmentally
hazardous
substance mark
is not required.
The
environmentally
hazardous
substance mark
may appear if
required by other
transportation
regulations.
145
ERG No.
145 145
ERG No. ERG No.
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Section 15. Regulatory information
All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED
and rely on information provided to us by our raw material suppliers. Our suppliers often provide an estimated value or
range less than a certain upper limit. We calculate MAXIMUM THEORETICAL VALUES using defined values, if provided,
or the upper limit reported by our supplier. Additionally, the suppliers information may include amounts present in the
product as unintentional byproducts or impurities. Variations may occur in individual batches due to adjustments made
during production. Reporting of chemicals in this section does not necessarily indicate their presence in the final
formulated product.
WARNING: This product contains a chemical known to the State of California to cause cancer.
California Prop. 65
Australia inventory (AIIC): Not determined.
China inventory (IECSC): Not determined.
Japan inventory (CSCL): Not determined.
Japan inventory (ISHL): Not determined.
Korea inventory (KECI): Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
Taiwan Chemical Substances Inventory (TCSI): Not determined.
Thailand inventory: Not determined.
Turkey inventory: Not determined.
Vietnam inventory: Not determined.
International regulations
International lists :
Montreal Protocol
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Zinc Compound 6
Dibenzoyl peroxide 50 94-36-0
Ingredient name CAS number% by weight
SARA 313
Section 16. Other information
Hazardous Material Information System (U.S.A.)
2
0
4
*
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS
ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS
Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual.
Procedure used to derive the classification
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Section 16. Other information
1/15/2025
History
Date of printing
Date of issue/Date of
revision
Version
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer,
or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements
are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is
responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The
conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is
responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user
should not use the product for any purpose other than the purpose shown in the applicable section of this SDS
without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of
sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs
obtained from any other source.
Date of previous issue
:
:
:
:
Indicates information that has changed from previously issued version.
Key to abbreviations :
1/15/2025
12/13/2024
13.03
ORGANIC PEROXIDES – Type E Expert judgment
SKIN CORROSION/IRRITATION – Category 2 Calculation method
SERIOUS EYE DAMAGE/ EYE IRRITATION – Category 2A Calculation method
SKIN SENSITIZATION – Category 1 Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) – Category 2 Calculation method
Classification Justification
Notice to reader
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. (“Marpol” = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
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3M Dyanatron White Cream Hardener 308, 30759 01/23/14
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Safety Data Sheet
Copyright,2014,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2)neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document Group: 24-8015-0 Version Number: 5.00
Issue Date: 01/23/14 Supercedes Date: 10/01/12
SECTION 1: Identification
1.1. Product identifier
3M Dyanatron White Cream Hardener 308, 30759
Product Identification Numbers
70-0080-0378-5, 70-0080-0379-3
1.2. Recommended use and restrictions on use
Recommended use
Automotive, Hardener for body fillers
1.3. Supplier s details
MANUFACTURER: 3M
DIVISION: Automotive Aftermarket
ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA
Telephone: 1-888-3M HELPS (1-888-364-3577)
1.4. Emergency telephone number
1-800-364-3577 or (651) 737-6501 (24 hours)
SECTION 2: Hazard identification
The label elements belowwere prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200.
This information may be different from the actual product label information for labels regulated by other agencies.
2.1. Hazard classification
Organic Peroxide: Type E.
Serious Eye Damage/Irritation: Category 2A.
Skin Sensitizer: Category 1.
2.2. Label elements
Signal word
Warning
Symbols
Flame | Exclamation mark |
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Pictograms
Hazard Statements
Heating may cause a fire.
Causes serious eye irritation.
Maycause an allergic skin reaction.
Precautionary Statements
General:
Keep out of reach of children.
If medical advice is needed, have product container or label at hand.
Prevention:
Keep awayfrom heat/sparks/open flames/hot surfaces. -No smoking.
Keep awayfrom clothing and other combustible materials.
Keep only in original container.
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves and eye/face protection.
Wash thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.
Response:
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention.
IF ON SKIN: Wash with plenty of soap and water.
If skin irritation or rash occurs: Get medical advice/attention.
Wash contaminated clothing before reuse.
Storage:
Protect from sunlight.
Store at temperatures not exceeding 32C/90F. Keep cool.
Store awayfrom other materials.
Disposal:
Dispose of contents/container in accordance with applicable local/regional/national/international regulations.
Notes to Physician:
Not applicable
2.3. Hazards not otherwise classified
None.
4% of the mixture consists of ingredients of unknown acute dermal toxicity.
SECTION 3: Composition/information on ingredients
Ingredient C.A.S. No. % by Wt
Benzoyl Peroxide 94-36-0 30 -60 Trade Secret *
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Benzoic Acid, C9-11-Branched Alkyl Esters 131298-44-7 10 -30 Trade Secret *
Water 7732-18-5 10 -30 Trade Secret *
Calcium Sulfate 7778-18-9 3 -7 Trade Secret *
Zinc Stearate 557-05-1 3 -7 Trade Secret *
Oxirane, Polymer with Methyloxirane, Monobutyl Ether9038-95-3 1 -5 Trade Secret *
*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.
Skin Contact:
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop,
get medical attention.
Eye Contact:
Immediatelyflush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical
attention.
If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1. Information on toxicological effects.
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.
5.2. Special hazards arising fromthe substance or mixture
Closed containers exposed to heat from fire may build pressure and explode.
5.3. Special protective actions for fire-fighters
No unusual fire or explosion hazards are anticipated.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Eliminate all ignition sources if safe to do so. Keep away from heat/sparks/open flames/hot surfaces. -No
smoking. Use only non-sparking tools. Ventilate the area with fresh air. Refer to other sections of this SDS for information
regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions
Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or
bodies of water.
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6.3. Methods and material for containment and cleaning up
Collect as much of the spilled material as possible using non-sparking tools. Place in a closed container approved for
transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized
person. Ventilate the area with fresh air. Read and followsafety precautions on the solvent label and SDS. Clean up residue.
Seal the container. Dispose of collected material as soon as possible.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Avoid eye contact. Keep out of reach of children. Keep away from heat/sparks/open flames/hot surfaces. -No smoking.
Avoid breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke
when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the
workplace. Avoid release to the environment. Wash contaminated clothing before reuse.
7.2. Conditions for safe storage including anyincompatibilities
Protect from sunlight. Store at temperatures not exceeding 32C/90F. Keep cool. Keep only in original container. Store
away from other materials. Keep/store awayfrom clothing and other combustible materials.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Occupational exposure limits
Ingredient C.A.S. No.Agency Limit type Additional Comments
STEARATES 557-05-1Amer Conf of
Gov. Indust.
Hyg.
TWA:10 mg/m3
Zinc Stearate 557-05-1US Dept of
Labor -OSHA
TWA(as total dust):15
mg/m3;TWA(respirable
fraction):5 mg/m3
Calcium Sulfate 7778-18-9Amer Conf of
Gov. Indust.
Hyg.
TWA(inhalable fraction):10
mg/m3
Calcium Sulfate 7778-18-9US Dept of
Labor -OSHA
TWA(as total dust):15
mg/m3;TWA(respirable
fraction):5 mg/m3
Benzoyl Peroxide 94-36-0 Amer Conf of
Gov. Indust.
Hyg.
TWA:5 mg/m3
Benzoyl Peroxide 94-36-0 US Dept of
Labor -OSHA
TWA:5 mg/m3
Amer Conf of Gov. Indust. Hyg. : American Conference of Governmental Industrial Hygienists
American Indust. Hygiene Assoc : American Industrial Hygiene Association
Chemical Manufacturer Rec Guid : Chemical Manufacturer’s Recommended Guidelines
US Dept of Labor -OSHA : United States Department of Labor -Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to belowrelevant Exposure
Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.
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8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Indirect Vented Goggles
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing.
Gloves made from the following material(s) are recommended: Nitrile Rubber
Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective
clothing material(s) are recommended: If this product is used in a manner that presents a higher potential for exposure (eg.
spraying, high splash potential etc.), then use of protective coveralls may be necessary. Apron Nitrile
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator
type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
General Physical Form: Solid
Specific Physical Form: Viscous
Odor, Color, Grade: White paste with slight ester odor
Odor threshold No Data Available
pH No Data Available
Melting point No Data Available
Boiling Point [Details: Decomposes]
Flash Point 111 C [Test Method: Estimated]
Evaporation rate Not Applicable
Flammability (solid, gas) Organic Peroxide: Type E.
Flammable Limits(LEL) Not Applicable
Flammable Limits(UEL) Not Applicable
Vapor Pressure Not Applicable
Vapor Density Not Applicable
Specific Gravity 1.2 [@ 25 C] [Ref Std: WATER=1]
Solubility in Water Negligible
Solubility-non-water No Data Available
Partition coefficient: n-octanol/ water No Data Available
Autoignition temperature No Data Available
Decomposition temperature No Data Available
Viscosity No Data Available
Hazardous Air Pollutants 0 % weight [Test Method: Calculated]
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Volatile Organic Compounds 0 g/l [Test Method: calculated SCAQMD rule 443.1]
Volatile Organic Compounds 0 % weight [Test Method: calculated per CARB title 2]
Percent volatile 20 % [Details: Water is the volatile component]
VOC Less H2O & Exempt Solvents 0 g/l [Test Method: calculated SCAQMD rule 443.1]
SECTION 10: Stability and reactivity
10.1. Reactivity
This material may be reactive with certain agents under certain conditions -see the remaining headings in this section.
10.2. Chemical stability
Stable. Stable unless exposed to heat, flames and drying conditions.
10.3. Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4. Conditions to avoid
Not determined
10.5. Incompatible materials
Accelerators
10.6. Hazardous decomposition products
Substance Condition
Carbon monoxide Not Specified
Carbon dioxide Not Specified
Toxic Vapor, Gas, Particulate Not Specified
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material clas sification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1. Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation:
Vapors released during curing may cause irritation of the respiratory system. Signs/symptoms may include cough, sneezing,
nasal discharge, headache, hoarseness, and nose and throat pain.
Dust from cutting, grinding, sanding or machining may cause irritation of the respiratory system. Signs/symptoms may
include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.
Skin Contact:
Maybe harmful in contact with skin.
Contact with the skin during product use is not expected to result in significant irritation. Allergic Skin Reaction (non-photo
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induced): Signs/symptoms may include redness, swelling, blistering, and itching.
Eye Contact:
Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the
cornea, and impaired vision.
Dust created by cutting, grinding, sanding, or machining may cause eye irritation. Signs/symptoms may include redness,
swelling, pain, tearing, and blurred or hazy vision.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
Name Route SpeciesValue
Overall product Dermal No data available; calculated ATE 4,464.3 mg/kg
Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg
Benzoyl Peroxide Dermal LD50 estimated to be 2,000 -5,000 mg/kg
Benzoyl Peroxide Inhalation-
Dust/Mist
(4 hours)
Rat LC50 > 24.3 mg/l
Benzoyl Peroxide IngestionRat LD50 > 5,000 mg/kg
Benzoic Acid, C9-11-Branched Alkyl Esters Dermal Rabbit LD50 > 2,000 mg/kg
Benzoic Acid, C9-11-Branched Alkyl Esters Inhalation-
Dust/Mist
(4 hours)
Rat LC50 2 mg/l
Benzoic Acid, C9-11-Branched Alkyl Esters IngestionRat LD50 > 5,000 mg/kg
Zinc Stearate Dermal Rabbit LD50 > 2,000 mg/kg
Zinc Stearate IngestionRat LD50 > 5,000 mg/kg
Oxirane, Polymer with Methyloxirane, Monobutyl EtherDermal Rabbit LD50 > 16,960 mg/kg
Calcium Sulfate IngestionRat LD50 > 5,000 mg/kg
Oxirane, Polymer with Methyloxirane, Monobutyl EtherInhalation-
Dust/Mist
(4 hours)
Rat LC50 > 5 mg/l
Oxirane, Polymer with Methyloxirane, Monobutyl EtherIngestionRat LD50 4,240 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name SpeciesValue
Benzoyl Peroxide Rabbit Minimal irritation
Benzoic Acid, C9-11-Branched Alkyl Esters Data not available or insufficient for classification
Zinc Stearate Data not available or insufficient for classification
Calcium Sulfate Data not available or insufficient for classification
Oxirane, Polymer with Methyloxirane, Monobutyl Ether Rabbit Minimal irritation
Serious Eye Damage/Irritation
Name SpeciesValue
Benzoyl Peroxide Rabbit Severe irritant
Benzoic Acid, C9-11-Branched Alkyl Esters Data not available or insufficient for classification
Zinc Stearate Data not available or insufficient for classification
Calcium Sulfate Data not available or insufficient for classification
Oxirane, Polymer with Methyloxirane, Monobutyl Ether Rabbit No significant irritation
Skin Sensitization
Name SpeciesValue
Benzoyl Peroxide Human
and
animal
Sensitizing
Benzoic Acid, C9-11-Branched Alkyl Esters Data not available or insufficient for classification
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Zinc Stearate Data not available or insufficient for classification
Calcium Sulfate Data not available or insufficient for classification
Oxirane, Polymer with Methyloxirane, Monobutyl Ether Data not available or insufficient for classification
Respiratory Sensitization
Name SpeciesValue
Benzoyl Peroxide Data not available or insufficient for classification
Benzoic Acid, C9-11-Branched Alkyl Esters Data not available or insufficient for classification
Zinc Stearate Data not available or insufficient for classification
Calcium Sulfate Data not available or insufficient for classification
Oxirane, Polymer with Methyloxirane, Monobutyl Ether Data not available or insufficient for classification
Germ Cell Mutagenicity
Name Route Value
Benzoyl Peroxide In VitroNot mutagenic
Benzoyl Peroxide In vivo Not mutagenic
Benzoic Acid, C9-11-Branched Alkyl Esters Data not available or insufficient for classification
Zinc Stearate Data not available or insufficient for classification
Calcium Sulfate Data not available or insufficient for classification
Oxirane, Polymer with Methyloxirane, Monobutyl Ether Data not available or insufficient for classification
Carcinogenicity
Name Route SpeciesValue
Benzoyl Peroxide IngestionMultiple
animal
species
Not carcinogenic
Benzoyl Peroxide Dermal Mouse Some positive data exist, but the data are not
sufficient for classification
Benzoic Acid, C9-11-Branched Alkyl Esters Data not available or insufficient for classification
Zinc Stearate Data not available or insufficient for classification
Calcium Sulfate Data not available or insufficient for classification
Oxirane, Polymer with Methyloxirane, Monobutyl Ether IngestionRat Not carcinogenic
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value SpeciesTest Result Exposure
Duration
Benzoyl Peroxide IngestionNot toxic to female reproductionRat NOAEL
1,000
mg/kg/day
premating &
during
gestation
Benzoyl Peroxide IngestionSome positive male reproductive data
exist, but the data are not sufficient for
classification
Rat NOAEL 500
mg/kg/day
premating &
during
gestation
Benzoyl Peroxide IngestionSome positive developmental data exist,
but the data are not sufficient for
classification
Rat NOAEL 500
mg/kg/day
premating &
during
gestation
Benzoic Acid, C9-11-Branched Alkyl
Esters
Data not available or insufficient for
classification
Zinc Stearate Data not available or insufficient for
classification
Calcium Sulfate Data not available or insufficient for
classification
Oxirane, Polymer with Methyloxirane,
Monobutyl Ether
IngestionNot toxic to female reproductionRat NOAEL
3,770
mg/kg/day
90 days
Oxirane, Polymer with Methyloxirane,
Monobutyl Ether
IngestionNot toxic to male reproduction Rat NOAEL
3,770
mg/kg/day
90 days
Oxirane, Polymer with Methyloxirane,
Monobutyl Ether
InhalationSome positive male reproductive data
exist, but the data are not sufficient for
classification
Rat NOAEL 1
mg/l
2 weeks
Target Organ(s)
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Specific Target Organ Toxicity -single exposure
Name Route Target Organ(s)Value SpeciesTest Result Exposure
Duration
Benzoyl Peroxide Data not available or insufficient
for classification
Benzoic Acid, C9-11-
Branched Alkyl Esters
Data not available or insufficient
for classification
Zinc Stearate Data not available or insufficient
for classification
Oxirane, Polymer with
Methyloxirane, Monobutyl
Ether
Ingestionnervous system Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL Not
available
Calcium Sulfate Data not available or insufficient
for classification
Specific Target Organ Toxicity -repeated exposure
Name Route Target Organ(s) Value SpeciesTest Result Exposure
Duration
Benzoyl Peroxide Data not available or insufficient
for classification
Benzoic Acid, C9-11-
Branched Alkyl Esters
Data not available or insufficient
for classification
Zinc Stearate Data not available or insufficient
for classification
Oxirane, Polymer with
Methyloxirane, Monobutyl
Ether
Inhalationendocrine system |
hematopoietic
system | liver |
nervous system
Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL 1
mg/l
2 weeks
Oxirane, Polymer with
Methyloxirane, Monobutyl
Ether
Inhalationkidney and/or
bladder
Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL .005
mg/l
2 weeks
Oxirane, Polymer with
Methyloxirane, Monobutyl
Ether
Inhalationrespiratory systemSome positive data exist, but the
data are not sufficient for
classification
Rat LOAEL .001
mg/l
2 weeks
Oxirane, Polymer with
Methyloxirane, Monobutyl
Ether
Inhalationheart All data are negative Rat NOAEL .5
mg/l
2 weeks
Oxirane, Polymer with
Methyloxirane, Monobutyl
Ether
Ingestionliver | kidney and/or
bladder
Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL 145
mg/kg/day
90 days
Oxirane, Polymer with
Methyloxirane, Monobutyl
Ether
Ingestionhematopoietic
system
All data are negative Rat NOAEL 500
mg/kg/day
2 years
Oxirane, Polymer with
Methyloxirane, Monobutyl
Ether
Ingestionheart | endocrine
system | respiratory
system
All data are negative Rat NOAEL
3,770
mg/kg/day
90 days
Calcium Sulfate Data not available or insufficient
for classification
Aspiration Hazard
Name Value
Benzoyl Peroxide Not an aspiration hazard
Benzoic Acid, C9-11-Branched Alkyl Esters Not an aspiration hazard
Zinc Stearate Not an aspiration hazard
Calcium Sulfate Not an aspiration hazard
Oxirane, Polymer with Methyloxirane, Monobutyl Ether Not an aspiration hazard
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
SECTION 12: Ecological information
Ecotoxicological information
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Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.
SECTION 13: Disposal considerations
13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.
Incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional
fuel during incineration processes. As a disposal alternative, Dispose of waste product in a permitted industrial waste
facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical
substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated &
disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective
regulating authorities to determine the available treatment anddisposal facilities.
SECTION 14: Transport Information
For Transport Information, please visit http://3M.com/Transportinfoor call 1-800-364-3577 or 651-737-6501.
SECTION 15: Regulatory information
15.1. US Federal Regulations
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard -No Pressure Hazard -No Reactivity Hazard -Yes Immediate Hazard -Yes Delayed Hazard -Yes
Section 313 Toxic Chemicals subject to the reporting requirements of thatsection and 40 CFR part 372 (EPCRA):
Ingredient C.A.S. No % by Wt
Zinc Stearate (ZINC COMPOUNDS) 557-05-1 3 -7
Benzoyl Peroxide 94-36-0 30 -60
15.2. State Regulations
Contact 3M for more information.
15.3. Chemical Inventories
The components of this product are in compliance with the chemical notification requirements of TSCA.
Contact 3M for more information.
15.4. International Regulations
Contact 3M for more information.
This SDS has been prepared to meet the U.S. OSHA Haza rd Communication Standard, 29 CFR 1910.1200.
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SECTION 16: Other information
NFPA Hazard Classification
Health:2 Flammability:2 Instability:1 Special Hazards:Oxidizer
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
Document Group: 24-8015-0 Version Number: 5.00
Issue Date: 01/23/14 Supercedes Date: 10/01/12
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product isfit for a particular purpose and suitable
for user’s method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user’s knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user’s method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M
3MUSA SDSs are available at www.3M.com
